{"id":223136,"date":"2021-06-11T14:00:41","date_gmt":"2021-06-11T06:00:41","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=223136"},"modified":"2021-06-11T10:57:56","modified_gmt":"2021-06-11T02:57:56","slug":"%e6%9c%80%e6%96%b0-acc-chem-res-%ef%bc%9a%e5%b1%82%e7%8a%b6%e6%9d%82%e5%8c%96%e7%94%b2%e8%84%92%e7%a2%98%e5%8c%96%e9%93%85%e9%92%99%e9%92%9b%e7%9f%bf%ef%bc%9a%e6%8c%91%e6%88%98%e4%b8%8e%e6%9c%ba","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=223136","title":{"rendered":"\u6700\u65b0 Acc. Chem. Res.\uff1a\u5c42\u72b6\u6742\u5316\u7532\u8112\u7898\u5316\u94c5\u9499\u949b\u77ff\uff1a\u6311\u6218\u4e0e\u673a\u9047"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u6742\u5316\u5364\u5316\u7269\u9499\u949b\u77ff\u6750\u6599\u5df2\u6210\u4e3a\u5404\u79cd\u5149\u7535\u5e94\u7528\u7684\u4e3b\u8981\u5019\u9009\u6750\u6599\u4e4b\u4e00\u3002\u5b83\u4eec\u57fa\u4e8e\u7531AMX3<\/sub>\u7ec4\u6210\u5b9a\u4e49\u7684\u6709\u673a-\u65e0\u673a\u7ed3\u6784\uff0cA\u662f\u4e2d\u5fc3\u9633\u79bb\u5b50\uff0c\u662f\u6709\u673a\uff08\u7532\u57fa\u94f5\u3001\u7532\u8112\uff08FA\uff09\u7b49\uff09\u6216\u65e0\u673a\uff08Cs+<\/sup>\u7b49\uff09\uff0cM\u662f\u4e8c\u4ef7\u91d1\u5c5e\u79bb\u5b50\uff08Pb2+<\/sup>\u3001Sn2+<\/sup>\u7b49\uff09\uff0cX\u662f\u5364\u5316\u7269\u9634\u79bb\u5b50\uff08I–<\/sup>\u3001Br–<\/sup>\u6216Cl–<\/sup>\uff09\uff0c\u7279\u522b\u662fFAPbI3<\/sub>\u9499\u949b\u77ff\u5177\u6709\u4f18\u5f02\u7684\u5149\u7535\u6027\u80fd\u548c\u70ed\u7a33\u5b9a\u6027\u3002\u7136\u800c\uff0c\u5149\u6d3b\u6027\u03b1-FAPbI3<\/sub>\uff08\u9ed1\u8272\uff09\u9499\u949b\u77ff\u76f8\u5728\u5ba4\u6e29\u4e0b\u6ca1\u6709\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\uff0c\u5e76\u5f62\u6210\u4e0d\u9002\u5408\u5149\u7535\u5e94\u7528\u7684\u03b4-FAPbI3<\/sub>\uff08\u9ec4\u8272\uff09\u76f8\uff0c\u56e0\u6b64\u7814\u7a76\u4eba\u5458\u4e3a\u7a33\u5b9a\u548c\u5b9e\u73b0\u03b1-FAPbI3<\/sub>\u9499\u949b\u77ff\u76f8\u800c\u8fdb\u884c\u4e86\u5927\u91cf\u7814\u7a76\u5de5\u4f5c\u3002\u6b64\u5916\uff0c\u6742\u5316\u9499\u949b\u77ff\u5728\u5916\u754c\u73af\u5883\uff08\u7a7a\u6c14\u548c\u6e7f\u6c14\uff09\u548c\u5668\u4ef6\u5de5\u4f5c\u6761\u4ef6\uff08\u7535\u538b\u548c\u5149\uff09\u4e0b\u5177\u6709\u4e0d\u7a33\u5b9a\u6027\u3002\u57fa\u4e8e\u4f4e\u7ef4\u6742\u5316\u9499\u949b\u77ff\u6750\u6599\u53ef\u4ee5\u514b\u670d\u8fd9\u4e9b\u4e0d\u7a33\u5b9a\u6027\uff0c\u7279\u522b\u662f\u7531\u5206\u79bb\u6742\u5316\u9499\u949b\u77ff\u677f\u7684\u6709\u673a\u5c42\u7ec4\u6210\u7684\u5c42\u72b6\u4e8c\u7ef4\uff082D\uff09\u9499\u949b\u77ff\u76f8\uff0c\u5bf9\u73af\u5883\u6761\u4ef6\u548c\u79bb\u5b50\u8fc1\u79fb\u66f4\u4e3a\u7a33\u5b9a\u3002\u8fd9\u4e9b\u6750\u6599\u4e3b\u8981\u57fa\u4e8eSx<\/sub>An-1<\/sub>Pbn<\/sub>X3n+1<\/sub>\u7ec4\u6210\uff0c\u5177\u6709\u5404\u79cd\u5355\uff08x=1\uff09\u6216\u53cc\u529f\u80fd\uff08x=2\uff09\u6709\u673a\u95f4\u9694\u9633\u79bb\u5b50\uff0c\u8fd9\u4e9b\u9633\u79bb\u5b50\u6a21\u677f\u6df7\u5408\u9499\u949b\u77ff\u677f\u5e76\u901a\u5e38\u5f62\u6210Ruddlesden-Popper\uff08RP\uff09\u6216Dion-Jacobson\uff08DJ\uff09\u76f8\u3002\u8fd9\u4e9b\u6750\u6599\u4e3a\u5929\u7136\u91cf\u5b50\u9631\uff0c\u968f\u7740\u65e0\u673a\u5c42\uff08n\uff09\u7684\u6570\u91cf\u4ecen=1\uff082D\uff09\u589e\u52a0\u5230n=\u221e\uff083D\uff09\u800c\u5e26\u9699\u9010\u6e10\u51cf\u5c0f\u3002\u867d\u7136\u5df2\u5f00\u53d1\u51fa\u5404\u79cd\u5c42\u72b62D\u9499\u949b\u77ff\uff0c\u4f46\u662f\u5b83\u4eec\u7684FA\u57fa\u7c7b\u4f3c\u7269\u4ee3\u8868\u6027\u4ecd\u7136\u4e0d\u8db3\u3002\u4e00\u4e9b\u7814\u7a76\u8fdb\u5c55\u4f7f\u5f97FA\u57fa\u5c42\u72b6\u9499\u949b\u77ff\u5f97\u4ee5\u5b9e\u73b0\uff0cFAPbBr3<\/sub>\u57fa\u5c42\u72b6\u9499\u949b\u77ff\u5728\u5149\u7535\u5e94\u7528\u4e2d\u663e\u793a\u51fa\u4e86\u6f5c\u529b\uff0c\u800cFAPbI3<\/sub>\u57fa\u9499\u949b\u77ff\u5728\u5149\u7535\u9886\u57df\u7684\u5e94\u7528\u4e5f\u5f15\u8d77\u4e86\u7279\u522b\u5173\u6ce8\uff0c\u4fc3\u8fdb\u4e86\u8fdb\u4e00\u6b65\u7684\u53d1\u5c55\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u745e\u58eb\u6d1b\u6851\u8054\u90a6\u7406\u5de5\u5b66\u9662\uff08EPFL\uff09Michael Gr\u00e4tzel\u548cMichael Gr\u00e4tzel\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u7bc7\u5173\u4e8e\u5c42\u72b6\u6742\u5316\u7532\u8112\u7898\u5316\u9499\u949b\u77ff\u6750\u6599\u53d1\u5c55\u673a\u9047\u548c\u6311\u6218\u7684\u7efc\u8ff0\u3002\u5728\u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u6982\u8ff0\u4e86\u57fa\u4e8e\u5c42\u72b6FAPbI3<\/sub>\u9499\u949b\u77ff\u7684\u6700\u65b0\u8fdb\u5c55\u53ca\u5176\u7ed3\u6784\u548c\u5149\u7535\u7279\u6027\uff0c\u5e76\u4e14\u57fa\u4e8e\u4ee3\u8868\u6027\u793a\u4f8b\u548c\u6a21\u578b\u7cfb\u7edf\u7279\u522b\u5173\u6ce8\u5b83\u4eec\u7684\u65b0\u5174\u7279\u6027\u548c\u5728\u5149\u4f0f\u4e2d\u7684\u5e94\u7528\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fdb\u4e00\u6b65\u8ba8\u8bba\u4e86\u4e0e\u8fd9\u4e9b\u6742\u5316\u6750\u6599\u76f8\u5173\u7684\u6301\u7eed\u6311\u6218\uff0c\u5e76\u4e14\u63ed\u793a\u4e86\u5b83\u4eec\u7684\u5e94\u7528\u673a\u4f1a\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cLayered Hybrid Formamidinium Lead Iodide Perovskites: Challenges and Opportunities\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAcc. Chem. Res.<\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001FA\u57fa\u5c42\u72b6\u9499\u949b\u77ff<\/strong>
\n \"\"\uff08a\uff09\u9876\u90e8\uff1a\u5177\u6709\u5206\u5b50\u5f0fABX3<\/sub>\u548c\u7531\u5171\u4eab\u89d2[MX6<\/sub>]4-<\/sup>\u516b\u9762\u4f53\u5f62\u6210\u7acb\u65b9\u7ed3\u6784\u7684\u6742\u5316\u9499\u949b\u77ff\u7684\u7ed3\u6784\u3002\u5e95\u90e8\uff1aFA\u9633\u79bb\u5b50\u7684\u5171\u632f\u7a33\u5b9a\uff1b<\/p>\n

\uff08b\uff09FAPbI3<\/sub>\u7684\u80fd\u91cf\u56fe\u8c31\uff0c\u5177\u67093D \u03b1-FAPbI3<\/sub>\u9499\u949b\u77ff\u76f8\u548c1D \u03b4-FAPbI3<\/sub> \u76f8\u5728\u73af\u5883\u6e29\u5ea6\u4e0b\u70ed\u529b\u5b66\u66f4\u7a33\u5b9a\uff1b<\/p>\n

\uff08c\uff09\u5206\u5b50\u8c03\u5236\u76843D\u548c2D\u9499\u949b\u77ff\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08d\uff09\u03b1-FAPbI3<\/sub>\u7684\u7a33\u5b9a\u6027\u548c2D\u9499\u949b\u77ff\u5f62\u6210\u7684\u4ee3\u8868\u6027\u6709\u673a\u90e8\u5206\u7684\u7ed3\u6784\u3002<\/p>\n

\u56fe\u4e8c\u3001\u4ee3\u8868\u6027FA\u57fa\u5c42\u72b6\u9499\u949b\u77ff\u7684\u7ed3\u6784\u7279\u6027<\/strong>
\n \"\"\uff08a-b\uff09RP\u548cDJ\u76f8\u4f4d\u7684\u793a\u610f\u56fe\uff0c\u5206\u522b\u5e26\u6709ADAM\u548cPDMA\u57ab\u7247\uff0c\u4f5c\u4e3a\u6700\u8fd1\u7814\u7a76\u7684\u6a21\u578b\u7cfb\u7edf\uff1b<\/p>\n

\uff08c\uff09(ADAM)2<\/sub>FAn-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\uff08n=1-3\uff09\u8584\u819c\u7684XRD\u56fe\uff1b<\/p>\n

\uff08d-e\uff09\u673a\u68b0\u5316\u5b66\u5236\u5907\u7684(ADAM)2<\/sub>FAn-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\uff08n=1-3\uff09\u7ec4\u5408\u7269\u7684\u56fa\u6001NMR\u5149\u8c31\uff1b<\/p>\n

\uff08f\uff09\u5de6\u56fe\uff1a(ADAM)2<\/sub>FA2<\/sub>Pb3<\/sub>I10<\/sub>\u7ed3\u6784\u793a\u610f\u56fe\u3002\u53f3\u56fe\uff1aA2<\/sub>FA2<\/sub>Pb3<\/sub>I10<\/sub>\u7ec4\u5408\u7269\u572821.1 T\u548c298 K\u4e0b\u76841<\/sup>H\u20131<\/sup>H SD\u56fa\u600120 kHz MAS NMR\u5149\u8c31\uff0c\u6df7\u5408\u65f6\u95f4\u4e3a3 \u03bcs\u548c23 ms\u3002<\/p>\n

\uff08g\uff09(PDMA)FAn-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\u8584\u819c\u7684XRR\u56fe\u6848\uff0c\u5176\u4e2dn=1\u30012\u548c3\u3002<\/p>\n

\u56fe\u4e09\u3001\u4ee3\u8868\u6027FA\u57fa\u5c42\u72b6\u9499\u949b\u77ff\u7684\u7ed3\u6784\u590d\u6742\u6027\u548c\u53d6\u5411<\/strong>
\n \"\"\uff08a\uff09n=1\u3001n=2\u548cn=3\u65f6\uff0cFTO\/mp-TiO2<\/sub>\u4e0a(PDMA)FAn-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\u8584\u819c\u7684q<\/em>\u6620\u5c04\u7684\u5f84\u5411\u79ef\u5206\u5f3a\u5ea6\uff1b<\/p>\n

\uff08b\uff09(ADAM)2<\/sub>FAn-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\u8584\u819c\u7684\u5165\u5c04\u89d2\u4e3a0.12\u00b0\u7684GIWAXS\u5012\u6613\u7a7a\u95f4\u56fe\uff1b<\/p>\n

\uff08c\uff09\u5728FTO\/mp-TiO2<\/sub>\u4e0a(PDMA)FAn-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\u8584\u819c\u7684GIWAXS\u5012\u6613\u7a7a\u95f4\u56fe\uff08\u03b1<\/em>i<\/sub>=0.1\u00b0\uff09\uff1b<\/p>\n

\uff08d\uff09DFT\u8ba1\u7b97FAPbI3<\/sub>\u3001(PDMA)FAn-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\u548c(ADAM)2<\/sub>FAn-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\u76f8\u7684\u76f8\u5bf9\u5f62\u6210\u7113\u3002<\/p>\n

\u56fe\u56db\u3001\u5c42\u72b6\u6742\u5316\u9499\u949b\u77ff\u4e2d\u7684\u6a21\u677f\u6548\u5e94<\/strong>
\n \"\"\uff08a-b\uff09\u5c42\u72b6\u9499\u949b\u77ff\u7684\u793a\u610f\u56fe\uff0c\u901a\u8fc7\u6709\u673a\u95f4\u9694\u7269\u7684\u7ed3\u6784\u5bfc\u5411\u4f5c\u7528\u6e17\u900f\u5230\u65e0\u673a\u9aa8\u67b6\u4e2d\uff0c\u7279\u5f81\u8ddd\u79bb\u4e3ad<\/em>1<\/sub>\u3001d<\/em>2<\/sub>\u548cd<\/em>3<\/sub>\uff1b<\/p>\n

\uff08c\uff09(ADAM)2<\/sub>PbI4<\/sub>\u7684DFT\u8ba1\u7b97\u548c\u5b9e\u9a8cXRD\u56fe\u6848\uff1b<\/p>\n

\uff08d-e\uff09DFT\u8ba1\u7b97\u7684(ADAM)2<\/sub>PbI4<\/sub>\u548c (PDMA)PbI4<\/sub>\u7ed3\u6784\uff1b<\/p>\n

\uff08f\uff09\u5176\u4ed6\u62a5\u9053\u7684FAPbI3<\/sub>\u57fa\u5c42\u72b6\u9499\u949b\u77ff\u76f8\u5229\u7528\u6b63\u620a\u57fa\u94f5\uff08PA\uff09\u548c2-\u567b\u5429\u7532\u57fa\u94f5\uff08TMA\uff09\u4e3a\u95f4\u9694\u7269\u3002<\/p>\n

\u56fe\u4e94\u3001\u5c42\u72b6\u6742\u5316\u9499\u949b\u77ff\u7684\u5149\u7535\u7279\u6027<\/strong>
\n \"\"\uff08a\uff09\u6709\u673a\u5c42\u7684\u80fd\u91cf\u6392\u5217\u793a\u610f\u56fe\uff0c\u4ee5\u53ca\u5b9a\u4e49\u5e26\u9699\uff08E<\/em>g<\/sub>\uff09\u76842D\u9499\u949b\u77ff\u65e0\u673a\u5c42\u7684\u5bfc\u5e26\uff08CB\uff09\u548c\u4ef7\u5e26\uff08VB\uff09\u8fb9\u7f18\uff1b<\/p>\n

\uff08b\uff09\u57fa\u4e8e\u5149\u5b66\u6027\u8d28\u548c\u5305\u62ec\u81ea\u65cb-\u8f68\u9053\u8026\u5408\u5728\u5185\u7684PBE0\u6c34\u5e73\u4e0a\u7684DFT\u8ba1\u7b97\uff0c\u5b9a\u4e492D\u30012D\/3D\u548c3D\u76f8\u7684\u4ee3\u8868\u60272D\u7ec4\u6210\u7269\uff08n\uff09\u7684\u80fd\u5e26\u9699\u4f30\u7b97\uff1b<\/p>\n

\uff08c-d\uff09(ADAM)FAn-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\u548c(PDMA)FAn-1<\/sub>Pbn<\/sub>I3n+1<\/sub>\uff08n=1-3\uff09\u5728FTO\/mp-TiO2<\/sub>\u548cFTO\/mp-Al2<\/sub>O3<\/sub>\u57fa\u677f\u4e0a\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

\uff08e-f\uff09ADAM2<\/sub>PbI4<\/sub>\u548cPDMAPbI4<\/sub>\u7684VB\u9876\u90e8\u548cCB\u5e95\u90e8\u7684\u8ba1\u7b97\u8f68\u9053\u3002<\/p>\n

\u56fe\u516d\u3001\u5149\u4f0f\u6027\u80fd\u548c\u7a33\u5b9a\u6027<\/strong>
\n \"\"\uff08a-b\uff09\u4ee3\u8868\u60272D\u548c2D\/3D\u9499\u949b\u77ff\u7ed3\u6784\u7684\u7535\u6d41-\u7535\u538b\u7279\u6027\uff1b<\/p>\n

\uff08c\uff09\u901a\u8fc7\u8fde\u7eed\u64cd\u4f5c\u83b7\u5f97\u7684\u5149\u4f0f\u6307\u6807\u968f\u65f6\u95f4\u7684\u6f14\u53d8\u3002<\/p>\n

\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aLayered Hybrid Formamidinium Lead Iodide Perovskites: Challenges and Opportunities<\/a><\/strong>. Acc. Chem. Res.<\/em>, 2021<\/strong>, DOI: 10.1021\/acs.accounts.0c00879.<\/p>\n

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