{"id":223598,"date":"2021-06-19T06:30:09","date_gmt":"2021-06-18T22:30:09","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=223598"},"modified":"2021-06-18T15:28:53","modified_gmt":"2021-06-18T07:28:53","slug":"%e4%b8%9c%e5%8d%97%e5%a4%a7%e5%ad%a6%e7%8e%8b%e8%82%b2%e4%b9%94%e5%9b%a2%e9%98%9facs-mater-lett-%e6%9e%84%e7%ad%91%e7%94%b1%e7%a1%ab%e5%8c%96%e7%89%a9%e5%8a%a0%e5%9b%ba%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=223598","title":{"rendered":"\u4e1c\u5357\u5927\u5b66\u738b\u80b2\u4e54\u56e2\u961fACS\u00a0Mater.\u00a0Lett. :\u00a0\u6784\u7b51\u7531\u786b\u5316\u7269\u52a0\u56fa\u7684\u672c\u5f81\u591a\u5b54NiCoP\u7535\u6781\uff0c\u4fc3\u8fdb\u5176\u9ad8\u5bb9\u91cf\u53ca\u957f\u5faa\u73af\u5bff\u547d"},"content":{"rendered":"

\u524d\u8a00<\/b><\/strong><\/p>\n

\u7535\u5316\u5b66\u50a8\u80fd\u88c5\u7f6e\u4e2d\u7535\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6d3b\u6027\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\u5bf9\u5668\u4ef6\u7684\u5e94\u7528\u524d\u666f\u5177\u6709\u81f3\u5173\u91cd\u8981\u7684\u5f71\u54cd\uff0c\u56e0\u6b64\u7b5b\u9009\u7535\u6781\u6750\u6599\u7ec4\u5206\u4e0e\u8bbe\u8ba1\u7535\u6781\u7ed3\u6784\u663e\u5f97\u5c24\u4e3a\u91cd\u8981\u3002\u53cc\u8fc7\u6e21\u91d1\u5c5e\u78f7\u5316\u7269\u56e0\u5176\u5177\u6709\u8f83\u9ad8\u7684\u7535\u5b50\u7535\u5bfc\u7387\uff0c\u7ec4\u5206\u4e0e\u7ed3\u6784\u6613\u8c03\u63a7\uff0c\u5143\u7d20\u50a8\u91cf\u4e30\u5bcc\u7b49\u4f18\u70b9\u800c\u5728\u7535\u5316\u5b66\u50a8\u80fd\u3001\u50ac\u5316\u7b49\u9886\u57df\u5185\u5907\u53d7\u5173\u6ce8\u3002\u4f46\u662f\uff0c\u78f7\u5316\u7269\u7684\u7535\u5316\u5b66\u6d3b\u6027\u8f83\u4f4e\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\u4e0d\u8db3\uff0c\u56e0\u800c\u9650\u5236\u4e86\u5176\u5728\u7535\u5316\u5b66\u50a8\u80fd\u9886\u57df\u5185\u7684\u5e7f\u6cdb\u5e94\u7528\u3002\u76ee\u524d\uff0c\u7535\u6781\u6750\u6599\u8868\u9762\u9020\u5b54\u7684\u65b9\u6cd5\u53ef\u7528\u4e8e\u589e\u52a0\u66b4\u9732\u5316\u5b66\u53cd\u5e94\u6d3b\u6027\u4f4d\u70b9\u4ee5\u53ca\u589e\u5f3a\u7535\u89e3\u6db2\u79bb\u5b50\u6269\u6563\u4f20\u8f93\u901f\u7387\u3002\u8be5\u7c7b\u578b\u591a\u5b54\u9053\u7ed3\u6784\u5e38\u5e38\u662f\u57fa\u4e8e\u5fae\u7eb3\u5c3a\u5ea6\u5355\u5143\u7ed3\u6784\u7684\u65e0\u5e8f\u5806\u79ef\u800c\u6210\uff0c\u5728\u957f\u65f6\u95f4\u5145\u7535\u653e\u7535\u8fc7\u7a0b\u5f53\u4e2d\u5b54\u9053\u7ed3\u6784\u5bb9\u6613\u584c\u9677\uff0c\u7531\u6b64\u5927\u5e45\u964d\u4f4e\u4e86\u5668\u4ef6\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u5982\u4f55\u8bbe\u8ba1\u548c\u5236\u5907\u540c\u65f6\u5177\u6709\u9ad8\u7535\u5316\u5b66\u6d3b\u6027\u548c\u7a33\u5b9a\u7684\u7ed3\u6784\u7684\u591a\u5b54\u6027\u7535\u6781\u6750\u6599\u6210\u4e3a\u4e86\u4e00\u4e2a\u6781\u5177\u6311\u6218\u7684\u7814\u7a76\u70ed\u70b9\u548c\u96be\u70b9\u3002<\/p>\n

\u4e1c\u5357\u5927\u5b66\u738b\u80b2\u4e54\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u5c06\u53cc\u6c22\u6c27\u5316\u7269\u4f9d\u6b21\u7ecf\u8fc7\u70ed\u89e3\u3001\u78f7\u5316\u548c\u786b\u5316\u5904\u7406\u83b7\u5f97\u5177\u6709\u786b\u5316\u7269\u52a0\u56fa\u7684\u78f7\u5316\u94b4\u954d (S-NiCoP) \u672c\u5f81\u591a\u5b54\u7ed3\u6784\u3002\u8fd9\u79cd\u672c\u5f81\u591a\u5b54\u7ed3\u6784\u4e0d\u540c\u4e8e\u7531\u5fae\u7eb3\u7c73\u7ed3\u6784\u5355\u5143\u5806\u780c\u6210\u7684\u4f20\u7edf\u7684\u5b54\u9053\u7ed3\u6784\uff0c\u672c\u5f81\u5b54\u9699\u662f\u4f34\u968f\u7740\u5fae\u7eb3\u5355\u5143\u7ed3\u6784\u5f62\u6210\u8fc7\u7a0b\u5f53\u4e2d\u5728\u7247\u72b6\u7ed3\u6784\u4e0a\u4ea7\u751f\u7684\u3002\u5b54\u9699\u5468\u8fb9\u5bcc\u96c6\u7684\u786b\u5316\u7269\uff0c\u5982NiS\u548cCo3<\/sub>S4<\/sub>\uff0c\u4e0d\u4ec5\u589e\u52a0\u4e86\u5b54\u8fb9\u7f18\u7684\u7535\u5316\u5b66\u6d3b\u6027\uff0c\u800c\u4e14\u50cf\u94c6\u9489\u4e00\u6837\u52a0\u56fa\u4e86\u591a\u5b54\u7ed3\u6784\u7684\u7a33\u56fa\u6027\u3002\u672c\u6587\u5de7\u5999\u5730\u5229\u7528\u4e86\u786b\u539f\u5b50\u548c\u78f7\u539f\u5b50\u5728\u7535\u8d1f\u6027\u548c\u539f\u5b50\u534a\u5f84\u4e0a\u7684\u5dee\u5f02\uff0c\u786e\u5b9a\u4e86\u5148\u78f7\u5316\u518d\u786b\u5316\u7684\u5236\u5907\u6d41\u7a0b\uff1b\u6839\u636e\u539f\u5b50\u5806\u79ef\u56e0\u5b50 (APF) \u53c2\u6570\u5408\u7406\u5730\u5339\u914d\u4e86\u786b\u3001\u78f7\u539f\u5b50\u5927\u5c0f\u5f15\u8d77\u7684\u7ed3\u6784\u53d8\u5316\uff1b\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u00a0(DFT) \u8ba1\u7b97\u8bc4\u4f30\u4e86\u7531\u786b\u539f\u5b50\u8bf1\u5bfc\u7684\u7535\u5b50\u7ed3\u6784\u91cd\u6784\u7684\u7ed3\u679c\uff1b\u901a\u8fc7\u9610\u8ff0S-NiCoP\u7ed3\u6784\u548c\u7ec4\u5206\u6f14\u53d8\u5bf9\u7535\u5316\u5b66\u884c\u4e3a\u7684\u5f71\u54cd\uff0c\u63ed\u793a\u4e86\u5176\u4fdd\u6301\u9ad8\u5bb9\u91cf\u548c\u6301\u4e45\u7a33\u5b9a\u6027\u7684\u539f\u56e0\u3002\u7531\u6b64\u843d\u5b9e\u4e86\u6211\u4eec\u56e2\u961f\u6240\u575a\u5b88\u7684\u201c\u7406\u8bba\u8bbe\u8ba1\u5728\u5148\uff0c\u5b9e\u9a8c\u9a8c\u8bc1\u5728\u540e\u201d\u7684\u7814\u7a76\u7b56\u7565\u3002<\/p>\n

\u8be5\u9879\u5de5\u4f5c\u4e3a\u8bbe\u8ba1\u548c\u5236\u5907\u5177\u6709\u7c7b\u4f3c\u6811\u53f6\u201c\u6c14\u5b54\u201d\u72b6\u7684\u672c\u5f81\u5b54\u7ed3\u6784\u53cc\u91d1\u5c5e\u78f7\u5316\u7269\u63d0\u4f9b\u4e86\u7814\u7a76\u601d\u8def\u3002\u4e3a\u5f00\u53d1\u540c\u65f6\u5177\u6709\u9ad8\u7535\u5316\u5b66\u6d3b\u6027\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\u7684\u65b0\u578b\u7535\u5316\u5b66\u50a8\u80fd\u6750\u6599\u63d0\u4f9b\u4e86\u7406\u8bba\u65b9\u6cd5\u548c\u5b9e\u8df5\u6307\u5bfc\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cSulfide-Fixed Intrinsic Porous NiCoP for\u00a0Boosting High Capacitance and Long-Term\u00a0Stability\u201d\u4e3a\u9898\u53d1\u8868\u5728ACS Materials Letters\u4e0a\u3002<\/p>\n

\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>\u4e00\u3001\u5177\u6709\u672c\u5f81\u591a\u5b54\u7ed3\u6784\u7684NiCoP\u4ee5\u53caS-NiCoP\u7684<\/b><\/strong>\u7ed3\u6784\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a1<\/sub>-a4<\/sub>.\u00a0\u672c\u5f81\u591a\u5b54NiCoP\u7684TEM\uff0cHRTEM\u4ee5SAED\uff1b<\/p>\n

b. NiCoP\u7684\u5b54\u5f84\u5360\u6bd4\u5206\u5e03\uff1b<\/p>\n

c. NiCoP\u7684\u5143\u7d20\u6620\u5c04\u56fe\uff1b<\/span><\/p>\n

d. S-NiCoP\u7684\u5b54\u5f84\u5360\u6bd4\u5206\u5e03\uff1b<\/p>\n

e,\u00a0f. S-NiCoP\u7684TEM\u3001HAADF-STEM\u53ca\u5143\u7d20\u6620\u5c04\u56fe\u3002<\/p>\n

\u56fe<\/b><\/strong>\u4e8c\u3001\u7535\u5b50\u7ed3\u6784\u91cd\u7ec4\u53ca\u7ed3\u6784\u7a33\u5b9a\u6027\u673a\u7406<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a. DFT\u8ba1\u7b97\u7684\u6a21\u578b\u56fe\uff1b<\/p>\n

b, c, d. \u7535\u5b50\u6001\u5bc6\u5ea6\u56fe\uff1b<\/p>\n

e. \u4e8c\u7ef4\u7535\u5b50\u5c40\u57df\u51fd\u6570\u56fe\uff1b<\/p>\n

f. \u4e0d\u540c\u6676\u9762\u7684\u9759\u7535\u52bf\uff1b<\/p>\n

g. \u7535\u5b50\u8f6c\u79fb\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/b><\/strong>\u4e09\u3001\u7535\u5316\u5b66\u6d4b\u8bd5\u53ca\u50a8\u80fd\u673a\u7406\u9610\u8ff0<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a, b. CV\u548c\u500d\u7387\u66f2\u7ebf\uff1b<\/p>\n

c. EIS\u6d4b\u8bd5\u66f2\u7ebf\uff1b<\/p>\n

d. \u957f\u5faa\u73af\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff1b<\/p>\n

e. b\u503c\uff1b<\/p>\n

f. \u7535\u6d41\u4e0e\u626b\u901f\u5173\u7cfb\uff1b<\/p>\n

g, h,\u00a0i.\u00a0\u6269\u6563\u63a7\u5236\u548c\u8868\u9762\u63a7\u5236\u7684\u5360\u6bd4\u7387\u3002<\/p>\n

\u56fe\u56db\u3001\u5168\u56fa\u6001<\/b><\/strong>\u8d85\u7ea7\u7535\u5bb9\u5668<\/b><\/strong>\u7684<\/b><\/strong>\u7279\u6027<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a. \u5668\u4ef6\u7ec4\u88c5\u793a\u610f\u56fe\uff1b<\/p>\n

b. \u6b63\u8d1f\u6781\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

c. \u5728\u5404\u79cd\u626b\u901f\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

d. \u5728\u5404\u79cd\u5145\/\u653e\u7535\u7535\u6d41\u4e0b\u7684GCD\u66f2\u7ebf\uff1b<\/p>\n

e. \u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u80fd\u91cf\u548c\u529f\u7387\u5bc6\u5ea6\u62c9\u8d21\u56fe\uff1b<\/p>\n

f. S-NiCoP\/\/AC\u5168\u56fa\u6001\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n

\u5c0f\u7ed3<\/b><\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u5de5\u4f5c\u57fa\u4e8e\u539f\u5b50\u7535\u8d1f\u6027\u548c\u534a\u5f84\u7684\u5dee\u5f02\uff0c\u6709\u6548\u5408\u6210\u4e86\u5177\u6709\u53cc\u786b\u5316\u7269\u52a0\u56fa\u672c\u5f81\u591a\u5b54\u7ed3\u6784\u7684S-NiCoP\u7535\u6781\u3002\u786b\u5316\u7269\u4e3b\u8981\u951a\u5b9a\u5728\u672c\u5f81\u5b54\u5468\u56f4\uff0c\u5728\u63d0\u4f9b\u66f4\u591a\u6d3b\u6027\u4f4d\u70b9\u7684\u540c\u65f6\uff0c\u8fd8\u53ef\u4ee5\u52a0\u56fa\u672c\u5f81\u5b54\u7ed3\u6784\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u9ad8\u7535\u5316\u5b66\u6d3b\u6027\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u901a\u8fc7DFT\u548cAPF\u53c2\u6570\u8ba1\u7b97\uff0c\u6709\u6548\u5730\u9884\u6d4b\u7535\u5b50\u7ed3\u6784\u548c\u51e0\u4f55\u7ed3\u6784\u7684\u6539\u53d8\u3002DFT\u7ed3\u679c\u8868\u660e\u7535\u5b50\u53ef\u4ee5\u5728\u786b\u5316\u7269\u548cNiCoP\u4e3b\u4f53\u6750\u6599\u4e4b\u95f4\u8fdb\u884c\u4f20\u8f93\u548c\u8f6c\u79fb\uff0c\u6709\u52a9\u4e8e\u63d0\u5347\u6574\u4f53\u7535\u5316\u5b66\u6d3b\u6027\u3002\u540c\u65f6\uff0c\u7531\u4e8e\u8f83\u5c0f\u7684APF\u503c\uff0c\u53cc\u786b\u5316\u7269\u5c06\u6709\u6548\u52a0\u56fa\u672c\u5f81\u5b54\u7ed3\u6784\u3002\u6b64\u5916\uff0c\u6240\u7ec4\u88c5\u7684S-NiCoP\/\/AC\u5168\u56fa\u6001\u8d85\u7ea7\u7535\u5bb9\u5668\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6bd4\u80fd\u91cf\u5bc6\u5ea6\uff0840.63\u00a0Wh kg-1<\/sup>\uff09\u548c\u6bd4\u529f\u7387\u5bc6\u5ea6\uff08748\u00a0W kg-1<\/sup>\uff09\uff0c\u5e76\u4e1410000\u6b21\u5faa\u73af\u540e\u7684\u5bb9\u91cf\u4fdd\u7559\u7387\u4ecd\u9ad8\u8fbe81.2\uff05\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Song, L.; Wang, Q.; Ye, X.; Yang, F.; Wang, L.; Wu, Y.; Xu, F.; Wang, Y. Sulfide-Fixed Intrinsic Porous NiCoP for Boosting High Capacitance and Long-Term Stability. ACS Materials Letters 2021, 3, 1016-1024.<\/p>\n

DOI\uff1a10.1021\/acsmaterialslett.1c00282.<\/p>\n

\u672c\u6587\u7531SLL\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u524d\u8a00 \u7535\u5316\u5b66\u50a8\u80fd\u88c5\u7f6e\u4e2d\u7535\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6d3b\u6027\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\u5bf9\u5668\u4ef6\u7684\u5e94\u7528\u524d\u666f\u5177\u6709\u81f3\u5173\u91cd\u8981\u7684\u5f71\u54cd\uff0c\u56e0\u6b64\u7b5b\u9009\u7535\u6781\u6750\u6599\u7ec4\u5206\u4e0e\u8bbe\u8ba1\u7535\u6781\u7ed3\u6784\u663e\u5f97\u5c24\u4e3a\u91cd\u8981\u3002\u53cc\u8fc7\u6e21\u91d1\u5c5e\u78f7\u5316\u7269\u56e0\u5176\u5177…<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-223598","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/223598"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=223598"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/223598\/revisions"}],"predecessor-version":[{"id":223604,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/223598\/revisions\/223604"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=223598"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=223598"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=223598"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}