{"id":223852,"date":"2021-07-02T06:30:43","date_gmt":"2021-07-01T22:30:43","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=223852"},"modified":"2021-07-01T17:09:38","modified_gmt":"2021-07-01T09:09:38","slug":"%e8%a5%bf%e5%ae%89%e4%ba%a4%e9%80%9a%e5%a4%a7%e5%ad%a6adv-sci-%ef%bc%9a%e8%b0%83%e6%95%b4%e5%a4%9a%e5%ad%94%e7%94%b5%e6%9e%81%e7%9a%84%e5%8a%9b%e5%ad%a6%e5%92%8c%e7%94%b5%e5%8c%96%e5%ad%a6%e7%89%b9","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=223852","title":{"rendered":"\u897f\u5b89\u4ea4\u901a\u5927\u5b66Adv. Sci.\uff1a\u8c03\u6574\u591a\u5b54\u7535\u6781\u7684\u529b\u5b66\u548c\u7535\u5316\u5b66\u7279\u5f81\uff0c\u6784\u5efa\u7535\u6c60\u7ea7\u80fd\u91cf\u76843D\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5fae\u578b\u7535\u5316\u5b66\u50a8\u80fd\u8bbe\u5907\u5bf9\u4e8e\u7269\u8054\u7f51(IoT)\u7684\u6784\u5efa\u81f3\u5173\u91cd\u8981\u3002\u5fae\u578b\u53cc\u7535\u5c42\u7535\u5bb9\u5668\uff08EDLCs\uff09\uff0c\u4e5f\u79f0\u4e3a\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\uff08MSCs\uff09\uff0c\u5c06\u7535\u8377\u5b58\u50a8\u5728\u7535\u6781\u6750\u6599\u548c\u7535\u89e3\u8d28\u7684\u754c\u9762\uff0c\u4e0e\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u6bd4\uff0c\u5176\u5177\u6709\u9ad8\u529f\u7387\u5bc6\u5ea6\u3001\u8d85\u957f\u5faa\u73af\u5bff\u547d\u548c\u9ad8\u53ef\u9760\u6027\u7684\u4f18\u70b9\u3002\u7136\u800c\uff0cMSCs\u7684\u9762\u80fd\u91cf\u5bc6\u5ea6\u901a\u5e38\u8f83\u4f4e\uff0c\u901a\u5e38\u6bcf\u5e73\u65b9\u5398\u7c73\u4e0d\u5230\u51e0\u5341\u5fae\u74e6\u65f6\uff0c\u6bd4\u9502\u79bb\u5b50\u5fae\u7535\u6c60\u4f4e\u4e00\u4e2a\u6570\u91cf\u7ea7\uff0c\u9650\u5236\u4e86\u5b83\u4eec\u7684\u5e7f\u6cdb\u4f7f\u7528\u3002\u5177\u6709\u9ad8\u7eb5\u6a2a\u6bd4\u7684\u539a\u4e09\u7ef4(3D)\u7535\u6781\u53ef\u80fd\u662f\u514b\u670d\u8fd9\u4e00\u7f3a\u70b9\u7684\u6709\u524d\u9014\u7684\u7b56\u7565\u3002\u4e1d\u7f51\u5370\u5237\u3001\u55b7\u58a8\u5370\u5237\u3001\u6324\u51fa\u5370\u5237\u7b49\u589e\u6750\u5236\u9020\u6280\u672f\u5728\u5fae\u7535\u6781\u7684\u5236\u9020\u4e2d\u5f88\u6709\u524d\u666f\u3002\u4f46\u662f\uff0c\u7535\u6781\u7684\u5236\u5907\u4ecd\u53d7\u5230\u58a8\u6c34\u6216\u6d46\u6599\u7684\u6269\u6563\u6027\u8d28\u7684\u9650\u5236\uff0c\u5236\u5907\u7684\u7535\u6781\u901a\u5e38\u5177\u6709\u539a\u5ea6\u5c0f\u548c\u95f4\u9694\u5927\u7684\u52a3\u52bf\uff0c\u964d\u4f4e\u4e86\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u9762\u80fd\u91cf\u5bc6\u5ea6\u3002\u78b3\u7eb3\u7c73\u9897\u7c92\u7684\u7535\u6cf3\u6c89\u79ef\u6216\u5bfc\u7535\u805a\u5408\u7269\u7535\u5316\u5b66\u805a\u5408\u5230\u9884\u5148\u56fe\u6848\u5316\u7684\u65b9\u6cd5\u4e5f\u88ab\u7528\u4e8e\u5236\u9020\u5fae\u7535\u6781\uff0c\u4f46\u8fd9\u4e9b\u8fc7\u7a0b\u975e\u5e38\u8017\u65f6\uff0c\u6c89\u79ef\u6216\u751f\u957f\u901f\u7387\u968f\u7740\u7535\u6781\u539a\u5ea6\u7684\u589e\u52a0\u800c\u964d\u4f4e\u3002\u4e3a\u4e86\u5236\u5907\u5177\u6709\u539a3D\u7535\u6781\u7684\u9ad8\u80fd\u91cf\/\u52a8\u6001MSC\uff0c\u9700\u8981\u63d0\u9ad8\u7535\u6781\u7684\u7535\u5316\u5b66\u548c\u529b\u5b66\u7a33\u5b9a\u6027\u3002\u7531\u4e8e\u5fae\u7535\u6781\u5bf9\u4e4b\u95f4\u6ca1\u6709\u9694\u677f\uff0c\u5728\u5236\u5907\u3001\u5c01\u88c5\u6216\u4f7f\u7528\u8fc7\u7a0b\u4e2d\uff0c\u5fae\u7535\u6781\u5f62\u53d8\u3001\u5265\u843d\u6216\u5265\u79bb\u901a\u5e38\u4f1a\u51fa\u73b0\u77ed\u8def\u95ee\u9898\u3002\u968f\u7740\u5fae\u7535\u6781\u7684\u8d28\u91cf\u8d1f\u8f7d\u3001\u9ad8\u5ea6\u548c\u7eb5\u6a2a\u6bd4\u7684\u589e\u52a0\uff0c\u60c5\u51b5\u53ef\u80fd\u53d8\u5f97\u66f4\u7cdf\u3002\u5982\u679c\u5728\u5236\u5907\u7535\u6781\u6750\u6599\u65f6\u4f7f\u7528\u66f4\u591a\u7684\u7c98\u5408\u5242\uff0c\u5219\u529b\u5b66\u6027\u80fd\u53ef\u4ee5\u5f97\u5230\u5f88\u5927\u7a0b\u5ea6\u7684\u63d0\u9ad8\u3002\u7136\u800c\uff0c\u989d\u5916\u7684\u7c98\u5408\u5242\u4e0d\u4ec5\u4f1a\u663e\u7740\u964d\u4f4e\u7535\u5bfc\u7387\uff0c\u8fd8\u4f1a\u5206\u79bb\u6216\u5b64\u7acb\u7eb3\u7c73\u9897\u7c92\uff0c\u964d\u4f4e\u7535\u6781\u8868\u9762\u79ef\u7684\u5229\u7528\u7387\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u897f\u5b89\u4ea4\u901a\u5927\u5b66<\/strong>\u7684\u674e\u7965\u660e\u6559\u6388<\/strong>\u548c\u90b5\u91d1\u53cb\u6559\u6388<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u53d1\u73b0\u591a\u5b54\u7535\u6781\u7684\u529b\u5b66\u548c\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4ee5\u53ca\u5b83\u4eec\u7684\u8868\u9762\u79ef\u5229\u7528\u7387\u548c\u79bb\u5b50\u6269\u6563\u9014\u5f84\uff0c\u53ef\u4ee5\u901a\u8fc7\u5c06\u51dd\u80f6\u7535\u89e3\u8d28\u586b\u5145\u5230\u591a\u5b54\u7535\u6781\u819c\u7684\u5185\u90e8\u5b54\u4e2d\u6765\u534f\u540c\u8c03\u8282\u3002\u539a\u591a\u5b54\u7535\u6781\u819c\u8db3\u591f\u575a\u56fa\uff0c\u80fd\u591f\u5bf93D\u5fae\u7535\u6781\u8fdb\u884c\u6fc0\u5149\u5904\u7406\uff0c\u4ee5\u5b9e\u73b0\u9ad8\u8d28\u91cf\u8d1f\u8f7d\u548c\u9ad8\u7eb5\u6a2a\u6bd4\u30023D\u5fae\u7535\u6781\u7684\u9762\u79ef\u7535\u5bb9\u80fd\u591f\u968f\u7740\u8d28\u91cf\u8d1f\u8f7d\uff08\u6216\u539a\u5ea6\uff09\u7ebf\u6027\u589e\u52a0\u523013 mg cm-2<\/sup>\uff08\u6216260 \u00b5m\uff09\uff0c\u57fa\u4e8e\u6d3b\u6027\u70ad\u9ad8\u8fbe4640 mF cm-2<\/sup>\u30023D MSC\u63d0\u4f9b1318 \u03bcWh cm-2<\/sup>\u7684\u9762\u80fd\u91cf\u5bc6\u5ea6\uff0c\u53ef\u4e0e\u6700\u597d\u7684\u9502\u79bb\u5b503D\u5fae\u7535\u6c60\u76f8\u5ab2\u7f8e\uff0c\u540c\u65f6\u8868\u73b0\u51fa\u5353\u8d8a\u7684\u7535\u5316\u5b66\u548c\u529b\u5b66\u7a33\u5b9a\u6027\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>Tuning the Mechanical and Electrical Properties of Porous Electrodes for Architecting 3D Microsupercapacitors with Batteries-Level Energy<\/strong>\u201d\u53d1\u8868\u5728Advanced Science<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 <\/strong>\u529b\u5b66\u548c\u7535\u5316\u5b66\u7279\u6027<\/strong><\/p>\n

 <\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u539a\u5806\u53e0\u7684\u7535\u6781\u7eb3\u7c73\u7c92\u5b50\u5177\u6709\u8f83\u5dee\u7684\u529b\u5b66\u5f3a\u5ea6\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u6df7\u5408\u51dd\u80f6\u7535\u89e3\u8d28\u63d0\u9ad8\u4e86MS\u4f46\u964d\u4f4e\u4e86\u7535\u5b50\u7535\u5bfc\u7387(EC)\u548c\u8868\u9762\u5229\u7528\u7387(US)\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08c\uff09\u51dd\u80f6\u7535\u89e3\u8d28\u7684\u4e0d\u5b8c\u5168\u586b\u5145\u4f7f\u79bb\u5b50\u7535\u5bfc\u7387(IC)\u3001MS\u548cUS\u9000\u5316\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08d\uff09\u51dd\u80f6\u7535\u89e3\u8d28\u7684\u5b8c\u5168\u586b\u5145\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08e\uff09\u51dd\u80f6\u7535\u89e3\u8d28\u81ea\u4e0b\u800c\u4e0a\u586b\u5145\u5230\u7535\u6781\u819c\u7684\u5185\u90e8\u5b54\u9699\u4e2d\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08f\uff0cg\uff09\u5728\u4e0d\u540c\u51dd\u80f6\u7535\u89e3\u8d28\u5b58\u5728\u4e0b\uff0cMWCNTs\u8584\u819c\u7684\u5f2f\u66f2\u548c\u91ca\u653e\u8fc7\u7a0b\u4e2d\u7684\u62c9\u4f38\u5e94\u53d8\u4e0e\u5e94\u529b\u548c\u66f2\u7387\u4e0e\u7535\u963b\u7684\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong> 2 <\/strong>\u6fc0\u5149\u6784\u5efa<\/strong>3D MSC<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-c\uff09\u5728\u586b\u5145\u51dd\u80f6\u7535\u89e3\u8d28\u7684\u7535\u6781\u819c\uff08a\uff09\u3001\u6fc0\u5149\u70e7\u8680\u76843D\u5fae\u7535\u6781\uff08b\uff09\u548c\u57283D\u5fae\u7535\u6781\u4e2d\u548c\u4e0a\u586b\u5145\u51dd\u80f6\u7535\u89e3\u8d28\u540e\u76843D\u5fae\u8d85\u7ea7\u7535\u5bb9\u5668\uff08c\uff09\u6e85\u5c04\u5c42\u5f62\u6210\u96c6\u7535\u5668\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08d\uff0ce\uff09\u672a\u5b8c\u5168\u586b\u5145\u7535\u6781\u819c\u7684\u5fae\u7535\u6781\u7684SEM\u56fe\u50cf\u5728\u9876\u89c6\u56fe\u548c\u4ea4\u53c9\u89c6\u56fe\uff1b<\/p>\n

\uff08f\uff0cg\uff09\u5b8c\u5168\u586b\u5145\u7684\u7535\u6781\u819c\u5728\u659c\u89c6\u56fe\u548c\u4ea4\u53c9\u89c6\u56fe\u4e0b\u751f\u6210\u7684\u9762\u51853D\u5fae\u7535\u6781\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08h\uff09\u572850\u5206\u949f\u5185\uff0c\u6fc0\u5149\u70e7\u8680\u83b7\u5f9792\u5bf93D\u5fae\u7535\u6781\u7684\u7535\u6781\u819c\u7684\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong> 3 <\/strong>\u4e0d\u540c\u51dd\u80f6\u7535\u89e3\u8d28\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09MWCNTs\u7535\u6781\u4e2d\uff0c\u4e0d\u540c\u542b\u91cf\u7684PVA\/H3<\/sub>PO4<\/sub>\u76843D MSCs\u7684GCD\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff091-20 mA cm-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u548c0-1 V\u7535\u538b\u7a97\u53e3\u4e0b\uff0c3D MSC\u7684\u9762\u79ef\u7535\u5bb9\u4e0e\u7535\u6d41\u5bc6\u5ea6\u7684\u5173\u7cfb\uff1b<\/p>\n

\uff08c\uff09\u5728100 kHz -10 mHz\u9891\u7387\u4e0b\uff0c3D MSC\u7684\u5948\u594e\u65af\u7279\u56fe\uff1b<\/p>\n

\uff08d\uff09\u572810 mA cm-2<\/sup>\u7684\u76f8\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c3D MSCs\u7684\u9762\u79ef\u7535\u5bb9\u4e0e\u539a\u5ea6\u3002<\/p>\n

\u56fe<\/strong> 4 <\/strong>\u5fae\u7535\u6781\u51e0\u4f55\u5c3a\u5bf8\u7684\u7535\u5316\u5b66\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff093D MSC\u548c\u5939\u5fc3\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u9762\u7535\u5bb9\u548c\u4f53\u79ef\u7535\u5bb9\u4e0e10-1000 mV s-1<\/sup>\u7684\u626b\u63cf\u901f\u7387\u7684\u5173\u7cfb\uff1b<\/p>\n

\uff08c\uff0ce\uff09\u4e0d\u540c\u7535\u538b\u626b\u63cf\u901f\u7387\u4e0b\uff0c\u9762\u79ef\u7535\u5bb9\u4e0e\u5bbd\u5ea6\u548c\u9ad8\u5ea6\u7684\u5173\u7cfb\uff1b<\/p>\n

\uff08d\uff0cf\uff09ESR\u4e0e\u5bbd\u5ea6\u548c\u9ad8\u5ea6\u7684\u5173\u7cfb\uff1b<\/p>\n

\uff08g\uff09\u4e0d\u540c\u9ad8\u5ea6\u548c\u5bbd\u5ea6\u7684\u5bf9\u79f0\u9762\u5185\u5fae\u7535\u6781\u5bf9\u534a\u5468\u671f\u4e2dEDL\u5206\u5e03\u7684\u56fe\u50cf\uff1b<\/p>\n

\uff08h\uff09\u4e0d\u540c\u5bbd\u5ea6\u548c\u9ad8\u5ea6\u7684\u5fae\u7535\u6781\u4e2d\u9762\u79bb\u5b50\u5bc6\u5ea6\u968f\u65f6\u95f4\u53d8\u5316\u7684\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong> 5 <\/strong>\u4e0d\u540c\u6750\u6599\u7684\u901a\u7528\u6027<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09\u4e0d\u540c\u7535\u6781\u548c\u51dd\u80f6\u7535\u89e3\u8d28\u6750\u6599\u76843D MSCs\u572820 mA cm-2<\/sup>\u4e0b\u7684GCD\u66f2\u7ebf\u548c\u5728100 mV s-1<\/sup>\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff0cd\uff09\u4e0d\u540c\u6750\u6599\u76843D MSC\u7684\u9762\u79ef\u7535\u5bb9\u4e0e\u7535\u6d41\u5bc6\u5ea6\u548c\u5145\u653e\u7535\u5faa\u73af\u66f2\u7ebf\uff1b<\/p>\n

\uff08e\uff09\u9762\u79ef\u7535\u5bb9\u4e0e\u5f2f\u66f2\u5faa\u73af\u7684\u5173\u7cfb\u3002<\/p>\n

\u56fe<\/strong> 6 <\/strong>\u9762\u79ef\u5f52\u4e00\u5316<\/strong>Ragone<\/strong>\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5<\/strong>Tuning the Mechanical and Electrical Properties of Porous Electrodes for Architecting 3D Microsupercapacitors with Batteries-Level Energy<\/strong><\/a>\uff08Advanced Science DOI: 10.1002\/advs.202004957\uff09\u3002<\/p>\n

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