{"id":224190,"date":"2021-07-06T06:00:06","date_gmt":"2021-07-05T22:00:06","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=224190"},"modified":"2021-07-05T22:42:24","modified_gmt":"2021-07-05T14:42:24","slug":"%ef%bc%88%e5%b7%b2%e6%a0%a1%e7%a8%bf%e4%bb%b6%ef%bc%89%e5%8d%97%e6%b4%8b%e7%90%86%e5%b7%a5-nature%e5%ad%90%e5%88%8a%ef%bc%9a%e8%ae%a9oer%e7%94%b5%e5%82%ac%e5%8c%96%e5%89%82%e6%80%a7%e8%83%bd%e6%9b%b4","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=224190","title":{"rendered":"\uff08\u5df2\u6821\u7a3f\u4ef6\uff09\u5357\u6d0b\u7406\u5de5 Nature\u5b50\u520a\uff1a\u8ba9OER\u7535\u50ac\u5316\u5242\u6027\u80fd\u66f4\u597d\uff01"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u662f\u6c34\u7535\u89e3\u69fd\u3001\u91d1\u5c5e-\u7a7a\u6c14\u53ef\u518d\u5145\u7535\u7535\u6c60\u7b49\u80fd\u6e90\u7cfb\u7edf\u4e2d\u7684\u4e00\u4e2a\u5173\u952e\u53cd\u5e94\uff0c\u4f46\u662f\u7531\u4e8e\u5176\u52a8\u529b\u5b66\u7f13\u6162\u800c\u963b\u788d\u80fd\u6e90\u7cfb\u7edf\u53d1\u5c55\u3002\u76ee\u524d\uff0cOER\u673a\u7406\u4e3b\u8981\u6709\u4e24\u79cd\uff1a\u5438\u9644\u8d28\u6f14\u5316\u673a\u7406\u548c\u6676\u683c\u6c27\u6c27\u5316\u673a\u7406\uff0c\u800c\u5df2\u6709\u62a5\u9053\u7684\u5f62\u6210O-O\u952e\u673a\u5236\u9075\u5faa\u9178-\u78b1\u4eb2\u6838\u8fdb\u653b\u548cO-O\u76f4\u63a5\u5076\u8054\u4e24\u79cd\u9014\u5f84\u3002\u5bf9\u4e8e\u524d\u8005\uff0c*OOH\u548c*OH\u4e2d\u95f4\u4f53\u7684\u5438\u9644\u80fd\u4e4b\u95f4\u5b58\u5728\u7740\u5185\u5728\u7684\u7ebf\u6027\u6807\u5ea6\u5173\u7cfb\uff08LSR\uff09\u3002\u4f46\u662f\uff0c\u5bf9\u4e8e\u5927\u591a\u6570\u50ac\u5316\u6750\u6599\uff0c\u5f88\u96be\u5177\u6709\u5f15\u53d1O-O\u76f4\u63a5\u5076\u8054\u7684\u7279\u5b9a\u50ac\u5316\u7ed3\u6784\u57fa\u5e8f\u3002\u56e0\u6b64\uff0c\u5f53\u524d\u7814\u7a76\u5de5\u4f5c\u4e3b\u8981\u662f\u4f18\u5316\u9178-\u78b1\u4eb2\u6838\u8fdb\u653b\u9014\u5f84\uff0c\u514b\u670dLSR\u7684\u5c40\u9650\u6027\uff0c\u4ee5\u5f00\u53d1\u5b9e\u7528\u7684\u7535\u50ac\u5316\u5242\u3002\u6fc0\u6d3b\u6676\u683c\u6c27\u4ee5\u751f\u6210\u81ea\u65cb\u7279\u5f81\u914d\u4f53\u7a7a\u7a74\u53ef\u4ee5\u8c03\u8282\u6676\u683c\u6c27\u53cd\u5e94\u6027\uff0c\u8fd9\u79cd\u53cd\u5e94\u6027\u4e0eO-H\u952e\u65ad\u88c2\u548c*OOH\u5f62\u6210\u4e4b\u95f4\u7684\u80fd\u5792\u5bf9\u79f0\u6027\u6709\u5173\u3002\u8fdb\u4e00\u6b65\u964d\u4f4e\u8fc7\u7535\u4f4d\u4e0a\u9650\u9700\u8981\u9009\u62e9\u6027\u7a33\u5b9a*OOH\uff0c\u4ee5\u514b\u670dLSR\u3002\u7814\u7a76\u8868\u660e\uff0c\u5f15\u5165\u6c34\u5408\u78b1\u91d1\u5c5e\u79bb\u5b50\uff08A+<\/sup>\uff09\u4f5c\u4e3a\u4fc3\u8fdb\u5242\uff0c\u901a\u8fc7\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u4ee5\u7a33\u5b9a\u5173\u952e\u4e2d\u95f4\u4f53\u6216\u8fc7\u6e21\u6001\u3002\u7136\u800c\uff0c\u5927\u591a\u6570\u50ac\u5316\u6750\u6599\u56fa\u6709\u7684LSR\u5e26\u6765\u4e86\u7406\u8bba\u4e0a\u7684\u8fc7\u7535\u4f4d\u4e0a\u9650\uff0c\u9650\u5236\u4e86\u5f00\u53d1\u9ad8\u6548\u7684\u7535\u50ac\u5316\u5242\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u738b\u6615\uff08Xin Wang\uff09\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u5236\u5907\u66f4\u597d\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u7535\u50ac\u5316\u5242\u7684\u6709\u6548\u65b9\u6cd5\uff0c\u5373\u5229\u7528\u6a21\u62df\u7684Nax<\/sub>Mn3<\/sub>O7<\/sub>\u6750\u6599\uff0c\u901a\u8fc7\u78b1\u91d1\u5c5e\u79bb\u5b50\u4ecb\u5bfc\u8c03\u8282\u6676\u683c\u6c27\u53cd\u5e94\u6027\u548c\u6807\u5ea6\u5173\u7cfb\u3002\u5177\u4f53\u800c\u8a00\uff0c\u94a0\u79bb\u5b50\uff08Na+<\/sup>\uff09\u7684\u6570\u91cf\u4e0e\u6676\u683c\u6c27\u53cd\u5e94\u6027\u6709\u5173\uff0c\u800c\u7531Mn\u7a7a\u4f4d\u5f62\u6210\u7684\u6c27\u5b64\u5bf9\u6001\u4e2d\u6c27\u7a7a\u7a74\u7684\u6570\u91cf\u51b3\u5b9a\u4e86\u6676\u683c\u6c27\u53cd\u5e94\u6027\uff0c\u5b83\u51b3\u5b9a\u4e86O-H\u952e\u65ad\u88c2\u548cO-O\u952e\u5f62\u6210\u4e4b\u95f4\u7684\u80fd\u5792\u5bf9\u79f0\u6027\u3002\u6b64\u5916\uff0cNa+<\/sup>\u7684\u5b58\u5728\u53ef\u4ee5\u514b\u670d\u7ebf\u6027\u6807\u5ea6\u5173\u7cfb\u7684\u9650\u5236\uff0c\u964d\u4f4e\u8fc7\u7535\u4f4d\u4e0a\u9650\u3002\u7ed3\u5408\u57fa\u4e8e\u539f\u4f4d\u5149\u8c31\u7684\u8868\u5f81\u548c\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\uff0c\u4f5c\u8005\u8bc1\u660e\u4e86\u4e2d\u95f4\u6c34\u5e73\u7684Na+<\/sup>\u4ecb\u5bfc\uff08NaMn3<\/sub>O7<\/sub>\uff09\u8868\u73b0\u51fa\u6700\u4f73\u7684OER\u6d3b\u6027\u3002\u603b\u4e4b\uff0c\u901a\u8fc7\u8c03\u6574\u6676\u683c\u6c27\u6d3b\u6027\u548c\u6807\u5ea6\u5173\u7cfb\uff0c\u4e3a\u5f00\u53d1\u9ad8\u6548\u7684\u6c34\u6c27\u5316\u6216\u5176\u5b83\u6c27\u5316\u53cd\u5e94\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u5408\u7406\u914d\u65b9\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cTuning of lattice oxygen reactivity and scaling relation to construct better oxygen evolution electrocatalyst\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNature Communications<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u6fc0\u6d3b\u6676\u683c\u6c27\u4ee5\u8c03\u8282O-O\u952e\u5f62\u6210\u7684\u9014\u5f84\u7ade\u4e89<\/strong>
\n \"\"\uff08a\uff09Nax<\/sub>Mn3<\/sub>O7<\/sub>\u5728|O2p<\/sub>|\u5b64\u5bf9\u6c27\u7a7a\u7a74\u7684\u5f62\u6210\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09Nax<\/sub>Mn3<\/sub>O7<\/sub>\u5e73\u677f\u72b6\u6001\u7684\u6295\u5f71\u5bc6\u5ea6\uff08x=2\u30011.5\u30011\u548c0.5\uff09\uff1b<\/p>\n

\uff08c\uff09\u56fe1b\u4e2d\u9634\u5f71\u533a\u57df\u6295\u5c04\u5728O\u539f\u5b50\u4e0a\u7684\u90e8\u5206\u7535\u8377\u5bc6\u5ea6\uff1b<\/p>\n

\uff08d\uff09\u5728\u4ee3\u8868\u6027\u6c27\u914d\u4f4d\u73af\u5883\u4e2d\uff0cA3(*O)\u548cR4(*OO*)\u7684\u4e24\u79cd\u5f02\u6784\u4e2d\u95f4\u4f53\u4e4b\u95f4\u7684\u81ea\u7531\u80fd\u5dee\u5f02\uff1b<\/p>\n

\uff08e\uff09\u5728S6\u7684\u7279\u5b9a\u914d\u4f4d\u73af\u5883\u4e0b\uff0c\u4eceA3\u5230R4\u7684\u6fc0\u6d3b\u81ea\u7531\u80fd\u5792\uff08\u0394G\u2021<\/sup>\uff09\uff1b<\/p>\n

\uff08f\uff09\u5f62\u6210*OOH\u7684\u81ea\u7531\u80fd\u5792\uff08\u0394G*OOH<\/sub>\uff09\u3002<\/p>\n

\u56fe\u4e8c\u3001\u8c03\u6574\u6676\u683c\u6c27\u53cd\u5e94\u6027\u548c\u6807\u5ea6\u5173\u7cfb\u6784\u5efa\u66f4\u597dOER\u7535\u50ac\u5316\u5242<\/strong>
\n \"\"\uff08a\uff09\u5408\u7406\u8bbe\u8ba1\u66f4\u597d\u7684Nax<\/sub>Mn3<\/sub>O7<\/sub>\u7535\u50ac\u5316\u5242\u7684\u65b9\u6848\uff1b<\/p>\n

\uff08b\uff09\u901a\u8fc7\u8c03\u6574O\u7684\u78c1\u5316\u77e9\uff0c\u5728P1 \u4e2d\u79fb\u52a8\u4ee5\u8c03\u8282\u7406\u8bba\u8fc7\u7535\u52bf\uff08\u03b7\uff09\uff1b<\/p>\n

\uff08c\uff09\u901a\u8fc7\u8c03\u6574Na+<\/sup>\u7279\u5b9a\u7684\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u6765\u514b\u670dLSR\uff0cP2\u4e2d\u7684\u79fb\u52a8\u4ee5\u964d\u4f4e\u8fc7\u7535\u4f4d\u4e0a\u9650\uff08\u03b7min<\/sub>\uff09\uff1b<\/p>\n

\uff08d\uff09\u91cd\u6784\u7684LSR\u7684\u52a8\u6001volcano\u56fe\uff08\u03b7\u5bf9\u0394G*O<\/sub>-\u0394G*OH<\/sub>\uff09\uff1b<\/p>\n

\uff08e\uff09\u4f7f\u7528P1-P2\u7684\u4e8c\u8fdb\u5236\u63cf\u8ff0\u7b26\u7684\u5f52\u4e00\u5316volcano\u56fe\uff08\u03b7\u4e0eP1-P2\uff09\u3002<\/p>\n

\u56fe\u4e09\u3001Nax<\/sub>Mn3<\/sub>O7<\/sub>\u7684\u7535\u5b50\u548c\u539f\u5b50\u914d\u4f4d\u7ed3\u6784<\/strong>
\n \"\"\uff08a\uff09Na2<\/sub>Mn3<\/sub>O7<\/sub>\u7684XRD\u56fe\uff1b<\/p>\n

\uff08b-c\uff09Nax<\/sub>Mn3<\/sub>O7<\/sub>\uff08x=2.0\u30011.5\u30011.0\u548c0.7\uff09\u7684\u5f52\u4e00\u5316Mn K-edge XANES\u5149\u8c31\u548cEXAFS\u632f\u8361\u51fd\u6570\uff1b<\/p>\n

\uff08d\uff09Mn K-edge EXAFS k2<\/sup>x(k)\u7684\u5085\u7acb\u53f6\u53d8\u6362\u5e45\u5ea6\uff1b<\/p>\n

\uff08e-f\uff09Na2<\/sub>Mn3<\/sub>O7<\/sub>\u548cNaMn3<\/sub>O7<\/sub>\u7684\u8f6fXAS\u5149\u8c31\u7684Mn L2,3<\/sub>-edge\u548cO K pre-edge\u3002<\/p>\n

\u56fe\u56db\u3001\u7535\u50ac\u5316OER\u6d4b\u91cf\u503c<\/strong>
\n \"\"\uff08a\uff09\u5408\u6210\u7684Nax<\/sub>Mn3<\/sub>O7<\/sub>\u7684\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09\u6bd4\u8f83\u57fa\u4e8e1.55 V versus RHE\u65f6BET\u8868\u9762\u79ef\u7684\u5f52\u4e00\u5316\u7535\u6d41\u5bc6\u5ea6\uff1b<\/p>\n

\uff08c\uff09\u6bd4\u8f83Nax<\/sub>Mn3<\/sub>O7<\/sub>\u4e0e\u57fa\u51c6IrO2<\/sub>\u7684Tafel\u56fe\uff1b<\/p>\n

\uff08d\uff09NaMn3<\/sub>O7<\/sub>\u57281.55 V versus RHE\u65f6\u7684\u8ba1\u65f6\u7535\u6d41\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e94\u3001\u5728OER\u6761\u4ef6\u4e0b\uff0c\u6676\u683c\u6c27\u4f5c\u4e3a\u53cd\u5e94\u4f4d\u70b9\u7684\u8bc1\u636e<\/strong>
\n \"\"\uff08a-b\uff09NaMn3<\/sub>O7<\/sub>\u7684Mn 2p\u548cO 1 s\u5728\u5f00\u8def\u30011.25\u548c1.55 V\u4e0b\u7684\u539f\u4f4dXPS\u5149\u8c31\uff1b<\/p>\n

\uff08c\uff09\u57281.23 V\u4e0b\u6c27\u7a7a\u4f4d\u518d\u586b\u5145\u7684\u8fc7\u7a0b\u548c\u76f8\u5173\u7684\u80fd\u5792\uff1b<\/p>\n

\uff08d\uff09NaMn3<\/sub>O7<\/sub>\u7684OER\u6d3b\u6027\u7684pH\u4f9d\u8d56\u6027\uff1b<\/p>\n

\uff08e\uff09\u9178-\u78b1\u4eb2\u6838\u8fdb\u653b\u7684OER\u9014\u5f84\u793a\u610f\u56fe\uff0c\u6d89\u53ca\u4e0e\u7535\u5b50\u8f6c\u79fb\u6b65\u9aa4\u89e3\u8026\u7684\u9650\u901f\u8d28\u5b50\u8f6c\u79fb\uff1b<\/p>\n

\uff08f\uff09NaMn3<\/sub>O7<\/sub>\u7535\u6781\u7684\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u901a\u8fc7\u57fa\u4e8e\u539f\u4f4d\u5149\u8c31\u7684\u8868\u5f81\u548c\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u7684\u7ed3\u5408\uff0c\u4f5c\u8005\u5229\u7528\u6a21\u62df\u7684Nax<\/sub>Mn3<\/sub>O7<\/sub>\u6750\u6599\u8bc1\u660e\u4e86\u78b1\u91d1\u5c5e\u4ecb\u5bfc\u5bf9\u8c03\u6574\u6676\u683c\u6c27\u53cd\u5e94\u6027\u548c\u6807\u5ea6\u5173\u7cfb\u7684\u5173\u952e\u4f5c\u7528\uff0c\u6709\u52a9\u4e8e\u5408\u7406\u8bbe\u8ba1\u66f4\u597d\u7684OER\u7535\u50ac\u5316\u5242\u3002\u5177\u4f53\u800c\u8a00\uff0c\u4e2d\u95f4\u6c34\u5e73\u7684Na+<\/sup>\u4ecb\u5bfc\uff08NaMn3<\/sub>O7<\/sub>\uff09\u8868\u73b0\u51fa\u6700\u4f73\u6d3b\u6027\uff0c\u7531\u4e8e\u5728\u514b\u670d\u5148\u524d\u5b58\u5728\u7684\u6807\u5ea6\u5173\u7cfb\u7684\u57fa\u7840\u4e0a\u8c03\u8282O-H\u952e\u65ad\u88c2\u548c*OOH\u5f62\u6210\u4e4b\u95f4\u7684\u80fd\u5792\u5bf9\u79f0\u6027\u3002\u6b64\u5916\uff0cpH\u4f9d\u8d56\u6027\u5b9e\u9a8c\u548cRaman\u5149\u8c31\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86\u5b83\u5728\u5e26\u8d1f\u7535\u8377\u7684\u6c27\u5316\u6c27\u7269\u79cd\u5b58\u5728\u4e0b\u4ee5\u89e3\u8026\u8d28\u5b50\/\u7535\u5b50\u9014\u5f84\u8d77\u4f5c\u7528\u3002\u901a\u8fc7\u8c03\u6574\u6676\u683c\u6c27\u53cd\u5e94\u6d3b\u6027\u548c\u6807\u5ea6\u5173\u7cfb\uff0c\u4e3a\u7535\u50ac\u5316\u6c34\u6c27\u5316\u6216\u5176\u5b83\u6c27\u5316\u53cd\u5e94\u7684\u50ac\u5316\u5242\u7684\u5408\u7406\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u6307\u5bfc\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aTuning of lattice oxygen reactivity and scaling relation to construct better oxygen evolution electrocatalyst<\/a><\/strong>. Nat. Commun.<\/em>, 2021<\/strong>, DOI: 10.1038\/s41467-021-24182-w.<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

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