{"id":224374,"date":"2021-07-10T06:28:04","date_gmt":"2021-07-09T22:28:04","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=224374"},"modified":"2021-07-09T21:28:38","modified_gmt":"2021-07-09T13:28:38","slug":"%e8%b5%b5%e4%b8%9c%e5%85%83%e9%99%a2%e5%a3%ab%e8%af%be%e9%a2%98%e7%bb%84%e4%bb%8b%e5%ad%94%e6%b0%a7%e5%8c%96%e9%92%9b%e5%b7%a5%e4%bd%9c%e4%b8%80%e8%a7%88%ef%bc%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=224374","title":{"rendered":"\u8d75\u4e1c\u5143\u9662\u58eb\u8bfe\u9898\u7ec4\u4ecb\u5b54\u6c27\u5316\u949b\u5de5\u4f5c\u4e00\u89c8\uff01"},"content":{"rendered":"

\"\"<\/p>\n

\u8d75\u4e1c\u5143\uff0c\u6559\u6388\uff0c1963\u5e746\u6708\u51fa\u751f\u4e8e\u8fbd\u5b81\u6c88\u9633\uff0c\u590d\u65e6\u5927\u5b66\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u3002\u4e3b\u8981\u4ece\u4e8b\u4ecb\u5b54\u5206\u5b50\u7b5b\u7684\u5408\u6210\u3001\u7ed3\u6784\u548c\u5e94\u7528\u7814\u7a76\uff0c\u5f00\u521b\u4e86\u591a\u79cd\u4ecb\u5b54\u6750\u6599\u5408\u6210\u65b0\u8def\u7ebf\uff0c\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u70ed\u7a33\u5b9a\u7684\u3001\u5927\u5b54\u5f84\u7684\u6709\u5e8f\u4ecb\u5b54\u6c27\u5316\u7269\u6750\u6599\u3001\u4ecb\u5b54\u9ad8\u5206\u5b50\u548c\u78b3\u6750\u6599\uff0c\u5728\u4ecb\u5b54\u5206\u5b50\u7b5b\u7ed3\u6784\u3001\u5916\u8c8c\u63a7\u5236\u53ca\u591a\u76f8\u7ec4\u88c5\u673a\u7406\u7b49\u65b9\u9762\u5f62\u6210\u72ec\u7279\u89c1\u89e3\uff0c\u4e3a\u4ecb\u5b54\u6750\u6599\u7684\u53d1\u5c55\u548c\u5e94\u7528\u505a\u51fa\u4e86\u6770\u51fa\u7684\u8d21\u732e\u3002\u5728Nature\u3001Science\u3001Nature Materials\u3001Nature Chemistry\u3001J. Am. Chem. Soc.\u3001Angew. Chem.\u3001Adv. Mater.\u7b49\u53d1\u8868SCI\u8bba\u6587700\u4f59\u7bc7\uff0c\u64b0\u5199\u4e13\u84572\u90e8\uff0c\u8bba\u6587\u88ab\u5f15\u7528\u8d85\u8fc712\u4e07\u6b21\uff08H-index169\uff09\u3002<\/p>\n

\u4ecb\u5b54\u6c27\u5316\u949b\u53d1\u8868\u6210\u679c\u4e00\u89c8\uff1a<\/b><\/strong><\/p>\n

1. ACS Central Science:\u6a44\u6984\u578b\u4ecb\u5b54\u6c27\u5316\u949b
\n \"\"<\/p>\n

\u65e0\u673a\u7eb3\u7c73\u6676\u4f53\u548c\u8868\u9762\u6d3b\u6027\u5242\u4e4b\u95f4\u7684\u5b9a\u5411\u81ea\u7ec4\u88c5\u662f\u83b7\u5f97\u65b0\u578b\u4ecb\u6676\u534a\u5bfc\u4f53\u7684\u6709\u6548\u9014\u5f84\u3002\u6b64\u5916\uff0c\u8fd9\u79cd\u591a\u5b54\u4ecb\u6676\u6027\u8d28\u6240\u5bf9\u5e94\u7684\u7269\u7406\u548c\u5316\u5b66\u6027\u8d28\uff0c\u5bf9\u4e8e\u8bbe\u8ba1\u9ad8\u6548\u7eb3\u7c73\u7ed3\u6784\u5668\u4ef6\u5341\u5206\u91cd\u8981\u3002\u7136\u800c\uff0c\u5177\u6709\u4e30\u5bcc\u8868\u9762\u4f4d\u70b9\u7684\u4ecb\u5b54\u534a\u5bfc\u4f53\u4ecb\u6676\u7684\u5408\u6210\u6781\u5176\u56f0\u96be\u3002\u5728\u6b64\uff0c\u8d75\u4e1c\u5143\u9662\u58eb\u56e2\u961f\u62a5\u544a\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u84b8\u53d1\u9a71\u52a8\u5b9a\u5411\u7ec4\u88c5\u65b9\u6cd5\uff0c\u7528\u4e8e\u5408\u6210\u65b0\u578b\u7684\u6a44\u6984\u5f62\u4ecb\u5b54\u00a0TiO2<\/sub>\u00a0\u4ecb\u6676\uff08FDU-19\uff09\uff0c\u8be5\u6750\u6599\u7531\u8d85\u8584\u7247\u72b6\u9510\u949b\u77ff\u7eb3\u7c73\u6676\u4f53\uff08\u7ea6 8 nm \u539a\uff09\u7ec4\u6210\u3002\u4ecb\u5b54\u4ecb\u6676 FDU-19 \u5177\u6709\u8d85\u9ad8\u8868\u9762\u79ef\uff08~189 m2<\/sup>\/g\uff09\u3001\u5927\u7684\u5b54\u4f53\u79ef\uff080.56 cm3<\/sup>\/g\uff09\u548c\u4e30\u5bcc\u7684\u7f3a\u9677\uff08\u6c27\u7a7a\u4f4d\u6216\u4e0d\u9971\u548c\u00a0Ti3+<\/sup>\u4f4d\u70b9\uff09\u3002\u901a\u8fc7\u5728\u771f\u7a7a\u4e2d\u9000\u706b\uff0c\u4ecb\u6676\u53d1\u751f\u4e09\u7ef4\u5230\u4e8c\u7ef4\u7ed3\u6784\u8f6c\u53d8\uff0c\u5f62\u6210\u8d85\u8584\u9510\u949b\u77ff\u5355\u6676\u7eb3\u7c73\u7247\uff08NS-FDU-19\uff0c~8 nm\u539a\u5ea6\uff09\u3002\u63d0\u51fa\u4e86\u5438\u5f15\u529b\u548c\u9759\u7535\u6392\u65a5\u4e4b\u95f4\u7684\u5e73\u8861\u6765\u786e\u5b9a\u6240\u4ea7\u751f\u7684\u51e0\u4f55\u5f62\u72b6\u548c\u7ef4\u5ea6\u3002\u57fa\u4e8e FDU-19\u6837\u54c1\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u663e\u793a\u51fa\u9ad8\u8fbe\u00a011.6%\u00a0\u7684\u8d85\u9ad8\u5149\u8f6c\u6362\u6548\u7387\uff0c\u8fd9\u4e3b\u8981\u5f52\u56e0\u4e8e\u5176\u7684\u5355\u6676\u6027\u8d28\u548c\u9ad8\u5b54\u9699\u7387\u3002\u8fd9\u9879\u5de5\u4f5c\u5bf9\u4ecb\u5b54\u534a\u5bfc\u4f53\u4ecb\u6676\u7684\u7269\u7406\u548c\u5316\u5b66\u6027\u8d28\u63d0\u4f9b\u4e86\u65b0\u7684\u7406\u89e3\uff0c\u5e76\u4e3a\u8bbe\u8ba1\u5177\u6709\u6240\u9700\u4ecb\u89c2\u7ed3\u6784\u7684\u5404\u79cd\u5355\u6676\u534a\u5bfc\u4f53\u5f00\u8f9f\u4e86\u65b0\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/acscentsci.5b00256<\/p>\n

2. Science advance:\u4ecb\u5b54\u6c27\u5316\u949b\u5fae\u7403<\/p>\n

\"\"<\/p>\n

\u9ad8\u7ed3\u6676\u4ecb\u5b54\u6750\u6599\u53ef\u4ee5\u6ee1\u8db3\u9ad8\u6027\u80fd\u80fd\u91cf\u8f6c\u6362\u88c5\u7f6e\u7684\u9700\u6c42\u3002\u4f5c\u8005\u5728\u6b64\u62a5\u544a\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u84b8\u53d1\u9a71\u52a8\u5b9a\u5411\u7ec4\u88c5\u65b9\u6cd5\u6765\u5408\u6210\u76f4\u5f84\u4e3a~800 nm \u7684\u4e09\u7ef4\u5f00\u653e\u4ecb\u5b54\u6c27\u5316\u949b\u5fae\u7403\u3002\u8be5\u6750\u6599\u5177\u6709\u5f84\u516d\u8fb9\u5f62\u4ecb\u5b54\u901a\u9053\u548c\u6676\u6001\u9510\u949b\u77ff\u5b54\u58c1\u3002\u4ecb\u5b54\u6c27\u5316\u949b\u5fae\u7403\uff0c\u5177\u6709\u9ad8\u7684\u8868\u9762\u79ef (112 m2<\/sup>\/g)\u3001\u5927\u7684\u5b54\u4f53\u79ef (0.164 cm3<\/sup>\/g) \u548c\u5355\u6676\u9510\u949b\u77ff\u5b54\u58c1\uff0c\u4f7f\u5176\u6210\u4e3a\u5bfc\u7535\u4ecb\u89c2\u5149\u9633\u6781\u8584\u819c\u7684\u7406\u60f3\u9009\u62e9\u3002\u57fa\u4e8e\u4ecb\u5b54\u6c27\u5316\u949b\u5fae\u7403\u548c\u5546\u7528\u67d3\u6599 N719 \u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60 (DSSC) \u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u9ad8\u8fbe12.1%\u3002\u8fd9\u79cd\u84b8\u53d1\u9a71\u52a8\u7684\u65b9\u6cd5\u53ef\u4ee5\u4e3a\u5728\u5404\u79cd\u4ecb\u5b54\u6750\u6599\u7684\u7ec4\u88c5\u5f00\u62d3\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/advances.sciencemag.org\/content\/1\/4\/e1500166<\/p>\n

3. JACS:\u4e09\u7ef4\u82b1\u675f\u72b6\u4ecb\u5b54\u6c27\u5316\u949b<\/p>\n

\"\"<\/p>\n

\u6784\u5efa\u5177\u6709\u7279\u6b8a\u5f62\u8c8c\u7684\u3001\u5355\u6676\u7684\u548c\u529f\u80fd\u6027\u7684\u4e09\u7ef4\u4ecb\u5b54\u7ed3\u6784\u4ecd\u7136\u662f\u6750\u6599\u79d1\u5b66\u4e2d\u7684\u4e00\u5927\u6311\u6218\u3002\u5728\u6b64\uff0c\u4f5c\u8005\u62a5\u544a\u4e86\u4e00\u79cd\u5fae\u4e73\u6db2\u81ea\u7ec4\u88c5\u65b9\u6cd5\u6765\u5408\u6210\u4e00\u79cd\u65b0\u578b\u7684\u6709\u5e8f3D\u4ecb\u5b54\u6c27\u5316\u949b\u8d85\u7ed3\u6784\u3002\u8be5\u7ed3\u6784\u7531 1 \u4e2a\u7403\u5f62\u6838\u5fc3\u548c 12 \u4e2a\u5bf9\u79f0\u536b\u661f\u534a\u7403\u7ec4\u6210\uff0c\u4ece\u6838\u5fc3\u9876\u70b9\u5916\u5ef6\u751f\u957f\u3002\u6240\u83b7\u5f97\u7684 3D \u4ecb\u5b54\u6c27\u5316\u949b\u8d85\u7ed3\u6784\u5177\u6709\u82b1\u675f\u72b6\u5f62\u8c8c\u3001\u516d\u8fb9\u5f62\u4ecb\u5b54\u901a\u9053\u3001\u9ad8\u7684\u8868\u9762\u79ef\u00a0(134-148 m2<\/sup>\/g<\/sub>)\u3001\u5927\u7684\u5b54\u4f53\u79ef (0.48-0.51 cm3<\/sup>\/g<\/sub>)\u3002\u6240\u6709\u5706\u67f1\u5f62\u4ecb\u5b54\u901a\u9053\u5728\u6574\u4e2a\u8d85\u7ed3\u6784\u4e2d\u76f8\u4e92\u8fde\u63a5\u5e76\u5448\u653e\u5c04\u72b6\u5206\u5e03\u3002\u5176\u6c27\u5316\u949b\u5927\u591a\u662f\u5355\u6676\u9510\u949b\u77ff\uff0c\u4f7f\u5176\u5177\u6709\u5149\u50ac\u5316\u6d3b\u6027\u3002\u5177\u4f53\u800c\u8a00\uff0c\u82b1\u675f\u72b6\u4ecb\u5b54\u6c27\u5316\u949b\u8d85\u7ed3\u6784\u50ac\u5316\u5242\u5728\u5404\u79cd\u7094\u70c3\u7684\u987a\u5f0f\u534a\u6c22\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\uff08\u226599.7%\uff09\u548c\u9009\u62e9\u6027\uff08\u226596%\uff09\uff0c\u8d85\u8fc7\u5546\u4e1a\u6c27\u5316\u949b\uff08P25\uff09\u50ac\u5316\u5242\u3002\u5728 25 \u6b21\u5faa\u73af\u6d4b\u8bd5\u4e2d\uff0c\u672a\u89c2\u5bdf\u5230\u6d3b\u6027\u8870\u51cf\uff0c\u8868\u660e\u4ecb\u5b54\u6c27\u5316\u949b\u8d85\u7ed3\u6784\u8d1f\u8f7d\u50ac\u5316\u5242\u5177\u6709\u9ad8\u7a33\u5b9a\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/jacs.6b11641<\/p>\n

4.\u00a0Chem:\u4ecb\u5b54\u6c27\u5316\u949b\u201c\u5f00\u53e3\u7b11\u201d\u5fae\u7403<\/p>\n

\"\"<\/p>\n

\u4ecb\u5b54\u6c27\u5316\u949b\u7eb3\u7c73\u6750\u6599\u7814\u7a76\u4e86\u8fd1\u5e74\u6765\u53d1\u5c55\u8fc5\u901f\u3002\u7136\u800c\uff0c\u5927\u591a\u6570\u7814\u7a76\u90fd\u96c6\u4e2d\u5728\u63a2\u7d22\u5b83\u4eec\u5728\u5404\u79cd\u5e94\u7528\u4e2d\u7684\u6f5c\u529b\u3002\u4ee5\u9ad8\u5ea6\u53ef\u63a7\u7684\u65b9\u5f0f\u5236\u5907\u4ecb\u5b54\u6c27\u5316\u949b\u7684\u57fa\u7840\u7814\u7a76\u4ecd\u7136\u6ca1\u6709\u592a\u591a\u6210\u679c\u3002\u5728\u6b64\uff0c\u4f5c\u8005\u62a5\u544a\u4e86\u4e00\u79cd\u7b80\u4fbf\u7684\u538b\u529b\u9a71\u52a8\u5b9a\u5411\u7ec4\u88c5\u65b9\u6cd5\uff0c\u4ee5\u5408\u6210\u4e00\u79cd\u65b0\u578b\u7684\u5177\u6709\u5f84\u5411\u4ecb\u5b54\u901a\u9053\u7684\u5f00\u88c2\u4ecb\u5b54\u6c27\u5316\u949b\u5fae\u7403\u3002\u901a\u8fc7\u6539\u53d8\u6d53 HCl \u7684\u91cf\uff0c\u4f5c\u8005\u80fd\u591f\u8c03\u63a7\u5fae\u7403\u4e2d\uff0c\u91d1\u7ea2\u77f3\/\u9510\u949b\u77ff\u76f8\u7684\u6bd4\u503c\u3002\u901a\u8fc7\u8fdb\u4e00\u6b65\u63a7\u5236\u53cd\u5e94\u6761\u4ef6\uff0c\u5305\u62ec\u6eb6\u5242\u84b8\u53d1\u65f6\u95f4\u548c\u6c34\u70ed\u6e29\u5ea6\uff0c\u8fd8\u53ef\u4ee5\u5f88\u597d\u5730\u8c03\u63a7\u7f1d\u9699\u3002\u8fd9\u79cd\u5f00\u88c2\u7684\u4ecb\u5b54\u6c27\u5316\u949b\u5fae\u7403\u5177\u6709\u826f\u597d\u7684\u6e17\u900f\u6027\u548c\u4f18\u5f02\u7684\u5149\u50ac\u5316\u5236\u6c22\u6027\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/www.sciencedirect.com\/science\/article\/pii\/S2451929418303607?via%3Dihub<\/p>\n

5. Chemical Science:\u00a0\u5177\u6709\u53ef\u63a7\u76f8\u7ed3\u7684\u4ecb\u5b54\u6c27\u5316\u949b\u5fae\u7403<\/p>\n

\"\"<\/p>\n

\u5546\u4e1a\u00a0P25-TiO2<\/sub>\u4f5c\u4e3a\u57fa\u51c6\u5149\u50ac\u5316\u5242\uff0c\u5df2\u5e7f\u6cdb\u7528\u4e8e\u5404\u79cd\u5149\u50ac\u5316\u5e94\u7528\u3002\u7136\u800c\uff0c\u4f4e\u8868\u9762\u79ef\u548c\u8f83\u5dee\u7684\u591a\u5b54\u7ed3\u6784\u6781\u5927\u5730\u9650\u5236\u4e86\u5176\u6027\u80fd\u3002\u5728\u6b64\uff0c\u901a\u8fc7\u914d\u4f4d\u534f\u540c\u81ea\u7ec4\u88c5\u65b9\u6cd5\u5408\u6210\u4e86\u5177\u6709\u53ef\u63a7\u9510\u949b\u77ff\/\u91d1\u7ea2\u77f3\u76f8\u7ed3\u548c\u5f84\u5411\u53d6\u5411\u7684\u4ecb\u5b54\u901a\u9053\u7684\u5747\u5300\u6709\u5e8f\u4ecb\u5b54 TiO2<\/sub>\u00a0\u5fae\u7403\u3002\u901a\u8fc7\u6539\u53d8\u76d0\u9178\u7684\u6d53\u5ea6\uff0c\u53ef\u4ee5\u6839\u636e\u9700\u8981\u8c03\u6574\u6240\u5f97\u5fae\u7403\u4e2d\u7684\u9510\u949b\u77ff\/\u91d1\u7ea2\u77f3\u6bd4\u4f8b\uff08\u91d1\u7ea2\u77f3\u767e\u5206\u6bd4\uff1a0-100\uff09\u3002\u5236\u5907\u7684 Meso-TiO2<\/sub>-25 \u5fae\u7403\u5177\u6709\u4e0e\u5546\u4e1a P25 \u76f8\u4f3c\u7684\u9510\u949b\u77ff\/\u91d1\u7ea2\u77f3\u6bd4\u4f8b\u3002\u4f46\u662f\u6240\u5f97\u5fae\u7403\u7684\u8868\u9762\u79ef\u00a0(78.6 m2<\/sup>\u00a0g-1<\/sup>) \u548c\u5b54\u4f53\u79ef (0.39 cm3<\/sup>\u00a0g-1<\/sup>) \u5927\u4e8e\u5546\u4e1a P25\u3002\u5f53\u7528\u4f5c\u4ea7H2<\/sub>\u00a0\u7684\u5149\u50ac\u5316\u5242\u65f6\uff0cMeso-TiO2<\/sub>-25\u7684 H2<\/sub>\u00a0\u4ea7\u7387\u660e\u663e\u5927\u4e8e\u5546\u4e1a P25\u3002\u8fd9\u79cd\u914d\u4f4d\u534f\u540c\u81ea\u7ec4\u88c5\u65b9\u6cd5\u4e3a\u9ad8\u6027\u80fd\u4ecb\u5b54\u5149\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u548c\u5408\u6210\u5f00\u8f9f\u4e86\u4e00\u6761\u65b0\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2019\/SC\/C8SC04155E#!divAbstract<\/p>\n

6. JACS:\u5355\u5c42\u4ecb\u5b54\u6c27\u5316\u949b<\/p>\n

\"\"<\/p>\n

\u4e8c\u7ef4\u00a0(2D) \u7eb3\u7c73\u6750\u6599\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u7279\u6027\uff0c\u6210\u4e3a\u7814\u7a76\u7684\u7126\u70b9\u3002\u7136\u800c\uff0c\u7531\u4e8e\u96be\u4ee5\u5728\u4e8c\u7ef4\u7eb3\u7c73\u7ed3\u6784\u4e2d\u5f62\u6210\u5b54\u9699\uff0c\u4e8c\u7ef4\u591a\u5b54\u6750\u6599\u4ecd\u7136\u6bd4\u8f83\u5c11\u89c1\u3002\u5728\u6b64\uff0c\u4f5c\u8005\u901a\u8fc7\u6c34\u70ed\u8bf1\u5bfc\u6eb6\u5242\u9650\u5236\u7ec4\u88c5\u65b9\u6cd5\u5408\u6210\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u5355\u5c42\u4e8c\u7ef4\u4ecb\u5b54 TiO2<\/sub>\u00a0\u7eb3\u7c73\u7247\u3002\u5176\u5177\u6709\u5747\u5300\u7684\u5c3a\u5bf8\u548c\u539a\u5ea6\u4ee5\u53ca\u6709\u5e8f\u7684\u4ecb\u5b54\u7ed3\u6784\u3002\u5747\u5300\u7684 TiO2<\/sub>\u00a0\u7eb3\u7c73\u7247\u80fd\u591f\u4e3a\u94a0\u79bb\u5b50\u5438\u9644\u548c\u5d4c\u5165\u63d0\u4f9b\u5927\u7684\u7a7a\u9699\uff0c\u5e76\u9632\u6b62\u4f53\u79ef\u81a8\u80c0\u3002\u4ecb\u5b54 TiO2<\/sub>\u00a0\u7eb3\u7c73\u7247\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u9633\u6781\u5728 100 mA g-1<\/sup>\u00a0\u4e0b\u8868\u73b0\u51fa 220 mAh g-1<\/sup>\u00a0\u7684\u4f18\u5f02\u53ef\u9006\u5bb9\u91cf\u3002\u5e76\u4e14\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u591a\u6b21\u5faa\u73af\u540e\uff0c\u53ef\u4ee5\u4fdd\u6301\u5728\u00a0199 mAh g-1<\/sup>\u3002\u5373\u4f7f\u5728 10 A g-1<\/sup>\u00a0\u7684\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c10000 \u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4ecd\u4fdd\u6301\u5728 44 mAh g-1<\/sup>\uff0c\u8868\u660e\u5176\u5177\u6709\u5353\u8d8a\u7684\u50a8\u80fd\u6027\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/jacs.8b00909<\/p>\n

7. JACS:\u4e8c\u7ef4\u4ecb\u5b54\u6c27\u5316\u949b\u5f02\u7ed3\u6784<\/p>\n

\"\"<\/p>\n

\u4ecb\u5b54\u4e8c\u7ef4\u00a0(2D) \u5f02\u8d28\u7ed3\u6784\u7531\u4e8e\u5176\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u8f83\u77ed\u7684\u6269\u6563\u8ddd\u79bb\uff0c\u4e3a\u7535\u50ac\u5316\u3001\u5149\u50ac\u5316\u3001\u80fd\u91cf\u5b58\u50a8\u548c\u8f6c\u6362\u6280\u672f\u7684\u53d1\u5c55\u63d0\u4f9b\u4e86\u65b0\u7684\u7b56\u7565\u3002\u7136\u800c\uff0c\u7531\u4e8e\u4f20\u7edf\u5316\u5b66\u3001\u673a\u68b0\u5265\u79bb\u6216\u81ea\u7ec4\u88c5\u65b9\u6cd5\u8f83\u4e3a\u56f0\u96be\uff0c\u5c42\u72b6\u4ecb\u5b54\u5f02\u7ed3\u6784\u8fd8\u9c9c\u6709\u62a5\u9053\u3002\u5728\u6b64\uff0c\u4f5c\u8005\u63a2\u7d22\u4e86\u4e00\u79cd\u81ea\u4e0b\u800c\u4e0a\u7684\u7b56\u7565\uff0c\u7528\u4e8e\u7b80\u6613\u5408\u6210\u5177\u6709\u5747\u5300\u4ecb\u5b54\u5c3a\u5bf8\u7684\u4ecb\u5b54\u78b3-\u4e8c\u6c27\u5316\u949b-\u4ecb\u5b54\u78b3\u5f02\u8d28\u7ed3\u6784\uff0c\u4ece\u800c\u5b9e\u73b0\u5728\u975e\u6c34\u7535\u89e3\u8d28\u4e2d\u7684\u8d5d\u7535\u5bb9\u94a0\u79bb\u5b50\u5b58\u50a8\u7684\u8d85\u9ad8\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u5bff\u547d\u3002\u8fd9\u79cd\u65b0\u578b\u7684\u5f02\u8d28\u7ed3\u6784\u7531\u6709\u5e8f\u7684\u5355\u5c42\u4ecb\u5b54\u4e8c\u6c27\u5316\u949b\u7eb3\u7c73\u7247\u548c\u4e24\u4fa7\u7ec4\u88c5\u7684\u4ecb\u5b54\u78b3\u5355\u5c42\u7ec4\u6210\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8d2f\u901a\u7684\u5b54\u9053\u548c\u5f02\u8d28\u754c\u9762\u7684\u7ec4\u5408\u53ef\u4ee5\u63d0\u5347\u53ef\u9006\u8d5d\u7535\u5bb9\uff081 mV s-1<\/sup>\u00a0\u626b\u63cf\u901f\u7387\u4e0b\u603b\u7535\u8377\u5b58\u50a8\u7684 96.4%\uff09\uff0c\u5e76\u4e14\u4f7f\u6750\u6599\u5728\u5feb\u901f\u94a0\u5316\u548c\u8131\u76d0\u8fc7\u7a0b\u4fdd\u7559\u4e86\u8f83\u5f3a\u7684\u673a\u68b0\u7a33\u5b9a\u6027\u3002\u8be5\u7814\u7a76\u63ed\u793a\u4e86\u5c06\u4ecb\u5b54\u4e8c\u7ef4\u00a0(2D) \u5f02\u8d28\u7ed3\u6784\u4f5c\u4e3a\u589e\u5f3a\u7535\u6d3b\u6027\u6750\u6599\u7535\u8377\u5b58\u50a8\u52a8\u529b\u5b66\u7b56\u7565\u7684\u91cd\u8981\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/jacs.9b06962<\/p>\n

8. Angew:\u5bccTi3+<\/sup>\u7f3a\u9677\u4ecb\u5b54\u6c27\u5316\u949b<\/p>\n

\"\"<\/p>\n

\u901a\u8fc7\u5728\u5355\u80f6\u675f\u7ec4\u88c5\u8fc7\u7a0b\u4e2d\u5f15\u5165\u8fd8\u539f\u5242\uff082-\u4e59\u57fa\u54aa\u5511\uff09\uff0c\u4f5c\u8005\u8bbe\u8ba1\u4e86\u4e00\u79cd\u6709\u5e8f\u7684\u4ecb\u5b54 TiO2<\/sub>\u00a0\u5fae\u7403\uff0c\u5b83\u5c06\u5f84\u5411\u6392\u5217\u7684\u4ecb\u5b54\u7ed3\u6784\u4e0e\u4ecb\u5b54\u6846\u67b6\u4e2d\u7684 Ti3+<\/sup>\u00a0\u7f3a\u9677\u76f8\u7ed3\u5408\u3002\u8fd9\u79cd\u8fd8\u539f\u5242\u4e5f\u90e8\u5206\u5145\u5f53\u4e86\u4ecb\u5b54\u6846\u67b6\u4e2d\u7684\u7ec4\u6210\u90e8\u5206\uff0c\u5e76\u5728\u7145\u70e7\u8fc7\u7a0b\u4e2d\u539f\u4f4d\u8fd8\u539f Ti4+<\/sup>\u00a0\u4ee5\u4ea7\u751f\u7f3a\u9677\uff0c\u4ece\u800c\u5bfc\u81f4\u4f53\u76f8 Ti3+<\/sup>\u00a0\u7f3a\u9677\u548c\u6709\u5e8f\u4ecb\u5b54\u7ed3\u6784\u5171\u5b58\u3002\u4ecb\u5b54 TiO2<\/sub>\u00a0\u5177\u6709\u4f18\u5f02\u7684\u4ecb\u5b54\u7279\u6027\uff08106 m2<\/sup>\u00a0g\u22121<\/sup>\u00a0\u7684\u9ad8\u8868\u9762\u79ef\uff0c18.4 nm \u7684\u5e73\u5747\u5b54\u5f84\uff09\u548c\u7a33\u5b9a\u7684\u7f3a\u9677\u3002\u72ec\u7279\u7684\u4ecb\u89c2\u7ed3\u6784\u548c\u539f\u5b50\u7f3a\u9677\u63d0\u4f9b\u4e86\u6709\u6548\u7684\u8d28\u91cf\u4f20\u8f93\u548c\u589e\u5f3a\u7684\u5149\u5229\u7528\u6548\u7387\uff0c\u4ece\u800c\u663e\u7740\u63d0\u9ad8\u4e86 H2<\/sub>\u00a0\u751f\u6210\u7387\u3002\u8be5\u6750\u6599\u53ef\u4ee5\u5b9e\u73b0 19.8 mmol g\u22121<\/sup>\u00a0h\u22121<\/sup>\u00a0\u7684H2<\/sub>\u00a0\u6790\u51fa\u901f\u7387\uff0c\u540c\u65f6\u5728\u592a\u9633\u5149\u4e0b\u5177\u6709\u51fa\u8272\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202007859<\/p>\n

\u672c\u6587\u7531\u4e00\u4e00\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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