{"id":224431,"date":"2021-07-09T06:52:14","date_gmt":"2021-07-08T22:52:14","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=224431"},"modified":"2021-07-08T20:52:42","modified_gmt":"2021-07-08T12:52:42","slug":"%e7%9b%98%e7%82%b9%ef%bc%9a%e9%99%88%e7%ab%8b%e6%b3%89%e9%99%a2%e5%a3%ab%e3%80%81%e4%b8%87%e7%ab%8b%e9%aa%8f%e9%99%a2%e5%a3%ab%e3%80%81%e5%8d%97%e7%ad%96%e6%96%87%e9%99%a2%e5%a3%ab%e8%af%be%e9%a2%98","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=224431","title":{"rendered":"\u76d8\u70b9\uff1a\u9648\u7acb\u6cc9\u9662\u58eb\u3001\u4e07\u7acb\u9a8f\u9662\u58eb\u3001\u5357\u7b56\u6587\u9662\u58eb\u8bfe\u9898\u7ec4\u8fd1\u671f\u56fa\u6001\u7535\u6c60\u91cd\u8981\u7814\u7a76\u6210\u679c"},"content":{"rendered":"

\u56fa\u6001\u7535\u6c60\u91c7\u7528\u56fa\u6001\u7535\u89e3\u8d28\u66ff\u4ee3\u4f20\u7edf\u6709\u673a\u6db2\u6001\u7535\u89e3\u6db2\uff0c\u6709\u671b\u4ece\u6839\u672c\u4e3b\u89e3\u51b3\u7535\u6c60\u5b89\u5168\u6027\u95ee\u9898\uff0c\u63d0\u9ad8\u7535\u6c60\u80fd\u91cf\u5bc6\u5ea6\uff0c\u662f\u7535\u52a8\u6c7d\u8f66\u548c\u89c4\u6a21\u5316\u50a8\u80fd\u7406\u60f3\u7684\u5316\u5b66\u7535\u6e90\u3002\u8fd1\u5e74\u6765\uff0c\u56fa\u6001\u7535\u6c60\u53d7\u5230\u5b66\u672f\u754c\u548c\u5de5\u4e1a\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\u4e0e\u7814\u7a76\u3002\u672c\u6587\u91cd\u70b9\u4ecb\u7ecd\u9648\u7acb\u6cc9\u9662\u58eb\u3001\u4e07\u7acb\u9a8f\u9662\u58eb\u3001\u5357\u7b56\u6587\u9662\u58eb\u4ee5\u53ca\u4ed6\u4eec\u7684\u8fd1\u671f\u7814\u7a76\u8fdb\u5c55\u3002<\/p>\n

<\/b>\u4e00\u3001\u9648\u7acb\u6cc9\"\"<\/b><\/strong><\/p>\n

1940\u5e743\u670829\u65e5\u751f\u4e8e\u56db\u5ddd\u7701\u5357\u5145\u30021964\u5e74\u6bd5\u4e1a\u4e8e\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u3002\u73b0\u4efb\u4e2d\u79d1\u9662\u7269\u7406\u6240\u7814\u7a76\u5458\u3002\u66fe\u4efb\u4e9a\u6d32\u56fa\u4f53\u79bb\u5b50\u5b66\u4f1a\u526f\u4e3b\u5e2d\u30022001\u5e74\u5f53\u9009\u4e3a\u4e2d\u56fd\u5de5\u7a0b\u9662\u9662\u58eb\u30022004\uff5e\u81f3\u4eca\u4efb\u4e2d\u56fd\u7845\u9178\u76d0\u5b66\u4f1a\u526f\u7406\u4e8b\u957f\u3002\u5728\u4e2d\u56fd\u7387\u5148\u5f00\u5c55\u9502\u7535\u6c60\u53ca\u76f8\u5173\u6750\u6599\u7814\u7a76\u3002\u5728\u56fd\u5185\u9996\u5148\u7814\u5236\u6210\u529f\u9502\u79bb\u5b50\u7535\u6c60\u3002\u89e3\u51b3\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u89c4\u6a21\u5316\u751f\u4ea7\u7684\u79d1\u5b66\u6280\u672f\u4e0e\u5de5\u7a0b\u95ee\u9898\uff0c\u5b9e\u73b0\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u7684\u4ea7\u4e1a\u5316\u3002\u4ed6\u66fe\u662f\u7269\u7406\u6240\u9ad8\u6e29\u8d85\u5bfc\u6750\u6599\u7814\u7a76\u7684\u8d1f\u8d23\u4eba\u548c\u4e3b\u8981\u7814\u7a76\u8005\uff0c\u9996\u6b21\u53d1\u73b070K\u8d85\u5bfc\u8ff9\u8c61\uff0c\u7814\u5236\u51fa\u6db2\u6c2e\u6e29\u533a\u8d85\u5bfc\u4f53\u5e76\u9996\u6b21\u516c\u5e03\u4e86\u6750\u6599\u6210\u5206\u3002\u8fd1\u5e74\u6765\uff0c\u5f00\u5c55\u4e86\u5168\u56fa\u6001\u9502\u7535\u6c60\u3001\u9502\u786b\u7535\u6c60\u3001\u9502\u7a7a\u6c14\u7535\u6c60\u3001\u5ba4\u6e29\u94a0\u79bb\u5b50\u7535\u6c60\u548c\u56fa\u4f53\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60\u4e2d\u7684\u7269\u7406\u5316\u5b66\u8fc7\u7a0b\u53ca\u76f8\u5173\u6750\u6599\u7684\u8bbe\u8ba1\u3001\u5408\u6210\u3001\u8868\u5f81\u3001\u7269\u7406\u548c\u7535\u5316\u5b66\u6027\u80fd\u53ca\u5176\u5e94\u7528\u7814\u7a76\u3002\u4e3a\u5f00\u53d1\u4e0b\u4e00\u4ee3\u52a8\u529b\u7535\u6c60\u548c\u50a8\u80fd\u7535\u6c60\u5960\u5b9a\u4e86\u57fa\u7840\u3002\u53d1\u8868\u8bba\u6587250\u4f59\u7bc7\uff0c\u7533\u62a5\u53d1\u660e\u4e13\u522915\u4f59\u9879\u3002\u66fe\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956\u3001\u4e2d\u79d1\u9662\u79d1\u6280\u8fdb\u6b65\u7279\u7b49\u5956\u548c\u4e8c\u7b49\u5956\uff0c2007\u5e74\u83b7\u56fd\u9645\u7535\u6c60\u6750\u6599\u534f\u4f1a\u7ec8\u751f\u6210\u5c31\u5956\u3002<\/p>\n

\u8fd1\u671f\u4ee3\u8868\u6027\u6210\u679c<\/b><\/strong><\/p>\n

1. Adv. Mater.\uff1a\u5168\u7535\u5316\u5b66\u6d3b\u6027\u7535\u6781\u56fa\u6001\u7535\u6c60<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u80fd\u91cf\u5bc6\u5ea6\u662f\u9502\uff08Li\uff09\u79bb\u5b50\u7535\u6c60\u7684\u6838\u5fc3\u7ade\u4e89\u529b\u3002\u5728\u4f20\u7edf\u7684\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c\u7531\u4e8e 3D \u591a\u5b54\u7535\u6781\u4e4b\u95f4\u5b58\u5728\u975e\u7535\u5316\u5b66\u6d3b\u6027\u90e8\u5206\uff08\u5305\u62ec\u7535\u89e3\u8d28\u3001\u7c98\u5408\u5242\u548c\u78b3\u6dfb\u52a0\u5242\uff09\uff0c\u8fd9\u4e9b\u88ab\u8ba4\u4e3a\u662f\u7535\u5b50\u548c\u79bb\u5b50\u4f20\u8f93\u7f51\u7edc\u4e2d\u4e0d\u53ef\u6216\u7f3a\u4e14\u4e0d\u53ef\u8fd8\u539f\u7684\u7ec4\u6210\u90e8\u5206\uff0c\u4f7f\u5f97\u5728\u7535\u6781\u6c34\u5e73\u4e0a\u7684\u91cd\u91cf\/\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u5229\u7528\u7387\u5e76\u4e0d\u4ee4\u4eba\u6ee1\u610f\uff08\u5206\u522b<84 wt% \u548c <62 vol%\uff09\u3002\u4e3a\u6b64\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u6240\u9648\u7acb\u6cc9\u9662\u58eb\u3001\u7d22\u938f\u654f\u6559\u6388\u3001\u9ebb\u7701\u7406\u5de5\u5b66\u9662\u674e\u5de8<\/b><\/strong>\u6559\u6388<\/b><\/strong>\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u79cd\u7528\u4e8e\u5168\u56fa\u6001\u9502\u7535\u6c60\u7684\u81f4\u5bc6\u201c\u5168\u7535\u5316\u5b66\u6d3b\u6027\u201d\uff08AEA\uff09\u7535\u6781\uff0c\u8be5\u7535\u6781\u5b8c\u5168\u7531\u4e00\u7cfb\u5217\u4f18\u5f02\u7684\u6df7\u5408\u7535\u5b50-\u79bb\u5b50\u5bfc\u7535\u9634\u6781\u6784\u6210\uff0c\u4ee5\u6700\u5927\u9650\u5ea6\u5730\u51cf\u5c11\u9502\u7535\u6c60\u4e4b\u95f4\u7684\u80fd\u91cf\u5bc6\u5ea6\u5dee\u8ddd\u3002\u7535\u6781\u6c34\u5e73\u7684\u53ef\u53ca\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u3002\u6b64\u5916\uff0c\u7531\u4e8e AEA \u6b63\u6781\u81ea\u652f\u6491\u79bb\u5b50-\u7535\u5b50\u5bfc\u7535\u7f51\u7edc\uff0c\u81f4\u5bc6\u7684\u6742\u5316\u786b (S) \u57fa AEA \u7535\u6781\u8868\u73b0\u51fa 91.8% \u7684\u9ad8\u538b\u5b9e\u586b\u5145\u7387\u3002\u572870\u00b0C\u65f6\uff0c\u7535\u6781\u6c34\u5e73\u4e0a\u7684\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u8fbe 777 W h kg-1<\/sup>\u00a0\u548c 1945 W h L-1 <\/sup>(\u4ee5\u603b\u9634\u6781\u548c\u9633\u6781\u4e3a\u57fa\u51c6)\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1002\/adma.202008723<\/u><\/a><\/p>\n

<\/b>2. Adv.\u00a0<\/strong>Mater.\uff1a<\/b><\/strong>\u7531\u5177\u6709\u8d85\u9ad8\u6c34\u5206\u7a33\u5b9a\u6027\u548c\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u6c14\u76f8\u5408\u6210\u786b\u5316\u7269\u7535\u89e3\u8d28\u5b9e\u73b0\u7684\u9ad8\u6027\u80fd\u5168\u56fa\u6001\u7535\u6c60<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\uff08SEs\uff09\u56e0\u5176\u4f18\u5f02\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u5353\u8d8a\u7684\u5ef6\u5c55\u6027\u800c\u88ab\u516c\u8ba4\u4e3a\u5168\u56fa\u6001\u7535\u6c60\uff08ASSBs\uff09\u6700\u6709\u524d\u9014\u7684\u5019\u9009\u6750\u6599\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u7a7a\u6c14\u7a33\u5b9a\u6027\u5dee\u3001\u5408\u6210\u5de5\u827a\u590d\u6742\u3001\u6536\u7387\u4f4e\u3001\u751f\u4ea7\u6210\u672c\u9ad8\u7b49\u95ee\u9898\u963b\u788d\u4e86\u786b\u5316\u7269SEs\u7684\u5927\u89c4\u6a21\u5e94\u7528\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u6240\u5434\u51e1\u7814\u7a76\u5458\u3001\u9648\u7acb\u6cc9\u9662\u58eb\u3001\u674e\u6cd3\u7814\u7a76\u5458\u7b49\u4eba<\/b><\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u5728\u73af\u5883\u7a7a\u6c14\u4e2d\u7528\u6c27\u5316\u7269\u539f\u6599\u4e00\u6b65\u6c14\u76f8\u5408\u6210\u786b\u5316\u7269 SEs \u7684\u65b9\u6cd5\uff0c\u5b8c\u5168\u6446\u8131\u4e86\u624b\u5957\u7bb1\uff0c\u4ece\u800c\u4f7f\u5927\u89c4\u6a21\u751f\u4ea7\u6210\u4e3a\u53ef\u80fd\u3002\u901a\u8fc7\u8c03\u6574\u53d6\u4ee3\u5143\u7d20\u548c\u6d53\u5ea6\uff0cLi4-x<\/sub>Sn1-x<\/sub>Mx<\/sub>S4<\/sub>\u00a0\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u53ef\u4ee5\u8fbe\u5230 2.45 mS cm-1<\/sup>\uff0c\u8fd9\u662f\u6240\u6709\u62a5\u9053\u7684\u6f6e\u6e7f\u7a7a\u6c14\u7a33\u5b9a\u548c\u53ef\u56de\u6536\u7684\u9502\u79bb\u5b50\u786b\u5316\u7269 SE \u4e2d\u7684\u6700\u9ad8\u503c\u3002\u6b64\u5916\uff0c\u5177\u6709\u7a7a\u6c14\/\u6c34\u66b4\u9732\u548c\u4e2d\u6e29\u5904\u7406\u7684\u00a0Li3.875<\/sub>Sn0.875<\/sub>As0.125<\/sub>S4<\/sub>\u00a0\u7684 ASSB \u53ef\u4ee5\u4fdd\u6301\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u5177\u6709\u6700\u9ad8\u7684\u53ef\u9006\u5bb9\u91cf\uff08188.4 mAh g-1<\/sup>\uff09\u548c\u6700\u957f\u7684\u5faa\u73af\u5bff\u547d\uff08210 \u6b21\u5faa\u73af\uff09\uff0c\u8fd9\u4e5f\u6253\u7834\u4e86\u5df2\u6709\u8bb0\u5f55\u3002\u56e0\u6b64\uff0c\u5b83\u53ef\u80fd\u6210\u4e3a\u786b\u5316\u7269ASSBs\u5411\u5176\u5b9e\u9645\u5e94\u7528\u548c\u5546\u4e1a\u5316\u53d1\u5c55\u8fc7\u7a0b\u4e2d\u6700\u5173\u952e\u7684\u7a81\u7834\u4e4b\u4e00\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/adma.202100921<\/u><\/a><\/p>\n

\u00a03.\u00a0Adv.\u00a0<\/strong><\/b><\/strong>Funct. Mater.<\/b><\/strong>\uff1a<\/b><\/strong>\u5177\u6709\u4f18\u8d8a\u7684\u5faa\u73af\u548c\u5b89\u5168\u6027\u80fd<\/b><\/strong>\u7684<\/b><\/strong>4.2 V\u805a(\u73af\u6c27\u4e59\u70f7)\u57fa\u5168\u56fa\u6001\u9502\u7535\u6c60<\/b><\/strong><\/p>\n

\"\"<\/strong><\/b><\/strong><\/p>\n

\u5168\u56fa\u6001\u7535\u6c60\u88ab\u8ba4\u4e3a\u662f\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u9ad8\u5b89\u5168\u6027\u7684\u50a8\u80fd\u7cfb\u7edf\u7684\u7ec8\u6781\u89e3\u51b3\u65b9\u6848\u3002\u7136\u800c\uff0c\u660e\u663e\u7684\u56fa-\u56fa\u63a5\u89e6\u548c\u754c\u9762\u7a33\u5b9a\u6027\u95ee\u9898\u5bf9\u6784\u5efa\u5177\u6709\u5b9e\u7528\u6027\u80fd\u7684\u5168\u56fa\u6001\u7535\u6c60\u6784\u6210\u4e86\u5de8\u5927\u6311\u6218\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u6240\u9648\u7acb\u6cc9\u9662\u58eb\u3001\u674e\u6cd3\u7814\u7a76\u5458\u3001\u79b9\u4e60\u8c26\u7814\u7a76\u5458\u7b49\u4eba<\/b><\/strong>\u53d1\u73b0\u78b3\u9178\u4e9a\u4e59\u70ef\u916f (VC) \u7684\u70ed\u5f15\u53d1\u805a\u5408\u548c\u6b63\u6781\u7535\u89e3\u8d28\u4e2d\u95f4\u76f8 (CEI) \u7684\u540c\u65f6\u63ba\u5165\u5f62\u6210\u6dfb\u52a0\u5242\u4e8c\u6c1f\uff08\u8349\u9178\uff09\u787c\u9178\u9502\uff08LiDFOB\uff09\u53ef\u4ee5\u534f\u540c\u4fc3\u8fdb\u9ad8\u538b\u7a33\u5b9a\u4ee5\u53ca\u6b63\u6781\u548c\u56fa\u4f53\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u4f4e\u7535\u963b\u754c\u9762\u5c42\u3002\u91c7\u7528\u901a\u8fc7\u8fd9\u79cd\u539f\u4f4d CEI \u7b56\u7565\u6539\u6027\u7684 LiCoO2<\/sub>\u00a0\u6b63\u6781\u7684PEO \u57fa\u5168\u56fa\u6001\u9502\u7535\u6c60 (ASSLB) \u8868\u73b0\u51fa\u4f18\u5f02\u7684 4.2 V \u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u653e\u7535\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a\u00a071.5% 500 \u6b21\u5faa\u73af\u3002\u6b64\u5916\uff0c\u52a0\u901f\u91cf\u70ed\u6cd5 (ARC) \u6d4b\u8bd5\u8868\u660e\uff0c\u8be5\u7535\u6c60\u663e\u793a\u51fa\u975e\u51e1\u7684\u5b89\u5168\u6027\u80fd\uff0c\u5728 350\u00b0C \u4ee5\u4e0b\u6ca1\u6709\u660e\u663e\u7684\u70ed\u5931\u63a7\u3002\u8fd9\u9879\u5de5\u4f5c\u5c55\u793a\u4e86\u4e00\u79cd\u6709\u6548\u7684\u754c\u9762\u5de5\u7a0b\u7b56\u7565\uff0c\u53ef\u4ee5\u4fdd\u8bc1\u5f62\u6210\u7535\u5316\u5b66\u548c\u70ed\u7a33\u5b9a\u7684\u6b63\u6781\/\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\uff0c\u8fd9\u5bf9\u4e8e ASSLB \u7684\u7a33\u5b9a\u548c\u5b89\u5168\u8fd0\u884c\u81f3\u5173\u91cd\u8981\u3002\u6b64\u5916\uff0c\u57fa\u4e8e PEO \u7684 ASSLBs \u5728\u9ad8\u538b\u4e0b\u7a33\u5b9a\u5faa\u73af\u7684\u9a8c\u8bc1\u53ef\u80fd\u4f1a\u9f13\u52b1\u8fdb\u4e00\u6b65\u4f18\u5316\u754c\u9762\u5de5\u7a0b\u5de5\u827a\u4ee5\u53ca\u5927\u89c4\u6a21\u5236\u9020\u7684\u52aa\u529b\uff0c\u56e0\u4e3a\u57fa\u4e8e PEO \u7684 ASSLBs \u80fd\u91cf\u5bc6\u5ea6\u7684\u63d0\u9ad8\u5c06\u662f\u5bf9\u5b9e\u9645\u5e94\u7528\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a\u00a0https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/adfm.201909392<\/u><\/a><\/p>\n

\u4e8c\u3001\u4e07\u7acb\u9a8f\"\"<\/strong><\/b><\/strong><\/p>\n

\u7269\u7406\u5316\u5b66\u5bb6\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u7814\u7a76\u5458\u30021957\u5e747\u6708\u751f\u4e8e\u8fbd\u5b81\u5927\u8fde\uff0c\u7c4d\u8d2f\u8fbd\u5b81\u5927\u8fde\u30021982\u5e741\u6708\u6bd5\u4e1a\u4e8e\u5927\u8fde\u5de5\u5b66\u9662\u673a\u68b0\u7cfb\uff0c1987\u5e74\u83b7\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7855\u58eb\u5b66\u4f4d\uff0c1996\u5e74\u83b7\u65e5\u672c\u4e1c\u5317\u5927\u5b66\u535a\u58eb\u5b66\u4f4d\u30022009\u5e74\u5f53\u9009\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u30022010\u5e74\u5f53\u9009\u7b2c\u4e09\u4e16\u754c\u79d1\u5b66\u9662\u9662\u58eb\u30022015\u5e74\u81f32017\u5e74\u62c5\u4efb\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6821\u957f\u3002\u4e3b\u8981\u4ece\u4e8b\u7535\u5316\u5b66\u626b\u63cf\u96a7\u9053\u663e\u5fae\u5b66\uff08ECSTM\uff09\u3001\u7535\u5316\u5b66\u548c\u8868\u9762\u79d1\u5b66\u7684\u4ea4\u53c9\u5b66\u79d1\u7684\u7814\u7a76\uff0c\u5728\u5305\u62ecNature Comm., Acc. Chem. Res., PNAS, Angew. Chem., JACS\u7b49\u5b66\u672f\u520a\u7269\u53d1\u8868\u5b66\u672f\u8bba\u6587300\u4f59\u7bc7\u3002\u53d1\u5c55\u4e86ECSTM\u7684\u9ad8\u5206\u8fa8\u7a33\u5b9a\u6210\u50cf\u6280\u672f\u548c\u8868\u9762\u5206\u5b50\u7ec4\u88c5\u7684\u7cfb\u5217\u65b9\u6cd5\uff0c\u63d0\u51fa\u4e86\u57fa\u4e8e\u4e0d\u540c\u76f8\u4e92\u4f5c\u7528\u7684\u8868\u9762\u5206\u5b50\u5438\u9644\u548c\u7ec4\u88c5\u89c4\u5f8b\uff0c\u5e76\u5e94\u7528\u4e8e\u8868\u9762\u5206\u5b50\u7ec4\u88c5\u3001\u7ec4\u88c5\u7ed3\u6784\u8f6c\u5316\u548c\u539f\u5b50\u5206\u5b50\u8fc1\u79fb\u7b49\u57fa\u672c\u7269\u7406\u5316\u5b66\u95ee\u9898\u7814\u7a76\u3002\u7814\u7a76\u4e86\u591a\u79cd\u7c7b\u578b\u624b\u6027\u5206\u5b50\u7684\u8868\u9762\u5438\u9644\u548cSTM\u6210\u50cf\u673a\u5236\uff0c\u4e3a\u8868\u9762\u624b\u6027\u8bc6\u522b\u548c\u7ed3\u6784\u7814\u7a76\u63d0\u4f9b\u4e86\u53c8\u4e00\u65b9\u6cd5\u3002\u5728\u7535\u5316\u5b66\u548c\u7eb3\u7c73\u79d1\u5b66\u7684\u4ea4\u53c9\u9886\u57df\u8fdb\u884c\u7814\u7a76\uff0c\u6240\u53d1\u5c55\u7684\u5fae\u7eb3\u590d\u5408\u7ed3\u6784\u548c\u78b3\u7f51\u7edc\u6280\u672f\u663e\u8457\u63d0\u9ad8\u4e86\u7eb3\u7c73\u6750\u6599\u7684\u7535\u50ac\u5316\u6027\u80fd\u548c\u7535\u8377\u4f20\u8f93\u901f\u7387\u3002\u66fe\u83b72007\u5e74\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\uff0c2009\u5e74\u53d1\u5c55\u4e2d\u56fd\u5bb6\u79d1\u5b66\u9662\uff08TWAS\uff09\u5316\u5b66\u5956\u7b49\u3002<\/p>\n

\u8fd1\u671f\u4ee3\u8868\u6027\u6210\u679c<\/b><\/strong><\/p>\n

1. Angew. <\/b><\/strong>Chem. Int. Ed.\uff1a\u5229\u7528\u4e2d\u6e29\u8f6c\u5316\u5316\u5b66\u6784\u5efa\u7a7a\u6c14\u7a33\u5b9a\u3001\u9502\u6c89\u79ef\u53ef\u8c03\u8282\u7684\u77f3\u69b4\u77f3\u754c\u9762<\/b><\/strong><\/p>\n

\"\"<\/strong><\/b><\/strong><\/p>\n

\u77f3\u69b4\u77f3\u578b\u7535\u89e3\u8d28\u5bf9\u7a7a\u6c14\u66b4\u9732\u5177\u6709\u4e0d\u7a33\u5b9a\u7684\u5316\u5b66\u6027\u8d28\uff0c\u8fd9\u4f1a\u5728\u7535\u89e3\u8d28\u8868\u9762\u4ea7\u751f\u6c61\u67d3\u7269\u5e76\u5bfc\u81f4\u4e0e\u9502\u91d1\u5c5e\u7684\u754c\u9762\u63a5\u89e6\u4e0d\u826f\u3002\u5728>700 \u00b0C \u4e0b\u5bf9\u77f3\u69b4\u77f3\u8fdb\u884c\u70ed\u5904\u7406\u53ef\u4ee5\u53bb\u9664\u8868\u9762\u6c61\u67d3\u7269\uff0c\u4f46\u5b83\u4f1a\u4f7f\u7a7a\u6c14\u4e2d\u7684\u6c61\u67d3\u7269\u518d\u751f\uff0c\u5e76\u4e14\u968f\u7740\u66f4\u591a\u7684\u7535\u5b50\u4f20\u5bfc\u7f3a\u9677\u4f4d\u70b9\u66b4\u9732\u51fa\u6765\uff0c\u4f1a\u52a0\u5267\u9502\u679d\u6676\u95ee\u9898\u3002\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u7684\u4e07\u7acb\u9a8f\u9662\u58eb\u3001\u90ed\u7389\u56fd\u3001\u8f9b\u68ee\u7b49\u4eba<\/b><\/strong>\u62a5\u544a\u4e86\u4e00\u79cd\u65b0\u7684\u8868\u9762\u5316\u5b66\u65b9\u6cd5\uff0c\u53ef\u5728 <180 \u00b0C \u7684\u4e2d\u7b49\u6e29\u5ea6\u4e0b\u5c06\u6c61\u67d3\u7269\u8f6c\u5316\u4e3a\u6c1f\u5316\u754c\u9762\u3002\u6539\u6027\u540e\u7684\u754c\u9762\u5bf9\u4e8e Li+<\/sup>\u00a0\u8868\u9762\u6269\u6563\u663e\u793a\u51fa\u9ad8\u7535\u5b50\u96a7\u9053\u52bf\u5792\u548c\u4f4e\u80fd\u91cf\u52bf\u5792\uff0c\u56e0\u6b64\u5b83\u80fd\u591f\u5728 1.4 mA cm-2<\/sup>\u00a0\u7684\u9ad8\u4e34\u754c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5b9e\u73b0\u6297\u679d\u6676\u9502\u7535\u9540\/\u5265\u79bb\u3002\u6b64\u5916\uff0c\u6539\u6027\u754c\u9762\u5bf9\u7a7a\u6c14\u66b4\u9732\u5177\u6709\u9ad8\u5316\u5b66\u548c\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u53ef\u9632\u6b62\u6c61\u67d3\u7269\u518d\u751f\u5e76\u4fdd\u6301\u00a01.1 mA cm-2 <\/sup>\u7684\u9ad8\u4e34\u754c\u7535\u6d41\u5bc6\u5ea6\u3002\u8fd9\u79cd\u65b0\u7684\u5316\u5b66\u65b9\u6cd5\u4e3a\u5b9e\u73b0\u9ad8\u80fd\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u79cd\u5b9e\u7528\u7684\u89e3\u51b3\u65b9\u6848\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.202003177<\/u><\/a><\/p>\n

2. Angew.\u00a0<\/strong>Chem. Int. Ed.\uff1a\u51c6\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u4e2d\u9502\u679d\u6676\u53ca\u5176\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u5c42\u7684\u754c\u9762\u6f14\u5316<\/b><\/strong><\/p>\n

\"\"<\/strong><\/b><\/strong><\/p>\n

\u4e0d\u7a33\u5b9a\u7684\u7535\u6781\/\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u548c\u5185\u90e8\u9502\u679d\u6676\u6e17\u900f\u963b\u788d\u4e86\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\uff08SSLMB\uff09\u7684\u5e94\u7528\uff0c\u5176\u6f5c\u5728\u673a\u5236\u5c1a\u4e0d\u6e05\u695a\u3002 \u4e2d\u79d1\u9662\u5316\u5b66\u6240\u7684\u4e07\u7acb\u9a8f\u9662\u58eb\u3001\u6587\u9510\u7814\u7a76\u5458\u7b49\u4eba<\/b><\/strong>\u5229\u7528\u539f\u4f4d\u5149\u5b66\u663e\u5fae\u955c\u63d0\u4f9b\u4e86\u5bf9\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28\u4e2d\u9502\u7535\u9540\/\u5265\u79bb\u8fc7\u7a0b\u7684\u6d1e\u5bdf\uff0c\u5e76\u63ed\u793a\u4e86\u5176\u52a8\u6001\u6f14\u53d8\u3002 \u968f\u7740\u7535\u6d41\u5bc6\u5ea6\u7684\u589e\u52a0\uff0c\u7403\u5f62\u9502\u91d1\u5c5e\u6f14\u53d8\u6210\u82d4\u85d3\u72b6\u548c\u6811\u679d\u72b6\u7684\u9502\u679d\u6676\u3002 \u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u9502\u679d\u6676\u4e0a\u539f\u4f4d\u5f62\u6210\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u4e2d\u95f4\u76f8\uff08SEI\uff09\u58f3\u5728\u9502\u5265\u79bb\u540e\u88ab\u660e\u663e\u6355\u83b7\u3002 \u8bf1\u5bfc\u539f\u4f4d\u5f62\u6210\u7684\u5177\u6709\u589e\u5f3a\u6a21\u91cf\u7684 SEI \u58f3\u4ee5\u81f4\u5bc6\u4e14\u5747\u5300\u5730\u5305\u88f9\u9502\u6c89\u6dc0\u53ef\u4ee5\u8c03\u8282\u65e0\u679d\u6676\u884c\u4e3a\u3002 \u6df1\u5165\u4e86\u89e3\u9502\u679d\u6676\u6f14\u5316\u53ca\u5176\u529f\u80fd SEI \u58f3\u5c06\u6709\u52a9\u4e8e\u4f18\u5316 SSLMB\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/ange.202001117<\/u><\/a><\/p>\n

3. J. Am. Chem. Soc.<\/b><\/strong>\uff1a\u5168\u56fa\u6001\u5408\u91d1\u91d1\u5c5e\u7535\u6c60\u7684\u5fae\u89c2\u673a\u5236\uff1a\u8c03\u8282\u5747\u8d28\u9502\u6c89\u6dc0\u548c\u67d4\u6027\u56fa\u4f53\u7535\u89e3\u8d28\u76f8\u95f4\u6f14\u5316<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u4e0e\u5408\u91d1\u8d1f\u6781\u76f8\u5339\u914d\u7684\u786b\u5316\u7269\u56fa\u6001\u7535\u89e3\u8d28\uff08SSE\uff09\u88ab\u8ba4\u4e3a\u662f\u5168\u56fa\u6001\u7535\u6c60\uff08ASSB\uff09\u5e94\u7528\u7684\u6709\u5e0c\u671b\u7684\u5019\u9009\u8005\uff0c\u4ee5\u514b\u670d\u9502\uff08Li\uff09\u8d1f\u6781\u7684\u74f6\u9888\u3002\u7136\u800c\uff0c\u5bf9 SSE \u4e2d\u5408\u91d1\u9633\u6781\u7684\u52a8\u6001\u7535\u5316\u5b66\u8fc7\u7a0b\u7684\u7406\u89e3\u4ecd\u7136\u96be\u4ee5\u6349\u6478\u3002\u4e3a\u6b64\uff0c\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u4e07\u7acb\u9a8f\u9662\u58eb\u3001\u6587\u9510\u7814\u7a76\u5458\u7b49\u4eba<\/b><\/strong>\u5229\u7528\u539f\u4f4d\u539f\u5b50\u529b\u663e\u5fae\u955c\u6df1\u5165\u4e86\u89e3\u9502\u7535\u6781\u4e0a\u9502\u6c89\u6dc0\u7684\u5757\u72b6\u5f62\u6210\u548c\u5806\u53e0\u79ef\u7d2f\u884c\u4e3a\uff0c\u63ed\u793a\u4e86\u7eb3\u7c73\u7ea7\u9502\u5728 ASSB \u4e2d\u6c89\u79ef\/\u6eb6\u89e3\u7684\u5f62\u6001\u6f14\u53d8\u3002\u6b64\u5916\uff0c\u4e8c\u7ef4\u9502\u94df (In) \u5408\u91d1\u8584\u7247\u548c In \u7535\u6781\u4e0a\u7684\u5747\u8d28\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762 (SEI) \u58f3\u63ed\u793a\u4e86\u5408\u91d1\u9633\u6781\u5728\u5fae\u89c2\u4e0a\u8c03\u8282\u7684\u6790\u51fa\u673a\u5236\u3002\u67d4\u6027\u548c\u76b1\u7eb9\u7ed3\u6784\u7684SEI\u58f3\u8fdb\u4e00\u6b65\u5728\u5faa\u73af\u4e2d\u5b9e\u73b0\u7535\u6781\u4fdd\u62a4\u548c\u5185\u90e8\u9502\u8c03\u8282\uff0c\u9610\u660e\u4e86SEI\u58f3\u5bf9\u5faa\u73af\u884c\u4e3a\u7684\u529f\u80fd\u5f71\u54cd\u3002\u8fd9\u79cd\u5bf9\u5f62\u6001\u6f14\u5316\u548c\u52a8\u529b\u5b66\u673a\u5236\u7684\u539f\u4f4d\u8ddf\u8e2a\u63d0\u4f9b\u4e86\u6df1\u5165\u7684\u7406\u89e3\uff0c\u4ece\u800c\u6709\u5229\u4e8e\u5408\u91d1\u57faASSB\u7684\u4f18\u5316\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a\u00a0https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.0c10121<\/u><\/a><\/p>\n

\u00a0\u4e09\u3001<\/b><\/strong>\u5357\u7b56\u6587\"\"<\/strong><\/b><\/strong><\/p>\n

1962\u5e74\u751f\uff0c\u6e56\u5317\u6d60\u6c34\u4eba\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\uff0c\u53d1\u5c55\u4e2d\u56fd\u5bb6\u79d1\u5b66\u9662\u9662\u58eb\uff0c\u6750\u6599\u79d1\u5b66\u4e13\u5bb6\uff0c\u6e05\u534e\u5927\u5b66\u6750\u6599\u5b66\u9662\u6559\u6388\u3002\u66fe\u4efb\u6e05\u534e\u5927\u5b66\u6750\u6599\u7cfb\u7cfb\u4e3b\u4efb\u3002\u73b0\u4efb\u6e05\u534e\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7814\u7a76\u9662\u9662\u957f\uff0c\u517c\u4efb\u56fd\u9645\u9676\u74f7\u8054\u76df(ICF)\u7406\u4e8b\u957f\u3001\u4e2d\u56fd\u7845\u9178\u76d0\u5b66\u4f1a\u526f\u7406\u4e8b\u957f\u7b49\uff0c\u66fe\u4efb\u4e9a\u6d32\u7535\u5b50\u9676\u74f7\u534f\u4f1a\u4e3b\u5e2d\u7b49\u3002\u4efb”\u529f\u80fd\u9676\u74f7”\u5b66\u79d1\u65b9\u5411\u56fd\u5bb6973\u8ba1\u5212\u9879\u76ee\u9996\u5e2d\u79d1\u5b66\u5bb6(\u81ea2002\u5e74-)\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u521b\u65b0\u7814\u7a76\u7fa4\u4f53\u5b66\u672f\u5e26\u5934\u4eba(2006-2015\u5e74)\u3002\u6784\u5efa\u4e86\u5904\u7406\u590d\u5408\u6750\u6599\u4e2d\u590d\u6742\u591a\u573a\u8026\u5408\u6548\u5e94\u7684\u6709\u6548\u4ecb\u8d28\u65b9\u6cd5\uff0c\u7ed9\u51fa\u4e86\u8ba1\u7b97\u5b8f\u89c2\u591a\u573a\u8026\u5408\u6027\u80fd\u7cfb\u6570\u7684\u89e3\u3002\u8bbe\u8ba1\u53d1\u5c55\u4e86\u94c1\u78c1\u5408\u91d1\u57fa\u78c1\u7535\u590d\u5408\u65b0\u4f53\u7cfb\uff0c\u63d0\u51fa\u4e86\u590d\u5408\u5de8\u78c1\u7535\u6548\u5e94\u3002\u7cfb\u7edf\u7814\u7a76\u4e86\u591a\u94c1\u6027\u78c1\u7535\u590d\u5408\u8584\u819c\uff0c\u63d0\u51fa\u4e86\u591a\u79cd\u65b0\u578b\u78c1\u7535\u5b58\u50a8\u5668\u53ca\u4f20\u611f\u5143\u4ef6\u3002\u5efa\u7acb\u4e86\u8ba1\u7b97\u975e\u5747\u8d28\u6750\u6599\u754c\u9762\u56e0\u7d20\u5bf9\u5b8f\u89c2\u7269\u7406\u8f93\u8fd0\u6027\u80fd\u5f71\u54cd\u7684\u6709\u6548\u4ecb\u8d28\u6a21\u578b\u65b9\u6cd5\uff1b\u5728\u754c\u9762\u6a21\u578b\u6307\u5bfc\u4e0b\uff0c\u53d1\u5c55\u4e86\u65b0\u578b\u9ad8\u4ecb\u7535\u6750\u6599\u3001\u5b89\u5168\u9502\u7535\u6c60\u7528\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u7b49\u3002\u53d1\u8868\u5b66\u672f\u8bba\u6587400\u4f59\u7bc7\uff0c\u88abSCI\u4ed6\u4eba\u5f15\u752810000\u591a\u6b21 (H\u56e0\u5b50=52)\uff1b\u51fa\u7248\u5b66\u672f\u4e13\u84571\u90e8\uff1b\u83b7\u6388\u6743\u56fd\u5bb6\u53d1\u660e\u4e13\u522930\u9879\u3002\u591a\u6b21\u4e3b\u6301\u53ec\u5f00\u56fd\u9645\u3001\u56fd\u5185\u5b66\u672f\u4f1a\u8bae\uff0c\u5728\u56fd\u9645\u4f1a\u8bae\u505a\u4e3b\u9898\u62a5\u544a\u3001\u9080\u8bf7\u62a5\u544a50\u6b21\u3002\u66fe\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u59561\u9879\u3001\u7701\u90e8\u7ea7\u59563\u9879\u3001\u56fd\u5916\u5956\u52b12\u9879\u7b49\u3002<\/p>\n

<\/b>\u8fd1\u671f\u4ee3\u8868\u6027\u6210\u679c<\/b><\/strong><\/p>\n

1. Nat. Rev. Mater.\uff1a<\/b><\/strong>\u4e3a\u56fa\u6001\u7535\u6c60\u7684\u5927\u89c4\u6a21\u751f\u4ea7\u91cf\u8eab\u5b9a\u5236\u65e0\u673a\u805a\u5408\u7269\u590d\u5408\u6750\u6599<\/b><\/strong><\/p>\n

\"\"<\/strong><\/b><\/strong><\/p>\n

\u56fa\u6001\u7535\u6c60\u00a0(SSB) \u6700\u8fd1\u5df2\u88ab\u590d\u5174\uff0c\u4ee5\u589e\u52a0\u80fd\u91cf\u5bc6\u5ea6\u5e76\u6d88\u9664\u4e0e\u5177\u6709\u6613\u71c3\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u5173\u7684\u5b89\u5168\u95ee\u9898\u3002\u4e3a\u4e86\u5c3d\u5feb\u5b9e\u73b0SSBs\u7684\u5927\u89c4\u6a21\u4f4e\u6210\u672c\u751f\u4ea7\uff0c\u6709\u5229\u4e8e\u6539\u9020\u6210\u719f\u7684\u5236\u9020\u5e73\u53f0\uff0c\u5305\u62ec\u6d46\u6599\u6d47\u94f8\u548c\u5377\u5bf9\u5377\u6280\u672f\uff0c\u7528\u4e8e\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\u5e94\u7528\u4e8eSSBs\u3002\u7136\u800c\uff0cSSB \u7684\u5236\u9020\u53d6\u51b3\u4e8e\u5408\u9002\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u5f00\u53d1\u3002\u65e0\u673a-\u805a\u5408\u7269\u590d\u5408\u7535\u89e3\u8d28\u7ed3\u5408\u4e86\u65e0\u673a\u56fa\u4f53\u7535\u89e3\u8d28\u548c\u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u4f18\u70b9\uff0c\u7279\u522b\u9002\u7528\u4e8eSSBs\u7684\u5927\u89c4\u6a21\u751f\u4ea7\u3002\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u6e05\u534e\u5927\u5b66\u7684\u5357\u7b56\u6587\u9662\u58eb\u7b49\u4eba<\/b><\/strong>\u8ba8\u8bba\u4e86\u5305\u542b\u65e0\u673a-\u805a\u5408\u7269\u590d\u5408\u6750\u6599\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u7279\u6027\uff0c\u5e76\u6982\u8ff0\u4e86\u7528\u4e8e\u5b9e\u73b0\u9ad8\u6027\u80fd\u5668\u4ef6\u7684\u590d\u5408\u7535\u89e3\u8d28\u7684\u8bbe\u8ba1\u3002\u4ed6\u4eec\u8fd8\u8bc4\u4f30\u4e86\u5c06\u590d\u5408\u7535\u89e3\u8d28\u96c6\u6210\u5230\u7535\u6c60\u4e2d\u7684\u6311\u6218\uff0c\u8fd9\u5c06\u4f7f\u00a0SSB \u7684\u5927\u89c4\u6a21\u751f\u4ea7\u6210\u4e3a\u53ef\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/www.nature.com\/articles\/s41578-021-00320-0<\/u><\/a><\/p>\n

2. Adv. Energy Mater.<\/b><\/strong>\uff1a\u5168\u56fa\u6001\u9502\u7535\u6c60\u7528\u8d85\u8584\u67d4\u6027\u4e0d\u71c3\u77f3\u69b4\u77f3\u57fa\u590d\u5408\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u65e0\u6eb6\u5242\u5408\u6210<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u4e0b\u4e00\u4ee3\u5b89\u5168\u3001\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u9502\u91d1\u5c5e\u7535\u6c60\u8feb\u5207\u9700\u8981\u5177\u6709\u4e0d\u53ef\u71c3\u6027\u3001\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u3001\u4f4e\u754c\u9762\u7535\u963b\u548c\u826f\u597d\u52a0\u5de5\u6027\u7684\u8584\u56fa\u6001\u7535\u89e3\u8d28\u3002\u5317\u4eac\u79d1\u6280\u5927\u5b66\u7684\u8303\u4e3d\u73cd\u3001\u6e05\u534e\u5927\u5b66\u7684\u5357\u7b56\u6587\u9662\u58eb\u7b49\u4eba<\/b><\/strong>\u901a\u8fc7\u4e0d\u4f7f\u7528\u4efb\u4f55\u6eb6\u5242\u7684\u7b80\u5355\u7814\u78e8\u65b9\u6cd5\u5236\u5907\u4e86\u7531\u805a\u56db\u6c1f\u4e59\u70ef\u00a0(PTFE) \u7c98\u5408\u5242\u4e92\u8fde\u7684 3D Li6.75<\/sub>La3<\/sub>Zr1.75<\/sub>Ta0.25<\/sub>O12<\/sub>\u00a0(LLZTO) \u81ea\u652f\u6491\u9aa8\u67b6\u3002\u968f\u540e\uff0c\u901a\u8fc7\u7528\u4e01\u4e8c\u8148\u56fa\u4f53\u7535\u89e3\u8d28\u586b\u5145\u67d4\u6027 3D LLZTO \u6846\u67b6\uff0c\u5b9e\u73b0\u4e86\u77f3\u69b4\u77f3\u57fa\u590d\u5408\u7535\u89e3\u8d28\u3002\u7531\u4e8e\u77f3\u69b4\u77f3\u9676\u74f7\u7684\u9ad8\u542b\u91cf (80.4 wt%) \u548c PTFE \u7c98\u5408\u5242\u7684\u9ad8\u8010\u70ed\u6027\uff0c\u8fd9\u79cd\u5177\u6709\u4e0d\u53ef\u71c3\u6027\u548c\u9ad8\u52a0\u5de5\u6027\u7684\u590d\u5408\u7535\u89e3\u8d28\u819c\u8868\u73b0\u51fa 4.8 V \u5bf9 Li\/Li+<\/sup>\u00a0\u7684\u5bbd\u7535\u5316\u5b66\u7a97\u53e3\u548c\u9ad8\u79bb\u5b50\u8f6c\u79fb\u65700.53\u3002\u4e92\u8fde\u7684 LLZTO \u9897\u7c92\u548c\u4e01\u4e8c\u8148\u4e4b\u95f4\u7684\u8fde\u7eed Li+<\/sup>\u00a0\u4f20\u8f93\u901a\u9053\u4ee5\u53ca\u67d4\u8f6f\u7535\u89e3\u8d28\/\u7535\u6781\u754c\u9762\u5171\u540c\u4fc3\u6210\u4e86 1.2 \u00d7 10\u22124<\/sup>\u00a0S cm\u22121<\/sup>\u00a0\u7684\u9ad8\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u9502\u5bf9\u79f0\u7535\u6c60\u4f18\u5f02\u7684\u957f\u671f\u7a33\u5b9a\u6027\uff08\u5728 0.1 mA cm-2<\/sup>\u00a0\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7a33\u5b9a\u8d85\u8fc7 500 \u5c0f\u65f6\uff09\u3002\u6b64\u5916\uff0c\u57fa\u4e8e\u8584\u590d\u5408\u7535\u89e3\u8d28\u5236\u5907\u7684 LiFePO4<\/sub>|Li \u548c LiNi0.5<\/sub>Mn0.3<\/sub>Co0.2<\/sub>O2<\/sub>|Li \u7535\u6c60\u5206\u522b\u5177\u6709 153 mAh g-1<\/sup>\u00a0\u548c 158 mAh g-1<\/sup>\u00a0\u7684\u9ad8\u653e\u7535\u6bd4\u5bb9\u91cf\u4ee5\u53ca\u7406\u60f3\u7684\u5ba4\u6e29\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/aenm.201903376<\/u><\/a><\/p>\n

3. Energy Storage Mater. \uff1a\u8010\u6c27\u548c\u6291\u5236\u9502\u679d\u6676\u7684\u8d85\u5e72\u805a\u5408\u7269\u7535\u89e3\u8d28\u7528\u4e8e\u56fa\u6001Li-O<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u6c60<\/b><\/strong><\/p>\n

\"\"<\/strong><\/b><\/strong><\/p>\n

\u5728\u00a0Li-O2<\/sub>\u00a0\u7535\u6c60\u4e2d\u4f7f\u7528\u805a\u5408\u7269\u7535\u89e3\u8d28\u53ef\u4ee5\u6709\u6548\u89e3\u51b3\u6613\u71c3\u6db2\u4f53\u7535\u89e3\u8d28\u5f15\u8d77\u7684\u5b89\u5168\u95ee\u9898\u3002\u7136\u800c\uff0c\u805a\u5408\u7269\u57fa\u8d28\u548c\u989d\u5916\u7684\u6db2\u4f53\u7535\u89e3\u8d28\u5bf9 Li-O2<\/sub>\u00a0\u7535\u6c60\u5faa\u73af\u6027\u80fd\u7684\u5f71\u54cd\u4ecd\u4e0d\u6e05\u695a\u3002\u6e05\u534e\u5927\u5b66<\/b><\/strong>\u5357\u7b56\u6587<\/b><\/strong>\u9662\u58eb\u3001\u674e\u4eae\u4eae\u526f\u7814\u7a76\u5458\u7b49\u4eba<\/b><\/strong>\u901a\u8fc7\u7b80\u5355\u7684\u6d41\u5ef6\u548c\u771f\u7a7a\u5e72\u71e5\u65b9\u6cd5\u5408\u6210\u4e86\u65e0\u9700\u989d\u5916\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u81ea\u7acb\u5f0f\u9502\u79bb\u5b50\u5bfc\u7535\u8d85\u5e72\u805a\u5408\u7269\u7535\u89e3\u8d28\uff08UDPE\uff09\u3002\u57fa\u4e8e UDPE \u7684\u5bf9\u79f0 Li-Li \u7535\u6c60\u5728 O2<\/sub>\u00a0\u6c14\u6c1b\u4e2d\u7684\u957f\u671f\u5faa\u73af\u6027\u80fd\uff08\u8d85\u8fc7 800 \u5c0f\u65f6\uff09\u8868\u660e\uff0cUDPE \u663e\u7740\u62b5\u6297 O2<\/sub>\u00a0\u548c\u9502\u679d\u6676\u6e17\u900f\u3002\u6b64\u5916\uff0c\u53ef\u4ee5\u51cf\u8f7b\u7531\u6db2\u4f53\u7535\u89e3\u8d28\u964d\u89e3\u5f15\u8d77\u7684\u526f\u53cd\u5e94\uff0c\u5e76\u5728 UDPE \u548c\u9502\u91d1\u5c5e\u4e4b\u95f4\u5f62\u6210\u7a33\u5b9a\u7684\u542b LiF \u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\u3002\u540c\u65f6\uff0c\u57fa\u4e8eUDPE\u7684\u65e0\u50ac\u5316\u5242Li-O2<\/sub>\u7535\u6c60\u57280.4 mA cm-2<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u5bff\u547d\u4e0e\u57fa\u4e8e\u6db2\u4f53\u7535\u89e3\u8d28\u7684Li-O2<\/sub>\u7535\u6c60\u76f8\u6bd4\u63d0\u9ad8\u4e86\u4e24\u500d\u4ee5\u4e0a\u3002UDPEs\u66ff\u4ee3\u6db2\u4f53\u7535\u89e3\u8d28\u5e76\u6ca1\u6709\u6539\u53d8\u56fa\u6001Li-O2<\/sub>\u7535\u6c60\u7684\u57fa\u672c\u53cd\u5e94\uff0c\u8fd9\u4ecd\u7136\u662f\u5178\u578b\u7684Li2<\/sub>O2<\/sub>\u6676\u4f53\u7684\u5f62\u6210\u548c\u5206\u89e3\u3002 UDPE \u51fa\u8272\u7684\u7efc\u5408\u6027\u80fd\u53ef\u80fd\u4f1a\u5f15\u53d1\u5bf9 Li-O2<\/sub>\u00a0\u7535\u6c60\u751a\u81f3\u5176\u4ed6\u78b1\u91d1\u5c5e\u57fa O2<\/sub>\uff08\u7a7a\u6c14\uff09\u7535\u6c60\u4e2d\u591a\u529f\u80fd\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u8fdb\u4e00\u6b65\u7814\u7a76\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/www.sciencedirect.com\/science\/article\/pii\/S2405829720300404<\/u><\/a><\/p>\n

\u672c\u6587\u7531\u5de5\u5b66\u8005\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u56fa\u6001\u7535\u6c60\u91c7\u7528\u56fa\u6001\u7535\u89e3\u8d28\u66ff\u4ee3\u4f20\u7edf\u6709\u673a\u6db2\u6001\u7535\u89e3\u6db2\uff0c\u6709\u671b\u4ece\u6839\u672c\u4e3b\u89e3\u51b3\u7535\u6c60\u5b89\u5168\u6027\u95ee\u9898\uff0c\u63d0\u9ad8\u7535\u6c60\u80fd\u91cf\u5bc6\u5ea6\uff0c\u662f\u7535\u52a8\u6c7d\u8f66\u548c\u89c4\u6a21\u5316\u50a8\u80fd\u7406\u60f3\u7684\u5316\u5b66\u7535\u6e90\u3002\u8fd1\u5e74\u6765\uff0c\u56fa\u6001\u7535\u6c60\u53d7\u5230\u5b66\u672f\u754c…<\/p>\n","protected":false},"author":11454,"featured_media":224444,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-224431","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/224431"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=224431"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/224431\/revisions"}],"predecessor-version":[{"id":224446,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/224431\/revisions\/224446"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/224444"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=224431"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=224431"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=224431"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}