{"id":224570,"date":"2021-07-15T06:31:02","date_gmt":"2021-07-14T22:31:02","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=224570"},"modified":"2021-07-14T20:31:21","modified_gmt":"2021-07-14T12:31:21","slug":"%e5%8a%a9%e5%8a%9b%e7%a2%b3%e8%be%be%e5%b3%b0%e7%a2%b3%e4%b8%ad%e5%92%8c-%e8%b0%a2%e6%af%85%e3%80%81%e9%99%88%e5%86%9b%e3%80%81%e9%82%93%e5%be%b7%e4%bc%9a%e3%80%81%e9%99%86%e5%a5%87%e3%80%81%e9%83%91","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=224570","title":{"rendered":"\u52a9\u529b\u78b3\u8fbe\u5cf0\u78b3\u4e2d\u548c \u8c22\u6bc5\u3001\u9648\u519b\u3001\u9093\u5fb7\u4f1a\u3001\u9646\u5947\u3001\u90d1\u803f\u5cf0\u3001\u5f20\u94c1\u9510\u3001\u6c6a\u9a8b\u7b49\u4eba\u8fd1\u671f\u5de5\u4f5c\u6c47\u603b"},"content":{"rendered":"

1<\/b><\/strong>.<\/b><\/strong>Advanced<\/b><\/strong>\u00a0<\/b><\/strong>Energy<\/b><\/strong>\u00a0<\/b><\/strong>Materials<\/b><\/strong>\uff1a<\/b><\/strong>Fe<\/b><\/strong>\u57fa\u50ac\u5316\u5242<\/b><\/strong>\u7684<\/b><\/strong>\u5149\u8fd8\u539f<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u5230\u9ad8\u78b3\u70c3<\/b><\/strong>\u7684\u6027\u80fd\u63a2\u7a76<\/b><\/strong><\/p>\n

CO2<\/sub>\u52a0\u6c22\u662f\u4e00\u79cd\u65b0\u578b\u7684\u80fd\u6e90\u5229\u7528\u8def\u5f84\uff0c\u5206\u4e3a\u76f4\u63a5\u8f6c\u5316\u6cd5\u548c\u95f4\u63a5\u8f6c\u5316\u6cd5\u3002\u95f4\u63a5\u8f6c\u5316\u6cd5\u7684\u8def\u5f84\u7e41\u591a\uff0c\u5bfc\u81f4\u6709\u5f88\u591a\u7684\u526f\u4ea7\u7269\u4ea7\u751f\uff0c\u9009\u62e9\u6027\u8f83\u4f4e\u3002Fe\u57fa\u50ac\u5316\u5242\u4f5c\u4e3a\u4e00\u79cd\u5ec9\u4ef7\u7684\u4f20\u7edf\u7684CO2<\/sub>\u52a0\u6c22\u50ac\u5316\u5242\uff0c\u5728\u76f4\u63a5\u8f6c\u5316CO2<\/sub>\u7684\u8def\u5f84\u4e2d\u5c55\u793a\u51fa\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u4f46\u662f\u5982\u4f55\u5229\u7528\u5355\u4e00\u7684\u5ec9\u4ef7\u91d1\u5c5eFe\u5728\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\u5b9e\u73b0CO2<\/sub>\u7684\u9ad8\u6548\u8f6c\u5316\u4ecd\u5177\u6311\u6218\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u7406\u5316\u6280\u672f\u7814\u7a76\u6240\u7814\u7a76\u5458\u5f20\u94c1\u9510\u56e2\u961f\u5229\u7528Fe\u57fa\u6c34\u6ed1\u77f3\u4e3a\u524d\u9a71\u4f53\uff0c\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0bH2<\/sub>\u6c1b\u56f4\u4e2d\u8fd8\u539f\uff0c\u5229\u7528\u6c34\u6ed1\u77f3\u7684\u62d3\u6251\u8f6c\u53d8\u5f97\u5230\u4e00\u7cfb\u5217\u4e0d\u540c\u7269\u76f8\u7684Fe\u57fa\u50ac\u5316\u5242\uff0c\u5728\u5149\u7167\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e86CO2<\/sub>\u5230\u9ad8\u9644\u52a0\u503c\u5316\u5b66\u54c1\u7684\u9ad8\u6548\u8f6c\u5316\u3002<\/p>\n

\u7814\u7a76\u901a\u8fc7\u4e00\u7cfb\u5217\u7684\u7ed3\u6784\u8868\u5f81X\u5c04\u7ebf\u884d\u5c04\u3001\u540c\u6b65\u8f90\u5c04\u7b49\u8bc1\u660e\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u5408\u6210\u4e86\u4e0d\u540c\u7684\u4ea7\u7269\uff0c\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\u5f62\u6210\u7684\u662fFeOx<\/sub>\u8d1f\u8f7d\u578b\u7eb3\u7c73\u50ac\u5316\u5242\uff0c\u5728\u4e2d\u6e29\u6761\u4ef6\u4e0b\u8fd8\u539f\u5f62\u6210\u7684\u662fFeOx<\/sub>\u4fee\u9970\u7684\u5355\u8d28Fe\u754c\u9762\u7ed3\u6784\u578b\u50ac\u5316\u5242\uff0c\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u8fd8\u539f\u5f62\u6210\u7684\u662f\u5355\u8d28Fe\u8d1f\u8f7d\u578b\u7eb3\u7c73\u50ac\u5316\u5242\u3002\u5e76\u4e14\u8003\u5bdf\u4e86\u4e0d\u540c\u7269\u76f8\u7684Fe\u57fa\u578b\u50ac\u5316\u5242\u5728\u5149\u7167\u6761\u4ef6\u4e0b\u5bf9\u5e94\u7684CO2<\/sub>\u52a0\u6c22\u6027\u80fd\uff0c\u53d1\u73b0\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\u8fd8\u539f\u5f97\u5230\u7684FeOx<\/sub>\u578b\u50ac\u5316\u5242\u5bf9\u5e94\u7684\u4ea7\u7269\u4e3aCO\uff1b\u5728\u4e2d\u6e29\uff08500\u2103\uff09\u6761\u4ef6\u4e0b\u5f97\u5230\u7684FeOx<\/sub>\/Fe\u578b\u50ac\u5316\u5242\u5bf9\u5e94\u7684\u4ea7\u7269\u4e3aC2+<\/sup>\uff0c\u9009\u62e9\u6027\u53ef\u8fbe52.9%\uff1b\u800c\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u5f97\u5230\u7684\u5355\u8d28Fe\u57fa\u578b\u50ac\u5316\u5242\u5bf9\u5e94\u7684\u4ea7\u7269\u662fCH4<\/sub>\u3002\u7814\u7a76\u8fdb\u4e00\u6b65\u901a\u8fc7DFT\u9a8c\u8bc1\u4e86\u8fd9\u79cdFeOx<\/sub>\/Fe\u754c\u9762\u7ed3\u6784\u53ef\u6291\u5236\u4e2d\u95f4\u4f53-CH2<\/sub>\u548c-CH3<\/sub>\u7684\u52a0\u6c22\uff0c\u540c\u65f6\u53ef\u4ee5\u4fc3\u8fdbC-C\u8026\u8054\u53cd\u5e94\u4ece\u800c\u751f\u6210\u9ad8\u9009\u62e9\u6027\u7684C2<\/sub>+<\/sub>\u3002\u8be5\u7814\u7a76\u6253\u7834\u4e86\u4eba\u4eec\u5bf9Fe\u57fa\u50ac\u5316\u5242\u53ea\u6709\u5728\u52a9\u5242\u5b58\u5728\u7684\u65f6\u5019\u624d\u80fd\u5b9e\u73b0CO2<\/sub>\u5230\u9ad8\u9644\u52a0\u503c\u5316\u5b66\u54c1\u8f6c\u5316\u7684\u4f20\u7edf\u8ba4\u8bc6\uff0c\u4e3a\u5149\u9a71\u52a8CO2<\/sub>\u8f6c\u5316\u63d0\u4f9b\u4e86\u9ad8\u6548\u7684\u3001\u5168\u65b0\u7684\u3001\u53ef\u6301\u7eed\u7684\u80fd\u6e90\u8f6c\u5316\u8def\u5f84\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5Fe<\/i><\/b><\/em><\/strong>\u2010<\/i><\/b><\/em><\/strong>Based<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Catalysts<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>for<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>the<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Direct<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Photohydrogenation<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>of<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0<\/i><\/b><\/em><\/strong>to<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Value<\/i><\/b><\/em><\/strong>\u2010<\/i><\/b><\/em><\/strong>Added<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Hydrocarbons<\/i><\/b><\/em><\/strong>\u4e3a\u9898\uff0c\u53d1\u8868\u5728Advanced<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Energy<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Materials<\/i><\/b><\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

Figure\u00a01\u00a0\u94c1\u57fa\u50ac\u5316\u5242\u7684\u6676\u4f53\u7ed3\u6784\u53ca\u7535\u5b50\u6001\u7ed3\u6784\u8868\u5f81\u3002<\/p>\n

2<\/b><\/strong>.<\/b><\/strong>Journal of the American Chemical Society<\/b><\/strong>\uff1a<\/b><\/strong>\u673a\u5668\u5b66\u4e60\u6307\u5bfc<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u8fd8\u539f\u7684<\/b><\/strong>Cu<\/b><\/strong>\u57fa\u50ac\u5316\u5242\u5236\u5907<\/b><\/strong><\/p>\n

\u7535\u5316\u5b66CO2<\/sub>\u8fd8\u539f\u8f6c\u5316\u6210\u5316\u5b66\u54c1\u88ab\u8ba4\u4e3a\u662f\u78b3\u8d44\u6e90\u5faa\u73af\u5229\u7528\u7684\u91cd\u8981\u65b9\u5411\u3002\u94dc\u57fa\u50ac\u5316\u5242\u53ef\u4ee5\u5c06CO2<\/sub>\u7535\u5316\u5b66\u8fd8\u539f\u5f97\u5230\u4e00\u7cfb\u5217\u4ea7\u7269\uff0c\u5305\u62ecC1<\/sub>\uff08CO\uff0cHCOOH\uff0cCH4<\/sub>\uff0cCH3<\/sub>OH\uff09\u548cC2<\/sub>+<\/sub>\uff08C2<\/sub>H4<\/sub>\uff0cC2<\/sub>H6<\/sub>\uff0cC2<\/sub>H5<\/sub>OH\uff0cC3<\/sub>H7<\/sub>OH\uff09\u3002\u53a6\u95e8\u5927\u5b66\u6c6a\u9a8b\u6559\u6388\u548c\u5468\u8fbe\u526f\u6559\u6388\u901a\u8fc7\u673a\u5668\u5b66\u4e60\u8fdb\u884c\u6709\u6548\u7684\u6570\u636e\u5206\u6790\uff0c\u53d1\u73b0\u548c\u4f18\u5316\u4e86\u6f5c\u5728\u7684\u65b0\u578b\u50ac\u5316\u5242\u3002\u8be5\u7814\u7a76\u901a\u8fc7\u4e09\u4e2a\u8fed\u4ee3\u5468\u671f\u63a2\u7d22\u4e86CO2<\/sub>\u7535\u8fd8\u539fCu\u50ac\u5316\u5242\uff08\u7535\u5316\u5b66\u6c89\u79ef\u5236\u5907\uff09\u7684\u6dfb\u52a0\u5242\u5bf9\u4e8e\u4ea7\u7269\u7684\u5f71\u54cd\uff0c\u5305\u62ec\u5b9e\u9a8c\u6d4b\u8bd5\uff0c\u673a\u5668\u5b66\u4e60\u5206\u6790\uff0c\u9884\u6d4b\u548c\u91cd\u65b0\u8bbe\u8ba1\uff0c\u83b7\u5f97\u4e86\u5bf9CO\u3001HCOOH\u548cC2<\/sub>+<\/sub>\u4ea7\u7269\u5177\u6709\u9ad8\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\u3002\u7814\u7a76\u53d1\u73b0\u542b\u6709\u8102\u80aa\u65cf\u7f9f\u57fa\u7684\u5206\u5b50\u6dfb\u52a0\u5242\u53ef\u4ee5\u901a\u8fc7\u63a7\u5236\u50ac\u5316\u5242\u524d\u9a71\u4f53Cu2<\/sub>O\u7acb\u65b9\u4f53\u7684\u5f62\u6210\u6765\u63d0\u9ad8C2<\/sub>+<\/sub>\u4ea7\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u3002\u8fd9\u4e00\u5de5\u4f5c\u51f8\u663e\u4e86\u673a\u5668\u5b66\u4e60\u901a\u8fc7\u4ece\u6709\u9650\u6570\u91cf\u7684\u5b9e\u9a8c\u6570\u636e\u4e2d\u6709\u6548\u63d0\u53d6\u4fe1\u606f\u6765\u52a0\u901f\u6750\u6599\u5f00\u53d1\u7684\u6f5c\u529b\u3002\u8fd9\u7bc7\u5de5\u4f5c\u4e2d\u7814\u7a76\u4e86\u7ea6300\u4e2a\u4e0d\u540c\u50ac\u5316\u5242\uff0c\u901a\u8fc7\u673a\u5668\u5b66\u4e60\u7684\u65b0\u6280\u672f\u65b0\u65b9\u6cd5\u5bf9\u6570\u636e\u8fdb\u884c\u9ad8\u6548\u5206\u6790\uff0c\u590d\u73b0\u4e86\u8fd1\u4e9b\u5e74\u7684\u5f88\u591a\u91cd\u70b9\u7ed3\u8bba\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5Machine<\/i><\/b><\/em><\/strong>–<\/i><\/b><\/em><\/strong>Learning<\/i><\/b><\/em><\/strong>–<\/i><\/b><\/em><\/strong>Guided<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Discovery<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>and<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Optimization<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>of<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Additives<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>in<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Preparing<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Cu<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Catalysts<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>for<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>CO<\/i><\/b><\/em><\/strong>2<\/i><\/b><\/sub><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Reduction<\/i><\/b><\/em><\/strong>\u4e3a\u9898\uff0c\u53d1\u8868\u5728Journal<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>of<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>American<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Chemistry<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Society<\/i><\/b><\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

Figure\u00a02\u00a0Cu\u7535\u50ac\u5316\u5242\u7684\u673a\u5668\u5b66\u4e60\u6a21\u5f0f\u53ca\u63a2\u7a76\u65b9\u6cd5\u3002<\/p>\n

3<\/b><\/strong>.<\/b><\/strong>ACS<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Catalysis<\/i><\/b><\/em><\/strong>\uff1a<\/i><\/b><\/em><\/strong>\u805a\u5408\u7269\u7684\u8868\u9762\u4eb2\u758f\u6c34\u6548\u5e94\u5728\u94dc\u8868\u9762\u7684\u50ac\u5316\u5236\u4e59\u70ef\u6027\u80fd\u5f71\u54cd\u7684\u63a2\u7a76<\/b><\/strong><\/p>\n

\u5c71\u4e1c\u5927\u5b66\u80e1\u65b0\u660e\u6559\u6388\u53ca\u5408\u4f5c\u8005\u5728\u6b64\u5de5\u4f5c\u4e2d\uff0c\u901a\u8fc7\u5728\u7535\u50ac\u5316\u5242\u8868\u9762\u6d82\u8986\u4e0d\u540c\u805a\u5408\u7269\uff0c\u7cfb\u7edf\u7814\u7a76\u4e86\u7535\u50ac\u5316\u5242\u8868\u9762\u4eb2\u758f\u6c34\u6027\u5bf9CO2<\/sub>RR\u4ea7\u4e59\u70ef\u7684\u5f71\u54cd\u3002\u7814\u7a76\u8868\u660e\uff0c\u758f\u6c34\u805a\u5408\u7269\uff08\u805a\u504f\u6c1f\u4e59\u70ef\u548c\u805a\u4e59\u70ef\uff09\u4fee\u9970\u7eb3\u7c73\u94dc\u8868\u9762\u53ef\u4ee5\u6291\u5236\u6790\u6c22\u526f\u53cd\u5e94\uff0c\u5e76\u663e\u8457\u63d0\u9ad8\u7eb3\u7c73\u94dc\u50ac\u5316CO2<\/sub>RR\u4ea7\u4e59\u70ef\u7684\u9009\u62e9\u6027\u3001\u6d3b\u6027\u4ee5\u53ca\u7a33\u5b9a\u6027\uff0c\u800c\u4eb2\u6c34\u805a\u5408\u7269\uff08\u805a\u4e59\u70ef\u9187\u548c\u805a\u4e59\u70ef\u5421\u54af\u70f7\u916e\uff09\u4fee\u9970\u7684\u7eb3\u7c73\u94dc\u7535\u6781\u5219\u66f4\u6709\u5229\u4e8e\u6790\u6c22\u53cd\u5e94\u3002\u4ee5PVDF\u4e3a\u4f8b\uff0c\u5728-1.12\u00a0V\u00a0vs<\/i><\/em>\u00a0<\/i><\/em>RHE\u7684\u7535\u52bf\u4e0b\uff0c\u758f\u6c34\u6539\u6027\u7684\u7eb3\u7c73\u94dc\u4e0e\u672a\u6539\u6027\u7684\u7eb3\u7c73\u94dc\u76f8\u6bd4\uff0c\u4e59\u70ef\u9009\u62e9\u6027\u63d0\u9ad8\u81f3\u539f\u6765\u7684\u4e24\u500d\uff0816.7%\u523032.0%\uff09\uff0c\u4e59\u70ef\u5206\u7535\u6d41\u5bc6\u5ea6\u4ece1.4\u00a0mA\u00a0cm–<\/sup>2<\/sup>\u63d0\u9ad8\u81f33.8\u00a0mA\u00a0cm-2<\/sup>\uff0c\u5e76\u4e14\u57286\u5c0f\u65f6\u7684\u7535\u89e3\u8fc7\u7a0b\u4e2d\uff0c\u4e59\u70ef\u7684\u9009\u62e9\u6027\u548c\u5206\u7535\u6d41\u5bc6\u5ea6\u7684\u7a33\u5b9a\u6027\u5747\u5f97\u5230\u4e86\u663e\u8457\u6539\u5584\u3002\u8fdb\u4e00\u6b65\u7814\u7a76\u53cd\u5e94\u673a\u7406\u53d1\u73b0\uff0cPVDF\u758f\u6c34\u6539\u6027\u5e76\u4e0d\u4f1a\u5f71\u54cd\u53cd\u5e94\u524d\u540e\u7eb3\u7c73\u94dc\u7684\u5f62\u8c8c\u3001\u6676\u578b\u4e0e\u6c27\u5316\u6001\uff0c\u56e0\u800c\u6392\u9664\u4e86\u8fd9\u4e9b\u56e0\u7d20\u5bf9\u50ac\u5316\u6027\u80fd\u7684\u5f71\u54cd\u3002\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u7ed3\u679c\u663e\u793a\uff0c\u5728PVDF\u7684\u5b58\u5728\u4e0b\uff0c\u6c34\u7684\u6269\u6563\u7cfb\u6570\u7531\u539f\u6765\u76842.35\u00d710–<\/sup>9<\/sup>\u00a0m2<\/sup>\u00a0s–<\/sup>1<\/sup>\u964d\u4f4e\u52301.81\u00a0\u00d710–<\/sup>9<\/sup>\u00a0m2<\/sup>\u00a0s–<\/sup>1<\/sup>\u3002\u540c\u65f6\uff0c\u901a\u8fc7\u8ba1\u7b97\u7535\u6781\u8868\u9762\u6269\u6563\u5c42\u7684OH–<\/sup>\u6d53\u5ea6\u53d1\u73b0\uff0c\u7531\u4e8ePVDF\u5bf9\u6c34\u5206\u5b50\u6269\u6563\u7684\u6291\u5236\uff0c\u5bfc\u81f4\u7535\u6781\u8868\u9762\u7684OH–<\/sup>\u6d53\u5ea6\u589e\u52a0\uff0cpH\u4ece9.2\u63d0\u9ad8\u52309.4\u3002\u8f83\u9ad8\u7684\u8868\u9762pH\u6709\u5229\u4e8e\u78b3\u78b3\u5076\u8054\u7684\u8fdb\u884c\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e59\u70ef\u7684\u751f\u6210\u3002\u5728\u8fdb\u4e00\u6b65\u5b9e\u9a8c\u4e2d\uff0c\u4fdd\u6301\u7eb3\u7c73\u94dc\u7535\u6781\u4e0d\u53d8\uff0c\u5c06\u7535\u89e3\u6db2\u4e2d\u7684\u6c34\u6362\u6210\u6c18\u4ee3\u6c34\uff08\u81ea\u6269\u6563\u7cfb\u6570\u4e3a1.87\u00a0\u00d710–<\/sup>9<\/sup>\u00a0m2<\/sup>\u00a0s–<\/sup>1<\/sup>\uff09\u4e4b\u540e\uff0c\u53ef\u4ee5\u5f97\u5230\u4e0e\u758f\u6c34\u4fee\u9970\u7535\u6781\u76f8\u4f3c\u7684\u50ac\u5316\u6027\u80fd\uff0c\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u4e86\u758f\u6c34\u754c\u9762\u5bf9\u6c34\u5206\u5b50\u6269\u6563\u7684\u6291\u5236\u4f5c\u7528\u662f\u50ac\u5316\u6027\u80fd\u6539\u5584\u7684\u51b3\u5b9a\u6027\u56e0\u7d20\uff1a\u4e00\u65b9\u9762\uff0c\u758f\u6c34\u754c\u9762\u7684\u5f15\u5165\u4f1a\u9650\u5236\u6c34\u5411\u7535\u6781\u8868\u9762\u7684\u6269\u6563\uff0c\u8fdb\u800c\u6291\u5236\u4ea7\u6c22\u526f\u53cd\u5e94\u7684\u53d1\u751f\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u8868\u9762pH\u503c\u7684\u63d0\u9ad8\u53c8\u4fc3\u8fdb\u4e86\u4e59\u70ef\u7684\u751f\u6210\uff0c\u4ece\u800c\u63d0\u9ad8CO2<\/sub>RR\u7684\u6027\u80fd\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5Hydrophobic<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Copper<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Interfaces<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Boost<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Electroreduction<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>of<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Carbon<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Dioxide<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>to<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Ethylene<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>in<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Water<\/i><\/b><\/em><\/strong>\u4e3a\u9898\uff0c\u53d1\u8868\u5728ACS<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Catalysis<\/i><\/b><\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

Figure\u00a03\u00a0PVDF\u4fee\u9970\u7684Cu\u6837\u54c1\u7684\u5f62\u8c8c\u548c\u7535\u5b50\u6001\u7ed3\u6784\u8868\u5f81\u3002<\/p>\n

4<\/b><\/strong>.<\/b><\/strong>Nature<\/b><\/strong>\u00a0<\/b><\/strong>communications<\/b><\/strong>\uff1a<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u8fd8\u539f\u5236<\/b><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>\u53ca<\/b><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>H<\/b><\/strong>4<\/b><\/sub><\/strong>\u7684\u8868\u9762\u53cd\u5e94\u673a\u7406\u63a2\u7a76<\/b><\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u4ee5\u5149\u4f0f\u3001\u98ce\u7535\u4e3a\u4ee3\u8868\u7684\u65b0\u80fd\u6e90\u4ea7\u4e1a\u53d6\u5f97\u4e86\u5feb\u901f\u53d1\u5c55\uff0c\u5229\u7528\u53ef\u518d\u751f\u80fd\u6e90\u8f6c\u5316\u50a8\u5b58\u7684\u7535\u80fd\u5b9e\u73b0\u9ad8\u6548\u4e8c\u6c27\u5316\u78b3\u7535\u50ac\u5316\u8fd8\u539f\uff08CO2<\/sub>RR\uff09\u88ab\u8ba4\u4e3a\u662f\u51cf\u7f13\u6e29\u5ba4\u6548\u5e94\u5e76\u5b9e\u73b0\u78b3\u4e2d\u548c\u7684\u6709\u6548\u624b\u6bb5\u3002\u5efa\u7acb\u5bf9CO2<\/sub>RR\u673a\u7406\u7684\u6df1\u5165\u8ba4\u8bc6\uff0c\u5bf9\u4e8e\u5f00\u53d1\u9ad8\u6548\u7684\u50ac\u5316\u8f6c\u5316\u8fc7\u7a0b\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002CO\uff08\u4e00\u6c27\u5316\u78b3\uff09\u88ab\u8ba4\u4e3a\u662fCO2<\/sub>\uff08\u4e8c\u6c27\u5316\u78b3\uff09\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u91cd\u8981\u7684\u4e2d\u95f4\u4f53\uff0c\u56e0\u6b64\uff0c\u76f4\u63a5\u7814\u7a76\u4e00\u6c27\u5316\u78b3\u7535\u50ac\u5316\u7535\u8fd8\u539f\uff08CORR\uff09\u8fc7\u7a0b\u4e5f\u4e3a\u7814\u7a76CO2<\/sub>RR\u7684\u53cd\u5e94\u673a\u7406\u63d0\u4f9b\u4e86\u66f4\u591a\u4fbf\u5229\uff0c\u4e3b\u8981\u5f52\u56e0\u4e8eCO\u4e0d\u4e0e\u7535\u89e3\u6db2\u672c\u8eab\u53d1\u751f\u4efb\u4f55\u5316\u5b66\u53cd\u5e94\uff0c\u53ef\u4ee5\u5728\u5f88\u5bbd\u7684pH\u8303\u56f4\u5185\u7814\u7a76\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u3002\u7136\u800c\uff0c\u7531\u4e8eCO\u4f20\u8d28\u53d7\u9650\u95ee\u9898\uff0c\u5f88\u5927\u7a0b\u5ea6\u4e0a\u5f71\u54cd\u5230\u4e86\u73b0\u6709\u7684CORR\u7684\u52a8\u529b\u5b66\u7814\u7a76\u7684\u53ef\u9760\u6027\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6e05\u534e\u5927\u5b66\u5316\u5de5\u7cfb\u9646\u5947\u56e2\u961f\u901a\u8fc7\u5c06\u7535\u5316\u5b66\u52a8\u529b\u5b66\u5b9e\u9a8c\u548c\u8868\u9762\u589e\u5f3a\u539f\u4f4d\u5149\u8c31\u6280\u672f\u76f8\u7ed3\u5408\u6df1\u5165\u63a2\u8ba8\u4e86CO2<\/sub>\/CO\u7535\u50ac\u5316\u8fd8\u539f\u7684\u53cd\u5e94\u673a\u7406\u3002\u8be5\u5de5\u4f5c\u7cfb\u7edf\u7814\u7a76\u4e86\u7535\u89e3\u6db2pH\u5bf9\u4e3b\u8981\u8fd8\u539f\u4ea7\u7269CH4<\/sub>\u4ee5\u53caC2<\/sub>+<\/sub>\u4ea7\u7269\uff08\u4e59\u70ef\u3001\u4e59\u9187\u3001\u4e59\u9178\u548c\u6b63\u4e19\u9187\uff09\u751f\u6210\u901f\u7387\u7684\u5f71\u54cd\u89c4\u5f8b\uff0c\u901a\u8fc7\u4e25\u683c\u52a8\u529b\u5b66\u5206\u6790\u786e\u5b9a\u4e86C2<\/sub>+<\/sub>\u4ea7\u7269\u548cCH4<\/sub>\u751f\u6210\u7684\u51b3\u901f\u6b65\u9aa4\uff0c\u5e76\u7ed3\u5408\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u6280\u672f\uff0c\u6784\u5efa\u4e86\u4e0d\u540cpH\u7535\u89e3\u6db2\u4e2dCu\u50ac\u5316\u5242\u8868\u9762\u7269\u79cd\u7684\u5b58\u5728\u5f62\u6001\u4e0e\u53cd\u5e94\u6d3b\u6027\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u8fd9\u9879\u7814\u7a76\u4e2d\u6240\u5f97\u5230\u7684\u5bf9CO2<\/sub>\/CO\u7535\u50ac\u5316\u8fd8\u539f\u53cd\u5e94\u673a\u7406\u7684\u6df1\u523b\u8ba4\u8bc6\uff0c\u5f25\u8865\u4e86\u76ee\u524d\u9886\u57df\u5185\u5bf9\u8be5\u53cd\u5e94\u673a\u7406\u8ba4\u77e5\u7684\u4e0d\u8db3\uff0c\u5e76\u4fbf\u4e8e\u4f18\u5316\u73b0\u6709\u7684\u53cd\u5e94\u4f53\u7cfb\u53ca\u8bbe\u8ba1\u66f4\u52a0\u9ad8\u6548\u7684\u50ac\u5316\u5242\uff0c\u4ee5\u83b7\u5f97\u9ad8\u9644\u52a0\u503c\u8fd8\u539f\u4ea7\u54c1\u3002\u76f8\u5173\u5de5\u4f5c\u4ee5Electrokinetic<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>a<\/i><\/b><\/em><\/strong>nd<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>i<\/i><\/b><\/em><\/strong>n<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>s<\/i><\/b><\/em><\/strong>itu<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Spectroscopic<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Investigations<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>o<\/i><\/b><\/em><\/strong>f<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>CO<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Electrochemical<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Reduction<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>o<\/i><\/b><\/em><\/strong>n<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Copper<\/i><\/b><\/em><\/strong>\u4e3a\u9898\uff0c\u53d1\u8868\u4e8eNature<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>communications<\/i><\/b><\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

Figure\u00a04\u00a0C2<\/sub>\u4ea7\u7269\u53caCH4<\/sub>\u7684\u4ea7\u751f\u673a\u7406\u548c\u76f8\u5e94\u7684\u5854\u83f2\u5c14\u659c\u7387\u3002<\/p>\n

5<\/b><\/strong>.<\/b><\/strong>Angewandte Chemie International Edition<\/b><\/strong>:<\/b><\/strong>\u00a0<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u8fd8\u539f\u81f3<\/b><\/strong>CO<\/b><\/strong>\u7684\u8fdb\u5c55\u4e0e\u6311\u6218–\u4ece\u57fa\u7840\u7814\u7a76\u5230\u5de5\u4e1a\u5316<\/b><\/strong><\/p>\n

\u7535\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u53cd\u5e94 (CO2<\/sub>RR) \u4e3a\u53ef\u518d\u751f\u7535\u529b\u80fd\u6e90\u4ee5\u50a8\u5b58\u5728\u5316\u5b66\u952e\u4e2d\u7684\u5f62\u5f0f\u8f6c\u5316\u4e3a\u9ad8\u9644\u52a0\u503c\u7684\u71c3\u6599\u548c\u5316\u5de5\u539f\u6599\u63d0\u4f9b\u4e86\u4e00\u79cd\u53ef\u884c\u7684\u65b9\u6cd5\u3002\u5728CO2<\/sub>RR\u7684\u4e0d\u540c\u4ea7\u7269\u4e2d\uff0cCO2<\/sub>\u8f6c\u5316\u4e3aCO\u56e0\u5176\u6280\u672f\u548c\u7ecf\u6d4e\u4e0a\u7684\u53ef\u884c\u6027\u88ab\u8ba4\u4e3a\u662f\u5316\u5b66\u5de5\u4e1a\u4e2d\u6700\u6709\u524d\u9014\u7684\u53cd\u5e94\u4e4b\u4e00\u3002\u5c06\u50ac\u5316\u5242\u548c\u7535\u89e3\u8d28\u8bbe\u8ba1\u4ee5\u53ca\u50ac\u5316\u673a\u7406\u76f8\u7ed3\u5408\uff0c\u63d0\u4f9b\u79d1\u5b66\u7684\u89c1\u89e3\uff0c\u4ee5\u63a8\u52a8\u8fd9\u9879\u6280\u672f\u8d70\u5411\u5de5\u4e1a\u5e94\u7528\u7684\u5f81\u7a0b\u3002CO2<\/sub>RR\u4e0d\u540c\u4ea7\u7269\u7684\u70ed\u529b\u5b66\u6c27\u5316\u8fd8\u539f\u52bf\u63a5\u8fd1\uff0c\u5bfc\u81f4\u4e86\u5176\u5bf9\u7279\u5b9a\u4ea7\u7269\u7684\u9009\u62e9\u6027\u8f83\u5dee\u3002\u76ee\u524d\u4e3a\u6b62\uff0c\u7535\u8fd8\u539fCO2<\/sub>\u81f3CO\u5df2\u7ecf\u5177\u5907\u9ad8\u7684\u7535\u6d41\u5bc6\u5ea6\u548c\u6cd5\u62c9\u7b2c\u6548\u7387\uff0c\u9009\u62e9\u6027\u5730\u5c06CO2<\/sub>\u8fd8\u539f\u4e3aCO\u975e\u5e38\u6709\u5e0c\u671b\u5b9e\u73b0\u5de5\u4e1a\u5e94\u7528\uff0c\u8fd9\u4e3a\u5efa\u7acb\u53ef\u6301\u7eed\u7684\u78b3\u4e2d\u548c\u63d0\u4f9b\u4e86\u89e3\u51b3\u65b9\u6848\u3002\u5728\u6b64\u8fc7\u7a0b\u4e2d\uff0c\u53ef\u518d\u751f\u80fd\u6e90\u9a71\u52a8CO2<\/sub>\u7535\u89e3\u69fd\uff0c\u5c06CO2<\/sub>\u8f6c\u5316\u4e3aCO\uff0cCO\u53ef\u4f5c\u4e3a\u591a\u79cd\u5de5\u4e1a\u539f\u6599\u3002\u7531\u6b64\u4ea7\u751f\u7684\u71c3\u6599\u53ef\u4ee5\u88ab\u50a8\u5b58\u3001\u5206\u914d\u6216\u6d88\u8017\uff0c\u91ca\u653e\u51faCO2<\/sub>\u4f5c\u4e3a\u4e3b\u8981\u4ea7\u7269\uff0c\u7136\u540e\u88ab\u6355\u83b7\u5e76\u56de\u6536\u56de\u53cd\u5e94\u5806\uff0c\u5173\u95ed\u78b3\u5faa\u73af\u3002<\/p>\n

\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u5357\u5f00\u5927\u5b66\u9648\u519b\u9662\u58eb\u548c\u4e25\u632f\u534e\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u7efc\u8ff0\u4e86\u8fd1\u5e74\u6765CO2<\/sub>\u9009\u62e9\u6027\u8f6c\u5316\u4e3aCO\u7684\u7814\u7a76\u8fdb\u5c55\u548c\u9762\u4e34\u7684\u6311\u6218\uff0c\u4ece\u539f\u5b50\u6c34\u5e73\u89e3\u8bfb\u50ac\u5316\u6750\u6599\uff0c\u5e76\u5bf9\u7535\u89e3\u8d28\u548c\u5668\u4ef6\u7684\u8bbe\u8ba1\u8fdb\u884c\u4e86\u5168\u9762\u5206\u6790\u603b\u7ed3\uff0c\u4ee5\u63d0\u9ad8\u7535\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u4e3aCO\u7684\u9009\u62e9\u6027\u548c\u6d3b\u6027\u3002\u6700\u540e\uff0c\u786e\u5b9a\u4e86CO2<\/sub>RR\u76ee\u524d\u5b58\u5728\u7684\u74f6\u9888\uff0c\u63d0\u51fa\u4e86CO2<\/sub>RR\u5728CO\u4ea7\u4e1a\u5316\u5e94\u7528\u4e2d\u5c1a\u5b58\u5728\u7684\u6280\u672f\u6311\u6218\u548c\u672a\u6765\u7684\u53d1\u5c55\u65b9\u5411\u3002\u8be5\u5de5\u4f5c\u4ee5Advances and Challenges for Electrochemical Reduction of CO<\/i><\/b><\/em><\/strong>2<\/i><\/b><\/sub><\/em><\/strong>\u00a0to CO: From Fundamental to Industrialization<\/i><\/b><\/em><\/strong>\u4e3a\u9898\uff0c\u53d1\u8868\u5728Angewandte Chemie International Edition<\/i><\/b><\/em><\/strong>\u671f\u520a\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

Figure\u00a05\u00a0CO2<\/sub>\u548cCO\u8f6c\u5316\u7684\u50ac\u5316\u5242\u53d1\u5c55\u5386\u7a0b\u3002<\/p>\n

6<\/b><\/strong>.<\/b><\/strong>Nature Communications<\/b><\/strong>:<\/b><\/strong>\u00a0<\/b><\/strong>\u9502\u8c03\u63a7\u7684\u53cc\u786b\u7a7a\u4f4d\u589e\u5f3a<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7535\u8fd8\u539f\u5236\u53d6\u6b63\u4e19\u9187<\/b><\/strong><\/p>\n

\u5229\u7528\u53ef\u518d\u751f\u80fd\u6e90\u9a71\u52a8\u4e8c\u6c27\u5316\u78b3\u7535\u5316\u5b66\u8fd8\u539f\u53cd\u5e94\uff08CO2<\/sub>RR\uff09\uff0c\u4ece\u800c\u8f6c\u5316\u4e3a\u9ad8\u9644\u52a0\u503c\u7684\u5316\u5b66\u539f\u6599\uff0c\u662f\u51cf\u5c11\u6e29\u5ba4\u6c14\u4f53\u548c\u5b58\u50a8\u5316\u5b66\u80fd\u7684\u53ef\u6301\u7eed\u9014\u5f84\u4e4b\u4e00\u3002\u590d\u65e6\u5927\u5b66\u90d1\u803f\u950b\u6559\u6388\u548c\u5357\u4eac\u5e08\u8303\u5927\u5b66\u674e\u4e9a\u98de\u6559\u6388\u5728\u5de5\u4f5c\u4e2d\u53d1\u73b0\uff0c\u5728\u516d\u65b9\u76f8CuS\uff08100\uff09\u6676\u9762\u4e0a\u5f62\u6210\u7684\u53cc\u786b\u7a7a\u4f4d\u53ef\u4ee5\u4f5c\u4e3a\u6709\u6548\u7a33\u5b9aCO*\u548cOCCO*\u4e8c\u805a\u4f53\u7684\u50ac\u5316\u4e2d\u5fc3\uff0c\u5e76\u7ee7\u7eed\u5b8c\u6210CO-OCCO\u5076\u8054\u5f62\u6210C3<\/sub>\u7269\u79cd\uff0c\u800c\u5728\u5355\u786b\u7a7a\u4f4d\u6216\u65e0\u786b\u7a7a\u4f4d\u5219\u65e0\u6cd5\u5b9e\u73b0\u3002\u8fd0\u7528\u9502\u7535\u5316\u5b66\u8c03\u63a7\u7b56\u7565\uff0c\u901a\u8fc7\u63a7\u5236\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5145\u653e\u7535\u5faa\u73af\u6b21\u6570\u53ef\u5bf9\u786b\u7a7a\u4f4d\u7684\u5bc6\u5ea6\u8fdb\u884c\u8c03\u8282\u3002\u5728\u5faa\u73af\u5708\u6570\u4e3a10\u65f6\uff0c\u53ef\u5f62\u6210\u53cc\u786b\u7a7a\u4f4d\u3002\u5e26\u6709\u53cc\u786b\u7a7a\u4f4d\u7684\u786b\u5316\u94dc\uff08CuSx-DSV\uff09\u505a\u4e3a\u7535\u50ac\u5316\u5242\uff0c\u5728H-cell\u4f53\u7cfb\u4e0b\uff0c\u53ef\u5728-1.05\u00a0V\u00a0vs. RHE\u65f6\u83b7\u5f9715.4\u00a0\u00b1 1%\u7684\u6b63\u4e19\u9187\u6cd5\u62c9\u8fbe\u6548\u7387\uff0c\u8fd9\u662f\u76ee\u524dH-cell\u4e2d\u62a5\u9053\u7684\u6700\u9ad8\u503c\u4e4b\u4e00\u3002\u901a\u8fc7\u4f7f\u7528\u6d41\u52a8\u6c60\uff0c\u6b63\u4e19\u9187\u7684\u5206\u7535\u6d41\u5bc6\u5ea6\u53ef\u8fdb\u4e00\u6b65\u63d0\u5347\u81f39.9\u2009\u00b1\u20091\u2009mA\u00a0cm\u22122<\/sup>\u3002\u56e2\u961f\u7684\u5de5\u4f5c\u63d0\u51fa\u4e86\u4e00\u79cd\u6709\u5438\u5f15\u529b\u7684\u9502\u8c03\u63a7\u7b56\u7565\u6765\u521b\u9020\u9634\u79bb\u5b50\u7a7a\u4f4d\u5bf9\u4f5c\u4e3a\u591a\u78b3\u4ea7\u54c1\u7684\u50ac\u5316\u4e2d\u5fc3\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3aDouble Sulfur Vacancies by Lithium Tuning Enhance CO<\/i><\/b><\/em><\/strong>2<\/i><\/b><\/sub><\/em><\/strong>\u00a0Electroreduction to N-Propanol<\/i><\/b><\/em><\/strong>\u53d1\u8868\u5728\u4e86Nature Communications<\/b><\/strong>\u4e0a\u3002<\/p>\n

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Figure\u00a06\u00a0\u5177\u6709\u53cc\u786b\u7a7a\u4f4d\u7684CuSx<\/sub>\u7684CO2<\/sub>\u8f6c\u5316\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

7<\/b><\/strong>.<\/b><\/strong>Nano<\/b><\/strong>\u00a0<\/b><\/strong>Letters<\/b><\/strong>: <\/b><\/strong>\u57fa\u4e8e\u7eb3\u7c73\u9650\u57df\u6548\u5e94\u548c\u6bdb\u7ec6\u4f5c\u7528\u7684\u6ef4\u7ba1\u72b6\u7535\u50ac\u5316\u5242\u7528\u4e8e\u9ad8\u6548<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u8fd8\u539f<\/b><\/strong><\/p>\n

\u5728CO2<\/sub>\u8fd8\u539f\u7684\u4f17\u591a\u4ea7\u7269\u4e2d\uff0c\u7532\u9178\u76d0\uff08HCOOH\/HCOO\u2013<\/sup>\uff09\u4ea7\u7269\u5177\u6709\u6613\u4e8e\u50a8\u5b58\u548c\u9ad8\u5b89\u5168\u6027\u7684\u7a81\u51fa\u4f18\u70b9\uff0c\u5728\u6c22\u8f7d\u4f53\u548cHCOOH\u71c3\u6599\u7535\u6c60\u9886\u57df\u4e2d\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u7136\u800c\uff0c\u76ee\u524d\u7684\u5236\u7532\u9178\u50ac\u5316\u5242\u5728\u7535\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u9762\u4e34\u7740\u4f4e\u6d3b\u6027\u3001\u9009\u62e9\u6027\u548c\u7a33\u5b9a\u6027\u7684\u95ee\u9898\u3002\u9488\u5bf9\u8fd9\u4e00\u95ee\u9898\uff0c\u5357\u4eac\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u91d1\u949f\u6559\u6388\u7814\u53d1\u56e2\u961f\u5229\u7528\u745e\u5229\u4e0d\u7a33\u5b9a\u6027\u539f\u7406\u6784\u7b51\u4e86\u201c\u6ef4\u7ba1\u72b6\u201d\u4e00\u7ef4\u4e2d\u7a7a\u7ed3\u6784\u7684Bi\u7eb3\u7c73\u68d2@N\u63ba\u6742\u78b3\u7eb3\u7c73\u7ba1\uff08Bi-NRs@NCNTs\uff09\u590d\u5408\u50ac\u5316\u5242\uff0c\u5728\u8f83\u4f4e\u7684\u8fc7\u7535\u52bf\u4e0b\u53ef\u4ee5\u5c06CO2<\/sub>\u9ad8\u9009\u62e9\u6027\u5730\u50ac\u5316\u8f6c\u6362\u6210\u7532\u9178\u76d0\u4ea7\u7269\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0cBi-NRs@NCNTs\u5728-0.9\u00a0V\uff08vs. RHE\uff09\u7535\u538b\u4e0b\u5bf9\u7532\u9178\u76d0\u7684\u9009\u62e9\u6027\u53ef\u4ee5\u8fbe\u523090.9\uff05\uff1b\u6b64\u5916\uff0c\u7ecf\u8fc7\u8fde\u7eed24\u5c0f\u65f6\u7684\u957f\u671f\u7535\u50ac\u5316\u6d4b\u8bd5\u540e\uff0cBi-NRs@NCNTs\u4ecd\u7136\u53ef\u4ee5\u4fdd\u6301\u826f\u597d\u7684\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5Nanocapillarity<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>and<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Nanoconfinement<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Effects<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>of<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Pipet<\/i><\/b><\/em><\/strong>–<\/i><\/b><\/em><\/strong>like<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Bismuth@Carbon<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Nanotubes<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>for<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Highly<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Efficient<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Electrocatalytic<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>CO<\/i><\/b><\/em><\/strong>2<\/i><\/b><\/sub><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Reduction<\/i><\/b><\/em><\/strong>\u4e3a\u9898\u53d1\u8868\u5728Nano<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Letters<\/i><\/b><\/em><\/strong>\u671f\u520a\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

Figure\u00a07\u00a0Bi\u7eb3\u7c73\u68d2@\u6c2e\u63ba\u6742\u78b3\u7eb3\u7c73\u7ba1\u6837\u54c1\u7684\u5236\u5907\u53ca\u5f62\u8c8c\u8868\u5f81\u3002<\/p>\n

8<\/b><\/strong>.<\/b><\/strong>Nat<\/b><\/strong>ure<\/b><\/strong>\u00a0<\/b><\/strong>Commun<\/b><\/strong>ications<\/b><\/strong>:<\/b><\/strong>\u00a0<\/b><\/strong>\u7528\u5206\u5b50\u94dc\u7d2b\u7ea2\u7d20\u53d1\u8272\u56e2\u4fc3\u8fdb\u5149\u50ac\u5316\u8fd8\u539f<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong><\/p>\n

\u901a\u8fc7\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u8fd8\u539f\u4e8c\u6c27\u5316\u78b3\u662f\u5c06\u592a\u9633\u80fd\u8f6c\u5316\u4e3a\u71c3\u6599\u6216\u6709\u7528\u7684\u5316\u5b66\u539f\u6599\u7684\u4e00\u9879\u91cd\u8981\u7b56\u7565\u3002\u5728\u8fd9\u79cd\u7ed3\u6784\u4e2d\uff0c\u8bbe\u8ba1\u542b\u6709\u5730\u7403\u4e30\u5bcc\u5143\u7d20\u7684\u9ad8\u6548\u53d1\u8272\u56e2\u5bf9\u4e8e\u5149\u6536\u96c6\u548c\u7535\u5b50\u8f6c\u79fb\u90fd\u662f\u5fc5\u4e0d\u53ef\u5c11\u7684\u3002\u6709\u9274\u4e8e\u6b64\uff0c\u4e2d\u5c71\u5927\u5b66\u97e9\u6cbb\u9645\u6559\u6388\u7b49\u4eba\uff0c\u62a5\u544a\u4e86\u4e00\u79cd\u9ad8\u6d3b\u6027\u7684\u94dc\u7d2b\u7ea2\u7d20\u5149\u654f\u5242\uff0c\u7528\u4e8e\u5728\u65e0\u8d35\u91d1\u5c5e\u7684\u7cfb\u7edf\u4e2d\u5c06\u53ef\u89c1\u5149\u9a71\u52a8\u7684CO2<\/sub>\u8fd8\u539f\u4e3aCO\u3002\u7814\u7a76\u5de5\u4f5c\u53d1\u73b0\uff0c\u5929\u7136\u6709\u673a\u53d1\u8272\u56e2\u4e2d\u5e26\u6709\u989d\u5916\u7684\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u4e2d\u5fc3\u7684\u94dc\u7d2b\u7ea2\u7d20\u590d\u5408\u7269\uff0c\u53ef\u4ee5\u6709\u6548\u7684\u964d\u4f4e\u53cd\u5e94\u8fc7\u7535\u52bf\u3002\u5f53\u4e0eFe\u535f\u5549\u7ed3\u5408\u4f5c\u4e3a\u50ac\u5316\u5242\uff0cBIH\u4f5c\u4e3a\u727a\u7272\u7535\u5b50\u7ed9\u4f53\u65f6\uff0c\u4e0e\u6709\u673a\u67d3\u6599\u7ec4\u5206\u76f8\u6bd4\uff0c\u8be5Cu-PS\u7684CO2<\/sub>\u8fd8\u539f\u5149\u50ac\u5316\u6d3b\u6027\u663e\u8457\u63d0\u9ad8(>50\u500d)\u3002\u5f53\u5c06\u6b64\u94dc\u5149\u654f\u5242\u4e0e\u535f\u5549\u94c1\u4f5c\u4e3a\u50ac\u5316\u5242\u5e76\u75281,3-\u4e8c\u7532\u57fa-2-\u82ef\u57fa-2,3-\u4e8c\u6c22-1H-\u82ef\u5e76[d]\u54aa\u5511\uff081,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole\uff09\u4f5c\u4e3a\u727a\u7272\u8fd8\u539f\u5242\u4e00\u8d77\u4f7f\u7528\u65f6\uff0c\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\u8be5\u7cfb\u7edf\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u6210CO\u5177\u670995\uff05\u7684\u9009\u62e9\u6027\uff08CO\u00a0vs\u00a0H2<\/sub>\uff09\uff0c\u53ef\u5b9e\u73b0\u8d85\u8fc716100\u7684\u8f6c\u6362\u6570\uff0c\u8fd9\u662f\u5747\u76f8\u65e0\u8d35\u91d1\u5c5e\u4f53\u7cfb\u4e2d\u62a5\u544a\u7684\u6700\u9ad8\u503c\u3002\u8be5\u5de5\u4f5c\u53ef\u80fd\u4e3a\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u4e2d\u9ad8\u6548\u53d1\u8272\u56e2\u7684\u5408\u7406\u8bbe\u8ba1\u5f00\u8f9f\u4e00\u6761\u6709\u6548\u9014\u5f84\u3002\u8be5\u5de5\u4f5c\u4ee5Promoting<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Photocatalytic<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>CO<\/i><\/b><\/em><\/strong>2<\/i><\/b><\/sub><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Reduction<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>w<\/i><\/b><\/em><\/strong>ith<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>a<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Molecular<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Copper<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Purpurin<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Chromophore<\/i><\/b><\/em><\/strong>\u4e3a\u9898\uff0c\u53d1\u8868\u4e8eNat<\/i><\/b><\/em><\/strong>ure<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Communications<\/i><\/b><\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

Figure\u00a08\u00a0\u67d3\u6599\u654f\u5316\u5149\u50ac\u5316\u5242\u7684CO2<\/sub>\u8fd8\u539f\u53cd\u5e94\u673a\u7406\u3002<\/p>\n

9.\u00a0<\/b>Nature<\/b><\/strong>\u00a0<\/b><\/strong>Catalysis<\/b><\/strong>:<\/b><\/strong>\u00a0<\/b><\/strong>\u5bcc\u786b\u7a7a\u4f4d\u7684\u4e8c\u786b\u5316\u94bc\u7684<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u8f6c\u5316\u5236\u7532\u9187\u6027\u80fd\u63a2\u7a76<\/b><\/strong><\/p>\n

\u4f20\u7edf\u7684\u4e8c\u786b\u5316\u94bc\u4e3a\u826f\u597d\u7684\u5236\u6c22\u50ac\u5316\u5242\uff0c\u5176\u672c\u5f81\u7684\u5236\u6c22\u6d3b\u6027\u4f4d\u70b9\u5e76\u4e0d\u5229\u4e8eCO2<\/sub>\u8fd8\u539f\u53cd\u5e94\uff0c\u4f46\u662f\u5728\u8fd9\u7bc7\u5de5\u4f5c\u4e2d\uff0c\u5374\u5229\u7528\u4e86\u5176\u5236\u6c22\u6d3b\u6027\uff0c\u5bf9CO2<\/sub>\u8fdb\u884c\u52a0\u6c22\u5316\uff0c\u7a81\u7834\u4e86\u4e8c\u786b\u5316\u94bc\u5728CO2<\/sub>\u65b9\u5411\u7684\u5e94\u7528\u3002\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u9093\u5fb7\u4f1a\u56e2\u961f\u4e0e\u53a6\u95e8\u5927\u5b66\u6559\u6388\u738b\u91ce\u56e2\u961f\u5408\u4f5c\uff0c\u5229\u7528\u5bcc\u542b\u786b\u7a7a\u4f4d\u7684\u5c11\u5c42\u4e8c\u786b\u5316\u94bc\u50ac\u5316\u5242\u5b9e\u73b0\u4e86\u4f4e\u6e29\u3001\u9ad8\u6548\u3001\u957f\u5bff\u547d\u50ac\u5316CO2<\/sub>\u52a0\u6c22\u5236\u7532\u9187\u3002\u8be5\u50ac\u5316\u5242\u7684\u6d3b\u6027\u4e0e\u9009\u62e9\u6027\u5747\u663e\u8457\u4f18\u4e8e\u5df2\u62a5\u9053\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u50ac\u5316\u5242\uff0c\u5e76\u5177\u5907\u826f\u597d\u7684\u7a33\u5b9a\u6027\uff0c\u5728\u4f4e\u80fd\u8017\u3001\u9ad8\u6548\u7387\u7684CO2<\/sub>\u8f6c\u5316\u65b9\u9762\u5f00\u8f9f\u4e86\u65b0\u9014\u5f84\u3002\u5728\u5b9e\u9a8c\u5ba4\u6027\u80fd\u6d4b\u8bd5\u4e2d\uff0cCO2<\/sub>\u5728180\u6444\u6c0f\u5ea6\u4e0b\u7684\u5355\u7a0b\u8f6c\u5316\u7387\u53ef\u8fbe12.5%\uff0c\u7532\u9187\u9009\u62e9\u6027\u9ad8\u8fbe94.3%\uff0c\u663e\u8457\u4f18\u4e8e\u6b64\u524d\u62a5\u9053\u7684\u91d1\u5c5e\u548c\u91d1\u5c5e\u6c27\u5316\u7269\u7b49\u4f20\u7edf\u50ac\u5316\u5242\uff0c\u5e76\u4e14\u6027\u80fd\u80fd\u591f\u7a33\u5b9a\u7ef4\u63013000\u5c0f\u65f6\u800c\u672a\u89c1\u8870\u51cf\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5de5\u4e1a\u5e94\u7528\u6f5c\u529b\u3002\u8be5\u5de5\u4f5c\u88ab\u5361\u5c14\u65af\u9c81\u5384\u7406\u5de5\u5b66\u9662(KIT)\u6559\u6388Felix\u00a0Studt\u8bc4\u4ef7\u4e3a\u4ee4\u4eba\u60ca\u5947\u3001\u6709\u610f\u4e49\u7684\u5de5\u4f5c\uff0c\u6709\u671b\u4e3a\u4e8c\u6c27\u5316\u78b3\u52a0\u6c22\u5236\u7532\u9187\u7684\u5de5\u4e1a\u5e94\u7528\u5e26\u6765\u5de8\u5927\u7684\u6548\u7387\u63d0\u5347\u3002\u8be5\u5de5\u4f5c\u4ee5Sulfur<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Vacancy<\/i><\/b><\/em><\/strong>–<\/i><\/b><\/em><\/strong>Rich<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Mos<\/i><\/b><\/em><\/strong>2<\/i><\/b><\/sub><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>a<\/i><\/b><\/em><\/strong>s<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>a<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Catalyst<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>f<\/i><\/b><\/em><\/strong>or<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>t<\/i><\/b><\/em><\/strong>he<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Hydrogenation<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>o<\/i><\/b><\/em><\/strong>f<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>CO<\/i><\/b><\/em><\/strong>2<\/i><\/b><\/sub><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>t<\/i><\/b><\/em><\/strong>o<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Methanol<\/i><\/b><\/em><\/strong>\u4e3a\u9898\u53d1\u8868\u4e8eNature<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Catalysis<\/i><\/b><\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

 <\/p>\n

Figure\u00a09\u00a0\u5bcc\u786b\u7a7a\u4f4d\u7684\u4e8c\u786b\u5316\u94bc\u7684CO2<\/sub>\u52a0\u6c22\u53cd\u5e94\u7406\u8bba\u6a21\u62df\u793a\u610f\u56fe\u3002<\/p>\n

10<\/b><\/strong>.<\/b><\/strong>Nature<\/b><\/strong>\u00a0<\/b><\/strong>Catalysis<\/b><\/strong>:\u65b0\u578b\u56fa\u6db2\u76f8\u8f6c\u6362\u7535\u50ac\u5316\u5242\u7684\u9ad8\u6548<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u8fd8\u539f\u6027\u80fd\u63a2\u7a76<\/b><\/strong><\/p>\n

\u76ee\u524d\u7684\u5de5\u4f5c\u5927\u591a\u6570\u96c6\u4e2d\u4e8e\u5143\u7d20\u63ba\u6742\u3001\u7f3a\u9677\u8c03\u63a7\u3001\u5f62\u8c8c\u5de5\u7a0b\u3001\u57fa\u5e95\u8bbe\u8ba1\u7b49\u65b9\u9762\uff0c\u4f46\u662f\u8fd9\u4e9b\u8c03\u8282\u7b56\u7565\u53ea\u80fd\u6539\u53d8\u50ac\u5316\u5242\u7684\u7ed3\u6784\u3001\u7535\u5b50\u6001\u548c\u76f8\u5e94\u7684\u57fa\u672c\u50ac\u5316\u8def\u5f84\u53cd\u5e94\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u8c22\u6bc5\u6559\u6388\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u56fa\u6db2\u76f8\u8f6c\u53d8\u5408\u91d1\uff0c\u5229\u7528Ga-Sn\/Ga-In\u5408\u91d1\u8bf1\u5bfc\u4e86\u50ac\u5316\u5242\u5728\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7684\u539f\u5b50\u7684\u5373\u65f6\u8f6c\u5316\u548c\u79bb\u5b50\u4f20\u9012\uff0c\u5927\u5e45\u5ea6\u7684\u63d0\u5347\u4e86\u50ac\u5316\u6027\u80fd\u3002Sn\/In\u7684\u5206\u6563\u548c\u805a\u96c6\u6001\u7684\u4e0d\u65ad\u8fc7\u6e21\uff0c\u4ece\u591a\u539f\u5b50\u878d\u5316\u5230\u5355\u539f\u5b50\u7684\u8f6c\u6362\u8fc7\u7a0b\u53ef\u4ee5\u8fdb\u4e00\u6b65\u6539\u53d8Sn\/In\u548cGa\u7684\u6210\u5206\u53d8\u5316\uff0c\u4ea7\u751f\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u8fd9\u79cd\u539f\u5b50\/\u7535\u5b50\u7ed3\u6784\u4e4b\u95f4\u7684\u53d8\u5316\u53ef\u4ee5\u6291\u5236\u6c22\u7ade\u4e89\u53cd\u5e94\uff0c\u6cd5\u62c9\u7b2c\u6548\u7387\u4ece35%\u63d0\u5347\u523095%\u3002\u8fd9\u79cd\u53cc\u6001\u5207\u6362\u7b56\u7565\u540c\u6837\u53ef\u4ee5\u6269\u5c55\u5230\u5176\u4ed6\u50ac\u5316\u53cd\u5e94\uff0c\u8be5\u5de5\u4f5c\u62d3\u5bbd\u4e86CO2<\/sub>\u8fd8\u539f\u53cd\u5e94\u7684\u7814\u7a76\u89c6\u91ce\uff0c\u6253\u5f00\u4e86\u65b0\u601d\u8def\u3002\u6539\u5de5\u4f5c\u4ee5Solid<\/i><\/b><\/em><\/strong>\u2013<\/i><\/b><\/em><\/strong>Liquid<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Phase<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Transition<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Induced<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Electrocatalytic<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Switching<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>f<\/i><\/b><\/em><\/strong>rom<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Hydrogen<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Evolution<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>t<\/i><\/b><\/em><\/strong>o<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Highly<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Selective<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>CO<\/i><\/b><\/em><\/strong>2<\/i><\/b><\/sub><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Reduction<\/i><\/b><\/em><\/strong>\u4e3a\u9898\uff0c\u53d1\u8868\u4e8eNature<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Catalysis<\/i><\/b><\/em><\/strong>\u671f\u520a\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

Figure\u00a010\u00a0Ga-Sn\/Ga-In\u5408\u91d1\u7684\u56fa\u6db2\u76f8\u8f6c\u53d8\u5bf9\u4e8e\u6027\u80fd\u7684\u5f71\u54cd\u63a2\u7a76\u3002<\/p>\n

\u672c\u6587\u7531\u63d0\u7434\u8537\u8587\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

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