{"id":224685,"date":"2021-07-15T12:00:08","date_gmt":"2021-07-15T04:00:08","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=224685"},"modified":"2021-07-15T11:51:37","modified_gmt":"2021-07-15T03:51:37","slug":"%ef%bc%88%e5%b7%b2%e6%a0%a1%e7%a8%bf%e4%bb%b6%ef%bc%89%e5%a4%a7%e8%bf%9e%e5%8c%96%e7%89%a9%e6%89%80%e7%ad%89-adv-sci-%ef%bc%9a%e4%ba%86%e8%a7%a3%e6%b2%b8%e7%9f%b3%e5%be%ae%e5%ad%94%e5%8d%87%e7%ba%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=224685","title":{"rendered":"\u5927\u8fde\u5316\u7269\u6240\u7b49 Adv. Sci.\uff1a\u4e86\u89e3\u6cb8\u77f3\u5fae\u5b54\u5347\u7ea7\u7684\u57fa\u672c\u539f\u7406\uff1a\u63d0\u5347\u6269\u6563\u548c\u50ac\u5316\u6027\u80fd"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u6cb8\u77f3\u662f\u4e00\u79cd\u5177\u6709\u72ec\u7279\u9aa8\u67b6\u7ed3\u6784\u548c\u53ef\u8c03\u9178\u6027\u8d28\u7684\u7ed3\u6676\u94dd\u7845\u9178\u76d0\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u50ac\u5316\u3001\u5438\u9644\u548c\u5206\u79bb\u7b49\u9886\u57df\u3002\u5408\u6210\u540e\u9aa8\u67b6\u539f\u5b50\u7684\u53bb\u9664\u548c\u4f34\u968f\u7684\u4ecb\u5b54\u5f62\u6210\uff0c\u5df2\u88ab\u7528\u4e8e\u6539\u5584\u53cd\u5e94\u7269\u548c\u4ea7\u7269\u7684\u6676\u4f53\u5185\u5206\u5b50\u901a\u9053\u3002\u867d\u7136\u5728\u8bbe\u8ba1\u3001\u5408\u6210\u3001\u8868\u5f81\u548c\u4f7f\u7528\u8fd9\u4e9b\u5206\u7ea7\u6cb8\u77f3\u53d6\u5f97\u4e86\u91cd\u5927\u8fdb\u5c55\uff0c\u4f46\u662f\u8bb8\u591a\u91cd\u8981\u95ee\u9898\u4ecd\u7136\u9700\u8981\u89e3\u51b3\u3002\u4f8b\u5982\u5728\u5fae\u89c2\u5c3a\u5ea6\u4e0a\uff0c\u4ecb\u5b54\u7684\u5f62\u6210\u673a\u5236\u8fd8\u6ca1\u6709\u5b8c\u5168\u4e86\u89e3\u3002\u5c3d\u7ba1\u5404\u79cd\u663e\u5fae\u955c\u6280\u672f\u80fd\u591f\u5728\u4e0d\u540c\u7684\u957f\u5ea6\u5c3a\u5ea6\u4e0a\u89c2\u5bdf\u5230\u4ecb\u5b54\uff0c\u4f46\u5b83\u4eec\u5f62\u6210\u7684\u521d\u59cb\u6b65\u9aa4\uff0c\u5373\u53bb\u9664\u9aa8\u67b6\u539f\u5b50\u53ca\u5176\u540e\u679c\uff0c\u8fd8\u6ca1\u6709\u5b8c\u5168\u4e86\u89e3\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u4ecb\u5b54\u7684\u5b58\u5728\uff0c\u5206\u7ea7\u6cb8\u77f3\u7684\u6269\u6563\u548c\u50ac\u5316\u6027\u80fd\u7684\u589e\u5f3a\u4e0e\u4f20\u8d28\u7684\u6539\u5584\u6709\u5173\uff0c\u589e\u52a0\u4e86\u53cd\u5e94\u7269\u5bf9\u5fae\u5b54\u4e2d\u6d3b\u6027\u4f4d\u70b9\u7684\u53ef\u53ca\u6027\u3002\u7136\u800c\uff0c\u5b9a\u91cf\u63cf\u8ff0\u5929\u7136\u5fae\u5b54\u548c\u6dfb\u52a0\u7684\u4ecb\u5b54\u4e4b\u95f4\u7684\u8fde\u901a\u6027\u9700\u8981\u8fdb\u4e00\u6b65\u5173\u6ce8\u3002\u6cb8\u77f3\u5fae\u5b54\u7684\u5927\u5c0f\u548c\u5f62\u72b6\u51b3\u5b9a\u4e86\u5176\u50ac\u5316\u5242\u7684\u62e9\u5f62\u6027\uff0c\u5e76\u53d7\u5fae\u5b54\u7684\u7ec6\u5fae\u53d8\u5316\u7684\u663e\u8457\u5f71\u54cd\u3002\u8003\u8651\u5230\u5206\u5c42\u6cb8\u77f3\u5f62\u6210\u8fc7\u7a0b\u4e2d\u5927\u91cf\u7684\u9aa8\u67b6\u539f\u5b50\u8131\u9644\u4e8b\u4ef6\u53ca\u5176\u5fae\u5b54\u5c3a\u5bf8\u5927\u5c0f\u548c\u5f62\u72b6\u7684\u76f8\u5173\u7ec6\u5fae\u53d8\u5316\uff08\u79f0\u4e3a\u5fae\u5b54\u5347\u7ea7\uff09\uff0c\u9884\u8ba1\u4f1a\u5bf9\u6269\u6563\u548c\u53cd\u5e94\u8def\u5f84\u4ee5\u53ca\u4ea7\u7269\u9009\u62e9\u6027\u4ea7\u751f\u663e\u8457\u5f71\u54cd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u5f90\u8212\u6d9b\u7814\u7a76\u5458\u3001\u6cd5\u56fd\u8bfa\u66fc\u5e95\u5927\u5b66Svetlana Mintova\u6559\u6388\u548c\u6cd5\u56fd\u6d1b\u6797\u5927\u5b66Michael Badawi\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u5728\u516d\u65b9\u6cb8\u77f3\uff08FAU\uff09\u578b\u6cb8\u77f3\u4e2d\u5f62\u6210\u4ecb\u5b54\u662f\u4ece\u65b9\u94a0\u77f3\uff08SOD\uff09\u7b3c\u4e2d\u53bb\u9664\u9aa8\u67b6T\u539f\u5b50\uff0c\u7136\u540e\u5728\u6574\u4e2a\u6676\u4f53\u4e2d\u4f20\u64ad\u3002\u5bf9\u6bd4\u539f\u59cbFAU\u6cb8\u77f3\uff0c\u5229\u7528NH4<\/sub>F\u65e0\u504f\u6d78\u51fa\u6cd5\u5236\u5907\u7684\u4ecb\u5b54FAU\u6cb8\u77f3\u4e2d\u6c19\uff08Xe\uff09\u7684\u6269\u6563\u8bc1\u660e\u4e86\u8fd9\u4e00\u70b9\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86Xe\u5728\u4ecb\u5b54\u6cb8\u77f3\u4e2d\u6269\u6563\u7684\u65b0\u9014\u5f84\u3002\u5373Xe\u9996\u5148\u7a7f\u900f\u6253\u5f00\u7684SOD\u7b3c\uff0c\u7136\u540e\u6269\u6563\u5230\u4ecb\u5b54\u6cb8\u77f3\u7684\u8d85\u7b3c\u4e2d\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u8868\u660e\uff0cXe\u5728\u8d85\u6c27\u5316\u7269\u6b67\u5316\u9176\u7b3c\u548c\u8d85\u7b3c\u4e4b\u95f4\u7684\u6269\u6563\u53ea\u53d1\u751f\u5728\u542b\u6709\u516d\u5143\u73af\u7f3a\u9677\u7684\u5c42\u6b21FAU\u7ed3\u6784\u4e2d\u3002\u4ecb\u5b54FAU\u6cb8\u77f3\u7684\u50ac\u5316\u6027\u80fd\u8fdb\u4e00\u6b65\u8868\u660e\uff0c\u6539\u6027\u540e\u7684\u5fae\u5b54\u6709\u5229\u4e8e\u5206\u5b50\u5728\u6676\u5185\u7684\u6d41\u52a8\uff0c\u63d0\u9ad8\u4e86\u50ac\u5316\u6027\u80fd\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cUnderstanding the Fundamentals of Microporosity Upgrading in Zeolites: Increasing Diffusion and Catalytic Performances\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAdv. Sci.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001FY-20\u5206\u7ea7\u6cb8\u77f3\u7684\u7535\u5b50\u65ad\u5c42\u626b\u63cf\uff083D-TEM\uff09<\/strong>
\n \"\"\uff08a\uff09\u901a\u8fc7\u5408\u5e76\u51e0\u4e2a\u5fae\u5b54\u7b3c\u548c\u6cb8\u77f3\u6676\u4f53\u4e2d\u4ecb\u5b54\u548c\u5468\u56f4\u73af\u5883\u76843D\uff0c\u8868\u793a\u4ea7\u751f\u7684\u4ecb\u5b54\u7684\u9ad8\u5206\u8fa8\u7387\u89c6\u56fe\uff1b<\/p>\n

\uff08b\uff09\u4e00\u5bf9\u4e09\u4e2a\u4ecb\u5b54\u5408\u5e76\u7684\u9ad8\u5206\u8fa8\u7387\u89c6\u56fe\u548c\u6cb8\u77f3\u6676\u4f53\u4e2d\u4ecb\u5b54\u53ca\u5176\u5468\u56f4\u73af\u5883\u76843D\u8868\u793a\uff1b<\/p>\n

\uff08c\uff09FY-20\u6cb8\u77f3\u76843D\u91cd\u5efa\u56fe\u50cf\uff0c\u5c3a\u5bf8\u4e3a0.7-1.5 nm\u548c\u8f83\u5927\u4ecb\u5b54\u7684\u5fae\u7b3c\uff1b<\/p>\n

\uff08d\uff09\u5305\u542b\u7528\u4e8e\u91cf\u5316\u591a\u5b54\u7f51\u7edc\u7684\u4e09\u4e2a\u5706\u67f1\u4f53\u79ef\u76843D\u91cd\u5efa\u56fe\u50cf\uff1b<\/p>\n

\uff08e\uff09\u4ece\u56fe1d\u4e2d\u6cb8\u77f3\u6676\u4f53\u7684\u4e09\u4e2a\u4e0d\u540c\u533a\u57df\u8ba1\u7b97\u7684\u5b54\u5f84\u5206\u5e03\u3002<\/p>\n

\u56fe\u4e8c\u3001\u5206\u7ea7\u6cb8\u77f3FY60\u76843D-TEM\u56fe\u7247<\/strong>
\n \"\"\uff08a\uff09FY60\u6cb8\u77f3\u6676\u4f53\u76843D-TEM\u91cd\u5efa\uff1b<\/p>\n

\uff08b-c\uff09FY60\u6cb8\u77f3\u6676\u4f53\u7684\u4ecb\u5b54\u7f51\u7edc\u76843D\u5206\u5e03\uff1b<\/p>\n

\uff08d\uff09FY60\u6cb8\u77f3\u6676\u4f53\u76843D-TEM \u91cd\u5efa\u663e\u793a\u4ecb\u5b54\u4ece\u4e00\u4e2a\u8868\u9762\u5230\u53e6\u4e00\u4e2a\u8868\u9762\u7684\u4e92\u8fde\u6027\uff1b<\/p>\n

\uff08e\uff09\u5305\u542b\u4e09\u4e2a\u72ec\u7acb\u5185\u90e8\u4f53\u79ef\u76843D\u91cd\u5efa\u56fe\u50cf\uff1b<\/p>\n

\uff08f\uff09\u4ece\u56fe2e\u4e2d\u663e\u793a\u7684\u6cb8\u77f3\u6676\u4f53\u7684\u4e09\u4e2a\u4e0d\u540c\u533a\u57df\u8ba1\u7b97\u7684\u5b54\u5f84\u5206\u5e03\u3002<\/p>\n

\u56fe\u4e09\u3001\u5206\u7ea7\u6cb8\u77f3\u76841D HP 129<\/sup>Xe\u5149\u8c31<\/strong>
\n \"\"\uff08a\uff09\u5206\u7ea7\u6cb8\u77f3\uff08FY5-FY60\uff09\u5728253 K\u4e0b\u7684HP 129<\/sup>Xe\u5149\u8c31\uff1b<\/p>\n

\uff08b\uff09SOD\u7b3c\u548c\u5206\u7ea7\u6cb8\u77f3\u4e2d\u8d85\u7b3c\u4e2d\u4e0eXe\u76f8\u5173\u7684\u5cf0\u4e4b\u95f4\u7684\u5316\u5b66\u4f4d\u79fb\u5dee\u5f02\u3002<\/p>\n

\u56fe\u56db\u3001Xe\u5728\u5206\u7ea7\u6cb8\u77f3\u4e2d\u7684\u6269\u6563<\/strong>
\n \"\"\uff08a-d\uff09\u5728\u6e29\u5ea6\u4e3a253 K\uff0c\u6df7\u5408\u65f6\u95f4\u4e3a4\u30015\u30018\u300150 ms\u4e0b\uff0cXe\u5728FY5\u6cb8\u77f3\u4e0a\u7684HP 129<\/sup>Xe EXSY NMR\u5149\u8c31\uff1b<\/p>\n

\uff08e-h\uff09\u5728\u6e29\u5ea6\u4e3a253 K\uff0c\u6df7\u5408\u65f6\u95f4\u4e3a3\u30015\u30017\u300110 ms\u4e0b\uff0cXe\u5728FY60 \u6cb8\u77f3\u4e0a\u7684HP 129<\/sup>Xe EXSY NMR\u5149\u8c31\uff1b<\/p>\n

\uff08i\uff09\u5206\u7ea7\u6cb8\u77f3\u4e2dXe\u6269\u6563\u8def\u5f84\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u4e94\u3001\u5206\u7ea7\u6cb8\u77f3\u4e2dXe\u4eceSOD\u7b3c\u6269\u6563\u5230\u8d85\u7ea7\u7b3c\u7684\u52bf\u80fd\u5206\u5e03<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u8ff0\u6240\u8ff0\uff0c\u4f5c\u8005\u5229\u75283D-TEM\u548cHP 129<\/sup>Xe NMR\u7814\u7a76\u4e86FAU\u578b\u6cb8\u77f3\u4e2d\u5fae\u5b54\u548c\u4ecb\u5b54\u7684\u6f14\u5316\u3002FAU\u6cb8\u77f3\u4e2d\u4ecb\u5b54\u7684\u5f62\u6210\u662f\u7531\u4e8eNH4<\/sub>F\u523b\u8680\u65e0\u504f\u5730\u53bb\u9664\u9aa8\u67b6T\u539f\u5b50\uff08T=Si\u6216Al\uff09\u6240\u81f4\u3002T\u539f\u5b50\u7684\u53bb\u9664\u4ece\u8d85\u7b3c\u5f00\u59cb\uff0c\u6253\u5f00\u4e00\u4e9bSOD\u7b3c\uff0c\u8fdb\u4e00\u6b65\u5141\u8bb8\u76f8\u90bb\u7b3c\u7684\u8fde\u63a5\u3002\u5229\u7528HP 129<\/sup>Xe NMR\u5149\u8c31\u5bf9FAU\u6cb8\u77f3\u6837\u54c1\u4e2dXe\u7684\u5438\u9644\u548c\u6269\u6563\u8fdb\u884c\u4e86\u7814\u7a76\uff0c\u63ed\u793a\u4e86\u9897\u7c92\u5185\u6269\u6563\u7684\u589e\u52a0\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u7684\u6269\u6563\u9014\u5f84\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u7ed3\u679c\u90fd\u8868\u660e\uff0cXe\u9996\u5148\u6269\u6563\u5230\u5f00\u653e\u7684SOD\u7b3c\u4e2d\uff0c\u7136\u540e\u6269\u6563\u5230FAU\u6cb8\u77f3\u7684\u8d85\u7b3c\u4e2d\u3002\u8fd9\u79cd\u4f18\u8d8a\u7684\u50ac\u5316\u6027\u80fd\u662f\u7531\u4e8e\u65b0\u7684\u6269\u6563\u9014\u5f84\u4f7fFAU\u6cb8\u77f3\u6676\u4f53\u5177\u6709\u66f4\u9ad8\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u66f4\u4f4e\u7684\u4f20\u8f93\u9650\u5236\u7684\u76f4\u63a5\u7ed3\u679c\u3002\u7531\u4e8e\u4e00\u4e9b\u5de5\u4e1a\u4e0a\u76f8\u5173\u7684\u5206\u5b50\u7b5b\u542b\u6709\u7b3c\uff08FAU\u3001CHA\u3001LTA\u3001AEI\uff09\uff0c\u5373\u4f7f\u662f\u5c0f\u5206\u5b50\uff08H2<\/sub>\u3001NH3<\/sub>\u3001CH4<\/sub>\uff09\u4e5f\u5f88\u96be\u63a5\u8fd1\uff0c\u56e0\u6b64\u672c\u6587\u63cf\u8ff0\u7684\u6676\u4f53\u5de5\u7a0b\u53ef\u4ee5\u5728\u50ac\u5316\u3001\u9009\u62e9\u6027\u5438\u9644\u5206\u79bb\u3001\u6355\u83b7\u548c\u50a8\u5b58\u5206\u5b50\u65b9\u9762\u8fdb\u4e00\u6b65\u53d1\u6325\u6f5c\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aUnderstanding the Fundamentals of Microporosity Upgrading in Zeolites: Increasing Diffusion and Catalytic Performances<\/a><\/strong>. Adv. Sci.<\/em>, 2021<\/strong>, DOI: 10.1002\/advs.202100001.<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u6cb8\u77f3\u662f\u4e00\u79cd\u5177\u6709\u72ec\u7279\u9aa8\u67b6\u7ed3\u6784\u548c\u53ef\u8c03\u9178\u6027\u8d28\u7684\u7ed3\u6676\u94dd\u7845\u9178\u76d0\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u50ac\u5316\u3001\u5438\u9644\u548c\u5206\u79bb\u7b49\u9886\u57df\u3002\u5408\u6210\u540e\u9aa8\u67b6\u539f\u5b50\u7684\u53bb\u9664\u548c\u4f34\u968f\u7684\u4ecb\u5b54\u5f62\u6210\uff0c\u5df2\u88ab\u7528\u4e8e\u6539\u5584\u53cd\u5e94\u7269\u548c…<\/p>\n","protected":false},"author":7770,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[3553],"class_list":["post-224685","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-3553"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/224685"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7770"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=224685"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/224685\/revisions"}],"predecessor-version":[{"id":224708,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/224685\/revisions\/224708"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=224685"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=224685"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=224685"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}