{"id":224941,"date":"2021-07-30T06:35:02","date_gmt":"2021-07-29T22:35:02","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=224941"},"modified":"2021-07-29T18:35:17","modified_gmt":"2021-07-29T10:35:17","slug":"%e4%b8%9c%e4%ba%ac%e5%a4%a7%e5%ad%a6nature-catalysis%ef%bc%9a%e9%93%81%e5%82%ac%e5%8c%96%e7%9a%84%e5%8c%ba%e5%9f%9f%e9%80%89%e6%8b%a9%e6%80%a7%e5%99%bb%e5%90%a9c-h-c-h%e5%81%b6%e8%81%94%e5%92%8c","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=224941","title":{"rendered":"\u4e1c\u4eac\u5927\u5b66Nature Catalysis\uff1a\u94c1\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027\u567b\u5429C-H\/C-H\u5076\u8054\u548c\u7f29\u805a\u7528\u4e8e\u6709\u673a\u5c0f\u5206\u5b50\u548c\u805a\u5408\u7269\u534a\u5bfc\u4f53\u5236\u9020"},"content":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1aTakahiro Doba\u200a<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1aRui Shang\uff0cEiichi Nakamura<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u4e1c\u4eac\u5927\u5b66<\/p>\n<p>DOI\uff1ahttps:\/\/doi.org\/10.1038\/s41929-021-00653-7<\/p>\n<p><strong>\u80cc\u666f<\/strong><\/p>\n<p>\u533a\u57df\u9009\u62e9\u6027\u567b\u5429-\u567b\u5429\u5076\u8054\u662f\u6709\u673a\u7535\u5b50\u6750\u6599\u6700\u91cd\u8981\u7684\u8f6c\u53d8\u4e4b\u4e00\u3002\u901a\u8fc7\u5207\u65ad\u4e24\u4e2aC-H\u952e\u6765\u5076\u8054\u4e24\u4e2a\u567b\u5429\u57fa\u7684\u7406\u60f3\u6709\u673a\u5408\u6210\u539f\u578b\u9700\u8981\u7528\u6c27\u5316\u5242\u6b63\u5f0f\u53bb\u9664\u4e24\u4e2a\u6c22\u539f\u5b50\uff0c\u800c\u8fd9\u5f80\u5f80\u9650\u5236\u4e86\u6c27\u5316\u654f\u611f\u5e95\u7269(\u4f8b\u5982\u4f9b\u4f53\u548c\u7a7a\u7a74\u4f20\u8f93\u6750\u6599)\u7684\u5408\u6210\u6548\u7387\u548c\u901a\u7528\u6027\u3002<\/p>\n<p><strong>\u7814\u7a76\u7684\u95ee\u9898<\/strong><\/p>\n<p>\u672c\u6587\u53d1\u73b0\u8349\u9178\u4e8c\u4e59\u916f\u548cAlMe<sub>3<\/sub>\u4e00\u8d77\u5728\u94c1\u50ac\u5316\u7684C-H\u6d3b\u5316\u4e2d\u8d77\u5230\u53cc\u7535\u5b50\u53d7\u4f53\u7684\u4f5c\u7528\u3002\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff0c\u672c\u6587\u63cf\u8ff0\u4e86\u94c1(III)\u50ac\u5316\u5242\u3001\u4e09\u81a6\u914d\u4f53\u3001AlMe<sub>3<\/sub>\u548c\u8349\u9178\u4e8c\u4e59\u916f\u7684\u533a\u57df\u9009\u62e9\u6027\u567b\u5429\u57faC-H\/C-H\u5076\u8054\u53cd\u5e94\u3002\u7531\u914d\u4f53\u4f18\u5316\u52a0\u901f\u7684\u9ad8\u6548\u50ac\u5316\u4f53\u7cfb\u5c06\u542b\u567b\u5429\u7684\u5355\u4f53\u805a\u5408\u6210\u5177\u6709\u591a\u79cd\u7ed9\u7535\u5b50\u03c0\u57fa\u5e8f\u7684\u5747\u805a\u7269\u548c\u5171\u805a\u7269\u3002\u8fd9\u4e00\u53d1\u73b0\u8868\u660e\u94c1\u50ac\u5316\u5242\u5728\u5408\u6210\u529f\u80fd\u805a\u5408\u7269\u65b9\u9762\u7684\u591a\u529f\u80fd\u6027\uff0c\u8fd9\u79cd\u666e\u904d\u5b58\u5728\u7684\u91d1\u5c5e\u7684\u6f5c\u529b\u5230\u76ee\u524d\u4e3a\u6b62\u8fd8\u6ca1\u6709\u5f97\u5230\u5145\u5206\u7684\u8ba4\u8bc6\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-224943\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-1-25.png\" alt=\"\" width=\"435\" height=\"726\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-1-25.png 435w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-1-25-180x300.png 180w\" sizes=\"(max-width: 435px) 100vw, 435px\" \/><\/p>\n<p>\u56fe1|TP\/AlMe<sub>3<\/sub>\/DEO\u4f53\u7cfb\u5b9e\u73b0\u7684\u94c1\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027\u567b\u5429C-H\/C-H\u5076\u8054\u53cd\u5e94\u3002<\/p>\n<p>\u8981\u70b9\uff1a<\/p>\n<ul>\n<li>\u76f4\u63a5C-H\/C-H\u5076\u8054\u8fde\u63a5\u4e24\u4e2a\u6709\u673a\u5206\u5b50\u662f\u4e00\u79cd\u76f4\u63a5\u7684C-C\u6210\u952e\u7b56\u7565\uff0c\u8fd9\u79cd\u7b56\u7565\u5728\u8054\u82b3\u57fa\u5408\u6210\u4e2d\u65e9\u5df2\u4e3a\u4eba\u6240\u77e5\uff0c\u76ee\u524d\u4ecd\u88ab\u7528\u4e8e\u5408\u6210\u6750\u6599\u5e94\u7528\u4e2d\u7684\u7f29\u5408\u82b3\u70c3\u548c\u567b\u5429\u805a\u5408\u7269\u3002\u7136\u800c\uff0c\u901a\u5e38\u9700\u8981\u5f3a\u6c27\u5316\u6761\u4ef6\u624d\u80fd\u6b63\u5f0f\u9664\u53bb\u4e24\u4e2a\u6c22\u539f\u5b50\uff0c\u4ece\u800c\u9650\u5236\u4e86\u5e95\u7269\u7684\u901a\u7528\u6027\u548c\u53cd\u5e94\u9009\u62e9\u6027\u3002\u4f8b\u5982\uff0c\u901a\u8fc7\u9633\u79bb\u5b50\u6216\u81ea\u7531\u57fa\u9633\u79bb\u5b50\u673a\u5236(\u5982Scholl\u53cd\u5e94\u548c\u6c27\u5316\u82b3\u9999\u5076\u8054\u53cd\u5e94)\u8fdb\u884c\u7684\u7ecf\u5178\u53cd\u5e94\u8303\u56f4\u6709\u9650\uff0c\u4f1a\u4ea7\u751f\u5f02\u6784\u4f53\u548c\u4e0d\u9700\u8981\u7684\u526f\u4ea7\u7269(\u56fe1a)\u3002<\/li>\n<li>\u4e3a\u4e86\u66f4\u597d\u7684\u5408\u6210\u8bbe\u8ba1\uff0c\u672c\u6587\u9009\u62e9\u907f\u514d\u6574\u4e2a\u5f3a\u6c27\u5316\u6761\u4ef6\uff0c\u5e76\u4f7f\u7528\u94c1\u50ac\u5316\u7684C-H\u6d3b\u5316\u65b9\u6848\u5b9e\u73b0\u9ad8\u9009\u62e9\u6027(\u56fe1b\uff0cI\u548cII)\u3002\u672c\u6587\u8ba4\u8bc6\u5230\uff0c\u8349\u9178\u4e8c\u4e59\u916f(DEO)\u4f5c\u4e3a\u4e00\u79cd\u6f5c\u5728\u7684\u6c27\u5316\u5242\u4e0eAl(III)\u7269\u79cd\u7ed3\u5408\uff0c\u901a\u8fc7\u63a5\u53d7\u4e24\u4e2a\u7535\u5b50\uff0c\u53ef\u80fd\u901a\u8fc7\u5185\u90e8\u7403\u9762\u7535\u5b50\u8f6c\u79fb(\u56fe1b\uff0cIII)\u5f62\u6210\u4e8c\u5143\u94dd(\u56fe1b\uff0cIV)\uff0c\u4ece\u800c\u518d\u751f\u94c1(III)\u50ac\u5316\u5242\u3002Al(III)\u5f62\u6210\u70ed\u529b\u5b66\u7a33\u5b9a\u7684\u4e94\u5143\u73af\u4e8c\u5143\u94dd(\u56fe1b\uff0cIV)\u7684\u5f3a\u70c8\u4eb2\u6c27\u6027\u662fFe(III)\u518d\u751f\u7684\u9a71\u52a8\u529b\uff0c\u4eb2\u6c27\u94dd(III)\u9694\u79bb\u5242\u8fd8\u539fFe(III)\u4e2d\u7684\u8349\u9178\u4ee5\u786e\u4fdd\u50ac\u5316\u5242\u7684\u6709\u6548\u5faa\u73af\u3002<\/li>\n<li>\u5728\u8fd9\u91cc\uff0c\u672c\u6587\u8bb0\u5f55\u4e86\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff0c\u4f7f\u7528\u94c1(III)\u50ac\u5316\u5242TP\uff0cDEO\u548cAlMe<sub>3<\/sub>\u5bf9C<sub>2<\/sub>\u533a\u57df\u9009\u62e9\u6027\u567b\u5429C-H\/C-H\u5076\u8054\u7684\u50ac\u5316C-H\u6d3b\u5316(\u56fe1b)\u3002\u7531\u65b0\u8bbe\u8ba1\u7684\u914d\u4f53\u52a0\u901f\u7684\u53cd\u5e94\u5df2\u7ecf\u5b9e\u73b0\u4e86\u7528\u4e8e\u7535\u5b50\u5668\u4ef6\u5e94\u7528\u7684\u805a\u5408\u7269\u534a\u5bfc\u4f53\u6750\u6599\u7684\u76f4\u63a5C-H\/C-H\u5076\u8054\u65b9\u6cd5(\u56fe1d)\u3002<\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-224944\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-2-25.png\" alt=\"\" width=\"439\" height=\"839\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-2-25.png 439w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-2-25-157x300.png 157w\" sizes=\"(max-width: 439px) 100vw, 439px\" \/><\/p>\n<p>\u56fe2|\u53cd\u5e94\u53c2\u6570\u3002<\/p>\n<p>\u8981\u70b9\uff1a<\/p>\n<ul>\n<li>\u56fe2\u603b\u7ed3\u4e86\u5173\u952e\u7684\u53cd\u5e94\u53c2\u6570\u548c\u672c\u6587\u7684\u7814\u7a76\uff0c\u4ee5\u786e\u5b9a\u5728AlMe<sub>3<\/sub>\u5b58\u5728\u4e0b\uff0c\u8349\u9178\u4e8c\u4e59\u916f\u662f\u6700\u6709\u6548\u7684\u53cc\u7535\u5b50\u53d7\u4f53\u3002\u56fe2a\u4ee5\u82ef\u5e76[b]\u567b\u5429(<strong><b>1<\/b><\/strong>)\u4e3a\u5e95\u7269\uff0c\u5c55\u793a\u4e86\u94c1(III)\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027\u567b\u5429C-H\/C-H\u5076\u8054\u53cd\u5e94\u7684\u5178\u578b\u4f8b\u5b50\u3002\u572870\u00b0C\u7684\u56db\u6c22\u544b\u5583-\u7532\u82ef\u6df7\u5408\u6eb6\u5242\u4e2d\uff0c\u7528Fe(Acac)<sub>3<\/sub>(10mol%)\u3001AlMe<sub>3<\/sub>(100mol%)\u548cDEO(50mol%)\u5b9a\u91cf\u5f97\u5230C<sub>2<\/sub>\u4e8c\u805a\u4ea7\u7269(<strong><b>2<\/b><\/strong>)\u3002Fe(Acac)<sub>3<\/sub>(10mol%)\u662f\u4e00\u79cd\u5171\u8f6d\u4e09\u9f7f\u81a6\u914d\u4f53(<strong><b>TP2<\/b><\/strong>\uff1b11mol%)\uff0c\u7528\u94c1\u50ac\u5316\u7684C-H\u7532\u57fa\u5316\u7684AlMe<sub>3<\/sub>\u5bfc\u81f4<strong><b>1<\/b><\/strong>\u4e0d\u5b8c\u5168\u8f6c\u5316\u3002<\/li>\n<li>\u5bf9\u7167\u5b9e\u9a8c\u8868\u660e\uff0c\u94c1\u50ac\u5316\u5242\u5bf9C<sub>2<\/sub>-H\u5207\u5272\u662f\u5fc5\u4e0d\u53ef\u5c11\u7684\uff0c\u56e0\u4e3a\u5728\u6ca1\u6709\u94c1\u50ac\u5316\u5242\u7684\u60c5\u51b5\u4e0b\uff0c\u4ec5\u6709AlMe<sub>3<\/sub>\u4e0d\u4f1a\u4ea7\u751fC<sub>2<\/sub>\u91d1\u5c5e\u5316\u4ea7\u7269\u3002\u7528<strong><b>1<\/b><\/strong>\u548c<strong><b>1<\/b><\/strong>-2-d(\u82ef\u5e76[b]\u567b\u5429-2-d)\u5e73\u884c\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u540c\u4f4d\u7d20\u5b9e\u9a8c\u8868\u660e\uff0c\u6ca1\u6709\u4e3b\u8981\u7684\u52a8\u529b\u5b66\u540c\u4f4d\u7d20\u6548\u5e94(K<sub>H<\/sub>\/K<sub>d<\/sub>=1)\uff0c\u8fd9\u8868\u660eC-H\u88c2\u89e3\u4e0d\u662f\u50ac\u5316\u5faa\u73af\u4e2d\u7684\u5468\u8f6c\u9650\u5236\u6b65\u9aa4\u3002\u7528\u82ef\u5e76\u82ef\u4ee3\u66ffDEO\u7684\u53cd\u5e94\u4ea7\u751f\u4e86<strong><b>2<\/b><\/strong>\u548c\u5b89\u606f\u9999(\u56fe2b\u548c\u56fe2c)\uff0c\u4e3a\u70ef\u4e8c\u915aIV\u7684\u5f62\u6210\u63d0\u4f9b\u4e86\u8bc1\u636e\uff0c\u4ece\u800c\u652f\u6301\u4e86DEO\u4f5c\u4e3a\u4e24\u7535\u5b50\u53d7\u4f53\u7684\u63d0\u8bae\u3002\u6c34\u89e3\u540e\u539f\u4f4d\u68c0\u6d4bIV\u6216\u4e59\u919b\u9178\u4e59\u916f\u7684\u5c1d\u8bd5\u5230\u76ee\u524d\u4e3a\u6b62\u90fd\u5931\u8d25\u4e86\uff0c\u53ef\u80fd\u662f\u56e0\u4e3aAl(III)\u57fa\u56e2\u7684\u805a\u96c6\u548c\u9ad8\u4eb2\u6c27\u6027\u3002<\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-224945\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-3-25.png\" alt=\"\" width=\"569\" height=\"863\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-3-25.png 569w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-3-25-198x300.png 198w\" sizes=\"(max-width: 569px) 100vw, 569px\" \/><\/p>\n<p>\u56fe3|\u914d\u4f53\u5bf9\u7f29\u805a\u53cd\u5e94\u5f71\u54cd\u7684\u7814\u7a76\u3002<\/p>\n<p>\u8981\u70b9\uff1a<\/p>\n<ul>\n<li>\u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684C-H\/C-H\u7f29\u805a\u53cd\u5e94\u4e2d\uff0c\u53ea\u6709\u5c11\u6570\u51e0\u4e2a\u7f3a\u7535\u5b50\u805a\u5408\u7269\u7684\u4f8b\u5b50\u88ab\u62a5\u9053\uff0c\u800c\u5bf9\u4e8e\u7535\u5b50\u7ed9\u4f53\u7c7b\u578b\u7684\u534a\u5bfc\u4f53\u805a\u5408\u7269\uff0c\u8fd8\u6ca1\u6709\u88ab\u62a5\u9053\u3002\u4f5c\u4e3a\u57fa\u51c6(\u56fe3a)\uff0c\u672c\u6587\u9009\u62e9\u4e86\u5c062\uff0c7-\u4e8c\u567b\u5429\u5494\u5511(DTC)(<strong><b>3<\/b><\/strong>)\u8f6c\u5316\u4e3a\u7528\u4e8e\u6709\u673a\u8584\u819c\u6676\u4f53\u7ba1\u7684\u567b\u5429-\u5494\u5511\u805a\u5408\u7269(<strong><b>4<\/b><\/strong>)\u3002<\/li>\n<li>\u56fe3\u603b\u7ed3\u4e86DTC\u805a\u5408\u7269\u5408\u6210\u7684\u7814\u7a76\uff0c\u5728\u7ed3\u6784\u548c\u7535\u5b50\u8c03\u8c10(\u56fe3c)\u4e4b\u540e\uff0c\u6700\u7ec8\u5c06<strong><b>TP1<\/b><\/strong>\u8bbe\u8ba1\u4e3a\u672c\u7814\u7a76\u7684\u5173\u952e\u4f7f\u80fd\u5668(\u89c1\u56fe1c)\u3002<\/li>\n<li>\u52a8\u529b\u5b66\u5b9e\u9a8c\u8868\u660e\uff0c\u7f29\u805a\u53cd\u5e94\u7b26\u5408\u9636\u8dc3\u589e\u957f\u673a\u7406\u3002\u56fe3c\u663e\u793a\u4e86\u5728\u805a\u5408\u7269<strong><b>5<\/b><\/strong>(<strong><b>F8T2<\/b><\/strong>\u805a\u5408\u7269\uff1b\u56fe5)\u7684\u5408\u6210\u4e2d\uff0c\u4f5c\u4e3a\u5355\u4f53\u8f6c\u5316\u7387\u7684\u51fd\u6570\u7684Mn\u548cPDI\u503c\u4e4b\u95f4\u7684\u76f8\u5173\u6027\u3002\u5728\u8fd9\u91cc\uff0c\u672c\u6587\u6ce8\u610f\u5230\u5728\u5355\u4f53\u8f6c\u5316\u7387\u8f83\u9ad8\u65f6\uff0cMn\u503c\u6025\u5267\u589e\u52a0\uff0c\u800cPDI\u503c\u7f13\u6162\u63a5\u8fd12\uff0c\u8fd9\u662f\u9636\u8dc3\u589e\u957f\u7f29\u805a\u53cd\u5e94\u7684\u5178\u578b\u503c\u3002<\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-224946\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-4-24.png\" alt=\"\" width=\"600\" height=\"610\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-4-24.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-4-24-295x300.png 295w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe4|\u94c1\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027\u567b\u5429\u57faC-H\/C-H\u540c\u4f4d\u5076\u8054\u7684\u8303\u56f4\u3002<\/p>\n<p>\u8981\u70b9\uff1a<\/p>\n<ul>\n<li>\u56fe4\u8bf4\u660e\u4e86\u567b\u5429\u57faC-H\/C-H\u5076\u8054\u7684\u8303\u56f4\u3002\u8be5\u53cd\u5e94\u5bf9\u567b\u5429\u73af\u8868\u73b0\u51fa\u72ec\u6709\u7684C<sub>2<\/sub>(\u6216C<sub>5<\/sub>)\u9009\u62e9\u6027\uff0c\u5e76\u4ee5\u8f83\u9ad8\u7684\u4ea7\u7387\u5f97\u5230\u4e86\u82ef\u5e76[b]\u567b\u5429(<strong><b>2<\/b><\/strong>)\u3001\u567b\u5429(<strong><b>6<\/b><\/strong>\u548c<strong><b>7<\/b><\/strong>)\u548c\u82ef\u5e76[1\uff0c2-b\uff1a4\uff0c5-b\u2018]\u4e8c\u567b\u5429(11)\u7684\u4e8c\u805a\u4f53\u3002\u51e0\u4e4e\u6ca1\u6709\u53d1\u751fC<sub>2<\/sub>\u7532\u57fa\u5316 (\u4ec5\u68c0\u6d4b\u523018-20\u6b21\uff0c\u4ea7\u7387\u5c0f\u4e8e1%)\u3002<\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-224947\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-5-20.png\" alt=\"\" width=\"600\" height=\"751\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-5-20.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-5-20-240x300.png 240w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe5|\u94c1\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027\u567b\u5429C-H\/C-H\u7f29\u805a\u7684\u8303\u56f4\u3002<\/p>\n<p><strong>\u7ed3\u8bed<\/strong><\/p>\n<p>\u4e0a\u8ff0\u5de5\u4f5c\u5f3a\u8c03\u4e86\u5408\u4f5c\u4f7f\u7528\u4e24\u79cd\u5bcc\u542b\u7a00\u571f\u7684\u91d1\u5c5e(\u5373\u94c1\u548c\u94dd)\u6765\u5408\u6210\u6709\u673a\u7535\u5b50\u5668\u4ef6\u5e94\u7528\u4e2d\u91cd\u8981\u7684\u03c0\u5171\u8f6d\u5c0f\u5206\u5b50\u548c\u5927\u5206\u5b50\u7684\u597d\u5904\u3002\u672c\u6587\u8ba4\u4e3a\uff0cTP\u914d\u4f53\u548cDEO\/Al(III)\u7ec4\u5408\u4e2d\u7684\u7ed3\u6784\u548c\u7535\u5b50\u5143\u7d20\u5728\u63a7\u5236\u6709\u673a\u94c1\u4e2d\u95f4\u4f53\u7684\u4ef7\u6001\u548c\u81ea\u65cb\u6001\u65b9\u9762\u53d6\u5f97\u4e86\u5f88\u597d\u7684\u5e73\u8861\u3002C-H\/C-H\u7f29\u805a\u662f\u5bf9\u805a\u5408\u7269\u5408\u6210\u4e2d\u6709\u9650\u7684\u6709\u673a\u94c1\u50ac\u5316\u4f53\u7cfb\u7684\u8865\u5145\uff0c\u5c06\u6210\u4e3a\u8fdb\u4e00\u6b65\u5f00\u53d1\u5b9e\u7528\u94c1\u50ac\u5316\u7684\u4f8b\u5b50\u3002<\/p>\n<p><strong>\u56e2\u961f\u4ecb\u7ecd<\/strong><\/p>\n<p>\u6771\u4eac\u5927\u5b66\u9769\u65b0\u5206\u5b50\u6280\u672f\u8bb2\u5ea7\u4e2d\u6751\u7814\u7a76\u5ba4<\/p>\n<p>\u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u5de5\u4f5c\u6c47\u603b\u4ee5\u53ca\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350\uff1a<\/p>\n<p>1. Iron-Catalyzed Tandem Cyclization of Diarylacetylene to a Strained 1,4-Dihydropentalene Framework for Narrow-Band-Gap Materials<\/p>\n<p>Chen, M.; Sato, W.; Shang, R.*;\u00a0Nakamura,\u00a0E.* <em><i>J. Am. <\/i><\/em><em><i>Chem. Soc. <\/i><\/em><strong><b>20<\/b><\/strong><strong><b>21<\/b><\/strong>,\u00a0<em><i>1<\/i><\/em><em><i>43, <\/i><\/em>6823\u20136828.<\/p>\n<p>2. Chromium(III)-catalyzed C(sp<sup>2<\/sup>)-H Alkynylation and Allylation of Secondary Amides with Trimethylaluminum as Base<b><\/b><\/p>\n<p>Chen, M.; Doba, T.; Sato, T.;\u00a0Ilies, L.;\u00a0Shang, R.*;\u00a0Nakamura,\u00a0E.*\u00a0<em><i>J. Am. Chem. Soc.<\/i><\/em><strong><b>\u00a0<\/b><\/strong><strong><b>20<\/b><\/strong><strong><b>20<\/b><\/strong>, <em><i>142, <\/i><\/em>4883\u20134891<em><i>.<\/i><\/em><\/p>\n<p>3. Homocoupling-free Iron-catalyzed Twofold C\u2013H Activation\/cross-couplingsof Aromatics via Transient Connection of Reactants<\/p>\n<p>Doba, T.;\u00a0Matsubara, T.;\u00a0Ilies, L.;\u00a0Shang, R.*;\u00a0Nakamura,\u00a0E.*\u00a0<em><i>Nat. Catal. <\/i><\/em><strong><b>2019<\/b><\/strong>, <em><i>2, <\/i><\/em>400\u2013406.<\/p>\n<p>4. Iron-Catalyzed C\u2013H Bond Activation<\/p>\n<p>Shang, R.; Ilies, L.*;\u00a0Nakamura, E.*\u00a0<em><i>Chem. Rev.<\/i><\/em>\u00a0<strong><b>2017<\/b><\/strong><em><i>, 117, <\/i><\/em>9086\u20139139<em><i>.<\/i><\/em><\/p>\n<p>5. Iron-catalyzed ortho C\u2013H Methylationof Aromatics Bearing a Simple Carbonyl Group with Methylaluminum and Tridentate Phosphine Ligand<\/p>\n<p>Shang, R.; Ilies, L.*;\u00a0Nakamura, E.*\u00a0<em><i>J. Am. <\/i><\/em><em><i>Chem. Soc. <\/i><\/em><strong><b>201<\/b><\/strong><strong><b>6<\/b><\/strong>, <em><i>138, <\/i><\/em>10132\u201310135<em><i>.<\/i><\/em><\/p>\n<p>6. Iron-catalyzed Directed C(sp<sup>2<\/sup>)\u2013H and C(sp<sup>3<\/sup>)\u2013H Functionalization with Trimethylaluminium<\/p>\n<p>Shang, R.; Ilies, L.*; Nakamura, E.*<em><i>\u00a0J. Am. <\/i><\/em><em><i>Chem. Soc. <\/i><\/em><strong><b>201<\/b><\/strong><strong><b>5<\/b><\/strong>, <em><i>137, <\/i><\/em>7660\u20137663<em><i>.<\/i><\/em><\/p>\n<p>7. Iron-catalyzed C (sp<sup>2<\/sup>)\u2013H Bond Functionalization with Organoboron Compounds<\/p>\n<p>Shang, R.; Ilies, L.*; Sobi, A.; Nakamura, E.*<em><i>\u00a0J. Am. <\/i><\/em><em><i>Chem. Soc. <\/i><\/em><strong><b>201<\/b><\/strong><strong><b>4<\/b><\/strong>, <em><i>136, <\/i><\/em>14349\u201314352<em><i>.<\/i><\/em><\/p>\n<p>8. \u03b2-Arylation of carboxamides via iron-catalyzed C (sp<sup>3<\/sup>)\u2013H bond activation<\/p>\n<p>Shang, R.; Ilies, L.; Matsumoto, A.; Nakamura, E.*; <em><i>J. Am. Chem. Soc. <\/i><\/em><strong><b>2013<\/b><\/strong>, <em><i>135<\/i><\/em>, 6030\u20136032<em><i>.<\/i><\/em><\/p>\n<p>\u672c\u6587\u7531SSC\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1aTakahiro Doba\u200a \u901a\u8baf\u4f5c\u8005\uff1aRui Shang\uff0cEiichi Nakamura \u901a\u8baf\u5355\u4f4d\uff1a\u4e1c\u4eac\u5927\u5b66 DOI\uff1ahttps:\/\/doi.org&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-224941","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/224941"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=224941"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/224941\/revisions"}],"predecessor-version":[{"id":225235,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/224941\/revisions\/225235"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=224941"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=224941"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=224941"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}