{"id":225141,"date":"2021-07-28T06:30:24","date_gmt":"2021-07-27T22:30:24","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=225141"},"modified":"2021-07-27T11:07:58","modified_gmt":"2021-07-27T03:07:58","slug":"advanced-optical-materials-%e7%bc%ba%e9%99%b7%e8%af%b1%e5%af%bcmn4%e8%87%aa%e8%bf%98%e5%8e%9f%e5%8f%91%e5%85%89%e5%92%8c%e6%8a%97%e7%83%ad%e7%8c%9d%e7%81%ad","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=225141","title":{"rendered":"Advanced Optical Materials: \u7f3a\u9677\u8bf1\u5bfcMn4+\u81ea\u8fd8\u539f\u53d1\u5149\u548c\u6297\u70ed\u731d\u706d"},"content":{"rendered":"<p>\u521b\u65b0\u70b9\uff1a<\/p>\n<p>\u5357\u5f00\u5927\u5b66\u6b66\u8389\u3001\u5f20\u6bc5\u6559\u6388\u4e0e\u534e\u5357\u7406\u5de5\u5927\u5b66\u590f\u5fd7\u56fd\u6559\u6388\u5408\u4f5c\uff0c\u53d1\u73b0\u5728\u5177\u6709\u7c7b\u9499\u949b\u77ff\u7ed3\u6784\u7684\u65e0\u673a\u5316\u5408\u7269NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>\u4e2d\u7531\u4e8e\u7f3a\u9677\u8bf1\u5bfc\uff0c\u63ba\u5165\u7684\u9530\u79bb\u5b50\u81ea\u53d1\u7531+4\u8fd8\u539f\u4e3a+2\uff0c\u5408\u6210\u7684\u53d1\u5149\u6750\u6599\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6297\u70ed\u731d\u706d\u7279\u6027\u3002<\/p>\n<p>\u5173\u952e\u8bcd\uff1a<\/p>\n<p>\u53d1\u5149\u6750\u6599\uff0c\u7f3a\u9677\u8bf1\u5bfc\uff0c\u81ea\u8fd8\u539f\uff0c\u6297\u70ed\u731d\u706d<\/p>\n<p>\u76ee\u524d\u56fa\u6001\u7167\u660e\u4e0e\u663e\u793a\u7b49\u4e3b\u8981\u662f\u901a\u8fc7LED\u82af\u7247\u6d82\u8986\u53d1\u5149\u6750\u6599\u5b9e\u73b0\uff0c\u56e0\u6b64\uff0c\u53d1\u5149\u6750\u6599\u5728\u7167\u660e\u3001\u663e\u793a\u7b49\u9886\u57df\u5177\u6709\u65e0\u53ef\u66ff\u4ee3\u7684\u4f5c\u7528\u3002\u968f\u7740\u5de5\u4f5c\u65f6\u95f4\u5ef6\u957f\uff0c\u56fa\u6001\u82af\u7247\u5c06\u51fa\u73b0\u53d1\u70ed\u73b0\u8c61\uff0c\u8fd9\u5c06\u5bfc\u81f4\u6d82\u8986\u5728\u82af\u7247\u4e0a\u7684\u8367\u5149\u7c89\u6750\u6599\u56e0\u53d7\u70ed\u800c\u51fa\u73b0\u591a\u65b9\u9762\u7684\u6027\u80fd\u53d8\u5316\u3002\u524d\u671f\u7684\u7814\u7a76\u4e2d\uff0c\u5357\u5f00\u5927\u5b66\u6b66\u8389\u3001\u5f20\u6bc5\u6559\u6388\u7814\u7a76\u7ec4\u5bf9\u56e0\u82af\u7247\u6e29\u5ea6\u5347\u9ad8\u5bfc\u81f4\u53d1\u5149\u6750\u6599\u7684\u57fa\u8d28\u5316\u5408\u7269\u6750\u6599\u51fa\u73b0\u76f8\u53d8\u7684\u95ee\u9898\u8fdb\u884c\u6df1\u5165\u7814\u7a76\u3002\u4ed6\u4eec\u53d1\u73b0NaSrBO<sub>3<\/sub>\u5728120<sup>0<\/sup>C\u65f6\u53d1\u751f\u76f8\u53d8\uff0c\u800c\u4e14\u9ad8\u6e29\u76f8\u7684\u53d1\u5149\u6027\u80fd\u663e\u8457\u4f18\u4e8e\u4f4e\u6e29\u76f8\u3002\u7531\u4e8e\u76f8\u53d8\u524d\u540e\u6676\u4f53\u7ed3\u6784\u7684\u53d8\u5316\uff0c\u5c06\u4f7f\u5f97\u6d82\u8986\u5728\u82af\u7247\u4e0a\u7684\u53d1\u5149\u6750\u6599\u65e0\u6cd5\u7262\u56fa\u7c98\u8986\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\uff0c\u540c\u65f6\u4e5f\u4e3a\u4e86\u5229\u7528\u9ad8\u6e29\u76f8\u4e3a\u57fa\u8d28\u5236\u5907\u53d1\u5149\u6750\u6599\u7684\u4f18\u5f02\u6027\u80fd\uff0c\u4ed6\u4eec\u901a\u8fc7\u5c11\u91cf\u63ba\u5165\u78b1\u91d1\u5c5e\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u9ad8\u6e29\u76f8\u5728\u5ba4\u6e29\u65f6\u7a33\u5b9a\u5b58\u5728\uff0c\u65e2\u907f\u514d\u4e86\u56e0\u9ad8\u6e29\u76f8\u53d8\u5bfc\u81f4\u5236\u5907\u7684\u5149\u7535\u5668\u4ef6\u5931\u6548\uff0c\u540c\u65f6\u4e5f\u83b7\u5f97\u4e86\u53d1\u5149\u6027\u80fd\u4f18\u5f02\u7684\u84dd\u8272\u53d1\u5149\u6750\u6599\uff08Yi. H. et al., Inorg. Chem. 55 (2016) 6487\uff09\u3002\u4f46\u662f\uff0c\u56e0\u82af\u7247\u5de5\u4f5c\u51fa\u73b0\u7684\u7ed3\u533a\u6e29\u5ea6\u4e0a\u5347\u5bfc\u81f4\u7684\u53d1\u5149\u6027\u80fd\u52a3\u5316\u7684\u95ee\u9898\uff0c\u7279\u522b\u662f\u5bf9\u4e8e\u4e00\u4e9b\u6fc0\u6d3b\u79bb\u5b50\u662f\u4f4e\u4ef7\u6001\u7684\u79bb\u5b50\uff0c\u5982Eu<sup>2+<\/sup>\u548cMn<sup>2+<\/sup>\u7b49\uff0c\u5728\u6e29\u5ea6\u4e0a\u5347\u65f6\u4f4e\u4ef7\u6001\u6fc0\u6d3b\u79bb\u5b50\u88ab\u6c27\u5316\u4e3a\u9ad8\u4ef7\u6001\u79bb\u5b50\uff0c\u4f7f\u5f97\u53d1\u5149\u6750\u6599\u6027\u80fd\u51fa\u73b0\u4e0d\u53ef\u9006\u8f6c\u7684\u52a3\u5316\u3002\u5982\u4f55\u4fdd\u969c\u53d1\u5149\u6750\u6599\u5728\u9ad8\u6e29\u4e0b\u65e2\u5177\u6709\u826f\u597d\u7684\u53d1\u5149\u5f3a\u5ea6\uff0c\u53c8\u80fd\u4fdd\u6301\u826f\u597d\u7684\u8272\u5ea6\u5750\u6807\u7a33\u5b9a\u6027\uff0c\u5373\u53d1\u5149\u6750\u6599\u5177\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u662f\u6ee1\u8db3\u56fa\u6001\u7167\u660e\u548c\u663e\u793a\u7b49\u5668\u4ef6\u6027\u80fd\u7684\u4e00\u4e2a\u91cd\u8981\u4fdd\u969c\u3002<\/p>\n<p>\u6700\u8fd1\uff0c\u5357\u5f00\u5927\u5b66\u7269\u7406\u79d1\u5b66\u5b66\u9662\u7684\u6b66\u8389\u6559\u6388\u3001\u5b54\u52c7\u53d1\u6559\u6388\u3001\u8bb8\u4eac\u519b\u6559\u6388\u3001\u7535\u5b50\u4fe1\u606f\u4e0e\u5149\u5b66\u5de5\u7a0b\u5b66\u9662\u5f20\u6bc5\u6559\u6388\u53ca\u534e\u5357\u7406\u5de5\u5927\u5b66\u590f\u5fd7\u56fd\u6559\u6388\u7b49\u901a\u529b\u5408\u4f5c\uff0c\u5728\u5177\u6709\u9ad8\u70ed\u7a33\u5b9a\u6027\u4e0e\u6297\u70ed\u731d\u706d\u53d1\u5149\u6750\u6599\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\u3002\u4ed6\u4eec\u901a\u8fc7\u9009\u62e9\u5728\u7ed3\u6784\u4e0a\u5177\u6709\u521a\u6027\u7f51\u72b6\u9aa8\u67b6\u7684\u7c7b\u9499\u949b\u77ff\u7ed3\u6784\u5316\u5408\u7269NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>\u4e3a\u57fa\u8d28\u6750\u6599\uff0c\u901a\u8fc7\u63ba\u5165Mn<sup>4+<\/sup>\uff0c\u5728\u7a7a\u6c14\u4e2d\u70e7\u7ed3\uff0c\u4e0d\u4ec5\u5b9e\u73b0\u4e86\u9530\u79bb\u5b50\u4ece+4\u4ef7\u5230+2\u4ef7\u7684\u81ea\u8fd8\u539f\uff0c\u800c\u4e14\u83b7\u5f97\u4e86\u5177\u6709\u4f18\u5f02\u6297\u70ed\u731d\u706d\u6027\u80fd\u7684\u53d1\u5149\u6750\u6599\u3002\u76f8\u5173\u7ed3\u679c\u8fd1\u671f\u53d1\u8868\u5728Advanced. Optical Materials\u4e0a\uff08DOI: 10.1002\/adom.202100870\uff09\u3002<\/p>\n<p>\u201c\u81ea\u8fd8\u539f\u201d\u662f\u63ba\u5165\u57fa\u8d28\u7684\u9ad8\u4ef7\u6001\u6fc0\u6d3b\u79bb\u5b50\u5728\u6ca1\u6709\u8fd8\u539f\u6027\u6c14\u6c1b\u4e0b\u88ab\u8fd8\u539f\u4e3a\u4f4e\u4ef7\u6001\u7684\u79bb\u5b50\u3002\u8be5\u7814\u7a76\u56e2\u961f\u9009\u62e9\u5177\u6709\u521a\u6027\u7f51\u72b6\u7c7b\u9499\u949b\u77ff\u7ed3\u6784\u5316\u5408\u7269NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>\u4e3a\u57fa\u8d28\uff0c\u5728\u5176\u4e2d\u63ba\u5165MnO<sub>2<\/sub>\uff0c\u7a7a\u6c14\u4e2d\u70e7\u7ed3\u540e\u5236\u5907\u51fa\u7684\u53d1\u5149\u6750\u6599\u5b8c\u5168\u8868\u73b0\u4e3aMn<sup>2+<\/sup>\u7684\u53d1\u5149\u6027\u8d28\uff0cEPR\u68c0\u6d4b\u7ed3\u679c\u8868\u660e\u6240\u5236\u5907\u53d1\u5149\u6750\u6599\u4e2d\u7684\u63ba\u5165\u79bb\u5b50\u4e3aMn<sup>2+<\/sup>\uff08\u56fe1\uff09\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u786e\u5b9a\u7a7a\u6c14\u4e2d\u70e7\u7ed3\u540e\u751f\u6210\u7684\u662fMn<sup>2+<\/sup>\uff0c\u7528\u540c\u6b65\u8f90\u5c04X-\u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u7ed3\u6784\uff08XANES\uff09\u8c31\u548c\u6269\u5c55X-\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\uff08EXAFS\uff09\u8c31\u5bf9\u6837\u54c1\u8fdb\u884c\u5206\u6790\uff0c\u786e\u5b9a\u5408\u6210\u7684\u6837\u54c1\u4e2d\u662fMn<sup>2+<\/sup>\uff0c\u4e14\u5904\u4e8e\u516d\u914d\u4f4d\u6676\u573a\u73af\u5883\uff0c\u8fd9\u4e0eXRD\u7ed3\u6784\u7cbe\u4fee\u7ed3\u679cMn<sup>2+<\/sup>\u5360Zn<sup>2+<\/sup>\u4f4d\u76f8\u543b\u5408\u3002\u70ed\u91ca\u5149\u6d4b\u91cf\u8868\u660e\u6837\u54c1\u4e2d\u7684\u7f3a\u9677\u80fd\u7ea7\u6df1\u5ea6\u4e3a1.75eV\uff0c\u8be5\u6df1\u80fd\u7ea7\u7f3a\u9677\u4e3aZn\u9633\u79bb\u5b50\u7a7a\u4f4d\u7f3a\u9677\uff0c\u8bf1\u5bfc\u63ba\u5165\u7684Mn<sup>4+<\/sup>\u88ab\u8fd8\u539f\u4e3aMn<sup>2+<\/sup>\u79bb\u5b50\uff08\u56fe2\uff09\u3002\u7b2c\u4e00\u6027\u539f\u7406\u53ca\u7b2c\u4e00\u6027\u5206\u5b50\u52a8\u529b\u5b66\u8ba1\u7b97\u8868\u660e\u5728\u8be5\u4f53\u7cfb\u4e2d\uff0c\u9ad8\u6e29\u4e0d\u4ec5\u6ca1\u6709\u5bfc\u81f4Mn<sup>2+<\/sup>\u79bb\u5b50\u88ab\u6c27\u5316\uff0c\u53cd\u800c\u4fc3\u8fdb\u4e86Mn<sup>2+<\/sup>\u7684\u7a33\u5b9a\uff0c\u9a8c\u8bc1\u4e86\u6df1\u80fd\u7ea7\u7f3a\u9677\u8bf1\u5bfc\u63ba\u5165\u7684Mn<sup>4+<\/sup>\u88ab\u8fd8\u539f\u4e3aMn<sup>2+<\/sup>\u79bb\u5b50\u8fd9\u4e00\u79d1\u5b66\u601d\u60f3\uff08\u56fe3\uff09\u3002\u968f\u540e\uff0c\u5bf9\u8367\u5149\u7c89\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u53d1\u5149\u6027\u80fd\u8fdb\u884c\u68c0\u6d4b\uff0c\u53d1\u73b0\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u53d1\u5149\u6750\u6599\u7684\u53d1\u5149\u5f3a\u5ea6\u4e0d\u4ec5\u6ca1\u6709\u4e0b\u964d\uff0c\u53cd\u800c\u51fa\u73b0\u4e0a\u5347\uff0c\u5f53\u6e29\u5ea6\u4e3a250<sup>o<\/sup>C\u65f6\uff0c\u5176\u53d1\u5149\u5f3a\u5ea6\u662f\u5ba4\u6e29\u65f6\u76841.2\u500d\u3002\u5728\u9530\u79bb\u5b50\u7531\u56db\u4ef7\u5411\u4e8c\u4ef7\u8f6c\u5316\u7684\u8fc7\u7a0b\u4e2d\uff0c\u4f34\u968f\u7740\u5728\u6676\u683c\u4e2d\u5f62\u6210\u4e86\u5927\u91cf\u7f3a\u9677\uff0c\u8fd9\u4e9b\u7f3a\u9677\u4e0d\u4ec5\u8f85\u52a9\u4e86\u81ea\u8fd8\u539f\u7684\u8fc7\u7a0b\uff0c\u540c\u65f6\u5728\u7981\u5e26\u4e2d\u5f62\u6210\u4e86\u7f3a\u9677\u80fd\u7ea7\uff0c\u4f1a\u968f\u6e29\u5ea6\u5347\u9ad8\u91ca\u653e\u4fd8\u83b7\u7684\u8f7d\u6d41\u5b50\uff0c\u4f7f\u6750\u6599\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6297\u70ed\u731d\u706d\u7279\u6027\uff08\u56fe4\uff09\u3002<\/p>\n<p>\u8be5\u5de5\u4f5c\u4e0d\u4ec5\u7b80\u5316\u4e86\u4f4e\u4ef7\u6001\u53d1\u5149\u79bb\u5b50\u7684\u5236\u5907\u5de5\u827a\uff0c\u66f4\u91cd\u8981\u7684\u662f\u80fd\u591f\u4fdd\u8bc1\u53d1\u5149\u6750\u6599\u5728\u9ad8\u6e29\u4e0b\u6fc0\u6d3b\u79bb\u5b50\u4e0d\u88ab\u6c27\u5316\uff0c\u4ecd\u7136\u5177\u6709\u4e0e\u5ba4\u6e29\u65f6\u76f8\u540c\u7684\u4f18\u5f02\u6027\u80fd\uff0c\u800c\u4e14\u7531\u4e8e\u81ea\u8fd8\u539f\u4e2d\u5f15\u5165\u7684\u5927\u91cf\u6df1\u80fd\u7ea7\u7f3a\u9677\u4f7f\u5f97\u53d1\u5149\u6750\u6599\u5177\u6709\u826f\u597d\u7684\u6297\u70ed\u731d\u706d\u6027\u80fd\uff0c\u4e3a\u89e3\u51b3\u56e0\u82af\u7247\u6e29\u5ea6\u4e0a\u5347\u5bfc\u81f4\u53d1\u5149\u6750\u6599\u6027\u80fd\u52a3\u5316\u8fd9\u4e00\u96be\u9898\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5168\u65b0\u7684\u601d\u8def\u3002\u76f8\u5173\u7ed3\u679c\u4ee5\u201cDefect-induced Self-reduction and Antithermal Quenching in NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:Mn<sup>2+ <\/sup>Red Phosphor\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Optical Materials\uff08DOI: 10.1002\/adom.202100870\uff09\u4e0a\u3002\u6b66\u8389\u6559\u6388\u3001\u590f\u5fd7\u56fd\u6559\u6388\u548c\u5f20\u6bc5\u6559\u6388\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002\u8be5\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u3001\u5929\u6d25\u5e02\u79d1\u6280\u5c40\u7684\u8d44\u52a9\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-225142\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-1-31.png\" alt=\"\" width=\"600\" height=\"305\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-1-31.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-1-31-300x153.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe1. (a) NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\u3002(b) NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>\u7c7b\u9499\u949b\u77ff\u7ed3\u6784\u6f14\u5316\u793a\u610f\u56fe \uff0c\u5176\u4e2d\u4e0eNa3\u76f8\u8fde\u7684PO<sub>4<\/sub>\u57fa\u56e2\u7528\u7ea2\u8272\u6807\u8bc6\u3002(c) NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:0.12Mn<sup>2+<\/sup>\u53d1\u5149\u6750\u6599\u5ba4\u6e29\u4e0b\u7684PL\u8c31\u548cPLE\u8c31\uff0c\u63d2\u5165\u56fe\u662f\u7d2b\u5916\u5149\u6fc0\u53d1\u4e0b\u53d1\u5149\u6750\u6599\u7684\u7167\u7247\u3002(d) \u53d1\u5c04\u8c31\u7684\u5206\u5cf0\u62df\u5408\u8c31\u56fe\uff0c\u7ed3\u679c\u663e\u793a\u662f\u4e24\u4e2a\u53d1\u5c04\u4e2d\u5fc3\u3002(e) NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:0.001Mn<sup>2+<\/sup>\u7684EPR\u8c31\uff0c\u63d2\u5165\u56fe\u662f\u5176\u516d\u6307\u5cf0\u7684\u653e\u5927\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-225143\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-2-30.png\" alt=\"\" width=\"600\" height=\"515\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-2-30.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-2-30-300x258.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe2. (a) NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:0.12Mn<sup>2+<\/sup>\u6837\u54c1\u7684Rietveld\u7ed3\u6784\u7cbe\u4fee\u7ed3\u679c\u3002(b) NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:0.12Mn<sup>2+<\/sup>\u6837\u54c1\u4e2dMn\u7684X-\u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u7ed3\u6784\uff08XANES\uff09\u8c31\u3002(c) \u6269\u5c55X-\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\uff08EXAFS\uff09\u8c31\u548cNaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:0.12Mn<sup>2+<\/sup>\u6837\u54c1\u4e2d\u6700\u8fd1\u90bb\u7684Mn-O\u914d\u4f4d\u62df\u5408\u7ed3\u679c\u3002(d) \u6837\u54c1\u5408\u6210\u7684\u539f\u4f4d\u53d8\u6e29X-\u5c04\u7ebf\u884d\u5c04\u8c31\u3002(e) NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:0.12Mn<sup>2+<\/sup>\u6837\u54c1\u7684SEM\u3001mapping\u56fe\u4ee5\u53caEDS\u8c31\u3002(f) NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:0.12Mn<sup>2+<\/sup>\u6837\u54c1\u4e0d\u540c\u52a0\u70ed\u901f\u5ea6\u4e0b\u7684\u70ed\u91ca\u5149\u8c31\uff0c\u63d2\u5165\u56fe\u662fHoogenstraaten\u56fe\uff0c\u62df\u5408\u83b7\u5f97\u9677\u9631\u80fd\u91cf\u4e3a1.751eV\u3002(g) Mn<sup>4+<\/sup>\u5230Mn<sup>2+<\/sup>\u7684\u81ea\u8fd8\u539f\u793a\u610f\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-225144\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-3-31.png\" alt=\"\" width=\"600\" height=\"406\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-3-31.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-3-31-300x203.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe3. \u5bc6\u5ea6\u6cdb\u51fd\uff08DFT\uff09\u8ba1\u7b97\u7ed3\u679c\u3002(a) NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>\u3001NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:Mn+V<sub>Zn<\/sub>\u548cNaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:Mn\u7684\u80fd\u5e26\u7ed3\u6784\u3002(b) \u57fa\u8d28\u6750\u6599\u548c\u5177\u6709Zn\u7a7a\u4f4d\u7684\u63ba\u6742\u6837\u54c1\u7684\u7535\u5b50\u6001\u5bc6\u5ea6\uff08DOS\uff09\u56fe\u3002(c) NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>\u3001NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:Mn+V<sub>Zn<\/sub>\u548cNaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:Mn\u5206\u6ce2\u6001\u5bc6\u5ea6\uff08PDOS\uff09\u56fe\u3002(d) NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>\u548cNaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:Mn+V<sub>Zn<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\u548c\u4e8c\u7ef4\u7535\u8377\u5bc6\u5ea6\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-225145\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-4-29.png\" alt=\"\" width=\"600\" height=\"501\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-4-29.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-4-29-300x251.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe4. (a) \u7a7a\u6c14\u4e2d\u70e7\u7ed3\u5236\u5907\u7684NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:0.12Mn<sup>2+<\/sup>\u6837\u54c1\u7684\u53d8\u6e29PL\u8c31\uff08\u03bbex=360 nm\uff09\u3002(b) \u8fd8\u539f\u540eNaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:0.12Mn<sup>2+<\/sup>\u6837\u54c1\u7684\u53d8\u6e29PL\u8c31\uff08\u03bbex=360 nm\uff09\u3002(c) \u53d1\u5149\u5f3a\u5ea6\u4e0e\u6e29\u5ea6\u5173\u7cfb\u56fe\u3002(a)\u548c(b)\u56fe\u4e2d\u7684\u63d2\u5165\u56fe\u662f\u76f8\u5e94\u7684\u4e0d\u540c\u6e29\u5ea6\u4e0bMn<sup>2+<\/sup>\u7684\u53d1\u5c04\u5cf0\u5f52\u4e00\u5316\u56fe\u3002(d) NaZn(PO<sub>3<\/sub>)<sub>3<\/sub>:0.12Mn<sup>2+<\/sup>\u6837\u54c1\u6297\u70ed\u6dec\u706d\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n<p>\u76f8\u5173\u6587\u7ae0\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1002\/adom.202100870<\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u521b\u65b0\u70b9\uff1a \u5357\u5f00\u5927\u5b66\u6b66\u8389\u3001\u5f20\u6bc5\u6559\u6388\u4e0e\u534e\u5357\u7406\u5de5\u5927\u5b66\u590f\u5fd7\u56fd\u6559\u6388\u5408\u4f5c\uff0c\u53d1\u73b0\u5728\u5177\u6709\u7c7b\u9499\u949b\u77ff\u7ed3\u6784\u7684\u65e0\u673a\u5316\u5408\u7269NaZn(PO3)3\u4e2d\u7531\u4e8e\u7f3a\u9677\u8bf1\u5bfc\uff0c\u63ba\u5165\u7684\u9530\u79bb\u5b50\u81ea\u53d1\u7531+4\u8fd8\u539f\u4e3a&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-225141","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/225141"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=225141"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/225141\/revisions"}],"predecessor-version":[{"id":225146,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/225141\/revisions\/225146"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=225141"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=225141"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=225141"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}