{"id":225921,"date":"2021-08-12T06:30:19","date_gmt":"2021-08-11T22:30:19","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=225921"},"modified":"2021-08-11T18:46:02","modified_gmt":"2021-08-11T10:46:02","slug":"%e6%b5%8e%e5%8d%97%e5%a4%a7%e5%ad%a6%e5%88%98%e5%ae%8f%e6%95%99%e6%8e%88%e5%be%90%e5%bd%a9%e9%9c%9e%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9fnano-energy%ef%bc%9a%e8%87%aa%e6%94%af%e6%92%91%e5%a4%9a","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=225921","title":{"rendered":"\u6d4e\u5357\u5927\u5b66\u5218\u5b8f\u6559\u6388&\u5f90\u5f69\u971e\u6559\u6388\u56e2\u961fNano Energy\uff1a\u81ea\u652f\u6491\u591a\u7ea7\u591a\u5b54NiZn\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u548cNi\u5f02\u8d28\u7ed3\u6784\u5728\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\u4f5c\u4e3a\u9ad8\u6548\u6790\u6c22\u7535\u50ac\u5316\u5242"},"content":{"rendered":"

1. \u7814\u7a76\u80cc\u666f<\/b><\/strong><\/p>\n

\u5316\u77f3\u71c3\u6599\u7684\u8fc7\u5ea6\u6d88\u8017\u5bfc\u81f4\u73af\u5883\u6c61\u67d3\u548c\u80fd\u6e90\u5371\u673a\uff0c\u56e0\u6b64\uff0c\u5f00\u53d1\u7eff\u8272\u6c22\u80fd\u5bf9\u4eba\u7c7b\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u81f3\u5173\u91cd\u8981\u3002\u7535\u5316\u5b66\u6c34\u88c2\u89e3\u5236\u6c22\u7531\u4e8e\u6210\u672c\u4f4e\u3001\u64cd\u4f5c\u65b9\u4fbf\u3001\u65e0\u6c61\u67d3\u7b49\u4f18\u70b9\uff0c\u662f\u6700\u6709\u6f5c\u529b\u5927\u89c4\u6a21\u5e94\u7528\u7684\u7eff\u8272\u5236\u6c22\u6280\u672f\u3002\u7136\u800c\uff0c\u5de5\u4e1a\u4e0a\u78b1\u6027\u7535\u89e3\u6c34\u4f7f\u7528\u7684\u954d\u6790\u6c22\u50ac\u5316\u5242\u7f13\u6162\u7684\u6c22\u6790\u51fa\u52a8\u529b\u5b66\u81f4\u4f7f\u5176\u8fc7\u7535\u4f4d\u8f83\u5927\uff0c\u4ece\u800c\u5bfc\u81f4\u80fd\u8017\u548c\u6210\u672c\u589e\u52a0\uff0c\u4e25\u91cd\u5236\u7ea6\u4e86\u81ea\u8eab\u7684\u53d1\u5c55\u3002\u4e3a\u4e86\u6ee1\u8db3\u9ad8\u6548\u5236\u6c22\u7684\u5de5\u4e1a\u8981\u6c42\uff0c\u589e\u5f3a\u954d\u7684\u6790\u6c22\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u5bf9\u63d0\u9ad8\u78b1\u6027\u7535\u89e3\u6c34\u5236\u6c22\u6548\u7387\u5177\u6709\u91cd\u8981\u7684\u73b0\u5b9e\u610f\u4e49\u3002<\/p>\n

\u6210\u679c\u4ecb\u7ecd\uff1a<\/p>\n

\u6d4e\u5357\u5927\u5b66\u524d\u6cbf\u4ea4\u53c9\u79d1\u5b66\u7814\u7a76\u9662\u5f90\u5f69\u971e<\/b><\/strong>\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u5218\u5b8f<\/b><\/strong>\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u501f\u52a9\u201c\u7535\u6c89\u79ef-\u70ed\u5904\u7406-\u8150\u8680\u201d\u7684\u7b56\u7565\uff0c\u5728\u6ce1\u6cab\u954d\u7684\u8868\u9762\u539f\u4f4d\u6784\u7b51\u591a\u7ea7\u591a\u5b54\u03b21<\/sub>-NiZn\u91d1\u5c5e\u95f4\u5316\u5408\u7269\/Ni\u5f02\u8d28\u7ed3\u6784(TMP NiZn-Ni\/NF)\uff0c\u7a81\u7834\u4e86\u4f20\u7edf\u6e7f\u5316\u5b66\u65b9\u6cd5\u9650\u5236\u9ad8\u6d3b\u6027Zn\u57fa\u5408\u91d1\u5236\u5907\u7684\u74f6\u9888\uff0c\u4e3a\u6d3b\u6027\u4f4d\u70b9\u4e30\u5bcc\u3001\u9ad8\u50ac\u5316\u6548\u7387\u7684\u81ea\u652f\u6491\u975e\u8d35\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u7eb3\u7c73\u6750\u6599\u7684\u5236\u5907\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cFree-standing trimodal porous NiZn intermetallic and Ni heterojunction as highly efficient hydrogen evolution electrocatalyst in the alkaline electrolyte\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNano Energy<\/i><\/b><\/em><\/strong>\u4e0a\u3002\u8be5\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u524d\u6cbf\u4ea4\u53c9\u79d1\u5b66\u7814\u7a76\u9662\u548c\u81ea\u65cb\u7535\u5b50\u7814\u7a76\u9662\u5171\u540c\u57f9\u517b\u7684\u535a\u58eb\u7814\u7a76\u751f\u5468\u79cb\u971e\uff0c\u8bba\u6587\u94fe\u63a5\u5982\u4e0b\uff1ahttps:\/\/doi.org\/10.1016\/j.nanoen.2021.106402<\/u><\/a>\u3002<\/p>\n

<\/b>2. TMP NiZn-Ni\/NF<\/b><\/strong>\u7684<\/b><\/strong>\u5f62\u8c8c\u7ed3\u6784\u8868\u5f81<\/b><\/strong><\/p>\n

\u9996\u5148\uff0c\u5728\u6ce1\u6cab\u954d(NF)\u8868\u9762\u7535\u6c89\u79ef\u4e00\u5c42\u91d1\u5c5e\u950c\uff0c\u901a\u8fc7\u70ed\u5904\u7406\u83b7\u5f97NiZn\/NF\uff1b\u7136\u540e\u9009\u62e9\u6027\u5730\u6eb6\u89e3Zn\u539f\u5b50\u83b7\u5f97\u6700\u7ec8\u4ea7\u54c1\u3002XRD\u8868\u5f81\u8bc1\u660e\u6240\u5236\u5907\u4ea7\u54c1\u7531NiZn\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u548cNi\u4e24\u79cd\u7269\u76f8\u7ec4\u6210\uff1a<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe1. NiZn\/NF\u548cTMP NiZn-Ni\/NF\u6837\u54c1\u7684XRD\u8868\u5f81\u3002<\/p>\n

SEM(a&b)\u8868\u5f81\u53d1\u73b0\u950c\u7684\u8150\u8680\u5728\u8868\u9762\u5f62\u6210\u4e86\u5747\u5300\u7684\u5b54\u5f84\u5c3a\u5bf8\u7ea6\u51e0\u767e\u7eb3\u7c73\u7684\u5927\u5b54\uff0cTEM (c)\u7814\u7a76\u53d1\u73b0\u5728\u5b54\u58c1\u4e2d\u8fd8\u5206\u5e03\u6709\u4e00\u5c42\u4e30\u5bcc\u7684\u5b54\u5f84\u5c0f\u81f37 nm\u7684\u7eb3\u7c73\u5b54\u3002BJH\u5b54\u5f84\u5206\u6790(g)\u4e5f\u8bc1\u660e\u8fd9\u5c42\u7eb3\u7c73\u5b54\u4e3b\u8981\u5206\u5e03\u57287 nm\u5de6\u53f3\u3002\u8fd9\u4e9b\u7ed3\u679c\u8bc1\u660e\u4e86\u81ea\u652f\u6491\u591a\u7ea7\u591a\u5b54\u7ed3\u6784\u7684\u5f62\u6210\u3002HRTEM(d&e)\u3001SEAD(g)\u548cEBSD(h&i)\u56fe\u50cf\u8fdb\u4e00\u6b65\u8868\u660e\u5df2\u5236\u5907\u7684\u6837\u54c1\u7531\u03b21<\/sub>-NiZn\u91d1\u5c5e\u5316\u5408\u7269\u548cNi\u5171\u540c\u7ec4\u6210\uff0c\u8bc1\u5b9e\u6211\u4eec\u6210\u529f\u5236\u5907\u4e86\u81ea\u652f\u6491\u578b\u539f\u4f4d\u951a\u5b9a\u5728NF\u4e0a\u7684\u591a\u7ea7\u591a\u5b54NiZn\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u548cNi\u5f02\u8d28\u7ed3\u6784\u3002XPS\u5206\u6790\u53d1\u73b0\u03b21<\/sub>-NiZn\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u5bf9Ni\u7684\u7535\u5b50\u7ed3\u6784\u8d77\u5230\u4e86\u5927\u5e45\u5ea6\u7684\u8c03\u8282\u4f5c\u7528\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe2. TMP NiZn-Ni\/NF\u6837\u54c1\u7684\u5f62\u8c8c\u8868\u5f81\uff1a(a&b) SEM\u3001(c) TEM\u3001(d&e) HRTEM\u3001(f) SAED\u3001(g) BJH\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\u548c(h&i) EBSD\u56fe\u50cf\u3002\u63d2\u56fee1\u548ce2\u5206\u522b\u4e3aNi\u548c\u03b21<\/sub>-NiZn\u7684FFT\u53d8\u6362\u56fe\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe3. TMP NiZn-Ni\/NF\u7684XPS\u56fe\u8c31\u3002<\/p>\n

3. TMP NiZn-Ni\/NF\u7684<\/b><\/strong>\u6790\u6c22\u6027\u80fd(<\/b><\/strong>HER)\u6d4b\u8bd5<\/b><\/strong><\/p>\n

\u6211\u4eec\u901a\u8fc7LSV\u3001Tafel\u66f2\u7ebf\u3001EIS\u4ee5\u53ca\u7535\u5bb9\u6d4b\u8bd5\u7b49\u7814\u7a76\u53d1\u73b0TMP NiZn-Ni\/NF\u5177\u6709\u53ef\u4ee5\u4e0ePt\/C\u76f8\u5ab2\u7f8e\u7684HER\u6d3b\u6027\uff0c\u5c24\u5176\u5728\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5c55\u793a\u4e86\u6bd4Pt\/C\u66f4\u4f4e\u7684\u6790\u6c22\u8fc7\u7535\u4f4d\u3002\u800c\u4e14\uff0c\u6240\u5236\u5907\u7535\u6781\u7531\u4e8e\u4e00\u4f53\u5316\u591a\u7ea7\u591a\u5b54\u7684\u81ea\u652f\u6491\u7ed3\u6784\uff0c\u663e\u793a\u4e86\u6bd4Pt\/C\u66f4\u52a0\u4f18\u5f02\u7684\u957f\u65f6\u95f4\u50ac\u5316\u7a33\u5b9a\u6027\uff0c\u8fde\u7eed50\u5c0f\u65f6\u8fd0\u884c\u51e0\u4e4e\u6ca1\u6709\u7535\u6d41\u5bc6\u5ea6\u7684\u635f\u5931\uff0c\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8868\u9762\u7684\u591a\u5b54\u7ed3\u6784\u6ca1\u6709\u53d1\u751f\u5c3a\u5bf8\u7684\u7c97\u5316\u548c\u56e2\u805a\uff0c\u76f8\u7ed3\u6784\u4e5f\u6ca1\u6709\u53d1\u751f\u4efb\u4f55\u53d8\u5316\uff0c\u8868\u660e\u4e86\u03b21<\/sub>-NiZn\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u5728\u78b1\u6027\u6eb6\u6db2\u4e2d\u9ad8\u7535\u538b\u6761\u4ef6\u4e0b\u7684\u4f18\u5f02\u7a33\u5b9a\u6027\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe4. \u6240\u5236\u5907\u7684\u6837\u54c1\u7684HER\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\uff1a(a)\u00a0LSV\u66f2\u7ebf\u6d4b\u8bd5\u3001(b)\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u8fc7\u7535\u4f4d\u3001(c)\u00a0Tafel\u66f2\u7ebf\u3001(d&e)\u00a0EIS\u6d4b\u8bd5\u3001(f)\u7535\u5bb9\u6d4b\u8bd5\u3001(g)\u00a0i-t\u6d4b\u8bd5\u548c(h)\u00a0TMP NiZn-Ni\/NF\u7a33\u5b9a\u6027\u6d4b\u8bd5\u524d\u540e\u7684LSV\u66f2\u7ebf\u3002<\/p>\n

\u4e3a\u4e86\u6df1\u5165\u4e86\u89e3\u03b21<\/sub>-NiZn\u548cNi\u5f02\u8d28\u7ed3\u6784\u5bf9\u4e8eHER\u9ad8\u50ac\u5316\u6d3b\u6027\u7684\u8d77\u6e90\uff0c\u6211\u4eec\u5229\u7528DFT\u8ba1\u7b97\u6a21\u62df\u4e86H2<\/sub>O\u3001H+OH\u548cH\u5728Ni(111)\u6676\u9762\u3001\u03b21<\/sub>-NiZn (101)\u6676\u9762\u3001NiZn (101)\/Ni (111)\u7684\u5438\u9644\u80fd\u3002\u7ed3\u679c\u8868\u660e\u03b21<\/sub>-NiZn\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u672c\u8eab\u5177\u6709\u8f83\u4f4e\u7684H\u5438\u9644\u5409\u5e03\u65af\u81ea\u7531\u80fd(\u0394GH*<\/sub>)\uff0c\u800c\u4e14\u53ef\u4ee5\u663e\u8457\u964d\u4f4e\u754c\u9762\u76f8\u8fde\u7684\u91d1\u5c5eNi\u539f\u5b50\u8868\u9762\u7684\u0394GH*<\/sub>\u3002\u56e0\u6b64\uff0c\u03b21<\/sub>-NiZn\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u548cNi\u4e24\u76f8\u5f02\u8d28\u7ed3\u6784\u7684\u5f62\u6210\u53ef\u4ee5\u589e\u52a0\u8868\u9762\u9ad8\u6d3b\u6027\u4f4d\u70b9\u7684\u5bc6\u5ea6\uff0c\u4f18\u5316\u6c34\u88c2\u89e3\u4e2d\u7684HER\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u4ece\u800c\u5927\u5927\u63d0\u9ad8\u4e86\u6790\u6c22\u53cd\u5e94\u7684\u6027\u80fd\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe5.\u00a0(a)\u7ed3\u6784\u7684\u4f18\u5316(\u7070\u8272\u7403Ni\u3001\u84dd\u8272\u7403Zn\u3001\u7eff\u8272\u7403H\u3001\u7ea2\u8272\u7403O)\uff1bHER\u8fc7\u7a0b\u4e2d\u5206\u522b\u5728Ni (111)\u9762\u3001NiZn (101)\u9762\u548cNiZn (101)\/Ni (111)\u5f02\u8d28\u7ed3\u8868\u9762\u4e0a\u7684(b)\u00a0\u0394GH2O*<\/sub>\u548c\u0394GH*+OH*<\/sub>\u548c(c) \u0394GH*<\/sub>\u3002<\/p>\n

4. \u7ed3\u8bba<\/b><\/strong><\/p>\n

\u91c7\u7528\u6ce1\u6cab\u954d\u4f5c\u4e3a\u57fa\u5e95\u548cNi\u6e90\uff0c\u901a\u8fc7\u201c\u7535\u6c89\u79ef-\u70ed\u5904\u7406-\u8150\u8680\u201d\u7b56\u7565\u5236\u5907\u4e86\u5728\u6ce1\u6cab\u954d\u8868\u9762\u539f\u4f4d\u6784\u7b51\u7684\u591a\u7ea7\u591a\u5b54\u03b21<\/sub>-NiZn\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u548cNi\u7684\u5f02\u8d28\u7ed3\u6784\u3002\u7531\u4e8e\u9ad8\u5bc6\u5ea6\u7684\u53cd\u5e94\u6d3b\u6027\u4f4d\u70b9\u548c\u5177\u6709\u9ad8\u6548\u4f20\u8d28\u7684\u81ea\u652f\u6491\u591a\u7ea7\u591a\u5b54\u7ed3\u6784\uff0cTMP NiZn-Ni\/NF\u5728HER\u4e2d\u5c55\u73b0\u51fa\u4f18\u8d8a\u7684\u7535\u50ac\u5316\u6d3b\u6027\u3001\u4f4e\u8fc7\u7535\u4f4d\u548c\u957f\u65f6\u95f4\u7684\u50ac\u5316\u7a33\u5b9a\u6027\uff0c\u751a\u81f3\u6bd4\u5546\u4e1aPt\/C\u5177\u6709\u66f4\u4f18\u5f02\u7684\u6790\u6c22\u6027\u80fd\u3002\u6b64\u9879\u5de5\u4f5c\u4e3a\u8bbe\u8ba1\u5177\u6709\u9ad8\u50ac\u5316\u6548\u7387\u7684\u81ea\u652f\u6491\u975e\u8d35\u91d1\u5c5e\u57fa\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u7eb3\u7c73\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4e00\u79cd\u4fbf\u6377\u3001\u7eff\u8272\u3001\u53ef\u6269\u5c55\u7684\u65b9\u6848\u3002<\/p>\n

\u672c\u6587\u7531\u4f5c\u8005\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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