{"id":226191,"date":"2021-08-19T10:52:15","date_gmt":"2021-08-19T02:52:15","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=226191"},"modified":"2021-08-19T10:50:40","modified_gmt":"2021-08-19T02:50:40","slug":"electrochemical-energy-reviews%ef%bc%9a%e8%a7%a3%e5%86%b3%e9%94%82%e7%94%b5%e6%b1%a0%e7%83%ad%e5%a4%b1%e6%8e%a7%e7%9a%84%e7%ad%96%e7%95%a5%ef%bc%9a%e4%bb%8e%e6%9c%ba%e7%90%86%e5%88%b0%e6%94%b9","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=226191","title":{"rendered":"Electrochemical Energy Reviews\uff1a\u89e3\u51b3\u9502\u7535\u6c60\u70ed\u5931\u63a7\u7684\u7b56\u7565\uff1a\u4ece\u673a\u7406\u5230\u6539\u6027"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

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\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

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\n \"\"\uff08a\uff09Al2<\/sub>O3<\/sub>\u9897\u7c92\u3001\u5177\u6709Li-Al-O\u5c42\u7684Al2<\/sub>O3<\/sub>\u9aa8\u67b6\u548c3D LIA\u7535\u6781\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

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\n \"\"\uff08a\uff09NPCC-Li\u7684\u63d2\u56fe\u3002<\/p>\n

\uff08b\uff09\u7eaf\/N\u63ba\u6742\/N-P\u63ba\u6742\/P\u63ba\u6742\u77f3\u58a8\u70ef\u7247\u4e2d\u9502\u4e0d\u540c\u7535\u8377\u5bc6\u5ea6\u7684\u4f18\u5316\u7ed3\u6784\uff1b<\/p>\n

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\n \"\"\uff08a\uff09Li\u548cPA-MXene\u5c42\u4e0a\u7684Li\u6210\u6838\/\u7535\u9540\u8fc7\u7a0b\u56fe\u89e3\uff1b<\/p>\n

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\n \"\"\uff08a\uff09PTMEG-Li\/Sn\u7684\u5f62\u6210\u673a\u7406\uff1b<\/p>\n

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\uff08c\uff09\u88f8Li\u548cLiF-\u5bccLi\u7684Li\u9540\u5c42\u884c\u4e3a\u793a\u610f\u56fe\uff1b<\/p>\n

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\uff08f\uff09\u901a\u8fc7FEC\u5904\u7406\u5728\u9502\u8d1f\u6781\u4e0a\u5f62\u6210\u53cc\u5c42\u8584\u819c\u7684\u65b9\u6848\u3002<\/p>\n

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\n \"\"\uff08a\uff09SEM\u56fe\u50cf\u663e\u793a\u77f3\u58a8VGCF CNHs\u88ab\u78b3\u8584\u819c\u5305\u56f4\uff1b<\/p>\n

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\uff08c\uff09Al2<\/sub>O3<\/sub>\u5305\u8986\u5929\u7136\u77f3\u58a8\u590d\u5408\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\uff08d\uff09Sn-Al2<\/sub>O3<\/sub>-C\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7684\u5408\u6210\u8def\u7ebf\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08e\uff09\u77f3\u58a8\u4e0aAl2<\/sub>O3<\/sub>\u6d82\u5c42\u7684\u793a\u610f\u56fe\u548cSEM\u56fe\u50cf\uff1b<\/p>\n

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\n \"\"\uff08a\uff09\u6291\u5236\u7535\u6c60\u6545\u969c\u7684\u81ea\u52a8\u5173\u95ed\u8d1f\u6781\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u88f8\u6c2e\u5316\u7845\u548cTiO2<\/sub>\u6d82\u5c42\u6c2e\u5316\u7845\u7684\u663e\u5fae\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08c\uff09Li4<\/sub>Ti5<\/sub>O12<\/sub>\u548cLi7<\/sub>Ti5<\/sub>O12<\/sub>\u7684\u7ed3\u6784\uff0c\u4f53\u79ef\u6ca1\u6709\u53d8\u5316\uff1b<\/p>\n

\uff08d\uff09\u591a\u5b54\u6708\u997c\u72b6\u7ed3\u6784\u7684\u5408\u6210\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08e\uff09\u4ecb\u5b54TiNb2<\/sub>O7<\/sub>\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u5341\u56db\u3001\u7528\u4e8e\u6b63\u6781\u4fdd\u62a4\u7684\u6dfb\u52a0\u5242\u548c\u6d82\u5c42<\/strong>
\n \"\"\uff08a\uff09\u975e\u6676\u6001LiFePO4<\/sub>\u7684ALD\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u9000\u706bLiFePO4<\/sub>\/CNT\u57281 C\u548c0.1 C\u4e0b\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff1b<\/p>\n

\uff08c\uff09\u901a\u8fc7HF\u4fb5\u8680\u548c\u6c34\u518d\u751f\u7684\u6b63\u6781\u964d\u89e3\u5faa\u73af\uff1b<\/p>\n

\uff08d\uff09LiMn2<\/sub>O4<\/sub>\u9897\u7c92\u7684CeO2<\/sub>\u57faALD\u6d82\u5c42\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08e\uff09\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0cLNMO-n\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\uff08f\uff09LiNix<\/sub>Coy<\/sub>Mnz<\/sub>O2<\/sub>\u7684SEM\u56fe\u50cf\u548c\u76f8\u5e94\u5143\u7d20Ni\u3001Co\u548cMn\u7684\u80fd\u91cf\u8272\u6563X\u5c04\u7ebf\u5149\u8c31\uff08EDS\uff09\u7ed8\u56fe\uff1b<\/p>\n

\uff08g\uff09\u591a\u5c42LiNix<\/sub>Coy<\/sub>Mnz<\/sub>O2<\/sub>\u4e2d\u7a7a\u7ea4\u7ef4\u7684\u6a2a\u622a\u9762SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u5341\u4e94\u3001\u63d0\u9ad8Li\u63d2\u5c42\u6b63\u6781\u7684\u7a33\u5b9a\u6027<\/strong>
\n \"\"\uff08a\uff09Fe\u53d6\u4ee3\u5bf9\u7ed3\u6784\u6539\u6027\u7684\u5f71\u54cd\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5145\u653e\u7535\u66f2\u7ebf\u4e0eLiNi0.5-x<\/sub>Mn1.5-x<\/sub>Fe2x<\/sub>O4<\/sub>\uff082x=0, 0.33\uff09\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\uff1b<\/p>\n

\uff08c\uff09LiNi0.5-x<\/sub>Mn1.5-x<\/sub>Fe2x<\/sub>O4<\/sub>\uff082x=0, 0.33\uff09\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

\uff08d\uff09\u70ed\u54cd\u5e94LCO-PTC\u6b63\u6781\u7684\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u5341\u516d\u3001CFx<\/sub>\u6b63\u6781\u7684\u521b\u65b0<\/strong>
\n \"\"\uff08a\uff09\u6765\u81eaC 1s XPS\u5149\u8c31\u7684\u79bb\u5b50\/\u534a\u79bb\u5b50\/\u5171\u4ef7C-F\u952e\u80fd\uff1b<\/p>\n

\uff08b\uff09\u6c1f\u4ee3\u77f3\u58a8\u70ef\u4e2dC-F\u952e\u7684\u957f\u5ea6\u548c\u4ece\u6c1f\u4ee3\u77f3\u58a8\u70ef\u4e2d\u53bb\u9664\u4e2d\u6027F\u539f\u5b50\u7684\u80fd\u91cf\uff1b<\/p>\n

\uff08c\uff0910 mA g-1<\/sup>\u65f6F-CMN\u7684\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff09\u4f7f\u7528\u5bb9\u91cf\u4e3a1 Ah\u7684F-cMNS-280\u57280.01 C\u4e0b\u5236\u9020\u7684\u888b\u5f0f\u9502\u7535\u6c60\u7684\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08e\uff09\u7ecf\u8fc7\u6eb6\u5242\u70ed\u5265\u843d\u7684\u6c1f\u5316\u77f3\u58a8\u7684\u9ad8\u5206\u8fa8\u7387XPS\u5149\u8c31\uff1b<\/p>\n

\uff08f\uff09\u5728\u9ad8\u6e29\u4e0b\uff0c\u4f7f\u7528F2<\/sub>\u5408\u6210\u6c1f\u4ee3\u77f3\u58a8\u70ef\u7eb3\u7c73\u5e26\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u5341\u4e03\u3001\u9502\u7535\u6c60\u4e2d\u5e38\u7528\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u57fa\u672c\u6027\u8d28<\/strong><\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe\u5341\u516b\u3001\u7a33\u5b9a\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u6dfb\u52a0\u5242<\/strong>
\n \"\"\uff08a\uff09\u6eb6\u89e3\u5728LiTFSI-LiBOB\u7535\u89e3\u8d28\u4e2d\u4ee5\u63d0\u9ad8\u9502\u8d1f\u6781\u5b89\u5168\u6027\u7684LiPF6<\/sub>\u6dfb\u52a0\u5242\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a1.75 mA cm-2<\/sup>\u300160 \u00b0C\u4e0b\uff0c\u5728EC-EMC\u6eb6\u5242\u4e2d\u4f7f\u7528\u5404\u79cd\u7535\u89e3\u8d28\u7684Li-NMC\u5168\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1b<\/p>\n

\uff08c\uff09\u7535\u6c60\u4e2dEM-5Li-Na IL\u7535\u89e3\u8d28\u7684\u7ec4\u6210\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08d\uff09\u5177\u6709\u4e0d\u540c\u5faa\u73af\u7684EM-5Li-Na IL\u7535\u89e3\u8d28\u7684\u5bf9\u79f0\u9502\u7535\u6c60\uff1b<\/p>\n

\uff08e\uff09PF5<\/sub>\u7a33\u5b9a\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08f\uff09TMSPC\u6dfb\u52a0\u5242\u6e05\u9664HF\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08g\uff09\u5728\u6709\u65e0MTE-TMS\u6dfb\u52a0\u5242\u4e0b\uff0c\u77f3\u58a8\/NCM851005\u7535\u6c60\u7684\u5931\u6548\u673a\u5236\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08h\uff09\u6709\u65e0MTE-TMS\u6dfb\u52a0\u5242\u4e0b\uff0c\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u548c\u5e93\u4f26\u6548\u7387\u3002<\/p>\n

\u56fe\u5341\u4e5d\u3001\u5b89\u5168\u7684SSEs<\/strong>
\n \"\"\uff08a\uff09Li-FEC\/LiFePO4<\/sub>\u56fa\u6001\u7535\u6c60\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09Li-FEC\/LiFePO4<\/sub>\u7535\u6c60\u548cLi-FEC\/LiNi0.5<\/sub>Mn0.3<\/sub>Co0.2<\/sub>O2<\/sub>\u7535\u6c60\u5728\u4e0d\u540c\u901f\u7387\u4e0b\u7684\u7535\u538b\u6ce2\u5f62\uff1b<\/p>\n

\uff08c\uff09PIC\u3001CIP\u548c\u5939\u5c42\u578b\u7535\u89e3\u8d28\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08d\uff09LFP\/SCE\/Li\u548cLFP\/PIC\/Li\u7535\u6c60\u5728\u4e0d\u540c\u7535\u6d41\u901f\u7387\u4e0b\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

\uff08e\uff09SPEs\u7684\u975e\u539f\u4f4d\u548c\u539f\u4f4d\u5408\u6210\uff1b<\/p>\n

\uff08f\uff09PEO-LCO\u3001CMC-LCO\u548c\u6d77\u85fb\u9178\u94a0-LCO\u7535\u6781\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08g\uff09\u6bd4\u8f83PEO\u3001PVDF\u3001CMC\u5355\u4f53\u548c\u6d77\u85fb\u9178\u94a0\u5355\u4f53\u5728LiCoO2<\/sub>\uff08001\uff09\u4e0a\u7684\u5438\u9644\u80fd\u3002<\/p>\n

\u56fe\u4e8c\u5341\u3001\u57fa\u4e8e\u70ed\u7a33\u5b9a\u6027\u7684\u5206\u79bb\u5668<\/strong>
\n \"\"\uff08a\uff09\u4e0d\u540c\u6e29\u5ea6\u4e0b\uff0cPP\u3001PI\u548cAl2<\/sub>O3<\/sub>-PI\u5206\u79bb\u5668\u6536\u7f29\u7684\u6570\u5b57\u56fe\u50cf\uff1b<\/p>\n

\uff08b\uff09PP\u3001PI\u548cAl2<\/sub>O3<\/sub>-PI\u5206\u79bb\u5668\u6db2\u4f53\u7535\u89e3\u8d28\u6e17\u900f\u884c\u4e3a\u7684\u6570\u5b57\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff09PE\u3001PPS1-81\u548cPPS2-81\u5206\u79bb\u5668\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u70ed\u5904\u7406\u540e\u7684\u6570\u5b57\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff09\u914d\u5907PE\u3001PPS1-81\u548cPPS2-81\u9694\u677f\u7684\u7535\u6c60\u7684\u989d\u5b9a\u6027\u80fd\uff1b<\/p>\n

\uff08e\uff09\u5177\u6709\u70ed\u89e6\u53d1\u7535\u6c60\u963b\u71c3\u6027\u80fd\u7684\u201c\u667a\u80fd\u201d\u9759\u7535\u7eba\u4e1d\u5206\u79bb\u5668\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08f\uff09LIBs\u540c\u8f74fber-\u5206\u79bb\u5668\u5173\u95ed\u6982\u5ff5\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08g\uff09\u70ed\u54cd\u5e94\u5fae\u7403\u6d82\u5c42\u5206\u79bb\u5668\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08h\uff09\u5177\u6709\u70ed\u89e6\u53d1\u963b\u71c3\u6027\u80fd\u7684\u591a\u529f\u80fd\u7535\u7eba\u5206\u79bb\u5668\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08i\uff09APP\u4e0aLi2<\/sub>Sx<\/sub>\u7684\u793a\u610f\u56fe\u4ee5\u53caAPP\u548cLi-S\u7684\u7ed3\u5408\u80fd\u3002<\/p>\n

\u56fe\u4e8c\u5341\u4e00\u3001\u6982\u8ff0\u89e3\u51b3\u9502\u7535\u6c60\u70ed\u95ee\u9898\u7684\u5404\u79cd\u65b9\u6cd5<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n

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\u672c\u6587\u8ba8\u8bba\u7684\u6539\u8fdb\u65b9\u6cd5\u5982\u4e0b\uff1a\uff081\uff09\u8d1f\u6781\u6750\u6599<\/strong>\u3002\u9502\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\u5305\u62ec\u91d1\u5c5e\u9502\u3001\u78b3\u57fa\u6750\u6599\u548c\u7845\u57fa\u6750\u6599\u3002\u8d1f\u6781\u8868\u9762\u5f62\u6210\u5177\u6709\u4f18\u5f02\u70ed\u7a33\u5b9a\u6027\u548c\u673a\u68b0\u6027\u80fd\u7684SEI\u5c42\u662f\u4efb\u4f55\u8d1f\u6781\u6750\u6599\u6539\u6027\u7b56\u7565\u7684\u6838\u5fc3\uff0c\u53ef\u4ee5\u63d0\u9ad8\u5b89\u5168\u6027\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff082\uff09\u6b63\u6781\u6750\u6599<\/strong>\u3002\u5728\u7535\u6c60\u5185\u90e8\u7684\u53cd\u5e94\u8fc7\u7a0b\u4e2d\uff0c\u6b63\u6781\u6bd4\u8d1f\u6781\u5bfc\u7535\u6027\u5dee\uff0c\u4ea7\u751f\u66f4\u591a\u7684\u70ed\u91cf\u3002\u4f7f\u7528\u6dfb\u52a0\u5242\u6216\u6d82\u5c42\u548c\u5143\u7d20\u66ff\u4ee3\u662f\u5e7f\u6cdb\u4f7f\u7528\u7684\u63d2\u5c42\u578b\u6b63\u6781\u4e2d\u5e38\u7528\u7684\u6709\u6548\u65b9\u6cd5\u3002\u5728\u6b63\u6781\u4e0a\u6d82\u8986\u70ed\u54cd\u5e94\u6750\u6599\u53ef\u4ee5\u63d0\u9ad8\u7535\u6c60\u7684\u5b89\u5168\u6027\u3002\uff083\uff09\u7535\u89e3\u8d28\u6750\u6599<\/strong>\u3002\u78f7\u9178\u4e09\u82ef\u916f\u3001\u542b\u7845\u548c\u542b\u6c1f\u7684\u6dfb\u52a0\u5242\u53ef\u4ee5\u63d0\u9ad8\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u70ed\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u56fa\u4f53\u7535\u89e3\u8d28\u6709\u52a9\u4e8e\u89e3\u51b3\u4e0b\u4e00\u4ee3\u9ad8\u6027\u80fd\u7535\u5316\u5b66\u5b58\u50a8\u5668\u4ef6\u7684\u70ed\u5931\u63a7\u95ee\u9898\u3002\uff084\uff09\u5206\u79bb\u5668\u6750\u6599<\/strong>\u3002\u4f7f\u7528\u5177\u6709\u6539\u8fdb\u70ed\u7a33\u5b9a\u6027\u7684PI\u548cPPS\u6750\u6599\u4f5c\u4e3a\u5206\u79bb\u5668\uff0c\u7ed3\u5408\u6539\u6027\u548c\u6d82\u5c42\uff0c\u53ef\u5927\u5927\u63d0\u9ad8\u5206\u79bb\u5668\u6750\u6599\u7684\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u4f7f\u7528\u70ed\u54cd\u5e94\u6750\u6599\u53ef\u4ee5\u5728\u8fc7\u70ed\u671f\u95f4\u53ca\u65f6\u5173\u95ed\u7535\u6c60\uff0c\u5e76\u9632\u6b62\u70ed\u5931\u63a7\u3002<\/p>\n

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\u603b\u4e4b\uff0c\u4ece\u63d0\u9ad8\u9502\u7535\u6c60\u7684\u5b89\u5168\u6027\u3001\u5bb9\u91cf\u3001\u7535\u538b\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3001\u5e93\u4ed1\u6548\u7387\u548c\u50a8\u5b58\u6027\u80fd\u7b49\u65b9\u9762\u6765\u770b\uff0c\u9700\u8981\u63a8\u8fdb\u9502\u7535\u6c60\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u3002\u5728\u9502\u7535\u6c60\u7684\u5546\u4e1a\u5e94\u7528\u4e2d\uff0c\u8bb8\u591a\u6539\u8fdb\u6ca1\u6709\u5f97\u5230\u5145\u5206\u4f18\u5316\u3002\u4f46\u662f\uff0c\u5b83\u4eec\u53ef\u4ee5\u4e3a\u672a\u6765\u9502\u7535\u6c60\u7684\u53d1\u5c55\u505a\u51fa\u8d21\u732e\u3002<\/p>\n

\n \u6587\u732e\u94fe\u63a5\uff1aStrategies to Solve Lithium Battery Thermal Runaway: From Mechanism to Modifcation<\/a><\/strong>. Electrochemical Energy Reviews<\/em>, 2021<\/strong>, DOI: 10.1007\/s41918-021-00109-3.<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

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