{"id":226658,"date":"2021-08-28T06:30:03","date_gmt":"2021-08-27T22:30:03","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=226658"},"modified":"2021-08-28T22:24:51","modified_gmt":"2021-08-28T14:24:51","slug":"nature-reviews-materials%e8%b6%85%e7%ba%a7%e7%bb%bc%e8%bf%b0%ef%bc%9a%e8%85%90%e8%9a%80%e5%ad%a6%e8%a7%92%e5%ba%a6%e8%a7%a3%e5%af%86%e9%87%91%e5%b1%9e%e9%94%82%e7%94%b5%e6%9e%81%e9%92%9d%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=226658","title":{"rendered":"Nature Reviews Materials\u8d85\u7ea7\u7efc\u8ff0\uff1a\u8150\u8680\u5b66\u89d2\u5ea6\u89e3\u5bc6\u91d1\u5c5e\u9502\u7535\u6781\u949d\u5316\u819c"},"content":{"rendered":"

\"\"<\/p>\n

\u8fd1\u65e5\uff0c\u56db\u5ddd\u5927\u5b66\u5316\u5b66\u5de5\u7a0b\u5b66\u9662\u4f55\u6b23\u7279\u8058\u7814\u7a76\u5458\u5728Nature Review Materials (\u5f71\u54cd\u56e0\u5b5066.308)\u4e0a\u53d1\u8868\u7efc\u8ff0\uff0c\u4ece\u8150\u8680\u89d2\u5ea6\u89e3\u5bc6\u91d1\u5c5e\u9502\u7535\u6781\u949d\u5316\u819c\u201cThe passivity of lithium electrodes in liquid electrolytes for secondary batteries\u201d\u3002<\/p>\n

\u80cc\u666f<\/strong><\/p>\n

\u9502\u91d1\u5c5e\u5177\u6709\u5f88\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf(3,860 mAh g\u22121<\/sup>)\u548c\u6781\u4f4e\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d(\u76f8\u5bf9\u4e8e\u6807\u51c6\u6c22\u7535\u6781(SHE) \u7684\u22123.040 V)\uff0c\u56e0\u6b64\u53ef\u4ee5\u63d0\u4f9b\u8f83\u9ad8\u7684\u6bd4\u80fd(500 Wh kg\u22121<\/sup>)\u3002\u56e0\u6b64\uff0c\u65e9\u572820\u4e16\u7eaa60\u5e74\u4ee3\u5c31\u63d0\u51fa\u5e76\u7b5b\u9009\u4e86\u9502\u91d1\u5c5e\u4f5c\u4e3a\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u7cfb\u7edf\u7684\u8d1f\u6781\u3002\u5c3d\u7ba1\u9502\u5728\u6db2\u6001\u7535\u89e3\u8d28\u4e2d\u6781\u4e3a\u6d3b\u8dc3\uff0c\u4f46\u7531\u4e8e\u8868\u9762\u4fdd\u62a4\u819c\u7684\u5feb\u901f\u589e\u957f\uff0c\u5b83\u4ecd\u7136\u76f8\u5bf9\u7a33\u5b9a\u3002\u7406\u60f3\u7684\u949d\u5316\u819c\u5fc5\u987b\u6ee1\u8db3\u4ee5\u4e0b\u5148\u51b3\u6761\u4ef6\uff1a\u5b83\u5e94\u8be5\u4fdd\u62a4\u9502\u91d1\u5c5e\u8868\u9762\u4e0d\u4e0e\u7535\u89e3\u8d28\u63a5\u89e6\uff1b\u5141\u8bb8\u9502\u79bb\u5b50\uff08Li+<\/sup>\uff09\u5728\u819c\u4e0a\u5feb\u901f\u4f20\u8f93\uff1b\u6291\u5236\u9502\u548c\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\uff1b\u9632\u6b62\u9502\u679d\u6676\u7684\u6210\u6838\u548c\u751f\u957f\uff1b\u5e76\u7b26\u5408\u9502\u5265\u79bb\u548c\u6c89\u79ef\u671f\u95f4\u7684\u9502\u8868\u9762\u5f62\u6001\u53d8\u5316\u3002\u521b\u5efa\u8fd9\u6837\u4e00\u4e2a\u7406\u60f3\u7684\u949d\u5316\u819c\u9700\u8981\u6df1\u5165\u4e86\u89e3\u819c\u7684\u7ec4\u6210\u3001\u7ed3\u6784\u3001\u5f62\u6001\u548c\u62d3\u6251\u7ed3\u6784\u4e0e\u5176\u5728\u7535\u6c60\u5355\u5143\u4e2d\u7684\u57fa\u672c\u529f\u80fd\u548c\u64cd\u4f5c\u4e4b\u95f4\u7684\u5173\u7cfb\u3002<\/p>\n

\u5de5\u4f5c\u4ecb\u7ecd<\/strong><\/p>\n

\u4e00\u4e9b\u5173\u4e8e\u9502\u91d1\u5c5e\u9633\u6781\u7684\u4f18\u79c0\u8bc4\u8bba\u6587\u7ae0\u5df2\u7ecf\u53d1\u8868\uff0c\u8fd9\u4e9b\u6587\u7ae0\u4e3b\u8981\u96c6\u4e2d\u5728\u5148\u8fdb\u7684\uff08\u4e3b\uff09\u7ed3\u6784\u4ee5\u53ca\u4eba\u5de5\u4fdd\u62a4\u5c42\u7684\u8bbe\u8ba1\u4e0a\u3002\u57fa\u4e8e\u6b64\uff0c\u56db\u5ddd\u5927\u5b66\u5316\u5b66\u5de5\u7a0b\u5b66\u9662\u7684\u4f55\u6b23\u7279\u8058\u7814\u7a76\u5458<\/strong>\u5728\u672c\u7efc\u8ff0\u4e2d\uff0c\u4ece\u4e00\u4e2a\u7a0d\u5fae\u4e0d\u540c\u7684\u89d2\u5ea6\u5bf9\u53d1\u751f\u5728\u9502\u7535\u6781-\u6db2\u6001\u7535\u89e3\u8d28\u754c\u9762\u7684\u53cd\u5e94\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\uff0c\u53c2\u8003\u4e86\u91d1\u5c5e\u4e0a\u8150\u8680\u548c\u949d\u5316\u73b0\u8c61\u7684\u4e00\u822c\u6982\u5ff5\uff0c\u5e76\u91cd\u65b0\u5ba1\u67e5\u4e86\u76f8\u5e94\u7684\u3001\u6210\u719f\u7684\u7535\u5316\u5b66\u7406\u8bba\u548c\u6a21\u578b\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5c3d\u7ba1\u4e0e\u5176\u4ed6\u91d1\u5c5e\u5728\u6c34\u548c\u975e\u6c34\u7535\u89e3\u8d28\u4e2d\u89c2\u5bdf\u5230\u7684\u8868\u9762\u73b0\u8c61\u6709\u76f8\u4f3c\u4e4b\u5904\u548c\u7c7b\u4f3c\u4e4b\u5904\uff0c\u4f46\u91d1\u5c5e\u9502\u8fd8\u6ca1\u6709\u4ece\u8150\u8680\u79d1\u5b66\u7684\u89d2\u5ea6\u8fdb\u884c\u5f7b\u5e95\u7814\u7a76<\/strong>\u3002\u5728\u8fd9\u91cc\uff0c\u6211\u4eec\u901a\u8fc7\u8ba8\u8bba\uff08\u53ef\u9006\u7684\uff09Li+<\/sup>\u5728\u77ac\u95f4\u5f62\u6210\u7684\u949d\u5316\u5c42\u4e0a\u7684\u8f6c\u79fb\uff0c\u901a\u5e38\u88ab\u79f0\u4e3a\u56fa\u4f53\u7535\u89e3\u8d28\u95f4\u76f8\uff08SEI\uff09\uff0c\u5728\u8150\u8680\u79d1\u5b66\u548c\u7535\u6c60\u7535\u5316\u5b66\u4e4b\u95f4\u5efa\u7acb\u4e00\u5ea7\u6865\u6881<\/strong>\u3002\u6211\u4eec\u5c06\u8fd9\u4e9b\u8003\u8651\u4e0e\u4ee5\u6750\u6599\u79d1\u5b66\u4e3a\u5bfc\u5411\u7684\u65b9\u6cd5\u7ed3\u5408\u8d77\u6765\uff0c\u4ee5\u5b9e\u73b0\u7cbe\u5fc3\u8bbe\u8ba1\u7684\u949d\u5316\u5c42\u6216\u4eba\u5de5\u5939\u5c42\uff0c\u8fd9\u4e9b\u949d\u5316\u5c42\u6216\u4eba\u5de5\u5939\u5c42\u53ef\u4ee5\u5728\u539f\u4f4d\uff08\u5373\u5728\u7535\u6c60\u4e2d\uff09\u6216\u975e\u539f\u4f4d\uff08\u5373\u5728\u7535\u6c60\u7ec4\u88c5\u524d\uff09\u83b7\u5f97\uff0c\u5b83\u4eec\u53ef\u4ee5\u6291\u5236\u8fde\u7eed\u7684\u7535\u89e3\u8d28\u5206\u89e3\u548c\u9502\u6d88\u8017\u3002\u6700\u540e\uff0c\u6211\u4eec\u63d0\u4f9b\u4e86\u4e00\u4efd\u7406\u60f3\u7684\u949d\u5316\u5c42\u7684\u613f\u671b\u6e05\u5355\uff0c\u5e76\u786e\u5b9a\u4e86\u53ef\u80fd\u5bfc\u81f4\u5728\u5546\u4e1a\u7535\u6c60\u5355\u5143\u4e2d\u90e8\u7f72\u91d1\u5c5e\u9502\u9633\u6781\u7684\u77e5\u8bc6\u5dee\u8ddd\u548c\u7814\u7a76\u65b9\u5411\u3002<\/p>\n

\u91d1\u5c5e\u949d\u5316<\/strong><\/p>\n

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\"\"<\/p>\n

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\u9502\u7684\u6807\u51c6\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u6781\u4f4e\uff08\u76f8\u5bf9\u4e8eSHE\u4e3a-3.040V\uff09\uff0c\u56e0\u6b64\uff0c\u57fa\u672c\u4e0a\u53ef\u4ee5\u7acb\u5373\u4e0e\u4efb\u4f55\u7535\u89e3\u8d28\u53cd\u5e94\u3002\u5982\u679c\u949d\u5316\u5f15\u8d77\u7684\u8868\u9762\u819c\u5141\u8bb8Li+<\/sup>\u79bb\u5b50\u7684\u4f20\u8f93\uff0c\u5b83\u53ef\u4ee5\u652f\u6301\u7535\u6c60\u5355\u5143\u4e2d\u7684Li\u9633\u6781\u64cd\u4f5c\uff08\u56fe1e\uff09\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u9502\u7684\u949d\u5316\u53d1\u751f\u5728\u6ca1\u6709\u4efb\u4f55\u5916\u90e8\u65bd\u52a0\u7684\u7535\u6d41\u6216\u7535\u4f4d\u6781\u5316\u7684\u60c5\u51b5\u4e0b\u3002\u9502\u7684\u8150\u8680\u6216\u949d\u5316\u53ef\u4ee5\u7528\u4e24\u4e2a\u90e8\u5206\u7684\u7535\u5316\u5b66\u53cd\u5e94\u6765\u63cf\u8ff0\uff0c\u5b83\u4eec\u4ee5\u76f8\u540c\u7684\u901f\u5ea6\u5e73\u884c\u53d1\u751f\u3002\u9633\u6781\u90e8\u5206\u53cd\u5e94\uff08\u516c\u5f0f\uff083\uff09\uff09\u5305\u62ec\u9502\u7684\u6c27\u5316\uff0c\u6216\u6eb6\u89e3\uff0c\u9634\u6781\u90e8\u5206\u53cd\u5e94\uff08\u516c\u5f0f\uff084\uff09\uff09\u5305\u62ec\u7535\u89e3\u8d28\u7684\u8fd8\u539f\u3002<\/p>\n

nLi \u2192 n Li+<\/sup> + n e–<\/sup>\u00a0\u00a0 (3)<\/p>\n

Electrolyte + n e\u2212<\/sup> \u2192SEI + soluble species + gaseous species\u00a0\u00a0 (4)<\/p>\n

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\u9502\u949d\u5316\u8fc7\u7a0b<\/strong><\/p>\n

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Box1 |\u9502\u91d1\u5c5e\u7535\u6781\u7684\u964d\u89e3\u53cd\u5e94<\/p>\n

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The passivity of lithium electrodes in liquid electrolytes for secondary batteries Nature Reviews Materials ( IF 66.308 ) Pub Date : 2021-08-24 , DOI: 10.1038\/s41578-021-00345-5<\/p>\n

He, Xin, Bresser, Dominic, Passerini, Stefano, Baakes, Florian, Krewer, Ulrike, Lopez, Jeffrey, Mallia, Christopher Thomas, Shao-Horn, Yang, Cekic-Laskovic, Isidora, Wiemers-Meyer, Simon, Soto, Fernando A., Ponce, Victor, Seminario, Jorge M., Balbuena, Perla B., Jia, Hao, Xu, Wu, Xu, Yaobin, Wang, Chongmin, Horstmann, Birger, Amine, Rachid, Su, Chi-Cheung, Shi, Jiayan, Amine, Khalil, Winter, Martin, Latz, Arnulf, Kostecki, Robert<\/p>\n

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