{"id":226770,"date":"2021-09-01T12:00:08","date_gmt":"2021-09-01T04:00:08","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=226770"},"modified":"2021-09-01T11:37:12","modified_gmt":"2021-09-01T03:37:12","slug":"%e4%b8%ad%e5%b1%b1%e5%a4%a7%e5%ad%a6nature-communications%ef%bc%9a%e5%8a%a8%e6%80%81%e9%85%8d%e4%bd%8d%e7%9b%b8%e4%ba%92%e4%bd%9c%e7%94%a8%e5%ae%9e%e7%8e%b0%e5%bf%ab%e9%80%9f%e7%94%b5%e5%ad%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=226770","title":{"rendered":"\u4e2d\u5c71\u5927\u5b66Nature Communications\uff1a\u52a8\u6001\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u5b9e\u73b0\u5feb\u901f\u7535\u5b50\u8f6c\u79fb\u2014\u2014\u5149\u50ac\u5316CO2\u8fd8\u539f\u7684\u91cf\u5b50\u6548\u7387\u7684\u63d0\u9ad8"},"content":{"rendered":"

\u80cc\u666f\u4ecb\u7ecd<\/b><\/strong><\/p>\n

\u6536\u96c6\u9633\u5149\u5c06\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u8f6c\u5316\u4e3a\u78b3\u8d28\u71c3\u6599\u4e00\u76f4\u88ab\u89c6\u4e3a\u5236\u9020\u78b3\u4e2d\u6027\u80fd\u6e90\u7684\u53ef\u6301\u7eed\u9014\u5f84\uff0c\u5e76\u6709\u671b\u7f13\u89e3\u6e29\u5ba4\u6c14\u4f53\u3002\u51ed\u501f\u7ed3\u6784\u660e\u786e\u548c\u5206\u5b50\u7ed3\u6784\u9ad8\u5ea6\u53ef\u8c03\u7b49\u4f18\u70b9\uff0c\u8bb8\u591a\u5316\u5b66\u5bb6\u81f4\u529b\u4e8e\u8bbe\u8ba1\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u7684\u8fc7\u6e21\u91d1\u5c5e\u914d\u5408\u7269\u7684\u5206\u5b50\u4f53\u7cfb\uff0c\u8fc7\u6e21\u91d1\u5c5e\u914d\u5408\u7269\u65e2\u53ef\u4ee5\u4f5c\u4e3a\u5149\u654f\u5242(PSs)\u5728\u5149\u6fc0\u53d1\u4e0b\u4f20\u8f93\u7535\u5b50\uff0c\u6216\u63a5\u53d7\u7535\u5b50\u4ee5\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u7684\u50ac\u5316\u5242\u3002\u76ee\u524d\u5927\u91cf\u7684\u7814\u7a76\u81f4\u529b\u4e8e\u5b9e\u73b0\u9ad8\u50ac\u5316\u901f\u7387\uff0c\u5373\u9ad8\u8f6c\u6362\u9891\u7387(TOF)\u6216\u8f6c\u6362\u6570(TON)\u3002\u6b64\u5916\uff0c\u91cf\u5b50\u6548\u7387(QE)\u4e5f\u503c\u5f97\u5173\u6ce8\uff0c\u56e0\u4e3a\u5b83\u88ab\u8ba4\u4e3a\u662f\u8bc4\u4f30\u5149\u50ac\u5316\u7cfb\u7edf\u5149\u5b50\u8f6c\u5316\u4e3a\u4ea7\u54c1\u6548\u7387\u7684\u91cd\u8981\u5185\u5728\u53c2\u6570\u3002\u5b9e\u73b0\u9ad8 QE\u5177\u6709\u6311\u6218\u6027\uff0c\u56e0\u4e3a\u5b83\u53d7\u5230\u5149\u50ac\u5316\u7cfb\u7edf\u4e2d\u591a\u79cd\u56e0\u7d20\u7684\u9650\u5236\uff0c\u5305\u62ec\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd\u3001PS\u7684\u5149\u7269\u7406\u6027\u8d28\uff0c\u4ee5\u53caPS\u548c\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u5408\u7406\u8bbe\u8ba1\u50ac\u5316\u5242\u6216PSs\u5728\u4f18\u5316 CO2<\/sub> \u8fd8\u539f\u5206\u5b50\u7cfb\u7edf\u7684QE\u65b9\u9762\u6709\u5e0c\u671b\u53d6\u5f97\u91cd\u5927\u8fdb\u5c55\uff0c\u7279\u522b\u662f\u901a\u8fc7\u52a0\u5f3aPS\u548cPS\u4e4b\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\u6765\u8fdb\u4e00\u6b65\u4f18\u5316\u50ac\u5316\u5242QE\u3002<\/p>\n

\u5728\u6b64\u80cc\u666f\u4e0b\uff0c\u8feb\u5207\u9700\u8981\u6709\u6548\u7684\u7b56\u7565\u6765\u52a0\u901fPS\u4e0e\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\u3002\u8fd1\u5e74\u6765\uff0c\u5229\u7528\u5171\u4ef7\u952e\u5c06PS\u4e0e\u50ac\u5316\u5242\u8fde\u63a5\u5728\u4e00\u8d77\uff0c\u6784\u5efa\u8d85\u5206\u5b50\u5149\u50ac\u5316\u4f53\u7cfb\u7684\u7814\u7a76\u5df2\u7ecf\u5f00\u59cb\u3002\u5f00\u521b\u6027\u7684\u4f8b\u5b50\u5305\u62ecRe-\/Ru-bpy\u50ac\u5316\u5242\u548c\u4e0d\u540c\u7684PS\u7ec4\u5206\u4e4b\u95f4\u7684\u5171\u4ef7\u8fde\u63a5\uff0c\u4e00\u822c\u8868\u73b0\u4e3a\u5feb\u901f\u7684\u5206\u5b50\u5185\u7535\u8377\u8f6c\u79fb\uff0c\u5e76\u5b9e\u73b0\u9ad8QEs\u3002\u6b64\u5916\uff0c\u6700\u8fd1\u7684\u4e00\u4e2a\u4f8b\u5b50\u62a5\u9053\u4e86\u4e00\u4e2aZn -\u535f\u5549PS\u7684\u5408\u6210\uff0c\u5b83\u60ac\u6302\u5728Re-phen\u50ac\u5316\u6a21\u5757\u4e0a\uff0c\u5728420 nm\u663e\u793aTONs >1300\u548c8%\u7684QE\uff0c\u7528\u4e8e\u9ad8\u9009\u62e9\u6027CO2<\/sub>-to-CO\u5149\u8f6c\u6362\u3002\u7136\u800c\uff0c\u8fd9\u6837\u7684\u5de5\u4f5c\u9700\u8981\u5927\u91cf\u7684\u5408\u6210\u6765\u5236\u5907\u8fd9\u6837\u7684\u4e8c\u8054\u4f53\u5206\u5b50\u3002\u6b64\u5916\uff0c\u8106\u5f31\u7684\u5171\u4ef7\u63a5\u5934\uff08\u5982\u4e59\u7094\u6216\u9170\u80fa\u952e\uff09\u548c\u901a\u8fc7\u5171\u4ef7\u8fde\u63a5\u7684\u53cd\u5411\u7535\u5b50\u8f6c\u79fb\u53ef\u80fd\u5bfc\u81f4\u7a33\u5b9a\u6027\u548c\u6d3b\u6027\u7684\u4e0d\u53ef\u9006\u635f\u5931\u3002\u4e0e\u4f20\u7edf\u7684\u5171\u4ef7\u7b56\u7565\u76f8\u6bd4\uff0cPS\u548c\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u52a8\u6001\u7ed3\u5408\u53ef\u4ee5\u63d0\u4f9b\u7a33\u5b9a\u7684\u6027\u80fd\uff0c\u56e0\u4e3a\u52a8\u6001\u76f8\u4e92\u4f5c\u7528\u7684\u53ef\u9006\u7279\u6027\u53ef\u4ee5\u5b9e\u73b0\u81ea\u6211\u4fee\u6b63\u884c\u4e3a\u3002\u7136\u800c\uff0c\u9664\u4e86\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u7cfb\u7edf\u5916\uff0c\u6709\u6587\u732e\u8bb0\u8f7d\u7684\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u7684\u52a8\u6001\u7ec4\u88c5\u5f88\u5c11\u3002\u6b64\u5916\uff0c\u5206\u5b50\u95f4\u7535\u5b50\u8f6c\u79fb\u7684\u52a8\u529b\u5b66\u76f8\u4e92\u4f5c\u7528\u548c\u673a\u5236\u7814\u7a76\u5c1a\u4e0d\u660e\u786e\uff0c\u503c\u5f97\u6df1\u5165\u7814\u7a76\uff0c\u4e3a\u8fdb\u4e00\u6b65\u4f18\u5316\u8fd9\u7c7b\u7cfb\u7edf\u63d0\u4f9b\u601d\u8def\u3002\u56e0\u6b64\uff0c\u8feb\u5207\u9700\u8981\u63a2\u7d22\u67b6\u8d77PS\u4e0e\u50ac\u5316\u5242\u4e4b\u95f4\u52a8\u6001\u4ea4\u4e92\u4f5c\u7528\u7684\u7b56\u7565\u3002<\/p>\n

\u914d\u4f4d\u952e\u4f5c\u4e3a\u4e00\u79cd\u5171\u4ef7\u952e\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u4e00\u79cd\u7406\u60f3\u7684\u5206\u5b50\u95f4\u4f5c\u529b\u6765\u5438\u9644PS\u548c\u50ac\u5316\u5242\u3002\u8fd9\u79cd\u4e0d\u7a33\u5b9a\u7279\u6027\u8d4b\u4e88\u4e86\u534f\u8c03\u76f8\u4e92\u4f5c\u7528\u7cfb\u7edf\u7684\u52a8\u6001\u7a33\u5b9a\u6027\u3002\u540c\u65f6\uff0c\u9664\u4e86PS\u4e0e\u50ac\u5316\u5242\u5728\u6df7\u5408\u7269\u4e2d\u968f\u673a\u78b0\u649e\u7684\u4f20\u7edf\u5916\u7403\u7535\u5b50\u8f6c\u79fb\u5916\uff0c\u8fd8\u53ef\u4ee5\u901a\u8fc7\u914d\u4f4d\u4f5c\u7528\u4fc3\u8fdb\u5185\u7403\u7535\u5b50\u8f6c\u79fb(ISET) \uff0c\u65e2\u53ef\u4ee5\u662f\u7a33\u5b9a\u7684\u52a0\u5408\u7269\uff0c\u4e5f\u53ef\u4ee5\u662f\u8fc7\u6e21\u6001\u3002\u6709\u53ef\u80fd\u514b\u670d\u6269\u6563\u6781\u9650\u3002PS\u4e0e\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u8fd9\u79cd\u914d\u4f4d\u4f5c\u7528\u5df2\u88ab\u7528\u4e8e\u975e\u5747\u76f8\u6750\u6599\u4e0a\u7684\u6790\u6c22\u5206\u5b50\u4f53\u7cfb\u6216\u56fa\u5b9a\u5316\u5206\u5b50\u50ac\u5316\u5242\u3002\u53d4\u80fa\u4f5c\u4e3a\u6f5c\u5728\u727a\u7272\u8bd5\u5242\u4e0e\u5e73\u9762PSs\u4e4b\u95f4\u7684\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u4e5f\u6709\u62a5\u9053\u3002\u7136\u800c\uff0c\u5728\u5168\u5206\u5b50\u5149\u50ac\u5316\u4f53\u7cfb\u4e2d\uff0c\u5229\u7528PS\u4e0e\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u8fdb\u884cCO2<\/sub>\u51cf\u6392\u5c1a\u5c5e\u7f55\u89c1\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u5c71\u5927\u5b66\u6b27\u9633\u94a2\u950b<\/b><\/strong>\u56e2\u961f\u5728Nature Communications\u4e0a\u53d1\u8868\u6587\u7ae0\uff0c\u9898\u4e3a\u201cRapid electron transfer via dynamic coordinative interaction boosts quantum efficiency for photocatalytic CO2<\/sub>\u00a0reduction\u201d\u3002\u8be5\u56e2\u961f\u5229\u7528\u914d\u4f4d\u952e\u5c06\u5421\u5576\u57fa\u94f1\u5149\u654f\u5242\u548c\u5206\u5b50\u50ac\u5316\u5242\u8fde\u63a5\u8d77\u6765\u7528\u4e8eCO2<\/sub>\u8fd8\u539f\uff0c\u5e76\u901a\u8fc71H\u6838\u78c1\u5171\u632f\u6ef4\u5b9a\u3001\u7406\u8bba\u8ba1\u7b97\u548c\u5149\u8c31\u6d4b\u91cf\u7cfb\u7edf\u5730\u8bc1\u660e\u4e86\u8fd9\u4e00\u70b9\u3002\u7406\u7814\u7a76\u8868\u660e\uff0c\u5149\u654f\u5242\u548c\u672a\u6539\u6027\u94b4\u915e\u83c1\u4e4b\u95f4\u7684\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u663e\u8457\u52a0\u901f\u4e86\u7535\u5b50\u8f6c\u79fb\uff0c\u4ece\u800c\u5728450 nm\u5904\u5b9e\u73b0\u4e86\u51fa\u8272\u7684\u5149\u50ac\u5316 CO2<\/sub>\u8f6c\u5316\u4e3a CO \u91cf\u5b50\u6548\u7387\uff0810.2%\u00b10.5%\uff09\uff0c\u5176\u8f6c\u6362\u6570\u91cf\u9ad8\u8fbe391\u00b17\uff0c\u5e76\u5177\u6709\u63a5\u8fd1100%\u7684\u9009\u62e9\u6027\uff0c\u6bd4\u65e0\u989d\u5916\u76f8\u4e92\u4f5c\u7528\u7684\u5bf9\u6bd4\u7cfb\u7edf(2.4%\u00b10.2%)\u9ad84\u500d\u4ee5\u4e0a\u3002\u6b64\u5916\uff0c\u94b4\u915e\u83c1\u4e0a\u7ed9\u7535\u5b50\u6c28\u57fa\u7684\u4fee\u9970\u53ef\u4ee5\u5c06425 nm\u5904\u7684\u91cf\u5b50\u6548\u7387\u4f18\u5316\u81f327.9%\u00b10.8%\uff0c\u8fd9\u5f52\u56e0\u4e8e\u589e\u5f3a\u7684\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u800c\u4e0d\u662f\u5185\u5728\u6d3b\u6027\u3002\u5bf9\u7167\u5b9e\u9a8c\u8868\u660e\uff0c\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u7684\u52a8\u6001\u7279\u6027\u5bf9\u4e8e\u9632\u6b62\u4e0d\u7a33\u5b9a\u4f4d\u70b9\u7684\u914d\u4f4d\u5360\u636e\u5f88\u91cd\u8981\uff0c\u4e5f\u4f7f\u5f97\u5728\u5404\u79cd\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u4e0a\u5177\u6709\u5e7f\u6cdb\u7684\u9002\u7528\u6027\u3002<\/p>\n

\"\"<\/p>\n

\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1. \u6bd4\u8f83\u4e0d\u540c\u7684\u6865\u63a5PS\u548c\u50ac\u5316\u5242\u7684CO2<\/sub>\u51cf\u6392\u65b9\u6cd5\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2.\u00a0\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u7684\u8868\u5f81\u3002<\/p>\n

a.\u5728 0.20 mM IrQPY\u7684DMF-d7 \u6eb6\u6db2\u4e2d\u7528CoPc\u8fdb\u884c1H NMR\u6ef4\u5b9a\uff0c\u7a81\u51fa\u4e86\u4e00\u4e9b\u504f\u79fb\u7684\u8d28\u5b50\u4fe1\u53f7\u3002<\/p>\n

b IrQPY-CoPc\u548cIrQPY-(CoPc)2<\/sub> \u7684DFT\u8ba1\u7b97\u7ed3\u6784\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3.\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u3002<\/p>\n

a. \u4f7f\u7528IrQPY\/CoPc\uff08\u7ea2\u8272\uff09\u6216IrBPY\/CoPc\uff08\u84dd\u8272\uff09\u7cfb\u7edf\u7684\u5149\u50ac\u5316CO\uff08\u661f\u5f62\uff09\u548cH2<\/sub>\uff08\u4e94\u8fb9\u5f62\uff09\u5408\u6210\u7684\u65f6\u95f4\u66f2\u7ebf\u3002<\/p>\n

b. IrQPY\/CoPc\uff08\u7ea2\u8272\uff09\u548cIrBPY\/CoPc\uff08\u84dd\u8272\uff09\u7cfb\u7edf\u5408\u6210CO\u548cH2<\/sub>\u7684QE\u3002<\/p>\n

c. IrQPY\/CoPc\uff08\u7ea2\u8272\uff09\u7cfb\u7edf\u5149\u50ac\u5316CO\uff08\u661f\u5f62\uff09\u548cH2<\/sub>\uff08\u4e94\u8fb9\u5f62\uff09\u5408\u6210\u7684\u65f6\u95f4\u66f2\u7ebf\u30024\u5c0f\u65f6\u540e\uff0c\u5c06CoPc\uff080.4 mol\uff0c\u6a59\u8272\uff09\u3001IrQPY\uff080.4 mol\uff0c\u7eff\u8272\uff09\u6216BIH\uff0832 mol\uff0c\u84dd\u8272\uff09\u5206\u6563\u57280.5 mL CO2<\/sub>\u9971\u548c\u7684CH3<\/sub>CN\u4e2d\uff0c\u5e76\u5206\u522b\u6ce8\u5165\u6eb6\u6db2\u4e2d\u3002<\/p>\n

d. \u5728\u4e0d\u540c\u4f53\u79ef\u7684H2<\/sub>O\u4e2d\uff0c IrQPY\/CoPc\u5149\u50ac\u5316CO\uff08\u7d2b\u8272\uff09\u548cH2<\/sub>\uff08\u6a59\u8272\uff09\u7684\u4ea7\u7387\u7684\u4ee5\u53ca\u76f8\u5e94\u7684CO%\uff08\u84dd\u8272\u5706\u5708\uff09\u3002<\/p>\n

e. \u5728 30\u5206\u949f\u5185\uff0c150 mM BIH\u4e2d\uff0c 425 nm\u5149\u4e0b\uff0cIrQPY\/CoPc\u3001IrBPY\/CoPc IrQPY\/CoTAPc\u548cIrBPY\/CoTAPc\u7cfb\u7edf\u7684CO\uff08\u7d2b\u8272\uff09\u548cH2<\/sub>\uff08\u6a59\u8272\uff09\u5408\u6210\u7684QE\u3002<\/p>\n

f. \u5728N2<\/sub>\u4e0b\uff0c CoPc\uff08\u6a59\u8272\uff09\u548cCoTAPC\uff08\u7d2b\u8272\uff09\u7684CV\u3002\u56fe\u4e2d\u7684\u8bef\u5dee\u6761\u4ee3\u8868\u4e09\u4e2a\u72ec\u7acb\u6d4b\u91cf\u7684\u6807\u51c6\u504f\u5dee\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4. 1H NMR\u6ef4\u5b9a\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5.\u00a0\u52a8\u6001\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u7684\u5e7f\u6cdb\u9002\u7528\u6027\u3002<\/p>\n

a. FePor\u7684\u7ed3\u6784\u3002<\/p>\n

b. FePor (0.1 mM)\u3001IrQPY(\u84dd\u8272\uff0c1 mM)\u6216IrBPY(\u54c1\u7ea2\uff0c0.1 mM)\u3001TEA (2.5 v%)\u548cBIH (80 mM)\u7684\u6df7\u5408\u7269\u7684\u5149\u50ac\u5316CO(\u83f1\u5f62)\u548cH2<\/sub>(\u65b9\u5f62)\u5408\u6210\u65f6\u95f4\u66f2\u7ebf\u3002<\/p>\n

c. CoTPA\u7684\u7ed3\u6784\u3002<\/p>\n

d.CoTPA\uff081 mM\uff09\u3001IrQPY\uff08\u6a59\u8272\uff0c0.1 mM\uff09\u6216IrBPY\uff08\u7eff\u8272\uff0c0.1 mM\uff09\u3001PhOH\uff085.0 v%\uff09\u3001TEA\uff082.5 v%)\u548cBIH (80 mM)\u7684\u6df7\u5408\u7269\u7684\u5149\u50ac\u5316CO(\u83f1\u5f62)\u548cH2<\/sub>(\u65b9\u5f62)\u5408\u6210\u65f6\u95f4\u66f2\u7ebf\u3002<\/p>\n

e. \u5728\u7535\u5b50\u8f6c\u79fb\u548cCO2<\/sub>\u8fd8\u539f\u8fc7\u7a0b\u4e2dIrQPY\u548cCoPc\u7684\u53cd\u5e94\u673a\u5236\u3002<\/p>\n

f. \u5421\u5576\uff080.1 M\uff09\u3001CoPc\uff080.1 mM\uff09\u3001IrQPY\uff08\u7c89\u7ea2\u8272\uff0c0.1 mM\uff09\u6216IrBPY\uff08\u6d77\u519b\u84dd\uff0c0.1 mM\uff09\u3001TEA\uff082.5 v%)\u3001PhOH (6.0 v%)\u548cBIH (80 mM)\u7684\u6df7\u5408\u7269\u7684\u5149\u50ac\u5316CO(\u83f1\u5f62)\u548cH2<\/sub>(\u65b9\u5f62)\u5408\u6210\u65f6\u95f4\u66f2\u7ebf\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6.\u00a0\u77ac\u6001\u5438\u6536\u5149\u8c31<\/p>\n

a. 0.03 mM IrQPY\u7684TA\u8c31\u3002<\/p>\n

b. \u5728530 nm\uff0c\u4e0d\u5b58\u5728\uff08\u7ea2\u8272\uff09\u6216\u5b58\u5728\uff08\u6a59\u8272\uff0912 mM CoPc\u7684\u60c5\u51b5\u4e0b\uff0c0.03 mM IrQPY\u7684TA\u8870\u51cf\u8c31\u7ebf\u3002<\/p>\n

c. \u5728350 nm\u5904\uff0c\u542b\u67099 mM BIH\u65f6\uff0c0.03 mM IrQPY\u7684TA\u8870\u51cf\u8c31\u7ebf\u3002<\/p>\n

d. \u5728\u542b\u67090 mM DMT\u65f60.03 mM IrQPY\u7684TA\u8c31\u3002<\/p>\n

e. \u5728\u4e0d\u5b58\u5728\uff08\u7d2b\u8272\uff09\u6216\u5b58\u57286\uff08\u7c89\u7ea2\u8272\uff09\u300115\uff08\u7ea2\u8272\uff09\u300122\uff08\u6a59\u8272\uff09\u300130\uff08\u9ec4\u8272\uff09\u03bcM CoPc\u7684\u60c5\u51b5\u4e0b\uff0c0.03 mM IrQPY\u548c3.0 mM DMT\u5728350 nm\u4e0b\u7684TA\u8870\u51cf\u8c31\u7ebf\u3002<\/p>\n

f. \u5bf9IrQPY\u7cfb\u7edf\u8fdb\u884c\u7ebf\u6027\u62df\u5408\u5f97\u51fa\u7684(\u03c41<\/sub>\/\u03c4–<\/sub>1<\/sub>)\u4e0e[CoPc]\u7684\u5173\u7cfb\u56fe\u3002<\/p>\n

\u5c0f\u7ed3<\/b><\/strong><\/p>\n

\u5728\u7eaf\u5206\u5b50\u4f53\u7cfb\u4e2d\uff0cPS\u4e0e\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u88ab\u7528\u4e8e\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u3002\u901a\u8fc7\u5bf9\u6c27\u5316\u8fd8\u539f\u6027\u8d28\u3001\u5206\u5b50\u52a8\u529b\u5b66\u548c\u5149\u81f4\u7535\u5b50\u4f20\u9012\u7684\u7814\u7a76\uff0c\u63ed\u793a\u4e86\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u5728\u5149\u50ac\u5316\u673a\u5236\u4e2d\u7684\u4f5c\u7528\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0c\u52a8\u6001\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u4e0d\u4ec5\u52a0\u901f\u4e86\u5206\u5b50\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\uff0c\u800c\u4e14\u907f\u514d\u4e86\u5728\u4e0d\u7a33\u5b9a\u4f4d\u70b9\u7684\u7a33\u5b9a\u5360\u636e\uff0c\u4ece\u800c\u963b\u788d\u4e86\u5e95\u7269\u7684\u7ed3\u5408\u3002\u6700\u7ec8\uff0c\u4f18\u5316\u540e\u7684PS\u548c\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u534f\u540c\u4f5c\u7528\u5b9e\u73b0\u91cf\u5b50\u6548\u7387\u4f18\u5316\u81f327.9%\u00b10.8%\u3002\u4e0e\u6587\u732e\u8bb0\u8f7d\u7684\u5171\u4ef7\u7b56\u7565\u76f8\u6bd4\uff0c\u914d\u4f4d\u952e\u7684\u5e94\u7528\u5177\u6709\u52a8\u6001\u7279\u6027\u3001\u4eb2\u548c\u529b\u5408\u9002\u3001\u9002\u7528\u6027\u5e7f\u3001\u5bf9\u6761\u4ef6\u53d8\u5316\u7684\u8010\u53d7\u6027\u5f3a\u7b49\u4f18\u70b9\u3002\u8be5\u5de5\u4f5c\u63d0\u4f9b\u4e86\u4e00\u4e2a\u901a\u7528\u7684\u65b9\u6cd5\uff0c\u4ee5\u4fc3\u8fdb\u7535\u5b50\u8f6c\u79fb\u548c\u5bb9\u6613\u63d0\u9ad8\u5149\u50ac\u5316\u6548\u7387\u7684\u4e8c\u6c27\u5316\u78b3\u51cf\u6392\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aRapid electron transfer via dynamic coordinative interaction boosts quantum efficiency for photocatalytic CO<\/u>2<\/sub><\/u>\u00a0reduction. Nat Communications<\/u>, 2021,<\/u>\u00a012, 4276.<\/u><\/a><\/p>\n

\u672c\u6587\u7531\u7eb3\u7c73\u5c0f\u767d\u4f9b\u7a3f\u3002\u00a0<\/p>\n","protected":false},"excerpt":{"rendered":"

\u80cc\u666f\u4ecb\u7ecd \u6536\u96c6\u9633\u5149\u5c06\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u8f6c\u5316\u4e3a\u78b3\u8d28\u71c3\u6599\u4e00\u76f4\u88ab\u89c6\u4e3a\u5236\u9020\u78b3\u4e2d\u6027\u80fd\u6e90\u7684\u53ef\u6301\u7eed\u9014\u5f84\uff0c\u5e76\u6709\u671b\u7f13\u89e3\u6e29\u5ba4\u6c14\u4f53\u3002\u51ed\u501f\u7ed3\u6784\u660e\u786e\u548c\u5206\u5b50\u7ed3\u6784\u9ad8\u5ea6\u53ef\u8c03\u7b49\u4f18\u70b9\uff0c\u8bb8\u591a\u5316\u5b66\u5bb6\u81f4\u529b\u4e8e\u8bbe…<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-226770","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/226770"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=226770"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/226770\/revisions"}],"predecessor-version":[{"id":226784,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/226770\/revisions\/226784"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=226770"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=226770"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=226770"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}