{"id":226862,"date":"2021-09-04T06:30:35","date_gmt":"2021-09-03T22:30:35","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=226862"},"modified":"2021-09-03T16:41:04","modified_gmt":"2021-09-03T08:41:04","slug":"%e6%b8%af%e7%a7%91%e5%a4%a7am-%e4%ba%8c%e7%bb%b4ti3c2tx-mxene%ef%bc%9a%e7%ba%a2%e5%a4%96%e6%98%be%e7%99%bd%e7%9a%84%e9%bb%91%e8%89%b2%e6%9c%ac%e5%be%81%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=226862","title":{"rendered":"\u6e2f\u79d1\u5927AM:\u00a0\u4e8c\u7ef4Ti3C2Tx\u00a0MXene\uff1a\u7ea2\u5916\u663e\u767d\u7684\u9ed1\u8272\u672c\u5f81\u6750\u6599"},"content":{"rendered":"

\u7814\u7a76\u80cc\u666f<\/b><\/strong><\/p>\n

\u81ea\u7136\u754c\u4e2d\uff0c\u9664\u91d1\u5c5e\u6750\u6599\u5916\uff0c\u7edd\u5927\u591a\u6570\u7684\u6750\u6599\u90fd\u6709\u5f88\u9ad8\u7684\u7ea2\u5916\u53d1\u5c04\u7387\uff0c\u5373\u5728\u7ea2\u5916\u6ce2\u6bb5\u7c7b\u4f3c\u9ed1\u4f53\u3002\u5982\u6728\u5934\uff0c\u6c34\uff0c\u6ce5\u571f\uff0c\u77f3\u5934\uff0c\u591a\u6570\u5851\u6599\uff0c\u5e03\u6599\u548c\u4eba\u4f53\u7b49\u7684\u7ea2\u5916\u53d1\u5c04\u7387\u90fd\u572890%\u4ee5\u4e0a\u3002\u5e38\u89c1\u7684\u9ed1\u8272\u6750\u6599\u5982\u77f3\u58a8\uff0c\u70ad\u9ed1\u7b49\u4e5f\u90fd\u6709\u7740\u5f88\u9ad8\u7684\u53d1\u5c04\u7387\u548c\u7ea2\u5916\u5438\u6536\u7387\uff08\u7ea2\u5916\u663e\u9ed1\uff09\u3002\u9ed1\u8272\u7684\u4f4e\u7ea2\u5916\u53d1\u5c04\u6750\u6599\uff08\u7ea2\u5916\u663e\u767d\uff09\u5728\u81ea\u7136\u754c\u7684\u672c\u5f81\u6750\u6599\u4e2d\u66f4\u4e3a\u5c11\u89c1\uff0c\u4f46\u662f\u5728\u5f88\u591a\u9886\u57df\u90fd\u6709\u7740\u6781\u5927\u7684\u9700\u6c42\uff0c\u5982\u5149\u70ed\u8f6c\u6362\u3001\u591a\u9891\u8c31\u9690\u8eab\u3001\u9694\u70ed\u3001\u548c\u4fe1\u606f\u9632\u4f2a\u52a0\u5bc6\u7b49\u3002\u5149\u70ed\u8f6c\u6362\u9886\u57df\uff0c\u4f4e\u7ea2\u5916\u53d1\u5c04\u7387\u592a\u9633\u80fd\u5438\u6536\u6750\u6599\u53ef\u4ee5\u6291\u5236\u56e0\u8f90\u5c04\u6362\u70ed\u5bfc\u81f4\u7684\u80fd\u91cf\u635f\u5931\uff0c\u4ece\u800c\u83b7\u5f97\u6bd4\u9ed1\u4f53\u6750\u6599\u66f4\u9ad8\u7684\u5149\u70ed\u8f6c\u6362\u6548\u7387\u3002\u53e6\u5916\uff0c\u5373\u4f7f\u8fd9\u7c7b\u6750\u6599\u8868\u9762\u6e29\u5ea6\u9ad8\u4e8e\u9ed1\u4f53\u6750\u6599\uff0c\u4f4e\u53d1\u5c04\u7387\u4e5f\u4f7f\u5176\u5728\u7ea2\u5916\u63a2\u6d4b\u4e2d\u5f88\u597d\u5730\u9690\u85cf\u81ea\u5df1\uff0c\u540c\u65f6\u5b83\u7684\u6df1\u9ed1\u8272\u5916\u8868\u4f7f\u5176\u5728\u5f31\u5149\u6216\u8005\u9ed1\u591c\u5f88\u96be\u88ab\u53d1\u73b0\uff0c\u8fbe\u5230\u4e86\u7ea2\u5916\u548c\u53ef\u89c1\u5149\u4e0b\u7684\u53cc\u9891\u6bb5\u9690\u8eab\u6548\u679c\u3002\u7531\u4e8e\u672c\u5f81\u6750\u6599\u7f3a\u4e4f\u7406\u60f3\u7684\u5149\u8c31\u9009\u62e9\u6027\uff0c\u8fd9\u79cd\u53cd\u76f4\u89c9\u7684\u5149\u5b66\u7279\u6027\u4e0d\u5f97\u4e0d\u5229\u7528\u9ad8\u7cbe\u5c16\u7684\u7eb3\u7c73\u5236\u9020\u6280\u672f\u6784\u5efa\u590d\u6742\u7684\u4e9a\u6ce2\u957f\u8d85\u6750\u6599\u6765\u5b9e\u73b0\u3002<\/p>\n

\u6210\u679c\u7b80\u4ecb<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u9ec4\u5b9d\u9675\u6559\u6388\u56e2\u961f<\/b><\/strong>\u8054\u5408\u8d75\u5929\u5bff\u9662\u58eb\u56e2\u961f<\/b><\/strong>\u62a5\u9053\u4e86\u4e8c\u7ef4Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0MXene\u7684\u672c\u5f81\u4f4e\u7ea2\u5916\u53d1\u5c04\u7387\u7684\u7279\u6027\uff0c\u5e76\u4ece\u5b9e\u9a8c\u548c\u7406\u8bba\u4e24\u65b9\u9762\u8fdb\u884c\u4e86\u5145\u5206\u7684\u8bba\u8bc1\u3002\u5177\u4f53\u6765\u8bb2\uff0c\u867d\u7136\u4e8c\u7ef4Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0Mxene\u819c\u5728\u53ef\u89c1\u5149\uff0c\u8fd1\u7ea2\u5916\uff0c\u548c\u5fae\u6ce2\u6ce2\u6bb5\u6709\u5f88\u5f3a\u7684\u5438\u6536\u7279\u6027\uff0c\u4f46\u5728\u4e2d\u7ea2\u5916\uff082.5-20 \u5fae\u7c73\uff09\u6ce2\u6bb5\u8868\u73b0\u51fa\u9ad8\u8fbe90%\u7684\u53cd\u5c04\u7279\u6027\uff08\u56fe1\uff09\u3002\u6839\u636e\u57fa\u5c14\u970d\u592b\u70ed\u8f90\u5c04\u5b9a\u5f8b\uff0c\u00a0Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>T<\/b><\/strong>x<\/b><\/sub><\/strong>\u00a0MXene\u7684\u7ea2\u5916\u53d1\u5c04\u7387\u4f4e\u81f310%\u5de6\u53f3\uff0c\u4e0e\u629b\u5149\u7684\u4e0d\u9508\u94a2\u7247\u76f8\u8fd1\uff0c\u662f\u8fc4\u4eca\u4e3a\u6b62\u5df2\u77e5\u7684\u5177\u6709\u6700\u9ad8\u592a\u9633\u80fd\u5438\u6536\u9009\u62e9\u6027\u7684\u672c\u5f81\u6750\u6599\u3002<\/b><\/strong>\u5728\u4e00\u4e2a\u592a\u9633\u8f90\u7167\u4e0b\uff0c\u66b4\u9732\u5728\u7a7a\u6c14\u4e2d\u7684MXene\u819c\u76f8\u5bf9\u4e8e\u73af\u5883\u7684\u6e29\u5347\u9ad8\u8fbe62\u00b0C\uff0c\u8fd9\u662f\u7531\u4e8e\u4f4e\u7ea2\u5916\u53d1\u5c04\u7387\u6291\u5236\u4e86\u8f90\u5c04\u70ed\u635f\u5931\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u53d1\u5c04\u7387\u9ad8\u8fbe93%\u7684CNT\u819c\u5728\u4e00\u4e2a\u592a\u9633\u8f90\u7167\u4e0b\u7684\u6e29\u5347\u4ec5\u4e3a50\u00b0C\uff08\u56fe1\uff09\u3002\u4f5c\u8005\u8fd8\u63ed\u793a\u4e86\u8fd9\u79cd\u4f4e\u53d1\u5c04\u7387\u7279\u6027\u4e0eMXene\u7eb3\u7c73\u7247\u7684\u5806\u53e0\u65b9\u5f0f\u76f8\u5173\uff0c\u4f46\u4e0e\u539a\u5ea6\u65e0\u5173\uff08\u56fe2\uff09\u3002\u901a\u8fc7\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\uff0c\u4f5c\u8005\u4e0d\u4ec5\u8bc1\u5b9e\u4e86MXene\u6750\u6599\u7684\u4f4e\u53d1\u5c04\u7387\uff0c\u8fd8\u6709\u5f88\u591a\u66f4\u6709\u610f\u601d\u7684\u53d1\u73b0\uff08\u56fe4\uff09\u3002MXene\u6750\u6599\u7684\u4f4e\u53d1\u5c04\u7387\u548c\u7eb3\u7c73\u7247\u7684\u53d6\u5411\u548c\u672b\u7aef\u5b98\u80fd\u56e2\u3002\u5177\u4f53\u6765\u8bf4\uff0c\u5f53\u7eb3\u7c73\u7247\u4e0e\u886c\u5e95\u5e73\u884c\u6392\u5217\uff0c\u4e14\u672b\u7aef\u6709-OH\u548c-F\u5b98\u80fd\u56e2\u65f6\uff0c\u8584\u819c\u7684\u53d1\u5c04\u7387\u66f4\u4f4e\u3002\u4f5c\u8005\u6f14\u793a\u4e86\u8fd9\u79cd\u4f4e\u53d1\u5c04\u7387\u3001\u67d4\u6027\u7684\u9ed1\u8272\u672c\u5f81\u6750\u6599\u5728\u591a\u5b54\u57fa\u5e95\u5149\u70ed\u8f6c\u6362\u3001\u591a\u9891\u8c31\u9690\u8eab\u548c\u9632\u4f2a\u52a0\u5bc6\u4e0a\u7684\u5de8\u5927\u6f5c\u529b\uff08\u56fe3\uff09\u3002\u8be5\u5de5\u4f5c\u5f00\u542f\u4e86\u4e8c\u7ef4\u6750\u6599MXene\u5728\u4e2d\u7ea2\u5916\u6ce2\u6bb5\u7684\u7814\u7a76\u4e0e\u5e94\u7528\u7684\u53ef\u80fd\u6027\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c2D Ti<\/b><\/strong>3<\/b><\/sub><\/strong>C<\/b><\/strong>2<\/b><\/sub><\/strong>T<\/b><\/strong>x<\/b><\/sub><\/strong>\u00a0MXenes\uff1aVisible Black but Infrared White Materials<\/b><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAdvanced Materials<\/i><\/b><\/em><\/strong>\u4e0a\u3002\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u535a\u58eb\u540e\u7814\u7a76\u5458\u674e\u6d0b<\/b><\/strong>\uff0c\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u718a\u8bda\u535a\u58eb\uff0c\u9ec4\u6cb3\u535a\u58eb<\/b><\/strong>\u3002<\/p>\n

\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><\/p>\n

\u56fe1 \u629b\u5149\u91d1\u5c5e\u3001\u78b3\u6750\u6599\u548cMXene\u7684\u5149\u5b66\u7279\u6027<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a, c) \u629b\u5149\u4e0d\u9508\u94a2\u7247\u7684\u9ad8\u592a\u9633\u8c31\u53cd\u5c04\u548c\u9ad8\u7ea2\u5916\u53cd\u5c04\u7279\u6027\u3002<\/p>\n

(b, d) CNT\u819c\u7684\u9ad8\u592a\u9633\u8c31\u5438\u6536\u548c\u9ad8\u7ea2\u5916\u5438\u6536\u7279\u6027\u3002<\/p>\n

(e, f) MXene\u819c\u7684\u9ad8\u592a\u9633\u5438\u6536\u548c\u4f4e\u7ea2\u5916\u8c31\u5438\u6536\u7279\u6027\u3002<\/p>\n

(g) \u4e00\u4e2a\u592a\u9633\u8f90\u7167\u4e0b\uff0cMXene\u819c\u548cCNT\u819c\u7684\u6e29\u5347\u66f2\u7ebf\u3002<\/p>\n

(h) \u5e38\u89c1\u672c\u5f81\u6750\u6599\u7684\u592a\u9633\u80fd\u5438\u6536\u7387\u548c\u7ea2\u5916\u53d1\u5c04\u7387\u5bf9\u6bd4\u3002<\/p>\n

(i) \u7ea2\u5916\u6210\u50cf\u4eea\u4e0b\uff0c\u540c\u4e3a100\u00b0C\u7684\u629b\u5149\u4e0d\u9508\u94a2\u7247\uff0cCNT\u819c\u548cMXene\u819c\u7684\u56fe\u50cf\u5bf9\u6bd4\u3002<\/p>\n

\u56fe2 MXene\u819c\u7684\u8868\u5f81\u4e0e\u5149\u5b66\u7279\u6027<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a) MXene\u819c\u7684\u6a2a\u622a\u9762\u3002<\/p>\n

(b) MXene\u819c\u7684\u7167\u7247\u53caXRD\u66f2\u7ebf\u3002<\/p>\n

(c) MXene\u819c\u4e0a\u3001\u4e0b\u4e24\u9762\u7684\u5438\u6536\/\u53d1\u5c04\u5149\u8c31\u66f2\u7ebf\u3002<\/p>\n

(d) MXene\u819c\u4e0a\u3001\u4e0b\u4e24\u9762\u7684\u7ea2\u5916\u56fe\u50cf\u5bf9\u6bd4\u3002<\/p>\n

(e) MXene\u819c\u4e0a\u3001\u4e0b\u4e24\u9762\u7684\u8868\u9762\u5fae\u7ed3\u6784\u5bf9\u6bd4\u3002<\/p>\n

(f) MXene\u819c\u5438\u6536\/\u53d1\u5c04\u5149\u8c31\u66f2\u7ebf\u968f\u539a\u5ea6\u7684\u53d8\u5316\u3002<\/p>\n

\u56fe3 \u4f4e\u53d1\u5c04\u9ed1\u8272MXene\u6750\u6599\u7684\u6f5c\u5728\u5e94\u7528<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a-b) \u57fa\u4e8e\u591a\u5b54\u57fa\u5e95\u7684\u5149\u70ed\u8f6c\u6362\u5e94\u7528\uff0c\u5728\u591a\u5b54\u5c3c\u9f99\u57fa\u5e95\u4e0a\uff0cMXene\u819c\u7ef4\u6301\u4e86\u5f88\u9ad8\u7684\u5149\u8c31\u9009\u62e9\u6027\uff0c\u800c\u8d85\u6750\u6599\u5931\u53bb\u4e86\u5176\u9009\u62e9\u6027\u3002<\/p>\n

(c-d) \u591a\u9891\u6bb5\u9690\u8eab\u5e94\u7528\uff0cMXene\u6d82\u5c42\u5b9e\u73b0\u4e86\u5728\u7ea2\u5916\u548c\u53ef\u89c1\u5149\u6ce2\u6bb5\u7684\u53cc\u6ce2\u6bb5\u9690\u8eab\u3002<\/p>\n

(e-g) \u7ea2\u5916\u9632\u4f2a\u6d82\u5c42\u5e94\u7528\uff0cMXene\u58a8\u6c34\u548c\u666e\u901a\u7684\u9ed1\u8272\u58a8\u6c34\u642d\u914d\uff0c\u5b9e\u73b0\u4e86\u8089\u773c\u4e0d\u53ef\u5206\u8fa8\uff0c\u4f46\u7ea2\u5916\u53ef\u5206\u8fa8\u7684\u9632\u4f2a\u6548\u679c\u3002<\/p>\n

\u56fe4 \u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a) MXene\u7684\u5206\u5b50\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

(b-c) \u5e26\u6709\u4e0d\u540c\u672b\u7aef\u5b98\u80fd\u56e2\u7684Ti3<\/sub>C2<\/sub>\u00a0MXene \u7684\u4ecb\u7535\u5e38\u6570\u7684\u7684\u5b9e\u90e8\u548c\u865a\u90e8\u3002<\/p>\n

(d) \u5e26\u6709\u4e0d\u540c\u672b\u7aef\u5b98\u80fd\u56e2\u7684Ti3<\/sub>C2<\/sub>\u00a0MXene \u7684\u5438\u6536\/\u53d1\u5c04\u5149\u8c31\u66f2\u7ebf\u3002<\/p>\n

(e-f) Ti3<\/sub>C2<\/sub>\u548cTi3<\/sub>C2<\/sub>(OH)2<\/sub>\u00a0MXene \u5728x, y, z\u65b9\u5411\u4e0a\u4ecb\u7535\u5e38\u6570\u7684\u5b9e\u90e8\u548c\u865a\u90e8\u3002<\/p>\n

(g) Ti3<\/sub>C2<\/sub>\u00a0\u548cTi3<\/sub>C2<\/sub>(OH)2<\/sub>\u00a0MXene \u5728x, y, z\u65b9\u5411\u4e0a\u7684\u5438\u6536\/\u53d1\u5c04\u5149\u8c31\u66f2\u7ebf\u3002<\/p>\n

(h) \u9664Ti3<\/sub>C2<\/sub>\u00a0MXene\u5916\uff0c\u5176\u4ed6\u5982Ti2<\/sub>C\uff0cNb2<\/sub>C\uff0c\u548cV2<\/sub>C MXene\u7684\u5438\u6536\/\u53d1\u5c04\u5149\u8c31\u66f2\u7ebf\u3002<\/p>\n

\u5c0f\u7ed3<\/b><\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/adma.202103054<\/p>\n

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