{"id":226869,"date":"2021-09-05T06:30:13","date_gmt":"2021-09-04T22:30:13","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=226869"},"modified":"2021-09-04T23:28:06","modified_gmt":"2021-09-04T15:28:06","slug":"j-colloid-inter-sci-%ef%bc%9a%e5%ae%a4%e6%b8%a9%e4%b8%8b%e5%8e%bb%e8%b4%a8%e5%ad%90%e5%8c%96%e7%ad%96%e7%95%a5%e5%88%b6%e5%a4%87%e5%85%ad%e6%a3%b1%e6%9f%b1%e9%94%8c%e5%9f%bamof%e5%8f%8a%e5%85%b6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=226869","title":{"rendered":"J. Colloid Inter. Sci.\uff1a\u5ba4\u6e29\u4e0b\u53bb\u8d28\u5b50\u5316\u7b56\u7565\u5236\u5907\u516d\u68f1\u67f1\u950c\u57faMOF\u53ca\u5176\u9ad8\u6027\u80fd\u7535\u5bb9\u78b3\u6750\u6599"},"content":{"rendered":"

\u7b2c\u4e00\u4f5c\u8005\uff1a<\/b><\/strong>\u5218\u5a1c\u5a1c\u00a0<\/p>\n

\u901a\u8baf\u4f5c\u8005\uff1a<\/b><\/strong>\u6f58\u519b\u9752\u6559\u6388\u00a0<\/b><\/strong><\/p>\n

\u901a\u8baf\u5355\u4f4d\uff1a<\/b><\/strong>\u5317\u4eac\u5316\u5de5\u5927\u5b66<\/p>\n

\u8d85\u7ea7\u7535\u5bb9\u5668\uff08SPs\uff09\u4f5c\u4e3a\u4e00\u79cd\u65b0\u80fd\u6e90\u8bbe\u5907\uff0c\u56e0\u5176\u5177\u6709\u9ad8\u6bd4\u529f\u7387\u3001\u9ad8\u7a33\u5b9a\u6027\u7b49\u4f18\u70b9\uff0c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u7535\u52a8\u6c7d\u8f66\u3001\u98de\u673a\u3001\u4fbf\u643a\u5f0f\u6570\u7801\u8bbe\u5907\u7b49\u9886\u57df\u3002SPs\u5728\u5b9e\u73b0\u4f4e\u78b3\u7ecf\u6d4e\u4e2d\u53d1\u6325\u7740\u8d8a\u6765\u8d8a\u91cd\u8981\u7684\u4f5c\u7528\u3002\u56e0\u6b64\uff0c\u5bf9\u9ad8\u6bd4\u7535\u5bb9\u3001\u5faa\u73af\u5bff\u547d\u957f\u7684\u7535\u6781\u6750\u6599\u63d0\u51fa\u4e86\u66f4\u9ad8\u7684\u8981\u6c42\u3002\u5728\u5df2\u62a5\u9053\u7684\u7535\u5bb9\u6750\u6599\u4e2d\uff0c\u78b3\u6750\u6599\u5177\u6709\u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\u3001\u4e30\u5bcc\u7684\u591a\u5b54\u7ed3\u6784\u548c\u51fa\u8272\u7684\u5bfc\u7535\u6027\uff0c\u662f\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u4e3b\u8981\u6750\u6599\u4e4b\u4e00\u3002\u5df2\u62a5\u9053\u7684\u7528\u4e8e\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u78b3\u6750\u6599\u5305\u62ec\u591a\u5b54\u78b3\u3001\u78b3\u7eb3\u7c73\u7ba1\u548c\u77f3\u58a8\u70ef\u7b49\uff0c\u7136\u800c\uff0c\u5b83\u4eec\u7684\u6bd4\u7535\u5bb9\u4ecd\u4e0d\u80fd\u6ee1\u8db3\u4fbf\u643a\u5f0f\u8bbe\u5907\u7684\u9700\u6c42\u3002<\/p>\n

MOF\u884d\u751f\u7684\u591a\u5b54\u78b3\u56e0\u5176\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u3001\u5b54\u9699\u4e30\u5bcc\u3001\u7ed3\u6784\u7a33\u5b9a\u4e14\u53ef\u8c03\u8282\u7b49\u4f18\u70b9\u800c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u50a8\u80fd\u9886\u57df\u3002\u76ee\u524d\uff0cMOF\u7684\u5408\u6210\u5de5\u827a\u6bd4\u8f83\u590d\u6742\uff0c\u4e3b\u8981\u6709\u5fae\u6ce2\u8f85\u52a9\u5408\u6210\u3001\u6c34\u70ed\u5408\u6210\u3001\u754c\u9762\u7ec4\u88c5\u7b49\u3002\u8fd9\u4e9b\u65b9\u6cd5\u901a\u5e38\u9700\u8981\u7279\u5b9a\u7684\u53cd\u5e94\u88c5\u7f6e\uff0c\u53cd\u5e94\u65f6\u95f4\u957f\uff0c\u80fd\u8017\u9ad8\uff0c\u53cd\u5e94\u6761\u4ef6\u82db\u523b\uff0c\u5408\u6210\u6210\u672c\u9ad8\u4e14\u5408\u6210\u8fc7\u7a0b\u5177\u6709\u4e00\u5b9a\u7684\u5b89\u5168\u9690\u60a3\u3002\u56e0\u6b64\uff0c\u5728\u5ba4\u6e29\u4e0b\u9ad8\u6548\u5927\u89c4\u6a21\u5408\u6210MOF\u524d\u9a71\u4f53\u662f\u964d\u4f4eMOF\u884d\u751f\u78b3\u6750\u6599\u6210\u672c\u5e76\u4fc3\u8fdb\u5176\u5de5\u4e1a\u5316\u751f\u4ea7\u7684\u6709\u6548\u9014\u5f84\u3002<\/p>\n

\u3010\u5de5\u4f5c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u6709\u9274\u4e8e\u6b64\uff0c\u5317\u4eac\u5316\u5de5\u5927\u5b66\u6f58\u519b\u9752<\/b><\/strong>\u6559\u6388\u56e2\u961f\u63d0\u51fa\u4e86\u4e00\u79cd\u5728\u5ba4\u6e29\u4e0b\u4f7f\u7528\u53bb\u8d28\u5b50\u5316<\/b><\/strong>BTC\u548c\u918b\u9178\u950c\u4e00\u6b65\u6cd5\u5236\u5907\u516d\u68f1\u67f1Zn-MOF\u7684\u65b9\u6cd5\u3002<\/b><\/strong>Zn-MOF\u76f4\u63a5\u78b3\u5316\u5f97\u5230\u516d\u65b9\u68f1\u67f1\u591a\u5b54\u78b3\uff08BTCC\uff09\uff0c\u65e0\u9700\u6a21\u677f\u548c\u8fdb\u4e00\u6b65\u7684\u6d3b\u5316\u8fc7\u7a0b\u3002\u8be5\u65b9\u6cd5\u5927\u5927\u7f29\u77ed\u4e86MOF\u7684\u5408\u6210\u65f6\u95f4\uff0c\u4e14\u5408\u6210\u8fc7\u7a0b\u6613\u4e8e\u64cd\u4f5c\u3002\u83b7\u5f97\u7684BTCC\u5177\u67091,464 m2<\/sup>\u00a0g-1<\/sup>\u7684\u9ad8\u6bd4\u8868\u9762\u3002\u5728\u4e09\u7535\u6781\u6d4b\u8bd5\u4e0b\uff0c\u591a\u5b54\u78b3\u7535\u6781\u8868\u73b0\u51fa\u9ad8\u6bd4\u7535\u5bb9\u548c\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002BTCC\u7535\u6781\u7ec4\u88c5\u7684\u53cc\u7535\u5c42\u7535\u5bb9\u5668C|1M Na2<\/sub>SO4<\/sub>|C\u548cC|6M KOH|C\uff0c\u5206\u522b\u53ef\u4ee5\u63d0\u4f9b22.4 Wh kg-1<\/sup>\u548c13.7 Wh kg-1<\/sup>\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cA new rapid synthesis of hexagonal prism Zn-MOF as a precursor at room temperature for energy storage through pre-ionization strategy\u201d\u4e3a\u9898\u53d1\u8868\u5728\u671f\u520aJournal of Colloid and Interface Science\u4e0a\uff0cDOI: 10.1016\/j.jcis.2021.08.105\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1.\u00a0BTCC\u5236\u5907\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u6838\u5fc3\u5185\u5bb9\u3011<\/b><\/strong><\/p>\n

1<\/b><\/strong>.<\/b><\/strong>\u4f18\u5316\u524d\u9a71\u4f53\u5236\u5907\u6761\u4ef6<\/b><\/strong><\/p>\n

\u4f18\u5316Zn-MOF\u524d\u9a71\u4f53\u5236\u5907\u6761\u4ef6\uff0c\u6700\u4f73\u6761\u4ef6\uff1a\u53cd\u5e94\u65f6\u95f4\u4e3a0.5 h\uff0cZnAc2<\/sub>\u548cNa3<\/sub>BTC\u7684\u8fdb\u6599\u6bd4\u4e3a1:1\uff0cC2<\/sub>H5<\/sub>OH:CH3<\/sub>OH (v:v)=1:1\u3002\u56fe2c\u663e\u793a\u4e86Zn-MOF\u5408\u6210\u7b56\u7565\u4e0e\u5176\u4ed6\u65b9\u6cd5\u7684\u6bd4\u8f83\u3002\u8be5\u7b56\u7565\u5b9e\u73b0\u4e86\u5ba4\u6e29\u4e0bMOF\u7684\u5feb\u901f\u5408\u6210\uff0c\u5927\u5927\u964d\u4f4e\u4e86\u53cd\u5e94\u7684\u80fd\u8017\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2.\u4e0d\u540c\u5408\u6210\u6761\u4ef6\u4e0bMOF\u7684\u7535\u5316\u5b66\u6027\u80fd\u548c\u5f62\u8c8c\u8868\u5f81\u3002<\/p>\n

2<\/b><\/strong>. <\/b><\/strong>BTCC\u7684\u5f62\u8c8c\u8868\u5f81<\/b><\/strong><\/p>\n

\u56fe3\u663e\u793a\u4e86Zn-BTC\u3001ZnO\/C\u548cBTC\u7684SEM\u56fe\u50cf\u3002\u53ef\u4ee5\u770b\u51fa\uff0c\u5728\u78b3\u5316\u8fc7\u7a0b\u4e2d\u516d\u68f1\u67f1\u7ed3\u6784\u5f97\u4ee5\u4fdd\u6301\u3002\u56fe4\u63ed\u793a\u4e86Zn\u3001C\u548cO\u5143\u7d20\u542b\u91cf\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684\u53d8\u5316\u3002\u968f\u7740Zn\u84b8\u53d1\u548c\u7fa7\u57fa\u88c2\u89e3\u53cd\u5e94\u7684\u8fdb\u884c\uff0cZn\u548cO\u7684\u6d53\u5ea6\u9010\u6e10\u964d\u4f4e\uff0c\u7a00HNO3<\/sub>\u5904\u7406\u540e\uff0cZnO\u88ab\u5b8c\u5168\u53bb\u9664\uff08\u56fe4c\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3. SEM\u56fe\uff1a(a) Zn-BTC\uff1b(b) ZnO\/C\uff1b(c) BTCC\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4.\u00a0mapping\u8868\u5f81\uff1a(a) Zn-BTC\uff1b(b) ZnO\/C\uff1b(c) BTCC\u3002<\/p>\n

TEM\u548cHR-TEM\u6d4b\u8bd5\u8fdb\u4e00\u6b65\u5206\u6790\u4ea7\u7269\u7684\u5fae\u89c2\u7ed3\u6784\u3002\u56fe5a\u663e\u793a\u4e86\u6240\u5f97ZnO\/C\u4e3a\u5b9e\u5fc3\u516d\u68f1\u67f1\u7ed3\u6784\u3002ZnO\/C\u8868\u9762\u5448\u73b0\u51fa\u6e05\u6670\u7684\u5b54\u7ed3\u6784\uff0c\u5185\u90e8\u5f62\u6210\u7684\u5c11\u91cf\u6676\u4f53\u9897\u7c92d\u95f4\u8ddd\u503c\u4e3a0.36 nm\u548c0.48 nm\uff0c\u5bf9\u5e94\u4e8eZnO\u7684(002)\u548c(101)\u6676\u9762\u3002HNO3<\/sub>\u5904\u7406\u540e\uff0c\u78b3\u8868\u9762\u53d8\u5f97\u7a00\u758f\uff0c\u8868\u9762\u5b54\u9699\u589e\u5927\u4e14\u5206\u5e03\u5747\u5300\u3002\u56fe5b (iii) SAED\u56fe\u50cf\u4e2d\u6ca1\u6709ZnO\u7684\u884d\u5c04\u73af\uff0c\u8bc1\u660e\u9178\u6d17\u540e\u6ca1\u6709\u91d1\u5c5e\u5b58\u5728\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5.\u00a0HR-TEM\u548cSAED\u56fe\u50cf\uff1a(a) ZnO\/C\uff1b(b) BTCC\u3002<\/p>\n

3. BTCC\u7684\u7ed3\u6784\u8868\u5f81<\/b><\/strong><\/p>\n

\u56fe6a\u663e\u793a\u4e86Zn-BTC\u3001ZnO\/C\u548cBTCC\u7684XRD\u8c31\u3002Zn-BTC\u7684\u5cf0\u4e0e\u5df2\u62a5\u9053\u7684\u6587\u732e\u4e00\u81f4\u3002ZnO\u7684\u7279\u5f81\u884d\u5c04\u5cf0\u51fa\u73b0\u572831.7\u00b0\u300134.4\u00b0\u300136.2\u00b0\u548c47.5\u00b0\u5bf9\u5e94\u4e8eZnO(JCPDS NO.70-2551)\u7684(100) (002) (101) (102)\u6676\u9762\u3002BTC\u4e2d\u4ec5\u51fa\u73b0\u78b3\u7684\u7279\u5f81\u5cf0\uff0c\u572826.3\u00b0 \u548c44.3\u00b0\u7684\u5cf0\u5f52\u56e0\u4e8eC\uff08JCPDS No. 41-1487\uff09\u7684(002) (101)\u6676\u9762\u3002XRD\u7684\u7ed3\u679c\u4e0e\u56fe4\u4e2d\u7684\u5143\u7d20\u5206\u5e03\u548c\u56fe6c\u548cd\u4e2d\u7684XPS\u7ed3\u679c\u4e00\u81f4\u3002\u62c9\u66fc\u6d4b\u8bd5\u770b\u51fa\uff0c\u7531\u4e8eZnO\u9897\u7c92\u7684\u53bb\u9664\uff0cBTCC\u4e0eZnO\/C\u76f8\u6bd4\u65e0\u5e8f\u5ea6\u589e\u52a0\u3002BTCC\u7684BET-SSA\u4e3a1,464 m2 g-1<\/sup>\uff0c\u5b54\u4f53\u79ef\u4e3a1.571 cm3 g-1<\/sup>\uff0c\u5e76\u4e14\u5b58\u5728\u5927\u91cf\u4ecb\u5b54\u3002\u4e30\u5bcc\u7684\u591a\u7ea7\u5b54\u5206\u5e03\u6709\u5229\u4e8e\u7535\u89e3\u8d28\u4e2d\u79bb\u5b50\u7684\u5feb\u901f\u4ea4\u6362\uff0c\u4ece\u800c\u63d0\u9ad8\u500d\u7387\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6.\u00a0(a) Zn-BTC\u3001ZnO\/C\u548cBTCC\u7684XRD\u8c31\u56fe\uff1b(b) ZnO\/C\u548cBTCC\u7684\u62c9\u66fc\u5149\u8c31\uff1b(c-d) Zn-BTC\u3001ZnO\/C\u548cBTCC\u7684XPS\u5149\u8c31\uff1a(c) Zn 2p\u548c(d) C 1s\uff1b(e)\u6c2e\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf\uff1b(f) ZnO\/C\u548cBTCC\u7684\u5b54\u5f84\u5206\u5e03\u3002<\/p>\n

4<\/b><\/strong>. <\/b><\/strong>BTCC\u4e09\u7535\u6781\u4f53\u7cfb\u7535\u5316\u5b66\u6d4b\u8bd5<\/b><\/strong><\/p>\n

\u5728\u4e09\u7535\u6781\u6d4b\u8bd5\u4e2d\uff0cCV\u66f2\u7ebf\u572810-200 mVs-1<\/sup>\u7684\u626b\u63cf\u901f\u7387\u4e0b\u5747\u5448\u73b0\u51c6\u77e9\u5f62\u5f62\u72b6\u3002\u626b\u901f\u4e3a10 mV s-1<\/sup>\u65f6\uff0cBTCC\u53ef\u4ee5\u63d0\u4f9b310 F g-1<\/sup>\u7684\u6bd4\u7535\u5bb9\uff0c\u5145\u653e\u7535\u66f2\u7ebf\u572810-100 mV s-1<\/sup>\u5185\u4fdd\u6301\u5e73\u7a33\u5e76\u91cd\u53e0\uff0c\u8bc1\u5b9e\u4e86BTCC\u5353\u8d8a\u7684\u500d\u7387\u6027\u80fd\u3002\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u5448\u73b0\u51fa\u975e\u5e38\u5bf9\u79f0\u7684\u4e09\u89d2\u5f62\uff0c\u8868\u660e\u53cc\u7535\u5c42\u7684\u9ad8\u53ef\u9006\u5438\u9644\/\u89e3\u5438\u8fc7\u7a0b\u3002BTCC\u6837\u54c1\u57281A g-1<\/sup>\u4e0b\u63d0\u4f9b\u7684\u6bd4\u7535\u5bb9\u4e3a285 F g-1<\/sup>\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a50 A g-1<\/sup>\u65f6\uff0c\u6bd4\u7535\u5bb9\u4e3a\u521d\u59cb\u503c\u768481.5%\uff0c\u663e\u793a\u51fa\u5176\u5353\u8d8a\u7684\u500d\u7387\u6027\u80fd\uff0c\u8fd9\u5f97\u76ca\u4e8e\u5176\u7a33\u5b9a\u4e30\u5bcc\u7684\u5fae\u5b54\u548c\u4e2d\u5b54\u7ed3\u6784\uff0c\u4f7f\u5f97\u5145\u653e\u7535\u8fc7\u7a0b\u5177\u6709\u9ad8\u53ef\u9006\u6027\u548c\u8fd1100%\u7684\u5e93\u4ed1\u6548\u7387\u3002\u53e6\u5916\uff0c\u57281.0\u00d7104<\/sup>\u5468\u671f\u4e2d\uff0c\u6240\u6709CV\u66f2\u7ebf\u5747\u4fdd\u6301\u5b8c\u6574\u7684\u77e9\u5f62\u5f62\u72b6\uff0c\u5e76\u4e14\u51e0\u4e4e\u5f7c\u6b64\u91cd\u53e0\u3002\u572850 A g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af1.2\u00d7105<\/sup>\u6b21\u540e\uff0cBTCC\u7535\u6781\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u9ad8\u8fbe94.5%\uff0c\u5faa\u73af\u6d4b\u8bd5\u8868\u660e\uff0cBTCC\u5177\u6709\u51fa\u8272\u7684\u8010\u4e45\u6027\u3002\u7ed3\u679c\u8868\u660e\uff0c\u6240\u5236\u5907\u7684BTCC\u6750\u6599\u5177\u6709\u4f18\u5f02\u7684\u7535\u5bb9\u6027\u80fd\u548c\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u5b8c\u5168\u6ee1\u8db3\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u7684\u8981\u6c42\u3002<\/p>\n

\"\"<\/p>\n

\u56fe7. BTCC\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1a(a) \u4e0d\u540c\u626b\u63cf\u901f\u7387(10-600 mV s-1<\/sup>)\u4e0b\u7684CV\u66f2\u7ebf\uff1b(b) \u626b\u63cf\u901f\u7387\u4e0e\u6bd4\u7535\u5bb9\u7684\u5173\u7cfb\u66f2\u7ebf\uff1b(c) \u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\uff081-150 A g-1<\/sup>\uff09\u7684GCD\u66f2\u7ebf\uff1b(d) BTCC\u7535\u6781\u6750\u6599\u4e0e\u5df2\u62a5\u5bfc\u7684\u78b3\u6750\u6599\u7684\u6bd4\u7535\u5bb9\u5bf9\u6bd4\u56fe\uff1b(e) \u5728200 mV s-1<\/sup>\u626b\u63cf\u901f\u7387\u4e0b\uff0c10,000\u6b21\u5faa\u73af\u7684CV\u66f2\u7ebf\uff1b(f) \u572850 A g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c100,000\u6b21\u5faa\u73af\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002\uff08\u63d2\u56fe\uff1a\u83b7\u5f97\u7684BTCC\u7535\u6781\u4e0e\u5df2\u62a5\u9053\u7684MOF\u884d\u751f\u78b3\u6750\u6599\u5728\u5faa\u73af\u7a33\u5b9a\u6027\u65b9\u9762\u7684\u6bd4\u8f83\uff09<\/p>\n

5<\/b><\/strong>. <\/b><\/strong>BTCC\u4e24\u7535\u6781\u4f53\u7cfb\u7535\u5316\u5b66\u6d4b\u8bd5<\/b><\/strong><\/p>\n

\u4e3a\u4e86\u8bc1\u660e\u5176\u5b9e\u9645\u5e94\u7528\uff0c\u7814\u7a76\u8005\u4f7f\u7528BTCC\u7535\u6781\u7ec4\u88c5\u4e86\u4e24\u4e2a\u5bf9\u79f0\u8d85\u7ea7\u8d85\u5bb9\u5668(C|1M Na2<\/sub>SO4<\/sub>|C\u548cC|6M KOH|C)\u6d4b\u8bd5\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002\u56fe8a\u548cb\u663e\u793a\u4e86\u572820 mV s-1<\/sup>\u4e0b\uff0cC|1M Na2<\/sub>SO4<\/sub>|C\u548cC|6M KOH|C\u4e0d\u540c\u7535\u538b\u7a97\u53e3\u7684CV\u66f2\u7ebf\u3002\u5bf9\u4e8eC|1 M Na2<\/sub>SO4<\/sub>|C\uff0c\u5728 0-1.8V\u7684\u6700\u4f73\u7a97\u53e3\u5185\u53ef\u4ee5\u5145\u5206\u53d1\u6325\u5176\u6709\u6548\u7a33\u5b9a\u7684\u5145\u653e\u7535\u6027\u80fd\u3002\u540c\u6837\uff0cC|6M KOH|C \u7684\u6700\u4f73\u7535\u538b\u7a97\u53e3\u4e3a0 -1.3 V\u3002\u56fe8c\u548cd\u662f\u4e24\u79cd\u5668\u4ef6\u5728\u7684GCD\u66f2\u7ebf\u3002C|1 M Na2<\/sub>SO4<\/sub>|C\u57281 A g-1<\/sup>\u4e0b\u63d0\u4f9b99.8 F g-1<\/sup>\u7684\u6bd4\u5bb9\u91cf\u3002\u5f53\u529f\u7387\u5bc6\u5ea6\u4e3a450 W kg-1<\/sup>\u65f6\uff0c\u5b83\u53ef\u4ee5\u63d0\u4f9b22.4 Wh kg-1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u76f8\u5e94\u5730\uff0cC|6M KOH|C\u57281 A g-1<\/sup>\u65f6\u63d0\u4f9b101.7 F g-1<\/sup>\u7684\u6bd4\u5bb9\u91cf\uff0c\u5728650 W kg-1<\/sup>\u65f6\u5177\u670913.7 Wh kg-1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u56fe8e\u4e2d\u6bd4\u8f83\u4e86C|1 M Na2<\/sub>SO4<\/sub>|C\u3001C|6 M KOH|C\u4e0e\u5df2\u62a5\u544a\u7684EDLC\u7684Ragone\u56fe\u3002C|1 M Na2<\/sub>SO4<\/sub>|C\u63d0\u4f9b\u7684\u80fd\u91cf\u5bc6\u5ea6\u8fdc\u9ad8\u4e8e\u62a5\u544a\u7684EDLC\u3002\u6b64\u5916\uff0c\u56fe8f\u4e2d\u663e\u793a\u4e86C|1M Na2<\/sub>SO4<\/sub>|C\u548cC|6M KOH|C\u572820 A g-1<\/sup>\u4e0b\u5faa\u73af1.0\u00d7104<\/sup>\u6b21\u7684\u7a33\u5b9a\u6027\uff0c\u80fd\u91cf\u5bc6\u5ea6\u4fdd\u6301\u7387\u5206\u522b\u4e3a80.0%\u548c89.4%\u3002<\/p>\n

\"\"<\/p>\n

\u56fe8. \u57fa\u4e8eBTCC\u7684\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u5316\u5b66\u6027\u80fd\uff08\u5206\u522b\u4ee51 M Na2<\/sub>SO4<\/sub>\u548c 6 M KOH\u4e3a\u7535\u89e3\u6db2\uff09\uff1a(a)\u00a0C|1M Na2<\/sub>SO4<\/sub>|C\u57281.0 –\u00a02.0 V\u4e0d\u540c\u7535\u4f4d\u7a97\u53e3\u7684CV\u66f2\u7ebf\uff0c\u626b\u63cf\u901f\u7387\u4e3a 20 mV s\u00a0-1<\/sup>\u3002(b) C|6M KOH|C\u57280-1.5 V\u4e0d\u540c\u7535\u4f4d\u7a97\u53e3\u7684CV\u66f2\u7ebf\u3002(c,d) C|1M Na2<\/sub>SO4<\/sub>|C\u548cC|6M KOH|C\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684GCD\u66f2\u7ebf\u3002(e)\u7ec4\u88c5\u7684\u4e24\u4e2a\u8d85\u7ea7\u7535\u5bb9\u5668\u4e0e\u62a5\u544aEDLC\u7684Ragone\u56fe\u3002(f) \u4e24\u79cd\u5668\u4ef6\u572820 A g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8fdb\u884c10,000\u6b21\u5faa\u73af\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002\uff08\u63d2\u5165\uff1aC|1M Na2<\/sub>SO4<\/sub>|C\u8d85\u7ea7\u7535\u5bb9\u5668\u70b9\u4eae\u7684LED\u6307\u793a\u706f\u3002\uff09<\/p>\n

\u3010\u603b\u7ed3\u5c55\u671b\u3011<\/b><\/strong><\/p>\n

\u603b\u4e4b\uff0c\u901a\u8fc7\u918b\u9178\u950c\u548cNa3<\/sub>BTC\u7684\u4e00\u6b65\u6c89\u6dc0\u6210\u529f\u5236\u5907\u4e86Zn-BTC\u3002\u901a\u8fc7\u7145\u70e7\u8be5\u524d\u9a71\u4f53\uff0c\u6210\u529f\u5236\u5907\u4e86\u5177\u6709\u4e30\u5bcc\u5b54\u9699\u7ed3\u6784\u7684\u591a\u5b54\u78b3\uff08BTCC\uff09\u3002\u5236\u5907\u7684BTCC\u5177\u6709\u9ad8\u6bd4\u8868\u9762(1,464 m2<\/sup>\u00a0g-1<\/sup>) \u548c3.9 nm\u7684\u5408\u9002\u5b54\u5f84\u3002BTCC\u4e30\u5bcc\u7684\u591a\u5b54\u7ed3\u6784\u63d0\u4f9b\u4e86\u5353\u8d8a\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u6027\u80fd\uff0c\u5305\u62ec\u572810 mV s-1<\/sup>\u00a0\u4e0b\u7684310 F g-1<\/sup>\u6bd4\u7535\u5bb9\u548c\u51fa\u8272\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u7ec4\u88c5\u7684\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668C|1M Na2<\/sub>SO4<\/sub>|C\u548cC|6M KOH|C\u5206\u522b\u63d0\u4f9b\u4e8622.4 Wh kg-1<\/sup>\u548c13.7 Wh kg-1<\/sup>\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3002\u4e24\u79cd\u8d85\u7ea7\u7535\u5bb9\u5668\u90fd\u63d0\u4f9b\u6bd4\u62a5\u9053\u7684EDLC\u9ad8\u5f97\u591a\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u572820 A g-1<\/sup>\u4e0b\u5faa\u73af1.0\u00d7104<\/sup>\u00a0\u6b21\u540e\uff0c\u4fdd\u6301\u7387\u5206\u522b\u4e3a 80.0% \u548c 89.4%\u3002\u8be5\u5de5\u4f5c\u63d0\u51fa\u4e86\u4e00\u79cd\u5236\u5907MOF\u7684\u6709\u6548\u5408\u6210\u65b9\u6cd5\uff0c\u8be5\u65b9\u6cd5\u5c06\u663e\u7740\u964d\u4f4eMOF\u884d\u751f\u78b3\u6750\u6599\u7684\u6210\u672c\uff0c\u5e76\u5c06\u6210\u4e3a\u5de5\u4e1a\u5e94\u7528\u7684\u4e00\u4e2a\u6709\u524d\u666f\u7684\u7b56\u7565\u3002<\/p>\n

\u9898\u76ee\uff1a<\/b><\/strong>A new rapid synthesis of hexagonal prism Zn-MOF as a precursor at room temperature for energy storage through pre-ionization strategy<\/p>\n

\u4f5c\u8005\uff1a<\/b><\/strong>Nana Liu, Xiaoguang Liu, Junqing Pan*<\/p>\n

DOI: 10.1016\/j.jcis.2021.08.105<\/p>\n

\u672c\u6587\u7531\u4f5c\u8005\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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