{"id":226886,"date":"2021-09-06T06:30:48","date_gmt":"2021-09-05T22:30:48","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=226886"},"modified":"2021-09-04T23:23:24","modified_gmt":"2021-09-04T15:23:24","slug":"%e6%b1%9f%e8%a5%bf%e7%90%86%e5%b7%a5metall-mater-trans-a%e7%b3%bb%e5%88%97%e5%9b%9b%e6%96%87%ef%bc%9a%e9%92%a2%e4%b8%ad%e9%93%8c%e9%92%92%e9%92%9b%e7%a2%b3%e6%b0%ae%e5%8c%96%e7%89%a9%e5%9b%ba","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=226886","title":{"rendered":"\u6c5f\u897f\u7406\u5de5Metall. Mater. Trans. A\u7cfb\u5217\u56db\u6587\uff1a\u94a2\u4e2d\u94cc\u9492\u949b\u78b3\u6c2e\u5316\u7269\u56fa\u6eb6\u5ea6\u79ef"},"content":{"rendered":"<p><strong>\u80cc\u666f\u4ecb\u7ecd<\/strong><\/p>\n<p>\u91d1\u5c5e\u5143\u7d20Nb\u3001V\u3001Ti\u662f\u94a2\u4e2d\u78b3\u5316\u7269\u3001\u6c2e\u5316\u7269\u5f62\u6210\u5143\u7d20\uff0c\u5b83\u4eec\u5728\u5fae\u5408\u91d1\u94a2\u4e2d\u901a\u5e38\u4ee5\u56fa\u6eb6\u548c\u7b2c\u4e8c\u76f8\u5f62\u5f0f\u5b58\u5728\uff0c\u5f53\u7b2c\u4e8c\u76f8\u7684\u5c3a\u5bf8\u8fbe\u5230\u7eb3\u7c73\u7ea7\u522b\u65f6\uff0c\uff081\uff09\u4f1a\u4ea7\u751f\u5f3a\u70c8\u7684\u5f25\u6563\u5f3a\u5316\u4f5c\u7528\uff0c\uff082\uff09\u5f53\u5b83\u4eec\u5177\u6709\u8f83\u9ad8\u7684\u70ed\u7a33\u5b9a\u6027\u65f6\uff0c\u4f1a\u5f3a\u70c8\u6291\u5236\u9ad8\u6e29\u8fc7\u7a0b\u4e2d\u5965\u6c0f\u4f53\u6676\u7c92\u7684\u957f\u5927\uff0c\u6709\u5229\u4e8e\u7ec6\u5316\u6676\u7c92\u548c\u63d0\u9ad8\u710a\u63a5\u6027\u3002\u5728\u5bf9\u7b2c\u4e8c\u76f8\u4f5c\u7528\u6548\u679c\u5b9a\u91cf\u5206\u6790\u65f6\uff0c\u901a\u5e38\u9700\u8981\u83b7\u5f97\u5176\u5728\u94a2\u4e2d\u5206\u6570\u4fe1\u606f\uff0c\u56e0\u800c\u9700\u8981\u5229\u7528\u7b2c\u4e8c\u76f8\u5728\u94a2\u4e2d\u7684\u56fa\u6eb6\u5ea6\u79ef\u516c\u5f0f\u3002Metall. Mater. Trans. A\u7cfb\u5217\u56db\u6587\uff08\u6c5f\u897f\u7406\u5de5\u5927\u5b66\u96f7\u7384\u5a01\u535a\u58eb\u4e3a\u7b2c\u4e00\u4f5c\u8005\uff0c\u8d56\u671d\u5f6c\u6559\u6388\u3001\u6881\u5f64\u7965\u6559\u6388\u5206\u522b\u4e3a\u8bba\u6587\u901a\u8baf\u4f5c\u8005\uff09\uff0c\u901a\u8fc7\u70ed\u529b\u5b66\u65b9\u6cd5\uff0c\u63a8\u5bfc\u5efa\u7acb\u4e86Nb\u3001V\u3001Ti\u7684\u78b3\u5316\u7269\u3001\u6c2e\u5316\u7269\u3001\u78b3\u6c2e\u5316\u7269\u5206\u522b\u5728\u94c1\u7d20\u4f53\u548c\u5965\u6c0f\u4f53\u4e2d\u7684\u56fa\u6eb6\u5ea6\u79ef\u516c\u5f0f\u53ca\u70ed\u529b\u5b66\u65b9\u7a0b\uff0c\u5e76\u901a\u8fc7\u524d\u4eba\u7684\u6570\u636e\u3001\u7ed3\u679c\u8fdb\u884c\u4e86\u9a8c\u8bc1\u3002\u8fd9\u4e00\u5de5\u4f5c\u89e3\u51b3\u4e86\u5e73\u8861\u6761\u4ef6\u4e0b\uff0c\u94a2\u4e2dNb\u3001V\u3001Ti\u7b2c\u4e8c\u76f8\u5206\u6570\u7684\u8ba1\u7b97\u95ee\u9898\u3002<\/p>\n<p><strong>\u521b\u65b0\u70b9<\/strong><\/p>\n<p>\uff081\uff09\u63a8\u5bfc\u5efa\u7acb\u4e86\u4e8c\u5143\u7b2c\u4e8c\u76f8\u5728\u94c1\u7d20\u4f53\u56fa\u6eb6\u4f53\u4e2d\u56fa\u6eb6\u5ea6\u79ef\u7684\u70ed\u529b\u5b66\u65b9\u6cd5\uff0c\u83b7\u5f97\u4e86TiC\u3001NbC\u3001VC\u3001TiN\u3001NbN\u548cVN\u7684\u56fa\u6eb6\u5ea6\u79ef\u516c\u5f0f\uff1b<\/p>\n<p>\uff082\uff09\u63a8\u5bfc\u5efa\u7acb\u4e86\u4e8c\u5143\u7b2c\u4e8c\u76f8\u5728\u5965\u6c0f\u4f53\u56fa\u6eb6\u4f53\u4e2d\u56fa\u6eb6\u5ea6\u79ef\u7684\u70ed\u529b\u5b66\u65b9\u6cd5\uff0c\u83b7\u5f97\u4e86TiC\u3001NbC\u3001VC\u3001TiN\u3001NbN\u548cVN\u7684\u56fa\u6eb6\u5ea6\u79ef\u516c\u5f0f\uff1b<\/p>\n<p>\uff083\uff09\u63a8\u5bfc\u5efa\u7acb\u4e86\u5316\u5b66\u8ba1\u91cf\u6bd4\u7684\u4e09\u5143\u7b2c\u4e8c\u76f8\u5206\u522b\u5728\u94c1\u7d20\u4f53\u548c\u5965\u6c0f\u4f53\u4e2d\u56fa\u6eb6\u5ea6\u79ef\u53ca\u70ed\u529b\u5b66\u65b9\u7a0b\u7684\u70ed\u529b\u5b66\u65b9\u6cd5\uff0c\u83b7\u5f97\u4e86TiC<em><sub>x<\/sub><\/em>N<sub>1-<em>x<\/em><\/sub>\u3001NbC<em><sub>x<\/sub><\/em>N<sub>1-<em>x<\/em><\/sub>\u3001VC<em><sub>x<\/sub><\/em>N<sub>1-<em>x<\/em><\/sub>\u7684\u56fa\u6eb6\u5ea6\u79ef\u8868\u8fbe\u5f0f\uff0c\u5e76\u5206\u522b\u63ed\u793a\u4e86\u5176\u4e0e\u5176\u4e24\u4e2a\u4e8c\u5143\u7b2c\u4e8c\u76f8\u56fa\u6eb6\u5ea6\u79ef\u7684\u5173\u7cfb\uff1b<\/p>\n<p>\uff084\uff09\u63a8\u5bfc\u5efa\u7acb\u4e86\u975e\u5316\u5b66\u8ba1\u91cf\u6bd4\u7684\u4e09\u5143\u7b2c\u4e8c\u76f8\u5206\u522b\u5728\u94c1\u7d20\u4f53\u548c\u5965\u6c0f\u4f53\u4e2d\u56fa\u6eb6\u5ea6\u79ef\u53ca\u70ed\u529b\u5b66\u65b9\u7a0b\u7684\u70ed\u529b\u5b66\u65b9\u6cd5\uff0c\u83b7\u5f97\u4e86NbC<em><sub>x<\/sub><\/em>N<em><sub>y<\/sub><\/em>\u7684\u56fa\u6eb6\u5ea6\u79ef\u8868\u8fbe\u5f0f\uff0c\u5e76\u63ed\u793a\u4e86\u5176\u4e0e\u5176\u4e09\u4e2a\u4e8c\u5143\u7b2c\u4e8c\u76f8\u56fa\u6eb6\u5ea6\u79ef\u7684\u5173\u7cfb\u3002<\/p>\n<p><strong>\u7ed3\u679c\u5c55\u793a<\/strong><\/p>\n<p>\uff081\uff09Nb\u3001V\u3001Ti\u7684\u78b3\u5316\u7269\u3001\u6c2e\u5316\u7269\u5206\u522b\u5728\u94c1\u7d20\u4f53\u4e2d\u7684\u56fa\u6eb6\u5ea6\u79ef\u516c\u5f0f\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226890\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/4.png\" alt=\"\" width=\"600\" height=\"299\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/4.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/4-300x150.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226887\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/1.png\" alt=\"\" width=\"600\" height=\"329\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/1.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/1-300x165.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe1\u00a0 \u7b2c\u4e8c\u76f8\u5728\u94c1\u7d20\u4f53\u4e2d\u56fa\u6eb6\u5ea6\u79ef\u7684\u8ba1\u7b97\u7ed3\u679c\u4e0e\u524d\u4eba\u7814\u7a76\u7ed3\u679c\u7684\u5bf9\u6bd4: (a)TiC , (b)NbC , (c)VC , (d)TiN , (e)NbN , (f) VN.<\/p>\n<p>\uff082\uff09Nb\u3001V\u3001Ti\u7684\u78b3\u5316\u7269\u3001\u6c2e\u5316\u7269\u5206\u522b\u5728\u5965\u6c0f\u4f53\u4e2d\u7684\u56fa\u6eb6\u5ea6\u79ef\u516c\u5f0f\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226891\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/5.png\" alt=\"\" width=\"600\" height=\"362\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/5.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/5-300x181.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226888\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/2.png\" alt=\"\" width=\"600\" height=\"167\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/2.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/2-300x84.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe2\u00a0 \u7b2c\u4e8c\u76f8\u5728\u5fae\u5408\u91d1\u94a2\u5965\u6c0f\u4f53\u4e2d\u56fa\u6eb6\u5ea6\u79ef\u7684\u8ba1\u7b97\u7ed3\u679c\u4e0e\u524d\u4eba\u7814\u7a76\u7ed3\u679c\u7684\u5bf9\u6bd4: (<em>a<\/em>) \u5965\u6c0f\u4f53\u4e2dCr\u542b\u91cf\u4e3a8.85wt%, (<em>b<\/em>) \u5965\u6c0f\u4f53\u4e2dMn\u542b\u91cf\u4e3a0~10wt%, (<em>c<\/em>) \u5965\u6c0f\u4f53\u4e2dCr\u542b\u91cf\u4e3a7.2wt%.<\/p>\n<p>\uff083\uff09\u5316\u5b66\u8ba1\u91cf\u6bd4\u7684Nb\u3001V\u3001Ti\u7684\u78b3\u6c2e\u5316\u7269\u5206\u522b\u5728\u94c1\u7d20\u4f53\u548c\u5965\u6c0f\u4f53\u4e2d\u7684\u56fa\u6eb6\u5ea6\u79ef\u516c\u5f0f\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-226920 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/13-1-e1630768960867.png\" alt=\"\" width=\"600\" height=\"98\" \/><\/p>\n<p>\u8ba1\u7b97\u5316\u5b66\u8ba1\u7b97\u6bd4\u7684\u7b2c\u4e8c\u76f8\u78b3\u6c2e\u5316\u7269\u5206\u6570\u7684\u70ed\u529b\u5b66\u65b9\u7a0b\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226893\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/7.png\" alt=\"\" width=\"600\" height=\"107\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/7.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/7-300x54.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff084\uff09\u975e\u5316\u5b66\u8ba1\u91cf\u6bd4\u7684Nb\u7684\u78b3\u6c2e\u5316\u7269\u5206\u522b\u5728\u94c1\u7d20\u4f53\u548c\u5965\u6c0f\u4f53\u4e2d\u7684\u56fa\u6eb6\u5ea6\u79ef\u516c\u5f0f:<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226894\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/8.png\" alt=\"\" width=\"600\" height=\"151\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/8.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/8-300x76.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u8ba1\u7b97\u975e\u5316\u5b66\u8ba1\u7b97\u6bd4\u7684Nb\u7684\u78b3\u6c2e\u5316\u7269\u5206\u6570\u7684\u70ed\u529b\u5b66\u65b9\u7a0b\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226895\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/9.png\" alt=\"\" width=\"600\" height=\"192\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/9.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/9-300x96.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226889\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/3.png\" alt=\"\" width=\"600\" height=\"204\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/3-300x102.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe3\u00a0 Nb\u7684\u78b3\u6c2e\u5316\u7269\u5728\u5965\u6c0f\u4f53\u4e2d\u56fa\u6eb6\u5ea6\u79ef\u7684\u8ba1\u7b97\u7ed3\u679c\u4e0e\u524d\u4eba\u7814\u7a76\u7ed3\u679c\u7684\u5bf9\u6bd4: (a) NbC<sub>0.87<\/sub>, (b) NbN<sub>0.87<\/sub> , (c) NbC<sub>0.87<\/sub>N<sub>0.14<\/sub>.<\/p>\n<p>\u4ee5\u4e0a\u5f0f\u5b50\u4e2d\uff0c [wt.%<em>M<\/em>]\u8868\u793a<em>M<\/em>\u5143\u7d20\u7684\u56fa\u6eb6\u8d28\u91cf\u767e\u5206\u542b\u91cf\uff0c<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-226896 alignleft\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/10.png\" alt=\"\" width=\"28\" height=\"24\" \/>\u4e3a\u94a2\u4e2d<em>M<\/em>\u5143\u7d20\u7684\u6469\u5c14\u5206\u6570\uff0c<em> f<sub>mole<\/sub><\/em>\u4e3a\u7b2c\u4e8c\u76f8\u6469\u5c14\u5206\u6570\uff0c<em>x<sub>j<\/sub> <\/em>\u4e3a<em>j<\/em>\u5143\u7d20\u7684\u56fa\u6eb6\u6469\u5c14\u5206\u6570\uff0c<em>A<sub>j<\/sub><\/em> \u4e3a<em>j<\/em>\u5143\u7d20\u7684\u76f8\u5bf9\u539f\u5b50\u8d28\u91cf\uff0c<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-226897 alignleft\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/11.png\" alt=\"\" width=\"54\" height=\"23\" \/>\u8868\u793afcc\u6676\u683c\u4e2d\u7b2c\u4e00\u70b9\u9635\u4e3a<em>M<\/em>\u539f\u5b50\u7b2c\u4e8c\u70b9\u9635\u4e3a<em> N<sub>1<\/sub><\/em>\u6216 <em>N<sub>2<\/sub><\/em>\u539f\u5b50\u7684\u4e92\u6613\u7cfb\u76f8\u4e92\u4f5c\u7528\u53c2\u6570\u3002<\/p>\n<p><strong>\u7ed3\u8bba<\/strong><\/p>\n<p>\u8bba\u6587\u5de5\u4f5c\u8bc1\u5b9e\u4e86\u53cc\u4e9a\u70b9\u9635\u6a21\u578b\u53ef\u7528\u4e8e\u63a8\u5bfc\u8ba1\u7b97\u7b2c\u4e8c\u76f8\u56fa\u6eb6\u5ea6\u79ef\u53ca\u5206\u6570\u3002\u4e3a\u7814\u7a76\u4eba\u5458\u6446\u8131\u70ed\u529b\u5b66\u8f6f\u4ef6\u8fdb\u884c\u5fae\u5408\u91d1\u6210\u4efd\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b9\u6cd5\u53c2\u8003\u3002\u8bba\u6587\u5f97\u5230\u7684Nb\u3001V\u3001Ti\u7684\u78b3\u5316\u7269\u3001\u6c2e\u5316\u7269\u3001\u78b3\u6c2e\u5316\u7269\u56fa\u6eb6\u5ea6\u79ef\u8868\u8fbe\u5f0f\u53ca\u70ed\u529b\u5b66\u65b9\u7a0b\uff0c\u53ef\u76f4\u63a5\u4e3aNb\u3001V\u3001Ti\u5fae\u5408\u91d1\u94a2\u6210\u4efd\u8bbe\u8ba1\u63d0\u4f9b\u53c2\u8003\u3002<\/p>\n<p><strong>\u8bba\u6587\u4fe1\u606f<\/strong><\/p>\n<p>Effect of solid solution elements on solubility products of carbides and nitrides in ferrite: thermodynamic calculations, <a href=\"https:\/\/link.springer.com\/journal\/11661\">Metallurgical and Materials Transactions A<\/a>, 2019, https:\/\/doi.org\/10.1007\/s11661-019-05188-y<\/p>\n<p>Effect of solid solution elements on solubility products of carbides and nitrides in austenite: thermodynamic calculations, <a href=\"https:\/\/link.springer.com\/journal\/11661\">Metallurgical and Materials Transactions A<\/a>, 2019, https:\/\/doi.org\/10.1007\/s11661-019-05295-w<\/p>\n<p>Solubility products and equilibrium equations of carbonitrides in steels: thermodynamic calculations, <a href=\"https:\/\/link.springer.com\/journal\/11661\">Metallurgical and Materials Transactions A<\/a>, 2021, <a href=\"https:\/\/doi.org\/10.1007\/s11661-021-06184-x\">https:\/\/doi.org\/10.1007\/s11661-021-06184-x<\/a><\/p>\n<p>Solubility product and rquilibrium rquations of non-dtoichiometric niobium carbonitride in steels: thermodynamic calculations, <a href=\"https:\/\/link.springer.com\/journal\/11661\">Metallurgical and Materials Transactions A<\/a>, 2021, <a href=\"https:\/\/doi.org\/10.1007\/s11661-021-06393-4\">https:\/\/doi.org\/10.1007\/s11661-021-06393-4<\/a><\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u80cc\u666f\u4ecb\u7ecd 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