{"id":227770,"date":"2021-09-25T06:30:17","date_gmt":"2021-09-24T22:30:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=227770"},"modified":"2021-09-24T18:03:32","modified_gmt":"2021-09-24T10:03:32","slug":"%e8%a5%bf%e5%ae%89%e4%ba%a4%e9%80%9a%e5%a4%a7%e5%ad%a6%e5%94%90%e4%bc%9f%e6%95%99%e6%8e%88eem%ef%bc%9a%e7%94%a8%e4%ba%8e%e9%ab%98%e6%80%a7%e8%83%bd%e8%b6%85%e7%ba%a7%e7%94%b5%e5%ae%b9%e5%99%a8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=227770","title":{"rendered":"\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5510\u4f1f\u6559\u6388EEM\uff1a\u7528\u4e8e\u9ad8\u6027\u80fd\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5177\u6709\u4e9a\u7eb3\u7c73\u5fae\u5b54\u7684 N \u63ba\u6742\u4e8c\u7ef4\u78b3\u7eb3\u7c73\u7247\u7684\u901a\u7528\u7b56\u7565"},"content":{"rendered":"
\n
\n
\n
\n
\n
\n
\n

\u8fd1\u65e5\uff0c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5510\u4f1f\u6559\u6388\u3001\u5b59\u5b5d\u98de\u8054\u5408\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u5434\u5b87\u5e73\u6559\u6388<\/strong>\u56e2\u961f<\/strong>\u5728Energy & Environmental Materials<\/strong><\/em>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cA Universal Strategy For N-Doped 2D Carbon Nanosheets With Sub-Nanometer Micropore For High-Performance Supercapacitor<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8be5\u56e2\u961f\u63d0\u51fa\u4e86\u4e00\u79cd\u7b80\u5355\u800c\u6709\u6548\u7684\u65e0\u6dfb\u52a0\u5242\u65b9\u6cd5\uff0c\u901a\u8fc7\u7145\u70e7\u8fc7\u7a0b\u4e2d\u7684\u81ea\u6fc0\u6d3b\u5c06\u5757\u72b6\u5c42\u72b6\u90bb\u82ef\u4e8c\u7532\u9170\u4e9a\u80fa\u94be\u76d0\u8f6c\u5316\u4e3a\u65b0\u578b\u6c2e\u63ba\u6742\u4e8c\u7ef4\u78b3\u7247\u3002\u83b7\u5f97\u7684\u6837\u54c1\u5177\u6709\u5927\u5c3a\u5bf8\u6241\u5e73\u7ed3\u6784\uff0c\u6a2a\u5411\u5c3a\u5bf8\u7ea6\u4e3a10 \u00b5m\uff0c\u5747\u5300\u7684\u4e9a\u7eb3\u7c73\u5fae\u5b54\u5c3a\u5bf8\u5206\u5e03\u7ea6\u4e3a0.65 nm\uff0c\u6bd4\u8868\u9762\u79ef\u9ad8\u8fbe2276.7m2<\/sup>\u00a0g-1<\/sup>\uff0c\u6c2e\u63ba\u6742\u9002\u5b9c\u3002\u53d7\u76ca\u4e8e\u8fd9\u4e9b\u4f18\u70b9\uff0c\u4f18\u5316\u540e\u7684\u6837\u54c1\u5728 1 A g-1<\/sup>\u00a0\u65f6\u63d0\u4f9b\u4e86345 F g-1<\/sup>\u00a0\u7684\u9ad8\u6bd4\u7535\u5bb9\uff0c\u5e76\u4e14\u5373\u4f7f\u5728 6.0 M KOH \u7535\u89e3\u6db2\u4e2d50 A g-1<\/sup>\u00a0\u65f6\u4e5f\u4fdd\u6301\u4e86 270 F g-1<\/sup>\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u57286.0 M KOH \u548c 1.0 M\u00a0Na2<\/sub>SO4<\/sub>\u00a0\u7535\u89e3\u8d28\u4e2d\u7684\u6700\u5927\u80fd\u91cf\u5bc6\u5ea6\u5206\u522b\u4e3a16.43Wh kg-1<\/sup>\u00a0\u548c 23.6 Wh kg-1<\/sup>\u3002\u91cd\u8981\u7684\u662f\uff0c\u7531\u4e8e\u8be5\u65b9\u6cd5\u7684\u901a\u7528\u6027\u548c\u7b80\u5355\u6027\uff0c\u53ef\u4ee5\u4ece\u5177\u6709\u5c42\u72b6\u7ed3\u6784\u7684\u4e0d\u540c\u542b\u94be\u76d0\u5408\u6210\u5177\u6709\u5747\u5300\u4e9a\u7eb3\u7c73\u5fae\u5b54\u5206\u5e03\u7684\u672a\u63ba\u6742\u5236\u5907\u7684\u78b3\u7247\uff0c\u53ef\u4f5c\u4e3a\u4e00\u79cd\u6807\u5fd7\u6027\u6a21\u578b\u6df1\u5165\u7814\u7a76\u4e9a\u7eb3\u7c73\u5fae\u5b54\u5bf9\u7535\u5bb9\u6027\u80fd\u7684\u5f71\u54cd\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n

\n
<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u6587\u7ae0\u7b80\u8bfb<\/strong><\/p>\n<\/section>\n

\u8d85\u7ea7\u7535\u5bb9\u5668\u56e0\u5176\u529f\u7387\u5bc6\u5ea6\u9ad8\u3001\u5145\u653e\u7535\u901f\u7387\u5feb\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u597d\u7b49\u4f18\u70b9\u800c\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u4f4e\u80fd\u91cf\u5bc6\u5ea6\u9650\u5236\u4e86\u5176\u8fdb\u4e00\u6b65\u5927\u89c4\u6a21\u7684\u5b9e\u9645\u5e94\u7528\u3002\u901a\u5e38\uff0c\u7535\u6781\u6750\u6599\u88ab\u8ba4\u4e3a\u662f\u5c06\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u80fd\u91cf\u5bc6\u5ea6\u63a8\u5411\u7279\u5b9a\u76ee\u6807\u7684\u91cd\u8981\u7ec4\u6210\u90e8\u5206\u3002\u5728\u4f17\u591a\u5019\u9009\u7535\u6781\u4e2d\uff0c\u77f3\u58a8\u70ef\u3001\u591a\u5b54\u78b3\u3001\u78b3\u7eb3\u7c73\u7ba1\u548c\u78b3\u7ea4\u7ef4\u7b49\u78b3\u6750\u6599\u7531\u4e8e\u5176\u4e30\u5bcc\u7684\u5b54\u9699\u7387\u3001\u9ad8\u5bfc\u7535\u6027\u548c\u53ef\u63a7\u7684\u5f62\u8c8c\uff0c\u5df2\u6210\u4e3a\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u4f7f\u7528\u7684\u4e3b\u6d41\u7535\u6781\u6750\u6599\u3002\u8fd1\u5e74\u6765\uff0c\u4e8c\u7ef4\u00a0(2D)\u00a0\u78b3\u8584\u7247\u7531\u4e8e\u7eb3\u7c73\u76f8\u00a0Sp2<\/sup>\u00a0\u6742\u5316\u78b3\u5728\u7ef4\u5ea6\u4e0a\u72ec\u7279\u7684\u7535\u5b50\u6027\u8d28\u548c\u7269\u7406\u5316\u5b66\u6027\u8d28\u800c\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u7531\u4e8e\u66f2\u6298\u5b54\u9699\u4e2d\u79bb\u5b50\u4f20\u8f93\u7684\u52a8\u529b\u5b66\u9650\u5236\uff0c\u5b83\u4ecd\u7136\u4e0d\u80fd\u6ee1\u8db3\u5b9e\u9645\u5e94\u7528\u7684\u8981\u6c42\u3002\u63d0\u9ad8\u6bd4\u7535\u5bb9\u7684\u7b2c\u4e00\u79cd\u65b9\u6cd5\u662f\u63ba\u5165\u6742\u539f\u5b50\uff08N\uff0cS\uff0cB\uff0cP\uff09\u4e3a\u78b3\uff0c\u53ef\u4ee5\u4e3a\u8d5d\u7535\u5bb9\u63d0\u4f9b\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u4f18\u5316\u8868\u9762\u6da6\u6e7f\u6027\u4ee5\u964d\u4f4e\u63a5\u89e6\u7535\u963b\u548c\u589e\u52a0\u7535\u8d1f\u6027\u4ee5\u83b7\u5f97\u66f4\u597d\u7684\u5bfc\u7535\u6027\u3002\u589e\u5927\u6bd4\u8868\u9762\u79ef\u00a0(SSA)\u00a0\u5df2\u88ab\u8bc1\u660e\u662f\u63d0\u9ad8\u7535\u5bb9\u6027\u80fd\u7684\u6709\u6548\u65b9\u6cd5\u3002<\/section>\n
\u7a84\u7684\u4e9a\u7eb3\u7c73\u5b54(< 1 nm)\u00a0\u5c3a\u5bf8\u5206\u6563\u5df2\u88ab\u9884\u6d4b\u53ef\u5b9e\u73b0\u524d\u6240\u672a\u6709\u7684\u6bd4\u7535\u5bb9\uff0c\u4f46\u5728\u4e8c\u7ef4\u78b3\u6750\u6599\u4e2d\u5f88\u5c11\u5b9e\u73b0\u3002\u56e0\u6b64\uff0c\u5177\u6709\u4e30\u5bcc\u591a\u5b54\u5f00\u653e\u5f62\u6001\u548c\u5747\u5300\u4e9a\u7eb3\u7c73\u5fae\u5b54\u5f84\u5206\u6563\u7684\u4e8c\u7ef4\u78b3\u7eb3\u7c73\u7247\u5c06\u5177\u6709\u5feb\u901f\u7535\u8377\u5b58\u50a8\u7684\u5185\u5728\u4f18\u52bf\u3002\u6b64\u5916\uff0c\u5e94\u4e86\u89e3\u4e9a\u7eb3\u7c73\u5fae\u5b54\u5bf9\u7535\u5bb9\u6027\u80fd\u7684\u5f71\u54cd\uff0c\u4ee5\u5f00\u53d1\u5148\u8fdb\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u4e8c\u7ef4\u78b3\u6750\u6599\u7684\u5408\u6210\u65b9\u6cd5\u5927\u81f4\u53ef\u5206\u4e3a\u6c14\u76f8\u548c\u6db2\u76f8\u5408\u6210\u4e24\u5927\u7c7b\u3002\u6c14\u76f8\u6cd5\u5305\u62ec\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\uff08CVD\uff09\u901a\u8fc72D\u6a21\u677f\uff0c\u53ef\u4ee5\u751f\u4ea7\u5b8c\u6574\u7684\u5927\u5c3a\u5bf8\u4e8c\u7ef4\u78b3\u7eb3\u7c73\u7247\u3002\u7136\u800c\uff0c\u8be5\u7b56\u7565\u7684\u590d\u6742\u5de5\u827a\u548c\u9ad8\u6210\u672c\u9650\u5236\u4e86\u5176\u5927\u89c4\u6a21\u5e94\u7528\u3002\u6db2\u76f8\u6cd5\u53ef\u4ee5\u7b80\u5355\u800c\u5927\u89c4\u6a21\u5730\u751f\u4ea7\u78b3\u7eb3\u7c73\u7247\uff0c\u901a\u8fc7\u6709\u673a\u53cd\u5e94\u5236\u5907\u4e8c\u7ef4\u78b3\u7eb3\u7c73\u3002<\/section>\n
\u4f46\u662f\u8fd9\u4e24\u79cd\u65b9\u6cd5\u5728\u5236\u5907\u8fc7\u7a0b\u4e2d\u603b\u662f\u4f1a\u5bfc\u81f4\u5c0f\u5c3a\u5bf8\u548c\u7834\u788e\u7684\u9897\u7c92\uff0c\u56e0\u6b64\u9700\u8981\u989d\u5916\u7684\u7eaf\u5316\u8fc7\u7a0b\u3002\u6b64\u5916\uff0c\u4e0a\u8ff0\u4e24\u79cd\u65b9\u6cd5\u96be\u4ee5\u7cbe\u786e\u63a7\u5236\u4e9a\u7eb3\u7c73\u5fae\u5b54\u7684\u5206\u5e03\uff0c\u8fd9\u4e5f\u5bfc\u81f4\u7814\u7a76\u8005\u5bf9\u4e8e\u4e9a\u7eb3\u7c73\u5fae\u5b54\u6709\u4e00\u5b9a\u7684\u4e89\u8bae\u3002\u56e0\u6b64\uff0c\u4e00\u79cd\u901a\u7528\u4e14\u53ef\u6269\u5c55\u7684\u65b9\u6cd5\u53ef\u4ee5\u5f88\u597d\u5730\u63a7\u52362D\u591a\u5b54\u7eb3\u7c73\u7247\u4e0a\u7684\u4e9a\u7eb3\u7c73\u5fae\u5b54\u975e\u5e38\u5177\u6709\u6311\u6218\u6027\u3002\u5728\u6b64\uff0c\u901a\u8fc7\u7b80\u5355\u7684\u4e00\u9505\u6d3b\u5316\u548c\u7145\u70e7\u5c42\u72b6\u90bb\u82ef\u4e8c\u7532\u9170\u4e9a\u80fa\u94be\u76d0\uff0c\u4e0d\u6dfb\u52a0\u4efb\u4f55\u989d\u5916\u7684\u6d3b\u5316\u5242\u3001\u6a21\u677f\u6216\u50ac\u5316\u5242\uff0c\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u00a0N\u00a0\u63ba\u6742\u7684\u9ad8\u8868\u9762\u79ef\u5927\u5c3a\u5bf8\u78b3\u7247(LCN)\u3002\u6700\u4f73\u6837\u54c1\u5b9e\u73b0\u4e86\u6a2a\u5411\u5c3a\u5bf8\u7ea6\u4e3a10 \u00b5m\u7684\u5927\u5c3a\u5bf82D\u7eb3\u7c73\u7247\uff0c2276.7 m2<\/sup>\u00a0g-1<\/sup>\u7684\u5927\u6bd4\u8868\u9762\u79ef\uff0c\u4ee5\u53ca\u7ea60.65 nm\u5c3a\u5bf8\u7684\u5747\u5300\u4e9a\u7eb3\u7c73\u5fae\u5b54\u5206\u5e03\u3002<\/section>\n

\"\"<\/p>\n

 <\/p>\n

\u56fe1.<\/strong>\u78b3\u7eb3\u7c73\u7247\u5408\u6210\u793a\u610f\u56fe\u3002<\/p>\n

\"\"<\/p>\n

 <\/p>\n

\u56fe2.<\/span><\/strong>\u00a0a)\u00a0<\/span>\u57fa\u4e8eLCN-750-3<\/span>\u7684SSC<\/span>\u57281 M Na2SO4<\/sub>\u00a0<\/span>\u4e2d\u4ee510<\/span>\u5230\u00a0mV S-1<\/sup><\/span>\u7684\u4e0d\u540c\u626b\u7387\u4e0b\u6d4b\u8bd5\u7684CV<\/span>\u66f2\u7ebf\uff1bb)\u00a0<\/span>\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u6d4b\u8bd5\u7684LCN-750-3<\/span>\u7684SSC<\/span>\u7684GCD<\/span>\u66f2\u7ebf\uff1b\u00a0c)<\/span>\u57fa\u4e8eLCN-750-3<\/span>\u7684SSC\u00a0<\/span>\u57280.5 A g-1<\/sup><\/span>\u81f320 A g-1<\/sup><\/span>\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u7535\u5bb9\uff1bd)\u00a0<\/span>\u57fa\u4e8eLCN-750-3<\/span>\u7684SSC<\/span>\u7684Nyquist<\/span>\u56fe\uff1b\u00a0e)<\/span>\u57fa\u4e8eLCN-750-3<\/span>\u7684SSC<\/span>\u572810 A g-1<\/sup><\/span>\u4e0b\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u00a0f)\u00a0<\/span>\u5206\u522b\u5728\u00a01.0 M Na2<\/sub>SO4\u00a0<\/span>\u548c6.0 M KOH\u00a0<\/span>\u4e2d\u6d4b\u8bd5\u7684\u57fa\u4e8eLCN-750-3<\/span>\u7684SSC<\/span>\u7684Ragone<\/span>\u56fe\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong><\/p>\n

Jiangqi Zhou , Li Jiang, Chengyong Shu, Long Kong, Iqbal Ahmad, Ya-Nan Zhou, Wei Tang* , Xiaofei Sun*, and Yuping Wu*.\u00a0A Universal Strategy For N-Doped 2D Carbon Nanosheets With Sub-Nanometer Micropore For High-Performance Supercapacitor.<\/p>\n

Energy\u00a0Environ.\u00a0<\/em>Mater<\/em>.\u00a02020.<\/strong><\/p>\n

DOI: 10.1002\/eem2.12137.<\/p>\n

\n
\n
\n
\n
\n
\n
\n
\n
\n
\n
\n
https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/eem2.12137<\/section>\n<\/section>\n
<\/section>\n
\u672c\u6587\u7531EEM\u671f\u520a\u6295\u7a3f\u3002<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"

\u8fd1\u65e5\uff0c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5510\u4f1f\u6559\u6388\u3001\u5b59\u5b5d\u98de\u8054\u5408\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u5434\u5b87\u5e73\u6559\u6388\u56e2\u961f\u5728Energy & Environmental Materials\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cA Un…<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-227770","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/227770"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=227770"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/227770\/revisions"}],"predecessor-version":[{"id":227774,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/227770\/revisions\/227774"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=227770"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=227770"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=227770"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}