{"id":227869,"date":"2021-09-28T06:30:25","date_gmt":"2021-09-27T22:30:25","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=227869"},"modified":"2021-09-27T21:51:43","modified_gmt":"2021-09-27T13:51:43","slug":"mof%e3%80%81cof%e5%88%b7%e5%b1%8f%e4%ba%86%ef%bd%9c%e9%a1%b6%e5%88%8a%e9%80%9f%e8%a7%88","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=227869","title":{"rendered":"MOF\u3001COF\u5237\u5c4f\u4e86\uff5c\u9876\u520a\u901f\u89c8"},"content":{"rendered":"<p><strong><b>Nature Photon.\uff1a\u57fa\u4e8e<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF\u4e2d\u7684\u9499\u949b\u77ff\u7eb3\u7c73\u6676\u7684\u660e\u4eae\u7a33\u5b9a\u53d1\u5149\u4e8c\u6781\u7ba1<\/b><\/strong><\/p>\n<p>\u9499\u949b\u77ff\u7eb3\u7c73\u6676\u4f53\u662f\u53d1\u5149\u4e8c\u6781\u7ba1(led)\u7684\u7279\u6b8a\u5019\u9009\u6750\u6599\u3002\u7136\u800c\uff0c\u5b83\u4eec\u5728\u56fa\u4f53\u8584\u819c\u4e2d\u662f\u4e0d\u7a33\u5b9a\u7684\uff0c\u5e76\u503e\u5411\u4e8e\u964d\u89e3\u56de\u4f53\u76f8\uff0c\u8fd9\u524a\u5f31\u4e86\u5b83\u4eec\u5728LED\u4e2d\u7684\u6f5c\u529b\u3002\u5728\u8fd9\u91cc\uff0c\u6d1b\u65af\u963f\u62c9\u83ab\u65af\u56fd\u5bb6\u5b9e\u9a8c\u5ba4Wanyi Nie\u548cHsinhan Tsai\u7b49\u4eba\u8bc1\u660e\u4e86\u7a33\u5b9a\u5728\u91d1\u5c5e\u6709\u673a\u6846\u67b6 (MOF) \u8584\u819c\u4e2d\u7684\u9499\u949b\u77ff\u7eb3\u7c73\u6676\u4f53\u53ef\u4ee5\u5236\u9020\u660e\u4eae\u4e14\u7a33\u5b9a\u7684LED\u3002\u00a0MOF\u8584\u819c\u4e2d\u7684\u9499\u949b\u77ff\u7eb3\u7c73\u6676\u4f53\u53ef\u4ee5\u5728\u6301\u7eed\u7684\u7d2b\u5916\u7ebf\u7167\u5c04\u3001\u70ed\u548c\u7535\u5e94\u529b\u4e0b\u4fdd\u6301\u5149\u81f4\u53d1\u5149\u548c\u7535\u81f4\u53d1\u5149\u3002\u5149\u5b66\u548cX\u5c04\u7ebf\u5149\u8c31\u5206\u6790\u8868\u660e\uff0c\u5f3a\u53d1\u5c04\u6e90\u4e8e\u5c40\u57df\u8f7d\u6d41\u5b50\u590d\u5408\u3002\u91c7\u7528\u9499\u949b\u77ff-MOF\u7eb3\u7c73\u6676\u4f53\u5236\u6210\u7684\u53d1\u5149\u4e8c\u6781\u7ba1\uff0c\u5728\u5668\u4ef6\u8fbe\u5230\u7a33\u5b9a\u540e\uff0c\u6700\u5927\u5916\u90e8\u91cf\u5b50\u6548\u7387\u8d85\u8fc715%\uff0c\u4eae\u5ea6\u8d85\u8fc710<sup>5<\/sup>\u00a0cd m<sup>\u2212<\/sup><sup>2<\/sup>\u3002\u5728LED\u5de5\u4f5c\u8fc7\u7a0b\u4e2d\uff0c\u901a\u8fc7MOF\u57fa\u4f53\u7684\u4fdd\u62a4\uff0c\u7eb3\u7c73\u6676\u4f53\u53ef\u4ee5\u5f88\u597d\u5730\u4fdd\u5b58\uff0c\u6ca1\u6709\u79bb\u5b50\u8fc1\u79fb\u6216\u6676\u4f53\u5408\u5e76\uff0c\u4f7f\u5176\u6027\u80fd\u7a33\u5b9a\u8d85\u8fc750\u5c0f\u65f6\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cBright and stable light-emitting diodes made\u00a0with perovskite nanocrystals stabilized in\u00a0metal\u2013organic frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Photon.\u4e0a\u3002DOI: 10.1038\/s41566-021-00857-0<\/p>\n<p>\u56fe1\u00a0PeMoF\u8584\u819c\u7684\u5f62\u6210\u4e0e\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-227871\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72471-14.png\" alt=\"\" width=\"600\" height=\"355\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72471-14.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72471-14-300x178.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>Nature<\/b><\/strong><strong><b>\u00a0Commun<\/b><\/strong><strong><b>.\uff1a\u57fa\u4e8e\u5fae\u6d41\u4f53\u7684\u6eb6\u6db2\u526a\u5207\u5927\u9762\u79ef\u5408\u6210\u7eb3\u7c73\u50ac\u5316\u5242\u88c5\u9970\u7684\u5bfc\u7535 MOF \u8584\u819c<\/b><\/strong><\/p>\n<p>\u5bfc\u7535\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(C-MOF)\u8584\u819c\u5728\u7535\u5b50\u3001\u4f20\u611f\u5668\u548c\u80fd\u6e90\u5668\u4ef6\u7b49\u9886\u57df\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u5c06\u5404\u79cd\u529f\u80fd\u7269\u79cd\u56fa\u5b9a\u5728C-MOFs\u7684\u5b54\u5185\uff0c\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8C-MOFs\u8584\u819c\u7684\u6027\u80fd\uff0c\u62d3\u5c55\u5176\u6f5c\u5728\u7684\u5e94\u7528\u9886\u57df\u3002\u7136\u800c\uff0c\u5f00\u53d1\u6613\u4e8e\u548c\u53ef\u6269\u5c55\u7684\u9ad8\u8d28\u91cf\u8d85\u8584C-MOFs\u7684\u5408\u6210\uff0c\u540c\u65f6\u5728MOF\u5b54\u9699\u5185\u56fa\u5b9a\u529f\u80fd\u7269\u79cd\u4ecd\u7136\u5177\u6709\u6311\u6218\u6027\u3002\u5728\u8fd9\u91cc\uff0c\u97e9\u56fdKAIST Il-Doo Kim\u3001Steve Park\u7b49\u4eba\u5f00\u53d1\u4e86\u5fae\u6d41\u63a7\u901a\u9053\u5d4c\u5165\u6eb6\u6db2\u526a\u5207(MiCS)\uff0c\u7528\u4e8e\u8d85\u9ad8\u901f(\u22645 mm\/s)\u548c\u5927\u9762\u79ef\u5408\u6210\u9ad8\u8d28\u91cf\u7684\u7eb3\u7c73\u50ac\u5316\u5242\u5d4c\u5165C-MOF\u8584\u819c\uff0c\u539a\u5ea6\u53ef\u63a7\u5236\u5230\u51e0\u5341\u7eb3\u7c73\u3002MiCS\u65b9\u6cd5\u5728\u5fae\u6d41\u63a7\u901a\u9053\u4e2d\u5408\u6210\u7eb3\u7c73\u50ac\u5316\u5242\u5305\u57cbC-MOF\u9897\u7c92\uff0c\u5e76\u901a\u8fc7\u6eb6\u6db2\u526a\u5207\u5728\u5927\u9762\u79ef\u5747\u5300\u751f\u957f\u50ac\u5316\u5242\u5305\u57cbC-MOF\u8584\u819c\u3002\u7531\u4e8e\u8d85\u8584C-MOFs\u7684\u9ad8\u6bd4\u8868\u9762\u79ef\u548c\u9ad8\u5b54\u9699\u7387\uff0c\u4ee5\u53ca\u5d4c\u5728C-MOFs\u4e2d\u7684\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u8be5\u8584\u819c\u5728\u5ba4\u6e29\u4e0b\u5728\u4e8c\u7ef4\u6750\u6599\u4e4b\u95f4\u7684\u7a7a\u6c14\u4e2d\u8868\u73b0\u51fa\u9ad8\u4e8c\u6c27\u5316\u6c2e(NO<sub>2<\/sub>)\u4f20\u611f\u6027\u80fd\u3002\u56e0\u6b64\uff0cMiCS\u65b9\u6cd5\u53ef\u4ee5\u63d0\u4f9b\u4e00\u79cd\u6709\u6548\u7684\u65b9\u6cd5\u6765\u5236\u5907\u9ad8\u6d3b\u6027\u548c\u5bfc\u7535\u7684\u591a\u5b54\u6750\u6599\u7684\u5404\u79cd\u5e94\u7528\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cLarge-area synthesis of nanoscopic catalyst-decorated conductive MOF film using microfluidic-based solution shearing\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Commun.\u4e0a\u3002DOI:\u00a010.1038\/s41467-021-24571-1<\/p>\n<p>\u56fe2\u00a0\u4f7f\u7528\u5fae\u6d41\u4f53\u901a\u9053\u5d4c\u5165\u6eb6\u6db2\u526a\u5207\u5236\u5907Pt@Cu<sub>3<\/sub>(HHTP)<sub>2<\/sub>\u00a0MOF\u8584\u819c<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-227872\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72472-12.png\" alt=\"\" width=\"600\" height=\"651\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72472-12.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72472-12-276x300.png 276w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>A<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>\uff1a\u57fa\u4e8e\u7eb3\u7c73M<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u7684\u8499\u7279\u5361\u6d1b\u6a21\u62df\u63ed\u793a\u653e\u5c04\u589e\u654f\u5242\u7684\u65b0\u8bbe\u8ba1\u539f\u7406<\/b><\/strong><\/p>\n<p>\u7eb3\u7c73\u5c3a\u5ea6\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(nMOFs)\u5728X\u5c04\u7ebf\u6fc0\u53d1\u4e0b\u5177\u6709\u6bd4\u56fa\u4f53\u7eb3\u7c73\u9897\u7c92(NPs)\u66f4\u597d\u7684\u8f90\u5c04\u654f\u5316\u6548\u679c\u3002\u829d\u52a0\u54e5\u5927\u5b66\u6797\u6587\u658c\u7b49\u4eba\u91c7\u7528\u7531\u7eb3\u7c73\u7ea7\u4e8c\u7ea7\u5efa\u7b51\u5355\u5143(SBUs)\u4e09\u7ef4\u9635\u5217\u7ec4\u6210\u7684\u6676\u683c\u6a21\u578b\uff0c\u5bf9NPs\u548cnMOFs\u7684\u4e0d\u540c\u8f90\u5c04\u654f\u5316\u6548\u5e94\u8fdb\u884c\u4e86\u8499\u7279\u5361\u6d1b\u6a21\u62df\uff0c\u57fa\u4e8e\u7eb3\u7c73\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\u548c\u56fa\u4f53\u7eb3\u7c73\u7c92\u5b50\u7684\u8499\u7279\u5361\u6d1b\u6a21\u62df\u7ed3\u679c\u53ca\u76f8\u5e94\u7684\u7ec6\u80de\u5b9e\u9a8c\uff0c\u7cfb\u7edf\u5730\u6bd4\u8f83\u4e86\u4e24\u8005\u5728\u4e0d\u540c\u653e\u5c04\u6761\u4ef6\u548c\u51e0\u4f55\u7ed3\u6784\u4e0b\u7684\u5242\u91cf\u589e\u5f3a\u56e0\u5b50\uff08DEF\uff09\uff0c\u4ece\u800c\u63ed\u793a\u4e86\u653e\u5c04\u589e\u654f\u5242\u7684\u65b0\u8bbe\u8ba1\u539f\u7406\u3002\u6a21\u62df\u7ed3\u679c\u8868\u660e\uff0c\u65e0\u8bba\u8f90\u5c04\u6e90\u6216\u7c92\u5b50\u5927\u5c0f\u5982\u4f55\uff0c\u6676\u683c\u90fd\u4f18\u4e8e\u56fa\u4f53NPs\uff0c\u56e0\u4e3a\u6676\u683c\u4e2d\u5149\u5b50\u548c\u7535\u5b50\u7684\u6563\u5c04\u589e\u5f3a\u3002\u6700\u4f73\u5242\u91cf\u589e\u5f3a\u53ef\u4ee5\u901a\u8fc7\u8c03\u6574SBU\u5927\u5c0f\u548cSBU\u95f4\u8ddd\u79bb\u6765\u5b9e\u73b0\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMonte Carlo Simulations Reveal New Design Principles for Efficient Nanoradiosensitizers Based on Nanoscale Metal\u2013Organic Frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002DOI: 10.1002\/adma.202104249<\/p>\n<p>\u56fe3\u00a0\u8499\u7279\u5361\u6d1b\u6a21\u62df\u8fc7\u7a0b\u53ca\u4e0d\u540c\u653e\u5c04\u6e90\u4e0b\u5242\u91cf\u589e\u5f3a\u56e0\u5b50\u4f5c\u4e3a\u6c34\u58f3\u534a\u5f84\u7684\u51fd\u6570<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-227873\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72473-12.png\" alt=\"\" width=\"600\" height=\"341\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72473-12.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72473-12-300x171.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>AM<\/b><\/strong><strong><b>\uff1aC<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u819c<\/b><\/strong><strong><b>\u4e2d<\/b><\/strong><strong><b>\u4e9a2-nm\u901a\u9053\u7528\u4e8e<\/b><\/strong><strong><b>\u9ad8\u6548\u79bb\u5b50\u7b5b\u5206<\/b><\/strong><\/p>\n<p>\u4e9a2\u7eb3\u7c73\u901a\u9053\u7684\u819c\u5177\u6709\u8f83\u9ad8\u7684\u79bb\u5b50\u4f20\u8f93\u901f\u7387\uff0c\u4f46\u8bbe\u8ba1\u5177\u6709\u7406\u60f3\u7684\u79bb\u5b50\u9009\u62e9\u6027\u7684\u79bb\u5b50\u5206\u79bb\u819c\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u4e2d\u79d1\u5927\u5f90\u94dc\u6587\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u4e9a2-nm\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\u819c\uff0c\u5e76\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u4e00\u4ef7\u9633\u79bb\u5b50\u6e17\u900f\u901f\u7387\u548c\u6781\u4f4e\u7684\u4e8c\u4ef7\u9633\u79bb\u5b50\u900f\u8fc7\u7387\uff0c\u5b9e\u73b0\u4e86\u9ad8\u6548\u7684\u79bb\u5b50\u4f20\u8f93\u4e0e\u5206\u79bb\u3002\u7ed3\u679c\u8868\u660e\uff0cCOF\u819c\u5177\u6709\u7ea61.4 nm\u7684\u901a\u9053\u5c3a\u5bf8\u548c\u4e30\u5bcc\u7684\u6c22\u952e\u4f4d\u70b9\uff0c\u5177\u6709\u9ad8\u6548\u7684\u79bb\u5b50\u7b5b\u5206\u6027\u80fd\u3002\u6784\u7b51\u7684COFs\u819c\uff08TpBDMe<sub>2<\/sub>\uff09\u8868\u73b0\u51fa\u9ad8\u7684\u4e00\u4ef7\u9633\u79bb\u5b50\u6e17\u900f\u901f\u7387\uff080.1 ~ 0.2 mol m<sup>\u2212<\/sup><sup>2<\/sup>\u00a0h<sup>\u2212<\/sup><sup>1<\/sup>\uff09\u548c\u6781\u4f4e\u7684\u591a\u4ef7\u9633\u79bb\u5b50\u900f\u8fc7\u7387\uff0c\u5b9e\u73b0\u4e86\u9ad8\u7684\u79bb\u5b50\u9009\u62e9\u6027\uff0c\u6bd4\u5982K<sup>+<\/sup>\/Mg<sup>2+<\/sup>\u7684\u9009\u62e9\u6027~765\uff0cNa<sup>+<\/sup>\/Mg<sup>2+<\/sup>\u7684\u9009\u62e9\u6027~680\uff0cLi<sup>+<\/sup>\/Mg<sup>2+<\/sup>\u7684\u9009\u62e9\u6027~217\uff0c\u663e\u8457\u4f18\u4e8e\u5df2\u62a5\u9053\u7684\u4e9a2-nm\u901a\u9053\u819c\u3002\u5b9e\u9a8c\u6d4b\u91cf\u548c\u7406\u8bba\u6a21\u62df\u8868\u660e\uff0c\u6c34\u5408\u9633\u79bb\u5b50\u4e0eCOF\u901a\u9053\u58c1\u4e4b\u95f4\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u51b3\u5b9a\u4e86COF\u901a\u9053\u7684\u9ad8\u9009\u62e9\u6027\uff0c\u4e8c\u4ef7\u9633\u79bb\u5b50\u901a\u8fc7\u901a\u9053\u7684\u8f93\u8fd0\u9700\u8981\u514b\u670d\u6bd4\u4e00\u4ef7\u9633\u79bb\u5b50\u66f4\u9ad8\u7684\u80fd\u91cf\u52bf\u5792\u3002\u8fd9\u4e9b\u53d1\u73b0\u4e3a\u5f00\u53d1\u5177\u6709\u7279\u5b9a\u76f8\u4e92\u4f5c\u7528\u4f4d\u70b9\u7684\u4e9a2\u7eb3\u7c73\u819c\u63d0\u4f9b\u4e86\u4e00\u79cd\u9ad8\u6548\u79bb\u5b50\u5206\u79bb\u7684\u6709\u6548\u7b56\u7565\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cEfficient Ion Sieving in Covalent Organic Framework\u00a0Membranes with Sub-2-Nanometer Channels\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002DOI: 10.1002\/adma.202104404<\/p>\n<p>\u56fe4\u00a0TpBDMe<sub>2<\/sub>\u819c\u819c\u79bb\u5b50\u5206\u79bb\u6027\u80fd<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-227874\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72474-12.png\" alt=\"\" width=\"600\" height=\"480\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72474-12.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72474-12-300x240.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>Matter\uff1a<\/b><\/strong><strong><b>\u9ad8\u6548\u5c3a\u5bf8\u9009\u62e9\u6027\u50ac\u5316\u7684\u53cc\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e2d\u7684\u5b9a\u70b9\u8fd8\u539f\u5de5\u7a0b<\/b><\/strong><\/p>\n<p>\u5c06\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\u5b9a\u5411\u52a0\u5de5\u6210\u5177\u6709\u7406\u60f3\u7ed3\u6784\u548c\u6027\u80fd\u7684\u72ec\u7279\u6742\u5316\u6750\u6599\u662f\u63a2\u7d22\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u5316\u5408\u7269\u589e\u5f3a\u529f\u80fd\u548c\u6f5c\u5728\u5e94\u7528\u7684\u5173\u952e\u79d1\u5b66\u6311\u6218\u3002\u4e2d\u79d1\u9662\u91d1\u5c5e\u7814\u7a76\u6240\u6c88\u9633\u6750\u6599\u79d1\u5b66\u56fd\u5bb6\u7814\u7a76\u4e2d\u5fc3\u9f50\u4f1f\u4e0e\u4e1c\u5317\u5927\u5b66\u4ed8\u6631\u7b49\u4eba\u5408\u4f5c\u9996\u5148\u4ece\u8fd8\u539f\u52bf\u80fd\u7684\u89d2\u5ea6\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u63ed\u793a\u4e86MOF\u56e2\u7c07\u7684\u8fd8\u539f\u6027\uff0c\u8fd8\u539f\u52bf\u80fd\u662fMOF\u5b9a\u70b9\u8fd8\u539f\u5904\u7406\u7684\u57fa\u672c\u539f\u5219\u3002\u5728\u6b64\u8fc7\u7a0b\u4e2d\uff0c\u53cc\u91d1\u5c5eMOFs\u4e2d\u8fd8\u539f\u7387\u9ad8\u7684\u6d3b\u6027\u7ec4\u5206\u88ab\u9009\u62e9\u6027\u8fd8\u539f\u4e3a\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\uff0c\u800c\u5176\u4ed6(\u60f0\u6027)\u7ec4\u5206\u4fdd\u6301\u5176\u7ed3\u6784\u5b8c\u6574\u6027\u3002\u6210\u529f\u5b9a\u5236\u4e86\u4e00\u7cfb\u5217\u4e0d\u540c\u7ed3\u6784\u7684MOFs\/\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u590d\u5408\u6750\u6599\uff0c\u5305\u62ec\u6838\u58f3\u5f0f\u3001\u5206\u6563\u5f0f\u7b49\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u6240\u5236\u5907\u7684\u6742\u5316\u6750\u6599(Co-B@ZIF-8)\u5728\u50ac\u5316\u916e\u6c22\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u72ec\u7279\u7684\u5c3a\u5bf8\u9009\u62e9\u6027\u80fd\uff0c\u8fd9\u662f\u7eb3\u7c73\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u9ad8\u50ac\u5316\u6027\u80fd\u4e0eMOFs\u660e\u786e\u7684\u5fae\u5b54\u6027\u8d28\u7684\u5206\u5b50\u7b5b\u5206\u884c\u4e3a\u76f8\u7ed3\u5408\u7684\u7ed3\u679c\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cSite-directed reduction engineering\u00a0within bimetal-organic frameworks\u00a0for efficient size-selective catalysis\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Matter\u4e0a\u3002DOI:\u00a010.1016\/j.matt.2021.06.038<\/p>\n<p>\u56fe5\u00a0\u591a\u79cd\u7c7b\u578bMOFs\u7684\u4f4d\u70b9\u9009\u62e9\u6027\u8fd8\u539f<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-227875\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72475-12.png\" alt=\"\" width=\"600\" height=\"831\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72475-12.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72475-12-217x300.png 217w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>N<\/b><\/strong><strong><b>a<\/b><\/strong><strong><b>no L<\/b><\/strong><strong><b>etter<\/b><\/strong><strong><b>s<\/b><\/strong><strong><b>\uff1aM<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u4e2d<\/b><\/strong><strong><b>\u7b49\u79bb\u5b50\u4f53\u6fc0\u5b50\u4e0e\u5206\u5b50\u6fc0\u5b50\u7684\u5f3a\u8026\u5408<\/b><\/strong><\/p>\n<p>\u7f8e\u56fd\u897f\u5317\u5927\u5b66Teri W. Odom\u7b49\u4eba\u63cf\u8ff0\u4e86\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOFs)\u548c\u7b49\u79bb\u5b50\u4f53\u7eb3\u7c73\u7c92\u5b50(NP)\u6676\u683c\u4e2d\u5bc6\u96c6\u6392\u5217\u7684\u5206\u5b50\u53d1\u5c04\u5668\u7684\u5f3a\u8026\u5408\u3002\u5728Ag NP\u9635\u5217\u4e0a\u751f\u957f\u4e86\u6709\u5e8fMOF\u819c\u4e2d\u5177\u6709\u5c0f\u8dc3\u8fc1\u5076\u6781\u77e9\u7684\u535f\u5549\u884d\u751f\u7269\u3002\u5bf9MOF- NP\u6676\u683c\u7cfb\u7edf\u7684\u89d2\u5ea6\u5206\u8fa8\u5149\u5b66\u6d4b\u91cf\u663e\u793a\uff0c\u5f62\u6210\u4e86\u4e00\u4e2a\u80fd\u91cf\u8f83\u4f4e\u4e14\u4e0d\u7a7f\u8fc7\u672a\u8026\u5408MOF Q<sub>1<\/sub>\u6ce2\u6bb5\u7684\u6781\u5316\u5b50\u3002\u6a21\u578b\u9884\u6d4b\u4e86\u4e0a\u6781\u5316\u5b50\u80fd\u91cf\u548c110 meV\u7684Rabi\u5206\u88c2\u3002\u8026\u5408\u5f3a\u5ea6\u662f\u901a\u8fc7\u6539\u53d8\u6e17\u5165MOF\u5b54\u9699\u7684\u6eb6\u5242\u6298\u5c04\u7387\u6765\u5931\u8c10\u7b49\u79bb\u5b50\u4f53\u80fd\u91cf\u6765\u7cfb\u7edf\u63a7\u5236\u7684\u3002\u901a\u8fc7\u77ac\u6001\u5438\u6536\u5149\u8c31\uff0c\u7814\u7a76\u53d1\u73b0\u7531\u4e8e\u4e0a\u6781\u5316\u5b50\u7684\u80fd\u91cf\u8f6c\u79fb\uff0c\u4f4e\u6781\u5316\u5b50\u5728\u8f83\u77ed\u7684\u65f6\u95f4\u5c3a\u5ea6(&lt;500 ps)\u5185\u5feb\u901f\u8870\u51cf\uff0c\u800c\u5728\u8f83\u957f\u7684\u65f6\u95f4\u5c3a\u5ea6\u5185\u7f13\u6162\u8870\u51cf\u3002\u8fd9\u4e2a\u6742\u5316\u7cfb\u7edf\u5c55\u793a\u4e86MOFs\u5982\u4f55\u4f5c\u4e3a\u4e00\u79cd\u53ef\u7528\u4e8e\u6781\u5316\u5316\u5b66\u7684\u6fc0\u5b50\u6750\u6599\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cStrong Coupling Between Plasmons and Molecular Excitons in Metal-Organic Frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nano\u00a0Letters\u4e0a\u3002DOI: 10.1021\/acs.nanolett.1c02740<\/p>\n<p>\u56fe6\u00a0Ag NP\u6676\u683c\u2212Pd\u2212P-MOF\u4e2d\u7684\u5f3a\u8026\u5408<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-227876\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72476-11.png\" alt=\"\" width=\"600\" height=\"617\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72476-11.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72476-11-292x300.png 292w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>J<\/b><\/strong><strong><b>ACS<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>\u5c42\u95f4\u76f8\u4e92\u4f5c\u7528\u4f5c\u4e3a\u5927\u5b54\u9699COFs\u7684\u8bbe\u8ba1\u5de5\u5177<\/b><\/strong><\/p>\n<p>\u5728\u8fd9\u4e00\u65b0\u5174\u9886\u57df\u4e2d\uff0c\u5b54\u5f84\u8d85\u8fc75nm\u7684\u5171\u4ef7\u6709\u673a\u6846\u67b6\u5316\u5408\u7269(COFs)\u4ecd\u7136\u5f88\u5c11\u89c1\u3002\u9664\u4e86\u9700\u8981\u8db3\u591f\u6eb6\u89e3\u5ea6\u7684\u5927\u8fde\u63a5\u57fa\uff0c\u5927\u5b54COFs\u5408\u6210\u8fd8\u9762\u4e34\u5176\u5b83\u66f4\u591a\u6311\u6218\uff0c\u5305\u62ec\u5b54\u95ed\u585e\u548c\u584c\u9677\u3002\u8fd1\u65e5\uff0c\u9a6c\u514b\u65af\u666e\u6717\u514b\u56fa\u6001\u7814\u7a76\u6240Bettina V. Lotsch\u7b49\u4eba\u62a5\u9053\u4e86\u4e24\u4e2aisoreticular\u7cfb\u5217\u5b54\u5f84\u9ad8\u8fbe5.8 nm\u7684\u5927\u5b54\u4e9a\u80faCOFs\uff0c\u5e76\u5c06\u5c42\u95f4\u76f8\u4e92\u4f5c\u7528\u4e0eCOFs\u7684\u7ed3\u6784\u548c\u70ed\u884c\u4e3a\u76f8\u5173\u8054\u3002\u901a\u8fc7\u52a0\u5165\u4f5c\u4e3a\u5b54\u9699\u5bfc\u5411\u201c\u951a\u201d\u7684\u7532\u6c27\u57fa\u6765\u8c03\u8282\u5c42\u95f4\u76f8\u4e92\u4f5c\u7528\uff0c\u53ef\u4ee5\u8fdb\u5165\u4e0d\u540c\u7684\u5806\u79ef\u6a21\u5f0f\uff0c\u4ece\u800c\u5f62\u6210\u4fee\u9970\u7684\u5806\u79ef\u591a\u578b\uff0c\u4ece\u800c\u5f62\u6210\u6709\u6548\u5b54\u9699\u5c3a\u5bf8\u3002\u5728\u70ed\u5e94\u529b\u8fc7\u7a0b\u4e2d\uff0c\u5806\u579b\u80fd\u91cf\u5411\u9ad8\u5ea6\u6709\u5e8f\u3001\u8fd1\u91cd\u53e0\u7ed3\u6784\u3001\u66f4\u9ad8\u7ed3\u6784\u5b8c\u6574\u6027\u7684\u65b9\u5411\u53d1\u5c55\uff0c\u4e0eCOFs\u4e2d\u5806\u579b\u6a21\u5f0f\u7684\u4e00\u79cd\u65b0\u7684\u70ed\u8bf1\u5bfc\u76f8\u53d8\u4e4b\u95f4\u5b58\u5728\u5f88\u5f3a\u7684\u76f8\u5173\u6027\uff0c\u8fd9\u4e3a\u63d0\u9ad8\u5927\u5b54\u9699COFs\u7684\u7ed3\u6784\u63a7\u5236\u548c\u7a33\u5b9a\u6027\u63d0\u4f9b\u4e86\u53ef\u884c\u7684\u8bbe\u8ba1\u7b56\u7565\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cInterlayer Interactions as Design Tool for Large-Pore COFs\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002DOI:\u00a010.1021\/jacs.1c06518<\/p>\n<p>\u56fe7\u00a0mPP-TAB\u4e2d\u53ef\u80fd\u7684\u5806\u53e0\u987a\u5e8f<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-227877\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72477-9.png\" alt=\"\" width=\"600\" height=\"314\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72477-9.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72477-9-300x157.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>An<\/b><\/strong><strong><b>gew<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>\u529f\u80fd\u535f\u5549\u91d1\u5c5e-\u6709\u673a\u6846\u67b6<\/b><\/strong><strong><b>\u7528\u4f5c<\/b><\/strong><strong><b>\u4e00\u79cd\u65b0\u578b\u591a\u76f8\u5364\u7d20\u952e\u7ed9\u4f53\u50ac\u5316\u5242<\/b><\/strong><\/p>\n<p>\u4eff\u751f\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\u4f5c\u4e3a\u4eff\u751f\u6a21\u578b\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u8fd9\u4f7f\u5f97\u80fd\u591f\u6df1\u5165\u4e86\u89e3\u5927\u578b\u751f\u7269\u5206\u5b50\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u529f\u80fd\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u7f8e\u56fd\u5317\u5fb7\u514b\u8428\u65af\u5dde\u5927\u5b66Shengqian Ma\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u91d1\u5c5e-\u91d1\u5c5e\u535f\u5549\u6846\u67b6(MMPF)\u7684\u5408\u6210\u548c\u5229\u7528\uff0c\u5b83\u662f\u7531\u4e00\u4e2a\u5b9a\u5236\u7684\u914d\u4f53\u6784\u5efa\u7684\uff0c\u4f5c\u4e3a\u4e00\u4e2a\u9ad8\u6548\u7684\u5364\u7d20\u952e\u7ed9\u4f53\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u73af\u5883\u6761\u4ef6\u4e0b\u7684Diels-Alder\u53cd\u5e94\u3002\u91c7\u7528\u5364\u7d20\u952e\u5408\u80f6\u56ca\u4f5c\u4e3a\u9ad8\u5bc6\u5ea6C-Br\u952e\u5408\u888b\uff0c\u5229\u7528\u5364\u7d20\u952e\u5408\u4fc3\u8fdb\u5176\u4e09\u7ef4\u8154\u4f53\u4e2d\u7684\u6709\u673a\u8f6c\u5316\u3002\u901a\u8fc7\u5b9e\u9a8c\u548c\u8ba1\u7b97\u76f8\u7ed3\u5408\u7684\u7814\u7a76\uff0c\u7814\u7a76\u53d1\u73b0\u5e95\u7269\u5206\u5b50\u901a\u8fc7\u5fae\u5b54\u6269\u6563\uff0c\u901a\u8fc7C-Br\u00b7\u00b7\u03c0\u76f8\u4e92\u4f5c\u7528\u5f62\u6210\u4e3b\u5ba2\u4f53\u4f53\u7cfb\u3002\u5364\u7d20\u952e\u7684\u5f62\u6210\u662fDiels-Alder\u53cd\u5e94\u4e2d\u89c2\u5bdf\u5230\u7684\u63d0\u9ad8\u50ac\u5316\u6548\u7387\u7684\u5408\u7406\u89e3\u91ca\u3002\u6b64\u5916\uff0cMMPF\u7684\u72ec\u7279\u80fd\u529b\u7a81\u51fa\u4e86\u5229\u7528\u4eba\u5de5\u975e\u5171\u4ef7\u7ed3\u5408\u56ca\u4f5c\u4e3a\u9ad8\u5ea6\u53ef\u8c03\u548c\u9009\u62e9\u6027\u50ac\u5316\u6750\u6599\u7684\u65b0\u673a\u9047\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cFunctional 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