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\u8be5\u7cfb\u5217\u5206\u5b50\u6210\u529f\u5c06\u81ea\u8eab\u4ea4\u8054\u548c\u4ea4\u8054\u534a\u5bfc\u4f53\u8fd9\u4e24\u4e2a\u91cd\u8981\u53cd\u5e94\u8fdb\u884c\u201c\u53bb\u8026\u201d\u3002\u5728\u7814\u7a76\u4e2d\u53d1\u73b0\uff08\u56fe2h\uff09\uff0c\u53ea\u6709BH\/DPPTT\u7684\u590d\u5408\u534a\u5bfc\u4f53\u819c\u7684\u8fc1\u79fb\u7387\u968fBH\u542b\u91cf\u589e\u52a0\u800c\u663e\u8457\u4e0b\u964d\uff08\u6700\u7ec8\u964d\u81f30.06 cm2<\/sup>\u00a0V-1<\/sup>\u00a0s-1<\/sup>\uff09\uff0c\u4f46BA\u3001BF\u3001BAc\u4e0eDPPTT\u7684\u590d\u5408\u534a\u5bfc\u4f53\u8584\u819c\u8fc1\u79fb\u7387\u4e0e\u7eafDPPTT\u7684\u8fc1\u79fb\u7387\u4e00\u81f4\uff0c\u65e0\u8bba\u6df7\u5408\u6bd4\u4f8b\u5982\u4f55\uff0c\u90fd\u7ef4\u6301\u5728>1 cm2<\/sup>\u00a0V-1<\/sup>\u00a0s-1<\/sup>\u7684\u503c\u3002\u901a\u8fc7UV-vis\u8bc1\u660e\uff08\u56fe2j\uff09\uff0c\u6b63\u662f\u56e0\u4e3a\u5728BH\u4f53\u7cfb\u4e2d\uff0c\u5927\u91cf\u53e0\u6c2e\u4e0eDPPTT\u8fdb\u884c\u53cd\u5e94\uff0c\u7834\u574f\u534a\u5bfc\u4f53\u539f\u6709\u5806\u79ef\u548c\u7535\u5b50\u4f20\u8f93\u9014\u5f84\uff1b\u800c\u5176\u4f59\u5bf9\u6bd4\u5206\u5b50\uff0c\u5c24\u5176\u662f\u7cbe\u5de7\u8bbe\u8ba1\u7684BA\u5206\u5b50\uff0c\u5728\u9002\u5ea6\u4ea4\u8054\u534a\u5bfc\u4f53\uff08\u4fdd\u8bc1\u5176\u6297\u6eb6\u5242\u6027\u3001\u53ef\u5149\u56fe\u6848\u5316\u6027\u7b49\uff09\u7684\u540c\u65f6\uff0c\u5927\u91cf\u53e0\u6c2e\u5b9e\u9645\u4e0a\u662f\u4e0e\u81ea\u8eab\u9aa8\u67b6\u4e2d\u7684C=C\u53cc\u952e\u53cd\u5e94\uff0c\u5e76\u4e0d\u8fc7\u5ea6\u7834\u574f\u9ad8\u5206\u5b50\u534a\u5bfc\u4f53\u7684\u539f\u6709\u5806\u79ef\u548c\u7535\u5b50\u4f20\u8f93\u3002\u5728\u7ef4\u6301\u4f18\u5f02\u7535\u5b66\u6027\u80fd\u7684\u524d\u63d0\u4e0b\uff0cBA\/DPPTT\u7684\u590d\u5408\u534a\u5bfc\u4f53\u819c\u7684\u529b\u5b66\u6027\u80fd\uff08\u67d4\u6027\u548c\u53ef\u62c9\u4f38\u6027\uff09\u6709\u663e\u8457\u63d0\u9ad8\u3002\u4e0e\u7eafDPPTT\u76f8\u6bd4\uff0c\u590d\u5408\u819c\u7684\u6a21\u91cf\u51cf\u5c0f\u4e86\u56db\u500d\uff0c\u4e14\u62c9\u4f38\u65ad\u88c2\u957f\u5ea6\u63d0\u9ad8\u4e86\u4e00\u4e2a\u6570\u91cf\u7ea7\uff08\u56fe2k-m\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2\uff1a\u56db\u4e2a\u5bf9\u6bd4\u5206\u5b50\u7684\u5206\u5b50\u7ed3\u6784\uff0c\u4ee5\u53caiRUM\u7528\u4e8e\u534a\u5bfc\u4f53\u4e2d\u7684\u57fa\u672c\u529b\u5b66\u3001\u7535\u5b50\u5b66\u8868\u5f81\u3002<\/p>\n

\u4e3a\u4e86\u8868\u5f81\u62c9\u4f38\u8fc7\u7a0b\u4e2d\u7684BA\/DPPTT\u590d\u5408\u819c\u7535\u5b50\u5b66\u6027\u80fd\u7684\u53d8\u5316\uff0c\u4f5c\u8005\u4eec\u5236\u4f5c\u4e86\u672c\u5f81\u53ef\u62c9\u4f38\u573a\u6548\u5e94\u6676\u4f53\u7ba1\uff08\u56fe3\uff09\u3002\u5728\u62c9\u4f38\u8fc7\u7a0b\u4e2d\uff08\u56fe3c\uff09\uff0c\u590d\u5408\u819c\u53ef\u4ee5\u5b8c\u7f8e\u7ef4\u6301\u8fc1\u79fb\u7387\u76f4\u81f3100%\u62c9\u4f38\u957f\u5ea6\uff0c\u800c\u7eafDPPTT\u819c\u7684\u8fc1\u79fb\u7387\u663e\u8457\u4e0b\u964d\u8fd1\u4e24\u4e2a\u6570\u91cf\u7ea7\u3002\u540c\u65f6\uff0c\u4e3a\u4e86\u8868\u5f81\u590d\u5408\u819c\u7684\u201c\u9ad8\u5ea6\u53ef\u9006\u5f39\u6027\u201d\uff0c\u4f5c\u8005\u91c7\u7528\u4e86\u8f83\u4e3a\u82db\u523b\u7684\u62c9\u4f38\u5faa\u73af\uff0850%\u62c9\u4f38\u957f\u5ea6\uff0c1000\u5faa\u73af\uff09\uff0c\u53d1\u73b0\u590d\u5408\u819c\u80fd\u7a33\u5b9a\u5730\u7ef4\u6301\u7535\u5b66\u6027\u80fd\uff0c\u800c\u7eafDPPTT\u8fc1\u79fb\u7387\u4e0b\u964d\u4e24\u4e2a\u6570\u91cf\u7ea7\uff08\u56fe3d\uff09\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u8bc1\u660eiRUM\u7b56\u7565\u7684\u666e\u9002\u6027\uff0c\u4f5c\u8005\u53c8\u9009\u7528\u4e86\u53e6\u4e00\u79cd\u4e0eDPPTT\u8584\u819c\u5f62\u8c8c\u5b8c\u5168\u4e0d\u540c\u7684\u9ad8\u5206\u5b50\u534a\u5bfc\u4f53\uff0cIDTBT\uff08\u56fe3g\uff09\u3002IDTBT\u4e4b\u524d\u5df2\u7ecf\u88abZhenan\u00a0Bao\u7ec4\u62a5\u9053\u5177\u6709\u9ad8\u5ea6\u7684\u201c\u53ef\u62c9\u4f38\u6027\u201d\uff0c\u4f46\u8be5\u53ef\u62c9\u4f38\u6027\u5374\u5b8c\u5168\u4e0d\u53ef\u9006\uff08\u5373\u975e\u5f39\u6027\uff1a\u5728\u5916\u754c\u62c9\u4f38\u88ab\u64a4\u53bb\u540e\u65e0\u6cd5\u56de\u5230\u539f\u6709\u72b6\u6001\uff0c\u5448\u73b0\u5927\u91cf\u8936\u76b1\uff0c\u7535\u5b66\u6027\u80fd\u663e\u8457\u4e0b\u964d\uff09\u3002\u800c\u4f7f\u7528\u4e86iRUM\u7b56\u7565\u540e\uff0cBA\/IDTBT\u590d\u5408\u819c\u57281000\u6b2150%\u62c9\u4f38\u957f\u5ea6\u5faa\u73af\u540e\uff0c\u4f9d\u7136\u7ef4\u6301>1 cm2<\/sup>\u00a0V-1<\/sup>\u00a0s-1<\/sup>\u7684\u8fc1\u79fb\u7387\uff1b\u800c\u7eafIDTBT\u5c06\u81f30.07 cm2<\/sup>\u00a0V-1<\/sup>\u00a0s-1<\/sup>\uff08\u56fe3h\uff09\uff0c\u8be5\u5faa\u73af\u6027\u80fd\u5df2\u662f\u76ee\u524d\u62a5\u9053\u7684\u9ad8\u5206\u5b50\u534a\u5bfc\u4f53\u4e2d\u7684\u6700\u9ad8\u503c\u3002\u7136\u800c\u66f4\u4ee4\u4f5c\u8005\u60ca\u8bb6\u7684\u662f\uff0c\u5373\u4f7f\u5faa\u73af\u6570\u589e\u52a0\u52305000\u5708\uff084\u5c0f\u65f6\u8fde\u7eed\u4e0d\u65ad\u5faa\u73af\uff09\uff0c\u590d\u5408\u534a\u5bfc\u4f53\u819c\u4f9d\u7136\u7ef4\u6301\u975e\u5e38\u7a33\u5b9a\u7684\u8fc1\u79fb\u7387\u6027\u80fd\uff0c\u8be5\u62c9\u4f38\u5faa\u73af\u5bff\u547d\u5df2\u662f\u76ee\u524d\u4efb\u4f55\u4e00\u4f8b\u62a5\u9053\u76845\u500d\uff08\u56fe3i\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3\uff1aiRUM\u534a\u5bfc\u4f53\u7684\u53ef\u62c9\u4f38\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u8868\u5f81\u3001iRUM\u8584\u819c\u5faa\u73af\u62c9\u4f38\u6d4b\u8bd5\u3001\u62c9\u4f38\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u7535\u5b50\u5b66\u6027\u80fd\u3001\u6297\u6eb6\u5242\u6027\u7b49\u8868\u5f81\u3002<\/p>\n

\u9664\u4e86\u4f18\u826f\u7684\u529b\u5b66\u5f39\u6027\u548c\u7535\u5b66\u6027\u80fd\uff0cBA\/DPPTT\u590d\u5408\u819c\u5177\u6709\u826f\u597d\u7684\u6297\u6eb6\u5242\u6027\uff08\u56fe3k\uff09\u3002\u7ed3\u5408\u4e0aBA\u7684\u5149\u5f15\u53d1\u4ea4\u8054\u7279\u6027\uff0c\u8fd9\u4e5f\u542f\u53d1\u4e86\u4f5c\u8005\u5bf9BA\/DPPTT\u8fdb\u884c\u5149\u56fe\u6848\u5316\u7684\u5b9e\u9a8c\u3002\u5149\u56fe\u6848\u5316\u540e\uff0c\u590d\u5408\u819c\u7684\u8fc1\u79fb\u7387\u4e5f\u7ef4\u6301\u5728>1 cm2<\/sup>\u00a0V-1<\/sup>\u00a0s-1<\/sup>\u7684\u503c\uff08\u56fe4a-c\uff09\u3002<\/p>\n

\u53e6\u5916\uff0c\u4f5c\u8005\u4eec\u53d1\u73b0iRUM\u7684\u7b56\u7565\u4e5f\u80fd\u7528\u4e8e\u4ecb\u7535\u5c42\u6750\u6599\u3002\u4e0e\u534a\u5bfc\u4f53\u5c42\uff0830-40nm\uff09\u76f8\u6bd4\uff0c\u5fae\u7c73\u7ea7\u522b\u539a\u5ea6\u7684\u4ecb\u7535\u5c42\u66f4\u5bb9\u6613\u88ab\u6709\u673a\u6eb6\u5242\u6eb6\u89e3\u6216\u8005\u6eb6\u80c0\u3002\u63d0\u9ad8\u4ecb\u7535\u5c42\u6750\u6599\u4e0e\u524d\u9a71\u4f53\u95f4\u7684\u4ea4\u8054\u5bc6\u5ea6\u53ef\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\u3002\u4f5c\u8005\u53d1\u73b0\u4f20\u7edf\u7684\u4ecb\u7535\u5c42\u805a\u5408\u7269\u6750\u6599SEBS\u5728\u7528\u5927\u91cfBH\uff08BH:SEBS\u8d28\u91cf\u6bd44:5\uff09\u4ea4\u8054\u540e\uff0c\u53d8\u5f97\u6781\u5176\u6297\u6eb6\u5242\u4fb5\u8680\uff08\u56fe4d\uff09\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5728\u8fd9\u91cc\u4f5c\u8005\u4eec\u4f7f\u7528\u4e86BH\u800c\u975eBA\uff0c\u8fd9\u4e5f\u662f\u7ecf\u8fc7\u7cbe\u5de7\u8bbe\u8ba1\u7684\uff1aBA\u8fc7\u591a\u7684\u4e0e\u81ea\u8eab\u4ea4\u8054\uff0c\u4e0d\u80fd\u5f88\u597d\u5730\u4ea4\u8054SEBS\u4ece\u800c\u4f7f\u5176\u6297\u6eb6\u5242\uff1b\u800cBH\u4e0eSEBS\u5747\u5300\u6df7\u5408\u540e\uff0c\u53e0\u6c2e\u57fa\u56e2\u65e0\u6cd5\u533a\u5206\u81ea\u8eab\u9aa8\u67b6\u4e0eSEBS\u9aa8\u67b6\uff0c\u4ece\u800c\u540c\u65f6\u4ea4\u8054\uff0c\u52a0\u4e0a\u8be5\u4ecb\u7535\u5c42\u590d\u5408\u819c\u4e2dBH\u5360\u6bd4\u9ad8\u3001\u4ea4\u8054\u7a0b\u5ea6\u9ad8\uff0c\u4f7f\u5f97\u8be5\u4ecb\u7535\u5c42\u590d\u5408\u819c\u6781\u5176\u6297\u6eb6\u5242\u3002\u540c\u65f6\uff0c\u8be5\u4ecb\u7535\u5c42\u590d\u5408\u819c\u7684\u529b\u5b66\u5f39\u6027\u4e5f\u88ab\u8bc1\u660e\u6781\u597d\uff08\u56fe4h\uff09\u3002<\/p>\n

\u6700\u540e\uff0c\u4f5c\u8005\u5c06iRUM\u534a\u5bfc\u4f53\u590d\u5408\u819c\u4e0eiRUM\u4ecb\u7535\u5c42\u590d\u5408\u819c\u96c6\u6210\u5230\u4e00\u4f53\uff0c\u5236\u4f5c\u4e86\u5f39\u6027\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u9635\u5217\uff0c\u572850%\u62c9\u4f38\u957f\u5ea6\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4e5f\u83b7\u5f97\u4e86\u6781\u5176\u7a33\u5b9a\u7684\u6027\u80fd\uff08\u56fe4i\u3001j\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4\uff1a\u4ee5\u7845\u7247\u4e3a\u57fa\u5e95\u7684iRUM\u534a\u5bfc\u4f53\u5149\u56fe\u6848\u5316\u5668\u4ef6\u6027\u80fd\u3001iRUM\u4ecb\u7535\u5c42\u7684\u53ef\u5149\u56fe\u6848\u5316\u6027\u4e0e\u529b\u5b66\u6027\u80fd\u3001\u5f39\u6027\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u9635\u5217\u5728\u62c9\u4f38\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u7535\u5b50\u5b66\u6027\u80fd\u3002<\/p>\n

\u3010\u603b\u7ed3\u3011<\/p>\n

\u5728\u672c\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u4f7f\u7528\u4e86\u4e00\u7cfb\u5217\u53ef\u539f\u4f4d\u5f62\u6210\u5f39\u6027\u4f53\u57fa\u8d28\u7684\u524d\u9a71\u4f53\uff0c\u7528\u4e8e\u4f5c\u4e3a\u666e\u901aDPPTT\u9ad8\u5206\u5b50\u534a\u5bfc\u4f53\u6216SEBS\u4ecb\u7535\u5c42\u6750\u6599\u7684\u57fa\u8d28\uff0c\u901a\u8fc7\u52a0\u70ed\u6216\u8005\u7d2b\u5916\u5149\u5f15\u53d1\u4ea4\u8054\uff0c\u5b9e\u73b0\u4e86\u9ad8\u8fc1\u79fb\u7387\u7ef4\u6301\u3001\u53ef\u9006\u5f39\u6027\u3001\u6297\u6eb6\u5242\u3001\u5149\u56fe\u6848\u5316\u3001\u53ef\u91cf\u4ea7\u3001\u5ec9\u4ef7\u6027\u7b49\u4f18\u826f\u6027\u80fd\u7684\u96c6\u6210\u4e8e\u4e00\u4f53\u3002\u8be5\u5de5\u4f5c\u4ece\u5206\u5b50\u8bbe\u8ba1\u89d2\u5ea6\u771f\u6b63\u63d0\u51fa\u4e86\u4ece\u201c\u67d4\u6027\u53ef\u62c9\u4f38\u534a\u5bfc\u4f53\u201d\u5411\u201c\u53ef\u9006\u5f39\u6027\u591a\u529f\u80fd\u534a\u5bfc\u4f53<\/b><\/strong>\u201d\u7684\u8f6c\u53d8\uff0c\u4e3a\u9ad8\u5206\u5b50\u534a\u5bfc\u4f53\u5411\u771f\u6b63\u5b9e\u7528\u3001\u7b26\u5408\u6d88\u8d39\u8005\u9700\u6c42\u7684\u5546\u4e1a\u5316\u63d0\u4f9b\u4e86\u4e00\u79cd\u53ef\u80fd\u3002\u66f4\u591a\u8be6\u5b9e\u7684\u7814\u7a76\u548c\u4ea4\u53c9\u6620\u8bc1\u7684\u8868\u5f81\uff0c\u8bf7\u8be6\u89c1\u672c\u6587\u7684Supplementary\u00a0Information\u3002<\/p>\n

\u3010\u6587\u7ae0\u94fe\u63a5\u3011<\/p>\n

Zheng, Y., Yu, Z. et al.\u00a0A molecular design approach towards elastic and multifunctional polymer electronics. Nat. Commun. (2021). DOI:\u00a010.1038\/s41467-021-25719-9<\/p>\n

\u3010\u4f5c\u8005\u4ecb\u7ecd\u3011<\/p>\n

\"\"<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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