{"id":228411,"date":"2021-10-18T06:19:20","date_gmt":"2021-10-17T22:19:20","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=228411"},"modified":"2021-10-17T21:19:28","modified_gmt":"2021-10-17T13:19:28","slug":"%e6%a1%86%e6%9e%b6%e6%9d%90%e6%96%99%e5%a4%a7%e4%bd%ac%e7%ba%a7%e4%ba%ba%e7%89%a9omar-m-yaghi%e8%bf%91%e4%b8%a4%e5%b9%b4%e5%86%85%e5%8f%88%e6%9c%89%e5%93%aa%e4%ba%9b%e5%a5%bd%e6%96%87%e7%ab%a0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=228411","title":{"rendered":"\u6846\u67b6\u6750\u6599\u5927\u4f6c\u7ea7\u4eba\u7269Omar M.Yaghi\u8fd1\u4e24\u5e74\u5185\u53c8\u6709\u54ea\u4e9b\u597d\u6587\u7ae0\u5462\uff1f\u5feb\u6765\u901f\u89c8"},"content":{"rendered":"<p><strong>\u4e2a\u4eba\u7b80\u4ecb<\/strong><\/p>\n<p>Omar M.Yaghi\u6559\u6388\u662f\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u3001\u6cb8\u77f3\u54aa\u5511\u9178\u916f\u9aa8\u67b6\u3001\u914d\u4f4d\u805a\u5408\u7269\u7b49\u9886\u57df\u7684\u5f00\u62d3\u8005\u548c\u5960\u57fa\u4eba\u3002\u4ed6\u5728\u529f\u80fd\u591a\u5b54\u6750\u6599\u7684\u5408\u6210\uff0c\u53ca\u5176\u50a8\u80fd\u3001\u73af\u4fdd\u7b49\u9886\u57df\u7684\u5e94\u7528\u8fdb\u884c\u4e86\u591a\u5e74\u7684\u7814\u7a76\uff0c\u5e76\u53d6\u5f97\u4e86\u6770\u51fa\u7684\u7814\u7a76\u6210\u679c\u3002\u672c\u6587\u76d8\u70b9\u4e86\u4e00\u4e0b2020-2021\u671f\u95f4\uff0c9\u7bc7\u91cd\u91cf\u7ea7\u6587\u732e\uff0c\u5e0c\u671b\u80fd\u591f\u5bf9\u76f8\u5173\u9886\u57df\u7814\u7a76\u8005\u6709\u5e2e\u52a9\u3002<\/p>\n<p><strong><b>1.Cu(I)\u548c Ag(I)\u5bf9\u63a5\u7684\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u53ef\u7528\u4e8e\u5438\u9644\u548c\u5206\u79bb\u6c19 <\/b><\/strong><\/p>\n<p>Omar M.Yaghi\u6559\u6388\u4e8e2021\u5e741\u6708\u4e8eAngew.Chem.Int.Ed\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u76ee\u4e3a\u201cDocking of CuI and AgI in Metal\u2010Organic Frameworks for Adsorption and Separation of Xenon\u201d\u7684\u6587\u7ae0\u3002\u8be5\u6587\u7ae0\u4e3b\u8981\u8bb2\u8ff0\u5229\u7528\u591a\u5b54\u5438\u9644\u5242\u4ece\u6c2a\u6c14\u4e2d\u5206\u79bb\u6c19\u6c14\u662f\u4e00\u79cd\u53ef\u6301\u7eed\u751f\u4ea7\u5c0f\u4f53\u79ef\u4f46\u9ad8\u4ef7\u503c\u60f0\u6027\u6c14\u4f53\u7684\u6280\u672f\u3002MOF \u662f\u8bbe\u8ba1\u597d\u7684\u6c19\u6c14\u5438\u9644\u5242\uff0c\u5176\u5438\u9644\u5206\u79bb\u6027\u80fd\u53ef\u4ee5\u901a\u8fc7\u8c03\u6574\u5b54\u9699\u6307\u6807\u3001\u529f\u80fd\u548c\u6297\u8861\u79bb\u5b50\u6765\u589e\u5f3a\u3002Yue-Biao Zhang\u3001Omar M. Yaghi \u548c\u5176\u4ed6\u5408\u4f5c\u8005\u63cf\u8ff0\u4e86\u4e00\u79cd\u65b0\u7684 MOF \u5408\u6210\u540e\u91d1\u5c5e\u5316\u65b9\u6cd5\uff0c\u8be5\u65b9\u6cd5\u901a\u8fc7\u4fdd\u7559\u591a\u4f59\u7684\u91d1\u5c5e\u79bb\u5b50\u548c\u6297\u8861\u79bb\u5b50\u6765\u540c\u65f6\u63d0\u9ad8\u5438\u9644\u9009\u62e9\u6027\u548c\u5438\u6536\u80fd\u529b\u3002<\/p>\n<p>\u7279\u522b\u662f\uff0cAg-MOF-303 \u5728 298 K \u548c 0.2 bar \u4e0b\u8868\u73b0\u51fa 59 cm<sup>3<\/sup>\u2022cm <sup>-3<\/sup>\u00a0\u7684 Xe \u5438\u6536\uff0c\u9009\u62e9\u6027\u4e3a 10.4\uff0c\u4f7f\u5176\u6210\u4e3a\u6027\u80fd\u6700\u9ad8\u7684 MOF\u3002\u4e0e\u539f\u59cb MOF-303 \u76f8\u6bd4\uff0c\u52a8\u6001\u5206\u79bb\u6027\u80fd\u63d0\u9ad8\u4e86 100%\u3002\u8fd9\u79cd\u91d1\u5c5e\u5316\u7b56\u7565\u4ee3\u8868\u4e86\u4e00\u79cd\u8bbe\u8ba1 MOF \u4ee5\u63d0\u4f9b\u9ad8\u6027\u80fd\u6c14\u4f53\u5206\u79bb\u7684\u65b0\u7b56\u7565\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-228413\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72471-4.png\" alt=\"\" width=\"600\" height=\"380\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72471-4.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72471-4-300x190.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe 1. a) \u7531 3D EDT \u786e\u5b9a\u7684 Cu-MOF-303 \u7ed3\u6784\uff0c\u5176\u4e2d Cu(I) \u79bb\u5b50\u88ab\u6765\u81ea\u4e24\u4e2a\u76f8\u90bb PZDC \u63a5\u5934\u7684 N \u539f\u5b50\u87af\u5408\u3002 b) MOF-303 \u7ed3\u6784\u7531 3D EDT \u786e\u5b9a\uff0c\u76f8\u90bb PZDC \u63a5\u5934\u4e4b\u95f4\u5177\u6709\u57fa\u4e8e\u5421\u5511\u7684\u91d1\u5c5e\u5bf9\u63a5\u4f4d\u70b9\u3002 c) Ag-MOF-303 \u7ed3\u6784\u7531 3D EDT \u786e\u5b9a\uff0cAg(I) \u79bb\u5b50\u88ab\u6765\u81ea\u4e24\u4e2a\u76f8\u90bb PZDC \u63a5\u5934\u7684 N \u539f\u5b50\u87af\u5408\u3002 d) \u91cd\u6784\u7684 Cu-MOF-303 \u4e09\u7ef4\u5012\u6613\u6676\u683c\u6cbf[010] \u65b9\u5411\u3002 e) \u91cd\u6784\u540e\u7684 MOF-303 \u4e09\u7ef4\u5012\u6613\u6676\u683c\u6cbf [010] \u65b9\u5411\u7684\u6295\u5f71\u3002 f) \u91cd\u5efa\u7684 Ag-MOF-303 \u4e09\u7ef4\u5012\u6613\u6676\u683c\u6cbf [010] \u65b9\u5411\u7684\u6295\u5f71\u3002 \u5706\u5708\u4ee3\u8868 1.0 \u00c5 \u7684\u5206\u8fa8\u7387\u3002 \u989c\u8272\u4ee3\u7801\uff1aC\uff0c\u7070\u8272\uff1b O\uff0c\u7ea2\u8272\uff1b N\uff0c\u7eff\u8272\uff1b Al\uff0c\u84dd\u8272\uff1b Cu\uff0c\u7c89\u7ea2\u8272\uff1b Ag\uff0c\u6df1\u84dd\u8272\u3002 \u4e3a\u6e05\u695a\u8d77\u89c1\u7701\u7565\u4e86 H \u539f\u5b50\u3002<\/p>\n<p><strong><b>2.<\/b><\/strong>\u00a0<strong><b>\u7f51\u72b6\u5316\u5b66<\/b><\/strong><strong><b>\u5bb6<\/b><\/strong><\/p>\n<p>2020\u5e7411\u6708\uff0cOmar M.Yaghi\u6559\u6388\u672c\u4eba\u5728Nano Lett\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cThe Reticular Chemist\u201d\u7684\u6587\u7ae0\u3002\u8be5\u6587\u7ae0\u53d1\u8868\u7684\u4e3b\u8981\u76ee\u7684\u662f\u5411\u8bfb\u8005\u4ecb\u7ecd\u7f51\u72b6\u5316\u5b66\uff0cMOF \u548c COF \u80cc\u540e\u7684\u5316\u5b66\u4ee5\u53ca\u4e0e\u901a\u8fc7\u5f3a\u952e\u5c06\u5206\u5b50\u6784\u5efa\u5355\u5143\u8fde\u63a5\u6210\u6676\u4f53\u6269\u5c55\u7ed3\u6784\u3002Omar M.Yaghi\u6559\u6388\u6307\u51fa\u7f51\u72b6\u5316\u5b66\u4e0d\u4ec5\u8d77\u6e90\u4e8e\u57fa\u7840\u6709\u673a\u5316\u5b66\u548c\u65e0\u673a\u5316\u5b66\uff0c\u800c\u4e14\u7814\u7a76\u8005\u4eec\u5bf9\u5b83\u7684\u8ffd\u6c42\u6269\u5927\u4e86\u8fd9\u4e9b\u5316\u5b66\u7684\u8303\u56f4\u548c\u77e5\u8bc6\u57fa\u7840\uff0c\u800c\u4e14\u5b83\u4e0e\u8d85\u5206\u5b50\u548c\u9ad8\u5206\u5b50\u5316\u5b66\u622a\u7136\u4e0d\u540c\u3002\u7f51\u72b6\u5316\u5b66\u662f\u5728\u539f\u5b50\u548c\u5206\u5b50\u6c34\u5e73\u4ee5\u53ca\u73b0\u5728\u7684\u6846\u67b6\u6c34\u5e73\u4e0a\u5236\u4f5c\u7269\u8d28\u3002\u60f3\u8981<strong><b>\u6df1\u5165\u4e86\u89e3MOF \u548c COF\u53ca\u7f51\u72b6\u5316\u5b66\u7684\u53d1\u5c55\uff0c\u503c\u5f97\u4e00\u770b<\/b><\/strong>\u3002<\/p>\n<p><strong><b>3.<\/b><\/strong>\u00a0<strong><b>\u7528\u4e8e\u968f\u65f6\u968f\u5730\u4ece\u7a7a\u6c14\u4e2d\u6536\u96c6\u6c34\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6<\/b><\/strong><\/p>\n<p>\u6c34\u5bf9\u751f\u547d\u81f3\u5173\u91cd\u8981\u3002\u636e\u4f30\u8ba1\uff0c\u5230 2050 \u5e74\uff0c\u7531\u4e8e\u5e72\u65f1\u6216\u7f3a\u4e4f\u6e05\u6d01\u6c34\u6e90\uff0c\u8fd1\u4e00\u534a\u7684\u4e16\u754c\u4eba\u53e3\u5c06\u751f\u6d3b\u5728\u7f3a\u6c34\u5730\u533a\u3002\u7a7a\u6c14\u4e2d\u7684\u5927\u91cf\u6c34\u4e0d\u4ec5\u53ef\u4ee5\u4ece\u6e7f\u5ea6\u8f83\u4f4e\u7684\u6c99\u6f20\u5927\u6c14\u4e2d\u83b7\u53d6\uff0c\u8fd8\u53ef\u4ee5\u4ece\u4e16\u754c\u4e0a\u9700\u8981\u6e05\u6d01\u6c34\u7684\u66f4\u6f6e\u6e7f\u5730\u533a\u83b7\u53d6\u3002\u539f\u5219\u4e0a\uff0c\u7528\u4e8e\u5728\u8fd9\u4e9b\u6c14\u5019\u6761\u4ef6\u4e0b\u4ece\u7a7a\u6c14\u4e2d\u6536\u96c6\u6c34\u7684\u6750\u6599\uff0c\u5e94\u8be5\u9002\u7528\u4e8e\u653e\u7f6e\u5728\u4e16\u754c\u4efb\u4f55\u5730\u65b9\uff0c\u5728\u4e00\u5e74\u4e2d\u7684\u4efb\u4f55\u65f6\u95f4\u63d0\u53d6\u5927\u6c14\u6c34\u3002\u9488\u5bf9\u8be5\u95ee\u9898\uff0cOmar M.Yaghi\u6559\u6388\u53ca\u5176\u5408\u4f5c\u8005\u60f3\u5230\u4e86\u91d1\u5c5e\u6709\u673a\u6846\u67b6 (MOF)\u8fd9\u7c7b\u72ec\u7279\u7684\u591a\u5b54\u6750\u6599\u3002\u5e76\u8fdb\u884c\u4e86\u7814\u7a76\u3002\u7ed3\u679c\u53d1\u73b0\u8be5\u6750\u6599\u786e\u5b9e\u80fd\u591f\u5728\u4f4e\u81f3 10% \u7684\u76f8\u5bf9\u6e7f\u5ea6\u6c34\u5e73\u4e0b\u6355\u83b7\u6c34\uff0c\u5e76\u4e14\u5177\u6709\u8f7b\u677e\u7684\u5438\u6536\u548c\u91ca\u653e\u52a8\u529b\u5b66\u3002\u4ece\u5b9e\u9a8c\u5ba4\u6d4b\u8bd5\u5230\u6700\u5e72\u71e5\u6c99\u6f20\u4e2d\u7684\u73b0\u573a\u8bd5\u9a8c\uff0c\u5df2\u7ecf\u5728\u51e0\u4ee3\u8bbe\u5907\u4e2d\u6d4b\u8bd5\u4e86\u5343\u514b\u6570\u91cf\u7684 MOF\u3002\u8fd9\u4e9b\u5b9e\u9a8c\u7684\u521d\u6b65\u7ed3\u679c\u8868\u660e\uff0cMOF \u53ef\u4ee5\u4ece\u6c99\u6f20\u6c14\u5019\u4e2d\u6355\u83b7\u6c34\uff0c\u5e76\u4e14\u6bcf\u5929\u6bcf\u516c\u65a4 MOF \u53ef\u4ee5\u8f93\u9001\u8d85\u8fc7 1 \u5347\u7684\u6c34\u3002\u5f53\u5728\u6bcf\u5929\u8fd0\u884c\u591a\u6b21\u5faa\u73af\u7684\u7535\u6c14\u8bbe\u5907\u4e2d\u4f7f\u7528 MOF \u5bb6\u65cf\u6210\u5458\u65f6\uff0c\u6c34\u751f\u4ea7\u7387\u53ef\u4ee5\u63d0\u9ad8\u4e00\u4e2a\u6570\u91cf\u7ea7\u4ee5\u4e0a\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-228414\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72472-4.png\" alt=\"\" width=\"600\" height=\"486\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72472-4.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72472-4-300x243.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>\u56fe 2. \u4fee\u6539\u7684\u7a7a\u6c14\u6e7f\u5ea6\u56fe\uff0c\u8bf4\u660e\u4e86\u4f4e\u76f8\u5bf9\u6e7f\u5ea6 (a) \u7684\u7a7a\u6c14\u5fc5\u987b\u51b7\u5374\u5230\u4f4e\u6e29 (b) \u624d\u80fd\u88ab\u6c34\u9971\u548c\uff08\u5373\u9732\u70b9\uff09\uff0c\u800c\u5728\u9ad8 RH (c) \u4e0b\uff0c\u8fd9\u79cd\u51b7\u5374\u662f\u6700\u5c0f (d)\u3002 MOF \u7684\u4f7f\u7528\u57fa\u672c\u4e0a\u9700\u8981\u4f4e RH \u7a7a\u6c14 (a) \u5e76\u4f7f\u5176\u5177\u6709\u9ad8 RH (c)\uff0c\u56e0\u6b64\u6bd4\u76f4\u63a5\u51b7\u5374\u66f4\u6709\u6548\u5730\u7528\u6c34\u9971\u548c\u6c99\u6f20\u7a7a\u6c14\u3002 \u7eff\u8272\u533a\u57df\u662f\u53ef\u4ee5\u4f7f\u7528\u76f4\u63a5\u51b7\u5374\u4ece\u7a7a\u6c14\u4e2d\u4ea7\u751f\u6c34\u7684\u5730\u65b9\uff0c\u4f46\u5728\u7c89\u7ea2\u8272\u533a\u57df\u4e2d\uff0cMOF \u975e\u5e38\u9002\u5408\u5c06\u6c99\u6f20\u7a7a\u6c14\u8f6c\u5316\u4e3a\u8f83\u4f4e\u6c34\u5e73\u7684\u7a7a\u6c14\u5c06\u6c34\u5206\u8f6c\u5316\u4e3a\u201c\u70ed\u5e26\u7a7a\u6c14\u201d\u3002 \u8fd9\u79cd MOF \u4e5f\u9002\u7528\u4e8e\u7eff\u8272\u533a\u57df\u3002<\/p>\n<p><strong><b>4.\u591a\u5143\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u4e2d\u91d1\u5c5e\u7684\u6d4b\u5e8f<\/b><\/strong><\/p>\n<p>\u5927\u591a\u6570\u91d1\u5c5e\u6709\u673a\u6846\u67b6 (MOF) \u5728\u8fde\u63a5\u6709\u673a\u8fde\u63a5\u5b50\u7684\u8282\u70b9\u4e2d\u4ec5\u5305\u542b\u4e00\u79cd\u91d1\u5c5e\u3002\u5305\u542b\u591a\u79cd\u91d1\u5c5e\u7684\u591a\u5143 MOF \u53ef\u4ee5\u5728\u5438\u9644\u548c\u50ac\u5316\u6027\u80fd\u65b9\u9762\u63d0\u4f9b\u66f4\u5927\u7684\u9009\u62e9\u6027\uff0c\u4f46\u786e\u5b9a\u8fd9\u4e9b\u6750\u6599\u4e2d\u91d1\u5c5e\u7684\u6392\u5217\u5177\u6709\u6311\u6218\u6027\u3002<\/p>\n<p>2020\u5e748\u6708\uff0cOmar M.Yaghi\u6559\u6388\u7b49\u4eba\u53d1\u73b0\u539f\u5b50\u63a2\u9488\u65ad\u5c42\u626b\u63cf\u53ef\u4ee5\u63ed\u793a\u542b\u6709\u94b4 (Co)\u3001\u9549 (Cd)\u3001\u94c5 (Pb) \u548c\u9530 (Mn)\u79bb\u5b50\u7ec4\u5408\u7684 MOF-74 \u5355\u6676\u7684\u91d1\u5c5e\u5e8f\u5217\u3002\u5728\u8fd9\u79cd MOF \u4e2d\uff0c\u91d1\u5c5e\u5f62\u6210\u6c27\u5316\u7269\u68d2\uff0c\u901a\u8fc7\u6709\u673a\u8fde\u63a5\u4f53\u8fde\u63a5\u6210\u8702\u7a9d\u72b6\u6676\u683c\u3002\u901a\u8fc7\u6539\u53d8\u91d1\u5c5e\u7684\u6bd4\u4f8b\u548c\u5408\u6210\u6e29\u5ea6\u6765\u8c03\u6574\u83b7\u5f97\u7684\u5e8f\u5217\uff0c\u53ef\u4ee5\u662f\u968f\u673a\u7684\u3001\u77ed\u7684\u548c\u957f\u7684\u91cd\u590d\u4ee5\u53ca\u5355\u4e2a\u91d1\u5c5e\u63d2\u5165\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-228415\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72473-4.png\" alt=\"\" width=\"600\" height=\"797\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72473-4.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72473-4-226x300.png 226w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>\u56fe3 \u00a0Co,CdMOF-74 \u5355\u6676\u4e2d\u91d1\u5c5e\u7684 APT \u6d4b\u91cf\u548c\u6d4b\u5e8f\u3002<\/p>\n<p><strong><b>5.MOF\u96c6\u6c34\u5668<\/b><\/strong><\/p>\n<p>\u4e3a\u4e86\u6709\u6548\u89e3\u51b3\u5168\u7403\u6c34\u8d44\u6e90\u77ed\u7f3a\u5371\u673a\uff0c\u5fc5\u987b\u5f00\u53d1\u66f4\u591a\u7684\u6de1\u6c34\u751f\u6210\u65b9\u6cd5\u3002\u5728\u8fd9\u65b9\u9762\uff0c\u63d0\u53d6\u65e0\u5904\u4e0d\u5728\u7684\u5927\u6c14\u6c34\u5206\u662f\u4e00\u79cd\u5f3a\u5927\u7684\u7b56\u7565\uff0c\u5141\u8bb8\u5206\u6563\u83b7\u53d6\u996e\u7528\u6c34\u3002\u5982\u679c\u5728\u5927\u6c14\u6c34\u53d1\u751f\u5668\u4e2d\u96c6\u6210\u4e86\u5408\u9002\u7684\u5438\u9644\u5242\uff0c\u5219\u53ef\u4ee5\u663e\u8457\u51cf\u5c11\u8fd9\u79cd\u65b9\u6cd5\u7684\u80fd\u91cf\u9700\u6c42\u4ee5\u53ca\u65f6\u95f4\u548c\u7a7a\u95f4\u9650\u5236\u3002\u6700\u8fd1\uff0c\u91d1\u5c5e\u6709\u673a\u6846\u67b6 (MOF) \u5df2\u6210\u529f\u7528\u4f5c\u5438\u9644\u5242\u4ece\u7a7a\u6c14\u4e2d\u6536\u96c6\u6c34\uff0c\u5373\u4f7f\u5728\u6c99\u6f20\u73af\u5883\u4e2d\u4e5f\u80fd\u4ea7\u751f\u5927\u6c14\u6c34\u3002Omar M.Yaghi\u6559\u6388\u4e8eScience\u4e0a\u7efc\u8ff0\u4e86\u80fd\u591f\u4ece\u7a7a\u6c14\u4e2d\u63d0\u53d6\u6c34\u5206\u7684 MOF \u7684\u6700\u65b0\u8fdb\u5c55\u4ee5\u53ca\u8bf4\u660e\u4e86\u8fd9\u79cd MOF \u7684\u5927\u6c14\u96c6\u6c34\u5668\u7684\u8bbe\u8ba1\u3002\u6b64\u5916\uff0c\u8fd8\u6982\u8ff0\u4e86\u8fd9\u4e00\u65b0\u5174\u9886\u57df\u7684\u672a\u6765\u53d1\u5c55\u65b9\u5411\uff0c\u5305\u62ec\u6750\u6599\u548c\u8bbe\u5907\u7684\u6539\u8fdb\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-228416\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72474-4.png\" alt=\"\" width=\"600\" height=\"575\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72474-4.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72474-4-300x288.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe4 \u7528\u4e8e\u5927\u6c14\u96c6\u6c34\u7684 MOF \u7684\u7f51\u72b6\u8bbe\u8ba1\u3002\u7f51\u72b6\u5316\u5b66\u7684\u91cd\u8981\u7279\u5f81\u4f7f MOF \u6210\u4e3a\u7528\u4e8e\u5927\u6c14\u6c34\u6536\u96c6\u7684\u4e00\u7c7b\u72ec\u7279\u7684\u5438\u9644\u5242\uff0c\u6536\u96c6\u6548\u679c\u7531\u5177\u6709\u5404\u81ea\u5438\u6c34\u7b49\u6e29\u7ebf\u7684\u9009\u5b9a\u793a\u4f8b\u8868\u793a\u3002\u987a\u65f6\u9488\uff0c\u4ece\u53f3\u4e0a\u89d2\u5f00\u59cb\uff1a\u53ef\u4ee5\u4f7f MOF \u6c34\u89e3\u7a33\u5b9a\u7684\u4e8c\u200b\u200b\u7ea7\u6784\u5efa\u5355\u5143 (SBU) \u7684\u793a\u4f8b\uff1b MOF-801 \u7684\u9636\u68af\u72b6\u7b49\u6e29\u7ebf\u8f6e\u5ed3\u4e0e\u5b54\u9699\u586b\u5145\u65f6\u6c34\u56e2\u7c07\u7684\u5f62\u6210\u6709\u5173\uff1b\u5b54\u4f53\u79ef\u5bf9\u7b49\u7f51\u72b6\u9aa8\u67b6MOF-801 \u548c UiO-66 11\u5438\u6c34\u7279\u6027\u7684\u5f71\u54cd\uff1b Cr-soc-MOF-1,\u4e00\u79cd\u6c34\u7a33\u5b9a\u7684 MOF\uff0c\u636e\u62a5\u9053\u5438\u6c34\u7387\u6700\u9ad8 35 \uff1b\u901a\u8fc7\u6539\u53d8\u5438\u6c34\u6027\u80fd\u5728SBU 41\u5904\u901a\u8fc7\u9634\u79bb\u5b50\u4ea4\u6362\u5c06Ni<sub>2<\/sub>Cl<sub>2<\/sub>BTDD\u8f6c\u5316\u4e3aNi<sub>2<\/sub>Br<sub>2<\/sub>BTDD\uff1b\u8fde\u63a5\u5668\u529f\u80fd\u5bf9\u7b49\u7f51\u72b6\u6846\u67b6 CAU-10 \u548c MIL-160 \u7684\u5438\u6c34\u7279\u6027\u7684\u5f71\u54cd\u3002\u5728\u9002\u7528\u7684\u60c5\u51b5\u4e0b\uff0cSBU \u4ee5\u5176\u6c34\u5408\u5f62\u5f0f\u663e\u793a\u3002\u4e3a\u6e05\u695a\u8d77\u89c1\uff0c\u7701\u7565\u4e86\u6240\u6709\u6c22\u539f\u5b50\u3002\u7c89\u7ea2\u8272\uff0cZr\uff1b\u6a59\u8272\uff0cCr\uff1b\u9ec4\u8272\uff0cNi\uff1b\u84dd\u8272\uff0cAl\uff1b\u7070\u8272\uff0cC\uff1b\u7ea2\u8272\uff0cO ; \u7eff\u8272\uff0cN\uff1b P\uff0c\u6c34\u84b8\u6c14\u538b\uff1b P sat , \u9971\u548c\u6c34\u84b8\u6c14\u538b<\/p>\n<p>6.<strong><b>\u5c06\u4e00\u7ef4\u4e1d\u5e26\u7f51\u901a\u8fc7\u4e9a\u80fa\u548c\u4e9a\u80fa\u952e\u94fe\u63a5\u53d8\u6210\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6<\/b><\/strong><\/p>\n<p>\u4ece\u5927\u5206\u5b50\u751a\u81f3\u65e0\u9650\u7684\u6784\u5efa\u5355\u5143\u8bbe\u8ba1\u548c\u5408\u6210 2D \u548c 3D \u7ed3\u6676\u5171\u4ef7\u6709\u673a\u6846\u67b6 (COF) \u5f88\u5927\u7a0b\u5ea6\u4e0a\u5c1a\u672a\u5f00\u53d1\u3002<\/p>\n<p>2020\u5e741\u6708Omar M.Yaghi\u6559\u6388\u53ca\u5176\u5408\u4f5c\u56e2\u961f\u62a5\u544a\u4e86\u4e00\u79cd\u5c06\u5206\u5b50\u548c\u4e00\u7ef4\u5e26\u8fde\u63a5\u5230\u4e8c\u7ef4\u7ed3\u6676\u6846\u67b6\u7684\u7b56\u7565\u3002\u4e09\u89d2\u5f62\u7684\u4e09\uff084-\u6c28\u57fa\u82ef\u57fa\uff09\u80fa\uff08TAA\uff09\u548c\u65b9\u5f62\u76841,3,6,8-\u56db\uff08\u5bf9\u7532\u9170\u57fa\u82ef\u57fa\uff09\u8298\uff08TFPPy\uff09\u6709\u673a\u7ed3\u6784\u5355\u5143\u901a\u8fc7\u4e9a\u80fa\u952e\u4ee5\u4e9a\u5316\u5b66\u8ba1\u91cf\u8fde\u63a5\u4ea7\u751f\u4e00\u7ef4\u5e26\uff0c\u79f0\u4e3aCOF-76\uff0c\u5e26\u6709\u6e38\u79bb\u80fa\uff0c\u7136\u540e\u7528\u4e8e\u5c06\u5e26\u8fde\u63a5\u5230\u4e8c\u7ef4\u6846\u67b6 COF-77 \u548c COF-78\u3002\u9664\u4e86\u8fd9\u79cd\u5faa\u5e8f\u6e10\u8fdb\u7684\u65b9\u6cd5\uff0c\u4ed6\u4eec\u8fd8\u5c55\u793a\u4e86\u4e00\u79cd\u8fd9\u4e9b COF\u7684\u539f\u4f4d\u5408\u6210\u3002\u6b64\u7814\u7a76\u5c06\u65e0\u9650\u7684\u6784\u5efa\u5757\uff08\u4f8b\u5982 COF-76 \u7684\u5e26\u72b6\u4f53\uff09\u8fde\u63a5\u5230\u66f4\u9ad8\u7ef4\u7684 COF\uff0c\u4e3a\u7531\u5206\u7ea7\u5316\u5b66\u7ed3\u6784\u7ec4\u6210\u7684\u5171\u4ef7\u6846\u67b6\u94fa\u5e73\u4e86\u9053\u8def\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-228417\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72475-4.png\" alt=\"\" width=\"600\" height=\"737\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72475-4.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72475-4-244x300.png 244w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe 5. 1D COF-76\u30012D COF-77 \u548c -78 \u901a\u8fc7\u9010\u6b65\uff08A \u548c B\uff09\u548c\u539f\u4f4d\u65b9\u6cd5 (C) \u5408\u6210\u3002 1,3,6,8-\u56db\uff08\u5bf9\u7532\u9170\u57fa\u82ef\u57fa\uff09\u8298\uff08TFPPy\uff09\u548c\u4e09\uff084-\u6c28\u57fa\u82ef\u57fa\uff09\u80fa\uff08TAA\uff09\u4ee51:2\u7684\u5316\u5b66\u8ba1\u91cf\u6bd4\u53cd\u5e94\u5f62\u6210COF-76\uff08A\uff09\u3002 COF-76 \u901a\u8fc7\u4e9a\u80fa-\uff08\u4e0e\u82ef-1,4-\u4e8c\u919b\uff0cBDA\uff09\u548c\u9170\u4e9a\u80fa-\u7f29\u5408\uff08\u4e0e\u5747\u82ef\u56db\u9178\u4e8c\u9150\uff0cPMDA\uff09\u8fde\u63a5\uff0c\u5206\u522b\u5f62\u6210 COF-77 \u548c COF-78\uff08B\uff09\u3002 COF-77 \u548c COF-78 \u7531 TFPPy \u548c TAA \u4e0e BDA \u6216 PMDA \u4e00\u6b65\u5f62\u6210 (C)\u3002 \u539f\u5b50\u7403\u989c\u8272\uff1aC\uff0c\u7070\u8272\uff1b N\uff0c\u84dd\u8272\uff1b O\uff0c\u7ea2\u8272\u3002\u4e3a\u6e05\u695a\u8d77\u89c1\u7701\u7565,\u6c22\u539f\u5b50\uff0c\u919b\u6c22\u548c\u80fa\u6c22\u7701\u7565\u3002<\/p>\n<p><strong><b>7. \u5171\u4ef7\u6709\u673a\u6846\u67b6\u4e2d\u66f4\u9ad8\u4ef7\u7684\u8bbe\u8ba1<\/b><\/strong><\/p>\n<p>\u76ee\u524d\u4e3a\u6b62\uff0c\u5171\u4ef7\u6709\u673a\u6846\u67b6 (COF) \u4e2d\u6784\u5efa\u5355\u5143\u7684\u4ef7\u6570\uff08\u8fde\u63a5\u6027\uff09\u4e3b\u8981\u4e3a 3 \u548c 4\uff0c\u5206\u522b\u5bf9\u5e94\u4e8e\u4e09\u89d2\u5f62\u548c\u6b63\u65b9\u5f62\u6216\u56db\u9762\u4f53\u3002<\/p>\n<p>Omar M.Yaghi\u6559\u6388\u5e26\u9886\u56e2\u961f\u7814\u7a76\u4e86\u4e00\u79cd\u5236\u9020\u5177\u6709 8 \u4ef7\uff08\u7acb\u65b9\u4f53\uff09\u548c\u201c\u65e0\u7a77\u5927\u201d\uff08\u68d2\uff09\u7684 COF \u7684\u7b56\u7565\u3002\u8fde\u63a5\u4f53 1,4-\u787c\u82ef\u57fa\u81a6\u9178\u88ab\u8bbe\u8ba1\u4e3a\u5177\u6709\u787c\u548c\u78f7\u4f5c\u4e3a\u78b3\u65cf\u5143\u7d20\u7684\u7b49\u7535\u5b50\u7ec4\u5408\u8fdb\u800c\u7f29\u5408\u6210\u591a\u5b54\u805a\u7acb\u65b9\u70f7\u7ed3\u6784\uff08BP-COF-\u00a01\uff09\uff0c\u901a\u8fc7 X \u5c04\u7ebf\u7c89\u672b\u884d\u5c04\u6280\u672f\u8fdb\u884c\u8868\u5f81\uff0c\u8be5\u6280\u672f\u63ed\u793a\u4e86\u4e0e\u82ef\u57fa\u76f8\u8fde\u7684\u7acb\u65b9\u4f53\u3002\u7b49\u7f51\u72b6\u5f62\u5f0f\uff08BP-COF-\u00a02\u81f35\u00a0) \u7c7b\u4f3c\u5730\u5236\u5907\u548c\u8868\u5f81\u3002\u7531\u68d2\u5355\u5143\u7ec4\u6210\u7684\u7ed3\u6784\u5f02\u6784 COF\uff08BP-COF-\u00a06\uff09\u7684\u5927\u5355\u6676\u4e5f\u4f7f\u7528\u76f8\u540c\u7684\u7b56\u7565\u5408\u6210\uff0c\u4ece\u800c\u63a8\u52a8 COF \u5316\u5b66\u8fdb\u5165\u65b0\u7684\u4ef7\u6001\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-228418\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72476-4.png\" alt=\"\" width=\"600\" height=\"642\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72476-4.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72476-4-280x300.png 280w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe6. \u4ece\u5355\u4e00\u6709\u673a\u8fde\u63a5\u5b50\u8bbe\u8ba1\u66f4\u9ad8\u4ef7\u7684 COF\u3002 (A) BPA \u63a5\u5934\uff08BPA-1 \u81f3 5\uff09\u5728\u5355\u4e2a\u5206\u5b50\u4e2d\u7ed3\u5408\u4e86\u787c\u9178\u548c\u81a6\u9178\u529f\u80fd\u3002 (B \u548c C) BPA-1 (B) \u7684\u81ea\u7f29\u5408\u5f97\u5230 8 \u4ef7\u7684 BP \u7acb\u65b9\u4f53 (C) \u53ca\u5176\u7f51\u72b6\u805a\u7acb\u65b9 BP-COF-1\u3002 \u7b49\u7f51\u72b6\u5f62\u5f0f\uff08BP-COF-2 \u5230 5\uff09\u8bc1\u660e\u4e86\u8fd9\u79cd\u5316\u5b66\u7684\u591a\u529f\u80fd\u6027\u3002 (D) \u52a0\u5165\u9178\u540e\uff0cBP-COF-1 \u91cd\u6392\u6210\u5c42\u72b6\u65e0\u9650\u4ef7\u6001\u7684\u68d2BP-COF-6\u3002<\/p>\n<p><strong><b>8. \u6570\u5b57\u7f51\u72b6\u5316\u5b66<\/b><\/strong><\/p>\n<p>2020\u5e749\u6708Omar M.Yaghi\u6559\u6388\u7b49\u4eba\u4e8eChem\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u76ee\u4e3a\u201cDigital Reticular Chemistry\u201d\u7684\u6587\u7ae0\u3002\u8be5\u6587\u7ae0\u9610\u8ff0\u4e86\u901a\u8fc7\u5b9e\u9a8c\u5ba4\u673a\u5668\u4eba\u548c\u4eba\u5de5\u667a\u80fd\u6570\u5b57\u5de5\u5177\u7684\u5f00\u53d1\uff0c\u53ef\u4ee5\u5145\u5206\u53d1\u6325\u901a\u8fc7\u5f3a\u952e\u8fde\u63a5\u5206\u5b50\u6784\u5efa\u5355\u5143\u4ee5\u5f62\u6210\u6269\u5c55\u5316\u5b66\u7ed3\u6784\uff08\u7f51\u72b6\u5316\u5b66\uff09\u7684\u5168\u90e8\u6f5c\u529b\u3002\u8fd9\u79cd\u6570\u5b57\u5316\u5bfc\u81f4\u66f4\u5feb\u7684\u53d1\u73b0\uff0c\u5bf9\u793e\u4f1a\u4ea7\u751f\u5f71\u54cd\uff0c\u5e76\u9610\u660e\u4ee5\u524d\u65e0\u6cd5\u60f3\u8c61\u7684\u95ee\u9898\u3002\u5c06\u5178\u578b\u7684\u7ecf\u9a8c\u5b9e\u8df5\u8f6c\u5316\u4e3a\u6570\u636e\u9a71\u52a8\u7684\u5b9e\u8df5\u6709\u671b\u6539\u53d8\u7f51\u72b6\u5316\u5b66\u7684\u73b0\u72b6\uff1a\u7814\u7a76\u4eba\u5458\u5236\u9020\u5316\u5b66\u7ed3\u6784\u5e76\u7814\u7a76\u5176\u53ef\u80fd\u7684\u6027\u8d28\uff0c\u800c\u4e0d\u662f\u9488\u5bf9\u7279\u5b9a\u6027\u8d28\u7684\u7ed3\u6784\u3002\u6570\u5b57\u7f51\u72b6\u5316\u5b66\u7684\u56db\u5927\u652f\u67f1\u2014\u2014\u7efc\u5408\u6570\u636e\u5e93\u3001\u8ba1\u7b97\u548c\u5b9e\u9a8c\u53d1\u73b0\u5468\u671f\u4ee5\u53ca\u4eba\u673a\u754c\u9762\u2014\u2014\u975e\u5e38\u9002\u5408\u9ad8\u6548\u751f\u6210\u3001\u8bbe\u8ba1\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-228419\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72477-3.png\" alt=\"\" width=\"600\" height=\"456\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72477-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72477-3-300x228.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe 7. \u5e7f\u9614\u7684\u7f51\u72b6\u7ed3\u6784\u7a7a\u95f4\u3002 \u7f51\u72b6\u7ed3\u6784\u7684\u591a\u6837\u6027\u4f53\u73b0\u5728\u6bcf\u4e2a\u8bbe\u8ba1\u5c42\u6b21\u7684\u591a\u6837\u6027\u53ca\u5176\u5728\u6240\u6709\u5c42\u6b21\u4e0a\u7684\u7ec4\u5408\u8fdb\u5c55\u3002\u5177\u6709\u7279\u5b9a\u51e0\u4f55\u5f62\u72b6\u7684\u521a\u6027\u5206\u5b50\u9996\u5148\u88ab\u786e\u5b9a\u4e3a\u6784\u5efa\u76ee\u6807\u62d3\u6251\u6846\u67b6\u7684\u6784\u5efa\u5355\u5143\u3002\u5bf9\u4e8e\u5206\u5b50\u6784\u5efa\u5355\u5143\u7684\u9009\u5b9a\u51e0\u4f55\u5f62\u72b6\uff08\u68d2\uff09\uff0c\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u6709\u673a\u7ed3\u6784\u7684\u957f\u5ea6\u800c\u4e0d\u6539\u53d8\u5176\u8fde\u63a5\u6027\u548c\u5f62\u72b6\u6765\u8c03\u6574\u5176\u5927\u5c0f\u3002\u7136\u540e\u6307\u5b9a\u8fde\u63a5\u7684\u6784\u5efa\u5355\u5143\u4e4b\u95f4\u7684\u8fde\u63a5\u57fa\u56e2\u4ee5\u5b8c\u6210\u6846\u67b6\u4e3b\u94fe\u7684\u6784\u5efa\uff0c\u5176\u4e0a\u53ef\u4ee5\u9644\u52a0\u6240\u9700\u5316\u5b66\u7279\u6027\u7684\u529f\u80fd\u3002\u5f53\u4e0d\u540c\u79cd\u7c7b\u7684\u591a\u79cd\u529f\u80fd\u7ed3\u5408\u5230\u4e00\u4e2a\u6846\u67b6\u4e2d\u65f6\uff0c\u5b83\u4eec\u7684\u7a7a\u95f4\u6392\u5217\u6784\u6210\u4e86\u4ece 1D \u5230 3D \u7a7a\u95f4\u6269\u5c55\u7684\u4e30\u5bcc\u5316\u5b66\u5e8f\u5217\u3002\u7ed9\u5b9a\u4e00\u4e2a\u529f\u80fd\u5e8f\u5217\uff0c\u53ef\u4ee5\u521b\u5efa\u4e0e\u5ba2\u4f53\u5206\u5b50\u4e0d\u540c\u76f8\u4e92\u4f5c\u7528\u7684\u590d\u6742\u591a\u6837\u7684\u5b54\u9699\u73af\u5883\u3002<\/p>\n<p><strong><b>9. \u916f\u952e\u8fde\u63a5\u7684\u7ed3\u6676\u5171\u4ef7\u6709\u673a\u6846\u67b6<\/b><\/strong><\/p>\n<p>2020\u5e748\u6708Omar M.Yaghi\u6559\u6388\u53ca\u5176\u56e2\u961f\u4e8e<strong><b>J. Am. Chem. Soc<\/b><\/strong>\u4e0a\u62a5\u9053\u4e86\u9996\u4e2a\u916f\u8fde\u63a5\u7684\u3001\u7ed3\u6676\u7684\u3001\u591a\u5b54\u7684\u5171\u4ef7\u6709\u673a\u9aa8\u67b6 (COF) \u7684\u5408\u6210\u53ca\u8868\u5f81\u3002\u53cc\u4f4d 2-\u5421\u5576\u57fa\u82b3\u65cf\u7fa7\u9178\u76d0\u548c\u4e09\u4f4d\u6216\u56db\u4f4d\u915a\u4e4b\u95f4\u7684\u916f\u4ea4\u6362\u53cd\u5e94\u5f97\u5230\u76f8\u5e94\u7684\u916f\u8fde\u63a5\u7684 COF\u3002\u5b83\u4eec\u4ee5kgm\u00a0(COF-119) \u548chcb\u00a0(COF-120, 121, 122) \u62d3\u6251\u7ed3\u6784\u7ed3\u6676\u4e3a\u4e8c\u7ef4\u7ed3\u6784\uff0c\u8868\u9762\u79ef\u9ad8\u8fbe 2092 m<sup>2<\/sup>\u00a0\/g\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u7ed3\u6676 COF-122 \u5305\u542b\u8de8\u8d8a 10 \u4e2a\u4e9a\u82ef\u57fa\u5355\u5143\u7684\u8fb9\u7f18\uff0c\u8fd9\u4e00\u65b9\u9762\u4ec5\u5728\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e2d\u5b9e\u73b0\u3002\u8fd9\u9879\u5de5\u4f5c\u6269\u5c55\u4e86\u7f51\u72b6\u5316\u5b66\u7684\u8303\u56f4\uff0c\u9996\u6b21\u5f97\u5230\u4e0e\u666e\u901a\u805a\u916f\u76f8\u5173\u7684\u7ed3\u6676\u916f\u8fde\u63a5 COF\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-228420\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72478-2.png\" alt=\"\" width=\"600\" height=\"608\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72478-2.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/\u56fe\u72478-2-296x300.png 296w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe 8. COF-120 \u548c COF-121 \u7684\u5408\u6210\u65b9\u6848\uff0c\u5305\u62ec\u5b83\u4eec\u5728\u7a7a\u95f4\u586b\u5145\u6837\u5f0f\u4e2d\u7684\u7c89\u672b X \u5c04\u7ebf\u884d\u5c04\u7ed3\u6784\u6a21\u578b\u3002 \u989c\u8272\u4ee3\u7801\uff1aH\uff0c\u767d\u8272\uff1b C\u3001\u7070\u8272\uff1b H\uff0c\u7ea2\u8272\u3002<\/p>\n<p>\u4e3b\u8981\u6210\u679c\u6c47\u603b\uff1a<\/p>\n<p><b><\/b><strong><b>1. Chem.Int.Ed<\/b><\/strong>: <a href=\"https:\/\/www.x-mol.com\/paperRedirect\/1346547728613789696\">Docking of CuI and AgI in Metal\u2010Organic Frameworks for Adsorption and Separation of Xenon\u00a0<\/a><\/p>\n<p>DOI\uff1a<a href=\"https:\/\/www.x-mol.com\/paperRedirect\/1346547728613789696\"><u>10.1002\/anie.202016907<\/u><\/a><\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.202016907<\/p>\n<p><b><\/b><strong><b>2. Nano Lett: <\/b><\/strong><a href=\"https:\/\/www.x-mol.com\/paperRedirect\/1326763386173825024\">The Reticular Chemist\u00a0<\/a><\/p>\n<p>DOI\uff1a<a href=\"https:\/\/doi.org\/10.1021\/acs.nanolett.0c04327\"><u>10.1021\/acs.nanolett.0c04327<\/u><\/a><\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.nanolett.0c04327<\/p>\n<p><strong style=\"line-height: 1.5;\"><b>3. ACS Cent. Sci:<\/b><\/strong><span style=\"line-height: 1.5;\">Metal-Organic Frameworks for Water Harvesting from Air, Anywhere, Anytime.<\/span><strong style=\"line-height: 1.5;\"><b>\u00a0<\/b><\/strong><\/p>\n<p>DOI:\u00a0<a href=\"https:\/\/www.x-mol.com\/paperRedirect\/1283168394018471936\"><u>10.1021\/acscentsci.0c00678<\/u><\/a>\u00a0<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acscentsci.0c00678<\/p>\n<p><b><\/b><strong><b>4. Science: <\/b><\/strong><a href=\"https:\/\/www.x-mol.com\/paperRedirect\/1291498134301188096\">Sequencing of metals in multivariate metal-organic frameworks<\/a><\/p>\n<p><a href=\"https:\/\/doi.org\/10.1126\/science.aaz4304\"><u>DOI\uff1a10.1126\/science.aaz4304<\/u><\/a><\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/www.science.org\/lookup\/doi\/10.1126\/science.aaz4304<\/p>\n<p><strong><b>5. Nature Nanotechnol<\/b><\/strong><strong style=\"line-height: 1.5;\"><b>\uff1a <\/b><\/strong><a style=\"line-height: 1.5;\" href=\"https:\/\/www.x-mol.com\/paperRedirect\/1257365591661895680\">MOF water harvesters.\u00a0<\/a><\/p>\n<p>DOI: <a href=\"https:\/\/www.x-mol.com\/paperRedirect\/1257365591661895680\"><u>10.1038\/s41565-020-0673-x<\/u><\/a>\u00a0<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<\/p>\n<p><a href=\"https:\/\/www.nature.com\/articles\/s41565-020-0673-x?utm_source=xmol&amp;utm_medium=affiliate&amp;utm_content=meta&amp;utm_campaign=DDCN_1_GL01_metadata\"><u>https:\/\/www.nature.com\/articles\/s41565-020-0673-x?utm_source=xmol&amp;utm_medium=affiliate&amp;utm_content=meta&amp;utm_campaign=DDCN_1_GL01_metadata<\/u><\/a><\/p>\n<p><strong style=\"line-height: 1.5;\"><b>6. J. Am. Chem. Soc: \u00a0<\/b><\/strong><span style=\"line-height: 1.5;\">Reticulating 1D Ribbons into 2D Covalent Organic Frameworks by Imine and Imide Linkages<\/span><\/p>\n<p>DOI:\u00a0<a href=\"https:\/\/www.x-mol.com\/paperRedirect\/1223357725135622144\"><u>10.1021\/jacs.9b13971<\/u><\/a>\u00a0<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/jacs.9b13971<\/p>\n<p><b><\/b><strong><b>7. Science: <\/b><\/strong><a href=\"https:\/\/www.x-mol.com\/paperRedirect\/1321263836052033536\">Design of higher valency in covalent organic frameworks<\/a><\/p>\n<p><a href=\"https:\/\/doi.org\/10.1126\/science.abd6406\"><u>DOI\uff1a<\/u><u>10.1126\/science.abd6406<\/u><\/a><\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/www.science.org\/doi\/10.1126\/science.abd6406<\/p>\n<p><strong style=\"line-height: 1.5;\"><b>8. Chem<\/b><\/strong><span style=\"line-height: 1.5;\">: \u00a0Digital Reticular Chemistry<\/span><\/p>\n<p>DOI:\u00a0<a href=\"https:\/\/www.x-mol.com\/paperRedirect\/1301587937149030400\"><u>10.1016\/j.chempr.2020.08.008<\/u><\/a><\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/www.sciencedirect.com\/science\/article\/pii\/S2451929420304186<\/p>\n<p><strong style=\"line-height: 1.5;\"><b>9. Am. Chem. Soc: <\/b><\/strong><a style=\"line-height: 1.5;\" href=\"https:\/\/www.x-mol.com\/paperRedirect\/1290718094877663232\">Ester-Linked Crystalline Covalent Organic Frameworks\u00a0<\/a><\/p>\n<p>DOI:\u00a0<a href=\"https:\/\/doi.org\/10.1021\/jacs.0c07015\"><u>10.1021\/jacs.0c07015<\/u><\/a><\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/jacs.0c07015<\/p>\n<p>\u672c\u6587\u7531try or fly\u4f9b\u7a3f\u3002<\/p>\n<p>\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n<p>\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e2a\u4eba\u7b80\u4ecb Omar M.Yaghi\u6559\u6388\u662f\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u3001\u6cb8\u77f3\u54aa\u5511\u9178\u916f\u9aa8\u67b6\u3001\u914d\u4f4d\u805a\u5408\u7269\u7b49\u9886\u57df\u7684\u5f00\u62d3\u8005\u548c\u5960\u57fa\u4eba\u3002\u4ed6\u5728\u529f\u80fd\u591a\u5b54\u6750\u6599\u7684\u5408\u6210\uff0c\u53ca\u5176\u50a8\u80fd\u3001\u73af\u4fdd\u7b49\u9886\u57df\u7684\u5e94\u7528\u8fdb\u884c&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":228421,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-228411","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/228411"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=228411"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/228411\/revisions"}],"predecessor-version":[{"id":228423,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/228411\/revisions\/228423"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/228421"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=228411"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=228411"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=228411"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}