{"id":228552,"date":"2021-10-20T06:30:25","date_gmt":"2021-10-19T22:30:25","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=228552"},"modified":"2021-10-19T17:22:56","modified_gmt":"2021-10-19T09:22:56","slug":"%ef%bc%88%e5%b7%b2%e6%a0%a1%e7%a8%bf%e4%bb%b6%ef%bc%89%e7%b4%a2%e9%8e%8f%e6%95%8f%e8%ae%b8%e5%ba%b7-nature-chemistry%ef%bc%9a%e5%af%8cco2-%e5%ae%bd%e7%94%b5%e4%bd%8d%e6%b0%b4%e7%b3%bb%e7%94%b5","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=228552","title":{"rendered":"\u7d22\u938f\u654f&\u8bb8\u5eb7 Nature Chemistry\uff1a\u5bccCO2-\u5bbd\u7535\u4f4d\u6c34\u7cfb\u7535\u89e3\u6db2"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u5728\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u4e4b\u524d\u7684\u65f6\u4ee3\uff0c\u6c34\uff08H2<\/sub>O\uff09\u662f\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u3001CO2<\/sub>\u7535\u5316\u5b66\u8fd8\u539f\u88c5\u7f6e\u7b49\u5927\u591a\u6570\u7535\u5316\u5b66\u8bbe\u5907\u4e2d\u7684\u5e38\u89c1\u6eb6\u5242\uff0c\u4ee5\u6c34\u4e3a\u6eb6\u5242\u7684\u88c5\u7f6e\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u52a8\u529b\u5b66\u6027\u80fd\uff0c\u53ef\u4ee5\u5b9e\u73b0\u5feb\u901f\u5145\u653e\u7535\uff0c\u540c\u65f6\u4e5f\u53ef\u4ee5\u5f88\u597d\u7684\u63a7\u5236\u6210\u672c\u3002\u4f46\u540c\u65f6\uff0c\uff0c\u56e0\u4e3a\u65e0\u6cd5\u50cf\u975e\u6c34\u7cfb\u7535\u89e3\u8d28\u4e2d\u90a3\u6837\u5f62\u6210\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u819c\uff08SEI\uff09\u6765\u63d0\u4f9b\u52a8\u529b\u5b66\u4fdd\u62a4\uff0c\u6c34\u7cfb\u7535\u89e3\u8d28\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u7a97\u53e3\u90fd\u8f83\u7a84\u4e14\u5b58\u5728\u4e25\u91cd\u7684\u6790\u6c22\u526f\u53cd\u5e94\uff0c\u6240\u4ee5\u4ee5\u6c34\u4e3a\u6eb6\u5242\u7684\u88c5\u7f6e\u901a\u5e38\u90fd\u53ea\u80fd\u5728\u4f4e\u7535\u538b\u4e0b\u8fd0\u884c\u3002\u8fd1\u671f\uff0c\u76d0\u5305\u6c34\uff08WIS\uff09\u7535\u89e3\u8d28\u7684\u63d0\u51fa\u6253\u7834\u4e86\u4f20\u7edf\u7535\u5316\u5b66\u7a33\u5b9a\u7a97\u53e3\u7684\u9650\u5236\uff0c\u901a\u8fc7\u5728H2<\/sub>O\u4e2d\u5f15\u5165\u8d85\u9ad8\u6d53\u5ea6\u9502\u76d0\uff0821 m\uff09\u8fdb\u800c\u5b9e\u73b0\u4e86\u7ea63.0 V\u7684\u7a97\u53e3\u3002\u6b64\u5916\uff0c\u8d85\u9ad8\u6d53\u5ea6LiNO3<\/sub>\u7535\u89e3\u8d28\u5728\u6c34\u7cfb\u7535\u6c60\u4e2d\u65e9\u5df2\u88ab\u5e7f\u6cdb\u4f7f\u7528\uff0c\u4f46\u662f\u5728\u8fd9\u4e9b\u7535\u89e3\u8d28\u4ece\u672a\u5f62\u6210\u8fc7SEI\u754c\u9762\u819c\u3002\u663e\u7136\uff0c\u9664\u4e86\u8d85\u9ad8\u6d53\u5ea6\u5916\uff0c\u9634\u79bb\u5b50\u5316\u5b66\u662f\u8bf1\u5bfc\u5f62\u6210SEI\u754c\u9762\u819c\u7684\u5173\u952e\u56e0\u7d20\u3002\u4e4b\u524d\u7684\u7814\u7a76\u63ed\u793a\u4e86WIS\u7535\u89e3\u8d28\u4e2d\u6240\u5f62\u6210\u7684SEI\u754c\u9762\u819c\u7684\u6210\u5206\uff0c\u662f\u7531LiF\u3001Li2<\/sub>O\u548cLi2<\/sub>CO3<\/sub>\u6784\u6210\u7684\u6df7\u5408\u7269\uff0c\u5206\u522b\u6765\u6e90\u4e8eTFSI\u7684\u8fd8\u539f\u4ee5\u53ca\u6eb6\u89e3\u6c14\u4f53\uff08O2<\/sub>\u548cCO2<\/sub>\uff09\u7684\u8fd8\u539f\u3002\u867d\u7136LiF\u5fc5\u987b\u7531\u6c1f\u9634\u79bb\u5b50\u63d0\u4f9b\uff0c\u4f46\u662f\u5374\u65e0\u6cd5\u5408\u7406\u89e3\u91ca\u4e3a\u4ec0\u4e48\u5728\u5176\u4ed6\u57fa\u4e8e\u65e0\u673a\u9634\u79bb\u5b50\uff08LiNO3<\/sub>\u548cLi2<\/sub>SO4<\/sub>\uff09\u7684\u8d85\u9ad8\u6d53\u5ea6\u7535\u89e3\u8d28\u4e2d\u4e0d\u80fd\u5f62\u6210SEI\u754c\u9762\u819c\uff0c\u5373\u4f7f\u5176\u4e2d\u5df2\u7ecf\u5b58\u5728O2<\/sub>\u548cCO2<\/sub>\u4f5c\u4e3aLi2<\/sub>O\u548cLi2<\/sub>CO3<\/sub>\u7684\u6765\u6e90\u3002
\n \"\"
\n \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u7269\u7406\u7814\u7a76\u6240\u7d22\u938f\u654f\u7814\u7a76\u5458\u548c\u7f8e\u56fd\u9646\u519b\u7814\u7a76\u5b9e\u9a8c\u5ba4\u8bb8\u5eb7\u7814\u7a76\u5458\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u6eb6\u89e3\u6c14\u4f53\u5982\u4f55\u5f71\u54cdWIS\u6210\u5206\uff08\u5373\u6c34\u548cTFSI\uff09\u8fdb\u800c\u5b9e\u73b0\u76d0\u6d53\u5ea6\u7684\u964d\u4f4e\u3002\u4f5c\u8005\u53d1\u73b0WIS\u5bf9CO2<\/sub>\u6709\u5f88\u9ad8\u7684\u9009\u62e9\u6027\u4eb2\u548c\u529b\uff0cCO2<\/sub>\u548cLiTFSI\u4e4b\u95f4\u5b58\u5728\u72ec\u7279\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\uff0c\u4f7f\u7528\u5e38\u89c4\u7684\u6c14\u4f53\u5439\u626b\u65e0\u6cd5\u5c06\u4e4b\u53bb\u9664\u3002\u800cCO2<\/sub>\u5728WIS\u4e2d\u8f83\u9ad8\u7684\u6eb6\u89e3\u5ea6\u4e5f\u4f7f\u5f97Li2<\/sub>CO3<\/sub>\u754c\u9762\u76f8\u7684\u5f62\u6210\u51e0\u7387\u5927\u5927\u589e\u52a0\u3002\u5229\u7528\u8be5\u53d1\u73b0\uff0c\u4f5c\u8005\u5f15\u5165\u4e86CO2<\/sub>\u4f5c\u4e3a\u6c34\u7cfb\u7535\u89e3\u8d28\u7684\u754c\u9762\u6210\u819c\u6dfb\u52a0\u5242\uff0c\u4ece\u800c\u4f7f\u5f97\u754c\u9762\u7279\u6027\u548c\u4f53\u76f8\u7535\u89e3\u8d28\u7279\u6027\u5206\u79bb\uff0c\u5373\u4e0d\u518d\u4f9d\u8d56\u4e8e\u8d85\u9ad8\u76d0\u6d53\u5ea6\u3002CO2<\/sub>\u8bf1\u5bfc\u754c\u9762\u76f8\u4f7f\u5f975 m LiTFSI\uff08m, mol\/kg\uff09\u4f4e\u6d53\u5ea6\u4e0b\u53ef\u4ee5\u5b9e\u73b0\u4e86\u4e00\u4e2a\u4e0eWIS\u7535\u89e3\u8d28\u76f8\u5f53\u7684\u7535\u5316\u5b66\u7a97\u53e3\uff0c\u4ece\u800c\u964d\u4f4e\u4e86\u5927\u91cf\u4f7f\u7528LiTFSI\u6240\u4ea7\u751f\u7684\u9ad8\u6210\u672c\u3002\u540c\u65f6\uff0c\u4f4e\u6d53\u5ea6\u7535\u89e3\u8d28\u8fd8\u63d0\u4f9b\u4e86WIS\u7535\u89e3\u8d28\u6240\u4e0d\u5177\u5907\u7684\u5176\u4ed6\u4f18\u70b9\uff0c\u5982\u4f18\u5f02\u7684\u7535\u5bfc\u7387\u3001\u4f4e\u7c98\u5ea6\u548c\u8f83\u5bbd\u7684\u4f7f\u7528\u6e29\u5ea6\u8303\u56f4\u3002\u57fa\u4e8e\u8be5\u4f4e\u6d53\u5ea6\u7535\u89e3\u8d28\u7684\u6c34\u7cfbLIBs\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u52a8\u529b\u5b66\u6027\u80fd\uff0c\u5305\u62ec\u500d\u7387\u6027\u80fd\u548c\u8010\u4f4e\u6e29\uff08-40 \u2103\uff09\u4ee5\u53ca\u9ad8\u8d1f\u8f7d\u539a\u7535\u6781\u4e0b\u7684\u6027\u80fd\u3002\u6b64\u7814\u7a76\u4e2d\u6240\u63ed\u793a\u7684\u9502\u76d0-\u6c14\u4f53-\u6c34\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u5bf9\u9ad8\u538b\u6c34\u7cfb\u7535\u89e3\u8d28\u4e0b\u8d85\u9ad8\u76d0\u6d53\u5ea6\u7684\u5b9e\u73b0\u65b9\u6cd5\u8fdb\u884c\u4e86\u91cd\u8981\u6821\u6b63\uff0c\u5e76\u4e14\u6709\u5229\u4e8e\u5f62\u6210\u5b9e\u7528\u6027\u6c34\u7cfbLIBs\u3002\u6b64\u5916\uff0c\u4ece\u57fa\u7840\u7814\u7a76\u7684\u5c42\u9762\u4e0a\uff0c\u4e86\u89e3\u6eb6\u89e3\u6c14\u4f53\u548c\u6c34\u7cfb\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u4ee5\u53ca\u8fd9\u4e9b\u6c14\u4f53\u5728\u7535\u6c60\u73af\u5883\u4e2d\u7684\u8fd8\u539f\u5316\u5b66\uff0c\u4e5f\u53ef\u4ee5\u4e3a\u6c34\u7cfb\u7535\u89e3\u8d28\u7684\u8bbe\u8ba1\u5f00\u53d1\u63d0\u4f9b\u65b0\u601d\u8def\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cAqueous interphase formed by CO2<\/sub> brings electrolytes back to salt-in-water regime\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNature Chemistry<\/strong>\u4e0a\u3002
\n \"\"\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u4e94\u79cdWIS\u7535\u89e3\u8d28\u4e2d\u521d\u59cb\u653e\u7535\u5bb9\u91cf\u7684\u9636\u6bb5\u6027\u5b9a\u91cf\u5206\u6790<\/strong>
\n \"\"\uff08a\uff09\u4e09\u7535\u6781\u88c5\u7f6e\u8fd0\u884c\u73af\u5883\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u4e09\u7535\u6781\u88c5\u7f6e\u4e0b\uff0cMo6<\/sub>S8<\/sub>\u5728\u4e0d\u540c\u6c14\u4f53\u5904\u7406\u540e\u7684WIS\u7535\u89e3\u6db2\u4e2d\u7684\u9996\u5468\u653e\u7535\u66f2\u7ebf\uff0c\u5176\u4e2dMo6<\/sub>S8<\/sub>\u5728\u6709\u673a\u4f53\u7cfb\u6263\u5f0f\u7535\u6c60\u4e2d\u7684\u9996\u5468\u653e\u7535\u66f2\u7ebf\u7528\u4f5c\u5bf9\u6bd4\uff1b<\/p>\n

\uff08c\uff09\u4e0d\u540c\u653e\u7535\u9636\u6bb5\uff08I-V\uff09\u7684\u6c14\u4f53\u8fd8\u539f\u8d21\u732e\u7684\u5bb9\u91cf\u3002<\/p>\n

\u56fe\u4e8c\u3001\u4e09\u7535\u6781\u88c5\u7f6e\u4e0b\uff0c\u4e0d\u540c\u6c14\u4f53\u6c1b\u56f4\u4e0bWIS\u7535\u89e3\u8d28\uff0821 m LiTFSI\uff09\u4e2dMo6<\/sub>S8<\/sub>\u7535\u6781\u8868\u9762\u6240\u5f62\u6210\u7684SEI\u819c\u7684\u6210\u5206\u5206\u6790<\/strong>
\n \"\"\uff08a\uff09\u4e09\u7535\u6781\u88c5\u7f6e\u4e0b\uff0cMo6<\/sub>S8<\/sub>\u5728\u4e0d\u540c\u6c14\u4f53\u5904\u7406\u540e\u7684WIS\u7535\u89e3\u6db2\u4e2d\u7684\u9996\u5468\u653e\u7535\u66f2\u7ebf\u6c47\u603b\uff1b<\/p>\n

\uff08b-e\uff09XPS\u5149\u8c31\u53caAr\u79bb\u5b50\u523b\u8680\u540e\u7684\u7ed3\u679c\u7ed3\u5408TEM\u56fe\u50cf\u6765\u8868\u5f81CO2<\/sub>\u3001Ar\u3001O2<\/sub>\u548c\u7a7a\u6c14\u7b49\u6c14\u4f53\u6c1b\u56f4\u4e0b\u5faa\u73af\u540eMo6<\/sub>S8<\/sub>\u7535\u6781\u7684\u76f8\u95f4\u5316\u5b66\u548c\u7ed3\u6784\u3002<\/p>\n

\u56fe\u4e09\u30015 m LiTFSI\u6eb6\u6db2\u7684\u7406\u5316\u6027\u8d28<\/strong>
\n \"\"\uff08a\uff09\u7c98\u5ea6\u548c\u7535\u5bfc\u7387\u7684\u6bd4\u8f83\u53ca\u968f\u6d53\u5ea6\u7684\u53d8\u5316\uff1b<\/p>\n

\uff08b\uff09\u6839\u636e1 m\u30015 m\u300110 m\u548c15 m\u7535\u89e3\u8d28\u7684\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u7ed3\u679c\u6240\u5f97\u7684LiTFSI-H2<\/sub>O\u4e8c\u5143\u76f8\u56fe\uff1b<\/p>\n

\uff08c\uff09\u4ece21 m\u52301 m\u7684\u6210\u672c\u53d8\u5316\u8d8b\u52bf\u53caM\uff08mol\/L\uff09\u4e0em\uff08mol\/kg\uff09\u7684\u5bf9\u5e94\u5173\u7cfb\uff1b<\/p>\n

\uff08d\uff09\u4e0d\u540c\u6c14\u4f53\u5904\u7406\u540e\uff08CO2<\/sub>\u3001Ar\u3001O2<\/sub>\u6216\u7a7a\u6c14\uff09\u540e5 m LiTFSI\u6eb6\u6db2\u7684CO2<\/sub>\u542b\u91cf\u548cpH\u503c\u7684\u5bf9\u6bd4\u3002<\/p>\n

\u56fe\u56db\u3001CO2<\/sub>\u5904\u7406\u524d\u540eCO2<\/sub>\u4e0eTFSI\u9634\u79bb\u5b50\u7684\u76f8\u4e92\u4f5c\u7528<\/strong>
\n \"\"\uff08a\uff09CO2<\/sub>\u5904\u7406\u524d\u540e5 m SIW\u7535\u89e3\u8d28\u768413<\/sup>C\u30011<\/sup>H\u548c17<\/sup>O\u6838\u78c1\u5171\u632f\u8c31\uff1b<\/p>\n

\uff08b\uff09\u4e0d\u540c\u6d53\u5ea6\u7535\u89e3\u8d28\uff081 m\u30015 m\u300110 m\u300115 m\u548c21 m\uff09\u7528CO2<\/sub>\u6c14\u4f53\u5904\u7406\u540e\u7684FTIR\u5149\u8c31\uff1b<\/p>\n

\uff08c-d\uff09\u4e0d\u540c\u6d53\u5ea6LiTFSI \u7535\u89e3\u6db2\u7528CO2<\/sub>\u6c14\u4f53\u5904\u7406\u524d\u540e19<\/sup>F NMR\u5149\u8c31\u5bf9\u6bd4\u53ca\u5176\u76f8\u5e94\u7684\u5316\u5b66\u4f4d\u79fb\uff1b<\/p>\n

\uff08e\uff09TFSI\u9634\u79bb\u5b50\u4e2dF\u5468\u56f4\u7535\u5b50\u4e91\u5bc6\u5ea6\u53d8\u5316\u7684\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u5206\u6790\u3002<\/p>\n

\u56fe\u4e94\u3001\u6c34\u7cfb\u5168\u7535\u6c60\uff08LiMn2<\/sub>O4<\/sub>\/CO2<\/sub>-SIW\/Mo6<\/sub>S8<\/sub>\uff09\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong>
\n \"\"\uff08a\uff09\u5168\u7535\u6c60\u5728CO2-SIW\u7535\u89e3\u6db2\u4ee5\u53ca\u5bf9\u6bd4\u7535\u89e3\u6db2\u4e2d\u7684\u9996\u5468\u5145\u653e\u7535\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n

\uff08b-c\uff090.5 C\u4e0b\u7684\u5faa\u73af\u5bff\u547d\u548c\u76f8\u5e94\u7684\u5e93\u4f26\u6548\u7387\uff1b<\/p>\n

\uff08d\uff092 C\u4e0b\u7684\u957f\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\uff08e\uff09CO2<\/sub>-SIW\u7535\u89e3\u6db2\u4e0b\u5168\u7535\u6c60\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\u53ca\u5bf9\u5e94\u7684\u62df\u5408\u7ed3\u679c\uff1b<\/p>\n

\uff08f\uff09\u5faa\u73af\u524d\u540e\uff0cMo6<\/sub>S8<\/sub>\u7535\u6781\u7684XPS\u56fe\u8c31\uff08C 1s\u548cO 1s\uff09\u3002<\/p>\n

\u56fe\u516d\u3001LiMn2<\/sub>O4<\/sub>\/Mo6<\/sub>S8<\/sub>\u6c34\u7cfb\u5168\u7535\u6c60\u5728CO2<\/sub>-SIW\u548cWIS\u7535\u89e3\u8d28\u4e2d\u7684\u52a8\u529b\u5b66\u6027\u80fd<\/strong>
\n \"\"\uff08a-b\uff09\uff0c0.5 C\u4e0b\uff0c\u539a\u7535\u6781\uff0840 mg cm-2<\/sup>\uff0c334 \u03bcm\uff09\u4e0b\u7684\u9996\u5468\u5145\u653e\u7535\u66f2\u7ebf\u53ca\u76f8\u5e94\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\uff08c-d\uff090.5 C\u4e0b\uff0c\u4f4e\u6e29\uff08-40 \u00b0C\uff09\u4e0b\u7684\u9996\u5468\u5145\u653e\u7535\u66f2\u7ebf\u53ca\u76f8\u5e94\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u4f7f\u7528\u7279\u5236\u7684\u4e09\u7535\u6781\u88c5\u7f6e\uff0c\u5b9e\u73b0\u4e86\u8fde\u7eed\u6c14\u6d41\u7684\u4f9b\u5e94\uff0c\u7814\u7a76\u4e86\u6eb6\u89e3\u5728WIS\u7535\u89e3\u6db2\u4e2d\u7684\u5404\u79cd\u6c14\u4f53\u7684\u8fd8\u539f\u673a\u7406\u3002\u7ed3\u5408\u5168\u9762\u7684\u754c\u9762\u8868\u5f81\uff0c\u4f5c\u8005\u53d1\u73b0CO2<\/sub>\u548cTFSI\u4e4b\u95f4\u5b58\u5728\u72ec\u7279\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u5f71\u54cd\u7535\u5316\u5b66\u884c\u4e3a\u5e76\u5bfc\u81f4\u4e86\u5bcc\u542bLi2<\/sub>CO3<\/sub>\u7684\u754c\u9762\u76f8\u7684\u5f62\u6210\u3002\u5229\u7528\u8be5\u53d1\u73b0\uff0c\u4f5c\u8005\u8bbe\u8ba1\u4e86\u4e00\u79cdCO2<\/sub>-SIW\u7535\u89e3\u8d28\uff085 m LiTFSI-H2O\u4e2d\u7684CO2<\/sub>\uff09\uff0c\u5176\u4e2dCO2<\/sub>\u4e3a\u754c\u9762\u6210\u819c\u6dfb\u52a0\u5242\u3002\u8fd9\u79cd\u4f4e\u6d53\u5ea6\u7535\u89e3\u8d28\u7ee7\u627f\u4e86WIS\u7535\u89e3\u6db2\u7684\u5bbd\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3\u548c\u5b89\u5168\u6027\uff0c\u540c\u65f6\u6210\u529f\u5730\u514b\u670d\u4e86\u5176\u52a8\u529b\u5b66\u7f13\u6162\u3001\u6db2\u76f8\u70b9\u6e29\u5ea6\u9ad8\u548c\u6210\u672c\u9ad8\u7b49\u7f3a\u70b9\u3002\u4f7f\u7528\u8fd9\u79cd\u7535\u89e3\u8d28\u6784\u5efa\u7684\u6c34\u7cfbLIBs\u4e0d\u4ec5\u663e\u793a\u51fa\u4e0eWIS\u7535\u89e3\u8d28\u76f8\u4f3c\u7684\u7535\u538b\u8010\u53d7\u6027\uff0c\u800c\u4e14\u8fd8\u63d0\u4f9b\u4e86\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u3001\u4f18\u5f02\u7684\u4f4e\u6e29\u6027\u80fd\uff08-40 \u2103\uff09\u4ee5\u53ca\u57fa\u4e8e\u9ad8\u8d28\u91cf\u8d1f\u8f7d\u539a\u5ea6\u7535\u6781\u4e0b\u7684\u9ad8\u5bb9\u91cf\u3002\u6b64\u5916\uff0c\u4f4e\u6d53\u5ea6\u4e0b\u6210\u672c\u4e5f\u53ef\u4ee5\u964d\u4f4e\u4e00\u534a\u3002\u603b\u7ed3\u6765\u770b\uff0cCO2<\/sub>-TFSI\u76f8\u4e92\u4f5c\u7528\u7684\u53d1\u73b0\u4f7f\u5f97\u5f00\u53d1\u5bbd\u7535\u4f4d\u6c34\u7cfb\u7535\u89e3\u6db2\u4e0d\u518d\u5355\u7eaf\u4f9d\u8d56\u8d85\u9ad8\u76d0\u6d53\u5ea6\u6765\u5b9e\u73b0\uff0c\u800c\u4e14\u5728\u66f4\u5e7f\u6cdb\u7684\u8303\u56f4\u5185\u4e86\u89e3\u4e86\u7535\u89e3\u8d28\u6210\u5206\u4e4b\u95f4\u88ab\u5ffd\u89c6\u7684\u590d\u6742\u76f8\u4e92\u4f5c\u7528\uff0c\u5e76\u5229\u7528\u5b83\u4eec\u8fdb\u884c\u754c\u9762\u8c03\u63a7\uff0c\u4e3a\u5bbd\u7535\u4f4d\u6c34\u7cfb\u7535\u89e3\u6db2\u7684\u8bbe\u8ba1\u5f00\u53d1\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aAqueous interphase formed by CO2<\/sub> brings electrolytes back to salt-in-water regime<\/a><\/strong>. Nature Chemistry<\/em>, 2021<\/strong>, DOI: 10.1038\/s41557-021-00787-y.<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong><\/p>\n

\u7d22\u938f\u654f\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\uff0c\u7814\u7a76\u5458<\/strong>\u3002\u957f\u671f\u4e13\u6ce8\u4e8e\u65b0\u578b\u50a8\u80fd\u7535\u6c60\u4f53\u7cfb\u57fa\u7840\u7814\u7a76\u4e0e\u5f00\u53d1\uff0c\u5177\u4f53\u6db5\u76d6\u5982\u4e0b\u7814\u7a76\u65b9\u5411\uff1a\uff081\uff09\u65b0\u578b\u7535\u89e3\u6db2\u4f53\u7cfb\u63a2\u7d22\u5f00\u53d1\u53ca\u57fa\u7840\u79d1\u5b66\u95ee\u9898\u7814\u7a76\uff1b\uff082\uff09\u5b89\u5168\u3001\u7eff\u8272\u3001\u4f4e\u6210\u672c\u6c34\u7cfb\u50a8\u80fd\u7535\u6c60\uff08\u9502\/\u94a0\u79bb\u5b50\u7535\u6c60\uff09\uff1b\uff083\uff09\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u91d1\u5c5e\u9502\u57fa\u52a8\u529b\u7535\u6c60\uff08\u9502\u786b\u7535\u6c60\/\u91d1\u5c5e\u9502\u7535\u6c60\uff09;\uff084\uff09\u65b0\u578b\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u591a\u4ef7\u8f6c\u79fb\u4e8c\u6b21\u7535\u6c60\uff08\u94dd\/\u9541\u7535\u6c60\uff09\u3002\u8fd1\u5e74\u6765\u53d1\u8868SCI\u8bba\u6587\u5171\u8ba163\u7bc7 \uff08IF >10, 52 \u7bc7), \u5f15\u7528\u6b21\u6570\uff1a> 1000\u6b21\uff082 \u7bc7\uff09\u3001> 100\u6b21\uff0821 \u7bc7\uff09\u3002\u901a\u8baf\/\u4e00\u4f5c\u8eab\u4efd\u53d1\u8868\u6587\u7ae033 \u7bc7\uff0c\u5305\u62ecScience\u3001Nature Energy\u3001Nature Chemistry\u3001Nature Communications\u3001Science Advances\u3001PNAS\u3001Adv.Mater (4 \u7bc7), Angew (3\u7bc7)\u3001JACS\/JACS Au (2 \u7bc7)\u3001Matter\u3001Adv.Energy.Mater (3 \u7bc7)\u3001ACS Nano\/Nano Letter (3 \u7bc7) \u7b49\u3002\u6587\u7ae0\u53d1\u8868\u4ee5\u6765 SCI \u5f15\u7528\u6b21\u6570\u5927\u4e8e8200\u6b21\uff0c\u5176\u4e2d60%\u4ee5\u4e0a\u6e90\u4e8e\u901a\u8baf\/\u7b2c\u4e00\u4f5c\u8005\u8bba\u6587\u8d21\u732e\uff0cH\u56e0\u5b50 38\u3002<\/p>\n

\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u548c\u6c34\u7cfb\u7535\u6c60\u65b9\u9762\u7814\u7a76\u6210\u679c\uff1a<\/strong><\/p>\n

1. \u63d0\u51fa\u65b0\u578b\u5bbd\u7535\u4f4d\u9ad8\u76d0\u6d53\u5ea6Water-in-Salt\u6c34\u7cfb\u7535\u89e3\u6db2 (Science, 350, 938, (2015))
\n \u5c06\u6c34\u7cfb\u7535\u89e3\u6db2\u7535\u5316\u5b66\u7a97\u53e3\u7531\u4f4e\u4e8e2.0 V\u63d0\u9ad8\u81f33.0 V, \u4e3a\u5b9e\u73b0\u957f\u5bff\u547d\u9ad8\u538b\u6c34\u7cfb\u9502\/\u94a0\u79bb\u5b50\u7535\u6c60\u63d0\u4f9b\u4e86\u5fc5\u8981\u524d\u63d0\u3002\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u5b9e\u73b0SEI\u819c, \u63a8\u7ffb\u524d\u4eba\u5bf9\u6c34\u7cfb\u9502\u7535\u6c60\u65e0\u6cd5\u5f62\u6210SEI\u819c\u7684\u8ba4\u8bc6\uff0c\u4ece\u6839\u672c\u4e0a\u89e3\u51b3\u4e86\u6c34\u7cfb\u4e8c\u6b21\u7535\u6c60\u201c\u6790\u6c22\u95ee\u9898\u201d\u800c\u5bfc\u81f4\u5faa\u73af\u5bff\u547d\u4f4e\u7684\u5173\u952e\u6280\u672f\u96be\u9898\u3002\u5c06\u6c34\u7cfb\u5168\u7535\u6c60\u8f93\u51fa\u7535\u538b\u7531 < 1.5 V\u63d0\u9ad8\u81f3 > 2 V\u3002<\/p>\n

\u00a0\u8d85\u9ad8\u76d0\u6d53\u5ea6Water-in-salt\u6c34\u7cfb\u7535\u89e3\u6db2SEI\u819c\u5f62\u6210\u673a\u5236\u7814\u7a76\uff08Journal of the American Chemical Society, 139, 18670, (2017)\uff09<\/p>\n

\u00a0\u8d85\u9ad8\u76d0\u6d53\u5ea6Water-in-salt\u6c34\u7cfb\u7535\u89e3\u6db2\u79bb\u5b50\u8f93\u8fd0\u673a\u5236\u7814\u7a76\uff08ACS Nano, 11, 10462, (2017)\/J. Phys. Chem. C, 125, 22, (2021)\uff09<\/p>\n

\u00a0\u8d85\u9ad8\u76d0\u6d53\u5ea6Water-in-salt \u6291\u5236\u7535\u6781\u6eb6\u89e3\u673a\u5236\u7814\u7a76\uff08Advanced Energy Materials, 10,36, (2020)\uff09<\/p>\n

2. \u63d0\u51fa\u5bccCO2<\/sub>\u5bbd\u7535\u4f4d\u6c34\u7cfb\u7535\u89e3\u6db2\u5b9e\u73b0SEI\u819c\u7cbe\u51c6\u8c03\u63a7\uff0c\u5b8c\u6210\u4ece\u9ad8\u76d0\u6d53\u5ea6Water-in-Salt\u5230\u4f4e\u76d0\u6d53\u5ea6Salt-in-water\u8f6c\u53d8\uff08Nature Chemistry, 2021\uff09<\/p>\n

3. \u57fa\u4e8e\u5bbd\u7535\u4f4d\u6c34\u7cfb\u7535\u89e3\u6db2\u5f00\u53d1\u51fa\u7cfb\u5217\u6c34\u7cfb\u9502\/\u94a0\u7535\u6c60<\/p>\n

\u00a02.3 V \u9ad8\u7535\u538b\u6c34\u7cfb\u9502\u79bb\u5b50\u50a8\u80fd\u7535\u6c60\uff08LiMn2<\/sub>O4<\/sub>\/Mo6<\/sub>S8<\/sub>\uff09\uff08Science, 350, 938, (2015)\uff09<\/p>\n

2.5 V\u9ad8\u7535\u538b\u6c34\u7cfb\u9502\u79bb\u5b50\u50a8\u80fd\u7535\u6c60\uff08LiMn2<\/sub>O4<\/sub>\/TiO2<\/sub>\uff09\uff08Angewandte Chemie-International Edition, 55, 7136, (2016)\uff09<\/p>\n

\u00a02.8 V \u9ad8\u7535\u538b\u6c34\u7cfb\u9502\u79bb\u5b50\u50a8\u80fd\u7535\u6c60\uff08LiMn2<\/sub>O4<\/sub>\/TiO2<\/sub>(B)\uff09\uff08Energy Storage Materials, 42, 438, (2021)\uff09<\/p>\n

\u00a02.5 V \u9ad8\u7535\u538b\u6c34\u7cfb\u94a0\u79bb\u5b50\u50a8\u80fd\u7535\u6c60\uff08Na1.88<\/sub>Mn[Fe(CN)6<\/sub>]0.97\u00b71.35<\/sub>H2<\/sub>O\/NaTiOPO4<\/sub>\uff09\uff08Advanced Materials, 32, 2, (2020)\uff09<\/p>\n

\u957f\u5bff\u547d\u94a0\u79bb\u5b50\u50a8\u80fd\u7535\u6c60\uff08Na0.66<\/sub>[Mn0.66<\/sub>Ti0.34<\/sub>]O2<\/sub>\/NaTi2<\/sub>(PO4<\/sub>)3<\/sub>\uff09\uff08Advanced Energy Materials, 7, (2017)\uff09<\/p>\n

\u00a0\u957f\u5bff\u547d\u9502\u79bb\u5b50\u50a8\u80fd\u7535\u6c60\uff08LiFePO4<\/sub>\/Mo6<\/sub>S8<\/sub>\uff09\uff08Journal of Materials Chemistry A, 4, 6639, (2016)\uff09<\/p>\n

\u6c34\u7cfb\u7535\u6c60\u65b9\u9762\u53d1\u8868\u6587\u7ae0\uff08\u6309\u7167\u5e74\u4ee3\u6392\u5e8f\uff09<\/strong>\uff1a<\/p>\n

1. Jinming Yue, Jinkai Zhang, Yuxin Tong, Ming Chen, Lilu Liu, Liwei, Jiang, Tianshi Lv, Yong-sheng Hu, Hong Li, Xuejie Huang, Lin Gu, Guang Feng, Kang Xu*, Liumin Suo*, Liquan Chen, Aqueous interphase formed by CO2<\/sub> brings electrolytes back to salt-in-water regime. Nature Chemistry, (2021). https:\/\/doi.org\/10.1038\/s41557-021-00787-y.<\/p>\n

2. Anxing Zhou, Yuan Liu, Xiangzhen Zhu, Xinyan Li, Jinming Yue, Xianguo Ma, Lin Gu*, Yong-Sheng Hu*, Hong Li*, Xuejie Huang*, Liquan Chen*, Liumin Suo*, TiO2<\/sub> (B) Anode for High-voltage Aqueous Li-Ion Batteries, Energy Storage Materials, 42, 438-444, (2021)<\/p>\n

3. Jinming Yue, Liumin Suo*, Progress in Rechargeable Aqueous Alkali-Ion Batteries in China, Energy&Fuels, 35, 11, 9228\u20139239 (2021)<\/p>\n

4. Pan Tan#, Jinming Yue#, Liumin Suo*, Liang Hong* et.al., Solid-like Nano-Anion-Cluster Constructs Free Lithium-ion Conducting Super-Fluid Framework in Water-in-salt Electrolyte. J. Phys. Chem. C, 125, 22, 11838\u201311847 (2021)<\/p>\n

5. Binghang Liu, Liumin Suo*, et.al., Sandwich-structure Corrosion-resistant Current Collector for Aqueous Batteries. ACS Applied Energy Materials, 4, 5, 4928\u20134934 (2021)<\/p>\n

6. Jinming Yue, Liangdong Lin, Liwei Jiang, Qiangqiang Zhang, Yuxin Tong, Liumin Suo*, Yong\u2010sheng Hu, Hong Li, Xuejie Huang, Liquan Chen, Interface Concentrated-Confinement Suppressing Cathode Dissolution in Water-in-Salt Electrolyte. Advanced Energy Materials, 10,36, 2000665 (2020)<\/p>\n

7. Liwei Jiang, Lilu Liu, Jinming Yue, Qiangqiang Zhang, Anxing Zhou, Oleg Borodin*, Liumin Suo*, Hong Li, Liquan Chen, Kang Xu and Yong-Sheng Hu*, High-Voltage Aqueous Na-Ion Battery Enabled by Inert-Cation-Assisted Water-in-Salt Electrolyte. Advanced Materials, 32,2, 1904427 (2020)<\/p>\n

8. Anxing Zhou, Liwei Jiang, Jinming Yue, Yuxin Tong, Qiangqiang Zhang, Zejing Lin, Binghang Liu, Chuan Wu, Liumin Suo*, Yong-Sheng Hu, Hong Li and Liquan Chen, \u201cWater-in-Salt\u201d Electrolyte Promotes High-Capacity Fefe(Cn)(6) Cathode for Aqueous Al-Ion Battery. ACS Applied Materials & Interfaces, 11, 41356, (2019)<\/p>\n

9. Liumin Suo, Dahyun Oh, Yuxiao Lin, Zengqing Zhuo, Oleg Borodin, Tao Gao, Fei Wang, Akihiro Kushima, Ziqing Wang, Ho-Cheol Kim, Yue Qi, Wanli Yang, Feng Pan, Ju Li, Kang Xu and Chunsheng Wang, How Solid-Electrolyte Interphase Forms in Aqueous Electrolytes. Journal of the American Chemical Society, 139, 18670, (2017)<\/p>\n

10. Liumin Suo, Oleg Borodin, Yuesheng Wang, Xiaohui Rong, Wei Sun, Xiiulin Fan, Shuyin Xu, Marshall A. Schroeder, Arthur V. Cresce, Fei Wang, Chongyin Yang, Yong-Sheng Hu, Kang Xu and Chunsheng Wang, “Water-in-Salt” Electrolyte Makes Aqueous Sodium-Ion Battery Safe, Green, and Long-Lasting. Advanced Energy Materials, 7, (2017)<\/p>\n

11. Oleg Borodin#, Liumin Suo#, Mallory Gobet, Xiaoming Ren, Fei Wang, Antonio Faraone, Jing Peng, Marco Olguin, Marshall Schroeder, Michael S. Ding, Eric Gobrogge, Arthur von Wald Cresce, Stephen Munoz, Joseph A. Dura, Steve Greenbaum, Chunsheng Wang and Kang Xu*, Liquid Structure with Nano-Heterogeneity Promotes Cationic Transport in Concentrated Electrolytes. ACS Nano, 11, 10462, (2017)<\/p>\n

12. Liumin Suo, Oleg Borodin, Wei Sun, Xiulin Fan, Chongyin Yang, Fei Wang, Tao Gao, Zhaohui Ma, Marshall Schroeder, Arthur von Cresce, Selena M. Russell, Michel Armand, Austen Angell, Kang Xu* and Chunsheng Wang, Advanced High-Voltage Aqueous Lithium-Ion Battery Enabled by “Water-in-Bisalt” Electrolyte. Angewandte Chemie-International Edition, 55, 7136, (2016)<\/p>\n

13. Liumin Suo, Fudong Han, Xiulin Fan, Huili Liu, Kang Xu and Chunsheng Wang, “Water-in-Salt” Electrolytes Enable Green and Safe Li-Ion Batteries for Large Scale Electric Energy Storage Applications. Journal of Materials Chemistry A, 4, 6639, (2016)<\/p>\n

14. Liumin Suo, Oleg Borodin, Tao Gao, Marco Olguin, Janet Ho, Xiulin Fan, Chao Luo, Chunsheng Wang* and Kang Xu, “Water-in-Salt” Electrolyte Enables High-Voltage Aqueous Lithium-Ion Chemistries. Science, 350, 938, (2015)<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

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