{"id":228826,"date":"2021-10-26T06:30:50","date_gmt":"2021-10-25T22:30:50","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=228826"},"modified":"2021-10-25T15:43:21","modified_gmt":"2021-10-25T07:43:21","slug":"%e9%83%91%e5%b7%9e%e5%a4%a7%e5%ad%a6%e6%9d%8e%e4%bf%9d%e5%86%9b%e6%95%99%e6%8e%88eem%ef%bc%9a%e5%9f%ba%e4%ba%8e%e5%88%86%e5%ad%90%e5%89%8d%e9%a9%b1%e4%bd%93%e7%83%ad%e8%a7%a3%e5%be%97%e5%88%b0bi2s3","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=228826","title":{"rendered":"\u90d1\u5dde\u5927\u5b66\u674e\u4fdd\u519b\u6559\u6388EEM\uff1a\u57fa\u4e8e\u5206\u5b50\u524d\u9a71\u4f53\u70ed\u89e3\u5f97\u5230Bi2S3\u7eb3\u7c73\u68d2\u8d1f\u8f7d\u5728\u6c27\u5316\u8fd8\u539f\u77f3\u58a8\u70ef\u8584\u7247\u7528\u4e8e\u9ad8\u6548\u9502\u79bb\u5b50\u5b58\u50a8"},"content":{"rendered":"

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\u800c\u901a\u5e38\u6709\u6548\u7684\u7b56\u7565\u662f\u5c06Bi2<\/sub>S3<\/sub>\u8bbe\u8ba1\u4e3a\u7eb3\u7c73\/\u5fae\u7c73\u7ed3\u6784\uff0c\u63d0\u4f9b\u66f4\u5927\u7684\u8868\u9762\u79ef\u4ee5\u53ca\u7f29\u77edLi+<\/sup>\u79bb\u5b50\u6269\u6563\u8def\u5f84\uff0c\u4ee5\u7f13\u89e3\u9502\u79bb\u5b50\u5d4c\u5165Bi2<\/sub>S3<\/sub>\u5f15\u8d77\u7684\u4f53\u79ef\u53d8\u5316\u5927\u7684\u95ee\u9898\u3002\u800c\u53e6\u4e00\u79cd\u7b56\u7565\u662f\u5c06Bi2<\/sub>S3<\/sub>\u8d1f\u8f7d\u5230\u5bfc\u7535\u78b3\u57fa\u4f53\u4e0a\uff0c\u901a\u8fc7\u4e8c\u8005\u7684\u534f\u540c\u4f5c\u7528\u63d0\u9ad8\u9502\u7684\u5b58\u50a8\u6027\u80fd\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u5728\u672c\u6587\u4e2d\u6211\u4eec\u7ed3\u5408\u4ee5\u4e0a\u4e24\u79cd\u7b56\u7565\u5373\u5c06\u7eb3\u7c73Bi2<\/sub>S3<\/sub>\u8d1f\u8f7d\u5728\u5bfc\u7535\u78b3\u57fa\u4f53\u4e0a\uff0c\u4ece\u800c\u5b9e\u73b0Bi2<\/sub>S3<\/sub>\u4f5c\u4e3a\u8d1f\u6781\u6750\u6599\u5728LIBs\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n

Bi2<\/sub>S3<\/sub>\u7684\u5236\u5907\u65b9\u6cd5\u6709\u7403\u78e8\uff0c\u6c34\u70ed\u4ee5\u53ca\u6eb6\u5242\u6cd5\u7b49\uff0c\u6bcf\u79cd\u65b9\u6cd5\u90fd\u53ef\u5236\u5907\u72ec\u7279\u5f62\u8c8c\u7684Bi2<\/sub>S3<\/sub>\u3002\u800c\u5206\u5b50\u524d\u9a71\u4f53\u70ed\u89e3\u6cd5\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u5b9e\u9a8c\u53c2\u6570\uff0c\u4ece\u800c\u7cbe\u786e\u8c03\u63a7\u76ee\u6807\u4ea7\u7269\u7684\u6676\u76f8\u3001\u7ec4\u6210\u548c\u5f62\u8c8c\u3002\u5229\u7528\u6709\u673a\u5206\u5b50\u914d\u4f53\u548c\u91d1\u5c5e\u94cb\u76d0\u5408\u6210\u5206\u5b50\u524d\u9a71\u4f53\uff0c\u4f7f\u91d1\u5c5e\u539f\u5b50\u9ad8\u5ea6\u5206\u6563\u3002\u800c\u6709\u673a\u914d\u4f53\u7684\u5feb\u901f\u70ed\u89e3\u6709\u5229\u4e8e\u5f62\u6210\u8868\u9762\u80fd\u8f83\u9ad8\u7684\u754c\u9762\uff0c\u66b4\u9732\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u63d0\u9ad8\u9502\u79bb\u5b50\u7684\u5b58\u50a8\u6027\u80fd\uff1b\u540c\u65f6\u7531\u4e8e\u77f3\u58a8\u70ef\u8868\u9762\u4eb2\u6c34\u6027\u5dee\uff0c\u4e00\u822c\u4e0e\u91d1\u5c5e\u786b\u5316\u7269\u4e0d\u76f8\u5bb9\uff0c\u800c\u6709\u673a\u914d\u4f53\u53ef\u4ee5\u4f7f\u91d1\u5c5e\u94cb\u76d0\u4e0e\u77f3\u58a8\u70ef\u66f4\u5bb9\u6613\u63a5\u89e6\uff0c\u63d0\u9ad8\u4e86\u6750\u6599\u7684\u5bfc\u7535\u6027\u3002\u5728\u70ed\u89e3\u8fc7\u7a0b\u4e2d\uff0c\u6709\u673a\u914d\u4f53\u7684\u5206\u89e3\u4ea7\u751f\u4e30\u5bcc\u7684\u5b54\u9699\u7ed3\u6784\uff0c\u6709\u5229\u4e8eLi+<\/sup>\u79bb\u5b50\u7684\u8fc1\u79fb\u3002\u800c\u8be5\u65b9\u6cd5\u5df2\u5e94\u7528\u4e8e\u786b\u5316\u94b4\u7684\u5236\u5907\uff0c\u5bf9\u6027\u80fd\u7684\u63d0\u9ad8\u6709\u663e\u8457\u4f5c\u7528\u3002\u56e0\u6b64\u91c7\u7528\u6b64\u6cd5\u5b9e\u73b0\u7eb3\u7c73\u68d2\u72b6Bi2<\/sub>S3<\/sub>\u8d1f\u8f7d\u5728\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\u3002<\/p>\n

\u800c\u5408\u6210\u7684\u8d1f\u8f7d\u7eb3\u7c73\u68d2\u72b6Bi2<\/sub>S3<\/sub>\u7684\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\uff0c\u7531\u4e8eBi2<\/sub>S3<\/sub>\u4e0e\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\u754c\u9762\u7684\u7535\u8377\u6781\u5316\u4f5c\u7528\u4fc3\u8fdb\u4e86\u7535\u8377\u8f6c\u79fb\uff0c\u540c\u65f6\u7531\u4e8e\u7eb3\u7c73\u68d2\u72b6\u4ee5\u53ca\u5c11\u91cf\u7a7a\u5fc3\u7eb3\u7c73\u68d2\u72b6\u7ed3\u6784\u7684Bi2<\/sub>S3<\/sub>\u7684\u5b58\u5728\u7f29\u77ed\u4e86\u9502\u79bb\u5b50\u6269\u6563\u8def\u5f84\uff0c\u589e\u52a0\u4e86\u7535\u6781\u4e0e\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u63a5\u89e6\u9762\u79ef\uff0c\u56e0\u6b64\u5177\u6709\u4f18\u5f02\u7684\u52a8\u529b\u5b66\u6027\u80fd\u3002\u53e6\u5916\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\u5177\u6709\u8868\u9762\u79ef\u5927\u548c\u5bfc\u7535\u6027\u597d\u7b49\u7279\u70b9\uff0c\u63d0\u9ad8\u7535\u5b50\u8fc1\u79fb\u901f\u7387\uff0c\u6709\u6548\u7f29\u77ed\u7535\u5b50\u548c\u9502\u79bb\u5b50\u7684\u8fc1\u79fb\u8def\u5f84\u3002\u56e0\u6b64\u5236\u5907\u7684BSG-400\u6750\u6599\u8868\u73b0\u51fa\u826f\u597d\u7684\u9502\u5b58\u50a8\u80fd\u529b\u3002\u603b\u7684\u6765\u8bf4\uff0c\u8fd9\u9879\u5de5\u4f5c\u4e3a\u91d1\u5c5e\u5316\u5408\u7269\/\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\u590d\u5408\u6750\u6599\u7684\u53d1\u5c55\u63d0\u4f9b\u4e86\u4e00\u4e2a\u901a\u7528\u7684\u7b56\u7565\uff0c\u63d0\u9ad8\u4e0e\u7535\u6c60\u6bd4\u5bb9\u91cf\u7684\u76f8\u5173\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

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<\/section>\n<\/section>\n

\u56fe<\/strong>1.<\/strong>\u00a0a)\u4ece\u5206\u5b50\u524d\u9a71\u4f53\u5230BSG-400\u6837\u54c1\u7684\u793a\u610f\u56fe\uff1bb) BSG-300\u3001BSG-400\u3001BSG-500\u3001BSG-600\u3001BSG-700\u548cBS\u6837\u54c1\u7684XRD\u8c31\u56fe\uff1bc) BSG-700\u4e0eBi\u6807\u51c6PDF\u5361\u7684XRD\u8c31\u56fe\uff0c\u4ee5\u53cad) Bi(S2<\/sub>CNEt2<\/sub>)3<\/sub>\u548ce) Bi(S2<\/sub>CNEt2<\/sub>)3<\/sub>\/GO\u524d\u9a71\u4f53\u5728Ar\u6c14\u6c1b\u4e0b\u7684TG\u66f2\u7ebf\u3002<\/p>\n

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\u56fe2.<\/strong>\u00a0a) Bi(S2<\/sub>CNEt2<\/sub>)3<\/sub>\u3001c) BS (\u63d2\u56fe\uff1a\u6837\u54c1\u4e0d\u542bP123\u7684\u900f\u5c04\u56fe)\u3001d) BSG-300\u3001f,g) BSG-400\u548c i) BSG-700\u7684\u900f\u5c04\u56fe\u50cf\uff1bb) BS\u3001e) BS-400\u548c h) BSG-700\u7684\u626b\u63cf\u56fe\u50cf\uff1bj) BSG-400\u7684\u80fd\u91cf\u8272\u6563\u8c31\u56fe\uff1bk) N2<\/sub>\u5438\u9644\u548c\u89e3\u5438\u7b49\u6e29\u7ebf\uff1bl) BS\u548cBSG-400\u7684\u5b54\u9699\u5206\u5e03\u56fe\u3002<\/p>\n

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\u56fe3.<\/strong>\u00a0a) BSG-400\u3001BSG-300\u3001BSG-400\u3001BSG-500\u3001BSG-600\u3001BSG-700\u7684\u62c9\u66fc\u5149\u8c31\uff0cb) BS\u548cBSG-400\u7684\u62c9\u66fc\u5149\u8c31\uff0cc) BSG-400\u7684\u9ad8\u5206\u8fa8\u7387XPS\u56fe\u8c31\uff0c d) Bi 4f, S 2p\u3001e) c 1s\u548c f) N 1s \u7684XPS\u5149\u8c31\u56fe\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4.<\/strong>\u00a0a) BSG-400\u548c b) BS\u4ee50.2g A-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u524d\u56db\u4e2a\u5faa\u73af\u7684\u5145\u653e\u7535\u66f2\u7ebf\u56fe\uff1bc) BSG-400\u548c d) BS\u4ee50.1mV S-1<\/sup>\u626b\u63cf\u901f\u7387\u7684CV\u56fe\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5.<\/strong>\u00a0a) BS\u548cBSG-400\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5145\u653e\u7535\u5faa\u73af\u56fe\uff1bb) BSG-500\u3001BSG-600\u548cBSG-700\u7535\u6781\u57280.2A g-1<\/sup>\u7684\u5145\u653e\u7535\u5faa\u73af\u6027\u80fd\u56fe\uff1bc) BS\u548cBSG-400\u5faa\u73af\u524d\u540e\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\uff1bd) BS\u548cBSG-400\u7684\u53d8\u500d\u7387\u6027\u80fd\u56fe\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong><\/p>\n

Zhongshuang Li, Mengmeng He, Bing Bo, Huijuan Wei, Yanyan Liu, Hao Wen, Yushan Liu, Ke Zhang, Panke Zhang*, Baojun Li*.\u00a0Bi2<\/sub>S3<\/sub>\u00a0Nanorods Hosted on rGO Sheets from Pyrolysis of Molecular Precursors for Efficient Li-Ion Storage.\u00a0Energy\u00a0Environ.\u00a0<\/em>Mater<\/em>.\u00a02020.<\/strong><\/p>\n

DOI: 10.1002\/eem2.12138.<\/p>\n

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https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/eem2.12138<\/section>\n<\/section>\n
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\u672c\u6587\u7531EEM\u671f\u520a\u6295\u7a3f\u3002<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"

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