{"id":229023,"date":"2021-10-31T06:30:13","date_gmt":"2021-10-30T22:30:13","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=229023"},"modified":"2021-10-30T22:02:26","modified_gmt":"2021-10-30T14:02:26","slug":"%e4%bd%9b%e5%b1%b1%e7%a7%91%e5%ad%a6%e6%8a%80%e6%9c%af%e5%ad%a6%e9%99%a2%e5%8d%8e%e5%8d%97%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6%e5%90%88%e4%bd%9ccej%e7%bb%bc%e8%bf%b0%e4%bc%98%e5%85%88%e5%90%b8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=229023","title":{"rendered":"\u4f5b\u5c71\u79d1\u5b66\u6280\u672f\u5b66\u9662&#038;\u534e\u5357\u7406\u5de5\u5927\u5b66\u5408\u4f5cCEJ\u7efc\u8ff0:\u4f18\u5148\u5438\u9644\u4e59\u70f7MOFs\u548c\u5176\u4ed6\u5438\u9644\u5242\u5206\u79bb\u4e59\u70ef\u4e59\u70f7\u7684\u7814\u7a76\u8fdb\u5c55"},"content":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u5415\u9053\u98de\u535a\u58eb<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u9648\u5ffb\u6559\u6388\u3001\u590f\u542f\u658c\u7814\u7a76\u5458<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u4f5b\u5c71\u79d1\u5b66\u6280\u672f\u5b66\u9662\u3001\u534e\u5357\u7406\u5de5\u5927\u5b66<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1016\/j.cej.2021.133208<\/p>\n<p><strong>01 <\/strong><strong>\u7814\u7a76\u80cc\u666f<\/strong><\/p>\n<p>\u4e59\u70ef\uff08C<sub>2<\/sub>H<sub>4<\/sub>\uff09\u662f\u77f3\u5316\u884c\u4e1a\u6700\u91cd\u8981\u548c\u9700\u6c42\u91cf\u6700\u5927\u7684\u5316\u5de5\u539f\u6599\uff0c\u5e7f\u6cdb\u7528\u4e8e\u5236\u9020\u805a\u4e59\u70ef\u548c\u5176\u4ed6\u6709\u673a\u5316\u5b66\u54c1\u3002\u5de5\u4e1a\u4e0a\u4e3b\u8981\u901a\u8fc7\u70ed\u88c2\u89e3\u77f3\u8111\u6cb9\u548c\u4e59\u70f7\uff08C<sub>2<\/sub>H<sub>6<\/sub>\uff09\u5148\u5236\u5907C<sub>2<\/sub>H<sub>4<\/sub>\/C<sub>2<\/sub>H<sub>6<\/sub>\u6df7\u5408\u7269\uff0c\u518d\u5c06C<sub>2<\/sub>H<sub>4<\/sub>\/C<sub>2<\/sub>H<sub>6<\/sub>\u6df7\u5408\u7269\u5206\u79bb\uff0c\u5236\u5907\u805a\u5408\u7ea7\u7eaf\u5ea6(\u226599.95%)\u7684\u4e59\u70ef\u3002C<sub>2<\/sub>H<sub>4<\/sub>\u548cC<sub>2<\/sub>H<sub>6<\/sub>\u5206\u5b50\u5177\u6709\u76f8\u8fd1\u7684\u6cb8\u70b9\uff0c\u76ee\u524dC<sub>2<\/sub>H<sub>4<\/sub>\/C<sub>2<\/sub>H<sub>6<\/sub>\u7684\u5de5\u4e1a\u5206\u79bb\u4e3b\u8981\u901a\u8fc7\u4f4e\u6e29\u9ad8\u538b\uff0822 bar, -25 \u2103\uff09\u7cbe\u998f\u6280\u672f\u5b9e\u73b0\uff0c\u8fd9\u662f\u4e00\u4e2a\u6781\u5176\u8017\u80fd\u7684\u8fc7\u7a0b\u3002\u6bcf\u5e74\u7eaf\u5316\u4e59\u70ef\u548c\u4e19\u70ef\u7684\u5e74\u80fd\u8017\u8d85\u8fc7\u4e86\u5168\u7403\u603b\u80fd\u8017\u76840.3%\u3002<\/p>\n<p>\u4f9d\u8d56\u4e8e\u591a\u5b54\u5438\u9644\u5242\u7684\u5438\u9644\u5206\u79bb\u6280\u672f\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u80fd\u591f\u9ad8\u6548\u3001\u8282\u80fd\u5206\u79bbC<sub>2<\/sub>H<sub>4<\/sub>\/C<sub>2<\/sub>H<sub>6<\/sub>\u7684\u6280\u672f\uff0c\u8be5\u6280\u672f\u672a\u6765\u6709\u671b\u80fd\u4ee3\u66ff\u4f4e\u6e29\u7cbe\u998f\u6280\u672f\u7528\u4e8eC<sub>2<\/sub>H<sub>4<\/sub>\/C<sub>2<\/sub>H<sub>6<\/sub>\u5206\u79bb\u3002\u73b0\u6709\u5438\u9644\u5242\u5206\u4e3a\u4f18\u5148\u5438\u9644\u4e59\u70ef\u578b\u548c\u4f18\u5148\u5438\u9644\u4e59\u70f7\u578b\u4e24\u79cd\u3002\u7531\u4e8e\u88c2\u89e3\u6c14\u4e2d\u4e59\u70ef\u7684\u542b\u91cf\u9ad8\u4e8e\u4e59\u70f7\uff08C<sub>2<\/sub>H<sub>4<\/sub>\/C<sub>2<\/sub>H<sub>6 <\/sub>\u2248 15:1\uff09\uff0c\u91c7\u7528\u4f18\u5148\u5438\u9644\u4e59\u70ef\u578b\u5438\u9644\u5242\u5206\u79bb\u4e59\u70ef\u4e59\u70f7\uff0c\u610f\u5473\u7740\u9700\u8981\u66f4\u591a\u7684\u5438\u9644\u5242\u548c\u66f4\u5927\u7684\u5438\u9644\u5e8a\u5c42\u4f53\u79ef\u6765\u5206\u79bb\u4e59\u70ef\u4e59\u70f7\u3002\u6b64\u5916\uff0c\u81f3\u5c11\u9700\u89814\u4e2a\u5438\u9644-\u8131\u9644\u5faa\u73af\uff0c\u5206\u79bb\u5f97\u5230\u7684\u4e59\u70ef\u624d\u80fd\u8fbe\u5230\u7eaf\u5ea6\u8981\u6c42\u3002\u5047\u5982\u91c7\u7528\u4f18\u5148\u5438\u9644\u4e59\u70f7\u578b\u5438\u9644\u5242\u5206\u79bbC<sub>2<\/sub>H<sub>4<\/sub>\/C<sub>2<\/sub>H<sub>6<\/sub>\u6df7\u5408\u7269\uff0c\u5438\u9644\u5242\u7528\u91cf\u548c\u6210\u672c\u66f4\u4f4e\uff0c\u5206\u79bb\u8fc7\u7a0b\u4e5f\u66f4\u7b80\u5355\uff08\u56fe1\uff09\u3002\u8fd1\u51e0\u5e74\u6765\uff0c\u5f00\u53d1\u9ad8\u6548\u7684\u4f18\u5148\u5438\u9644\u4e59\u70f7\u578b\u5438\u9644\u5242\u5df2\u6210\u4e3a\u7814\u7a76\u70ed\u70b9\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229044\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image001.png\" alt=\"\" width=\"600\" height=\"313\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image001.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image001-300x157.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1 <\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09\u4f18\u5148\u5438\u9644\u4e59\u70ef\uff08<\/strong><strong>b<\/strong><strong>\uff09\u4f18\u5148\u5438\u9644\u4e59\u70f7\u5438\u9644\u5242\u5206\u79bb\u4e59\u70ef\u4e59\u70f7\u6d41\u7a0b<\/strong><\/p>\n<p><strong>02 <\/strong><strong>\u6210\u679c\u7b80\u4ecb<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u4f5b\u5c71\u79d1\u5b66\u6280\u672f\u5b66\u9662\u9648\u5ffb\u6559\u6388\u548c\u534e\u5357\u7406\u5de5\u5927\u5b66\u590f\u542f\u658c\u7814\u7a76\u5458\u56e2\u961f<\/strong>\u8054\u5408\u7efc\u8ff0\u4e86\u73b0\u6709\u4e0d\u540c\u4f18\u5148\u5438\u9644\u4e59\u70f7\u591a\u5b54\u6750\u6599\uff08MOFs\uff0cCOFs\uff0cHOFs\uff0cPOCs\uff0c\u78b3\u6750\u6599\uff0c\u5206\u5b50\u7b5b\uff09\u5438\u9644\u5206\u79bbC<sub>2<\/sub>H<sub>4<\/sub>\/C<sub>2<\/sub>H<sub>6<\/sub>\u7684\u7814\u7a76\u8fdb\u5c55\uff0c\u4e5f\u8ba8\u8bba\u4e86\u4e0d\u540c\u5438\u9644\u5242\u9762\u4e34\u7684\u6311\u6218\u548c\u672a\u6765\u7684\u53d1\u5c55\u65b9\u5411\uff0c<strong>\u7b2c\u4e00\u4f5c\u8005\u4e3a\u4f5b\u5c71\u79d1\u5b66\u6280\u672f\u5b66\u9662\u5415\u9053\u98de\u535a\u58eb\uff0c\u8881\u6587\u5175\u6559\u6388\u3001\u8bb8\u950b\u535a\u58eb\u3001\u989c\u5065\u535a\u58eb\u7b49\u4e5f\u53c2\u4e0e\u4e86\u672c\u9879\u5de5\u4f5c\uff0c<\/strong>\u8be5\u8bba\u6587\u8fd1\u65e5\u4ee5\u9898\u201cRecent advances in adsorptive separation of ethane and ethylene by C<sub>2<\/sub>H<sub>6<\/sub>-selective MOFs and other adsorbents\u201d\u53d1\u8868\u5728\u5316\u5de5\u6743\u5a01\u520a\u7269\u300aChemical Engineering Journal\u300b\uff08IF: 13.273\uff09\u4e0a\u3002<\/p>\n<p><strong>03 <\/strong><strong>\u56fe\u6587\u89e3\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229045\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image002.png\" alt=\"\" width=\"600\" height=\"323\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image002.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image002-300x162.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2 <\/strong><strong>\u4f18\u5148\u5438\u9644\u4e59\u70f7\u578b\u5438\u9644\u5242\u53d1\u5c55\u7684\u65f6\u95f4\u8f74<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229046\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image003.png\" alt=\"\" width=\"600\" height=\"601\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image003.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image003-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image003-300x300.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3 <\/strong><strong>\u5de5\u4e1a\u5438\u9644\u5242\u9700\u8bc4\u4f30\u7684\u6027\u80fd\u6307\u6807<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229047\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image004.png\" alt=\"\" width=\"600\" height=\"236\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image004.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image004-300x118.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>4 <\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09\u73b0\u6709\u7684\u8d85\u8fc7<\/strong><strong>130<\/strong><strong>\u79cd<\/strong><strong>MOFs<\/strong><strong>\u6750\u6599\u4e2d\u4e59\u70f7\u5438\u9644\u5bb9\u91cf\u4f4d\u4e8e\u524d<\/strong><strong>15<\/strong><strong>\u4f4d\u7684<\/strong><strong>MOFs<\/strong><strong>\u6750\u6599\uff1b\uff08<\/strong><strong>b<\/strong><strong>\uff09\u5438\u9644\u5bb9\u91cf\u524d<\/strong><strong>15<\/strong><strong>\u7684<\/strong><strong>MOFs<\/strong><strong>\u6750\u6599\u7684\u5b54\u5f84\u5927\u5c0f\u548c\u6bd4\u8868\u9762\u79ef\u5927\u5c0f<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229048\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image005.png\" alt=\"\" width=\"600\" height=\"192\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image005.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image005-300x96.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>5 <\/strong><strong>\u5e38\u6e29\u5e38\u538b\u4e0b\u5177\u6709\u6700\u9ad8\u4e59\u70f7\u5438\u9644\u5bb9\u91cf\u7684<\/strong><strong>MOF<\/strong><strong>\u6750\u6599\uff08<\/strong><strong>SNNU-40, 7.54 mmol\/g<\/strong><strong>\uff09\u91cc\u9762\u7684\uff08<\/strong><strong>a<\/strong><strong>\uff09\u4e59\u70f7\uff0c\uff08<\/strong><strong>b<\/strong><strong>\uff09\u4e59\u70ef\u7684\u4f18\u5148\u5438\u9644\u4f4d\u70b9<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229049\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image006.png\" alt=\"\" width=\"600\" height=\"216\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image006.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image006-300x108.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>6 <\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09\u901a\u8fc7\u201c\u5b54\u9053\u5206\u5272\u6cd5\u201d\u5408\u6210\u5e38\u6e29\u5e38\u538b\u4e0b\u5177\u6709\u8d85\u9ad8\u4e59\u70f7\u5438\u9644\u5bb9\u91cf\u7684<\/strong><strong>MOF<\/strong><strong>\u6750\u6599\uff08<\/strong><strong>CPM<\/strong><strong>\u7cfb\u5217<\/strong><strong>, 7.13-7.45 mmol\/g<\/strong><strong>\uff09\u793a\u610f\u56fe\u3002\uff08<\/strong><strong>b<\/strong><strong>\uff09\u4e59\u70f7\u548c\u4e59\u70ef\u5728<\/strong><strong>CPM<\/strong><strong>\u7cfb\u5217\u6750\u6599\u4e2d\u7684\u5438\u9644\u5bc6\u5ea6\u5206\u5e03<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229050\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image007.png\" alt=\"\" width=\"600\" height=\"474\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image007.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image007-300x237.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>7 <\/strong><strong>\u73b0\u6709\u7684\u8d85\u8fc7<\/strong><strong>130<\/strong><strong>\u79cd<\/strong><strong>MOFs<\/strong><strong>\u6750\u6599\u4e2d<\/strong><strong>C<sub>2<\/sub>H<sub>6<\/sub>\/C<sub>2<\/sub>H<sub>4<\/sub><\/strong><strong>\u5438\u9644\u9009\u62e9\u6027<\/strong><strong>\u4f4d\u4e8e\u524d<\/strong><strong>15<\/strong><strong>\u4f4d\u7684<\/strong><strong>MOFs<\/strong><strong>\u6750\u6599<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229051\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image008.png\" alt=\"\" width=\"600\" height=\"490\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image008.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image008-300x245.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>8 <\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09\u5e38\u6e29\u5e38\u538b\u4e0b\u5177\u6709\u6700\u9ad8<\/strong><strong>C<sub>2<\/sub>H<sub>6<\/sub>\/C<sub>2<\/sub>H<sub>4<\/sub><\/strong><strong>\u5438\u9644\u9009\u62e9\u6027\u7684<\/strong><strong>MOF<\/strong><strong>\u6750\u6599\uff08<\/strong><strong>NIIC-20-Bu, 15.4<\/strong><strong>\uff09\u7684\u5206\u5b50\u9759\u7535\u52bf\uff0c\uff08<\/strong><strong>b<\/strong><strong>\uff09\u4e59\u70f7\u548c\uff08<\/strong><strong>c<\/strong><strong>\uff09\u4e59\u70ef\u5728<\/strong><strong>NIIC-20-Bu<\/strong><strong>\u7684<\/strong><strong>A<\/strong><strong>\u3001<\/strong><strong>B<\/strong><strong>\u3001<\/strong><strong>C<\/strong><strong>\u4e09\u79cd\u5438\u9644\u4f4d\u4e0a\u7684\u7ed3\u5408\u80fd<\/strong><\/p>\n<p>\u5f00\u53d1\u9ad8\u6548\u7684\u4f18\u5148\u5438\u9644\u4e59\u70f7MOFs\u6750\u6599\u7684\u5173\u952e\u662f\u63d0\u9ad8\u5176\u5438\u9644\u9009\u62e9\u6027\u3002\u6309\u7167\u5438\u9644\u673a\u7406\u5212\u5206\uff0c\u73b0\u6709\u56db\u79cd\u7b56\u7565\u589e\u5f3a\u6750\u6599\u7684C<sub>2<\/sub>H<sub>6<\/sub>\/C<sub>2<\/sub>H<sub>4<\/sub>\u5438\u9644\u9009\u62e9\u6027\uff1a\uff08i\uff09\u589e\u5f3a\u4e59\u70f7\u5206\u5b50\u548cMOFs\u9aa8\u67b6\u95f4\u7684C-H\u00b7\u00b7\u00b7O\/N\/F\u6c22\u952e\u7684\u6570\u91cf\u548c\u5f3a\u5ea6\uff1b\uff08ii\uff09\u589e\u5f3a\u4e59\u70f7\u5206\u5b50\u548cMOFs\u9aa8\u67b6\u95f4C-H\u00b7\u00b7\u00b7\u00b7\u03c0\u952e\u7684\u6570\u91cf\u548c\u5f3a\u5ea6\uff1b\uff08iii\uff09\u589e\u5f3a\u4e59\u70f7\u5206\u5b50\u548cMOFs\u9aa8\u67b6\u95f4\u7684\u8303\u5fb7\u534e\u4f5c\u7528\u6570\u91cf\u548c\u5f3a\u5ea6\uff1b(iv)\u540c\u65f6\u589e\u5f3a\u4e59\u70f7\u5206\u5b50\u548cMOFs\u9aa8\u67b6\u95f4C-H\u00b7\u00b7\u00b7O\/N\/F\uff0cC-H\u00b7\u00b7\u00b7\u00b7\u03c0\u6c22\u952e\u548c\u8303\u5fb7\u534e\u4f5c\u7528\u3002<\/p>\n<p><strong><u>\u2460\u5229\u7528\u7b56\u7565<\/u><\/strong><strong><u>i<\/u><\/strong><strong><u>\u589e\u5f3a\u5438\u9644\u9009\u62e9\u6027\u793a\u4f8b<\/u><\/strong><strong><u>:<\/u><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229052\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image009.png\" alt=\"\" width=\"600\" height=\"255\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image009.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image009-300x128.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>9 Li<\/strong><strong>\u7b49\u4eba\u901a\u8fc7\u5411<\/strong><strong>Fe<sub>2<\/sub>(dobdc)<\/strong><strong>\u9aa8\u67b6<\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09\u5185\u5f15\u5165\u8fc7\u6c27\u4f4d\u70b9\uff0c\u589e\u5f3a<\/strong><strong>\u4e59\u70f7\u5206\u5b50\u548c<\/strong><strong>MOFs<\/strong><strong>\u9aa8\u67b6\u95f4\u7684<\/strong><strong>C-H\u00b7\u00b7\u00b7O<\/strong><strong>\u6c22\u952e\u4f5c\u7528\u7684\u6570\u91cf\u548c\u5f3a\u5ea6\uff0c<\/strong><strong>\u7814\u5236\u51fa\u9ad8\u5438\u9644\u9009\u62e9\u6027\u7684<\/strong><strong>Fe<sub>2<\/sub>(O<sub>2<\/sub>)(dobdc)<\/strong><strong>\uff08<\/strong><strong>b<\/strong><strong>\uff09<\/strong><strong>,<\/strong><strong>\uff08<\/strong><strong>c<\/strong><strong>\uff09\u548c\uff08<\/strong><strong>d<\/strong><strong>\uff09\u5206\u522b\u4e3a\u4e59\u70f7\u548c\u4e59\u70ef\u5728<\/strong><strong>Fe<sub>2<\/sub>(O<sub>2<\/sub>)(dobdc)<\/strong><strong>\u4e0a\u7684\u4f18\u5148\u5438\u9644\u4f4d\u70b9<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229053\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image010.png\" alt=\"\" width=\"600\" height=\"230\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image010.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image010-300x115.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>10 <\/strong><strong>\u672c\u56e2\u961f\u901a\u8fc7\u9009\u7528\u542b\u5927\u91cf<\/strong><strong>N<\/strong><strong>\u539f\u5b50\u7684\u535f\u5549\u914d\u4f53\uff0c\u589e\u5f3a<\/strong><strong>\u4e59\u70f7\u5206\u5b50\u548c<\/strong><strong>MOF-545<\/strong><strong>\u9aa8\u67b6\u95f4<\/strong><strong>C-H\u00b7\u00b7\u00b7N<\/strong><strong>\u6c22\u952e\u4f5c\u7528\u7684\u6570\u91cf\u548c\u5f3a\u5ea6\uff0c\uff08<\/strong><strong>b<\/strong><strong>\uff09\u548c\uff08<\/strong><strong>c<\/strong><strong>\uff09\u5206\u522b\u4e3a\u4e59\u70ef\u548c\u4e59\u70f7\u5728<\/strong><strong>MOF-545<\/strong><strong>\u4e0a\u7684\u4f18\u5148\u5438\u9644\u4f4d\u70b9<\/strong><\/p>\n<p><strong><u>\u2461\u5229\u7528\u7b56\u7565<\/u><\/strong><strong><u>ii<\/u><\/strong><strong><u>\u589e\u5f3a\u5438\u9644\u9009\u62e9\u6027\u793a\u4f8b<\/u><\/strong><strong><u>:<\/u><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229054\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image011.png\" alt=\"\" width=\"600\" height=\"248\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image011.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image011-300x124.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>11 Lin<\/strong><strong>\u7b49\u4eba\u901a\u8fc7\u9009\u7528\u591a\u82b3\u70c3\u73af\u7684\u7fa7\u9178\u914d\u4f53\uff0c\u589e\u5f3a<\/strong><strong>\u4e59\u70f7\u5206\u5b50\u548c<\/strong><strong>Cu(Qc)<sub>2<\/sub><\/strong><strong>\u9aa8\u67b6\u95f4<\/strong><strong>C-H\u00b7\u00b7\u00b7\u03c0<\/strong><strong>\u6c22\u952e\u4f5c\u7528\u7684\u6570\u91cf\u548c\u5f3a\u5ea6\uff0c\uff08<\/strong><strong>a<\/strong><strong>\uff09\u548c\uff08<\/strong><strong>b<\/strong><strong>\uff09\u5206\u522b\u4e3a\u4e59\u70ef\u548c\u4e59\u70f7\u5728<\/strong><strong>Cu(Qc)<sub>2<\/sub><\/strong><strong>\u4e0a\u7684\u4f18\u5148\u5438\u9644\u4f4d\u70b9<\/strong><\/p>\n<p><strong><u>\u2462\u5229\u7528\u7b56\u7565<\/u><\/strong><strong><u>iii<\/u><\/strong><strong><u>\u589e\u5f3a\u5438\u9644\u9009\u62e9\u6027\u793a\u4f8b<\/u><\/strong><strong><u>:<\/u><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229055\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image012.png\" alt=\"\" width=\"600\" height=\"177\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image012.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image012-300x89.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>12 Schneemann<\/strong><strong>\u7b49\u4eba\u901a\u8fc7\u7532\u57fa\u529f\u80fd\u5316\u7fa7\u9178\u914d\u4f53\uff0c\u589e\u5f3a<\/strong><strong>\u4e59\u70f7\u5206\u5b50\u548c<\/strong><strong>Zn<sub>2<\/sub>(bdc)<sub>2<\/sub>(dabco) <\/strong><strong>\u9aa8\u67b6\u95f4\u8303\u5fb7\u534e\u4f5c\u7528\u7684\u6570\u91cf\u548c\u5f3a\u5ea6\uff0c\u63d0\u9ad8\u5176\u5438\u9644\u9009\u62e9\u6027\uff0c\uff08<\/strong><strong>a<\/strong><strong>\uff09\u548c\uff08<\/strong><strong>b<\/strong><strong>\uff09\u5206\u522b\u4e3a\u4e59\u70f7\u5728\u7532\u57fa\u6539\u6027\u524d\u540e\u6750\u6599\u4e0a\u7684\u4f18\u5148\u5438\u9644\u4f4d\u70b9\uff0c\uff08<\/strong><strong>c<\/strong><strong>\uff09\u4e3a\u4e59\u70ef\u5728\u7532\u57fa\u6539\u6027\u540e\u6750\u6599\u4e0a\u7684\u4f18\u5148\u5438\u9644\u4f4d\u70b9<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229056\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image013.png\" alt=\"\" width=\"600\" height=\"212\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image013.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image013-300x106.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>13 <\/strong><strong>\u672c\u56e2\u961f\u901a\u8fc7\u9009\u7528\u5177\u6709\u4e92\u7a7f\u7ed3\u6784\u7684\u6750\u6599\uff0c\u4f7f\u5355\u4f4d\u6676\u80de\u5185\u8303\u5fb7\u534e\u4f5c\u7528\u4f4d\u70b9\u6570\u91cf\u66f4\u591a\uff0c\u589e\u5f3a\u9aa8\u67b6\u5bf9<\/strong><strong>\u4e59\u70f7\u548c\u4e59\u70ef\u5206\u5b50\u8303\u5fb7\u534e\u4f5c\u7528\u529b\u5dee\u5f02\uff1b\u56fe\u4e2d\u5c55\u793a\u4e86\u4e59\u70f7\u4e59\u70ef\u5728\u6750\u6599\u5185\u7684\u4f18\u5148\u5438\u9644\u4f4d\u70b9<\/strong><\/p>\n<p><strong><u>\u2463\u5229\u7528\u7b56\u7565<\/u><\/strong><strong><u>iv<\/u><\/strong><strong><u>\u589e\u5f3a\u5438\u9644\u9009\u62e9\u6027\u793a\u4f8b<\/u><\/strong><strong><u>:<\/u><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229057\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image014.png\" alt=\"\" width=\"600\" height=\"467\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image014.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image014-300x234.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>14 <\/strong><strong>\u672c\u56e2\u961f\u901a\u8fc7\u63ba\u6742\u4e0d\u540c\u91d1\u5c5e\u79bb\u5b50\u8fdb\u5165<\/strong><strong>PCN-250<\/strong><strong>\uff08<\/strong><strong>Fe<\/strong><strong>\uff09\u6750\u6599\u5185\uff0c\u4f7f\u5f97\u5230\u7684\u53cc\u91d1\u5c5e<\/strong><strong>MOFs<\/strong><strong>\u6750\u6599\u5bf9\u4e59\u70f7\u7684<\/strong><strong>C-H\u00b7\u00b7\u00b7N<\/strong><strong>\uff0c<\/strong><strong>C-H\u00b7\u00b7\u00b7\u03c0<\/strong><strong>\u6c22\u952e\u4f5c\u7528\u548c\u8303\u5fb7\u534e\u4f5c\u7528\u529b\u540c\u65f6\u589e\u52a0\u3002<\/strong><strong>(a)-(e)<\/strong><strong>\u56fe\u662f\u4e59\u70ef\u4e59\u70f7\u5206\u5b50\u5728<\/strong><strong>PCN-250<\/strong><strong>\u7cfb\u5217\u6750\u6599\u5185\u7684\u4f18\u5148\u5438\u9644\u4f4d\u70b9<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229058\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image015.png\" alt=\"\" width=\"600\" height=\"488\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image015.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image015-300x244.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>15 <\/strong><strong>\u4f18\u5148\u5438\u9644\u4e59\u70f7<\/strong><strong>MOFs<\/strong><strong>\u6750\u6599\u4e2d\u70ed\u7a33\u5b9a\u6027\u6700\u9ad8\u7684\u524d<\/strong><strong>15<\/strong><strong>\u79cd\u6750\u6599<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229059\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image016.png\" alt=\"\" width=\"600\" height=\"491\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image016.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image016-300x246.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>16 Li<\/strong><strong>\u7b49\u4eba\u7814\u7a76\u4e86<\/strong><strong>8<\/strong><strong>\u79cd<\/strong><strong>COFs<\/strong><strong>\u5438\u9644\u5206\u79bb\u4e59\u70f7<\/strong><strong>\/<\/strong><strong>\u4e59\u70ef\u6027\u80fd\uff0c\u5e76\u53d1\u73b0<\/strong><strong>COFs<\/strong><strong>\u4f18\u5148\u5438\u9644\u4e59\u70f7\u7684\u673a\u7406\u4e3b\u8981\u4e3a\u4e59\u70f7\u4e0e<\/strong><strong>COFs<\/strong><strong>\u5b54\u58c1\u4e0a\u7684<\/strong><strong>O<\/strong><strong>\uff0c<\/strong><strong>Br<\/strong><strong>\u539f\u5b50\u6216\u82b3\u70c3\u73af\u5b58\u5728<\/strong><strong>C-H\u00b7\u00b7\u00b7O\/Br<\/strong><strong>\uff0c<\/strong><strong>C-H\u00b7\u00b7\u00b7\u03c0<\/strong><strong>\u6c22\u952e\u4f5c\u7528\u3002\u56fe<\/strong><strong>(a)-(h)<\/strong><strong>\u4e3a\u4e59\u70ef\u4e59\u70f7\u5728\u4e0d\u540c<\/strong><strong>COFs<\/strong><strong>\u4e0a\u7684\u5438\u9644\u7b49\u6e29\u7ebf\uff08<\/strong><strong>273<\/strong><strong>\u548c<\/strong><strong>298 K<\/strong><strong>\uff09<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229060\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image017.png\" alt=\"\" width=\"600\" height=\"243\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image017.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image017-300x122.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>17 Zhang<\/strong><strong>\u7b49\u4eba\u53d1\u73b0<\/strong><strong>ZJU-HOF-1<\/strong><strong>\u662f\u5177\u6709\u6700\u9ad8\u5438\u9644\u9009\u62e9\u6027\uff08<\/strong><strong>2.25<\/strong><strong>\uff09\u7684\u4f18\u5148\u5438\u4e59\u70f7<\/strong><strong>HOFs<\/strong><strong>\u6750\u6599\uff0c\u5176\u4f18\u5148\u5438\u9644\u4e59\u70f7\u673a\u7406\u4e3a\u9aa8\u67b6\u5bf9\u4e59\u70f7\u7684<\/strong><strong>C-H\u00b7\u00b7\u00b7O<\/strong><strong>\uff0c<\/strong><strong>C-H\u00b7\u00b7\u00b7\u03c0<\/strong><strong>\u6c22\u952e\u4f5c\u7528\u66f4\u5f3a\u3002<\/strong><strong>(a)-(d)<\/strong><strong>\u4e3a<\/strong><strong>ZJU-HOF-1<\/strong><strong>\u7684\u7ed3\u6784\u4ee5\u53ca\u5176\u4e09\u89d2\u72b6\u7684\u5b54\u9053\uff08\u9ec4\u7403\uff09\u548c\u7b3c\u72b6\u7684\u5b54\u9053\uff08\u84dd\u7403\uff09<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229061\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image018.png\" alt=\"\" width=\"600\" height=\"299\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image018.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image018-300x150.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>18 Su<\/strong><strong>\u7b49\u4eba\u53d1\u73b0\u9ad8\u7a33\u5b9a\u6027\u7684<\/strong><strong>CPOC-301<\/strong><strong>\u4f18\u5148\u5438\u9644\u4e59\u70f7<\/strong><strong>POCs<\/strong><strong>\u6750\u6599\uff0c\u5176\u4f18\u5148\u5438\u9644\u4e59\u70f7\u673a\u7406\u4e3a\u9aa8\u67b6\u5bf9\u4e59\u70f7\u7684<\/strong><strong>C-H\u00b7\u00b7\u00b7\u03c0<\/strong><strong>\u6c22\u952e\u4f5c\u7528\u66f4\u5f3a\u3002<\/strong><strong>(a)<\/strong><strong>\u548c<\/strong><strong>(b)<\/strong><strong>\u4e3a\u4e59\u70f7\u548c\u4e59\u70ef\u5728<\/strong><strong>CPOC-301<\/strong><strong>\u5185\u7684\u5438\u9644\u4f4d\u70b9<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-229062\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image019.png\" alt=\"\" width=\"600\" height=\"174\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image019.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/10\/image019-300x87.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>19 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