{"id":229378,"date":"2021-11-09T14:35:52","date_gmt":"2021-11-09T06:35:52","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=229378"},"modified":"2021-11-09T14:33:09","modified_gmt":"2021-11-09T06:33:09","slug":"%ef%bc%88%e5%b7%b2%e6%a0%a1%e7%a8%bf%e4%bb%b6%ef%bc%89%e9%bb%84%e7%bb%b4%e5%ba%9e%e6%ac%a2-nsr%ef%bc%9a%e5%8f%8c%e9%85%8d%e4%bd%93%e5%92%8chsab%e7%ad%96%e7%95%a5%e4%bc%98%e5%8c%96mof%e7%ba%b3","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=229378","title":{"rendered":"\u9ec4\u7ef4&\u5e9e\u6b22 NSR\uff1a\u53cc\u914d\u4f53\u548cHSAB\u7b56\u7565\u4f18\u5316MOF\u7eb3\u7c73\u6676\u4f53\u5b9e\u73b0\u7a33\u5b9a\u7684\u7535\u5316\u5b66\u5faa\u73af\u6027\u80fd"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u8d85\u7ea7\u7535\u5bb9\u5668\uff08SCs\uff09\u5177\u6709\u5bff\u547d\u957f\u3001\u529f\u7387\u5bc6\u5ea6\u9ad8\u3001\u5145\u7535\u901f\u5ea6\u5feb\u7b49\u4f18\u70b9\uff0c\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u7535\u5316\u5b66\u50a8\u80fd\u5668\u4ef6\u3002\u5176\u4e2d\uff0c\u4e8c\u7ef4\uff082D\uff09\u4f2a\u7535\u5bb9\u7eb3\u7c73\u6750\u6599\u88ab\u8bc1\u660e\u662fSCs\u9ad8\u80fd\u9ad8\u529f\u7387\u5e94\u7528\u7684\u6709\u6548\u7535\u6781\u6750\u6599\uff0c\u56e0\u6b642D\u4f2a\u7535\u5bb9\u7eb3\u7c73\u6750\u6599\u7684\u5236\u5907\u548c\u53d1\u5c55\u5bf9SCs\u7684\u672a\u6765\u53d1\u5c55\u81f3\u5173\u91cd\u8981\u3002\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u662f\u4e00\u79cd\u7ed3\u6784\u591a\u6837\u3001\u6bd4\u8868\u9762\u79ef\u5927\u3001\u5b54\u5f84\u53ef\u8c03\u7684\u6676\u4f53\u6750\u6599\u3002MOFs\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6c14\u4f53\u50a8\u5b58\u548c\u5206\u79bb\u3001SCs\u3001\u50ac\u5316\u3001\u6c34\u5904\u7406\u548c\u6d77\u6c34\u6de1\u5316\u7b49\u9886\u57df\u3002MOFs\u7eb3\u7c73\u6750\u6599\u5177\u6709\u8f83\u77ed\u7684\u6269\u6563\u8def\u5f84\u548c\u5c3a\u5bf8\u76f8\u5173\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u975e\u5e38\u9002\u5408\u7528\u4e8e\u7535\u5316\u5b66\u50a8\u80fd\u88c5\u7f6e\u3002\u7136\u800c\uff0c\u5927\u591a\u6570MOFs\u7eb3\u7c73\u6750\u6599\u5b58\u5728\u7a33\u5b9a\u6027\u4e0d\u8db3\u7684\u95ee\u9898\uff0c\u4e25\u91cd\u9650\u5236\u4e86\u5b83\u4eec\u7684\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u5408\u6210\u5c3a\u5bf8\/\u5f62\u8c8c\u53ef\u63a7\u4e14\u7a33\u5b9a\u6027\u63d0\u9ad8\u7684MOF\u7eb3\u7c73\u6676\u6210\u4e3a\u5176\u66f4\u5e7f\u6cdb\u5e94\u7528\u7684\u6838\u5fc3\u3002\u867d\u7136\u5df2\u62a5\u9053\u4f7f\u7528\u4e0d\u540c\u7684\u8bd5\u5242\u548c\u6a21\u677f\u6765\u8c03\u8282MOFs\u7684\u5c3a\u5bf8\/\u5f62\u8c8c\uff0c\u4f46\u662f\u5927\u591a\u6570\u65b9\u6cd5\u4ec5\u9002\u7528\u4e8e\u7279\u5b9a\u6750\u6599\u3002\u56e0\u6b64\uff0c\u975e\u5e38\u6709\u5fc5\u8981\u5f00\u53d1\u4e00\u79cd\u901a\u7528\u4e14\u9ad8\u6548\u7684\u65b9\u6cd5\u6765\u8c03\u8282\u4e0d\u540cMOFs\u7684\u6676\u4f53\u5c3a\u5bf8\u548c\u5f62\u8c8c\uff0c\u5e76\u4f7f\u5176\u5177\u6709\u4f18\u5f02\u7684\u7535\u5316\u5b66\u50a8\u80fd\u6027\u80fd\u3002
\n \"\"\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u4eac\u90ae\u7535\u5927\u5b66\u9ec4\u7ef4\u9662\u58eb\u548c\u626c\u5dde\u5927\u5b66\u5e9e\u6b22\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u5229\u75284, 4′-\u8054\u5421\u5576\uff08Bpy\uff09\u4f5c\u4e3a\u914d\u4f4d\u8c03\u8282\u5242\uff0c\u901a\u8fc7\u57fa\u4e8e\u53cc\u914d\u4f53\u548c\u786c-\u8f6f-\u9178-\u78b1\uff08HSAB\uff09\u7b56\u7565\u5b9e\u73b0MOF\u7684\u66f4\u53ef\u63a7\u5f62\u8c8c\u548c\u826f\u597d\u7a33\u5b9a\u6027\u3002\u4f5c\u8005\u901a\u8fc7\u4e00\u79cd\u901a\u7528\u7684\u3001\u5feb\u901f\u7684\u5ba4\u6e29\u6eb6\u6db2\u53cd\u5e94\u65b9\u6cd5\u6765\u5236\u5907\u5404\u79cd\u4e09\u7ef4\uff083D\uff09\u67f1\u72b6\u5c42[Ni(Tdc)(Bpy)]n<\/sub> MOF\u6750\u6599\uff08Tdc=\u567b\u5429-2, 5\u4e8c\u7fa7\u9178\u76d0\uff09\u3002Nill<\/sup>\u4e2d\u5fc3\u53ef\u4ee5\u8fde\u63a5\u5230\u8f83\u8f6f\u7684\u78b1Bpy\uff0c\u5f62\u6210\u7a33\u5b9a\u7684\u4e00\u7ef4\uff081D\uff09NiBpy\u7ebf\u6027\u94fe\uff0c\u5b83\u53ef\u4ee5\u7528\u4f5c\u67f1\u4f53\uff0c\u4ee5\u652f\u6301\u7531Nill<\/sup>\u4e2d\u5fc3\u4e0e\u7fa7\u9178\u914d\u4f53Tdc\u914d\u4f4d\u5f62\u6210\u7684\u4e8c\u7ef4\uff082D\uff09Ni-Tdc\u7f51\u7edc\u7ed3\u6784\u3002\u6211\u4eec\u901a\u8fc7\u8c03\u8282Bpy\u7684\u6d53\u5ea6\u6765\u63a7\u5236\u6676\u4f53\u751f\u957f\u7684\u65b9\u5411\uff0c\u6210\u529f\u5408\u6210\u4e86\u5177\u6709\u4e0d\u540c\u53ef\u63a7\u5f62\u6001\uff081D \u7eb3\u7c73\u7ea4\u7ef4\u30012D\u7eb3\u7c73\u7247\u548c3D\u805a\u96c6\u4f53\uff09\u7684[Ni(Tdc)(Bpy)]n<\/sub> MOF\u7eb3\u7c73\u6676\u4f53\u3002\u6240\u5236\u5907\u7684[Ni(Tdc)(Bpy)]n<\/sub> MOF\u7eb3\u7c73\u6676\u4f53\u7528\u4f5cSCs\u7684\u7535\u6781\uff0c2D\u7eb3\u7c73\u7247\u57280.5 A g-1<\/sup>\u4e0b\u663e\u793a\u51fa\u6700\u9ad8\u7684\u6bd4\u5bb9\u91cf\u4e3a612 F g-1<\/sup>\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u4f7f\u75282D\u7eb3\u7c73\u7247\u548c\u6d3b\u6027\u70ad\uff08AC\uff09\u6210\u529f\u5236\u9020\u4e86\u4e24\u4e2a\u4e32\u8054\u7684\u6c34\u7cfb\u975e\u5bf9\u79f0\u7684SC\uff08ASC\uff09\u5668\u4ef6\uff0c\u5e76\u5177\u6709\u4f18\u5f02\u7684\u5faa\u73af\u6027\u80fd\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cDual-ligand and hard-soft-acid-base strategies to optimize metal-organic framework nanocrystals for stable electrochemical cycling performance\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNational Science Review<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u53cc\u914d\u4f53\u548cHSAB\u7b56\u7565\u7528\u4e8e\u5236\u59073D\u67f1\u72b6\u5c42[Ni(Tdc)(Bpy)]n<\/sub> MOF\u7eb3\u7c73\u6676\u4f53\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c\u3001MOF\u7eb3\u7c73\u6750\u6599\u7684\u5f62\u8c8c\u8868\u5f81<\/strong>
\n \"\"\uff08a-c\uff09MOF\u7eb3\u7c73\u6750\u6599\u4ece1D\u7eb3\u7c73\u7ea4\u7ef4\u52303D\u805a\u96c6\u4f53\u7684\u5f62\u8c8c\u8f6c\u53d8\u8fc7\u7a0b\uff1b<\/p>\n

\uff08d-f\uff09SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08g-i\uff09\u6837\u54c1\u7684TEM\u56fe\u50cf\uff1a(a, d, g)M1\u3001(b, e, h)M5\u548c(c, f, i)M8\u3002<\/p>\n

\u56fe\u4e09\u3001M1\u3001M5\u548cM8\u7684\u7269\u7406\u8868\u5f81<\/strong>
\n \"\"\uff08a\uff09M1\u3001M5\u548cM8\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

\uff08b\uff09\u6cbf\uff08202\uff09\u65b9\u5411\u89c2\u5bdf\u7684\u5806\u79ef\uff1b<\/p>\n

\uff08c\uff09\u6cbf\uff08024\uff09\u65b9\u5411\u89c2\u5bdf\u7684\u79ef\u7d2f\uff1b<\/p>\n

\uff08d-i\uff09M5\u7684XPS\u5149\u8c31\uff1a\u8c03\u67e5\u548c\u9ad8\u5206\u8fa8\u7387\u3001Ni 2p\u3001NAs\u3001C 1s\u3001S 2p\u548cO 1s XPS\u5149\u8c31\u3002<\/p>\n

\u56fe\u56db\u3001M1\u3001M5\u548cM8\u7684\u7535\u5bb9\u6027\u80fd<\/strong>
\n \"\"\uff08a\uff09\u4e09\u7535\u6781\u7535\u6c60\u4e2dM1\u3001M5\u548cM8\u572830 mV s-1<\/sup>\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09M5\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09M5\u7684Log(i<\/em>)\u4e0elog(v<\/em>)\u6bd4\u503c\u56fe\uff1b<\/p>\n

\uff08d\uff09\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\uff0cM5\u7684\u7535\u5bb9\u8d21\u732e\u767e\u5206\u6bd4\u6761\u5f62\u56fe\uff1b<\/p>\n

\uff08e\uff09M1\u3001M5\u548cM8\u57281 A g-1<\/sup>\u4e0b\u7684\u6052\u7535\u6d41\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08f\uff09M1\u3001M5\u548cM8\u5728\u591a\u4e2a\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u7535\u5bb9\u3002<\/p>\n

\u56fe\u4e94\u3001M5\/\/AC\u5668\u4ef6\u7684\u6027\u80fd<\/strong>
\n \"\"\uff08a\uff09M5\/\/AC\u5728\u591a\u4e2a\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09M5\/\/AC\u7684Log(i<\/em>)\u4e0elog(v<\/em>)\u6bd4\u503c\u56fe\uff1b<\/p>\n

\uff08c\uff09\u572830 mV s-1<\/sup>\u65f6M5\/\/AC\u7684\u9634\u5f71\u533a\u57df\u663e\u793a\u7535\u5bb9\u5206\u6570\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff09\u5728\u591a\u4e2a\u7535\u6d41\u5bc6\u5ea6\u4e0b\u4e32\u8054\u7684\u4e24\u4e2aM5\/\/AC\u5668\u4ef6\u7684GCD\u66f2\u7ebf\uff1b<\/p>\n

\uff08e\uff09\u4e24\u4e2a\u4e32\u8054\u7684M5\/\/AC\u5668\u4ef6\u7684\u6bd4\u7535\u5bb9\u53d8\u5316\u4e0e\u7535\u6d41\u5bc6\u5ea6\u7684\u5173\u7cfb\uff0c\u4e24\u4e2a\u4e32\u8054\u7684M5\/\/AC\u5668\u4ef6\u7684\u5149\u5b66\u56fe\u50cf\uff1b<\/p>\n

\uff08f\uff09\u4e24\u4e2aM5\/\/AC\u7684\u793a\u610f\u56fe\uff0c\u5668\u4ef6\u4e32\u8054\u4ee5\u70b9\u4eae\u9ec4\u8272LED\u5e76\u4e3a\u65cb\u8f6c\u7535\u673a\u4f9b\u7535\uff1b<\/p>\n

\uff08g\uff09\u57283 mA cm-2<\/sup>\u4e0b\u8fdb\u884c5000\u6b21\u5faa\u73af\u7684\u5faa\u73af\u6027\u80fd\u548c\u5e93\u4ed1\u6548\u7387\uff0c\u8fde\u63a5inr\u7cfb\u5217\u7684\u4e24\u4e2aM5\/\/AC\u5668\u4ef6\u7684\u524d20\u6b21\u548c\u6700\u540e20\u6b21GCD\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u516d\u3001\u673a\u7406\u7814\u7a76<\/strong>
\n \"\"\uff08a\uff09\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u7535\u89e3\u8d28\u4e2d\u7684OH–<\/sup>\u4ece[Ni(Tdc)(Bpy)]n<\/sub>\u7eb3\u7c73\u7247\u4e2d\u9009\u62e9\u6027\u53bb\u9664Tdc\u7fa7\u9178\u76d0\u94fe\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09[Ni(Tdc)(Bpy)]n<\/sub> MOF\u57fa\u7535\u6781\u7684\u5145\u653e\u7535\u673a\u7406\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u57fa\u4e8e\u534f\u540c\u53cc\u914d\u4f53\u548cHSAB\u7b56\u7565\u7684\u5236\u5907\u5f62\u6001\u53ef\u63a7\u76843D\u67f1\u72b6\u5c42[Ni(Tdc)(Bpy)]n<\/sub> MOF\u7eb3\u7c73\u6676\u4f53\u7684\u7b80\u4fbf\u65b9\u6cd5\uff0c\u8be5\u65b9\u6cd5\u8868\u660e\u5b83\u662f\u4e00\u79cd\u5177\u6709\u4f18\u826f\u751f\u547d\u5468\u671f\u7684\u9ad8\u6548SCs\u7535\u6781\u6750\u6599\u3002Bpy\u4f5c\u4e3a\u914d\u4f4d\u8c03\u8282\u5242\u6765\u8c03\u8282[Ni(Tdc)(Bpy)]n<\/sub> MOF\u7eb3\u7c73\u6676\u4f53\u4ece1D\u7eb3\u7c73\u7ea4\u7ef4\u52302D\u7eb3\u7c73\u7247\u518d\u52303D\u805a\u96c6\u4f53\u7684\u5f62\u8c8c\u8f6c\u53d8\uff0c\u4f3c\u4e4e\u4e0e\u5f15\u5165\u7684Bpy\u6570\u91cf\u6709\u5173\u3002\u4f7f\u5f97MOF\u6676\u4f53\u6cbf1D Ni-Bpy\u7ebf\u6027\u94fe\u62162D Ni-Tdc\u7f51\u7edc\u65b9\u5411\u751f\u957f\u3002\u5bf9\u6bd41D\u7eb3\u7c73\u7ea4\u7ef4\u548c3D\u805a\u96c6\u4f53\uff0c2D\u7eb3\u7c73\u7247\u8868\u73b0\u51fa\u66f4\u9ad8\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4e0e\u79bb\u5b50\u6269\u6563\u548c\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\u5bc6\u5207\u76f8\u5173\uff0c\u56e0\u4e3a2D\u7eb3\u7c73\u7247\u7684\u79bb\u5b50\u4f20\u8f93\u8ddd\u79bb\u77ed\u3002\u6b64\u5916\uff0c\u901a\u8fc7HSAB\u7b56\u7565\uff0c\u57283D\u67f1\u72b6\u5c42[Ni(Tdc)(Bpy)]n<\/sub> MOF\u7ed3\u6784\u4e2d\uff0cNill\u4e2d\u5fc3\u53ef\u7528\u4f5c\u8f6f\u91d1\u5c5e\u4f4d\u70b9\u4e0e\u8f6f\u57faBpy\u8fde\u63a5\u4ee5\u6784\u5efa\u7a33\u5b9a\u76841D Ni-Bpy\u7ebf\u6027\u94fe\u3002\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cMOF\u6846\u67b6\u4e2d\u7684Ni-Tdc\u7f51\u7edc\u88ab\u7535\u89e3\u8d28\u4e2d\u7684OH–<\/sup>\u53bb\u9664\uff0c\u800cNi-Bpy\u5c42\u5f97\u5230\u4e86\u5f88\u597d\u7684\u4fdd\u62a4\uff0c\u4ece\u800c\u63d0\u4f9b\u4e86\u826f\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u4f5c\u8005\u76f8\u4fe1\u8be5\u5de5\u4f5c\u53ef\u4ee5\u63d0\u4f9b\u4e00\u79cd\u8bbe\u8ba1\u5c3a\u5bf8\/\u5f62\u8c8c\u53ef\u63a7\u548c\u529f\u80fd\u53ef\u8c03\u7684MOFs\u7684\u901a\u7528\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDual-ligand and hard-soft-acid-base strategies to optimize metal-organic framework nanocrystals for stable electrochemical cycling performance<\/a><\/strong>. National Science Review<\/em>, 2021<\/strong>, DOI: 10.1093\/nsr\/nwab197.<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

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