{"id":230181,"date":"2021-11-26T08:31:56","date_gmt":"2021-11-26T00:31:56","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=230181"},"modified":"2021-11-26T08:31:56","modified_gmt":"2021-11-26T00:31:56","slug":"%e4%ba%9a%e7%90%9b%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6%e6%9c%80%e6%96%b0science%ef%bc%9a%e9%80%9a%e8%bf%87%e6%97%a0%e7%9b%91%e7%9d%a3%e6%9c%ba%e5%99%a8%e5%ad%a6%e4%b9%a0%e5%8a%a0%e9%80%9f%e5%8f%8c","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=230181","title":{"rendered":"\u4e9a\u741b\u5de5\u4e1a\u5927\u5b66\u6700\u65b0Science\uff1a\u901a\u8fc7\u65e0\u76d1\u7763\u673a\u5668\u5b66\u4e60\u52a0\u901f\u53cc\u6838\u94af\u50ac\u5316\u5242\u8bc6\u522b"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u5747\u76f8\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u5f62\u6001\u662f\u53cd\u5e94\u6027\u3001\u6548\u7387\u548c\u9009\u62e9\u6027\u7684\u5173\u952e\u51b3\u5b9a\u56e0\u7d20\u3002\u7136\u800c\uff0c\u51b3\u5b9a\u50ac\u5316\u5242\u7684\u6838\u7d20\uff08\u5982\u5355\u4f53\u4e0e\u4e8c\u805a\u4f53\uff09\u3001\u6709\u5229\u7684\u6c27\u5316\u6001\u4ee5\u53ca\u50ac\u5316\u5242\u7684\u8fde\u63a5\u6001\u5e38\u5e38\u51e0\u4e4e\u4e0d\u88ab\u7406\u89e3\u3002\u4f8b\u5982\uff0c\u5728\u5e7f\u6cdb\u5e94\u7528\u7684Pd\u50ac\u5316\u4ea4\u53c9\u5076\u8054\u7684\u80cc\u666f\u4e0b\uff0cPd(<sup>0<\/sup>)[P(t-Bu)<sub>3<\/sub>]<sub>2<\/sub>\u4e0e\u82b3\u57fa\u6eb4\u7684\u6c27\u5316\u52a0\u6210\u5728\u539f\u4f4d\u751f\u6210Pd(I)\u4e8c\u805a\u4f53\uff0c\u5f53P(t-Bu)<sub>3<\/sub>\u88abPh<sub>2<\/sub>PH\u53d6\u4ee3\u65f6\uff0c\u76f8\u540c\u7684Pd(I)\u4e8c\u805a\u4f53\u8f6c\u5316\u4e3aPd\u4e09\u805a\u4f53\u3002\u5bf9\u4e8e\u975e\u8d35\u91d1\u5c5e\u7269\u79cd\uff08\u5982Fe\u3001Co\u3001Cu\u6216Ni\u50ac\u5316\u5242)\uff09\u6765\u8bf4\uff0c\u8fd9\u79cd\u5f62\u6001\u5f62\u6210\u7684\u6311\u6218\u8fdb\u4e00\u6b65\u52a0\u5267\uff0c\u5bf9\u4e8e\u8fd9\u4e9b\u975e\u8d35\u91d1\u5c5e\u7269\u79cd\u6765\u8bf4\uff0c\u9664\u4e86\u6c27\u5316\u6001\u548c\u6838\u6001\u4e4b\u5916\uff0c\u7ec6\u5fae\u7684\u914d\u4f53\u5dee\u5f02\u53ef\u80fd\u4f1a\u5f71\u54cd\u5176\u6709\u5229\u7684\u81ea\u65cb\u6001\u3002\u663e\u7136\uff0c\u914d\u4f4d\u4f53\u7684\u6027\u8d28\u4e25\u91cd\u5f71\u54cd\u4e86\u7269\u79cd\u7684\u5f62\u6210\u3002\u7136\u800c\uff0c\u6bcf\u4e2a\u914d\u4f53\u5f71\u54cd\u7684\u6839\u672c\u539f\u56e0\u5f88\u5c11\u88ab\u7406\u89e3\u6216\u53ef\u9884\u6d4b\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u4eca\u65e5\uff0c\u5728<strong><b>\u5fb7\u56fd\u4e9a\u741b\u5de5\u4e1a\u5927\u5b66Franziska Schoenebeck<\/b><\/strong><strong><b>\u56e2\u961f<\/b><\/strong><strong><b>\u7b49\u4eba<\/b><\/strong>\u5e26\u9886\u4e0b\uff0c\u62a5\u544a\u4e86\u4e00\u4e2a\u4ec5\u4f7f\u75285\u4e2a\u5b9e\u9a8c\u6570\u636e\u70b9\u7684\u65e0\u76d1\u7763\u673a\u5668\u5b66\u4e60\u5de5\u4f5c\u6d41\u7a0b\u3002\u5b83\u5229\u7528\u4e86\u901a\u7528\u53c2\u6570\u6570\u636e\u5e93\uff0c\u5e76\u8f85\u4ee5\u7279\u5b9a\u95ee\u9898\u7684\u8ba1\u7b97\u673a\u6570\u636e\u91c7\u96c6\u548c\u805a\u7c7b\u3002\u56e2\u961f\u5c55\u793a\u4e86\u94af\uff08Pd\uff09\u50ac\u5316\u5242\u5f62\u6001\u5f62\u6210\u7684\u8fd9\u4e00\u5177\u6709\u6311\u6218\u6027\u7684\u95ee\u9898\uff0c\u76ee\u524d\u7f3a\u4e4f\u4e00\u4e2a\u673a\u7406\u3002\u4ece348\u4e2a\u914d\u4f53\u7684\u603b\u7a7a\u95f4\u4e2d\uff0c\u8be5\u7b97\u6cd5\u9884\u6d4b\u5e76\u901a\u8fc7\u5b9e\u9a8c\u9a8c\u8bc1\u4e86\u8bb8\u591a\u81a6\u914d\u4f53\uff08\u5305\u62ec\u4ee5\u524d\u4ece\u672a\u5408\u6210\u7684\u914d\u4f53\uff09\uff0c\u5b83\u4eec\u5728\u66f4\u5e38\u89c1\u7684Pd(<sup>0<\/sup>)\u548cPd(<sup>II<\/sup>)\u7269\u79cd\u4e0a\u4ea7\u751f\u53cc\u6838Pd(<sup>I<\/sup>)\u914d\u5408\u7269\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a<strong><b>\u201cAccelerated dinuclear palladium catalyst identification through unsupervised machine learning\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86<strong><b>Science<\/b><\/strong>\u3002<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-230183\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/11\/0-10.jpg\" alt=\"\" width=\"600\" height=\"182\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/11\/0-10.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/11\/0-10-300x91.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong><b>\u56fe1<\/b><\/strong><strong><b>\u00a0\u5de5\u4f5c\u7684\u80cc\u666f<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-230184\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/11\/1-13.jpg\" alt=\"\" width=\"600\" height=\"548\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/11\/1-13.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/11\/1-13-300x274.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>2 \u6570\u636e\u751f\u6210\u548c\u805a\u7c7b<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-230185\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/11\/2-12.jpg\" alt=\"\" width=\"600\" height=\"632\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/11\/2-12.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/11\/2-12-285x300.jpg 285w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>3<\/b><\/strong><strong><b>\u00a0\u9884\u6d4b\u548c\u5b9e\u9a8c\u6d4b\u8bd5<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-230186\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/11\/3-12.jpg\" alt=\"\" width=\"600\" height=\"607\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/11\/3-12.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/11\/3-12-297x300.jpg 297w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><a href=\"https:\/\/www.science.org\/doi\/10.1126\/science.abj0999\"><u>Accelerated dinuclear palladium catalyst identification through unsupervised machine learning<\/u><\/a>\uff08Science\uff0c2021\uff0cDOI:10.1126\/science.abj0999\uff09<\/p>\n<p>\u672c\u6587\u7531<strong><b>\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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