{"id":230300,"date":"2021-11-30T06:30:34","date_gmt":"2021-11-29T22:30:34","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=230300"},"modified":"2021-11-29T18:33:04","modified_gmt":"2021-11-29T10:33:04","slug":"%e7%a6%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6esm%ef%bc%9a%e9%80%9a%e8%bf%87%e7%95%8c%e9%9d%a2%e8%bf%87%e7%a8%8b%e6%8e%a7%e5%88%b6%e5%ae%9e%e7%8e%b0%e6%97%a0%e6%9e%9d%e6%99%b6%e9%94%8c%e7%a6%bb%e5%ad%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=230300","title":{"rendered":"\u798f\u5dde\u5927\u5b66ESM\uff1a\u901a\u8fc7\u754c\u9762\u8fc7\u7a0b\u63a7\u5236\u5b9e\u73b0\u65e0\u679d\u6676\u950c\u79bb\u5b50\u7535\u6c60"},"content":{"rendered":"

\"\"<\/p>\n

\u7b2c\u4e00\u4f5c\u8005\uff1a\u674e\u777f\u3001\u674e\u731b\u8d85<\/p>\n

\u901a\u8baf\u4f5c\u8005\uff1a\u6768\u7a0b\u51ef*\u3001\u4e8e\u5ca9*<\/p>\n

\u5355\u4f4d\uff1a\u798f\u5dde\u5927\u5b66<\/p>\n

\u7814\u7a76\u80cc\u666f<\/strong><\/p>\n

\u6c34\u6eb6\u6db2\u950c\u79bb\u5b50\u7535\u6c60\u4e2d\u950c\u91d1\u5c5e\u7684\u754c\u9762\u53cd\u5e94\u590d\u6742\u800c\u4e0d\u7a33\u5b9a\uff0c\u8fd9\u9020\u6210\u4e86\u6811\u72b6\u679d\u6676\u7684\u5feb\u901f\u751f\u957f\u4ee5\u53ca\u526f\u53cd\u5e94\u53d1\u751f\u4ece\u800c\u5f15\u8d77\u7535\u89e3\u8d28\u52a0\u901f\u6d88\u8017\u548c\u5c40\u90e8pH\u53d8\u5316\uff0c\u963b\u788d\u4e86\u950c\u79bb\u5b50\u7535\u6c60\u4f5c\u4e3a\u50a8\u80fd\u5668\u4ef6\u7684\u5feb\u901f\u53d1\u5c55\uff0c\u662f\u950c\u79bb\u5b50\u7535\u6c60\u4e0d\u53ef\u907f\u514d\u7684\u5371\u5bb3\u3002\u4f7f\u7528\u7535\u89e3\u8d28\u6dfb\u52a0\u5242\u7a33\u5b9a\u950c\u91d1\u5c5e\u8d1f\u6781\u8868\u9762\u662f\u4e00\u79cd\u7b80\u5355\u6709\u6548\u7684\u65b9\u6cd5\uff0c\u4f46\u5bf9\u4e8e\u6dfb\u52a0\u5242\u662f\u5982\u4f55\u89e3\u51b3\u679d\u6676\u548c\u526f\u53cd\u5e94\u95ee\u9898\u7684\u57fa\u672c\u539f\u7406\u8fd8\u6ca1\u6709\u88ab\u5b8c\u6574\u6e05\u695a\u5730\u63cf\u8ff0\u3002\u4e3a\u6784\u5efa\u66f4\u52a0\u6709\u6548\u7684\u6dfb\u52a0\u5242\uff0c\u52a0\u901f\u950c\u79bb\u5b50\u7535\u6c60\u53d1\u5c55\uff0c\u5b8c\u5584\u5bf9\u6dfb\u52a0\u5242\u4f5c\u7528\u8fc7\u7a0b\u57fa\u672c\u539f\u7406\u7684\u8ba4\u8bc6\u662f\u5341\u5206\u91cd\u8981\u7684\u3002<\/p>\n

\u6587\u7ae0\u7b80\u4ecb<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u798f\u5dde\u5927\u5b66\u4e8e\u5ca9\u6559\u6388&\u6768\u7a0b\u51ef\u526f\u6559\u6388\u5728\u56fd\u9645\u77e5\u540d\u671f\u520aEnergy Storage Materials\u4e0a\u53d1\u8868\u9898\u4e3a\u201cHexaoxacyclooctadecane induced interfacial engineering to achieve dendrite-free Zn ion batteries\u201c\u7684\u6587\u7ae0\u3002\u8be5\u6587\u7ae0\u901a\u8fc7\u5f15\u5165\u516d\u6c27\u6742\u73af\u5341\u516b\u70f7 (\u5341\u516b\u51a0\u516d, 18C6)\u4f5c\u4e3a\u7535\u89e3\u8d28\u6dfb\u52a0\u5242\u6784\u5efa\u6df7\u5408\u7535\u89e3\u8d28\u3002\u5728\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u901a\u8fc7\u9650\u5236\u6548\u5e94\u5c06Zn2+<\/sup>\u5438\u964418C6\u5728\u8868\u9762\uff0c\u8c03\u8282\u950c\u79bb\u5b50\u6eb6\u5242\u5316\u7ed3\u6784\uff0c\u950c\u79bb\u5b50\u4f18\u5148\u4e0e18C6\u5f62\u6210\u4e00\u4e2a\u65b0\u7684\u7a33\u5b9a\u7684\u6eb6\u5242\u5316\u7ed3\u6784\uff0c\u6c89\u79ef\u5747\u5300\uff0c\u5e76\u4e14\u63d0\u9ad8\u4e86\u6eb6\u5242\u5316\u7ed3\u6784\u7684\u7535\u5bfc\u7387\uff0c\u4f7f\u7535\u8377\u66f4\u5bb9\u6613\u5728\u7535\u6781\u8868\u9762\u8f6c\u79fb\uff0c\u526f\u53cd\u5e94\u51cf\u5c11\u3002<\/p>\n

\u672c\u6587\u8981\u70b9<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1 (a)\u542b18C6\u6dfb\u52a0\u5242\u7684\u950c\u91d1\u5c5e\u8868\u9762\u793a\u610f\u56fe\u3002(b)\u4e0d\u540c\u6d53\u5ea618C6\u7684\u6781\u5316\u7535\u538b\u3002(c) \u5bf9\u79f0\u7535\u6c60CV\u66f2\u7ebf\u3002(d-e)\u65f6\u95f4\u7535\u6d41\u66f2\u7ebf\u3002(f) Tafel\u66f2\u7ebf\u3002(g)\u5dee\u5206\u7535\u5bb9-\u7535\u4f4d\u66f2\u7ebf\u3002(h) IHP\u7535\u8377\u8f6c\u79fb\u6d3b\u5316\u80fd(Ea2)\u62df\u5408\u66f2\u7ebf\u3002(i)\u4e0d\u540c\u7535\u89e3\u8d28\u4ea7\u6c22\u91cf\u968f\u65f6\u95f4\u7684\u66f2\u7ebf\u3002<\/p>\n

\u6781\u5316\u7535\u538b\u66f2\u7ebf\u8868\u660e\u6d53\u5ea6\u662f\u5f71\u54cd\u950c\u6c89\u79ef\u7684\u56e0\u7d20\u3002\u5faa\u73af\u4f0f\u5b89\u6cd5\u66f2\u7ebf\u8868\u660e\u4e8618C6\u5bf9\u950c\u79bb\u5b50\u7684\u6c89\u79ef\/\u6eb6\u51fa\u884c\u4e3a\u8d77\u5230\u66f4\u5927\u7684\u51cf\u901f\u4f5c\u7528\uff0c\u6210\u6838\u8fc7\u7a0b\u5177\u6709\u8d85\u77ac\u6001\u6210\u6838\u7279\u6027\u3002\u5dee\u5206\u7535\u5bb9-\u7535\u4f4d\u66f2\u7ebf\u548c\u6d3b\u5316\u80fd\u66f2\u7ebf\u7ed3\u679c\u663e\u793a18C6\u6bd4\u6c34\u66f4\u5bb9\u6613\u5438\u9644\u5728\u7535\u6781\u8868\u9762\u3002Tafel\u66f2\u7ebf\u548c\u6790\u6c22\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\u526f\u53cd\u5e94\u51cf\u5c11\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2 (a) DFT\u8ba1\u7b97Zn\u79bb\u5b50\u7684\u7edc\u5408\u80fd\u3002(b) HOMO-LUMO\u8f68\u9053\u548c\u95f4\u9699\u56fe\u3002(c-e) AIMD\u6a21\u62df\u6c34\u5206\u5b50\u7684\u5f84\u5411\u5206\u5e03\u51fd\u6570\u548c\u79ef\u5206\u66f2\u7ebf(\u77ed\u865a\u7ebf)\u3002<\/p>\n

\u901a\u8fc7DFT\u4e0eAIMD\u8ba1\u7b97\u5f97\u51fa\u950c\u79bb\u5b50\u4e0e\u4e0d\u540c\u5206\u5b50\u7684\u7edc\u5408\u80fd\u3001HOMO-LUMO\u8f68\u9053\u56fe\u4ee5\u53ca\u6c34\u5206\u5b50\u7684\u5f84\u5411\u5206\u5e03\u51fd\u6570\u548c\u79ef\u5206\u66f2\u7ebf\uff0c\u7ed3\u679c\u8868\u660e\u950c\u79bb\u5b50\u4f18\u5148\u4e0e18C6\u5f62\u6210\u4e00\u4e2a\u65b0\u7684\u7a33\u5b9a\u7684\u6eb6\u5242\u5316\u7ed3\u6784\uff0c\u6574\u4f53\u5177\u6709\u758f\u6c34\u6027\uff0c\u4e1418C6\u63d0\u9ad8\u4e86\u6eb6\u5242\u5316\u7ed3\u6784\u7684\u7535\u5bfc\u7387\uff0c\u4f7f\u7535\u8377\u66f4\u5bb9\u6613\u5728\u7535\u6781\u8868\u9762\u8f6c\u79fb\uff0c\u526f\u53cd\u5e94\u51cf\u5c11\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 (a-d)\u5faa\u73af20\u6b21\u540eZn\u8868\u9762\u5f62\u8c8c\u7684SEM\u56fe\u50cf\u3002(e-f)\u5faa\u73af20\u6b21\u540eZn\u8868\u9762\u6b8b\u7559C\u548cS\u7684XPS\u3002(g-h) ZnSO4\u7c89\u672b\u30011M ZnSO4 (aq)\u30011M ZnSO4\u542b0.2M 18C6\u548c18C6\u3002 (l)\u7684\u7ea2\u5916\u5149\u8c31\u3002 (i) 1M ZnSO4 (aq)\u30011M ZnSO4\u542b0.2M 18C6\u548c18C6 (l)\u7684\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n

\u901a\u8fc7\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u89c2\u5bdf\u4e0d\u540c\u7535\u89e3\u8d28\u6761\u4ef6\u4e0b\u950c\u6c89\u79ef\u5f62\u8c8c\uff0c\u542b\u670918C6\u6dfb\u52a0\u5242\u65f6\uff0c\u4f7f\u6c89\u79ef\u65b9\u5411\u65e0\u9009\u62e9\u6027\uff0c\u66f4\u52a0\u5747\u5300\u3002\u540c\u65f6\u7ed3\u5408\u7ea2\u5916\u5149\u8c31\u53ca\u62c9\u66fc\u5149\u8c31\u53d1\u73b0\uff0c18C6\u4e0e\u950c\u79bb\u5b50\u5f62\u6210\u65b0\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4 (a)\u539f\u4f4d\u5149\u5b66\u663e\u5fae\u955c\u4e0b\u7684\u5f62\u6001\u6f14\u53d8\u3002(b) 1mA cm-2<\/sup>\u548c1mAh cm-2<\/sup>\u4e0bZn\u5bf9\u79f0\u7535\u6c60\u7684\u957f\u5468\u671f\u66f2\u7ebf\u3002(c)\u542b18C6\u950c\u5bf9\u79f0\u7535\u6c60\u7684\u901f\u7387\u6027\u80fd\u3002(d) Zn || Cu\u7535\u6c60\u7684CE (e) Zn || VO2\u7535\u6c60\u7684CE\u3001\u6bd4\u5bb9\u91cf\u548c\u500d\u7387\u5145\u653e\u7535\u6027\u80fd (f) 0.5 C\u65f6Zn || VO2<\/sub>\u7535\u6c60\u6d4b\u8bd5\u3002<\/p>\n

18C6\u4f7f\u5bf9\u79f0\u7535\u6c60\u80fd\u591f\u7a33\u5b9a\u5730\u5faa\u73af2400h\u4ee5\u4e0a\uff0c\u5728\u4e0d\u540c\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7535\u6c60\u7684\u8fc7\u7535\u4f4d\u53d8\u5316\u76f8\u5bf9\u7a33\u5b9a\u3002Zn || Cu\u7535\u6c60\u6d4b\u8bd5\u663e\u793a\u542b\u670918C6\u7684\u7535\u89e3\u8d28\u53ef\u4ee5\u7ef4\u6301\u7a33\u5b9a\u768499.5%\u7684\u5e93\u4ed1\u6548\u7387\u8fbe\u5230200\u6b21\u5faa\u73af\u4ee5\u4e0a\u3002\u5728\u5168\u7535\u6c60\u6d4b\u8bd5\u4e2d\uff0c\u4f7f\u752818C6\u53ef\u4ee5\u660e\u663e\u63d0\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u6587\u7ae0\u94fe\u63a5<\/p>\n

Hexaoxacyclooctadecane induced interfacial engineering to achieve dendrite-free Zn ion batteries<\/p>\n

https:\/\/doi.org\/10.1016\/j.ensm.2021.11.015<\/u><\/a><\/p>\n

\u4f5c\u8005\u4ecb\u7ecd<\/strong><\/p>\n

\u4e8e\u5ca9\u6559\u63881995\u5e74\u6bd5\u4e1a\u4e8e\u798f\u5dde\u5927\u5b66\u5316\u5de5\u7cfb\u7845\u9178\u76d0\u5de5\u7a0b\u4e13\u4e1a\u83b7\u5b66\u58eb\u5b66\u4f4d\uff0c\u00a01998\u5e74\u6bd5\u4e1a\u4e8e\u798f\u5dde\u5927\u5b66\u5316\u5de5\u7cfb\u5316\u5b66\u5de5\u7a0b\u4e13\u4e1a\u83b7\u7855\u58eb\u58eb\u5b66\u4f4d\uff0c2006\u5e74\u4e8e\u798f\u5dde\u5927\u5b66\u6750\u6599\u5b66\u9662\u6750\u6599\u5b66\u4e13\u4e1a\u83b7\u535a\u58eb\u5b66\u4f4d\uff0c1998\u52a0\u5165\u798f\u5dde\u5927\u5b66\u6750\u6599\u5b66\u9662\u5f00\u5c55\u5de5\u4f5c\u3002\u4e2d\u56fd\u6750\u6599\u5b66\u4f1a\u73af\u5883\u6750\u6599\u5206\u4f1a\u526f\u4e3b\u4efb\u59d4\u5458\uff0c\u798f\u5efa\u7845\u9178\u76d0\u5b66\u4f1a\u7406\u4e8b\u957f\uff0c\u4e2d\u56fd\u673a\u68b0\u5de5\u7a0b\u5b66\u4f1a\u5de5\u7a0b\u9676\u74f7\u4e13\u4e1a\u59d4\u5458\u4f1a\u5e38\u52a1\u7406\u4e8b\u3002\u81f4\u529b\u4e8e\u9676\u74f7\u6750\u6599\u3001\u73af\u5883\u529f\u80fd\u6750\u6599\u3001\u7eb3\u7c73\u6750\u6599\u7b49\u65b9\u9762\u7814\u7a76\u3002<\/p>\n

\u6768\u7a0b\u51ef\u526f\u6559\u63882014\u5e74\u6bd5\u4e1a\u4e8e\u5929\u6d25\u5927\u5b66\u7406\u5b66\u9662\u5316\u5b66\u7cfb\uff0c\u53d6\u5f97\u5b66\u58eb\u5b66\u4f4d\uff0c2019\u5e74\u6bd5\u4e1a\u4e8e\u5317\u4eac\u5927\u5b66\u5316\u5b66\u4e0e\u5206\u5b50\u5de5\u7a0b\u5b66\u9662\uff0c\u53d6\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c\u5e76\u4e8e2019\u5e74\u52a0\u5165\u798f\u5dde\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u3002\u81f4\u529b\u4e8e\u7535\u6c60\u7535\u5316\u5b66\u4e0e\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u6a21\u62df\u7b49\u65b9\u9762\u7814\u7a76\u3002\u798f\u5efa\u7845\u9178\u76d0\u5b66\u4f1a\u7406\u4e8b\u3002\u6b22\u8fce\u5e7f\u5927\u79d1\u5b66\u7231\u597d\u8005\u4e0e\u540c\u5b66\u4eec\u6765\u4fe1\u8ba8\u8bba\uff0c\u90ae\u7bb11058360340@qq.com\uff0c\u5171\u540c\u63a8\u8fdb\u7535\u5316\u5b66\u7406\u8bba\u4e0e\u5b9e\u9a8c\u7814\u7a76\u3002<\/p>\n

\u672c\u6587\u7531\u4f5c\u8005\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u7b2c\u4e00\u4f5c\u8005\uff1a\u674e\u777f\u3001\u674e\u731b\u8d85 \u901a\u8baf\u4f5c\u8005\uff1a\u6768\u7a0b\u51ef*\u3001\u4e8e\u5ca9* \u5355\u4f4d\uff1a\u798f\u5dde\u5927\u5b66 \u7814\u7a76\u80cc\u666f \u6c34\u6eb6\u6db2\u950c\u79bb\u5b50\u7535\u6c60\u4e2d\u950c\u91d1\u5c5e\u7684\u754c\u9762\u53cd\u5e94\u590d\u6742\u800c\u4e0d\u7a33\u5b9a\uff0c\u8fd9\u9020\u6210\u4e86\u6811\u72b6\u679d\u6676\u7684\u5feb\u901f\u751f\u957f\u4ee5\u53ca\u526f\u53cd…<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-230300","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/230300"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=230300"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/230300\/revisions"}],"predecessor-version":[{"id":230306,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/230300\/revisions\/230306"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=230300"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=230300"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=230300"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}