{"id":230396,"date":"2021-12-02T08:37:40","date_gmt":"2021-12-02T00:37:40","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=230396"},"modified":"2021-12-02T08:45:25","modified_gmt":"2021-12-02T00:45:25","slug":"%e8%a7%a3%e8%af%bb-%e5%8e%9f%e4%bd%8d%e6%8b%89%e6%9b%bc%e5%85%89%e8%b0%b1%e6%8f%ad%e7%a7%98%e7%95%8c%e9%9d%a2%e6%b0%b4%e5%88%86%e5%ad%90%e7%9a%84%e7%bb%93%e6%9e%84%e5%92%8c%e8%a7%a3%e7%a6%bb","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=230396","title":{"rendered":"\u5317\u5927&#038;\u53a6\u5927\u6700\u65b0Nature"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p><strong><b>\u4e86\u89e3\u6c34\u5206\u5b50\u5728\u56fa\u6db2\u754c\u9762\u7684\u7ed3\u6784\u548c\u52a8\u6001\u8fc7\u7a0b\u662f\u8868\u9762\u79d1\u5b66\u3001\u80fd\u6e90\u79d1\u5b66\u548c\u50ac\u5316\u4e2d\u6781\u5176\u91cd\u8981\u7684\u7814\u7a76\u8bfe\u9898<\/b><\/strong>\u3002\u4f5c\u4e3a\u6a21\u578b\u50ac\u5316\u5242\uff0c\u539f\u5b50\u7ea7\u5e73\u5766\u7684\u5355\u6676\u7535\u6781\u8868\u73b0\u51fa\u826f\u597d\u9650\u5b9a\u7684\u8868\u9762\u548c\u7535\u573a\u7684\u7279\u6027\uff0c\u5e76\u4e14\u53ef\u4ee5\u88ab\u7528\u6765\u9610\u660e\u5728\u539f\u5b50\u6c34\u5e73\u7ed3\u6784\u548c\u7535\u50ac\u5316\u6d3b\u6027\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u4ece\u800c\u4e3a\u7814\u7a76\u5355\u6676\u8868\u9762\u7684\u754c\u9762\u6c34\u5206\u5b50\u884c\u4e3a\u7684\u7535\u50ac\u5316\u63d0\u4f9b\u4e86\u4e00\u4e2a\u6846\u67b6\u3002<strong><b>\u7136\u800c\uff0c\u7531\u4e8e\u6765\u754c\u9762\u6c34\u5206\u5b50\u7684\u5e72\u6270\u548c\u754c\u9762\u73af\u5883\u7684\u590d\u6742\u6027\uff0c\u754c\u9762\u6c34\u5f88\u96be\u63a2\u6d4b\u3002\u56e0\u6b64\uff0c\u5173\u4e8e\u754c\u9762\u6c34\u5206\u5b50\u5728\u7535\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\u53d8\u5316\u4e0e\u4f5c\u7528\u673a\u5236\u7684\u7814\u7a76\u53d8\u5f97\u56f0\u96be\u91cd\u91cd<\/b><\/strong>\u3002<\/p>\n<p>\u8868\u9762\u589e\u5f3a\u62c9\u66fc\u6563\u5c04(SERS)\u662f\u4e00\u79cd\u5177\u6709\u5355\u5206\u5b50\u7ea7\u5206\u8fa8\u80fd\u529b\u7684\u9ad8\u5ea6\u8868\u9762\u654f\u611f\u6280\u672f\u3002\u7136\u800c\uff0c\u539f\u5b50\u6241\u5e73\u7684\u5355\u6676\u8868\u9762\u4e0d\u80fd\u6709\u6548\u5730\u652f\u6301SERS\u7cbe\u786e\u68c0\u6d4b\u8868\u9762\u5316\u5b66\u5f62\u6001\u6240\u9700\u7684\u8868\u9762\u7b49\u79bb\u5b50\u4f53\u5171\u632f\u6548\u5e94\u3002<strong><b>\u58f3\u5c42\u9694\u7edd\u7eb3\u7c73\u7c92\u5b50\u589e\u5f3a\u62c9\u66fc\u5149\u8c31(SHINERS)\u6280\u672f\u662f\u4e3a\u4e86\u514b\u670dSERS\u7684\u56fa\u6709\u5f62\u6001\u9650\u5236\u800c\u53d1\u660e\u7684\uff0c\u53ef\u7528\u4e8e\u7814\u7a76\u5177\u6709\u6781\u9ad8\u8868\u9762\u7075\u654f\u5ea6\u7684\u5355\u6676\u8868\u9762\u4e0a\u7684\u7535\u50ac\u5316\u53cd\u5e94<\/b><\/strong>\u3002<\/p>\n<p><strong><b>\u4eca\u65e5\uff0c\u53a6\u95e8\u5927\u5b66\u674e\u5251\u950b\u6559\u6388\u548c\u5317\u4eac\u5927\u5b66\u6df1\u5733\u7814\u7a76\u751f\u9662\u6f58\u950b\u6559\u6388\u8bfe\u9898\u7ec4\u5408\u4f5c\uff0c\u7ed3\u5408\u7535\u5316\u5b66\u3001\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u548c\u8ba1\u7b97\u6280\u672f\uff0c\u5728\u7535\u50ac\u5316\u6790\u6c22\u53cd\u5e94\u8fc7\u7a0b\u4e2d\uff0c\u5bf9\u94af\u5355\u6676\u7535\u6781\/\u6eb6\u6db2\u754c\u9762\u6c34\u5206\u5b50\u7684\u6784\u578b\u53ca\u5176\u52a8\u6001\u53d8\u5316\u8fc7\u7a0b\u8fdb\u884c\u5b9e\u65f6\u76d1\u6d4b\u3002<\/b><\/strong>\u76f4\u63a5\u5149\u8c31\u8bc1\u636e\u8868\u660e\uff0c\u754c\u9762\u6c34\u5206\u5b50\u7531\u6c22\u952e\u548c\u6c34\u5408Na<sup>+<\/sup>\u79bb\u5b50\u6c34\u7ec4\u6210\u3002\u5728\u6790\u6c22\u53cd\u5e94(HER)\u7535\u4f4d\u4e0b\uff0c<strong><b>\u7531\u4e8e\u504f\u7f6e\u7535\u4f4d\u548cNa<\/b><\/strong><strong><sup><b>+<\/b><\/sup><\/strong><strong><b>\u79bb\u5b50\u7684\u534f\u540c\u4f5c\u7528<\/b><\/strong><strong><b>\uff0c\u89c2\u5bdf\u5230\u754c\u9762\u6c34\u5206\u5b50\u7ed3\u6784\u4ece\u968f\u673a\u5206\u5e03\u5230\u6709\u5e8f\u7ed3\u6784\u7684\u52a8\u6001\u53d8\u5316<\/b><\/strong>\u3002\u8fd9\u79cd\u7ed3\u6784\u6709\u5e8f\u7684\u754c\u9762\u6c34\u5206\u5b50\u4fc3\u8fdb\u4e86\u754c\u9762\u4e0a\u7684\u9ad8\u6548\u7535\u5b50\u8f6c\u79fb\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86HER\u901f\u7387\uff0c\u4e3a\u6307\u5bfc\u7eff\u8272\u5236\u6c22\u63d0\u4f9b\u65b0\u7684\u7406\u8bba\u9014\u5f84\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u53d1\u73b0\u7535\u89e3\u6db2\u548c\u7535\u6781\u8868\u9762\u4f1a\u5f71\u54cd\u754c\u9762\u6c34\u7684\u7ed3\u6784\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cIn situ Raman spectroscopy reveals the structure and dissociation of interfacial water\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-230397\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72471-1.png\" alt=\"\" width=\"741\" height=\"471\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72471-1.png 741w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72471-1-300x191.png 300w\" sizes=\"(max-width: 741px) 100vw, 741px\" \/>\u00a0<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong><b>\u56fe1. \u5728Pd(hkl)\u8868\u9762\u63a2\u6d4b\u754c\u9762\u6c34<\/b><\/strong><strong><b>\u5206\u5b50<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-230398\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72472-1.png\" alt=\"\" width=\"780\" height=\"490\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72472-1.png 780w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72472-1-300x188.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72472-1-768x482.png 768w\" sizes=\"(max-width: 780px) 100vw, 780px\" \/>\u00a0<\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>2<\/b><\/strong><strong><b>. \u754c\u9762\u6c34<\/b><\/strong><strong><b>\u5206\u5b50<\/b><\/strong><strong><b>\u7684\u62c9\u66fc\u5149\u8c31<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-230399\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72473-1.png\" alt=\"\" width=\"835\" height=\"536\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72473-1.png 835w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72473-1-300x193.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72473-1-768x493.png 768w\" sizes=\"(max-width: 835px) 100vw, 835px\" \/>\u00a0<\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>3<\/b><\/strong><strong><b>. <\/b><\/strong><strong><b>\u754c\u9762<\/b><\/strong><strong><b>\u6c34<\/b><\/strong><strong><b>\u5206\u5b50\u7684<\/b><\/strong><strong><b>\u89e3\u79bb<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-230400\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72474-1.png\" alt=\"\" width=\"699\" height=\"473\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72474-1.png 699w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72474-1-300x203.png 300w\" sizes=\"(max-width: 699px) 100vw, 699px\" \/>\u00a0<\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>4<\/b><\/strong><strong><b>. \u754c\u9762\u6c34<\/b><\/strong><strong><b>\u5206\u5b50<\/b><\/strong><strong><b>\u7684HER\u8c31\u548c\u62c9\u66fc\u5149\u8c31<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-230401\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72475-1.png\" alt=\"\" width=\"644\" height=\"482\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72475-1.png 644w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72475-1-300x225.png 300w\" sizes=\"(max-width: 644px) 100vw, 644px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a\u201cIn situ Raman spectroscopy reveals the structure and dissociation of interfacial water.\u201d Nature 600, 81\u201385 (2021). https:\/\/doi.org\/10.1038\/s41586-021-04068-z<\/p>\n<p>\u672c\u6587\u7531\u6e29\u534e\u4f9b\u7a3f\u3002<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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