{"id":230865,"date":"2021-12-19T06:47:52","date_gmt":"2021-12-18T22:47:52","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=230865"},"modified":"2021-12-18T20:48:07","modified_gmt":"2021-12-18T12:48:07","slug":"%e7%94%b5%e6%b1%a0%e9%a2%86%e5%9f%9f%e5%a4%a7%e7%89%9b%ef%bc%9a%e5%b4%94%e5%b1%b9%e3%80%81%e9%ba%a6%e7%ab%8b%e5%bc%ba%e3%80%81%e7%8e%8b%e6%98%a5%e7%94%9f%e3%80%81%e6%a5%bc%e9%9b%84%e6%96%87%e3%80%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=230865","title":{"rendered":"\u7535\u6c60\u9886\u57df\u5927\u725b\uff1a\u5d14\u5c79\u3001\u9ea6\u7acb\u5f3a\u3001\u738b\u6625\u751f\u3001\u697c\u96c4\u6587\u3001\u4e54\u4e16\u748b\u6700\u8fd1\u8fdb\u5c55"},"content":{"rendered":"

Science<\/strong>\uff1a\u6eb6\u5242\u5316\u9798\u5c42\u91cd\u7ec4\u8d4b\u4e88\u4e8c\u4ef7\u91d1\u5c5e\u7535\u6c60\u5feb\u901f\u7684\u754c\u9762\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66<\/strong><\/p>\n

\u53ef\u5145\u7535\u9541\u9499\u91d1\u5c5e\u7535\u6c60(RMBs\u548cRCBs)\u5177\u6709\u6781\u9ad8\u7684\u5730\u58f3\u4e30\u5ea6\u548c\u5bb9\u91cf\uff0c\u6709\u671b\u66ff\u4ee3\u9502\u79bb\u5b50\u7535\u6c60\u3002\u7136\u800c\uff0c\u5b83\u4eec\u53d7\u5230\u7f13\u6162\u7684\u52a8\u529b\u5b66\u548c\u5bc4\u751f\u53cd\u5e94\u7684\u56f0\u6270\u3002\u5728\u6b64\uff0c\u6765\u81ea\u7f8e\u56fd\u9a6c\u91cc\u5170\u5927\u5b66\u7684\u738b\u6625\u751f\u6559\u6388\u8054\u5408\u7f8e\u56fd\u9646\u519b\u4f5c\u6218\u80fd\u529b\u53d1\u5c55\u53f8\u4ee4\u90e8\u9646\u519b\u7814\u7a76\u5b9e\u9a8c\u5ba4Oleg Borodin \u7b49\u4eba\u53d1\u73b0\u4e86\u7532\u6c27\u57fa\u4e59\u57fa\u80fa\u87af\u5408\u5242\u5bb6\u65cf\uff0c\u901a\u8fc7\u6eb6\u5242\u9798\u91cd\u7ec4\uff0c\u6781\u5927\u5730\u4fc3\u8fdb\u4e86\u754c\u9762\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\uff0c\u5e76\u6291\u5236\u4e86\u9634\u6781\u548c\u91d1\u5c5e\u9633\u6781\u4e0a\u7684\u526f\u53cd\u5e94\u3002\u4ece\u800c\u5b9e\u73b0RMB\u548cRCB\u5168\u7535\u6c60\u7684\u7a33\u5b9a\u548c\u9ad8\u5ea6\u53ef\u9006\u5faa\u73af\uff0c\u80fd\u91cf\u5bc6\u5ea6\u5206\u522b\u4e3a412\u548c471\u74e6\u65f6\/\u5343\u514b\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u4e8c\u4ef7\u91d1\u5c5e\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u79cd\u901a\u7528\u7684\u7535\u89e3\u8d28\u8bbe\u8ba1\u7b56\u7565\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cSolvation sheath reorganization enables divalent metal batteries with fast interfacial charge transfer kinetics\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002DOI: 10.1126\/science.abg3954<\/p>\n

\u56fe1 \u4e0d\u540c\u7535\u89e3\u8d28\u4e2dMg\u7535\u9540\u548c\u6eb6\u51fa\u7684\u8fc7\u7535\u52bf\u548cCES<\/p>\n

\"\"<\/p>\n

AEnM<\/strong>\uff1a\u5b9a\u91cf\u548c\u6291\u5236\u8d28\u5b50\u63d2\u5c42\u4f7f\u9ad8\u538b\u950c\u79bb\u5b50\u7535\u6c60\u6210\u4e3a\u53ef\u80fd<\/strong><\/p>\n

\u53ef\u5145\u7535\u950c\u79bb\u5b50\u7535\u6c60(ZIBs)\u88ab\u5e7f\u6cdb\u8ba4\u4e3a\u662f\u6709\u524d\u666f\u7684\u5927\u89c4\u6a21\u50a8\u80fd\u5e94\u7528\u3002\u4e0e\u5927\u591a\u6570\u591a\u4ef7\u7535\u6c60\u7cfb\u7edf(\u57fa\u4e8eZn\u3001Mg\u3001Ca\u7b49)\u4e00\u6837\uff0cZIB\u5f00\u53d1\u7684\u8fdb\u4e00\u6b65\u8fdb\u5c55\u4f9d\u8d56\u4e8e\u53d1\u73b0\u548c\u8bbe\u8ba1\u80fd\u591f\u53ef\u9006\u63d2\u5165Zn2+<\/sup> \u7684\u65b0\u578b\u9634\u6781\u4e3b\u4f53\u3002\u5728\u6b64\uff0c\u7f8e\u56fd\u9a6c\u91cc\u5170\u5927\u5b66\u738b\u6625\u751f\u3001\u9646\u519b\u7814\u7a76\u5b9e\u9a8c\u5ba4\u8bb8\u5eb7\u53ca\u52a0\u62ff\u5927\u6ed1\u94c1\u5362\u5927\u5b66Linda F. Nazar\u7b49\u4eba\u91c7\u7528VPO4<\/sub>F\u4f5c\u4e3aZIB\u9634\u6781\uff0c\u63a2\u7d22\u968f\u540e\u7684\u63d2\u5c42\u673a\u5236\u4ee5\u53ca\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u754c\u9762\u52a8\u529b\u5b66\uff0c\u4ee5\u91cf\u5316\u9ad8\u6d53\u5ea6\u7535\u89e3\u8d28\u548c\/\u6216\u6c34-\u975e\u6c34\u6df7\u5408(HANEs)\u7535\u89e3\u8d28\u4e2d\u7684\u6c34\u52a8\u529b\u5b66\u3002\u4e0e\u5927\u591a\u6570\u6c27\u5316\u57fa\u6b63\u6781\u6750\u6599\u4e00\u6837\uff0c\u7531\u4e8e\u754c\u9762\u7684\u7f9f\u57fa\u5316\u6027\u8d28\uff0cZnx<\/sub>Hy<\/sub>VPO4<\/sub>F\u5728\u6c34\u4ecb\u8d28\u4e2d\u653e\u7535\u65f6\uff0c\u8d28\u5b50(H+<\/sup>)\u63d2\u5c42\u4e3b\u5bfc\u7740\u7535\u5316\u5b66\u6d3b\u6027\u3002\u8fd9\u79cdH+<\/sup>\u7535\u5316\u5b66\u964d\u4f4e\u4e86ZIB\u7684\u4f4e\u901f\u7387\u548c\/\u6216\u957f\u671f\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4ece\u800c\u6291\u5236\u4e86\u5b9e\u9645\u5e94\u7528\u7684\u5b9e\u73b0\u3002\u56e0\u6b64\uff0c\u8fd9\u9879\u7814\u7a76\u9996\u6b21\u8bc1\u660e\u4e86\u5404\u79cd\u7535\u89e3\u6db2\u4e2d\u6c34\u52a8\u529b\u5b66\u7684\u91cf\u5316\uff0c\u4f5c\u8005\u901a\u8fc7\u4e0d\u540c\u6bd4\u4f8b\u7684\u6c34\/\u975e\u6c34\u6eb6\u5242\u8bbe\u8ba1\u6210\u529f\u8c03\u8282\u4e86HANES\u4e2d\u7684Zn2+<\/sup>\/H+<\/sup>\u5171\u63d2\u5c42\uff0c\u8bbe\u8ba1\u51fa\u4e00\u79cd\u53ef\u589e\u5f3a\u6c34\u7cfb\u8d1f\u6781\u7a33\u5b9a\u6027\u5e76\u6291\u5236\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u6c34\/\u8d28\u5b50\u6d3b\u52a8\u7684\u7535\u89e3\u6db2\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cQuantifying and Suppressing Proton Intercalation to Enable High-Voltage Zn-Ion Batteries\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AEnM\u4e0a\u3002DOI: 10.1002\/aenm.202102016<\/p>\n

\u56fe2 VPO4<\/sub>F\u6b63\u6781\u6750\u6599\u7684\u7ed3\u6784\u548c\u5f62\u8c8c<\/p>\n

\"\"<\/p>\n

Nano Letters<\/strong>\uff1a\u4e0d\u6eb6\u4e8e\u7535\u89e3\u8d28\u7684\u53cc\u963b\u71c3\u6750\u6599\u7528\u4e8e\u534f\u540c\u63d0\u9ad8\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5b89\u5168\u6027<\/strong><\/p>\n

\u4e0e\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u5173\u7684\u5b89\u5168\u95ee\u9898\u662f\u4e3b\u8981\u5173\u6ce8\u7684\u95ee\u9898\uff0c\u7279\u522b\u662f\u968f\u7740\u5bf9\u66f4\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u5b58\u50a8\u8bbe\u5907\u7684\u9700\u6c42\u4e0d\u65ad\u589e\u957f\u3002\u5c3d\u7ba1\u5728\u7535\u89e3\u8d28\u4e2d\u6dfb\u52a0\u963b\u71c3\u5242\uff08FRs\uff09\u53ef\u4ee5\u51cf\u5c11\u706b\u707e\u5371\u9669\uff0c\u4f46\u8fd9\u9700\u8981\u5927\u91cf\u7684\u963b\u71c3\u5242\uff0c\u56e0\u800c\u4f1a\u4e25\u91cd\u964d\u4f4e\u7535\u6c60\u7684\u6027\u80fd\u3002\u5728\u6b64\uff0c\u65af\u5766\u798f\u5927\u5b66\u5d14\u5c79\u7b49\u4eba\u62a5\u9053\u4e86\u901a\u8fc7\u5728\u5546\u7528\u7535\u6c60\u9694\u819c\u4e0a\u6d82\u8986\u4e00\u79cd\u4e0d\u6eb6\u4e8e\u7535\u89e3\u8d28\u7684FR\u6765\u5e73\u8861\u963b\u71c3\u548c\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5f00\u53d1\u51fa\u4e00\u79cd\u5177\u6709\u76f8\u5f53\u9ad8\u7684FR\uff0c\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7684\u65b0\u578b\u590d\u5408\u9694\u819c\u3002\u901a\u8fc7\u53cc\u7ba1\u673a\u5236\u6574\u5408\u53cc\u6750\u6599\uff0c\u6240\u9700FR\u7684\u6570\u91cf\u53ef\u4ee5\u9650\u5236\u5728\u4e00\u4e2a\u5f88\u5c11\u5f71\u54cd\u7535\u5316\u5b66\u6027\u80fd\u7684\u8d85\u8584\u6d82\u5c42(4 \u03bcm)\u3002\u5728\u8f6f\u5305\u7535\u6c60\u6d4b\u8bd5\u4e2d\uff0c\u6240\u5f00\u53d1\u7684\u590d\u5408\u9694\u819c\u5177\u6709\u6bd4\u4f20\u7edf\u805a\u70ef\u70c3\u9694\u819c\u9ad8\u56db\u500d\u7684\u963b\u71c3\u6027\u3002\u6b64\u5916\uff0c\u8fd9\u79cd\u590d\u5408\u9694\u819c\u53ef\u4ee5\u5bb9\u6613\u5730\u5927\u89c4\u6a21\u5236\u9020\u4ee5\u7528\u4e8e\u5de5\u4e1a\u5e94\u7528\u3002\u7ec4\u88c5\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\uff082Ah\uff09\uff0c\u4ee5\u6f14\u793a\u590d\u5408\u9694\u819c\u7684\u7ed3\u57a2\u60c5\u51b5\uff0c\u5e76\u901a\u8fc7\u9489\u7a7f\u8bd5\u9a8c\u786e\u8ba4\u4e86\u5176\u4f18\u5f02\u7684\u5b89\u5168\u6027\u80fd\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cElectrolyte-Resistant Dual Materials for the Synergistic Safety Enhancement of Lithium-Ion Batteries\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nano Letters\u4e0a\u3002DOI: 10.1021\/acs.nanolett.0c04568<\/p>\n

\u56fe3 FR\u590d\u5408\u9694\u677f\u7684\u963b\u71c3\u6027\u80fd\u53ca\u6027\u80fd<\/p>\n

\"\"<\/p>\n

JACS<\/strong>\uff1a\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u5f3a\u5316\u5168\u56fa\u6001\u9502\u786b\u7535\u6c60<\/strong><\/p>\n

\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28(RMs)\u5728\u4e00\u4e9b\u57fa\u4e8e\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u7535\u5316\u5b66\u50a8\u80fd\u7cfb\u7edf\u4e2d\u8d77\u7740\u91cd\u8981\u7684\u4f5c\u7528\u3002\u7136\u800c\uff0c\u5728\u56fa\u6001\u7535\u6c60\u4e2d\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7684\u6982\u5ff5\u8fd8\u672a\u88ab\u63a2\u7d22\u3002\u5728\u6b64\uff0c\u65af\u5766\u798f\u5927\u5b66\u5d14\u5c79\u8054\u5408\u9c8d\u54f2\u5357\u6559\u6388\u7b49\u4eba\u9009\u62e9\u4e86\u4e00\u7ec4RM\u5019\u9009\u6750\u6599\uff0c\u5e76\u7814\u7a76\u4e86\u5b83\u4eec\u5728\u5168\u56fa\u6001\u9502\u7535\u6c60(ASSLSBs)\u4e2d\u7684\u884c\u4e3a\u548c\u4f5c\u7528\u3002\u53ef\u6eb6\u578b\u918c\u57faRM(AQT)\u8868\u73b0\u51fa\u6700\u6709\u5229\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u548c\u6700\u4f73\u7684\u6c27\u5316\u8fd8\u539f\u53ef\u9006\u6027\uff0c\u6709\u5229\u4e8e\u56fa\u4f53\u805a\u5408\u7269\u7535\u89e3\u8d28\u4e2dLi2<\/sub>S\u7684\u6c27\u5316\u3002\u56e0\u6b64\uff0c\u5177\u6709AQT\u7684Li2<\/sub>S\u9634\u6781\u5177\u6709\u660e\u663e\u7684\u80fd\u91cf\u52bf\u5792\u964d\u4f4e(\u5e73\u5747\u6c27\u5316\u7535\u4f4d2.4 V)\uff0c\u521d\u59cb\u5145\u7535\u6e29\u5ea6\u4e3a0.1\u2103\uff0c\u521d\u59cb\u5145\u7535\u6e29\u5ea6\u4e3a60\u2103\uff0c\u653e\u7535\u5bb9\u91cf\u4e3a1133 mAh gs<\/sub>\u22121<\/sup>\u3002\u5229\u7528Operato\u786bK\u8fb9X\u5c04\u7ebf\u5438\u6536\u5149\u8c31\uff0c\u76f4\u63a5\u8ddf\u8e2a\u4e86\u786b\u5728ASSLSBs\u4e2d\u7684\u5f62\u6001\uff0c\u8bc1\u660e\u4e86\u56fa\u4f53-\u591a\u786b\u5316\u7269-\u56fa\u4f53\u7684Li2<\/sub>S\u9634\u6781\u4e0eRMs\u7684\u53cd\u5e94\u4fc3\u8fdb\u4e86Li2<\/sub>S\u6c27\u5316\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5bf9\u4e8e\u88f8Li2<\/sub>S\u9634\u6781\uff0c\u56fa\u4f53-\u56fa\u4f53Li2<\/sub>S -\u786b\u5728\u7b2c\u4e00\u4e2a\u7535\u8377\u5faa\u73af\u4e2d\u76f4\u63a5\u8f6c\u6362\uff0c\u4ea7\u751f\u4e86\u8f83\u9ad8\u7684\u6fc0\u6d3b\u80fd\u91cf\u969c\u58c1(\u7535\u8377\u4e3a~ 4 V)\u548c\u8f83\u4f4e\u7684\u786b\u5229\u7528\u7387\u3002\u7531\u4e8e\u6709\u6548\u7684AQT\u589e\u5f3a\u7684Li-S\u53cd\u5e94\u52a8\u529b\u5b66\uff0cLi2<\/sub>S@AQT\u7535\u6c60\u5177\u6709\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027(150\u6b21\u5faa\u73af\u7684\u5e73\u5747\u5e93\u4ed1\u6548\u7387\u4e3a98.9%)\u548c\u901f\u7387\u80fd\u529b\u3002\u672c\u7814\u7a76\u901a\u8fc7\u8bbe\u8ba1\u6709\u6548\u7684\u786b\u5f62\u6001\u5f62\u6210\u9014\u5f84\uff0c\u63ed\u793a\u4e86\u786b\u5728ASSLSBs\u4e2d\u7684\u6f14\u5316\u8fc7\u7a0b\uff0c\u5b9e\u73b0\u4e86\u5feb\u901fLi-S\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cAll-Solid-State Lithium\u2212Sulfur Batteries Enhanced by Redox Mediators\u201d\u4e3a\u9898\u76ee \uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002DOI: 10.1021\/jacs.1c07754<\/p>\n

\u56fe4 \u5168\u56fa\u6001\u9502\u786b\u7535\u6c60(ASSLSBs)\u4e2d\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28(RMs)\u7684\u4f5c\u7528<\/p>\n

\"\"<\/p>\n

Angew.<\/strong>\uff1a\u94b4<\/strong>–<\/strong>\u9530\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\u5236\u5907\u7a7a\u5fc3\u7403\u7528\u4e8e\u9ad8\u6548\u6c34\u6eb6\u6db2\u950c\u79bb\u5b50\u7535\u6c60<\/strong><\/p>\n

\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269(Prussian blue analogs, PBAs)\u88ab\u8ba4\u4e3a\u662f\u53ef\u9760\u548c\u6709\u524d\u9014\u7684\u6c34\u6eb6\u6db2\u950c\u79bb\u5b50\u7535\u6c60(AZIBs)\u6b63\u6781\u6750\u6599\uff0c\u4f46\u7531\u4e8e\u79bb\u5b50\u63d2\u5165\/\u63d0\u53d6\u8fc7\u7a0b\u4e2d\u6d3b\u6027\u4f4d\u70b9\u4e0d\u8db3\u548c\u7ed3\u6784\u635f\u4f24\uff0c\u5176\u5bb9\u91cf\u4f4e\uff0c\u5faa\u73af\u7a33\u5b9a\u6027\u5dee\u3002\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u697c\u96c4\u6587\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u79cd\u6a21\u677f\u79bb\u5b50\u4ea4\u6362\u65b9\u6cd5\uff0c\u7528\u4e8e\u5408\u6210Co -\u53d6\u4ee3\u7684\u5bcc\u9530PBA\u7a7a\u5fc3\u7403(CoMn-PBA HSs)\u4f5c\u4e3a\u9634\u6781\u6750\u6599\u3002CoMn-PBA HSs\u5177\u6709\u7a7a\u5fc3\u7ed3\u6784\u3001\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\u3001\u5feb\u901f\u7684Zn2+<\/sup>\u79bb\u5b50\u6269\u6563\u548c\u90e8\u5206Co\u53d6\u4ee3\u7b49\u4f18\u70b9\uff0c\u5177\u6709\u9ad8\u5bb9\u91cf\u3001\u826f\u597d\u7684\u901f\u7387\u80fd\u529b\u548c\u5ef6\u957f\u5faa\u73af\u5bff\u547d\u7b49\u4f18\u70b9\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cConstruction of Co\u2013Mn Prussian Blue Analog Hollow Spheres for Efficient Aqueous Zn-ion Batteries\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002DOI: 10.1002\/anie.202107697<\/p>\n

\u56fe5 CoMn-PBA HSs\u7684\u5408\u6210\u5de5\u827a\u53ca\u8868\u5f81<\/p>\n

\"\"<\/p>\n

Science Advances<\/strong>\uff1a\u94f6\u7eb3\u7c73\u7c92\u5b50\u5d4c\u5165\u6c2e\u63ba\u6742\u78b3\u5927\u5b54\u7ea4\u7ef4\u5236\u5907\u9ad8\u7a33\u5b9a\u7684\u91d1\u5c5e\u9502\u9633\u6781<\/strong><\/p>\n

\u91d1\u5c5e\u9502\u88ab\u8ba4\u4e3a\u662f\u672a\u6765\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u9502\u7535\u6c60\u7684\u7406\u60f3\u9633\u6781\u5019\u9009\u6750\u6599\u3002\u5728\u6b64\uff0c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u697c\u96c4\u6587\u7b49\u4eba\u62a5\u9053\u4e86\u5f00\u53d1\u4e86\u4e00\u79cd\u4e09\u7ef4\uff083D\uff09\u6742\u5316\u4e3b\u4f53\uff08Ag@CMFs\uff09\uff0c\u5176\u7531Ag\u7eb3\u7c73\u9897\u7c92\u5d4c\u5165\u7684\u6c2e\u63ba\u6742\u78b3\u5927\u5b54\u7ea4\u7ef4\u7ec4\u6210\uff0c\u5177\u6709\u9009\u62e9\u6027Li\u6210\u6838\u548c\u9776\u5411\u6c89\u79ef\u7684\u529f\u80fd\u30023D\u5927\u5b54\u9aa8\u67b6\u53ef\u4ee5\u901a\u8fc7\u5728\u57fa\u4f53\u4e2d\u6355\u83b7Li\u91d1\u5c5e\u5e76\u964d\u4f4e\u5c40\u90e8\u7535\u6d41\u5bc6\u5ea6\u6765\u6291\u5236Li\u679d\u6676\u7684\u5f62\u6210\uff0c\u4eb2Li\u7684\u6c2e\u63ba\u6742\u78b3\u7531\u4e8e\u6210\u6838\u52bf\u5792\u5c0f\u800c\u6210\u4e3a\u4e86\u5747\u8d28\u6210\u6838\u4f4d\u70b9\uff0c\u800cAg\u7eb3\u7c73\u9897\u7c92\u5219\u901a\u8fc7\u53ef\u9006\u7684\u56fa\u6eb6\u4f53\u57fa\u5408\u91d1\u5316\u53cd\u5e94\u6539\u5584Li\u7684\u6210\u6838\u548c\u751f\u957f\u884c\u4e3a\u3002\u56e0\u6b64\uff0cAg@CMF\u590d\u5408\u6750\u6599\u80fd\u591f\u5b9e\u73b0\u65e0\u679d\u6676\u7535\u9540\/\u5265\u79bb\u884c\u4e3a\uff0c\u5e76\u5177\u6709500\u6b21\u4ee5\u4e0a\u7684\u9ad8\u5e93\u4ed1\u6548\u7387\u3002\u5f53\u8be5\u9633\u6781\u4e0e\u5546\u54c1\u5316\u7684LiFePO4<\/sub>\u9634\u6781\u8026\u5408\u65f6\uff0c\u7ec4\u88c5\u7684\u5168\u7535\u6c60\u8868\u73b0\u51fa\u9ad8\u901f\u7387\u80fd\u529b\u548c\u7a33\u5b9a\u7684\u5faa\u73af\u5bff\u547d\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cA highly stable lithium metal anode enabled by Ag nanoparticle\u2013embedded nitrogen-doped carbon macroporous fibers\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Science Advances\u4e0a\u3002DOI: 10.1126\/sciadv.abg3626<\/p>\n

\u56fe6 Ag-Li\u4e8c\u5143\u76f8\u56fe\u548cLi\u6c89\u79ef\u884c\u4e3a\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

JACS<\/strong>\uff1a\u539f\u5b50\u94b4\u548c\u5421\u5576\u6c2e\u534f\u540c\u50ac\u5316\u94be<\/strong>\u2212<\/strong>\u786b\u7535\u6c60<\/strong>K2<\/sub>S<\/strong>\u6c27\u5316<\/strong><\/p>\n

\u94be\u786b\u7535\u6c60\u5177\u6709\u8f83\u9ad8\u7684\u7406\u8bba\u91cd\u529b\u80fd\u91cf\u5bc6\u5ea6\u548c\u8f83\u4f4e\u7684\u6210\u672c\uff0c\u6709\u671b\u6210\u4e3a\u4e0b\u4e00\u4ee3\u7535\u6c60\u3002\u7136\u800c\uff0c\u91cd\u8981\u7684\u969c\u788d\u662f\u7f13\u6162\u7684K2<\/sub>S\u6c27\u5316\u52a8\u529b\u5b66\u548c\u7f3a\u4e4f\u5bf9K2<\/sub>S\u6c27\u5316\u7684\u539f\u5b50\u6c34\u5e73\u7684\u7406\u89e3\u3002\u5728\u6b64\uff0c\u6fb3\u5927\u5229\u4e9a\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u4e54\u4e16\u748b\u8054\u5408\u6e05\u534e\u5927\u5b66\u738b\u6d77\u8f89\u7b49\u4eba\u9996\u6b21\u62a5\u9053\u4e86\u7528Co\u5355\u539f\u5b50\u56fa\u5b9a\u5728\u6c2e\u63ba\u6742\u78b3\u4e0a\u50ac\u5316K2<\/sub>S\u5728\u786b\u5bbf\u4e3b\u4e0a\u7684\u6c27\u5316\u3002\u7ed3\u5408\u5149\u8c31\u8868\u5f81\u3001\u7535\u5316\u5b66\u8bc4\u4ef7\u548c\u7406\u8bba\u8ba1\u7b97\uff0c\u53d1\u73b0\u52a8\u6001Co-S\u548cN-K\u76f8\u4e92\u4f5c\u7528\u5bf9K2<\/sub>S\u6c27\u5316\u5177\u6709\u534f\u540c\u6548\u5e94\u3002\u57281\u548c2 C\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5408\u6210\u7684\u94be\u786b\u7535\u6c60\u5177\u6709773\u548c535 mAh g\u22121<\/sup>\u7684\u9ad8\u5bb9\u91cf\u8fd9\u4e9b\u53d1\u73b0\u4e3a\u9ad8\u6548\u786b\u8f7d\u4f53\u7684\u5408\u7406\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u539f\u5b50\u5c3a\u5ea6\u4e0a\u7684\u89c1\u89e3\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cCatalytic Oxidation of K2<\/sub>S via Atomic Co and Pyridinic N Synergy in Potassium\u2212Sulfur Batteries\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002DOI: 10.1021\/jacs.1c06255<\/p>\n

\u56fe7 (a) K\u2212S\u7535\u6c60\u7684\u5145\u653e\u7535\u539f\u7406\u56fe (b) S\/SA-NC\u7535\u6781\u7684\u6052\u6d41\u653e\u7535\u66f2\u7ebf\u548c\u76f8\u5e94\u7684\u539f\u4f4d\u540c\u6b65\u52a0\u901f\u5668XRD\u8c31\u56fe (c)\u653e\u75350.5 V\u548c\u5145\u75353.0 V\u4e0bS\/SA-NC\u7684XPS\u5149\u8c31 (d) 800 fs AIMD\u8f68\u8ff9\u7ed3\u679c\u4e2dS\u2212K\u952e\u957f\u5ea6\u7684RDF<\/p>\n

\"\"<\/p>\n

Nature Commun.<\/strong>\uff1a\u9ad8\u5de5\u4f5c\u7535\u538b<\/strong>Al -S<\/strong>\u7535\u6c60\u4e2d\u786b\u5728\u79bb\u5b50\u6db2\u4f53\u4e2d\u7684\u53ef\u9006\u7535\u5316\u5b66\u6c27\u5316<\/strong><\/p>\n

\u786b\u662f\u91d1\u5c5e\u786b\u7535\u6c60\u4e2d\u91cd\u8981\u7684\u7535\u6781\u6750\u6599\u3002\u5b83\u901a\u5e38\u4e0e\u91d1\u5c5e\u9633\u6781\u8026\u5408\uff0c\u5e76\u7ecf\u8fc7\u7535\u5316\u5b66\u8fd8\u539f\u5f62\u6210\u91d1\u5c5e\u786b\u5316\u7269\u3002\u5728\u6b64\uff0c\u6fb3\u5927\u5229\u4e9a\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u4e54\u4e16\u748b\u7b49\u4eba\u9996\u6b21\u6f14\u793a\u4e86AlCl3<\/sub>\/\u5c3f\u7d20\u79bb\u5b50\u6db2\u4f53\u4e2d\u786b\u7684\u53ef\u9006\u6c27\u5316\u8fc7\u7a0b\uff0c\u786b\u88abAlCl4<\/sub>\u2212<\/sup>\u7535\u5316\u5b66\u6c27\u5316\u5f62\u6210AlSCl7<\/sub>\u3002\u786b\u6c27\u5316\u5177\u6709:1)\u9ad8\u5ea6\u53ef\u9006\uff0c\u6c27\u5316\u6548\u7387\u7ea6\u4e3a94%\uff1b2)\u53ef\u5728\u5e7f\u6cdb\u7684\u9ad8\u7535\u4f4d\u8303\u56f4\u5185\u5de5\u4f5c\u3002\u7ed3\u679c\u8868\u660e\uff0c\u786b\u6c27\u5316\u94dd\u2212\u786b\u7535\u6c60\u53ef\u4ee5\u7a33\u5b9a\u5730\u5728~1.8 V\u5de6\u53f3\u5faa\u73af\uff0c\u8fd9\u662f\u94dd\u2212\u786b\u7535\u6c60\u7684\u6700\u9ad8\u5de5\u4f5c\u7535\u538b\u3002\u786b\u6c27\u5316\u8fc7\u7a0b\u7684\u7814\u7a76\u6709\u5229\u4e8e\u5bf9\u786b\u5316\u5b66\u7684\u7406\u89e3\uff0c\u5c06\u786b\u6c27\u5316\u4f5c\u4e3a\u5b9e\u73b0\u91d1\u5c5e-\u786b\u7535\u6c60\u9ad8\u538b\u5e94\u7528\u7684\u65b0\u9014\u5f84\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cReversible electrochemical oxidation of sulfur in ionic liquid for high-voltage Al\u2212S batteries\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Commun.\u4e0a\u3002DOI: 10.1038\/s41467-021-26056-7<\/p>\n

\u56fe8 \u786b\u5728\u79bb\u5b50\u6db2\u4f53\u4e2d\u7684\u7535\u5316\u5b66\u6c27\u5316\u548c\u8fd8\u539f\u8fc7\u7a0b<\/p>\n

\"\"<\/p>\n

EEM<\/strong>\uff1a\u6fc0\u6d3b\u7845\u9178\u94b4\u6c22\u6c27\u5316\u7269\u7684\u60f0\u6027\u4f4d\u70b9\u901a\u8fc7\u539f\u5b50\u63ba\u6742\u7684\u6c27\u6790\u51fa<\/strong><\/p>\n

\u91d1\u5c5e\u7845\u9178\u76d0\u6c22\u6c27\u5316\u7269\u5df2\u88ab\u516c\u8ba4\u4e3a\u9ad8\u6548\u6790\u6c27\u53cd\u5e94(OER)\u7535\u50ac\u5316\u5242\uff0c\u4f46\u5176\u5185\u5728\u6d3b\u6027\u7684\u786e\u5b9a\u4ecd\u662f\u4e00\u4e2a\u56f0\u60d1\u3002\u5728\u6b64\uff0c\u4ed9\u6e56\u5148\u8fdb\u80fd\u6e90\u79d1\u6280\u5b9e\u9a8c\u5ba4\u9ea6\u7acb\u5f3a\u7b49\u4eba\u5c06Fe\u5df2\u88ab\u7eb3\u5165\u94b4\u7845\u9178\u76d0\u6c22\u6c27\u5316\u7269\u7eb3\u7c73\u7247\uff0c\u7ed3\u679c\u6750\u6599\u8fbe\u5230\u4e00\u4e2a\u7ade\u4e89\u7684OER\u50ac\u5316\u6d3b\u6027\u3002\u7ed3\u679c\u8868\u660e\uff0c\u63ba\u6742\u72b6\u6001\u5bf9\u7535\u8f93\u8fd0\u6027\u80fd\u6709\u660e\u663e\u5f71\u54cd\u3002\u5177\u4f53\u6765\u8bf4\uff0c\u662f\u9ad8\u5ea6\u5206\u6563\u7684\u94c1\u539f\u5b50(\u4f4e\u6d53\u5ea6)Fe\u63ba\u6742\u5f15\u8d77Co\u539f\u5b50\u7684\u5c11\u91cf\u7535\u5b50\u8f6c\u79fb\uff0c\u800c\u4e00\u7cfb\u5217Fe(\u9ad8\u6d53\u5ea6Fe\u63ba\u6742)\u5438\u5f15\u5927\u91cf\u7535\u5b50\u3002\u901a\u8fc7\u5728 Fe\u63ba\u6742\u540e\uff0c\u90e8\u5206\u76f8\u5bf9\u60f0\u6027\u7684Co\u4f4d\u70b9\u88ab\u94c1\u539f\u5b50\u5206\u6563\u6fc0\u6d3b\uff0c\u5177\u6709\u6700\u4f73\u7684\u91d1\u5c5e\u4e09\u7ef4\u7535\u5b50\u5360\u4f4d\u548c\u5bf9\u6c27\u7684\u5438\u9644\u80fd\u529b\u4e2d\u95f4\u4f53\u3002\u5f15\u5165\u7684Co-O-Fe\u5355\u5143\u5f15\u53d1\u4e86\u03a0-donation\u6548\u5e94\uff0c\u51cf\u5c11\u4e86\u03a0*\u53cd\u952e\u8f68\u9053\u7684\u7535\u5b50\u6570\uff0c\u63d0\u9ad8\u4e86Fe-O\u7684\u5171\u4ef7\u6027\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u8be5\u6837\u54c1\u7684\u8fc7\u7535\u4f4d\u4e3a293 mV\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a10 mA cm-2<\/sup>\u3002\u8fd9\u9879\u5de5\u4f5c\u9610\u660e\u4e86\u539f\u5b50\u5206\u6563\u63ba\u6742\u6001\u7684\u4f18\u8d8a\u6027\uff0c\u8fd9\u5bf9\u63ba\u6742\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u5177\u6709\u6839\u672c\u6027\u7684\u610f\u4e49\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cActivating Inert Sites in Cobalt Silicate Hydroxides for Oxygen Evolution through Atomically Doping\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728EEM\u4e0a\u3002DOI: 10.1002\/eem2.12219<\/p>\n

\u56fe9 \u00a0FCSHNs-6\u7ed3\u6784\u4e0e\u8868\u5f81<\/p>\n

\"\"<\/p>\n

EES<\/strong>\uff1a\u6c34\u5206\u5b50\u5728\u6c34\u950c\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u4f5c\u7528<\/strong>:<\/strong>\u4ece\u7535\u89e3\u8d28\u5230\u7535\u6781\u6750\u6599<\/strong><\/p>\n

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\u56fe10 \u6c34\u5728AZIB\u4e2d\u7684\u4f18\u7f3a\u70b9\u53ca\u5f71\u54cd\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u6587\u4e2d\u6240\u8ff0\u5982\u6709\u4e0d\u59a5\u4e4b\u5904\uff0c\u6b22\u8fce\u8bc4\u8bba\u533a\u7559\u8a00~<\/p>\n

\u672c\u6587\u7531Junas\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

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