{"id":231190,"date":"2021-12-27T06:24:56","date_gmt":"2021-12-26T22:24:56","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=231190"},"modified":"2021-12-26T19:25:18","modified_gmt":"2021-12-26T11:25:18","slug":"%e4%bc%97%e9%99%a2%e5%a3%ab%e7%bb%a7%e7%bb%ad%e4%b8%ba%e6%96%b0%e8%83%bd%e6%ba%90%e9%a2%86%e5%9f%9f%e6%b7%bb%e7%a0%96%e5%8a%a0%e7%93%a6%ef%bc%8c%e4%b8%94%e7%9c%8b%e9%99%88%e7%ab%8b","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=231190","title":{"rendered":"\u4f17\u9662\u58eb\u7ee7\u7eed\u4e3a\u65b0\u80fd\u6e90\u9886\u57df\u201c\u6dfb\u7816\u52a0\u74e6\u201d\uff0c\u4e14\u770b\u9648\u7acb\u6cc9\u3001\u94b1\u9038\u6cf0\u3001\u5b59\u4e16\u521a\u5728\u8be5\u9886\u57df\u7684\u6700\u65b0\u6210\u679c"},"content":{"rendered":"

\u9648\u7acb\u6cc9<\/strong><\/p>\n

\u5728\u4e2d\u56fd\u7387\u5148\u5f00\u5c55\u9502\u7535\u6c60\u53ca\u76f8\u5173\u6750\u6599\u7814\u7a76\u3002\u5728\u56fd\u5185\u9996\u5148\u7814\u5236\u6210\u529f\u9502\u79bb\u5b50\u7535\u6c60\u3002\u89e3\u51b3\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u89c4\u6a21\u5316\u751f\u4ea7\u7684\u79d1\u5b66\u6280\u672f\u4e0e\u5de5\u7a0b\u95ee\u9898\uff0c\u5b9e\u73b0\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u7684\u4ea7\u4e1a\u5316\u30022001\u5e74\u5f53\u9009\u4e3a\u4e2d\u56fd\u5de5\u7a0b\u9662\u9662\u58eb\u3002<\/p>\n

1.Advanced Energy Materials<\/strong>\uff1a\u6c34\u7a33\u5b9a\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u819c\u53ef\u76f4\u63a5\u5e94\u7528\u4e8e\u7531\u8d85\u758f\u6c34\u9502\u79bb\u5b50\u5bfc\u7535\u4fdd\u62a4\u5c42\u5b9e\u73b0\u7684\u5168\u56fa\u6001\u7535\u6c60<\/strong><\/p>\n

\"\"<\/p>\n

\u5168\u56fa\u6001\u7535\u6c60\uff08ASSB\uff09\u5df2\u88ab\u516c\u8ba4\u4e3a\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u529f\u7387\u5bc6\u5ea6\u548c\u5b89\u5168\u6027\u7684\u4e0b\u4e00\u4ee3\u50a8\u80fd\u6280\u672f\u3002\u5728\u5b9e\u73b0ASSBs\u7684\u6240\u6709\u56fa\u4f53\u7535\u89e3\u8d28\uff08SEs\uff09\u4e2d\uff0c\u786b\u5316\u7269\u4ee3\u8868\u4e86\u4e00\u79cd\u6700\u6709\u524d\u9014\u7684\u6280\u672f\u8def\u7ebf\uff0c\u56e0\u4e3a\u5b83\u4eec\u5177\u6709\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u7406\u60f3\u7684\u673a\u68b0\u53d8\u5f62\u80fd\u529b\u3002\u7136\u800c\uff0c\u5927\u591a\u6570\u786b\u5316\u7269SEs\u672c\u8d28\u4e0a\u662f\u4e0d\u7a33\u5b9a\u7684\uff0c\u4f1a\u4e0e\u7a7a\u6c14\/\u6c34\u5206\/\u6c34\u53d1\u751f\u53cd\u5e94\uff0c\u91ca\u653e\u51fa\u6709\u6bd2\u7684H2<\/sub>S\uff0c\u5176\u7ed3\u6784\u5b8c\u5168\u53d7\u635f\uff0cLi+<\/sup>\u7535\u5bfc\u7387\u964d\u4f4e\u3002\u8fd9\u6781\u5927\u5730\u9650\u5236\u4e86\u786b\u5316\u7269SEs\u5728ASSBs\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\uff0c\u5bf9\u751f\u4ea7\u3001\u50a8\u5b58\u3001\u8fd0\u8f93\u3001\u7535\u6c60\u7ec4\u88c5\u7b49\u8fc7\u7a0b\u4e2d\u7684\u60f0\u6027\u6c14\u4f53\u4fdd\u62a4\u63d0\u51fa\u4e86\u6781\u9ad8\u7684\u6210\u672c\u548c\u82db\u523b\u7684\u8981\u6c42\u3002<\/p>\n

\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\uff0c\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u79cd\u9002\u7528\u4e8e\u6240\u6709\u7c7b\u578b\u786b\u5316\u7269SEs\u7684\u901a\u7528\u65b9\u6cd5\u6765\u5b9e\u73b0\u6c34\u7a33\u5b9a\u786b\u5316\u7269SE\u819c\uff0c\u901a\u8fc7\u55b7\u6d82Li1.4<\/sub>Al0.4<\/sub>Ti1.6<\/sub>(PO4<\/sub>)3<\/sub>\u7684Li+<\/sup>\u5bfc\u7535\u8d85\u758f\u6c34\u4fdd\u62a4\u5c42(LATP) \u7eb3\u7c73\u7c92\u5b50\u548c\u6c1f\u5316\u805a\u7845\u6c27\u70f7(F-POS)\u901a\u8fc7\u539f\u7845\u9178\u56db\u4e59\u916f\u548c1H ,1H ,2H ,2H-\u5168\u6c1f\u7678\u57fa\u4e09\u4e59\u6c27\u57fa\u7845\u70f7\u5206\u5b50\u7684\u6c34\u89e3\u548c\u7f29\u5408\u3002F-POS@LATP \u6d82\u5c42\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u8d85\u758f\u6c34\u6027\uff08\u6c34\u9759\u6001\u63a5\u89e6\u89d2>160\u00b0\uff09\uff0c\u4ee5\u62b5\u6297\u6781\u7aef\u66b4\u9732\uff08\u76f4\u63a5\u6c34\u55b7\u5c04\uff09\uff0c\u56e0\u4e3a\u5b83\u5177\u6709\u5fae\/\u7eb3\u7c73\u7ea7\u7c97\u7cd9\u5ea6\u548c\u4f4e\u8868\u9762\u80fd\u3002\u6b64\u5916\uff0c\u4f7f\u7528\u66b4\u9732\u4e8e\u6781\u7aef\u6761\u4ef6\u7684\u6539\u6027Li6<\/sub>PS5<\/sub>Cl\u819c\u7684 ASSB\u8868\u73b0\u51fa147.3mAh g-1<\/sup>\u7684\u53ef\u9006\u5bb9\u91cf\uff0c\u4e0e\u4f7f\u7528\u539f\u59cb\u786b\u5316\u7269\u819c\u7684 ASSB\u76f8\u5f53\u3002\u8d85\u758f\u6c34\u7684Li+<\/sup>-\u5bfc\u7535\u5c42\u88ab\u8bc1\u660e\u662f\u786b\u5316\u7269\u819c\u7684\u6709\u6548\u4fdd\u62a4\u65b9\u6cd5\uff0c\u4f7f\u5b83\u4eec\u5728\u6781\u7aef\u6c34\u66b4\u9732\u6761\u4ef6\u4e0b\u4fdd\u6301\u7a33\u5b9a\u548c\u529f\u80fd\uff0c\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u65b9\u6cd5\u6765\u4fdd\u62a4\u6240\u6709\u7c7b\u578b\u7684\u786b\u5316\u7269 SE \u548c\u5176\u4ed6\u7a7a\u6c14\/\u6c34\u5206\/\u6c34\u654f\u611f\u6750\u6599\uff0c\u800c\u4e0d\u4f1a\u727a\u7272\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

2.Materials Today Physics<\/strong>\uff1a\u5c42\u72b6\u7ed3\u6784<\/strong>Li2<\/sub>MoO3<\/sub><\/strong>\u7684\u9633\u79bb\u5b50\u65e0\u5e8f\u8c03\u8282\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\u968f\u7740\u7535\u52a8\u6c7d\u8f66\u548c\u50a8\u80fd\u7cfb\u7edf\u9700\u6c42\u7684\u5feb\u901f\u589e\u957f\uff0c\u8feb\u5207\u9700\u8981\u5177\u6709\u9ad8\u6bd4\u5bb9\u91cf\u548c\u957f\u5faa\u73af\u5bff\u547d\u7684\u9502\u79bb\u5b50\u7535\u6c60\u3002\u5177\u6709\u9ad8\u53ef\u9006\u5bb9\u91cf\u548c\u9ad8\u5de5\u4f5c\u7535\u4f4d\u7684\u5bcc\u9502\u5c42\u72b6\u6c27\u5316\u7269\u53ca\u5176\u884d\u751f\u7269 Li1+x<\/sub>TM1-x<\/sub>O2<\/sub>\uff08x > 0\u548cTM=\u8fc7\u6e21\u91d1\u5c5e\uff09\u88ab\u5f3a\u70c8\u8ba4\u4e3a\u662f\u6709\u524d\u9014\u7684\u9502\u79bb\u5b50\u6b63\u6781\u6750\u6599\u7535\u6c60\u3002\u7136\u800c\uff0c\u521d\u59cb\u5faa\u73af\u5e93\u4ed1\u6548\u7387\u4f4e\uff0c\u5faa\u73af\u8fc7\u7a0b\u4e2d\u5bb9\u91cf\u548c\u653e\u7535\u7535\u4f4d\u4e0d\u65ad\u4e0b\u964d\uff0c\u500d\u7387\u80fd\u529b\u5dee\u7b49\u4e00\u7cfb\u5217\u95ee\u9898\uff0c\u5fc5\u987b\u5728\u8fd9\u4e9b\u6750\u6599\u7684\u5546\u4e1a\u5e94\u7528\u4e4b\u524d\u5f97\u5230\u5f88\u597d\u7684\u89e3\u51b3\u3002<\/p>\n

\u5728\u6b64\uff0c\u9009\u62e9Li2<\/sub>MoO3<\/sub>\u4f5c\u4e3a\u5bcc\u9502\u5c42\u72b6\u6750\u6599\u7684\u539f\u578b\uff0c\u4ee5\u4e86\u89e3\u9633\u79bb\u5b50\u65e0\u5e8f\u5bf9\u8131\u9502\u7684\u5f71\u54cd\u3002\u5728\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT) \u8ba1\u7b97\u548c\u6027\u80fd\u8868\u5f81\u7684\u57fa\u7840\u4e0a\uff0c\u9610\u660e\u4e86Li2<\/sub>MoO3<\/sub>\u7684\u5c40\u90e8\u65e0\u5e8f\u7ed3\u6784\u8c03\u8282\u4ece\u4e0d\u540c\u4f4d\u70b9\u63d0\u53d6\u9502\u7684\u987a\u5e8f\uff0c\u8fd9\u4f1a\u5f71\u54cd\u6750\u6599\u7684\u6027\u8d28\uff0c\u5982\u5bb9\u91cf\u3001\u7535\u8377\u8865\u507f\u548c\u5bfc\u7535\u6027\u3002\u8fd9\u4e9b\u53d1\u73b0\u4e3a\u7406\u89e3\u9502\u79bb\u5b50\u7535\u6c60\u5bcc\u9502\u5c42\u72b6\u6c27\u5316\u7269\u7684\u6027\u80fd\u8870\u51cf\u548c\u7ed3\u6784\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u6df1\u523b\u7684\u89c1\u89e3\u3002<\/p>\n

3.Advanced Functional Materials<\/strong>\uff1a\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u548c\u65e0\u679d\u6676\u6db2\u6001\u9502\u9633\u6781\u5b9e\u73b0\u9ad8\u7535\u6d41\u5bc6\u5ea6\u548c\u957f\u5faa\u73af\u5bff\u547d<\/strong><\/p>\n

\"\"<\/p>\n

\u9502\u91d1\u5c5e\u662f\u7406\u60f3\u7684\u9633\u6781\u5019\u9009\u7269\uff0c\u4f46\u9762\u4e34\u7740\u5de8\u5927\u7684\u6311\u6218\uff0c\u5305\u62ec\u6db2\u4f53\u6709\u673a\u7535\u89e3\u8d28\u4e2d\u7684\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\u5dee\u4ee5\u53ca\u8fde\u7eed\u7535\u9540\/\u5265\u79bb\u8fc7\u7a0b\u4e2d\u7684\u679d\u6676\u6210\u6838\/\u751f\u957f\u3002<\/p>\n

\u4e3a\u4e86\u89e3\u51b3\u4e0a\u9762\u5217\u51fa\u7684\u56f0\u96be\uff0c\u8fd9\u91cc\u63d0\u51fa\u4e86\u4e00\u79cd\u7ed3\u5408\u6db2\u4f53\u9502\u6eb6\u6db2\u9633\u6781\u3001\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u548c\u754c\u9762\u4fdd\u62a4\u5c42\u7684\u7535\u6c60\u914d\u7f6e\uff0c\u4ee5\u9632\u6b62\u4e24\u79cd\u7ec4\u5206\u4e4b\u95f4\u53d1\u751f\u754c\u9762\u53cd\u5e94\u3002\u8fd9\u79cd\u914d\u7f6e\u7ed3\u5408\u4e86\u6db2\u4f53-\u9502-\u6eb6\u6db2\u9633\u6781\uff08\u6eb6\u89e3\u9502\u4ee5\u57fa\u672c\u4e0a\u9632\u6b62\u9502\u6210\u6838\uff09\u548c\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\uff08\u6240\u6709\u56fa\u4f53\u7535\u89e3\u8d28\u4e2d\u6700\u9ad8\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u7406\u60f3\u7684\u673a\u68b0\u5ef6\u5c55\u6027\uff0c\u53ea\u9700\u51b7\u538b\u5373\u53ef\u5b9e\u73b0\u5b8c\u5168\u81f4\u5bc6\u5c42\uff09\u7684\u4f18\u70b9\uff0c\u56e0\u6b64\u521b\u7eaa\u5f55\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\uff0817.78 mA cm-2<\/sup> ) \u548c\u957f\u5faa\u73af\u5bff\u547d\uff08\u8fd1 3000\u5c0f\u65f6\uff09\u3002\u540c\u65f6\uff0c\u7cfb\u7edf\u5730\u7814\u7a76\u4e86\u9502\u91d1\u5c5e\u5728\u6db2\u6001\u9502\u8d1f\u6781\u4e2d\u7684\u6eb6\u89e3\u5ea6\u548c\u6db2\u6001\u9502\u8d1f\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4ee5\u627e\u5230\u5ba4\u6e29\u7535\u5bfc\u7387\u6700\u9ad8\uff0812.2 mS cm-1<\/sup>\uff09\u7684\u6700\u5408\u9002\u7684\u6db2\u6001\u9502\u8d1f\u6781\u6d53\u5ea6\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5b9e\u73b0\u9ad8\u6bd4\u5bb9\u91cf\u3001\u9ad8\u80fd\u91cf\/\u529f\u7387\u5bc6\u5ea6\u548c\u957f\u5faa\u73af\u5bff\u547d\u7684\u4e8c\u6b21\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u524d\u666f\u7684\u65b9\u6cd5\u548c\u7535\u6c60\u914d\u7f6e\u3002<\/p>\n

\u94b1\u9038\u6cf0<\/strong><\/p>\n

\u65e0\u673a\u5316\u5b66\u5bb6\u3002\u4e3b\u8981\u4ece\u4e8b\u4e3b\u8981\u4ece\u4e8b\u7eb3\u7c73\u6750\u6599\u5316\u5b66\u5236\u5907\u548c\u8d85\u5bfc\u6750\u6599\u5236\u5907\u65b9\u9762\u7684\u7814\u7a76\u30021997\u5e74\u5f53\u9009\u4e3a\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u3002<\/p>\n

4.Journal of Energy Chemistry\uff1a\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u5148\u8fdb\u8d1f\u6781\u7684\u6c2e\u6c1f\u5171\u63ba\u6742\u4e8c\u6c27\u5316\u949b\/\u78b3\u5fae\u7403\uff1a\u9ad8\u4f53\u79ef\u5bb9\u91cf\u3001\u4f18\u5f02\u7684\u529f\u7387\u5bc6\u5ea6\u548c\u5927\u9762\u79ef\u5bb9\u91cf<\/p>\n

\"\"<\/p>\n

\u5feb\u901f\u5145\u7535\u548c\u9ad8\u5bb9\u91cf\u662f\u94a0\u79bb\u5b50\u7535\u6c60 (SIB) \u7684\u4e24\u4e2a\u5173\u952e\u9700\u6c42\u3002\u5c3d\u7ba1\u7eb3\u7c73\u7ed3\u6784\u6750\u6599\u5177\u6709\u51fa\u8272\u7684\u500d\u7387\u6027\u80fd\uff0c\u4f46\u5b83\u4eec\u7684\u632f\u5b9e\u5bc6\u5ea6\u4f4e\u548c\u4f53\u79ef\u5bb9\u91cf\u5c0f\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u540c\u65f6\u5b9e\u73b0\u5927\u4f53\u79ef\u5bb9\u91cf\u548c\u9ad8\u632f\u5b9e\u5bc6\u5ea6\u662f\u975e\u5e38\u5177\u6709\u6311\u6218\u6027\u7684\u3002<\/p>\n

\u5728\u8fd9\u91cc\uff0c\u5408\u6210\u4e86N\/F\u5171\u63ba\u6742\u7684TiO2<\/sub> \/\u78b3\u5fae\u7403\uff08NF-TiO2<\/sub> \/C\uff09\u4ee5\u5b9e\u73b0\u5927\u4f53\u79ef\u5bb9\u91cf\u548c\u9ad8\u632f\u5b9e\u5bc6\u5ea6\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0cN\u548cF\u5171\u63ba\u6742\u589e\u52a0\u4e86\u6c27\u7a7a\u4f4d\u7684\u542b\u91cf\uff0c\u7f29\u5c0f\u4e86TiO2<\/sub>\u548cC\u7684\u5e26\u9699\uff0c\u63d0\u9ad8\u4e86NF-TiO2<\/sub> \/C\u7684\u7535\u5b50\u7535\u5bfc\u7387\u3002\u6b64\u5916\uff0cNF-TiO2<\/sub>\/C\u8868\u73b0\u51faNa+<\/sup>\u7684\u9ad8\u7ed3\u5408\u80fd\u548c\u4f4e\u6269\u6563\u80fd\u5792\uff0c\u663e\u7740\u4fc3\u8fdbNa+<\/sup>\u5b58\u50a8\u548cNa+<\/sup>\u6269\u6563\u3002\u56e0\u6b64\uff0cNF-TiO2<\/sub> \/C\u5177\u6709\u9ad8\u632f\u5b9e\u5bc6\u5ea6\uff081.51 g cm-3<\/sup>\uff09\u3001\u51fa\u8272\u7684\u500d\u7387\u6027\u80fd\uff08100 C\u4e0b\uff0c~125.9 mAh g -1<\/sup> \uff09\u3001\u5927\u4f53\u79ef\u5bb9\u91cf\uff08\u5728100C\u4e0b\uff0c~190 mAh cm-3<\/sup>)\uff0c\u540c\u65f6\u5177\u6709\u9ad8\u9762\u79ef\u5bb9\u91cf\uff08~4.8 mAh cm-2<\/sup>\uff09\u548c\u8d85\u957f\u5faa\u73af\u6027\u80fd\uff0810C\u4e0b 10,000 \u6b21\u5faa\u73af\u540e~80.2%\uff09\u3002\u6b64\u5916\uff0cNF-TiO2<\/sub> \/C||Na3<\/sub> V2<\/sub> (PO4<\/sub> )3<\/sub>\u5168\u7535\u6c60\u5b9e\u73b0\u4e8625.2 kW kg-1<\/sup>\u7684\u8d85\u9ad8\u529f\u7387\u5bc6\u5ea6\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660eNF-TiO2<\/sub>\/C \u4f5c\u4e3aSIBs\u7684\u9ad8\u4f53\u79ef\u5bb9\u91cf\u548c\u9ad8\u529f\u7387\u5bc6\u5ea6\u8d1f\u6781\u6750\u6599\u7684\u5de8\u5927\u524d\u666f\u3002<\/p>\n

5.Advanced Energy Materials<\/strong>\uff1a\u7528\u4e8e\u9ad8\u6548\u50a8\u94be\u3001\u5bcc\u6c2e\u78b3\u53cc\u9650\u5236<\/strong> CoP <\/strong>\u590d\u5408\u6750\u6599\u7684\u96f6\u5e94\u53d8\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

\u540e\u9502\u79bb\u5b50\u7535\u6c60 (LIB) \u7684\u53d1\u5c55\u6709\u671b\u901a\u8fc7\u51cf\u5c11\u65e5\u76ca\u51cf\u5c11\u7684\u9502\u8d44\u6e90\u7684\u4f7f\u7528\u6765\u5e94\u5bf9\u53ef\u6301\u7eed\u7684\u8d44\u6e90\u6311\u6218\u3002\u4e0e\u6b64\u76f8\u4e00\u81f4\uff0c\u7531\u4e8e\u94be\u8d44\u6e90\u50a8\u91cf\u4e30\u5bcc\uff0c\u4ef7\u683c\u8bf1\u4eba\uff0cK+<\/sup>\/K(-2.93 V)\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u53ef\u4e0eLi+<\/sup>\/Li (-3.04 V)\u76f8\u5ab2\u7f8e\uff0c\u94be\u79bb\u5b50\u7535\u6c60(PIB)\u6709\u671b\u4ee5\u4f4e\u6210\u672c\u83b7\u5f97\u76f8\u5f53\u597d\u7684\u8f93\u51fa\u7535\u538b\u548c\u80fd\u91cf\u5bc6\u5ea6\u3002\u5c3d\u7ba1\u5982\u6b64\uff0c\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u4e2d\u5bfc\u81f4\u7ed3\u6784\u574d\u584c\u7684\u4e25\u91cd\u4f53\u79ef\u53d8\u5316\u548c\u7535\u6781\u53cd\u5e94\u52a8\u529b\u5b66\u7f13\u6162\u4ecd\u7136\u662f\u663e\u7740\u7684\u6311\u6218\uff0c\u9700\u8981\u4ed8\u51fa\u5de8\u5927\u52aa\u529b\u6765\u6539\u5584K+<\/sup>\u53cd\u5e94\u52a8\u529b\u5b66\u548c\u7ed3\u6784\u7a33\u5065\u6027\uff0c\u4ee5\u8fdb\u4e00\u6b65\u589e\u5f3a\u7535\u6781\u6750\u6599\u7684\u94be\u5b58\u50a8\u80fd\u529b\u3002<\/p>\n

\u5728\u6b64\uff0c\u901a\u8fc7\u81ea\u6a21\u677f\u50ac\u5316\u7cbe\u786e\u5408\u6210\u4e86\u4e00\u79cd\u65b0\u578b\u8d1f\u6781\u6750\u6599\uff0c\u5176\u4e2d\u5305\u8986\u6709N\u63ba\u6742\u78b3\u7684\u5c0f\u5c3a\u5bf8CoP\u7eb3\u7c73\u7c92\u5b50\u56fa\u5b9a\u5728\u4e00\u7ef4\u6c2e\u63ba\u6742\u78b3\u6846\u67b6\uff08CoP@NC\u2282NCFs\uff09\u4e2d\u3002\u5206\u7ea7\u7ed3\u6784\u5177\u6709\u591a\u79cd\u7ed3\u6784\u4f18\u52bf\uff0c\u5305\u62ec\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u7531\u5bcc\u6c2e\u63d0\u4f9b\u7684\u8d85\u9ad8\u7535\u5bfc\u7387\u3001CoP\u4e0eN\u63ba\u6742\u78b3\u4e4b\u95f4\u7684\u5f3a\u754c\u9762\u76f8\u4e92\u4f5c\u7528\u4ee5\u53ca\u7ed3\u6784\u7684\u7a33\u5b9a\u6027\u3002\u7ed3\u679c\uff0c\u901a\u8fc7\u6052\u7535\u6d41\u95f4\u6b47\u6ef4\u5b9a\u548c\u5bc6\u5ea6\u51fd\u6570\u7406\u8bba\u8ba1\u7b97\uff0c\u5b9e\u73b0\u4e86\u5feb\u901f\u7684\u94be\u79bb\u5b50\u53cd\u5e94\u52a8\u529b\u5b66\u548cCoP\u5bf9\u94be\u79bb\u5b50\u7684\u5f3a\u5438\u9644\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5148\u8fdb\u7684\u539f\u4f4d\u8868\u5f81\u6280\u672f\uff0c\u9610\u660e\u4e86CoP\u4e0e\u94be\u79bb\u5b50\u7684\u56fa\u6eb6\u53cd\u5e94\u673a\u7406\u3002\u5728 0.1 A g-1<\/sup>\u4e0b\u5faa\u73af1200\u6b21\uff0c\u5bb9\u91cf\u2248206mah g\u2212<\/sup>1<\/sup>\uff0c\u5b9e\u73b0 0.01%\u7684\u8d85\u4f4e\u8870\u51cf\u7387\u3002\u76f8\u5e94\u7684K\u79bb\u5b50\u5168\u7535\u6c60\u4e5f\u6309\u9884\u671f\u5236\u5907\uff0c\u5e76\u663e\u793a\u51fa\u7a33\u5b9a\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002<\/p>\n

6.Small<\/strong>\uff1a\u7528\u4e8e\u9ad8\u7a33\u5b9a\u6027\u94be\u79bb\u5b50\u7535\u6c60\u7684\u7852\u5316\u94a8<\/strong>@N<\/strong>\u63ba\u6742\u78b3\u7eb3\u7c73\u7ba1\u7684\u5408\u7406\u8bbe\u8ba1<\/strong><\/p>\n

\"\"<\/p>\n

\u94be\u79bb\u5b50\u7535\u6c60\uff08PIB\uff09\u7531\u4e8e\u5176\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u4f4e\u6210\u672c\u88ab\u8ba4\u4e3a\u662f\u6700\u6709\u524d\u9014\u7684\u50a8\u80fd\u7cfb\u7edf\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5408\u9002\u7684\u7535\u6781\u6750\u6599\u6709\u9650\uff0c\u5b83\u4eec\u7684\u5546\u4e1a\u5e94\u7528\u8fdc\u4e0d\u80fd\u4ee4\u4eba\u6ee1\u610f\u3002<\/p>\n

\u5728\u6b64\uff0c\u9996\u6b21\u901a\u8fc7\u5bf9WO3<\/sub>@\u805a\u5421\u54af\u8fdb\u884c\u7852\u5316\uff0c\u5408\u7406\u8bbe\u8ba1\u548c\u5408\u6210\u4e86\u6838\u58f3\u7ed3\u6784\u7684WSe2<\/sub>@N\u63ba\u6742\u78b3\u7eb3\u7c73\u7ba1\u3002WSe2<\/sub>\u7684\u5927\u5c42\u95f4\u8ddd\u53ef\u4ee5\u4fc3\u8fdbK+<\/sup>\u7684\u5d4c\u5165\/\u8131\u5d4c\u3002\u540c\u65f6\uff0c\u6838\u58f3\u7ed3\u6784\u7684\u7eb3\u7c73\u7ba1\u63d0\u4f9b\u4e86\u6709\u5229\u7684\u5185\u90e8\u7a7a\u9699\u7a7a\u95f4\u4ee5\u9002\u5e94WSe2<\/sub>\u7684\u4f53\u79ef\u81a8\u80c0\u9a91\u8f66\u65f6\u3002\u56e0\u6b64\uff0c\u6240\u83b7\u5f97\u7684\u7535\u6781\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5728120\u6b21\u5faa\u73af\u540e\u5728100 mA g-1<\/sup>\u4e0b\u5177\u6709301.7 mAh g-1<\/sup>\u7684\u9ad8\u5bb9\u91cf\uff0c\u5e76\u4e14\u5373\u4f7f\u57281300\u6b21\u5faa\u73af\u540e\uff0c\u5728500 mA g-1<\/sup>\u4e0b\u4ecd\u53ef\u4fdd\u6301122.1mAh g-1<\/sup>\u3002\u5f02\u4f4dX\u5c04\u7ebf\u884d\u5c04\u5206\u6790\u63ed\u793a\u4e86WSe2<\/sub> @N\u63ba\u6742C\u7684K\u79bb\u5b50\u5b58\u50a8\u673a\u5236\uff0c\u5305\u62ec\u5d4c\u5165\u548c\u8f6c\u5316\u53cd\u5e94\u3002\u5bc6\u5ea6\u51fd\u6570\u7406\u8bba(DFT)\u8ba1\u7b97\u8bc1\u660e\u4e86K+<\/sup>\u7684\u5408\u7406\u6269\u6563\u8def\u5f84\u3002\u53e6\u5916\uff0c\u5f97\u5230\u7684WSe2<\/sup>@N\u63ba\u6742\u7684\u78b3\u7eb3\u7c73\u7ba1\u5df2\u88ab\u7528\u4f5c\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\uff0c\u5176\u4e5f\u8868\u73b0\u51fa\u826f\u597d\u7684\u500d\u7387\u6027\u80fd\u548c\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5177\u6709\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u7684\u65b0\u578b\u7ed3\u6784\u7535\u6781\u6750\u6599\u7684\u914d\u6bd4\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u65b9\u6cd5\u3002<\/p>\n

\u5b59\u4e16\u521a<\/strong><\/p>\n

\u7269\u7406\u5316\u5b66\u5bb6\uff0c\u957f\u671f\u4ece\u4e8b\u7535\u5316\u5b66\u548c\u8868\u754c\u9762\u79d1\u5b66\u7814\u7a76\u30022015\u5e74\u5f53\u9009\u4e3a\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u3002<\/p>\n

7.Electrochimica Acta<\/strong>\uff1a\u901a\u8fc7\u589e\u52a0\u5bc6\u5ea6\u548c\u6539\u53d8<\/strong>Fe-NX<\/sub><\/strong>\u6d3b\u6027\u4f4d\u70b9\u7684\u7535\u5b50\u7ed3\u6784\u6765\u63d0\u9ad8<\/strong>Fe-N\/C<\/strong>\u50ac\u5316\u5242\u7684<\/strong>ORR<\/strong>\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\u5316\u77f3\u80fd\u6e90\u5371\u673a\u7684\u5230\u6765\uff0c\u4f7f\u5f97\u5f00\u53d1\u6e05\u6d01\u3001\u53ef\u6301\u7eed\u7684\u80fd\u6e90\u8feb\u5728\u7709\u776b\u3002\u71c3\u6599\u7535\u6c60\u4f5c\u4e3a\u4e00\u79cd\u80fd\u591f\u5c06\u71c3\u6599\u7684\u5316\u5b66\u80fd\u8f6c\u5316\u4e3a\u7535\u80fd\u7684\u65b0\u578b\u80fd\u6e90\u88c5\u7f6e\uff0c\u4ee5\u5176\u7406\u8bba\u6548\u7387\u9ad8\u3001\u6a21\u5757\u5316\u3001\u65e0\u6709\u6bd2\u6c14\u4f53\u3001\u65e0\u566a\u58f0\u6392\u653e\u7b49\u4f18\u70b9\u800c\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u662f\u71c3\u6599\u7535\u6c60\u5173\u952e\u7684\u534a\u53cd\u5e94\uff0c\u5176\u53cd\u5e94\u52a8\u529b\u5b66\u7f13\u6162\u5bfc\u81f4\u7684\u9ad8\u8fc7\u7535\u4f4d\u5927\u5927\u964d\u4f4e\u4e86\u71c3\u6599\u7535\u6c60\u8fd0\u884c\u8fc7\u7a0b\u4e2d\u7684\u5b9e\u9645\u8f93\u51fa\u529f\u7387\u3002\u94c2\u65cf\u91d1\u5c5e\uff08PGM\uff09\u662f\u6700\u5e7f\u6cdb\u4f7f\u7528\u7684ORR\u50ac\u5316\u5242\uff0c\u4f46\u5176\u9ad8\u6602\u7684\u4ef7\u683c\u548c\u7a00\u7f3a\u7684\u6765\u6e90\u4e25\u91cd\u9650\u5236\u4e86\u71c3\u6599\u7535\u6c60\u7684\u5546\u4e1a\u5316\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u4e0d\u542b\u94c2\u65cf\u91d1\u5c5e\u4f5c\u4e3a\u66ff\u4ee3\u54c1\u7684ORR\u50ac\u5316\u5242\u5177\u6709\u91cd\u8981\u7684\u7814\u7a76\u4ef7\u503c\u3002<\/p>\n

\u7531\u4e8e\u9ad8\u6d3b\u6027 Fe-NX<\/sub>\u914d\u4f4d\u90e8\u5206\u7684\u5b58\u5728\uff0c\u94c1\u6c2e\/\u78b3(Fe-N\/C)\u6750\u6599\u88ab\u8ba4\u4e3a\u662f\u6c27\u8fd8\u539f\u53cd\u5e94(ORR)\u7684\u6f5c\u5728\u7535\u50ac\u5316\u5242\u3002\u589e\u52a0Fe-NX<\/sub>\u4f4d\u70b9\u7684\u5bc6\u5ea6\u88ab\u8ba4\u4e3a\u662f\u63d0\u9ad8Fe-N\/C\u50ac\u5316\u5242ORR\u6027\u80fd\u7684\u6709\u7528\u7b56\u7565\u3002\u5728\u6b64\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u5206\u6b65\u5408\u6210\u7b56\u7565\uff0c\u4ee5\u6784\u5efa\u5177\u6709\u9ad8\u6bd4\u4f8b\u4ecb\u5b54\u548c\u9ad8\u6d53\u5ea6\u53ef\u8fbeFe-NX<\/sub>\u6d3b\u6027\u4f4d\u70b9\u7684Fe-N\/C\u50ac\u5316\u5242\u3002\u7efc\u5408\u6210\u5206\u548c\u5f62\u8c8c\u7279\u5f81\uff0c\u5408\u6210\u7684Fe-N\/C meso-evap\u50ac\u5316\u5242\u5177\u6709\u8f83\u597d\u7684ORR\u6d3b\u6027\uff0c\u57280.1 M HClO4\u4e2d\uff0c0.8 V\u65f6\u534a\u7535\u4f4d\u4e3a0.835 V\uff0c\u52a8\u529b\u5b66\u7535\u6d41\u5bc6\u5ea6\u4e3a31.02 mA cm2<\/sup>\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u8bbe\u8ba1\u9762\u5411ORR\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

8.ACS Applied Materials & Interfaces<\/strong>\uff1a<\/strong>\u4e00\u79cd\u6e29\u548c\u7684CO2<\/sub>\u8680\u523b\u65b9\u6cd5\u6765\u5b9a\u5236\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\u4e2d\u65e0\u94c2\u6c27\u8fd8\u539f\u50ac\u5316\u5242\u7684\u5b54\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

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\u5728\u6b64\uff0c\u91c7\u7528\u6e29\u548c\u7684\u4e8c\u6c27\u5316\u78b3(CO2<\/sub>)\u8680\u523b\u65b9\u6cd5\u7075\u6d3b\u8c03\u6574Fe\/N\/C\u7535\u50ac\u5316\u5242\u7684\u5b54\u7ed3\u6784\uff0c\u800c\u4e0d\u4f1a\u5bf9\u5176\u8868\u9762\u7ed3\u6784\u548c\u6027\u80fd\u4ea7\u751f\u5267\u70c8\u53d8\u5316\u3002\u901a\u8fc7\u8fd9\u79cd\u65b9\u5f0f\uff0c\u901a\u8fc7\u4f7f\u7528Fe\/N\/C\u7535\u50ac\u5316\u5242\u4f5c\u4e3a\u6a21\u578b\uff0c\u63ed\u793a\u4e86\u5b54\u7ed3\u6784\u5bf9ORR\u6d3b\u6027\u7684\u5185\u5728\u5f71\u54cd\u3002\u6b64\u5916\uff0cCO2<\/sub>\u8680\u523b\u65b9\u6cd5\u5f00\u53d1\u4e86\u4e00\u79cd\u9ad8\u8d28\u91cf\u7684\u7535\u50ac\u5316\u5242\uff08\u6837\u54c1Fe\/N\/C\u20135% CO2<\/sub>\uff09\uff0c\u5176\u6781\u5316\u6027\u80fd\u5728\u71c3\u6599\u7535\u6c60\u5de5\u4f5c\u7535\u538b\u8303\u56f4\u5185\uff08> 0.65 V\uff09\u8d85\u8fc7\u4e86\u5546\u7528Pt\/C\u50ac\u5316\u5242\u3002\u8fd9\u9879\u5de5\u4f5c\u5c06\u4fc3\u8fdb\u5bf9Fe\/N\/C\u7535\u50ac\u5316\u5242\u4e2d\u5b54\u7ed3\u6784\u5408\u7406\u8bbe\u8ba1\u7684\u6df1\u5165\u7814\u7a76\u3002<\/p>\n

9.Energy Storage Materials<\/strong>\uff1a\u5177\u6709\u5185\u90e8\u79bb\u5b50\u7535\u5bfc<\/strong>\/<\/strong>\u5916\u90e8\u7535\u5b50\u7edd\u7f18\u6df7\u5408\u7ed3\u6784\u7684\u5f02\u8d28<\/strong>SEI<\/strong>\u819c\u5b9e\u73b0\u9ad8\u5faa\u73af\u6027\u548c\u9ad8\u7535\u538b\u9502\u91d1\u5c5e\u7535\u6c60<\/strong><\/p>\n

\"\"<\/p>\n

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\u5728\u6b64\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u7b56\u7565\uff0c\u901a\u8fc7\u9009\u62e9\u6027\u8fd8\u539f\u7535\u89e3\u8d28\u7ec4\u5206\u6765\u6784\u5efa\u5f02\u8d28 SEI\uff0c\u4ee5\u63d0\u9ad8\u9502\u7684\u7a33\u5b9a\u6027\u5e76\u6291\u5236\u679d\u6676\u751f\u957f\u3002SEI\u819c\u7684\u5185\u90e8\u5bccN\u5b50\u5c42\u80fd\u591f\u5b9e\u73b0\u7ed3\u8282\u72b6\u9502\u6c89\u79ef\u7684\u5feb\u901fLi+<\/sup>\u4f20\u8f93\uff0c\u800cSEI\u819c\u7684\u5916\u90e8\u5bccC\u5b50\u5c42\u5177\u6709\u7535\u5b50\u7edd\u7f18\u6027\u80fd\u963b\u6b62\u7535\u89e3\u8d28\u5206\u89e3\u3002\u8fd9\u79cd\u6df7\u5408SEI\u8d4b\u4e88LMA\u9ad8\u5e93\u4ed1\u6548\u7387 (99.0%)\u3001\u957f\u5bff\u547d\u548c\u679d\u6676\u6291\u5236\u3002\u7406\u8bba\u8ba1\u7b97\u3001XPS\u548cAFM\u88ab\u7528\u6765\u68c0\u67e5\u5f02\u8d28SEI\u7ed3\u6784\u5e76\u9610\u660e\u5176\u5f62\u6210\u673a\u5236\u3002\u5728\u8d85\u8584\u9502\u9633\u6781(25\u03bcm)\u3001\u4f4eN\/P\u6bd4(1.67)\u7684LiCoO2<\/sub>\/Li\u888b\u7535\u6c60\u4e2d\uff0c\u57280.5 C\u6761\u4ef6\u4e0b\u5faa\u73af160\u6b21\u540e\uff0c\u7535\u6c60\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a91.6%\uff1b\u5728\u8f83\u9ad8\u7684\u5145\u7535\u7535\u4f4d(4.5 V)\u4e0b\u5faa\u73af300\u6b21\u540e\uff0c\u7535\u6c60\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a85.7%\u3002\u5bf9\u5f02\u8d28SEI\u5f62\u6210\u7684\u6d1e\u5bdf\u4e3a\u5b9e\u73b0\u9ad8\u6027\u80fd\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u5408\u7406\u7535\u5b50\/\u79bb\u5b50\u8f6c\u79fb\u9014\u5f84\u6784\u5efa\u63d0\u4f9b\u4e86\u65b0\u7684\u673a\u4f1a\u3002<\/p>\n

1.Xu J, Li Y, Lu P, et al. Water\u2010Stable Sulfide Solid Electrolyte Membranes Directly Applicable in All\u2010Solid\u2010State Batteries Enabled by Superhydrophobic Li+<\/sup>\u2010Conducting Protection Layer. Advanced Energy Materials. 2021.<\/p>\n

2.Liu Z, Zhang C, Tian M, et al. Cationic disordering modulated electrochemical performances of layer-structured Li2MoO3. Materials Today Physics. 2021;21.<\/p>\n

3.Peng J, Wu D, Song F, et al. High Current Density and Long Cycle Life Enabled by Sulfide Solid Electrolyte and Dendrite\u2010Free Liquid Lithium Anode. Advanced Functional Materials. 2021.<\/p>\n

4.Lv D, Wang D, Wang N, et al. Nitrogen and fluorine co-doped TiO2\/carbon microspheres for advanced anodes in sodium-ion batteries: High volumetric capacity, superior power density and large areal capacity. Journal of Energy Chemistry. 2022;68:104-112.<\/p>\n

5.Yun Y, Xi B, Tian F, et al. Zero\u2010Strain Structure for Efficient Potassium Storage Nitrogen\u2010Enriched Carbon Dual\u2010Confinement CoP Composite. Advanced Energy Materials. 2021.<\/p>\n

6.Chen X, Muheiyati H, Sun X, et al. Rational Design of Tungsten Selenide @ N-Doped Carbon Nanotube for High-Stable Potassium-Ion Batteries. Small. Nov 25 2021:e2104363.<\/p>\n

7.Qu X, Li Y, Li G, et al. Boosting the ORR performance of Fe-N\/C catalyst via increasing the density and modifying the electronic structure of Fe-NX active sites. Electrochimica Acta. 2022;403.<\/p>\n

8.Wan L, Chen W, Xu H, et al. A Mild CO2 Etching Method To Tailor the Pore Structure of Platinum-Free Oxygen Reduction Catalysts in Proton Exchange Membrane Fuel Cells. ACS Appl Mater Interfaces. Sep 29 2021;13(38):45661-45669.<\/p>\n

9.Zhang S-J, Yin Z-W, Wu Z-Y, et al. Achievement of high-cyclability and high-voltage Li-metal batteries by heterogeneous SEI film with internal ionic conductivity\/external electronic insulativity hybrid structure. Energy Storage Materials. 2021;40:337-346.<\/p>\n","protected":false},"excerpt":{"rendered":"

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