{"id":231359,"date":"2021-12-28T06:53:12","date_gmt":"2021-12-27T22:53:12","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=231359"},"modified":"2021-12-27T19:53:25","modified_gmt":"2021-12-27T11:53:25","slug":"%e5%8c%97%e7%90%86%e5%b7%a5jacs%ef%bc%9a%e5%9f%ba%e4%ba%8e14-%e4%ba%8c%e6%b0%a2%e5%90%a1%e5%95%b6%e8%81%9a%e5%90%88%e7%89%a9%e7%9a%84%e7%b0%87%e5%8f%91%e9%a2%9c%e8%89%b2%e5%8f%af%e8%b0%83%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=231359","title":{"rendered":"\u5317\u7406\u5de5JACS\uff1a\u57fa\u4e8e1,4-\u4e8c\u6c22\u5421\u5576\u805a\u5408\u7269\u7684\u7c07\u53d1\u989c\u8272\u53ef\u8c03\u7684\u5ba4\u6e29\u78f7\u5149"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u81ea\u7136\u754c\u4e2d\u5e38\u89c1\u7684\u805a\u5408\u7269\uff0c\u5982\u7ea4\u7ef4\u7d20\u548c\u6dc0\u7c89\u7b49\uff0c\u5728\u805a\u96c6\u72b6\u6001\u4e0b\uff0c\u53d7\u5230\u7d2b\u5916\u6fc0\u53d1\u65f6\u6709\u660e\u4eae\u7684\u8367\u5149\uff0c\u8fd9\u79cd\u72ec\u7279\u7684\u73b0\u8c61\u53eb\u505a\u7c07\u53d1\u5149\uff08CTE\uff09\u3002\u5ba4\u6e29\u78f7\u5149\uff08RTP\uff09\u6750\u6599\u56e0\u5177\u6709\u957f\u5bff\u547d\u6301\u4e45\u53d1\u5149\u7684\u7279\u6027\uff0c\u9002\u7528\u4e8e\u5149\u5b66\u8bb0\u5f55\u3001\u9632\u4f2a\u3001\u751f\u7269\u6210\u50cf\u7b49\u5e94\u7528\uff0c\u6b63\u5f15\u8d77\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u4f46\u662f\uff0c\u7531\u4e8eCTE\u6750\u6599\u7684\u4e09\u7ebf\u6001\u6fc0\u5b50\u4e0d\u7a33\u5b9a\uff0c\u5982\u4f55\u8d4b\u4e88CTE\u6750\u6599\u5177\u6709RTP\u6027\u80fd\u8fd8\u6ca1\u6709\u5f97\u5230\u5f88\u597d\u7684\u7814\u7a76\u3002\u65f6\u81f3\u4eca\u65e5\uff0c\u4ee5\u805a\u5408\u7269\u4e3a\u5ba2\u4f53\uff0c\u901a\u8fc7\u4e0e\u4e3b\u4f53\u63ba\u6742\u5b9e\u73b0\u4e09\u7ebf\u6001\u7684\u8c03\u63a7\u7814\u7a76\u5c1a\u5c5e\u7a7a\u767d\uff0c\u9700\u8981\u5f00\u53d1\u5177\u6709CTE\u6027\u8d28\u7684\u65b0\u578b\u805a\u5408\u7269\uff0c\u5e76\u9610\u660e\u63ba\u6742\u4e8e\u5c0f\u5206\u5b50\u4e3b\u4f53\u4e2d\u7684RTP\u673a\u7406\uff0c\u5c06\u4f1a\u63a8\u52a8\u76f8\u5173\u9886\u57df\u7684\u53d1\u5c55\u4e0e\u8fdb\u6b65\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u4f5c\u8005\u901a\u8fc7\u4e09\u952e\u591a\u7ec4\u5206\u805a\u5408\u53cd\u5e94\u6784\u5efa\u4e86\u5177\u6709CTE\u6027\u8d28\u7684\u805a\u5408\u7269\uff0c\u4ee5\u5176\u4e3a\u5ba2\u4f53\u4e0e\u521a\u6027\u4e3b\u4f53\u4e8c\u82ef\u7532\u916e\u8fdb\u884c\u63ba\u6742\uff0c\u901a\u8fc7\u8c03\u8282\u6bd4\u4f8b\u548c\u5206\u5b50\u91cf\u8c03\u63a7\u56e2\u7c07\u7684\u5927\u5c0f\uff0c\u4ece\u800c\u5229\u7528CTE\u6027\u8d28\u5b9e\u73b0\u4e86\u989c\u8272\u53ef\u8c03RTP\uff0c\u6700\u5927\u53d1\u5c04\u53ef\u8fbe645 nm\u3002<\/p>\n

\u3010\u7814\u7a76\u65b9\u6cd5\u3011<\/strong><\/p>\n

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\u56fe<\/strong>1. <\/strong>\u5408\u6210\u53ca\u673a\u7406\u8def\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe<\/strong>2. <\/strong>\u805a\u5408\u7269\u5149\u7269\u7406\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe<\/strong>3. <\/strong>\u52a8\u6001\u548c\u9759\u6001\u5149\u6563\u5c04<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe<\/strong>4. <\/strong>\u805a\u5408\u7269\u989c\u8272\u53ef\u8c03<\/strong>RTP<\/strong>\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u901a\u8fc7\u4e8c\u4e59\u7094\u916f\u3001\u82ef\u7532\u919b\u548c\u82ef\u80fa\u884d\u751f\u7269\u7684\u65e0\u91d1\u5c5e\u50ac\u5316MCP\u4e00\u6b65\u5408\u6210\u4e86\u5177\u6709CTE\u6027\u8d28\u7684PDHPs\u3002\u901a\u8fc7\u8c03\u8282PDHPs\u5728\u4e8c\u82ef\u7532\u916e\u4e2d\u7684\u56e2\u7c07\u6bd4\u4f8b\u4e0e\u5c3a\u5bf8\uff0c\u5b9e\u73b0\u4e86\u989c\u8272\u53ef\u8c03\u7684RTP\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u53d1\u5c55\u4e86MCP\uff0c\u4e30\u5bcc\u4e86\u529f\u80fd\u805a\u5408\u7269\u79cd\u7c7b\uff0c\u4e5f\u586b\u8865\u4e86\u4ee5\u805a\u5408\u7269\u4f5c\u4e3a\u5ba2\u4f53\u7684\u78f7\u5149\u63ba\u6742\u4f53\u7cfb\u7684\u7a7a\u767d\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.1c11607<\/p>\n

Clusterization-Triggered Color-Tunable Room-Temperature Phosphorescence from 1,4-Dihydropyridine-Based PolymersnYue Ren, Wenbo Dai, Shuai Guo, Lichao Dong, Siqi Huang, Jianbing Shi, Bin Tong, Nairong Hao, Lianwei Li, Zhengxu Cai, Yuping Dong, J. Am. Chem. Soc.<\/em>, 2021, DOI: 10.1021\/jacs.1c11607<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u81ea\u7136\u754c\u4e2d\u5e38\u89c1\u7684\u805a\u5408\u7269\uff0c\u5982\u7ea4\u7ef4\u7d20\u548c\u6dc0\u7c89\u7b49\uff0c\u5728\u805a\u96c6\u72b6\u6001\u4e0b\uff0c\u53d7\u5230\u7d2b\u5916\u6fc0\u53d1\u65f6\u6709\u660e\u4eae\u7684\u8367\u5149\uff0c\u8fd9\u79cd\u72ec\u7279\u7684\u73b0\u8c61\u53eb\u505a\u7c07\u53d1\u5149\uff08CTE\uff09\u3002\u5ba4\u6e29\u78f7\u5149\uff08RTP\uff09\u6750\u6599\u56e0\u5177\u6709…<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-231359","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/231359"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=231359"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/231359\/revisions"}],"predecessor-version":[{"id":231364,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/231359\/revisions\/231364"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=231359"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=231359"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=231359"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}