{"id":231556,"date":"2022-01-04T06:48:14","date_gmt":"2022-01-03T22:48:14","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=231556"},"modified":"2022-01-03T17:29:08","modified_gmt":"2022-01-03T09:29:08","slug":"%e6%88%90%e4%bc%9a%e6%98%8e%e9%99%a2%e5%a3%ab-%e6%9d%a8%e5%85%a8%e7%ba%a2-%e5%b4%94%e5%b1%b9-%e7%8e%8b%e6%98%a5%e7%94%9f-%e5%ad%99%e5%ad%a6%e8%89%af-%e7%89%9b%e5%bf%97%e5%bc%ba-%e5%ad%9f%e9%a2%96","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=231556","title":{"rendered":"\u6210\u4f1a\u660e\u9662\u58eb \u6768\u5168\u7ea2 \u5d14\u5c79 \u738b\u6625\u751f \u5b59\u5b66\u826f  \u725b\u5fd7\u5f3a \u5b5f\u9896 \u80fd\u6e90\u7c7b\u9876\u520a\u68b3\u7406"},"content":{"rendered":"<p><strong>\u4e00\u3001\u5d14\u5c79JACS 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\u6b63\u6781\u4e0eRMs\u7684\uff08\u56fa\u76f8-\u591a\u786b\u5316\u7269-\u56fa\u76f8\uff09\u53cd\u5e94\u4fc3\u8fdb\u4e86Li<sub>2<\/sub>S \u7684\u6c27\u5316\u3002\u76f8\u53cd\uff0c\u5bf9\u4e8e\u88f8Li<sub>2<\/sub>S\u6b63\u6781\uff0c\u5728\u7b2c\u4e00\u6b21\u5145\u7535\u5faa\u73af\u4e2d\uff0c Li<sub>2<\/sub>S-\u786b\uff08\u56fa\u76f8-\u56fa\u76f8\uff09\u7684\u76f4\u63a5\u8f6c\u5316\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u6d3b\u5316\u80fd\u80fd\u5792\uff0c\u540c\u65f6\u786b\u7684\u5229\u7528\u7387\u8f83\u4f4e\u3002Li<sub>2<\/sub>S@AQT \u7535\u6c60\u5177\u6709\u826f\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027(150\u6b21\u5faa\u73af\u5e73\u5747\u5e93\u4ed1\u6548\u7387\u4e3a98.9%)\u548c\u826f\u597d\u7684\u500d\u7387\u6027\u80fd\uff0c\u8fd9\u662f\u7531\u4e8e\u6709\u6548\u7684 AQT\u589e\u5f3a\u4e86 Li-S\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u672c\u7814\u7a76\u4e3a\u5f00\u53d1\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u9ad8\u5b89\u5168\u6027\u548c\u957f\u5faa\u73af\u5bff\u547d\u7684\u4e0b\u4e00\u4ee3\u56fa\u6001\u7535\u6c60\u5f00\u8f9f\u4e86\u65b0\u7684\u9014\u5f84\u3002<\/p>\n<p>\u5982\u56fea\u6240\u793a\uff0c\u662f\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\uff08RMs\uff09\u5728\u5168\u56fa\u6001\u9502\u2212\u786b\u7535\u6c60\uff08ASSLSB\uff09\u4e2d\u7684\u53cd\u5e94\u673a\u7406\u3002\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0cRMox\u5c06Li2S\u5316\u5b66\u6c27\u5316\u4e3a\u591a\u786b\u5316\u7269\uff0c\u540c\u65f6RMox\u88ab\u8fd8\u539f\u4e3aRMred\uff08\u6b65\u9aa4A\uff0c\u5316\u5b66\u53cd\u5e94\uff09\u3002\u901a\u8fc7\u5411\u96c6\u6d41\u4f53\u63d0\u4f9b\u7535\u5b50\uff0c\u5e76\u5728\u96c6\u6d41\u4f53\u8868\u9762\u9644\u8fd1\u88ab\u7535\u5316\u5b66\u6c27\u5316\u4e3aRMox\u7684\u521d\u59cb\u72b6\u6001\uff08\u6b65\u9aa4B\uff0c\u7535\u5316\u5b66\u53cd\u5e94\uff09\u3002<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72471-4.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-231558\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72471-4.jpg\" alt=\"\" width=\"692\" height=\"186\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72471-4.jpg 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72471-4-300x81.jpg 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/a><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5<\/strong><strong> https:\/\/doi.org\/10.1021\/jacs.1c07754<\/strong><\/p>\n<p><strong>\u4e8c\u3001Jaephil Cho Nature Energy \u4e9a\u7eb3\u7c73\u7845\u8d1f\u6781\u7684\u6676\u4f53\u751f\u957f\u6291\u5236\u673a\u7406\u53ca\u5176\u5728\u539f\u578b\u7535\u6c60\u7ec4\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p>\u7531\u4e8e\u9ad8\u5bb9\u91cf\u5408\u91d1\u57fa\u8d1f\u6781\u5728\u5faa\u73af\u671f\u95f4\u7684\u5927\u4f53\u79ef\u53d8\u5316\uff0c\u671f\u671b\u4f7f\u7528\u5c0f\u8d1f\u6781\u9897\u7c92\u4ee5\u5ef6\u957f\u7535\u6c60\u5faa\u73af\u5bff\u547d\u3002\u7136\u800c\uff0c\u5b9e\u73b0\u4e9a\u7eb3\u7c73\u5c3a\u5bf8\u9897\u7c92\uff08&lt;1nm\uff09\u4ecd\u7136\u5177\u6709\u6311\u6218\u6027\u3002\u5728\u8fd9\u91cc\uff0c\u97e9\u56fd\u851a\u5c71\u56fd\u7acb\u79d1\u5b66\u6280\u672f\u7814\u7a76\u9662Jaephil Cho\u6559\u6388\u8bfe\u9898\u7ec4\u5c55\u793a\u4e86\u4e00\u79cd\u751f\u957f\u6291\u5236\u673a\u5236\uff0c\u4e0e\u7eaf\u7845\u70f7\u7684\u5206\u89e3\u76f8\u53cd\uff0c\u5728\u7eaf\u7845\u70f7\u7684\u5206\u89e3\u4e2d\uff0cSi\u9897\u7c92\u7684\u5c3a\u5bf8\u7ee7\u7eed\u589e\u52a0\u3002\u800c\u8fd9\u79cd\u65b0\u673a\u5236\u53ef\u4ee5\u9632\u6b62\u5728\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u8fc7\u7a0b\u4e2d\u6210\u6838\u540e\u7acb\u5373\u7ee7\u7eed\u6269\u5927\u5c3a\u5bf8\u3002\u751f\u957f\u6291\u5236\u88ab\u6210\u529f\u5730\u5e94\u7528\u4e8e\u7845\u7684\u5408\u6210\uff0c\u4ece\u800c\u4ea7\u751f\u5d4c\u5165\u5728\u7531\u78b3\u548c\u78b3\u5316\u7845\u7ec4\u6210\u7684\u9ad8\u5ea6\u7a33\u5b9a\u7684\u53cc\u91cd\u57fa\u8d28\u4e2d\u7684\u4e9a\u7eb3\u7c73\u5c3a\u5bf8\uff08&lt;1nm\uff09\u7684\u7845\u3002\u4e59\u70ef\u4e0d\u4ec5\u8d77\u5230\u7845\u751f\u957f\u6291\u5236\u5242\u7684\u4f5c\u7528\uff0c\u4ece\u800c\u901a\u8fc7Si\u2013C\u952e\u7684\u5f62\u6210\u51cf\u7f13\u6210\u6838\u7845\u7684\u751f\u957f\uff0c\u800c\u4e14\u8fd8\u8d77\u5230\u4ea7\u751f\u53cc\u91cd\u57fa\u8d28\u7684\u6765\u6e90\u7684\u4f5c\u7528\u3002\u8fd9\u4e0d\u4ec5\u9632\u6b62\u4e86\u5929\u7136SiO2\u5c42\u7684\u5f62\u6210\uff0c\u800c\u4e14\u6709\u52a9\u4e8e\u5728\u957f\u671f\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4fdd\u6301C\uff085\uff09Si\u5c42\u7684\u5f62\u6001\u5b8c\u6574\u6027\u3002\u4e9a\u7eb3\u7c73\u5c3a\u5bf8\u7684\u7845\u8d1f\u6781\u589e\u5f3a\u4e86\u5faa\u73af\u7a33\u5b9a\u6027\uff0850\u6b21\u5faa\u73af\u7684\u5e93\u4ed1\u6548\u7387\u8fbe\u523099.96%\uff09\u3002\u6700\u540e\uff0c\u5c55\u793a\u4e86\u5305\u542b110Ah\u5168\u7535\u6c60\u7684\u5236\u9020\u7684\u80fd\u91cf\u5b58\u50a8\u7cfb\u7edf\uff08103.2kWh\uff09\u7684\u5b9e\u9645\u5e94\u7528\uff0c\u5faa\u73af2875\u6b21\u540e\u5176\u5bb9\u91cf\u4fdd\u6301\u7387\u9ad8\u8fbe91%\uff0c\u65e5\u5386\u5bff\u547d\u4e3a97.6% (1\u5e74)\u3002\u5728\u7845\u70f7\u70ed\u5206\u89e3\u8fc7\u7a0b\u4e2d\uff0c\u6211\u4eec\u4f7f\u7528\u4e59\u70ef\u4f5c\u4e3a\u9897\u7c92\u751f\u957f\u6291\u5236\u5242\u5408\u6210\u4e86\u4e9a\u7eb3\u7c73\u5c3a\u5bf8\u7684\u7845\u9633\u6781\u3002\u8fd9\u4e9b\u7ed3\u679c\u53ef\u4ee5\u4e3a\u7535\u6c60\u7814\u7a76\u4eba\u5458\u8003\u8651\u9ad8\u5bb9\u91cf\u5408\u91d1\u8d1f\u6781\u8bbe\u8ba1\u53c2\u6570\u63d0\u4f9b\u542f\u53d1\uff0c\u5e76\u4e3a\u4e0b\u4e00\u4ee3\u9ad8\u80fd\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u5728\u50a8\u80fd\u7cfb\u7edf\u548c\u7535\u52a8\u6c7d\u8f66\u4e2d\u7684\u5e94\u7528\u94fa\u5e73\u9053\u8def\u3002<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72472-3.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-231559\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72472-3.jpg\" alt=\"\" width=\"629\" height=\"509\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72472-3.jpg 629w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72472-3-300x243.jpg 300w\" sizes=\"(max-width: 629px) 100vw, 629px\" \/><\/a><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5: https:\/\/www.nature.com\/articles\/s41560-021-00945-z<\/strong><\/p>\n<p><strong>\u4e09\u3001\u725b\u5fd7\u5f3a Nature communications \u57fa\u4e8e\u63d2\u5c42\u5316\u5b66\u7684\u53ef\u5145\u7535\u6c34\u9530\u79bb\u5b50\u7535\u6c60<\/strong><\/p>\n<p>\u5728\u7535\u6c60\u7814\u7a76\u4e2d\u51e0\u4e4e\u6ca1\u6709\u5173\u4e8eMn<sup>2+<\/sup>\u79bb\u5b50\u5145\u7535\u8f7d\u4f53\u7684\u62a5\u9053\u3002\u76f8\u6bd4\u4e8e\u5927\u591a\u6570\u4e8c\u4ef7\u79bb\u5b50\uff0c\u5982Ca<sup>2+<\/sup>\u3001Mg<sup>2+<\/sup>\u3001Zn<sup>2+<\/sup>\u548cFe<sup>2+<\/sup>\uff0c\u4e8c\u4ef7\u7684Mn<sup>2+<\/sup>\u79bb\u5b50\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u62e5\u6709\u8f83\u5927\u7684\u6eb6\u89e3\u79bb\u5b50\u534a\u5f84\uff0c\u8bf4\u660eMn2+\u79bb\u5b50\u5728\u666e\u901a\u5bbf\u4e3b\u6750\u6599\u4e2d\u7684\u63d2\u5c42\u76f8\u5bf9\u6765\u8bf4\u6bd4\u8f83\u56f0\u96be\u3002\u56e0\u6b64\uff0c\u6c34\u6027MIB\u7684\u5b9e\u73b0\u53d6\u51b3\u4e8eMn<sup>2+<\/sup>\u79bb\u5b50\u5bbf\u4e3b\u6750\u6599\u7684\u8bbe\u8ba1\uff0c\u8fd9\u4e9b\u5bbf\u4e3b\u6750\u6599\u5177\u6709\u8f83\u5927\u7684\u95f4\u9694\u901a\u9053\uff0c\u800c\u4e14\u63d2\u5c42\u7684Mn<sup>2+<\/sup>\u79bb\u5b50\u548c\u5bbf\u4e3b\u6846\u67b6\u4e4b\u95f4\u7684\u7ed3\u5408\u5f3a\u5ea6\u8f83\u5f31\u3002\u9488\u5bf9\u8fd9\u4e2a\u95ee\u9898\uff0c\u5357\u5f00\u5927\u5b66\u725b\u5fd7\u5f3a\u56e2\u961f\u62a5\u544a\u4e86\u6c34\u6027\u7535\u89e3\u8d28\u6eb6\u6db2\u4e2d\u53ef\u9006\u7684Mn<sup>2+<\/sup>\u63d2\u5c42\u5316\u5b66\uff0c\u5176\u4e2d\u65e0\u673a\u548c\u6709\u673a\u5316\u5408\u7269\u5728\u4e0eMn\/\u78b3\u590d\u5408\u8d1f\u6781\u7ed3\u5408\u65f6\u4f5c\u4e3a\u6b63\u6781\u6d3b\u6027\u7269\u8d28\u8fdb\u884cMn<sup>2+<\/sup>\u5b58\u50a8\u3002\u5728\u4e00\u79cd\u60c5\u51b5\u4e0b\uff0c\u5c42\u72b6\u7684Mn<sub>0.18<\/sub>V<sub>2<\/sub>O<sub>5<\/sub>-nH<sub>2<\/sub>O\u65e0\u673a\u6b63\u6781\u7531\u4e8e\u6676\u683c\u95f4\u8ddd\u5927\uff0c\u8868\u73b0\u51fa\u5feb\u901f\u548c\u53ef\u9006\u7684Mn<sup>2+<\/sup>\u63d2\u5165\/\u63d0\u53d6\uff0c\u4ece\u800c\u5b9e\u73b0\u8db3\u591f\u7684\u529f\u7387\u6027\u80fd\u548c\u7a33\u5b9a\u7684\u5faa\u73af\u6027\u80fd\u3002Mn||MnVO\u7535\u6c60\u53ef\u4ee5\u572820\u79d2\u5de6\u53f3\u5145\u6ee1\u7535\u81f31.9 V\uff0810.0 A g-1\uff0c64.8 Wh kg<sup>-1<\/sup>\uff09\uff0c\u663e\u793a\u51fa\u5feb\u901f\u5145\u7535\u80fd\u529b\u3002\u53e6\u4e00\u4e2a4-Cl-BQ\u7684\u6709\u673a\u6b63\u6781\u8868\u73b0\u51faMn<sup>2+<\/sup>\u79bb\u5b50\u7684\u914d\u4f4d\/\u4e0d\u914d\u4f4d\u4e0eC=O\u548cC-O-\u57fa\u56e2\u4e4b\u95f4\u7684\u8f6c\u5316\u3002DFT\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u4e00\u4e2aMn<sup>2+<\/sup>\u79bb\u5b50\u5c06\u4e0e\u76f8\u90bb\u76844-Cl-BQ\u5206\u5b50\u4e2d\u7684\u4e24\u4e2aC-O-\u57fa\u56e2\u914d\u4f4d\u3002\u7ed3\u679cMn||4-Cl-BQ\u7535\u6c60\u663e\u793a\u51fa\u7ea61.37 V\u7684\u7a33\u5b9a\u7684\u653e\u7535\u7535\u538b\u3002\u8fd9\u9879\u5de5\u4f5c\u5c06\u628a\u7535\u6c60\u7684\u7814\u7a76\u6269\u5c55\u5230Mn<sup>2+<\/sup>\u79bb\u5b50\u4f5c\u4e3a\u7535\u8377\u8f7d\u4f53\uff0c\u5e76\u4e14\u6709\u52a9\u4e8e\u6539\u5584\u6c34\u7cfb\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72473-2.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-231560\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72473-2.jpg\" alt=\"\" width=\"706\" height=\"644\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72473-2.jpg 706w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72473-2-300x274.jpg 300w\" sizes=\"(max-width: 706px) 100vw, 706px\" \/><\/a><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5 <\/strong><a href=\"https:\/\/www.nature.com\/articles\/s41467-021-27313-5\"><strong>https:\/\/www.nature.com\/articles\/s41467-021-27313-5<\/strong><\/a><\/p>\n<p><strong>\u56db\u3001\u6210\u4f1a\u660eAdv. Mater\u8c03\u63a7\u916f\u7c7b\u7535\u89e3\u8d28\u6eb6\u5242\u5316\u7ed3\u6784\u6765\u6784\u5efa\u7a33\u5b9a\u7684\u754c\u9762\u5c42 \u00a0\u00a0\u00a0\u00a0\u00a0<\/strong><\/p>\n<p>\u9502\u91d1\u5c5e\u7535\u6c60\u56e0\u5176\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u800c\u88ab\u8ba4\u4e3a\u662f\u6709\u524d\u9014\u7684\u4e0b\u4e00\u4ee3\u7535\u6c60\u3002\u7136\u800c\uff0c\u7531\u4e8e\u78b3\u9178\u916f\u7535\u89e3\u8d28\u4e0e\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u76f8\u5bb9\u6027\u5dee\uff0c LiNO<sub>3<\/sub>\u4f5c\u4e3a\u65e0\u6781\u6dfb\u52a0\u5242\u5df2\u88ab\u7528\u4e8e\u89e3\u51b3\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u95ee\u9898\u3002\u4f46\u662f\uff0cLiNO<sub>3<\/sub>\u5728\u916f\u7c7b\u7535\u89e3\u8d28\u4e2d\u7684\u6eb6\u89e3\u5ea6\u5341\u5206\u6709\u9650\u3002\u800c\u4e14\u6dfb\u52a0\u5242\u4e00\u65e6\u5728\u524d\u51e0\u4e2a\u5faa\u73af\u4e2d\u88ab\u6d88\u8017\uff0c\u5c31\u4e0d\u80fd\u5f62\u6210\u7a33\u5b9a\u7684SEI\u5c42\u3002\u5728\u542bLiPF<sub>6<\/sub>\u7684\u7535\u89e3\u8d28\u4e2d\uff0cSEI\u5c42\u7684\u5b8c\u6574\u6027\u88abLiPF<sub>6<\/sub>\u5206\u89e3\u4ea7\u751f\u7684HF\u7834\u574f\uff0c\u56e0\u6b64\u4e0d\u80fd\u7528\u4e8e\u9502\u91d1\u5c5e\u7535\u6c60\u3002\u9488\u5bf9\u8fd9\u4e2a\u95ee\u9898\uff0c\u6e05\u534e\u5927\u5b66\u6df1\u5733\u56fd\u9645\u7814\u7a76\u751f\u9662\u6210\u4f1a\u660e\u9662\u58eb\u7b49\u901a\u8fc7\u5411\u5546\u7528\u78b3\u9178\u76d0\u7535\u89e3\u6db2\u4e2d\u5f15\u5165LiNO<sub>3<\/sub>\u6dfb\u52a0\u5242\u548c\u5c11\u91cf\u56db\u7532\u57fa\u8132\u4f5c\u4e3a\u591a\u529f\u80fd\u5171\u6eb6\u5242\uff0c\u901a\u5e38\u4e0d\u6eb6\u7684NO<sup>3-<\/sup>\u53ef\u4ee5\u5f15\u5165Li<sup>+<\/sup>\u7684\u6eb6\u5242\u5316\u7ed3\u6784\u4e2d\uff0cLiNO<sub>3<\/sub>\u6eb6\u89e3\u5728\u78b3\u9178\u76d0\u7535\u89e3\u8d28\u4e2d\uff0c\u5e76\u5728\u8d1f\u6781\u4e0a\u4f18\u5148\u88ab\u8fd8\u539f\u3002\u5f62\u6210\u7684\u5bcc\u542bLi<sub>3<\/sub>N \u7684SEI\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387, \u5e76\u4e14\u5728\u8f83\u5927\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u7a33\u5b9a\uff0c\u4ece\u800c\u4f7f\u9502\u5728\u57fa\u5e95\u4e0a\u5747\u5300\u6c89\u79ef\u3002\u540c\u65f6\uff0c\u901a\u8fc7\u63a7\u5236\u6eb6\u5242\u5316\u7ed3\u6784\u548c\u6e05\u9664\u4f5c\u7528\uff0c\u6291\u5236\u4e86HF\u7684\u751f\u6210\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5728\u5ba4\u6e29\u4e0b\uff0c\u4f7f\u7528\u6240\u8bbe\u8ba1\u7684\u78b3\u9178\u76d0\u7535\u89e3\u8d28\u7684Li||Cu\u534a\u7535\u6c60\u57281 mA cm<sup>-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5e93\u4ed1\u6548\u7387\u53ef\u8fbe\u523098.19%\uff0c\u5728\u4f4e\u6e29\uff08- 15 \u2103\uff09\u4e0b\u53ef\u8fbe\u523096.14%\uff0c\u5728600\u6b21\u5faa\u73af\u540e\uff0cLi || LFP\u7535\u6c60\u5177\u6709\u826f\u597d\u7684\u957f\u671f\u7a33\u5b9a\u6027\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u9ad8\u8fbe97.6%\uff0cCE\u9ad8\u8fbe99.7%\u3002\u8fd9\u9879\u5de5\u4f5c\u63d0\u4f9b\u4e86\u4e00\u79cd\u7b80\u5355\u800c\u6709\u6548\u7684\u65b9\u6cd5\u6765\u63a8\u5e7f\u9ad8\u6027\u80fd\u7535\u6c60\u7cfb\u7edf\u4e2d\u5546\u7528\u7535\u89e3\u6db2\u7684\u4f7f\u7528\u3002\uff0c\u8fd9\u9879\u5de5\u4f5c\u4e3a\u4e0b\u4e00\u4ee3\u7535\u6c60\u7cfb\u7edf\u63a8\u5e7f\u5546\u7528\u78b3\u9178\u76d0\u7535\u89e3\u6db2\u63d0\u4f9b\u4e86\u4e00\u79cd\u7b80\u5355\u6709\u6548\u7684\u65b9\u6cd5\u3002\u4e0b\u56fe\u662fCCE\u548cCCE-TMU\/LiNO<sub>3<\/sub>\u7535\u89e3\u8d28\u4e2d\u6eb6\u5242\u5316\u7ed3\u6784\u3001SEI\u6210\u5206\u3001\u9502\u6c89\u79ef\u5f62\u8c8c\u3001HF\u4fb5\u8680\u3001CEI\u539a\u5ea6\u548c\u7535\u5316\u5b66\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\u793a\u610f\u56fe<\/p>\n<p><strong>\u00a0<a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72474-3.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-231561\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72474-3.jpg\" alt=\"\" width=\"692\" height=\"415\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72474-3.jpg 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72474-3-300x180.jpg 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/a><\/strong><\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5: https:\/\/doi.org\/10.1002\/adma.202108400<\/strong><\/p>\n<p><strong>\u4e94\u3001\u5b59\u5b66\u826f<\/strong> \u00a0<strong>\u00a0Nature communications <\/strong>\u00a0\u00a0<strong>\u5421\u54af<\/strong><strong>-N4<\/strong><strong>\u578b\u5355\u539f\u5b50\u50ac\u5316\u5242<\/strong><\/p>\n<p>\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08SACs\uff09\u4ee5\u5176\u4f18\u8d8a\u7684\u50ac\u5316\u6027\u80fd\u5728\u8bb8\u591a\u9886\u57df\u5f97\u5230\u4e86\u5e94\u7528\u3002\u7531\u4e8e\u5355\u539f\u5b50\u4f4d\u7f6e\u7684\u72ec\u7279\u6027\u8d28\uff0c\u5229\u7528\u5355\u539f\u5b50\u4f5c\u4e3a\u50ac\u5316\u5242\u5408\u6210SACs\u662f\u5f88\u6709\u524d\u666f\u7684\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5176\u9ad8\u5ea6\u4e0d\u9971\u548c\u7684\u914d\u4f4d\u73af\u5883\uff0c\u975e\u5747\u5300\u652f\u6491\u7684\u5355\u539f\u5b50\u5177\u6709\u663e\u8457\u589e\u52a0\u7684\u8868\u9762\u81ea\u7531\u80fd\uff0c\u8fd9\u53ef\u80fd\u5bfc\u81f4\u5b83\u4eec\u805a\u96c6\u6210\u7eb3\u7c73\u9897\u7c92\uff0c\u7279\u522b\u662f\u5728\u9ad8\u91d1\u5c5e\u8d1f\u8f7d\u91cf\u7684\u60c5\u51b5\u4e0b\uff0c\u7eb3\u7c73\u9897\u7c92\u7684\u56e2\u805a\u73b0\u8c61\u5c24\u4e3a\u660e\u663e\u3002\u539f\u5b50\u5c42\u6c89\u79ef\uff08ALD\uff09\u662f\u4e00\u79cd\u4f9d\u8d56\u4e8e\u81ea\u9650\u5f0f\u7684\u8fde\u7eed\u8868\u9762\u5316\u5b66\u53cd\u5e94\u7684\u5236\u5907\u6280\u672f\uff0c\u7528\u4e8e\u5408\u6210\u975e\u8d35\u91d1\u5c5e\u5355\u539f\u5b50\u50ac\u5316\u5242\uff0c\u4e0d\u5e78\u7684\u662f\uff0c\u7531\u4e8e\u9ad8\u7684\u89e3\u79bb\u80fd\u5792\uff0c\u4ee5\u53ca\u91d1\u5c5e\u524d\u9a71\u4f53\u7684\u4e3b\u8981\u662f\u5f31\u7684\u7269\u7406\u5438\u9644\uff0c\u5bfc\u81f4\u4f4e\u91d1\u5c5e\u8d1f\u8f7d\u91cf\u548c\u7eb3\u7c73\u9897\u7c92\u7684\u5f62\u6210\uff0c\u7279\u522b\u662f\u5728\u78b3\u57fa\u8f7d\u4f53\u4e0a\u3002\u9488\u5bf9\u4ee5\u4e0a\u5b58\u5728\u7684\u95ee\u9898\uff0c\u897f\u5b89\u5927\u7565\u5927\u5b66\u5b59\u5b66\u826f\u6559\u6388\u56e2\u961f\u9996\u5148\u901a\u8fc7\u5728N\u63ba\u6742\u78b3\u7eb3\u7c73\u7247\uff08Pt1\/NCNS\uff09\u4e0a\u8d1f\u8f7dPt\u5355\u539f\u5b50\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u901a\u8fc7\u539f\u5b50\u5c42\u6c89\u79ef\u5408\u6210Co-SAC\u3002 XAS\u7ed3\u679c\u63ed\u793a\u4e86Co<sub>1<\/sub>\u539f\u5b50\u7684\u5355\u5206\u6563\uff0c XAS\u548cHAADFSTEM\u4e5f\u8bc1\u5b9e\u4e86\uff0c\u7ecfCo\u6c89\u79ef\u540e\uff0cPt<sub>1<\/sub>\u539f\u5b50\u4ecd\u7136\u5448\u73b0\u539f\u5b50\u7ea7\u5206\u6563\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8868\u660e\uff0c\u8fd9\u79cd\u5408\u6210\u7b56\u7565\u662f\u901a\u7528\u7684\uff0c\u5e76\u4e14\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u6269\u5c55\u5230Fe SACs\u548cNi SACs\u7684\u5408\u6210\u3002XANES\u6a21\u62df\u548c EXAFS\u5206\u6790\u7ed3\u679c\u8868\u660e\uff0c\u83b7\u5f97\u7684Co SACs\u3001Fe SACs\u548cNi SACs\u4e3aM1-pyrrolic-N4\u7ed3\u6784\uff08M=Fe\u3001Co\u548cNi\uff09\u3002DFT\u8ba1\u7b97\u8868\u660e\uff0cPt1\u539f\u5b50\u53ef\u4ee5\u6709\u6548\u4fc3\u8fdbCo(Cp)<sub>2<\/sub>\u89e3\u79bb\u6210CoCp\u548cCp\u3002Co(Cp)\u4ea7\u7269\u901a\u8fc7\u5f3a\u70c8\u7684\u5316\u5b66\u5438\u9644\u8fdb\u4e00\u6b65\u6c89\u79ef\u5728\u8f7d\u4f53\u4e0a\uff0c\u4ece\u800c\u5b9e\u73b0\u66f4\u9ad8\u7684\u91d1\u5c5e\u8d1f\u8f7d\u91cf\u548cCo<sub>1<\/sub>\u539f\u5b50\u7684\u5f62\u6210\u3002\u5728\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u4e0b\u5bf9\u8fd9\u4e9bSAC\u8fdb\u884c\u4e86\u8bc4\u4f30\uff0c\u73b0\u573aXAS\u7814\u7a76\u63ed\u793a\u4e86\u5355\u539f\u5b50\u4f4d\u70b9\u7684\u6027\u8d28\u3002\u6b64\u5916\uff0c\u5728\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u4e2d\uff0cNi<sub>1<\/sub> SAC\u663e\u793a\u51fa\u6bd4Fe1\u548cCo<sub>1<\/sub> SAC\u66f4\u9ad8\u7684\u6d3b\u6027\uff0c\u8fd9\u4e0eDFT\u9884\u6d4b\u4e00\u81f4\u3002\u3002\u8fd9\u4e9b\u65b0\u53d1\u73b0\u5c06\u6269\u5c55SACs\u7684\u5236\u5907\u65b9\u6cd5\uff0c\u4e3a\u65b0\u578bSACs\u7684\u5408\u7406\u8bbe\u8ba1\u63d0\u4f9b\u6307\u5bfc\u610f\u4e49\u3002<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72475-1.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-231562\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72475-1.jpg\" alt=\"\" width=\"692\" height=\"509\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72475-1.jpg 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72475-1-300x221.jpg 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/a><\/p>\n<p><strong>\u5168\u6587\u94fe\u63a5\uff1ahttps:\/\/www.nature.com\/articles\/s41467-021-27143-5<\/strong><\/p>\n<p><strong>\u516d\u3001\u738b\u6625\u751f Nature Nanotechnology\u00a0 \u94a0\u7535\u754c\u9762\u5de5\u7a0b\u4f7f\u4f4e\u6e29\u94a0\u91d1\u5c5e\u7535\u6c60\u5b9e\u7528\u5316<\/strong><\/p>\n<p>\u56fa\u6001\u94a0\u7535\u6c60\u9762\u4e34\u7684\u7684\u4e3b\u8981\u95ee\u9898\u662f\u56fa\u4f53\u7535\u89e3\u8d28\u548c\u7535\u6781\u4e4b\u95f4\u7684\u9ad8\u754c\u9762\u7535\u963b\u4ee5\u53ca\u94a0\u679d\u6676\u751f\u957f\u3002\u5728\u8fd9\u91cc\uff0c\u9a6c\u91cc\u5170\u5927\u5b66\u738b\u6625\u751f\u6559\u6388\u8bfe\u9898\u7ec4\u7b49\u63d0\u51fa\u5c06~37wt%\u6c27\u5316\u9487\u7a33\u5b9a\u7684\u6c27\u5316\u9506\u52a0\u5165\u5230BASE\uff08YSZ@BASE\uff09\u4e2d\uff0c\u572880\u2103\u4e0b,\u5c06\u754c\u9762\u7535\u963b\u4ece6.6\uff08BASE\/Na\uff09\u964d\u4f4e\u52303.6\u03a9cm2\uff08YSZ@BASE \/Na\uff09\uff0c\u5e76\u4e14\u5728&gt;330\u5c0f\u65f6\u7684\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u7ef4\u6301\u4e86\u8f83\u4f4e\u7684\u754c\u9762\u7535\u963b\u3002\u5bf9\u79f0Na\/YSZ@BASE \/Na\u7535\u6c60\u4e2dYSZ@BASE\u7684\u4e34\u754c\u7535\u6d41\u5bc6\u5ea6\u572880\u2103\u548c~0.18 MPa\u7684\u6e29\u548c\u538b\u529b\u4e0b\u8fbe\u5230~7.0 mA cm<sup>-2<\/sup>\u7684\u6781\u9ad8\u503c\uff0c\u51e0\u4e4e\u662f\u7eafBASE\u7535\u6c60\u76845\u500d (~1.5 mA cm<sup>\u20132<\/sup>)\u3002YSZ\u901a\u8fc7\u63d0\u9ad8\u65ad\u88c2\u97e7\u6027\u548c\u964d\u4f4eYSZ@BASE\u6750\u6599\u7684\u6574\u4f53\u7535\u5b50\u4f20\u5bfc\uff0c\u5728\u6291\u5236\u94a0\u679d\u6676\u7a7f\u900f\u65b9\u9762\u8d77\u7740\u5173\u952e\u4f5c\u7528\uff0c\u53ef\u9632\u6b62\u5185\u90e8\u94a0\u6c89\u79ef\u3002\u4f5c\u4e3a\u6c27\u79bb\u5b50\u5bfc\u4f53\uff0c\u6c27\u5316\u9487\u7a33\u5b9a\u7684\u6c27\u5316\u9506(YSZ)\u8fd8\u53ef\u4ee5\u4f20\u8f93\u6c27\u79bb\u5b50\uff0c\u4ece\u800c\u6d88\u9664\u03b2-\u6c27\u5316\u94dd\u56fa\u4f53\u7535\u89e3\u8d28\u8fd8\u539f\u5f15\u8d77\u7684\u6c27\u7a7a\u4f4d\uff0c\u4ece\u800c\u5f62\u6210\u8584\u800c\u7a33\u5b9a\u7684\u5bcc\u542b\u03b2-NaAlO<sub>2<\/sub>\u7684SEI\uff0c\u800c\u4e0d\u662f\u8f83\u539a\u7684\u5bcc\u542bNa<sub>2<\/sub>O\u7684SEI\u3002\u91c7\u7528\u5bcc\u954d\u6b63\u6781\u7684\u5168\u7535\u6c60\u53ef\u4ee5\u8fbe\u5230110 mAh g-1\u7684\u9ad8\u7684\u521d\u59cb\u5bb9\u91cf\uff0c\u5e76\u5728500\u6b21\u5faa\u73af\u4e2d\u5bb9\u91cf\u4fdd\u6301\u738773%\uff0c\u57284C\u7684\u500d\u7387\u4e0b\u5e93\u4ed1\u6548\u7387&gt;99.99%\uff0c\u8fd9\u9879\u7814\u7a76\u4ee3\u8868\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u94a0\u7535\u6c60\uff0c\u4e0eNa-S\u4ee5\u53ca\u5176\u4ed6\u56fa\u6001\u7535\u6c60\u76f8\u6bd4\uff0c\u5177\u6709\u663e\u8457\u66f4\u4f4e\u7684\u5de5\u4f5c\u6e29\u5ea6\u548c\u66f4\u9ad8\u7684\u5b89\u5168\u6027<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72476-3.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-231563\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72476-3.jpg\" alt=\"\" width=\"692\" height=\"372\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72476-3.jpg 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72476-3-300x161.jpg 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/a><\/p>\n<p><strong>\u5168\u6587\u94fe\u63a5https:\/\/doi.org\/10.1038\/s41565-021-01036-6<\/strong><\/p>\n<p><strong>\u4e03\u3001\u5b5f\u9896 \u5168\u56fa\u6001\u7845\u8d1f\u6781 Science<\/strong><\/p>\n<p>\u7845\u8d1f\u6781\u5faa\u73af\u7a33\u5b9a\u6027\u5dee\u7684\u539f\u56e0\u4e3b\u8981\u662f\u5728\u6db2\u6001\u7535\u89e3\u8d28\u4f53\u7cfb\u91cc\u9ad8\u6d3b\u6027\u7684\u9502\u7845\u5408\u91d1\u548c\u6db2\u4f53\u7535\u89e3\u8d28\u4e4b\u95f4\u8fde\u7eed\u4e0d\u65ad\u7684\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u95f4\u76f8\uff08SEI\uff09\u751f\u957f\uff0c\u800c\u4e0d\u65ad\u751f\u957f\u7684\u539f\u56e0\u662f\u7531\u4e8e\u9502\u5316\u8fc7\u7a0b\u4e2d\u7845\u7684\u5de8\u5927\u4f53\u79ef\u81a8\u80c0\uff08&gt;300%\uff09\u4ee5\u53ca\u7531\u4e8eSEI\u751f\u957f\u548c\u4e0d\u53ef\u9006\u5730\u56f0\u5728\u9502-\u7845\u5408\u91d1\u5185\u800c\u5bfc\u81f4\u7684\u9502\u5e93\u5b58\u635f\u5931\u800c\u52a0\u5267\u3002\u5728\u5168\u56fa\u6001\u7535\u6c60\uff08ASSB\uff09\u4e2d\u4f7f\u7528\u56fa\u6001\u7535\u89e3\u8d28\uff08SSEs\uff09\u662f\u4e00\u79cd\u6709\u5e0c\u671b\u7684\u66ff\u4ee3\u65b9\u6cd5\uff0c\u56e0\u4e3a\u5b83\u80fd\u591f\u5f62\u6210\u7a33\u5b9a\u548c\u949d\u5316\u7684SEI\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u5236\u5907\u4e86\u753199.9wt%\u7684\u5fae\u7c73\u7845\uff08\u03bcSi\uff09\u7ec4\u6210\u7684\u5fae\u7c73\u7845\u7535\u6781\u88ab\u7528\u4e8e\u03bcSi||SSE||\u9502\u954d\u94b4\u9530\u6c27\u5316\u7269\uff08NCM811\uff09\u7535\u6c60\uff0c\u7a33\u5b9a\u5fae\u7c73\u7845\u7684\u754c\u9762\u540c\u65f6\u514b\u670d\u5168\u56fa\u6001\u7535\u6c60\u7684\u7535\u6d41\u5bc6\u5ea6\u9650\u5236\u3002\u4e0e\u4f20\u7edf\u7684\u6db2\u6001\u7535\u6c60\u7ed3\u6784\u4e0d\u540c\uff0cSSE\u4e0d\u4f1a\u901a\u8fc7\u591a\u5b54\u7684\u03bcSi\u7535\u6781\u6e17\u900f\uff08\u56fe1\uff09\uff0c\u5e76\u4e14SSE\u548c\u03bcSi\u7535\u6781\u4e4b\u95f4\u7684\u754c\u9762\u63a5\u89e6\u9762\u79ef\u88ab\u51cf\u5c0f\u5230\u4e8c\u7ef4\uff082 D\uff09\u5e73\u9762\u3002\u03bcSi\u9502\u5316\u540e\uff0c\u5c3d\u7ba1\u4f53\u79ef\u81a8\u80c0\uff0c2 D\u5e73\u9762\u4ecd\u7136\u88ab\u4fdd\u7559\uff0c\u963b\u6b62\u4e86\u65b0\u754c\u9762\u7684\u4ea7\u751f\u3002\u5927\u91cf\u7684\u03bcSi\u8868\u73b0\u51fa\u7ea63\u00d710-5 S cm<sup>-1<\/sup>\u7684\u7535\u5b50\u4f20\u5bfc\u6027\uff0c\u4e0e\u5927\u591a\u6570\u5e38\u89c1\u9634\u6781\u6750\u6599\uff08\u301c10<sup>\u22126<\/sup>\u81f310<sup>\u22124<\/sup> S cm<sup>\u22121<\/sup>\uff09\u76f8\u5f53\uff0c\u56e0\u6b64\u4e0d\u9700\u8981\u989d\u5916\u7684\u78b3\u6dfb\u52a0\u5242\u3002\u6b64\u5916\uff0c\u4f17\u6240\u5468\u77e5\uff0c\u78b3\u4e0d\u5229\u4e8e\u786b\u5316\u7269SSE\u7684\u7a33\u5b9a\u6027\uff0c\u56e0\u4e3a\u5b83\u4fc3\u8fdbSSE\u5206\u89e3\u3002\u5c3d\u7ba1\u67d0\u4e9b\u7c7b\u578b\u7684\u78b3\u5df2\u88ab\u53d1\u73b0\u4e0e\u65e0\u8d1f\u6781ASSB\u517c\u5bb9\uff0c\u4f46\u5728\u03bcSi ASSB\u7cfb\u7edf\u4e2d\u5b8c\u5168\u6d88\u9664\u78b3\u662f\u6700\u4f18\u9009\u7684\u3002\u5728\u03bcSi\u7684\u9502\u5316\u8fc7\u7a0b\u4e2d\uff0cLi-Si\u7684\u5f62\u6210\u53ef\u4ee5\u5728\u6574\u4e2a\u7535\u6781\u4e2d\u4f20\u64ad\uff0c\u8fd9\u5f97\u76ca\u4e8eLi-Si\u548c\u03bcSi\u9897\u7c92\u4e4b\u95f4\u7684\u76f4\u63a5\u79bb\u5b50\u548c\u7535\u5b50\u63a5\u89e6\u3002\u8fd9\u4e00\u8fc7\u7a0b\u88ab\u53d1\u73b0\u662f\u9ad8\u5ea6\u53ef\u9006\u7684\uff0c\u4e0d\u9700\u8981\u4efb\u4f55\u9502\u8fc7\u5269\u3002\u8fdb\u884c\u5355\u72ec\u7684\u5168\u7535\u6c60\u5b9e\u9a8c\uff0c\u5b9e\u73b0\u7535\u6d41\u5bc6\u5ea6\u9ad8\u8fbe5 mA cm\u22122\uff0c\u5728\u221220\u00b0\u548c80\u00b0C\u4e4b\u95f4\u8fd0\u884c\uff0c\u4e0d\u540c\u7535\u6c60\u7684\u9762\u5bb9\u91cf\u9ad8\u8fbe11 mAh cm<sup>\u22122<\/sup>\uff082890 mAh g<sup>\u22121<\/sup>\uff09\u3002\u03bcSi -NCM811\u5168\u7535\u6c60\u57285 mA cm<sup>\u22122<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af500\u6b21\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u9ad8\u8fbe80%\uff0c\u8bc1\u660e\u4e86ASSBs\u4f7f\u03bcSi\u7684\u6574\u4f53\u575a\u56fa\u6027\u5f97\u5230\u4e86\u4f53\u73b0\u3002<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72477-2.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-231564\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72477-2.jpg\" alt=\"\" width=\"692\" height=\"178\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72477-2.jpg 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72477-2-300x77.jpg 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/a><\/p>\n<p><strong>\u5168\u6587\u94fe\u63a5<\/strong><strong>https:\/\/www.science.org\/doi\/10.1h26\/science.abg7217<\/strong><\/p>\n<p><strong>\u516b\u3001\u5929\u6d25\u5927\u5b66\u6768\u5168\u7ea2<\/strong><strong> Nature sustainability <\/strong><strong>\u9ad8\u5b89\u5168\u3001\u4f4e\u6210\u672c\u3001\u9ad8\u6027\u80fd\u65b0\u578b\u7535\u89e3\u6db2<\/strong><\/p>\n<p>\u957f\u671f\u4ee5\u6765\uff0c\u6c34\u7cfb\u950c (Zn) \u7535\u6c60\u4e00\u76f4\u88ab\u8ba4\u4e3a\u662f\u9502\u79bb\u5b50\u7535\u6c60\u7684\u6f5c\u5728\u66f4\u53ef\u6301\u7eed\u7684\u66ff\u4ee3\u54c1\uff0c\u56e0\u4e3a\u5b83\u4eec\u5177\u6709\u66f4\u597d\u7684\u73af\u5883\u517c\u5bb9\u6027\u3001\u66f4\u9ad8\u7684\u5b89\u5168\u6027\u548c\u6210\u672c\u4f18\u52bf\u3002\u7136\u800c\uff0c\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\uff0c\u950c\u8d1f\u6781\u53ef\u80fd\u4f1a\u53d1\u751f\u679d\u6676\u5931\u6548\u3001\u8150\u8680\u548c\u6790\u6c22\uff0c\u4ece\u800c\u5bfc\u81f4\u6027\u80fd\u5feb\u901f\u4e0b\u964d\u3002\u5728\u8fd9\u91cc\uff0c\u5929\u6d25\u5927\u5b66\u6768\u5168\u7ea2\u56e2\u961f\u62a5\u544a\u4e86\u4e00\u79cd\u4f4e\u6210\u672c\u65b0\u578b\u4e0d\u53ef\u71c3\u542b\u6c34\u6709\u673a\u7535\u89e3\u6db2\uff0c\u5305\u62ec\u4f5c\u4e3a\u963b\u71c3\u5242\u7684\u6c34\u5408 Zn(BF<sub>4<\/sub>)<sub>2<\/sub> \u76d0\u548c\u9ad8\u6cb8\u70b9\u7684\u4e59\u4e8c\u9187\u6eb6\u5242\uff0c\u5229\u7528\u4e59\u4e8c\u9187\u7684\u9ad8\u6cb8\u70b9\u53ca\u5176\u5b83\u4e0e\u6c34\u5206\u5b50\u548c\u56db\u6c1f\u787c\u9178\u6839\u9634\u79bb\u5b50\u4e4b\u95f4\u5f62\u6210\u7684\u4e30\u5bcc\u6c22\u952e\u7f51\u7edc\uff0c\u4f7f\u5f97\u7535\u89e3\u6db2\u5177\u5907\u96be\u6325\u53d1\u7684\u7279\u70b9\uff0c\u540c\u65f6\u4f7f\u5f97\u7535\u89e3\u6db2\u53ef\u4ee5\u5728\u4ece -30 \u00b0C \u5230 40 \u00b0C \u7684\u5bbd\u6e29\u5ea6\u8303\u56f4\u5185\u8fd0\u884c\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u56db\u6c1f\u787c\u9178\u6839\u9634\u79bb\u5b50\u548c\u6c34\u5206\u5b50\u4f1a\u8fdb\u4e00\u6b65\u4e0e\u950c\u53d1\u751f\u53cd\u5e94\uff0c\u5728\u950c\u8d1f\u6781\u8868\u9762\u539f\u4f4d\u5f62\u6210\u6c1f\u5316\u950c\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u5c42\uff0c\u4ece\u800c\u6709\u6548\u5730\u4fdd\u62a4\u4e86\u91d1\u5c5e\u950c\u8d1f\u6781\uff0c\u907f\u514d\u4e86\u7531\u4e8e\u950c\u679d\u6676\u523a\u7a7f\u9694\u819c\u4ee5\u53ca\u950c\u4e0e\u7535\u89e3\u6db2\u95f4\u7684\u8150\u8680\u526f\u53cd\u5e94\u5bfc\u81f4\u7684\u7535\u6c60\u8fc7\u65e9\u5931\u6548\uff0c\u540c\u65f6\u8868\u73b0\u51fa\u4e0d\u53ef\u71c3\u6027\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u950c\u8d1f\u6781\u5728 0.5 mA cm<sup>-2<\/sup> \u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u957f\u671f\u5faa\u73af\u8d85\u8fc7 4,000 h\uff0c\u5e93\u4ed1\u6548\u7387\u9ad8\u8fbe 99.4%\uff0c\u9762\u5bb9\u91cf\u9ad8\u8fbe 5 mAh cm<sup>-2<\/sup>\u3002\u4f7f\u7528\u6211\u4eec\u7684\u7535\u89e3\u8d28\u7684 Zn\/\/V<sub>2<\/sub>O<sub>5<\/sub> \u5168\u7535\u6c60\u5728\u5bb9\u91cf\u4fdd\u6301\u7387\u65b9\u9762\u4e5f\u6bd4\u4f7f\u7528 ZnSO<sub>4<\/sub> \u6c34\u6eb6\u6db2\u7535\u89e3\u8d28\u7684\u8868\u73b0\u5f97\u66f4\u597d\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u4e3a\u5f00\u53d1\u517c\u5177\u5b89\u5168\u6027\u3001\u4f4e\u6210\u672c\u548c\u53ef\u6301\u7eed\u6027\u7684\u5b9e\u7528\u950c\u7535\u6c60\u7535\u89e3\u6db2\u89e3\u51b3\u65b9\u6848\u63d0\u4f9b\u4e86\u4e00\u4e2a\u6709\u5e0c\u671b\u7684\u65b9\u5411\uff0c\u6709\u671b\u63a8\u52a8\u9ad8\u6027\u80fd\u950c\u7535\u6c60\u7684\u4ea7\u4e1a\u5316\u5e94\u7528\u3002<\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72478-1.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-231565\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72478-1.jpg\" alt=\"\" width=\"663\" height=\"468\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72478-1.jpg 663w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2021\/12\/\u56fe\u72478-1-300x212.jpg 300w\" sizes=\"(max-width: 663px) 100vw, 663px\" \/><\/a><\/p>\n<p><strong>\u5168\u6587\u94fe\u63a5<\/strong><strong>https:\/\/www.nature.com\/articles\/s41893-021-00800-9<\/strong><\/p>\n<p>\u672c\u6587\u7531Junas\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u5d14\u5c79JACS \u00a0\u00a0\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u589e\u5f3a\u7684\u5168\u56fa\u6001\u9502\u786b\u7535\u6c60 \u6c27\u5316\u8fd8\u539f\u4ecb\u8d28(RMs)\u5728\u67d0\u4e9b\u6db2\u4f53\u7535\u89e3\u8d28\u7535\u5316\u5b66\u50a8\u80fd\u7cfb\u7edf\u4e2d\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002\u7136\u800c\uff0c\u6c27\u5316\u8fd8\u539f\u4ecb\u4f53\u5728\u56fa\u6001\u7535\u6c60\u4e2d\u7684\u6982\u5ff5&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-231556","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/231556"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=231556"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/231556\/revisions"}],"predecessor-version":[{"id":231566,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/231556\/revisions\/231566"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=231556"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=231556"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=231556"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}