{"id":232462,"date":"2022-01-28T06:36:02","date_gmt":"2022-01-27T22:36:02","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=232462"},"modified":"2022-01-27T17:36:15","modified_gmt":"2022-01-27T09:36:15","slug":"%e4%b8%ad%e5%b1%b1%e5%a4%a7%e5%ad%a6%e7%ab%a0%e5%bf%97%e7%8f%8dnature-reviews-materials%ef%bc%9a%e5%ba%94%e7%94%a8paddle-wheel%e6%9c%ba%e5%88%b6%e8%ae%be%e8%ae%a1%e6%96%b0%e5%9e%8b%e5%bf%ab%e7%a6%bb","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=232462","title":{"rendered":"\u4e2d\u5c71\u5927\u5b66\u7ae0\u5fd7\u73cdNature Reviews Materials\uff1a\u5e94\u7528paddle-wheel\u673a\u5236\u8bbe\u8ba1\u65b0\u578b\u5feb\u79bb\u5b50\u5bfc\u4f53"},"content":{"rendered":"<p><strong><b>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/b><\/strong><\/p>\n<p>\u5feb\u79bb\u5b50\u5bfc\u4f53\u662f\u56fa\u6001\u5668\u4ef6\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u7ec4\u6210\u90e8\u5206\uff0c\u8fd9\u7c7b\u6750\u6599\u5728\u56fa\u6001\u72b6\u6001\u4e0b\u8868\u73b0\u51fa\u548c\u6db2\u6001\u5ab2\u7f8e\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u4ece\u539f\u5b50\u5c3a\u5ea6\u4e0a\u7406\u89e3\u79bb\u5b50\u8d85\u5feb\u4f20\u5bfc\u884c\u4e3a\u7684\u672c\u8d28\uff0c\u6709\u52a9\u4e8e\u5176\u5e94\u7528\u4e8e\u56fa\u6001\u7535\u6c60\u7b49\u65b0\u6280\u672f\u4e2d\uff0c\u4f46\u76ee\u524d\u4ecd\u662f\u4e00\u4e2a\u4e25\u5cfb\u7684\u6311\u6218\u3002\u8fc7\u53bb\u4e09\u5341\u5e74\u5bf9\u5404\u79cd\u6750\u6599\u79bb\u5b50\u8f93\u8fd0\u884c\u4e3a\u7684\u7814\u7a76\u5bf9\u7406\u89e3\u9633\u79bb\u5b50\u4f20\u5bfc\u673a\u5236\u63d0\u4f9b\u4e86\u6df1\u523b\u89c1\u89e3\uff0c\u7136\u800c\u8fd9\u4e9b\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u5728\u63a2\u7a76\u9759\u6001\u6676\u683c\u9aa8\u67b6\u5bf9\u9633\u79bb\u5b50\u6269\u6563\u7684\u5f71\u54cd\uff0c\u5ffd\u7565\u4e86\u9633\u79bb\u5b50-\u9634\u79bb\u5b50\u76f8\u4e92\u4f5c\u7528\u7684\u8d21\u732e\u3002\u8fd1\u671f\u7684\u7814\u7a76\u8868\u660e\uff0c\u57fa\u4e8epaddle-wheel\u673a\u5236\u7684\u9634\u79bb\u5b50\u8f6c\u52a8\u5bf9\u4e8e\u9633\u79bb\u5b50\u6269\u6563\u4f20\u5bfc\u5177\u6709\u663e\u8457\u7684\u4fc3\u8fdb\u4f5c\u7528\uff0c\u7136\u800c\uff0c\u9634\u79bb\u5b50\u8f6c\u52a8\u901a\u5e38\u53ea\u5728\u4e00\u4e9b\u79bb\u5b50\u5bfc\u4f53\u7684\u9ad8\u6e29\u76f8\u4e2d\u5b58\u5728\u3002\u672c\u6587\u901a\u8fc7\u56de\u987e\u8fd1\u4e9b\u5e74\u5bf9\u4e8e\u9634\u79bb\u5b50\u8f6c\u52a8\u73b0\u8c61\u7684\u7814\u7a76\u548c\u8ba4\u8bc6\uff0c\u63d0\u51fa\u901a\u8fc7\u91c7\u53d6\u673a\u68b0\u65b9\u6cd5\u6216\u8005\u7f3a\u9677\u5316\u5b66\u7684\u65b9\u6cd5\u53ef\u4ee5\u5c06\u9634\u79bb\u5b50\u8f6c\u52a8\u7a33\u5b9a\u5728\u5ba4\u6e29\uff0c\u4ece\u800c\u5728\u5ba4\u6e29\u4e0b\u5229\u7528paddle-wheel\u4fc3\u8fdb\u9633\u79bb\u5b50\u4f20\u5bfc\uff0c\u4e3a\u8bbe\u8ba1\u65b0\u578b\u7684\u5feb\u79bb\u5b50\u5bfc\u4f53\u63d0\u4f9b\u4e86\u65b0\u7684\u6307\u5bfc\u601d\u8def\u3002<\/p>\n<p><strong><b>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u4e2d\u5c71\u5927\u5b66\u7ae0\u5fd7\u73cd\u6559\u6388\uff08\u4e00\u4f5c\uff09<\/b><\/strong>\u3001<strong><b>\u52a0\u62ff\u5927\u6ed1\u94c1\u5362\u5927\u5b66Linda Nazar\u9662\u58eb\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u57fa\u4e8e\u5176\u5728\u8fd1\u671f\u7684\u7814\u7a76\u5de5\u4f5c\u4e2d\uff08J. Am. Chem. Soc., 2019, 141, 19360-19372\uff1bMatter, 2020\uff0c2 (6), 1667-1684\uff09\u9996\u6b21\u53d1\u73b0\u5ba4\u6e29\u805a\u9634\u79bb\u5b50\u8f6c\u52a8\u73b0\u8c61\u53ca\u9634\u79bb\u5b50\u8f6c\u52a8\u901a\u8fc7paddle-wheel\u673a\u5236\u4fc3\u8fdb\u9633\u79bb\u5b50\u4f20\u5bfc\u8fd9\u4e00\u65b0\u7684\u79bb\u5b50\u4f20\u5bfc\u673a\u5236\u8fdb\u884c\u4e86\u8bc4\u8ff0\uff0c\u5bf9\u9634\u79bb\u5b50\u8f6c\u52a8\u5982\u4f55\u5f71\u54cd\u9633\u79bb\u5b50\u7684\u6269\u6563\u5c55\u5f00\u4e86\u6df1\u5165\u7684\u8ba8\u8bba\uff0c\u5e76\u63d0\u51fa\u5c06\u9634\u79bb\u5b50\u8f6c\u52a8\u7a33\u5b9a\u5728\u5ba4\u6e29\u7684\u7b56\u7565\u4ece\u800c\u6210\u529f\u5730\u5728\u5ba4\u6e29\u4e0b\u5229\u7528paddle-wheel\u673a\u5236\u6765\u663e\u8457\u63d0\u9ad8\u9633\u79bb\u5b50\u7535\u5bfc\u7387\uff08\u51e0\u4e2a\u6570\u91cf\u7ea7\uff09\u3002\u8be5\u7814\u7a76\u4ee5\u9898\u4e3a\u201cExploiting the Paddle-Wheel Mechanism for the Design of Fast Ion Conductors\u201d\u7684\u8bba\u6587\u53d1\u8868\u5728\u6750\u6599\u9886\u57df\u56fd\u9645\u9876\u7ea7\u5b66\u672f\u671f\u520a\u300aNature Reviews Materials\u300b\u3002\u201d<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232464\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u7247-8-1.png\" alt=\"\" width=\"943\" height=\"424\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u7247-8-1.png 943w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u7247-8-1-300x135.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u7247-8-1-768x345.png 768w\" sizes=\"(max-width: 943px) 100vw, 943px\" \/><\/p>\n<p><strong><b>\u3010\u7814\u7a76\u4eae\u70b9\u3011<\/b><\/strong><\/p>\n<p>(1). \u5c06\u65e0\u673a\u79bb\u5b50\u5bfc\u4f53\u4e2d\u7684\u9634\u79bb\u5b50\u8f6c\u52a8\u884c\u4e3a\u4e0e\u5851\u6676\u6750\u6599\u4e2d\u7684\u79bb\u5b50\u884c\u4e3a\u8fdb\u884c\u4e86\u7c7b\u6bd4\uff0c\u5e76\u5bf9\u5404\u79cd\u7c7b\u578b\u7684\u9634\u79bb\u5b50\u8f6c\u52a8\u884c\u4e3a\u53ca\u5176\u4e0e\u9633\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u5173\u7cfb\u8fdb\u884c\u4e86\u68b3\u7406\uff1b<\/p>\n<p>(2). \u6df1\u5165\u63a2\u8ba8\u4e86\u9634\u79bb\u5b50\u8f6c\u52a8\u5982\u4f55\u901a\u8fc7paddle-wheel\u673a\u5236\u6539\u53d8\u9633\u79bb\u5b50\u4f20\u5bfc\u6240\u611f\u77e5\u7684\u52bf\u5792\uff0c\u4ece\u800c\u4fc3\u8fdb\u9633\u79bb\u5b50\u4f20\u5bfc\uff1b<\/p>\n<p>(3). 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1a\u5bf9\u6bd4\u8bf4\u660e\u4e86\u6709\u5e8f\u76f8\u548c\u5851\u6676\uff08\u8f6c\u52a8\u76f8\uff09\u4e2d\u5206\u5b50\u7684\u53d6\u5411\u3002<\/p>\n<p>\u5851\u6676\u5177\u6709\u591a\u79cd\u7279\u5f81\uff0c\u5176\u4e00\u662f\u5355\u4ef7\u548c\u4e8c\u4ef7\u9633\u79bb\u5b50\u5747\u53ef\u5728\u5851\u6027\u6676\u4f53\u4e2d\u8868\u73b0\u51fa\u9ad8\u7684\u53ef\u79fb\u52a8\u6027\uff0c\u4ec5\u56e0\u9633\u79bb\u5b50\u5c3a\u5bf8\u5dee\u5f02\u800c\u7565\u6709\u4e0d\u540c\uff0c\u663e\u8457\u533a\u522b\u4e8e\u5e38\u89c1\u7684\u56fa\u6001\u7535\u89e3\u8d28\uff08\u9633\u79bb\u5b50\u7684\u53ef\u79fb\u52a8\u6027\u4e3b\u8981\u53d6\u51b3\u4e8e\u79bb\u5b50\u534a\u5f84\u548c\u4ef7\u6001\uff09\uff1b\u53e6\u4e00\u4e2a\u663e\u8457\u7279\u5f81\u662f\u76f8\u8f83\u4e8e\u6709\u5e8f\u6676\u4f53\uff0c\u5851\u6676\u5728\u7194\u5316\u65f6\u5177\u6709\u8f83\u5c0f\u7684\u7113\u53d8\u548c\u71b5\u53d8\uff0c\u800c\u53d1\u751f\u56fa\u6001\u76f8\u53d8\u65f6\u7113\u53d8\u548c\u71b5\u53d8\u8f83\u5927\uff08\u56fe1b\uff09\u3002<\/p>\n<p>\u56fe1.\u00a0\u5851\u6027\u6676\u4f53\u7684\u7279\u70b9<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232466\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/Group-10.png\" alt=\"\" width=\"1297\" height=\"428\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/Group-10.png 1297w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/Group-10-300x99.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/Group-10-768x253.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/Group-10-1024x338.png 1024w\" sizes=\"(max-width: 1297px) 100vw, 1297px\" \/><\/p>\n<p>(a\uff09\u6709\u5e8f\u76f8\u548c\u8f6c\u5b50\u76f8\uff08\u5851\u6027\u6676\u4f53\uff09\u4e2d\u5206\u5b50\u53d6\u5411\u7684\u5bf9\u6bd4\uff1b<\/p>\n<p>(b)\u5178\u578b\u7684\u6709\u5e8f\u6676\u4f53\u548c\u5851\u6027\u6676\u4f53\u7194\u5316\u7113\u53d8\u548c\u56fa\u76f8\u8f6c\u53d8\u7113\u53d8\u3002<\/p>\n<p>\u8868\u5f81\u9634\u79bb\u5b50\u8fd0\u52a8\u7684\u6280\u672f\u624b\u6bb5<\/p>\n<p>\u6838\u78c1\u5171\u632f\uff08NMR\uff09\u53ef\u7528\u4e8e\u6d4b\u91cf\u8f83\u5bbd\u7684\u65f6\u95f4\u5c3a\u5ea6\u5185\u9634\u79bb\u5b50\u548c\u9633\u79bb\u5b50\u7684\u8fd0\u52a8\uff0c\u56fa\u6001\u6838\u78c1\u5f1b\u8c6b\u6cd5\u53ef\u83b7\u5f97\u539f\u5b50\u8dc3\u8fc1\u9891\u7387\u3001\u6269\u6563\u7cfb\u6570\u53ca\u76f8\u5173\u6d3b\u5316\u80fd\u3001\u9634\u9633\u79bb\u5b50\u8fd0\u52a8\u8fc7\u7a0b\u4e2d\u662f\u5426\u534f\u540c\u6548\u5e94\u7b49\u4fe1\u606f\u3002\u6269\u6563\u7cfb\u6570\uff08Dr\uff09\u7684\u7ed3\u679c\u53cd\u6620\u4e86\u4e0eNMR\u76f8\u4e92\u4f5c\u7528\u7684\u65f6\u95f4\u5c3a\u5ea6\u76f8\u5f53\u7684\u5c40\u90e8\u8fd0\u52a8\u8fc7\u7a0b\u3002\u7531\u4e8e\u4e2d\u5b50\u7684\u6ce2\u957f\u3001\u52a8\u80fd\u4e0e\u6750\u6599\u4e2d\u539f\u5b50\u95f4\u8ddd\u79bb\u3001\u6fc0\u53d1\u80fd\u76f8\u8fd1\uff0c\u51c6\u5f39\u6027\u4e2d\u5b50\u6563\u5c04\uff08QENS\uff09\u53ef\u7528\u4e8e\u63a2\u6d4b\u957f\u7a0b\u6269\u6563\u8fd0\u52a8\u548c\u77ed\u7a0b\u5c40\u90e8\u8fd0\u52a8\u76f8\u5173\u7684\u52a8\u529b\u5b66\u8fc7\u7a0b\u3002\u4f7f\u7528\u6700\u5927\u71b5\u6cd5\uff08MEM\uff09\u5206\u6790\u4e2d\u5b50\u884d\u5c04\u7684\u6570\u636e\uff0c\u91cd\u6784\u6838\u5bc6\u5ea6\u56fe\uff0c\u53ef\u4ee5\u83b7\u5f97\u7eb3\u79d2\u5c3a\u5ea6\u5185\u7ed3\u6784\u65e0\u5e8f\u7684\u76f8\u5173\u4fe1\u606f\uff0c\u8fdb\u800c\u63a2\u7d22\u805a\u9634\u79bb\u5b50\u7684\u65cb\u8f6c\u8fd0\u52a8\u3002\u4ece\u5934\u7b97\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\uff08AIMD\uff09\u80fd\u591f\u8bb0\u5f55\u6bcf\u4e2a\u539f\u5b50\u5728\u98de\u79d2\u5c3a\u5ea6\u5185\u7684\u8fd0\u52a8\u4fe1\u606f\uff0c\u5f25\u8865\u4e86QENS\u548cMEM\u4ec5\u80fd\u83b7\u5f97\u539f\u5b50\u8fd0\u52a8\u7684\u7edf\u8ba1\u5e73\u5747\u4fe1\u606f\u7684\u4e0d\u8db3\uff0c\u53ef\u76f4\u63a5\u8bc1\u660e\u9634\u9633\u79bb\u5b50\u7684\u8fd0\u52a8\u7684\u52a8\u529b\u5b66\u4fe1\u606f\uff0c\u4ece\u800c\u7814\u7a76\u5176\u8026\u5408\u5173\u7cfb\u3002<\/p>\n<p>\u65e0\u673a\u5bfc\u4f53\u4e2d\u9634\u79bb\u5b50\u7684\u65cb\u8f6c<\/p>\n<p>\u8fc7\u53bb\u56db\u5341\u5e74\u7684\u7814\u7a76\u8868\u660e\uff0c\u8f6c\u52a8\u76f8\u5b58\u5728\u4e8e\u78b1\u91d1\u5c5e\u65e0\u673a\u76d0\u4e2d\uff08\u56fe2\uff09\u3002\u4f5c\u8005\u5c06\u5b58\u5728\u9634\u79bb\u5b50\u65e0\u5e8f\u6216\u9634\u79bb\u5b50\u65cb\u8f6c\u8fd0\u52a8\u7684\u76d0\u6309\u7ed3\u6784\u5206\u7c7b\u5e76\u5206\u522b\u4ecb\u7ecd\u5176\u7279\u70b9\uff0c\u4ece\u800c\u5efa\u7acb\u8d77\u9634\u79bb\u5b50\u8f6c\u52a8\u3001\u6676\u4f53\u7ed3\u6784\u7279\u70b9\u3001\u9633\u79bb\u5b50\u8f93\u8fd0\u6027\u8d28\u4e4b\u95f4\u7684\u8054\u7cfb\u3002<\/p>\n<p>\u56fe2.\u6709\u673a\u548c\u65e0\u673a\u76d0\u4e2d\u8f6c\u52a8\u76f8\u7684\u53d1\u73b0\u65f6\u95f4\u8868\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232467\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72471-9.png\" alt=\"\" width=\"778\" height=\"307\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72471-9.png 778w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72471-9-300x118.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72471-9-768x303.png 768w\" sizes=\"(max-width: 778px) 100vw, 778px\" \/><\/p>\n<p><strong><b>1 \u00a0[SO<\/b><\/strong><strong><sub><b>4<\/b><\/sub><\/strong><strong><b>]<\/b><\/strong><strong><sup><b>2-<\/b><\/sup><\/strong><strong><b>\u4e0e[PO<\/b><\/strong><strong><sub><b>4<\/b><\/sub><\/strong><strong><b>]<\/b><\/strong><strong><sup><b>3-<\/b><\/sup><\/strong><strong><b>\u7684\u65cb\u8f6c<\/b><\/strong><\/p>\n<p>\u4e00\u4e9b\u5177\u6709[SO<sub>4<\/sub>]<sup>2-<\/sup>\u548c[PO<sub>4<\/sub>]<sup>3-<\/sup>\u7684\u65e0\u673a\u76d0\u5728\u9ad8\u6e29\u65f6\u5448\u5851\u6676\u76f8\uff0c\u5373[SO<sub>4<\/sub>]<sup>2-<\/sup>\u548c[PO<sub>4<\/sub>]<sup>3-<\/sup>\u805a\u9634\u79bb\u5b50\u53d1\u751f\u65cb\u8f6c\u8fd0\u52a8\uff0c\u8fd9\u79cd\u65cb\u8f6c\u8fd0\u52a8\u4e0e\u6709\u5e8f-\u65e0\u5e8f\u76f8\u53d8\u65f6\u4f34\u968f\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u51e0\u4e2a\u6570\u91cf\u7ea7\u7684\u8df3\u8dc3\u540c\u65f6\u53d1\u751f\u3002Li<sub>2<\/sub>SO<sub>4<\/sub>\u662f\u9996\u4e2a\u88ab\u62a5\u9053\u7684\u5177\u6709\u8fd9\u79cd\u9634\u79bb\u5b50\u8f6c\u52a8\u73b0\u8c61\u7684\u6750\u6599\uff0c\u8be5\u5316\u5408\u7269\u5728\u8f6c\u53d8\u6e29\u5ea6T<sub>trans<\/sub>\uff08848K\uff09\u65f6\u53d1\u751f\u4e00\u7ea7\u76f8\u53d8\uff0c\u4ece\u5355\u659c\u03b2\u591a\u6676\u8f6c\u53d8\u4e3a\u7acb\u65b9\u03b1\u76f8\u3002\u5b83\u7684\u4f4e\u6e29\u56db\u65b9\u76f8\u5177\u6709\u8f83\u5dee\u7684\u79bb\u5b50\u5bfc\u7535\u6027\u548c\u8f83\u9ad8\u7684\u6d3b\u5316\u80fd\uff08E<sub>a<\/sub>\uff1e2 eV\uff09\uff0c\u5f53\u6e29\u5ea6\u63a5\u8fd1\u76f8\u53d8\u6e29\u5ea6T<sub>trans<\/sub>\u65f6\uff0cLi<sup>+<\/sup>\u79bb\u5b50\u7535\u5bfc\u7387\u63d0\u9ad8\u4e86\u56db\u4e2a\u6570\u91cf\u7ea7\u3002\u8fd9\u4e00\u53d1\u73b0\u5f53\u65f6\u5e76\u6ca1\u6709\u5f15\u8d77\u8db3\u591f\u7684\u91cd\u89c6\uff0c\u76f4\u5230\u540e\u6765\u786e\u5b9a\u9ad8\u6e29\u76f8\u7684\u03b1-Li<sub>2<\/sub>SO<sub>4<\/sub>\u5176\u9634\u79bb\u5b50\u5c5e\u4e8e\u9762\u5fc3\u7acb\u65b9\u5bc6\u5806\u79ef(fcc)\u3002\u66f4\u4e3a\u91cd\u8981\u7684\u662f\uff0c\u5728\u63a5\u8fd1\u5176\u7194\u70b91,133K\u7684\u6e29\u5ea6\u4e0b\uff0c\u7535\u5bfc\u7387\uff081.0-3.0S cm-1\uff09\u4e0e\u7194\u878d\u72b6\u6001\u7684\u7535\u5bfc\u7387\u5927\u5c0f\u76f8\u540c\uff1a\u7194\u878d\u65f6\uff0c\u7535\u5bfc\u7387\u4ec5\u63d0\u9ad828%\u3002\u9634\u79bb\u5b50\u91c7\u7528\u9ad8\u5bf9\u79f0\u6027\u6392\u5217\uff0c\u786b\u9178\u6839\u79bb\u5b50\u56f4\u7ed5S\u7403\u5f62\u65e0\u5e8f\u6392\u5217\uff1bLi<sup>+<\/sup>\u79bb\u5b50\u4f4d\u4e8e\u56db\u9762\u4f53\u4f4d\u70b9\uff0c\u800c\u516b\u9762\u4f53\u4f4d\u70b9\u4ecd\u7136\u7a7a\u7740\u3002\u03b2\u2192\u03b1\u76f8\u53d8\u7684\u7279\u70b9\u662f\u4f53\u79ef\u660e\u663e\u81a8\u80c0\uff084.5%\uff09\uff0c\u5e76\u4e14\u8be5\u76f8\u53d8\u7684\u7113\u53d8\u5f88\u5927\uff0c\u9ad8\u8fbe24.8 kJ mol-1\uff0c\u7ea6\u4e3a\u7194\u5316\u7113\u53d8\uff089.0 kJ mol-1\uff09\u7684\u4e09\u500d\u3002\u4e8b\u5b9e\u4e0a\uff0cLi<sub>2<\/sub>SO<sub>4<\/sub>\u662f\u53ea\u662f\u786b\u9178\u76d0\u4e2d\u5177\u6709\u8f6c\u52a8\u7279\u6027\u7684\u5176\u4e2d\u4e4b\u4e00\uff0c\u5176\u4ed6\u5177\u6709\u7c7b\u4f3c\u7ed3\u6784\u7684\u79bb\u5b50\u5bfc\u4f53\uff0c\u5982LiNaSO<sub>4<\/sub>\u548cLiAgSO<sub>4<\/sub>\uff0c\u9ad8\u6e29\u76f8\u4e5f\u5448\u9ad8\u5bf9\u79f0\u6027\u7ed3\u6784\uff08\u4f53\u5fc3\u7acb\u65b9\u7ed3\u6784\uff09\uff0c\u5e76\u5177\u6709\u6781\u9ad8\u7684\u9633\u79bb\u5b50\u7535\u5bfc\u7387\uff08~1 S cm<sup>-1<\/sup>\uff09\uff0c\u4e14\u76f8\u53d8\u8fc7\u7a0b\u4e5f\u4f34\u968f\u7740\u6bd4\u7194\u5316\u66f4\u5927\u7684\u76f8\u53d8\u7113\u53d8\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u516d\u65b9Na<sub>2<\/sub>SO<sub>4<\/sub>\uff08\u9ad8\u6e29\u76f8\uff09\u6ca1\u6709\u8868\u73b0\u51fa\u9ad8\u7684\u7535\u5bfc\u7387\uff08\u56fe\u00a03a\uff09\uff0c\u4e5f\u4e0d\u662f\u8f6c\u52a8\u76f8\uff0c\u5176\u7194\u5316\u7113\u53d8\uff0821kJ mol<sup>-1<\/sup>\uff09\u8fdc\u5927\u4e8e\u76f8\u53d8\u7113\u53d8\uff086.5kJ mol<sup>-1<\/sup>\uff09\u3002<\/p>\n<p>Li<sub>2<\/sub>SO<sub>4<\/sub>\u8f6c\u52a8\u76f8\u8868\u73b0\u51fa\u7684\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u88ab\u8ba4\u4e3a\u662f\u7531\u4e8e\u9633\u79bb\u5b50\u7684\u6269\u6563\u4e0e\u9634\u79bb\u5b50\u8fd0\u52a8\u7684\u8026\u5408\u5f15\u8d77\u7684\u3002\u5f53\u65f6\u6709\u4eba\u63d0\u51fa\u9633\u79bb\u5b50\u7a7f\u8fc7\u7531\u9634\u79bb\u5b50\u8f6c\u52a8\u6784\u6210\u7684\u201c\u65cb\u8f6c\u95e8\u201d\u65f6\u5176\u6269\u6563\u53d7\u5230\u4fc3\u8fdb\u3002\u8fd9\u79cd\u6548\u5e94\u6700\u521d\u88ab\u79f0\u4e3a\u201ccog-wheel\u673a\u5236\u201d\uff0c\u540e\u6765\u88ab\u79f0\u4e3a\u9f7f\u8f6e\u673a\u5236(paddle-wheel)\uff08\u56fe3b\uff09\u3002paddle-wheel\u673a\u5236\u6307\u51fa\u9633\u79bb\u5b50\u5468\u56f4\u7684\u805a\u9634\u79bb\u5b50\u65cb\u8f6c\u6709\u52a9\u4e8e\u4fc3\u8fdb\u9633\u79bb\u5b50\u7684\u6269\u6563\u8dc3\u8fc1\u3002\u5c06\u7194\u878d\u7684Li<sub>2<\/sub>SO<sub>4<\/sub>\u8fdb\u884c\u6dec\u706b\u5904\u7406\uff0c\u53ef\u5c06\u5176\u65e0\u5e8f\u7ed3\u6784\u7a33\u5b9a\u81f3\u5ba4\u6e29\uff0c\u76f8\u8f83\u4e8e\u81ea\u7136\u51b7\u5374\u6240\u5f97\u7684\u4f4e\u6e29\u76f8\uff0c\u6dec\u706b\u4ea7\u7269\u5177\u6709\u66f4\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u7531\u6b64\u8bf4\u660e\u4e86paddle-wheel\u673a\u5236\u5bf9\u63d0\u9ad8\u9633\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u91cd\u8981\u6027\uff0c\u4e5f\u4e3a\u5177\u6709\u9634\u79bb\u5b50\u65e0\u5e8f\u7684\u79bb\u5b50\u6676\u4f53\u7684\u9ad8\u79bb\u5b50\u5bfc\u7535\u6027\u63d0\u4f9b\u4e86\u5408\u7406\u7684\u89e3\u91ca\u3002<\/p>\n<p>[PO<sub>4<\/sub>]<sup>3-<\/sup>\u805a\u9634\u79bb\u5b50\u4e5f\u53ef\u53d1\u751f\u65cb\u8f6c\u8fd0\u52a8\u3002\u7eafNa<sub>3<\/sub>PO<sub>4<\/sub>\u4f4e\u6e29\u65f6\u4e3a\u56db\u65b9\u591a\u6676\u03b1\u76f8\uff0c\u8868\u73b0\u51fa\u8f83\u5dee\u7684\u79bb\u5b50\u5bfc\u7535\u6027(~10<sup>-5<\/sup>\u00a0S cm<sup>-1<\/sup>, 573 K)\uff0c\u5728\u7ea6600 K\u65f6\u53d1\u751f\u76f8\u8f6c\u53d8\uff0c\u8f6c\u53d8\u4e3a\u5177\u6709\u9ad8\u5bf9\u79f0\u6027\u7684\u7acb\u65b9\u591a\u6676\u03b3\u76f8\uff0c\u5e76\u4f34\u968f\u7740\u4f53\u79ef\u81a8\u80c0(2.8%)\u3001\u7535\u5bfc\u7387\u63d0\u9ad8\u4e00\u4e2a\u6570\u91cf\u7ea7\u3001E<sub>a<\/sub>\u4e0b\u964d\u7b49\u73b0\u8c61\uff08\u56fe3d\uff09\u3002\u9ad8\u6e29\u76f8\u7684\u03b3-Na<sub>3<\/sub>PO<sub>4<\/sub>\u4e3a\u8f6c\u52a8\u76f8\uff08\u56fe3c\uff0c\u5de6\uff09\uff0c\u5373[PO<sub>4<\/sub>]<sup>3-<\/sup>\u7684\u4e00\u4e2aC<sub>3<\/sub>\u8f74\u968f\u673a\u6cbf\u516d\u4e2a\u7b49\u4ef7\u7684[100]\u53d6\u5411\uff0c\u5176\u4f59\u7684\u4e09\u4e2a\u6c27\u539f\u5b50\u5728\u5782\u76f4\u4e8e\u8be5[100]\u65b9\u5411\u7684\u9762\u4e0a\u79bb\u57df\u5316\u5206\u5e03\u3002\u5728Na<sub>3<\/sub>PO<sub>4<\/sub>\u7684\u76f8\u53d8\u8fc7\u7a0b\u4e2d\uff0c[PO<sub>4<\/sub>]<sup>3-<\/sup>\u53d6\u5411\u65e0\u5e8f\u4e0e\u9633\u79bb\u5b50\u7535\u5bfc\u7387\u63d0\u9ad8\u7684\u540c\u65f6\u53d1\u751f\u8bc1\u660e\u9634\u79bb\u5b50\u8fd0\u52a8\u53ef\u4ee5\u4fc3\u8fdbNa<sup>+<\/sup>\u7684\u6269\u6563\u3002\u6dec\u706b\u65e0\u6cd5\u7a33\u5b9aNa<sub>3<\/sub>PO<sub>4<\/sub>\u7684\u9ad8\u6e29\u03b3\u76f8\uff0c\u7136\u800c\u52a0\u5165NaOH\u7b49\u6dfb\u52a0\u5242\u80fd\u591f\u663e\u8457\u964d\u4f4eT<sub>trans<\/sub>\uff0c\u63ba\u6742\u4e8c\u4ef7\uff08Mg<sup>2+<\/sup>\u3001Zn<sup>2+<\/sup>\u3001Ca<sup>2+<\/sup>\u3001Sr<sup>2+<\/sup>\uff09\u6216\u56db\u4ef7\uff08Zr<sup>4+<\/sup>\uff09\u79bb\u5b50\u4e5f\u80fd\u4ea7\u751f\u76f8\u540c\u7684\u6548\u679c\uff0c\u4f7f\u7535\u5bfc\u7387\u63d0\u9ad82~3\u4e2a\u6570\u91cf\u7ea7\u3002\u8fd1\u671f\u6709\u7814\u7a76\u62a5\u9053\u6dfb\u52a0\u5242\u548c\u673a\u68b0\u7403\u78e8\u5bf9Na<sub>2<\/sub>Zn<sub>0.5<\/sub>PO<sub>4<\/sub>\u7ed3\u6784\u8f6c\u53d8\u7684\u5f71\u54cd\uff1aNa<sub>2<\/sub>Zn<sub>0.5<\/sub>PO<sub>4<\/sub>\u4f4e\u6e29\u5448\u03b1\u76f8\uff0c\u9ad8\u6e29\u4e3a\u03b2\u548c\u03b3\u591a\u6676\u76f8\u3002\u03b2\u591a\u6676\u76f8\u53ef\u4ee5\u901a\u8fc7\u7528Ga<sup>3+<\/sup>\u548cAl<sup>3+<\/sup>\u90e8\u5206\u53d6\u4ee3Zn<sup>2+<\/sup>\u6765\u7a33\u5b9a\uff0c\u800c\u03b3\u591a\u6676\u76f8\u53ef\u4ee5\u901a\u8fc7\u7403\u78e8\u5f15\u5165\u65e0\u5e8f\uff0c\u589e\u52a0\u4f53\u7cfb\u7684\u71b5\u800c\u4f7f\u5f97\u9ad8\u6e29\u76f8\u7a33\u5b9a\u5728\u5ba4\u6e29\u3002<\/p>\n<p>\u56fe3.\u00a0[SO<sub>4<\/sub>]<sup>2-<\/sup>\u548c[PO<sub>4<\/sub>]<sup>3-<\/sup>\u805a\u9634\u79bb\u5b50\u5728\u65e0\u673a\u78b1\u91d1\u5c5e\u79bb\u5b50\u5bfc\u4f53\u4e2d\u7684\u65cb\u8f6c\u3002(a)\u00a0Li<sub>2<\/sub>SO<sub>4<\/sub>\u548cNa<sub>2<\/sub>SO<sub>4<\/sub>\u7684\u7535\u5bfc\u7387(\u03c3\uff09\u4e0e\u6e29\u5ea6(T)\u7684\u5173\u7cfb\uff1b(b)\u00a0\u03b1-Li<sub>2<\/sub>SO<sub>4<\/sub>\u4e2d\u6240\u63d0\u51fa\u7684Li<sup>+<\/sup>\u8fc1\u79fb\u7684paddle-wheel\u673a\u5236\uff1b(c)\u00a0HT \u03b3-Na<sub>3<\/sub>PO<sub>4<\/sub>\u7684\u6676\u4f53\u7ed3\u53ca\u548c\u4e09\u4e2aO\u539f\u5b50\u5728Na<sub>3<\/sub>PO<sub>4<\/sub>\u4e2d\u7684\u65cb\u8f6c\u8fd0\u52a8\u793a\u610f\u56fe\uff08\u53f3\uff09\uff1b(d)\u00a0Na<sub>3<\/sub>PO<sub>4<\/sub>\u7684\u7535\u5bfc\u7387\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\uff1b(e) Na<sub>2<\/sub>Zn<sub>0.5<\/sub>PO<sub>4<\/sub>\u7684\u4e09\u79cd\u6676\u4f53\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232468\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72473-10.png\" alt=\"\" width=\"1292\" height=\"758\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72473-10.png 1292w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72473-10-300x176.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72473-10-768x451.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72473-10-1024x601.png 1024w\" sizes=\"(max-width: 1292px) 100vw, 1292px\" \/><\/p>\n<p><strong><b>2 [BH<\/b><\/strong><strong><sub><b>4<\/b><\/sub><\/strong><strong><b>]<\/b><\/strong><strong><sup><b>&#8211;<\/b><\/sup><\/strong><strong><b>\u7684\u91cd\u5b9a\u5411<\/b><\/strong><\/p>\n<p>LiBH<sub>4<\/sub>\u5728\u9ad8\u4e8eT<sub>trans<\/sub>\uff08390 K\uff09\u65f6\u8f6c\u53d8\u4e3a\u8d85\u79bb\u5b50\u5bfc\u4f53(\u03c3\u224810<sup>-3<\/sup>\u00a0S cm<sup>-1<\/sup>\uff09\u3002\u53d1\u751f\u4e00\u7ea7\u76f8\u53d8\u65f6\uff0c\u8be5\u6750\u6599\u4ece\u4f4e\u6e29\u6b63\u4ea4\u76f8\u8f6c\u53d8\u4e3a\u9ad8\u6e29\u516d\u65b9\u76f8\uff0c\u4e14\u4f34\u968f\u7740[BH<sub>4<\/sub>]<sup>&#8211;<\/sup>\u6709\u5e8f-\u65e0\u5e8f\u8f6c\u53d8\u3001\u5355\u80de\u4f53\u79ef\u51cf\u5c0f\u3001Li<sup>+<\/sup>\u7535\u5bfc\u7684\u663e\u8457\u63d0\u9ad8\uff08\u7ea6\u4e09\u4e2a\u6570\u91cf\u7ea7\uff09\u3002\u57fa\u4e8e\u539f\u4f4d\u540c\u6b65\u8f90\u5c04X\u5c04\u7ebf\u5f97\u5230\u7684\u5404\u5411\u5f02\u6027\u4f4d\u79fb\u692d\u7403\u63ed\u793a\u4e86\u9ad8\u6e29\u76f8\u4e2d[BH<sub>4<\/sub>]<sup>&#8211;<\/sup>\u56db\u9762\u4f53\u7684\u9ad8\u5ea6\u65e0\u5e8f\u6027\uff0c\u5bbd\u6e29\u5ea6\u8303\u56f4\u5185\u7684\u4e2d\u5b50\u7c89\u672b\u884d\u5c04\u4e5f\u8bc1\u5b9e\u4e86\u968f\u6e29\u5ea6\u5347\u9ad8[BH<sub>4<\/sub>]<sup>&#8211;<\/sup>\u7684\u65e0\u5e8f\u5ea6\u663e\u8457\u589e\u52a0\u3002\u76f8\u8f83\u4e8e\u4f4e\u6e29\u76f8\uff0c\u9ad8\u6e29\u76f8\u58f0\u5b50\u6001\u5bc6\u5ea6\u7684\u4f4e\u80fd\uff08&lt;15meV\uff09\u90e8\u5206\u66f4\u52a0\u663e\u8457\uff0c\u4e5f\u8bc1\u660e\u4e86[BH<sub>4<\/sub>]<sup>&#8211;<\/sup>\u91cd\u5b9a\u5411\u7684\u65e0\u5e8f\u6027\u3002<\/p>\n<p>T<sub>trans<\/sub>\u5bf9\u4e8e\u5229\u7528paddle-wheel\u673a\u5236\u3001\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u5b9e\u73b0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u81f3\u5173\u91cd\u8981\u3002\u9634\u79bb\u5b50\u6df7\u5408\u662f\u4e00\u79cd\u8c03\u63a7\u9634\u79bb\u5b50\u9aa8\u67b6\u53ca\u5176\u91cd\u5b9a\u5411\u80fd\u529b\u7684\u6709\u6548\u7b56\u7565\uff0c\u5411LiBH<sub>4<\/sub>\u4e2d\u6dfb\u52a0LiX (X=Cl, Br, I)\u53ef\u5c06T<sub>trans<\/sub>\u964d\u4f4e\u81f3353 K\uff0c\u8be5\u7b56\u7565\u7684\u8c03\u8282\u6548\u679c\u4e0e\u6676\u80de\u53c2\u6570\u76f8\u5173\uff0c\u5e76\u968f\u7740\u5364\u7d20\u79bb\u5b50\u534a\u5f84\u589e\u52a0\u800c\u53d8\u5f97\u66f4\u52a0\u663e\u8457\u3002\u5728LiBH<sub>4<\/sub>\u4e2d\u6dfb\u52a0\u8d85\u8fc712.5%\u7684LiI\u65f6\uff0c\u53ef\u5c06T<sub>trans<\/sub>\u964d\u4f4e\u81f3\u5ba4\u6e29\uff0c\u5e76\u663e\u8457\u63d0\u9ad8\u5176\u79bb\u5b50\u7535\u5bfc\u7387\uff082\u00d710<sup>-5<\/sup>\u00a0S cm<sup>-1<\/sup>, 300 K\uff09\u3002\u51c6\u5f39\u6027\u4e2d\u5b50\u6563\u5c04\u548c\u975e\u5f39\u6027\u4e2d\u5b50\u6563\u5c04\u7684\u7ed3\u679c\u8868\u660e\uff0cI<sup>&#8211;<\/sup>\u53ef\u5c06[BH<sub>4<\/sub>]<sup>&#8211;<\/sup>\u7684\u65cb\u8f6c\u9891\u7387\u63d0\u9ad8100\u500d\u4ee5\u4e0a\uff0c\u5e76\u663e\u8457\u964d\u4f4e[BH<sub>4<\/sub>]<sup>&#8211;<\/sup>\u7684\u65cb\u8f6c\u6fc0\u6d3b\u80fd\u3002\u591a\u79cd\u805a\u9634\u79bb\u5b50\u7684\u6df7\u5408\u6216\u9634\u79bb\u5b50\u6676\u683c\u7684\u91cd\u6392\uff0c\u53ef\u5bfc\u81f4Li<sup>+<\/sup>\u5728\u591a\u4e2a\u6676\u683c\u4f4d\u70b9\u91cd\u65b0\u5206\u5e03\uff0c\u5e76\u4ea7\u751f\u4e0d\u540c\u4e8e\u4e3b\u4f53\u6750\u6599\u7684Li<sup>+<\/sup>\u7684\u5c40\u90e8\u914d\u4f4d\u73af\u5883\u3002\u4f8b\u5982\uff0c\u5c06LiBH<sub>4<\/sub>\u548cLiNH<sub>2<\/sub>\u4ee5\u4e0d\u540c\u6bd4\u4f8b\u6df7\u5408\uff0c\u751f\u6210\u7684Li<sub>2<\/sub>(BH<sub>4<\/sub>)(NH<sub>2<\/sub>)\u3001Li<sub>3<\/sub>(BH<sub>4<\/sub>)(NH<sub>2<\/sub>)<sub>2<\/sub>\u3001Li<sub>4<\/sub>(BH<sub>4<\/sub>)(NH<sub>2<\/sub>)<sub>3<\/sub>\u7b49\u6c22\u5316\u7269\u8868\u73b0\u51fa\u6781\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u7814\u7a76\u8868\u660e\uff0c\u8fd9\u4e9b\u6750\u6599\u4e2dLi<sup>+<\/sup>\u9ad8\u7684\u53ef\u79fb\u52a8\u6027\u4e0eB-H\u3001N-H\u7684\u91cd\u5b9a\u5411\u8fd0\u52a8\u5bc6\u5207\u76f8\u5173\u3002\u6b64\u5916\uff0c\u5b9e\u9a8c\u6d4b\u5f97\u7684LiBH<sub>4<\/sub>\u4e2d[BH<sub>4<\/sub>]<sup>&#8211;<\/sup>\u7684H\u539f\u5b50\u65cb\u8f6c\u8fd0\u52a8\u7684\u6fc0\u6d3b\u80fd(0.69 eV)\u4e0eLi<sup>+<\/sup>\u6269\u6563\u6fc0\u6d3b\u80fd(0.67 eV)\u76f8\u8fd1\uff0c\u8868\u660e\u8fd9\u4e24\u79cd\u8fd0\u52a8\u53ef\u80fd\u4f1a\u5728\u540c\u4e00\u9891\u7387\u53d1\u751f\u3002<\/p>\n<p><strong><b>3 [B<\/b><\/strong><strong><sub><b>n<\/b><\/sub><\/strong><strong><b>H<\/b><\/strong><strong><sub><b>n<\/b><\/sub><\/strong><strong><b>]<\/b><\/strong><strong><sup><b>2-<\/b><\/sup><\/strong><strong><b>\u00a0(n = 10, 12)\u7684\u91cd\u5b9a\u5411<\/b><\/strong><\/p>\n<p>\u5c3d\u7ba1MBH<sub>4<\/sub>\u00a0(M = Li, Na)\u53ca\u5176\u884d\u751f\u7269\u5177\u6709\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u4f46\u5176\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3001\u70ed\u7a33\u5b9a\u6027\u53ca\u6e7f\u7a7a\u6c14\u7a33\u5b9a\u6027\u5dee\u3002\u7136\u800c\uff0c\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5176\u53cd\u5e94\u7684\u4e2d\u95f4\u4ea7\u7269M<sub>2<\/sub>B<sub>12<\/sub>H<sub>12<\/sub>\u56e0\u51c6\u7403\u5f62\u6846\u67b6\u4e2d\u6709\u8f83\u5f3a\u7684B-B\u952e\u800c\u5177\u6709\u826f\u597d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u70ed\u7a33\u5b9a\u6027\u3002M<sub>2<\/sub>B<sub>12<\/sub>H<sub>12<\/sub>\u8fd8\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u5bbd\u7535\u5316\u5b66\u7a97\u53e3\uff08\u9ad8\u8fbe5V\uff09\u3002 [B<sub>10<\/sub>H<sub>10<\/sub>]<sup>2-<\/sup>\u6216[B<sub>12<\/sub>H<sub>12<\/sub>]<sup>2-<\/sup>\u805a\u9634\u79bb\u5b50\u4e3aM<sub>2<\/sub>B<sub>10<\/sub>H<sub>10<\/sub>\u548cM<sub>2<\/sub>B<sub>12<\/sub>H<sub>12<\/sub>\u00a0(M = Li, Na)\u9633\u79bb\u5b50\u7684\u8f93\u8fd0\u63d0\u4f9b\u4e86\u66f4\u5927\u7684\u81ea\u7531\u4f53\u79ef\uff0c\u6709\u52a9\u4e8e\u4fc3\u8fdb\u9633\u79bb\u5b50\u7684\u6269\u6563\u3002\u5728\u8d85\u8fc7T<sub>trans<\/sub>\u65f6\u4f1a\u53d1\u751f\u6709\u5e8f-\u65e0\u5e8f\u7684\u76f8\u53d8\uff0c\u9ad8\u6e29\u76f8\u4e2d\u9ad8\u5ea6\u65e0\u5e8f\u7684\u805a\u9634\u79bb\u5b50\u7f51\u7edc\u7ed3\u6784\u52a0\u4e0a\u5bcc\u542b\u7a7a\u4f4d\u7684\u9633\u79bb\u5b50\u4e9a\u6676\u683c\uff0c\u4f7f\u5f97\u8fd9\u4e9b\u76d0\u5c55\u73b0\u51fa\u6781\u9ad8\u7684\u9633\u79bb\u5b50\u5bfc\u7535\u6027\uff08\u56fe4d\uff09\u3002<\/p>\n<p>Na<sub>2<\/sub>B<sub>12<\/sub>H<sub>12<\/sub>\u53ef\u53d1\u751f\u4e24\u6b21\u76f8\u53d8\uff0c\u5373\u5728529 K\u65f6\u4ece\u6709\u5e8f\u7684\u5355\u659c\u7ed3\u6784\u8f6c\u53d8\u4e3a\u90e8\u5206\u65e0\u5e8f\u3001\u9634\u79bb\u5b50\u4f2a\u4f53\u5fc3\u7acb\u65b9\u5bc6\u79ef\u7684\u7ed3\u6784\uff0c\u5e76\u5728545 K\u65f6\u8f6c\u53d8\u4e3a\u5b8c\u5168\u65e0\u5e8f\u3001\u9634\u79bb\u5b50\u4f53\u5fc3\u7acb\u65b9\u5bc6\u79ef\u7684\u7ed3\u6784\u3002\u5411\u9ad8\u6e29\u76f8\u7684\u8f6c\u53d8\u4f34\u968f\u7740\u5fae\u5c0f\u7684\u4f53\u79ef\u6536\u7f29\uff083.4%\uff09\u548c\u79bb\u5b50\u7535\u5bfc\u7387\u7ea6\u4e09\u4e2a\u6570\u91cf\u7ea7\u7684\u63d0\u9ad8(0.1 S cm<sup>-1<\/sup>, 540 K\uff09\u3002Na<sub>2<\/sub>B<sub>10<\/sub>H<sub>10<\/sub>\u7684\u6709\u5e8f-\u65e0\u5e8f\u76f8\u53d8\u53d1\u751f\u5728\u66f4\u4f4e\u7684\u6e29\u5ea6\u4e0b(373 K)\uff0c\u5e76\u5728\u9ad8\u4e8e\u8f6c\u53d8\u6e29\u5ea6\u65f6\u5c55\u73b0\u51fa\u6781\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387(0.01 S cm<sup>-1<\/sup>, 383 K)\u3002<sup>23<\/sup>Na NMR\u7684\u7ed3\u679c\u8868\u660e\u6709\u5e8f-\u65e0\u5e8f\u7684\u76f8\u53d8\u8fc7\u7a0b\u4f34\u968f\u7740Na<sup>+<\/sup>\u8dc3\u8fc1\u9891\u7387\u663e\u8457\u63d0\u9ad8\u3001\u6fc0\u6d3b\u80fd\u663e\u8457\u964d\u4f4e(\u9ad8\u6e29\u76f80.190 eV\uff0c\u4f4e\u6e29\u76f80.750 eV)\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\u8be5\u6750\u6599\u5f97\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u4e0e[B<sub>10<\/sub>H<sub>10<\/sub>]<sup>2-<\/sup>\u7684\u8f6c\u52a8\u76f8\u5173\uff1a\u9634\u79bb\u5b50\u8f6c\u52a8\u4fc3\u8fdbNa<sup>+<\/sup>\u8dc3\u8fc1\u5230\u516b\u9762\u4f53\u4f4d\uff0c\u5e76\u4f7f\u56db\u9762\u4f53\u4f4d\u8fde\u901a\u5f62\u6210\u8fde\u7eed\u7684\u79bb\u5b50\u8f93\u8fd0\u901a\u9053\uff0c\u663e\u8457\u964d\u4f4eNa<sup>+<\/sup>\u8fc1\u79fb\u80fd\u5792\u3002<\/p>\n<p>\u4f7f\u7528C-H\u53d6\u4ee3[B<sub>12<\/sub>H<sub>12<\/sub>]<sup>2-<\/sup>\u548c[B<sub>10<\/sub>H<sub>10<\/sub>]<sup>2-<\/sup>\u4e2d\u7684\u4e00\u4e2aB-H\u53ef\u751f\u6210\u7ed3\u6784\u76f8\u4f3c\u7684[CB<sub>11<\/sub>H<sub>12<\/sub>]<sup>&#8211;<\/sup>\u548c[CB<sub>9<\/sub>H<sub>10<\/sub>]<sup>&#8211;<\/sup>\u3002\u76f8\u8f83\u4e8eMB<sub>12<\/sub>H<sub>12<\/sub>\uff0cLiCB<sub>11<\/sub>H<sub>12<\/sub>\u548cNaCB<sub>11<\/sub>H<sub>12<\/sub>\u76f8\u53d8\u6e29\u5ea6\u663e\u8457\u964d\u4f4e(400 K, LiCB<sub>11<\/sub>H<sub>12<\/sub>; 380 K, NaCB<sub>11<\/sub>H<sub>12<\/sub>)\uff0c\u4e14\u9ad8\u6e29\u76f8\u5c55\u73b0\u51fa\u66f4\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u66f4\u4f4e\u7684\u6d3b\u5316\u80fd\u3002\u78b3\u4ee3\u787c\u9178\u76d0\u66f4\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u662f\u7531\u66f4\u4f4e\u7684\u9634\u79bb\u5b50\u4ef7\u6001\u3001\u66f4\u5f3a\u7684\u9634\u79bb\u5b50\u8fd0\u52a8\u80fd\u529b\uff0c\u66f4\u591a\u7684\u9633\u79bb\u5b50\u7a7a\u4f4d\u53ca\u66f4\u5927\u7684\u6676\u80de\u53c2\u6570\u5f15\u8d77\u7684\u3002<\/p>\n<p>\u56fe4.\u00a0[BH<sub>4<\/sub>]<sup>&#8211;<\/sup>\u548c[B<sub>n<\/sub>H<sub>n<\/sub>]<sup>2-<\/sup>\u805a\u9634\u79bb\u5b50\u5728\u65e0\u673a\u78b1\u91d1\u5c5e\u79bb\u5b50\u5bfc\u4f53\u4e2d\u7684\u65cb\u8f6c\u3002(a)\u00a0LiBH<sub>4<\/sub>\u7ed3\u6784\u4e2d\u7684\u516d\u5143Li-BH<sub>4<\/sub>\u73af\uff08\u5de6\uff09\u548cBH<sub>4<\/sub>\u6676\u80de\uff08\u53f3\uff09\uff0c\u692d\u5706\u4f53\u6982\u7387\u4e3a40%\uff1b(b)\u00a0Li<sub>2<\/sub>(BH<sub>4<\/sub>)(NH<sub>2<\/sub>)\u3001Li<sub>3<\/sub>(BH<sub>4<\/sub>)(NH<sub>2<\/sub>)<sub>2<\/sub>\u548cLi<sub>4<\/sub>(BH<sub>4<\/sub>)(NH<sub>2<\/sub>)<sub>3<\/sub>\u4ee5\u53ca\u4e3b\u4f53\u6750\u6599\u7684\u7535\u5bfc\u7387\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\uff1b(c)\u00a0NaBH<sub>4<\/sub>\u3001Na(BH<sub>4<\/sub>)<sub>0.75<\/sub>I<sub>0.25<\/sub>\u3001Na(NH<sub>2<\/sub>)<sub>0.5<\/sub>I<sub>0.5<\/sub>\u548cNa(BH<sub>4<\/sub>)<sub>0.5<\/sub>(NH<sub>2<\/sub>)<sub>0.5<\/sub>\u7684\u7535\u5bfc\u7387\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\uff1b(d)\u00a0\u94a0\u3001\u9502\u95ed\u5408\u578b\u787c\u9178\u76d0\u548c\u78b3\u4ee3\u95ed\u5408\u578b\u787c\u9178\u76d0\u7684\u7535\u5bfc\u7387\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\uff1b(e) \u57fa\u4e8e\u4ece\u5934\u7b97\u5206\u5b50\u52a8\u529b\u5b66(AIMD)\u00a0\u8ba1\u7b97\u7684Na<sup>+<\/sup>\u548c[CB<sub>11<\/sub>H<sub>12<\/sub>]<sup>&#8211;<\/sup>\u4e4b\u95f4\u7684\u5c40\u90e8\u76f8\u4e92\u4f5c\u7528\uff1b(f)\u00a0LiCB<sub>11<\/sub>H<sub>12<\/sub>\u548cNaCB<sub>11<\/sub>H<sub>12<\/sub>\u7684\u65e0\u5e8f\u76f8\u7684\u9634\u79bb\u5b50\u8df3\u8dc3\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232469\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72474-9.png\" alt=\"\" width=\"1231\" height=\"844\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72474-9.png 1231w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72474-9-300x206.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72474-9-768x527.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72474-9-1024x702.png 1024w\" sizes=\"(max-width: 1231px) 100vw, 1231px\" \/><\/p>\n<p><strong><b>4 [PnX<\/b><\/strong><strong><sub><b>4<\/b><\/sub><\/strong><strong><b>]<\/b><\/strong><strong><sup><b>3-<\/b><\/sup><\/strong><strong><b>\uff08X = S\uff0cSe\uff09\u7684\u65cb\u8f6c<\/b><\/strong><\/p>\n<p>\u8fd1\u671f\u5bf9Na<sub>11<\/sub>Sn<sub>2<\/sub>PnX<sub>12<\/sub>\uff08Pn=P, Sb\uff1bX=S, Se\uff09\u6750\u6599\u7684\u7814\u7a76\u8bc1\u5b9e\u4e86\u9633\u79bb\u5b50\u6269\u6563\u8fd0\u52a8\u4e0e\u805a\u9634\u79bb\u5b50\uff08[PS<sub>4<\/sub>]<sup>3-<\/sup>\u548c[PSe<sub>4<\/sub>]<sup>3-<\/sup>\uff09\u65cb\u8f6c\u8fd0\u52a8\u4e4b\u95f4\u5b58\u5728\u5f3a\u8026\u5408\u5173\u7cfb\u3002\u4f5c\u8005\u5229\u7528\u57fa\u4e8e\u4e2d\u5b50\u884d\u5c04\u7684MEM\u5206\u6790\uff0c\u9996\u6b21\u4ece\u5b9e\u9a8c\u4e0a\u8bc1\u5b9e\u4e86[PS<sub>4<\/sub>]<sup>3-<\/sup>\u57fa\u56e2\u5b58\u5728\u805a\u9634\u79bb\u5b50\u8f6c\u52a8\u73b0\u8c61\uff08\u56fe5a-c\uff09\u3002\u5e76\u53d1\u5c55\u4e86\u4e00\u79cd\u65f6\u95f4\u5173\u8054\u51fd\u6570\uff0c\u4ece\u7406\u8bba\u4e0a\u4e25\u683c\u8bc1\u5b9e\u4e86\u9634\u79bb\u5b50\u8f6c\u52a8\u80fd\u591f\u4fc3\u8fdb\u9633\u79bb\u5b50\u7684\u4f20\u5bfc\uff0c\u4e14\u4e24\u8005\u4e4b\u95f4\u7684\u8fd0\u52a8\u662f\u8026\u5408\u7684\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5728\u5bfc\u7535\u6027\u8f83\u5dee\u7684Na<sub>11<\/sub>Sn<sub>2<\/sub>SbS<sub>12<\/sub>\u4e2d\uff0c[SbS<sub>4<\/sub>]<sup>3-<\/sup>\u7684\u65cb\u8f6c\u8fd0\u52a8\u660e\u663e\u53d7\u963b\u3002\u8fd9\u4e00\u73b0\u8c61\u4e0e\u805a\u9634\u79bb\u5b50\u5f97\u6210\u952e\u6027\u8d28\u6709\u5173\uff1aP-S\u548cP-Se\u952e\u5177\u6709\u66f4\u5f3a\u7684\u5171\u4ef7\u6027\uff0c\u6709\u5229\u4e8e[PS<sub>4<\/sub>]<sup>3-<\/sup>\u548c[PSe<sub>4<\/sub>]<sup>3-<\/sup>\u7684\u65cb\u8f6c\uff1b\u800c\u5728Sb-S\u952e\u66f4\u5f3a\u7684\u79bb\u5b50\u6027\u63d0\u9ad8\u4e86\u4ea5\u59c6\u970d\u5179\u81ea\u7531\u80fd\u8c31\u4e2d\u7684\u52bf\u9631\u6df1\u5ea6\uff0c\u56e0\u6b64[SbS<sub>4<\/sub>]<sup>3-<\/sup>\u7684\u65cb\u8f6c\u53d7\u963b\u3002[PS<sub>4<\/sub>]<sup>3-<\/sup>\u548c[PSe<sub>4<\/sub>]<sup>3-<\/sup>\u7684\u65cb\u8f6c\u8fd0\u52a8\u4e0e\u9633\u79bb\u5b50\u7684\u6269\u6563\u76f8\u8026\u5408\uff0c\u5373\u53ef\u901a\u8fc7paddle-wheel\u673a\u5236\u5373\u65f6\u5730\u6269\u5927Na<sup>+<\/sup>\u6269\u6563\u6240\u9700\u8981\u8de8\u8d8a\u7684\u7531\u4e09\u4e2aS\u539f\u5b50\u6784\u6210\u7684\u4e09\u89d2\u5f62\u74f6\u9888\uff0c\u4fc3\u8fdb\u9633\u79bb\u5b50\u7684\u6269\u6563\uff08\u56fe5g, h\uff09\u3002\u963b\u6297\u8c31\u548cAIMD\u6a21\u62df\u7684\u7ed3\u679c\u4e5f\u8868\u660e\uff0c\u9ad8\u6e29\u8f6c\u52a8\u76f8\u7684\u9ad8\u79bb\u5b50\u5bfc\u7535\u6027\u4e0e\u9634\u79bb\u5b50\u65cb\u8f6c\u8fd0\u52a8\u6709\u5173\u3002<\/p>\n<p>Paddle-wheel\u673a\u5236\u4e5f\u53ef\u7528\u4e8e\u89e3\u91ca\u786b\u4ee3\u78f7\u9178\u76d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u5f97\u539f\u56e0\u3002\u4f7f\u7528Si<sup>4+<\/sup>\u53d6\u4ee3P<sup>5+<\/sup>\u53ef\u5c06\u9ad8\u6e29\u8f6c\u52a8\u76f8(\u03b2-Li<sub>3<\/sub>PS<sub>4<\/sub>)\u7a33\u5b9a\u81f3\u5ba4\u6e29\uff0c\u751f\u6210\u7684Li<sub>3.25<\/sub>Si<sub>0.25<\/sub>P<sub>0.75<\/sub>S<sub>4<\/sub>\u5177\u6709\u66f4\u5927\u7684\u6676\u80de\u53c2\u6570\u548c\u66f4\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387(1.22 mS cm<sup>-1<\/sup>)\uff0c\u8be5\u6750\u6599\u8868\u73b0\u51fa\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u539f\u56e0\u4e0eNa<sub>11<\/sub>Sn<sub>2<\/sub>PS<sub>12<\/sub>\u76f8\u540c\uff0c\u5373[PS<sub>4<\/sub>]<sup>3-<\/sup>\u8f6c\u52a8\u6269\u5927\u4e86Li<sup>+<\/sup>\u8f93\u8fd0\u74f6\u9888\uff0c\u4fc3\u8fdb\u4e86Li<sup>+<\/sup>\u6269\u6563\u3002\u6b64\u5916\uff0cLi<sub>6<\/sub>PS<sub>5<\/sub>X (X=Cl, Br, I)\u4e2d[PS<sub>4<\/sub>]<sup>3-<\/sup>\u4e5f\u5b58\u5728\u65cb\u8f6c\u8fd0\u52a8\u3002<\/p>\n<p>\u9664\u4e86\u805a\u9634\u79bb\u5b50\u65cb\u8f6c\u5916\uff0c\u9634\u9633\u79bb\u5b50\u76f8\u4e92\u4f5c\u7528\u4e5f\u5bf9\u9633\u79bb\u5b50\u7684\u8f93\u8fd0\u5177\u6709\u4fc3\u8fdb\u4f5c\u7528\u3002AIMD\u6a21\u62df\u7ed3\u679c\u8868\u660eLi<sub>3<\/sub>InBr<sub>6<\/sub>\u4e2dBr<sup>&#8211;<\/sup>\u5bfc\u81f4\u7684\u5c40\u90e8\u5316\u5b66\u73af\u5883\u6ce2\u52a8\u53ef\u4fc3\u8fdbLi<sup>+<\/sup>\u8f93\u8fd0\uff0c Li\u548cNa\u7684\u5364\u5316\u7269\u7535\u89e3\u8d28\u4e2dMCl<sub>6<\/sub>\u4e5f\u53ef\u4ee5\u53d1\u751f\u8f6c\u52a8\uff0c\u5176\u5bf9\u9633\u79bb\u5b50\u6269\u6563\u7684\u5f71\u54cd\u9700\u8981\u8fdb\u4e00\u6b65\u7814\u7a76\u3002<\/p>\n<p>\u56fe5.\u00a0[PnS<sub>4<\/sub>]<sup>3-<\/sup>\u805a\u9634\u79bb\u5b50\u5728Na<sub>11<\/sub>Sn<sub>2<\/sub>PnX<sub>12<\/sub>\uff08\u5176\u4e2dPn=P\u3001Sb\uff1bX=S\u3001Se\uff09\u4e2d\u7684\u65cb\u8f6c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232470\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72475-9.png\" alt=\"\" width=\"658\" height=\"660\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72475-9.png 658w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72475-9-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72475-9-300x300.png 300w\" sizes=\"(max-width: 658px) 100vw, 658px\" \/><\/p>\n<p>(a\uff0cb)\u00a0\u53d8\u6e29\u4e2d\u5b50\u7c89\u672b\u884d\u5c04\u7684Na<sub>11<\/sub>Sn<sub>2<\/sub>PS<sub>12<\/sub>\u7684\u6838\u5bc6\u5ea6\u56fe\uff1b(c) \u7531\u4ece\u5934\u7b97\u5206\u5b50\u52a8\u529b\u5b66(AIMD)\u6a21\u62df\u5f97\u5230\u7684Na<sub>11<\/sub>Sn<sub>2<\/sub>PS<sub>12<\/sub>\u3001Na<sub>11<\/sub>Sn<sub>2<\/sub>PSe<sub>12<\/sub>\u548cNa<sub>11<\/sub>Sn<sub>2<\/sub>SbS<sub>12<\/sub>\u7684[PnX<sub>4<\/sub>]<sup>3-<\/sup>\u805a\u9634\u79bb\u5b50\u7684\u4e09\u7ef4\u6982\u7387\u5bc6\u5ea6\u5206\u5e03\uff1b(d-f)\u00a0Na<sub>11<\/sub>Sn<sub>2<\/sub>PS<sub>12<\/sub>\u3001Na<sub>11<\/sub>Sn<sub>2<\/sub>PSe<sub>12<\/sub>\u548cNa<sub>11<\/sub>Sn<sub>2<\/sub>SbS<sub>12<\/sub>\u7684\u4ea5\u59c6\u970d\u5179\u81ea\u7531\u80fd\u8868\u9762\uff1b(g\uff0ch)\u00a0\u00a0AIMD\u6a21\u62df\u5206\u6790\u8bc1\u660e[PS<sub>4<\/sub>]<sup>3-<\/sup>\/[PSe<sub>4<\/sub>]<sup>3-<\/sup>\u9634\u79bb\u5b50\u65cb\u8f6c\u4e0eNa<sup>+<\/sup>\u8f93\u8fd0\u5b58\u5728\u8026\u5408\u3002<\/p>\n<p>\u5728\u5ba4\u6e29\u4e0b\u7a33\u5b9a\u8f6c\u52a8\u76f8<\/p>\n<p>\u5927\u591a\u6570\u5316\u5408\u7269\u4ec5\u80fd\u5728\u5176\u9ad8\u6e29\u76f8\u4e2d\u624d\u8868\u73b0\u51fa\u9634\u79bb\u5b50\u8f6c\u52a8\u884c\u4e3a\u53ca\u8d85\u5feb\u9633\u79bb\u5b50\u4f20\u5bfc\u6027\u8d28\uff0c\u6545\u800c\u6709\u5fc5\u8981\u5c06\u6709\u5e8f-\u65e0\u5e8f\u7684\u76f8\u53d8\u6e29\u5ea6\u964d\u4f4e\u5230\u63a5\u8fd1\u6216\u751a\u81f3\u4f4e\u4e8e\u5ba4\u6e29\uff0c\u4f7f\u5f97\u5728\u5ba4\u6e29\u4e0bpaddle-wheel\u673a\u5236\u88ab\u6fc0\u6d3b\u4ece\u800c\u5f00\u53d1\u5ba4\u6e29\u9ad8\u9633\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u6750\u6599\u3002\u65e0\u5e8f\u7684\u9ad8\u6e29\u76f8\u53ef\u901a\u8fc7\u7279\u5b9a\u7684\u5316\u5b66\u8c03\u63a7\u7b56\u7565\u6765\u7a33\u5b9a\uff0c\u5373\u63d0\u9ad8\u65e0\u5e8f\u76f8\u7684\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\u6765\u964d\u4f4eT<sub>trans<\/sub>\uff0c\u6216\u901a\u8fc7\u52a8\u529b\u5b66\u6291\u5236\u7684\u65b9\u5f0f\uff0c\u4f7f\u5f97\u9ad8\u6e29\u76f8\u7684\u65e0\u5e8f\u7ed3\u6784\u88ab\u90e8\u5206\u51bb\u7ed3\u5728\u5ba4\u6e29\u3002\u524d\u8005\u53ef\u4ee5\u901a\u8fc7\u8c03\u8282\u9634\/\u9633\u79bb\u5b50\u7684\u5c3a\u5bf8\u6bd4\u3001\u6539\u53d8\u805a\u9634\u79bb\u5b50\u7684\u5bf9\u79f0\u6027\u53ca\u6df7\u5408\u5176\u4ed6\u9634\u79bb\u5b50\u7b49\u65b9\u5f0f\uff0c\u8c03\u6574\u56fa\u5b9a\u7684\u6216\u53ef\u79fb\u52a8\u7684\u4e9a\u6676\u683c\u6765\u5b9e\u73b0\uff08\u56fe6a, b\uff09\uff0c\u5177\u4f53\u7684\u65b9\u5f0f\u5305\u62ec\uff1a\u5c06\u591a\u79cd\u5143\u7d20\u6574\u5408\u5230\u540c\u4e00\u6676\u683c\u4f4d\u70b9\u6216\u5f15\u5165\u9633\u79bb\u5b50\u65e0\u5e8f\uff0c\u901a\u8fc7\u71b5\u589e\u7684\u65b9\u5f0f\u5c06\u9633\u79bb\u5b50\u548c\u9634\u79bb\u5b50\u7684\u65e0\u5e8f\u7ed3\u6784\u7a33\u5b9a\u5728\u5ba4\u6e29\uff1b\u8fdb\u884c\u7403\u78e8\u5904\u7406\u51cf\u5c0f\u6676\u4f53\u5c3a\u5bf8\uff0c\u4ece\u800c\u6709\u6548\u964d\u4f4eT<sub>trans<\/sub>\uff08\u56fe6d\uff09\u3002\u540e\u8005\u53ef\u901a\u8fc7\u4f7f\u73bb\u7483\u6001\u524d\u9a71\u4f53\u7ed3\u6676\u4f7f\u5f97\u73bb\u7483\u6001\u7684\u65e0\u5e8f\u90e8\u5206\u4fdd\u7559\u5728\u5ba4\u6e29\uff08\u56fe6c\uff09\u6216\u5c06\u73bb\u7483\u6001\u524d\u9a71\u4f53\u6dec\u706b\u5904\u7406\u6765\u5b9e\u73b0\u3002<\/p>\n<p>\u503c\u5f97\u6ce8\u610f\u7684\u662f\u9634\u79bb\u5b50\u91cd\u5b9a\u5411\u6216\u65cb\u8f6c\u8fd0\u52a8\u7684\u8d77\u59cb\u6e29\u5ea6\u5e94\u901a\u8fc7\u5b9e\u9a8c\u7684\u65b9\u5f0f\u786e\u5b9a\uff0c\u4f8b\u5982\u7ed3\u5408\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\u3001X\u5c04\u7ebf\/\u4e2d\u5b50\u884d\u5c04\u53ca\u53d8\u6e29\u7535\u5bfc\u7684\u6d4b\u91cf\u6765\u5b8c\u6210\u3002\u65e0\u6cd5\u5355\u72ec\u901a\u8fc7AIMD\u6a21\u62df\u786e\u5b9a\u8be5\u6e29\u5ea6\uff0c\u8fd9\u4e3b\u8981\u662f\u56e0\u4e3a\u4f4e\u6a21\u62df\u6e29\u5ea6\u6240\u5f97\u7684\u6570\u636e\u5341\u5206\u6709\u9650\u3002<\/p>\n<p>\u56fe6.\u00a0\u5728\u5ba4\u6e29\u4e0b\u7a33\u5b9a\u65cb\u8f6c\u76f8\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232471\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72476-4.png\" alt=\"\" width=\"1297\" height=\"758\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72476-4.png 1297w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72476-4-300x175.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72476-4-768x449.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72476-4-1024x598.png 1024w\" sizes=\"(max-width: 1297px) 100vw, 1297px\" \/><\/p>\n<p>(a)\u00a0\u65e0\u5e8f\u7684\u8d85\u79bb\u5b50\u76f8\u53ef\u4ee5\u901a\u8fc7\u4e0e\u5176\u4ed6\u9634\u79bb\u5b50\u6df7\u5408\u4ee5\u8bf1\u5bfc\u9633\u79bb\u5b50\/\u7a7a\u4f4d\u65e0\u5e8f\uff0c\u4ece\u800c\u589e\u5f3a\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\uff1b(b)\u00a0\u7528[BH<sub>4<\/sub>]<sup>&#8211;<\/sup>\u53d6\u4ee3\u9634\u79bb\u5b50\u4f1a\u4ea7\u751f\u8f6c\u5b50\u76f8\u5e76\u5f15\u8d77\u7535\u5bfc\u7387\u03c3\u663e\u8457\u589e\u52a0\uff1b(c)\u00a0\u73bb\u7483\u524d\u9a71\u4f53\u7684\u7ed3\u6676\u53ef\u4ee5\u5728\u9634\u79bb\u5b50\u4e9a\u6676\u683c\u4e2d\u201c\u51bb\u7ed3\u201d\u65e0\u5e8f\uff0c\u4ece\u800c\u5f15\u53d1\u9633\u79bb\u5b50\u65e0\u5e8f\uff1b(d)\u00a0\u4f5c\u4e3a\u6dec\u706b\u7684\u66ff\u4ee3\u65b9\u6cd5\uff0c\u7403\u78e8\u51cf\u5c0f\u4e86\u5fae\u6676\u7684\u5c3a\u5bf8\u5e76\u5f15\u5165\u4e86\u65e0\u5e8f\u6548\u5e94\uff0c\u53ef\u4ee5\u5c06\u7c7b\u4f3c\u9ad8\u6e29\u7684\u5feb\u79bb\u5b50\u5bfc\u7535\u76f8\u5728\u5ba4\u6e29\u4e2d\u7a33\u5b9a\uff0c\u4ece\u800c\u5bfc\u81f4\u9633\u79bb\u5b50\u7535\u5bfc\u7387\u63d0\u9ad8\u51e0\u4e2a\u6570\u91cf\u7ea7\u3002<\/p>\n<p>\u9634\u79bb\u5b50\u52a8\u529b\u5b66\u7684\u5f71\u54cd<\/p>\n<p>\u5728Li<sub>2<\/sub>SO<sub>4<\/sub>\u7684\u8f6c\u52a8\u76f8\u4e2d\uff0c\u5355\u4ef7\u9633\u79bb\u5b50(Li<sup>+<\/sup>, Na<sup>+<\/sup>, K<sup>+<\/sup>, Ag<sup>+<\/sup>\u00a0,Rb<sup>+<\/sup>, Tl<sup>+<\/sup>)\u6269\u6563\u7cfb\u6570\u4e3a10<sup>-5<\/sup>\u00a0cm<sup>2<\/sup>\u00a0s<sup>-1<\/sup>\uff0c \u4e8c\u4ef7\u9633\u79bb\u5b50(Ca<sup>2+<\/sup>, Mg<sup>2+<\/sup>, Ba<sup>2+<\/sup>, Zn<sup>2+<\/sup>, Mn<sup>2+<\/sup>, Pb<sup>2+<\/sup>, Cd<sup>2+<\/sup>)\u6269\u6563\u7cfb\u6570\u4e3a10<sup>-6<\/sup>\u00a0cm<sup>2<\/sup>\u00a0s<sup>-1<\/sup>\uff0c\u8fd9\u4e00\u73b0\u8c61\u65e0\u6cd5\u7528\u4f20\u7edf\u7684\u79bb\u5b50\u8dc3\u8fc1\u673a\u5236\u89e3\u91ca\u3002\u6b64\u5916\uff0c\u5176\u79bb\u5b50\u7535\u5bfc\u7387-\u6e29\u5ea6\u66f2\u7ebf\u4e0d\u7b26\u5408Arrhenius\u5173\u7cfb\uff0c\u8868\u660e\u79bb\u5b50\u8dc3\u8fc1\u4e0d\u662f\u901a\u8fc7\u7b80\u5355\u7684\u70ed\u6fc0\u6d3b\u5bfc\u81f4\u7684\uff0c\u5e94\u5c06\u9634\u79bb\u5b50\u8f6c\u52a8\u8003\u8651\u8fdb\u6765\u3002<\/p>\n<p>\u5f53\u805a\u9634\u79bb\u5b50\u65cb\u8f6c\u4e0e\u9633\u79bb\u5b50\u6269\u6563\u53d1\u751f\u5728\u540c\u4e00\u65f6\u95f4\u5c3a\u5ea6\u4e0a\u65f6\uff0c\u8fd9\u4e24\u79cd\u8fd0\u52a8\u5b58\u5728\u534f\u540c\u4f5c\u7528\u3002AIMD\u6a21\u62df\u8868\u660e\uff0c\u9634\u79bb\u5b50\u65cb\u8f6c\u53ef\u77ac\u65f6\u6269\u5927\u9633\u79bb\u5b50\u8fc1\u79fb\u7684\u74f6\u9888\uff0c\u964d\u4f4e\u9633\u79bb\u5b50\u8dc3\u8fc1\u80fd\u5792\u3002\u5728\u5b8f\u89c2\u5c3a\u5ea6\u4e0a\uff0c\u805a\u9634\u79bb\u5b50\u65cb\u8f6c\u53ef\u5728\u6269\u6563\u5f00\u59cb\u65f6\u53ca\u6269\u6563\u8fc7\u7a0b\u4e2d\u964d\u4f4e\u9633\u79bb\u5b50\u6240\u611f\u77e5\u5230\u7684\u52bf\u80fd\u3002\u77ed\u65f6\u95f4\u5c3a\u5ea6\u7684\u9634\u79bb\u5b50\u65cb\u8f6c\u53ef\u6539\u53d8\u5c40\u90e8\u52bf\u80fd\uff0c\u4e3a\u9633\u79bb\u5b50\u6269\u6563\u63d0\u4f9b\u4e86\u9a71\u52a8\u529b\uff0c\u5bfc\u81f4\u9633\u79bb\u5b50\u91cd\u6392\u5e76\u6cbf\u7740\u4f4e\u80fd\u5792\u7684\u8def\u5f84\u6269\u6563\u3002<\/p>\n<p>ASSBs\u4e2d\u8f6c\u52a8\u76f8\u7684\u8bc4\u4f30<\/p>\n<p>\u805a\u9634\u79bb\u5b50\u7684\u65cb\u8f6c\u8fd0\u52a8\u5e7f\u6cdb\u5730\u5b58\u5728\u4e8e\u591a\u79cd\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\uff0c\u5305\u62ec\u786b\u4ee3\u78f7\u9178\u76d0\u3001\u786b\u9178\u76d0\u3001\u78f7\u9178\u76d0\u3001\u787c\u6c22\u5316\u7269\u3001\u95ed\u5408\u578b\u787c\u9178\u76d0\u548c\u5364\u5316\u7269\uff0c\u800c\u8d85\u79bb\u5b50\u5bfc\u4f53\u4e2d\u7684\u9634\u79bb\u5b50\u8fd0\u52a8\u53ca\u5176\u4e0e\u9633\u79bb\u5b50\u6269\u6563\u7684\u8026\u5408\u7a0b\u5ea6\u8fd8\u9700\u8981\u8fdb\u4e00\u6b65\u7684\u7814\u7a76\u3002\u76f8\u8f83\u4e8e\u57fa\u4e8e\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u4f20\u7edf\u5145\u7535\u7535\u6c60\uff08\u56fe7a\uff09\uff0cASSB\u6709\u671b\u5b9e\u73b0\u66f4\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u66f4\u9ad8\u5b89\u5168\u6027\uff0c\u56e0\u4e3a\u5b83\u4eec\u53ef\u4ee5\u6574\u5408\u9ad8\u538b\u6b63\u6781\u548c\u9502\u91d1\u5c5e\u8d1f\u6781\u4e14\u4e0d\u5177\u6709\u6613\u71c3\u6613\u7206\u7684\u6027\u8d28\uff08\u56fe7b\uff09\u3002\u4ee5\u4e24\u7c7b\u56fa\u6001\u7535\u89e3\u8d28\u4e3a\u4f8b\uff0c\u4ecb\u7ecd\u8f6c\u52a8\u76f8\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4e00\u7c7b\u662f\u5177\u6709\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u786b\u4ee3\u78f7\u9178\u76d0\uff1aLi<sub>10<\/sub>GeP<sub>2<\/sub>S<sub>12<\/sub>\uff0812 mS cm<sup>-1<\/sup>\uff09\u53ca\u5176\u884d\u751f\u7269\uff1b\u53e6\u4e00\u7c7b\u662fLi<sup>+<\/sup>\u5bfc\u7535\u6216Na<sup>+<\/sup>\u5bfc\u7535\u7684\u5364\u5316\u7269\uff0c\u5b83\u4eec\u5728\u4e0e\u9ad8\u538b\u6c27\u5316\u7269\u6b63\u6781\u63a5\u89e6\u65f6\u8868\u73b0\u51fa\u826f\u597d\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002<\/p>\n<p>\u786b\u4ee3\u78f7\u9178\u76d0\u5177\u6709\u826f\u597d\u7684\u5ef6\u5c55\u6027\uff0c\u5bb9\u6613\u5f62\u6210\u81f4\u5bc6\u7684\u4f4e\u7535\u963b\u6b63\u6781\u590d\u5408\u5c42\uff0c\u4f46\u5176\u7535\u5316\u5b66\u7a97\u53e3\u7a84\uff0c\u6613\u53d1\u751f\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u56e0\u6b64\uff0c\u5305\u8986\u6750\u6599\u5bf9\u4e8e\u7a33\u5b9a\u7535\u89e3\u8d28\/\u7535\u6781\u754c\u9762\u81f3\u5173\u91cd\u8981\u3002\u5728LiNbO<sub>3<\/sub>\u7684\u4fdd\u62a4\u4e0b\uff0c\u57fa\u4e8eLi<sub>10<\/sub>GeP<sub>2<\/sub>S<sub>12<\/sub>(LGPS)\u578b\u9aa8\u67b6\u786b\u4ee3\u78f7\u9178\u76d0\u6750\u6599\u7684ASSBs\u5373\u4f7f\u5728\u5145\u7535\u81f3\u9ad8\u538b\u65f6\uff0c\u4e5f\u80fd\u5728\u9ad8\u500d\u7387\u4e0b\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u6c60\u6027\u80fd\uff0c\u8868\u660eASSBs\u53ef\u63d0\u4f9b\u9ad8\u529f\u7387\u5bc6\u5ea6\uff08\u56fe\u00a07d\uff09\u3002<\/p>\n<p>\u6700\u8fd1\u53d1\u73b0\u7684\u5177\u6709\u9ad8\u5bfc\u7535\u6027\u7684\u5364\u5316\u7269\u7535\u89e3\u8d28\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u9502\u548c\u94a0\u7684\u5364\u5316\u7269\u5728\u4e0e\u9ad8\u538b\u6c27\u5316\u7269\u6b63\u6781\u63a5\u89e6\u65f6\u8868\u73b0\u51fa\u826f\u597d\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff08\u9ad8\u8fbe4.6V\uff0c\u751a\u81f34.8V\uff09\uff0c\u5e76\u5728ASSB\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u56fe7c\uff09\u3002\u8fd9\u4e9b\u7814\u7a76\u8868\u660e\uff0c\u65e0\u673a\u5851\u6676\u76f8\u662f\u6709\u524d\u9014\u7684\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u53ef\u4ee5\u5728\u672a\u6765\u51e0\u5e74\u8fdb\u4e00\u6b65\u63a8\u52a8\u5177\u6709\u9ad8\u529f\u7387\u5bc6\u5ea6\u548c\u9ad8\u7535\u538b\u7684ASSBs\u7684\u53d1\u5c55\u3002<\/p>\n<p>\u56fe7.\u00a0\u8bc4\u4f30ASSB\u4e2d\u7684\u65cb\u8f6c\u76f8\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232472\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72477-4.png\" alt=\"\" width=\"733\" height=\"664\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72477-4.png 733w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/\u56fe\u72477-4-300x272.png 300w\" sizes=\"(max-width: 733px) 100vw, 733px\" \/><\/p>\n<p>\uff08a\uff0cb\uff09\u4f20\u7edf\u6db2\u6001\u9502\u79bb\u5b50\u7535\u6c60\u548c\u9502\u91d1\u5c5e\u5168\u56fa\u6001\u7535\u6c60\u793a\u610f\u56fe\uff1b\uff08c\uff09\u4e24\u79cd\u4e0d\u540cASSB\u5728\u4e0d\u540c\u500d\u7387\u4e0b\u7684\u653e\u7535\u66f2\u7ebf\uff1b\uff08d\uff09\u5df2\u62a5\u9053\u7684\u7535\u6c60\u548c\u7535\u5bb9\u5668\u7684Ragone\u00a0\u56fe<\/p>\n<p><strong>\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n<p>\u5229\u7528\u6700\u5148\u8fdb\u7684\u6280\u672f(NMR, QENS\u548cAIMD)\u5df2\u79ef\u7d2f\u4e86\u8db3\u591f\u7684\u8bc1\u636e\u6765\u8bc1\u5b9e\u548c\u89e3\u91ca paddle-wheel \u673a\u5236\u2014\u2014\u5373\u8f6c\u52a8\u76f8\u4e2d\u9634\u79bb\u5b50\u7684\u65cb\u8f6c\u8fd0\u52a8\u6709\u5229\u4e8e\u4fc3\u8fdb\u9633\u79bb\u5b50\u7684\u5e73\u79fb\u6269\u6563\u3002\u8fc7\u53bb\u51e0\u5e74\u7684\u7814\u7a76\u4e0d\u4ec5\u62d3\u5bbd\u4e86\u6211\u4eec\u7684\u89c6\u91ce\uff0c\u66f4\u91cd\u8981\u7684\u662f\u6307\u51fa\u4e86\u5229\u7528paddle-wheel\u673a\u5236\u9884\u6d4b\u548c\u5f00\u53d1\u6750\u6599\u7684\u65b0\u65b9\u5411\u3002\u9634\u79bb\u5b50\u65cb\u8f6c\u7684\u8d77\u59cb\u6e29\u5ea6\u53ef\u4ee5\u901a\u8fc7\u71b5\u589e\u673a\u5236\u8fdb\u884c\u8c03\u63a7\uff0c\u5b9e\u73b0\u8f83\u4f4e\u7684\u76f8\u53d8\u6e29\u5ea6\u6216\u4ece\u52a8\u529b\u5b66\u4e0a\u5c06\u9ad8\u6e29\u65e0\u5e8f\u7ed3\u6784\u51b7\u51bb\u5728\u5ba4\u6e29\u3002\u5316\u5b66\u53d6\u4ee3\u3001\u673a\u68b0\u7403\u78e8\u548c\u9ad8\u6e29\u7194\u4f53\u6dec\u706b\u7b49\u65b9\u6cd5\u5df2\u88ab\u8bc1\u660e\u662f\u6709\u6548\u7684\u8c03\u63a7\u624b\u6bb5\u3002\u5229\u7528\u9634\u79bb\u5b50\u65cb\u8f6c\u6765\u63d0\u9ad8\u65e0\u673a\u8f6c\u52a8\u76f8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u662f\u4e00\u79cd\u5177\u6709\u6f5c\u529b\u7684\u63a2\u7d22\u65b0\u578b\u8d85\u79bb\u5b50\u5bfc\u4f53\u7684\u65b9\u6cd5\u3002\u9634\u79bb\u5b50\u52a8\u529b\u5b66\u4e5f\u53ef\u4ee5\u4f5c\u4e3a\u4e00\u79cd\u989d\u5916\u7684\u63cf\u8ff0\u7b26\uff0c\u5e2e\u52a9\u6211\u4eec\u7406\u89e3\u56fa\u6001\u6750\u6599\u79cd\u79bb\u5b50\u4f20\u5bfc\u73b0\u8c61\u53ca\u673a\u7406\u3002<\/p>\n<p><strong><b>\u3010\u53c2\u8003\u6587\u732e\u3011<\/b><\/strong><\/p>\n<p>[1] Zhang, Zhizhen; Nazar, Linda F*; Exploiting Paddle-wheel Mechanism for the Design of Fast Ion Conductors. <strong><em><b>Nature Reviews Materials<\/b><\/em><\/strong>, 2022, <u>https:\/\/www.nature.com\/articles\/s41578-021-00401-0.<\/u><\/p>\n<p>[2] Zhang, Zhizhen; Nazar, Linda F.*; Coupled Cation-Anion Dynamics Enhances Cation Mobility in Room-Temperature Superionic Solid-State Electrolytes, <strong><em><b>Journal of the American Chemical Society<\/b><\/em><\/strong>, 2019, 141(49): 19360-19372.<\/p>\n<p>[3] Zhang, Zhizhen; Linda F., Nazar*; Targeting Superionic Conductivity by Turning on Anion Rotation at Room Temperature in Fast Ion Conductors,<strong><em><b>\u00a0Matter<\/b><\/em><\/strong>, 2020, 2(6): 1667-1684.<\/p>\n<p><strong><b>\u3010\u4f5c\u8005\u4ecb\u7ecd\u3011<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232473\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/Picture-23.png\" alt=\"\" width=\"250\" height=\"320\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/Picture-23.png 250w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/Picture-23-234x300.png 234w\" sizes=\"(max-width: 250px) 100vw, 250px\" \/><\/p>\n<p><strong><b>\u7ae0\u5fd7\u73cd<\/b><\/strong>\uff0c\u4e2d\u5c71\u5927\u5b66\u201c\u767e\u4eba\u8ba1\u5212\u201d\u5f15\u8fdb\u4e2d\u9752\u5e74\u5b66\u672f\u9aa8\u5e72\u3002\u535a\u58eb\u6bd5\u4e1a\u4e8e\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\uff0c\u5e08\u4ece\u4e2d\u56fd\u5de5\u7a0b\u9662\u9662\u58eb\u9648\u7acb\u6cc9\u7814\u7a76\u5458\u548c\u4e2d\u79d1\u9662\u4e07\u4eba\u9886\u519b\u8ba1\u5212\u5f15\u8fdb\u7684\u80e1\u52c7\u80dc\u7814\u7a76\u5458\uff08\u56fd\u5bb6\u6770\u9752\uff09\u3002\u968f\u540e\u5728\u52a0\u62ff\u5927\u6ed1\u94c1\u5362\u5927\u5b66Linda Nazar\u9662\u58eb\u7ec4\u5b8c\u6210\u535a\u58eb\u540e\u7814\u7a76\u30022020\u5e74\u5165\u804c\u4e2d\u5c71\u5927\u5b66\u6750\u6599\u5b66\u9662\u3002\u957f\u671f\u4ece\u4e8b\u56fa\u6001\u7535\u5316\u5b66\u76f8\u5173\u7684\u50a8\u80fd\u7535\u5316\u5b66\u6750\u6599\u4e0e\u5668\u4ef6\u7684\u7814\u7a76\uff0c\u81f4\u529b\u4e8e\u9502\/\u94a0\u79bb\u5b50\u5728\u56fa\u4f53\u4e2d\u8f93\u8fd0\u673a\u7406\u7684\u7814\u7a76\u4ee5\u53ca\u9502\/\u94a0\u56fa\u6001\u7535\u6c60\u4e2d\u56fa-\u56fa\u754c\u9762\u6269\u6563\u52a8\u529b\u5b66\u7684\u8c03\u63a7\u3002\u7ed3\u5408\u4e2d\u5b50\u884d\u5c04\u3001\u900f\u5c04\u7535\u955c\u7b49\u5b9e\u9a8c\u8868\u5f81\u624b\u6bb5\u53ca\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u3001\u4ece\u5934\u7b97\u5206\u5b50\u52a8\u529b\u5b66 (AIMD) \u6a21\u62df\u3001\u58f0\u5b50\u8c31\u7b49\u7406\u8bba\u6a21\u62df\uff0c\u4ece\u5fae\u89c2\u539f\u5b50\u5c3a\u5ea6\u7406\u89e3\u56fa\u4f53\u6750\u6599\u4e2d\u79bb\u5b50\u8f93\u8fd0\u884c\u4e3a\u53ca\u8dc3\u8fc1\u673a\u5236\u3002\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u539f\u521b\u6027\u7684\u6210\u679c\uff0c\u8fd15\u5e74\u6765\u5171\u53d1\u8868\u9ad8\u6c34\u5e73\u5b66\u672f\u8bba\u6587\u8fd130\u7bc7\uff0c\u4e00\u4f5c\/\u901a\u8baf\u8bba\u6587\u5305\u62ec\u56fd\u9645\u9876\u7ea7\u5b66\u672f\u671f\u520aNature Review Materials, J. Am. Chem. Soc., Energy Environ. Sci., Matter, Sci. Advances, Adv. Energy Mater.\u7b49\uff0c\u591a\u7bc7ESI\u9ad8\u88ab\u5f15\u8bba\u6587\uff0c\u5355\u7bc7\u6700\u9ad8\u5f15\u7528\u8fd1600\u6b21\u3002\u8be6\u89c1\uff1a<a href=\"https:\/\/scholar.google.com\/citations?user=sD5G6F0AAAAJ&amp;hl=en\"><u>https:\/\/scholar.google.com\/citations?user=sD5G6F0AAAAJ&amp;hl=en<\/u><\/a><u>\u3002<\/u>\u62c5\u4efbFrontiers in Energy Research\u7684\u5ba2\u5ea7\u7f16\u8f91\u53ca\u591a\u4e2a\u5177\u6709\u91cd\u8981\u5f71\u54cd\u529b\u671f\u520a\u7684\u5e38\u7528\u5ba1\u7a3f\u4eba\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-232474\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/01\/Picture-24.png\" alt=\"\" width=\"160\" height=\"200\" \/><\/p>\n<p><strong><b>Linda Nazar<\/b><\/strong><strong><b>, <\/b><\/strong>\u52a0\u62ff\u5927\u7687\u5bb6\u5b66\u4f1a\u53ca\u82f1\u56fd\u7687\u5bb6\u5b66\u4f1a\u9662\u58eb\u3001\u56fd\u9645\u9876\u5c16\u7684\u80fd\u6e90\u6750\u6599\u4e0e\u56fa\u6001\u5316\u5b66\u4e13\u5bb6\u3001\u52a0\u62ff\u5927\u56fa\u6001\u80fd\u6e90\u9996\u5e2d\u79d1\u5b66\u5bb6<strong>\u3002<\/strong>\u5176\u7814\u7a76\u6db5\u76d6\u9502\u786b\u7535\u6c60\u3001\u9502\u7a7a\u6c14\u7535\u6c60\u3001\u9502\u79bb\u5b50\u7535\u6c60\u3001\u94a0\u79bb\u5b50\u7535\u6c60\u3001\u9541\u79bb\u5b50\u7535\u6c60\u7b49\u3002\u66fe\u83b7MRS \u5956\u7ae0\uff082020\uff09\u3001\u82f1\u56fd\u7687\u5bb6\u5b66\u4f1a\u4f1a\u58eb\uff082020\uff09\u3001CIC\u5956\u7ae0\uff082019\uff09\u3001\u52a0\u62ff\u5927\u59d4\u4efb\u5b98\u5458\uff082015\uff09\u3001\u52a0\u62ff\u5927\u7687\u5bb6\u5b66\u4f1a\u4f1a\u58eb\uff082011\uff09\u3001\u7f8e\u56fd\u5316\u5b66\u4f1a\u5316\u5b66\u6216\u5316\u5b66\u5de5\u7a0b\u6770\u51fa\u5973\u6027\u5956\uff082011\uff09\u3001\u52a0\u5dde\u7406\u5de5\u6770\u51fa\u6469\u5c14\u5b66\u8005\uff082010\uff09\u3001\u56fd\u9645\u7535\u5316\u5b66\u4f1a\u7535\u6c60\u7814\u7a76\u5956\uff082009\uff09\u3001\u201c\u5168\u7403\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u201d\uff082014\u30012016\u30012018\u30012020\uff09\u7b49\u3002\u5728Science\u3001Nat. Mater.\u3001Nat. Chem.\u3001Nat. Energy\u3001Chem. Rev.\u3001JACS\u3001Energy Environ. Sci.\u3001Nat. Commun.\u3001Angew\u3001Adv. Mater.\u3001Adv. Energy Mater.\u7b49\u56fd\u9645\u8457\u540d\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u6587300\u591a\u7bc7\uff0c\u88ab\u5f1553000\u591a\u6b21\uff0cH\u56e0\u5b50107\u3002\u62c5\u4efbEnergy Environ. Sci., Matter\u7b49\u6742\u5fd7\u7684\u7f16\u59d4\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u5feb\u79bb\u5b50\u5bfc\u4f53\u662f\u56fa\u6001\u5668\u4ef6\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u7ec4\u6210\u90e8\u5206\uff0c\u8fd9\u7c7b\u6750\u6599\u5728\u56fa\u6001\u72b6\u6001\u4e0b\u8868\u73b0\u51fa\u548c\u6db2\u6001\u5ab2\u7f8e\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u4ece\u539f\u5b50\u5c3a\u5ea6\u4e0a\u7406\u89e3\u79bb\u5b50\u8d85\u5feb\u4f20\u5bfc\u884c\u4e3a\u7684\u672c\u8d28\uff0c\u6709\u52a9\u4e8e\u5176\u5e94\u7528\u4e8e&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-232462","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/232462"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=232462"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/232462\/revisions"}],"predecessor-version":[{"id":232475,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/232462\/revisions\/232475"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=232462"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=232462"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=232462"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}