{"id":232710,"date":"2022-02-04T06:36:08","date_gmt":"2022-02-03T22:36:08","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=232710"},"modified":"2022-02-03T19:36:17","modified_gmt":"2022-02-03T11:36:17","slug":"%e5%a4%a9%e6%b4%a5%e5%a4%a7%e5%ad%a6%e5%ba%b7%e9%b9%8facs-ami%ef%bc%9a%e7%ba%b3%e7%b1%b3%e5%8f%8d%e5%ba%94%e5%99%a8%e7%94%a8%e4%ba%8e%e9%85%b8%e6%80%a7%e6%9d%a1%e4%bb%b6%e4%b8%8b%e7%9a%84%e7%94%b5","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=232710","title":{"rendered":"\u5929\u6d25\u5927\u5b66\u5eb7\u9e4fACS AMI\uff1a\u7eb3\u7c73\u53cd\u5e94\u5668\u7528\u4e8e\u9178\u6027\u6761\u4ef6\u4e0b\u7684\u7535\u50ac\u5316CO2\u8fd8\u539f\u53cd\u5e94"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u7535\u5316\u5b66CO2<\/sub>\u8fd8\u539f\u53cd\u5e94(CO2<\/sub>RR)\u53ef\u5229\u7528\u53ef\u518d\u751f\u7535\u529b\u5c06CO2<\/sub>\u8f6c\u5316\u4e3a\u71c3\u6599\u548c\u5316\u5b66\u54c1\uff0c\u662f\u91cd\u8981\u7684\u78b3\u4e2d\u548c\u7684\u6280\u672f\u3002\u76ee\u524dCO2<\/sub>RR\u7535\u50ac\u5316\u5242\u4e3b\u8981\u5728\u4e2d\u6027\u6216\u78b1\u6027\u7535\u89e3\u6db2\u4e2d\u5de5\u4f5c\uff0c\u8fd9\u4e9b\u6761\u4ef6\u4e0b\u539f\u6599\u6c14CO2<\/sub>\u4f1a\u5927\u91cf\u5730\u8f6c\u53d8\u4e3a\u65e0\u7528\u7684\u78b3\u9178\u76d0\uff0c\u4f7fCO2<\/sub>\u8f6c\u5316\u6548\u7387\u964d\u4f4e\uff0c\u50ac\u5316\u8fd0\u884c\u65f6\u957f\u7f29\u77ed\u3002\u5728\u9178\u6027\u7535\u89e3\u8d28\u4e2d\u8fdb\u884cCO2<\/sub>RR\u5219\u53ef\u4ee5\u907f\u514d\u78b3\u9178\u76d0\u7684\u5f62\u6210\uff0c\u7136\u800c\u5728\u9178\u6027\u6761\u4ef6\u4e0b\uff0c\u6790\u6c22\u53cd\u5e94(HER)\u5c06\u53d8\u5f97\u5341\u5206\u5267\u70c8\uff0c\u56e0\u6b64\u5f88\u5c11\u6709\u9178\u6027CO2<\/sub>RR\u7684\u6587\u732e\u62a5\u9053\u3002<\/p>\n

\u6210\u679c\u7b80\u4ecb<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5929\u6d25\u5927\u5b66\u5316\u5de5\u5b66\u9662\u5eb7\u9e4f\u6559\u6388\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u7a7a\u95f4\u9650\u57df\u7684\u7b56\u7565\uff0c\u5408\u6210\u4e86\u5c01\u88c5Ni\u7eb3\u7c73\u9897\u7c92\u7684N\u63ba\u6742\u78b3\u7eb3\u7c73\u7b3c(Ni5<\/sub>@NCN)\u4f5c\u4e3a\u9ad8\u6548\u7684CO2<\/sub>RR\u7eb3\u7c73\u53cd\u5e94\u5668\u3002\u7eb3\u7c73\u53cd\u5e94\u5668\u662f\u86cb\u9ec4-\u58f3(yolk-shell)\u7ed3\u6784\uff0c\u53ef\u5c06CO2<\/sub>RR\u9650\u5236\u5728\u5176\u5185\u90e8\uff0c\u5e76\u4e14\u80fd\u591f\u6291\u5236\u8d28\u5b50\u5411\u5176\u5185\u90e8\u6269\u6563\u3002\u5728CO2<\/sub>RR\u8fc7\u7a0b\u4e2d\uff0c\u7531\u4e8e\u8d28\u5b50\u7684\u6d88\u8017\u548cOH–<\/sup>\u7684\u79ef\u7d2f\uff0c\u7eb3\u7c73\u53cd\u5e94\u5668\u5185\u90e8\u7684\u5c40\u90e8pH\u503c\u5347\u9ad8\uff0c\u4f7f\u5176\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u4e5f\u80fd\u6291\u5236HER\u3002\u5728\u4e2d\u6027\u6761\u4ef6\u4e0b(pH~7.2)\uff0cNi5<\/sub>@NCN\u7684CO\u7684\u6cd5\u62c9\u7b2c\u6548\u7387(FE)\u53ef\u8fbe\u523093.2%\uff1b\u5728\u9178\u6027\u6761\u4ef6\u4e0b(pH~2.5)\uff0c FECO<\/sub>\u4e5f\u80fd\u8fbe\u523084.3%\u3002\u5229\u7528\u7eb3\u7c73\u53cd\u5e94\u5668\u7684\u4f18\u70b9\uff0cCO2<\/sub>RR\u4e5f\u53ef\u4ee5\u5728\u9178\u6027\u819c\u7535\u6781(MEA)\u88c5\u7f6e\u4e2d\u8fdb\u884c\uff0c\u76f8\u6bd4\u4e8e\u4e2d\u6027MEA\uff0c\u9178\u6027MEA\u53ef\u5b9e\u73b0\u66f4\u9ad8\u7684\u7535\u6d41\u5bc6\u5ea6\u548c\u66f4\u7a33\u5b9a\u7684\u6301\u7eed\u8fd0\u884c\u80fd\u529b\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1\u4e3a\u7eb3\u7c73\u53cd\u5e94\u5668\u7684\u5236\u5907\u8fc7\u7a0b\u3002\u9996\u5148\u901a\u8fc7\u6c34\u70ed\u6cd5\u5408\u6210\u915a\u919b\u6811\u8102\u5305\u8986\u7684SiO2<\/sub>\u7403\u505a\u524d\u9a71\u4f53\uff0c\u52a0\u5165\u4e09\u805a\u6c30\u80fa\u4f5c\u4e3aN\u6e90\uff0c\u524d\u9a71\u4f53\u70ed\u89e3\u540e\u523b\u8680\u6389\u7845\u7403\uff0c\u5f62\u6210N\u63ba\u6742\u78b3\u7eb3\u7c73\u7b3c(NCN)\u3002\u5728\u5fae\u5b54\u6bdb\u7ec6\u4f5c\u7528\u529b\u7684\u9a71\u52a8\u4e0b\uff0cNi2+<\/sup>\u6eb6\u6db2\u6269\u6563\u5230NCN\u5185\u90e8\u5f62\u6210NiO\u7eb3\u7c73\u9897\u7c92(NiO NPs)\u3002\u65bd\u52a0\u8fd8\u539f\u7535\u4f4d\u65f6\uff0cNiO NPs\u88ab\u8fd8\u539f\u6210Ni NPs\u3002<\/p>\n

\u56fe<\/strong>1<\/strong> \u7a7a\u95f4\u9650\u57df\u7eb3\u7c73\u53cd\u5e94\u5668\u7684\u5236\u5907\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u56fe2a, b\u6240\u793a\uff0cNCN\u5448\u73b0\u51fa\u4e2d\u7a7a\u7eb3\u7c73\u7b3c\u5f62\u8c8c(\u5e73\u5747\u76f4\u5f84~600 nm)\u3002\u56fe2d, e\u6240\u793a\uff0cNi5<\/sub>@NCNs\u5728\u52a0\u5165\u91d1\u5c5eNPs\u540e\u4fdd\u6301\u4e86\u7eb3\u7c73\u7b3c\u7684\u5f62\u72b6\uff0c N\u63ba\u6742\u58f3\u5c42\u7684\u539a\u5ea6\u4e3a20 nm\uff0c\u91d1\u5c5eNPs(\u5e73\u5747\u76f4\u5f84~17.3 nm)\u4f4d\u4e8eNCN\u8154\u5185\u3002<\/p>\n

\u56fe<\/strong>2<\/strong> \u7eb3\u7c73\u53cd\u5e94\u5668\u7684\u7535\u955c\u8868\u5f81\u7ed3\u679c<\/p>\n

\"\"<\/p>\n

NCN\u7684(a)SEM\u56fe\u50cf\u548c(b) TEM\u56fe\u50cf\uff1bNi5<\/sub>@NCN\u7684(c) SEM\u56fe\u50cf\u548c(d, e) TEM\u56fe\u50cf\uff1bNi5<\/sub>@NCN\u7684(f) HAADF-STEM\u56fe\u50cf\u548c(g-i) EDS\u56fe\u8c31\u3002<\/p>\n

Ni5<\/sub>@NCN\u5728\u6052\u7535\u4f4d\u7535\u89e3(CPE)\u524d\u540e\u7684Ni 2p XPS\u5982\u56fe3c\u6240\u793a\u3002\u5728CPE\u4e4b\u524d\uff0cNi 2p3\/2\u7684\u5cf0\u5f52\u5c5e\u4e8eNiII<\/sup> (856.3 eV)\uff0c\u800c\u5728CPE\u540e\uff0c\u5219\u662f\u4e3b\u8981\u662f\u91d1\u5c5e\u6001Ni (853.8 eV)\uff0c\u8bf4\u660e\u65bd\u52a0\u9634\u6781\u7535\u4f4d\u540e\uff0cNiO NPs\u88ab\u8fd8\u539f\u4e3aNi NPs\u3002<\/p>\n

\u56fe<\/strong>3<\/strong> \u7eb3\u7c73\u53cd\u5e94\u5668\u7684\u7269\u6027\u8868\u5f81\u7ed3\u679c<\/p>\n

\"\"<\/p>\n

NCN\u3001NiX<\/sub>@NCN\u548cNi5<\/sub>\/NCS\u7684(a) XRD\u8c31\u56fe\u548c(b) Raman\u5149\u8c31\uff1bNi5<\/sub>@NCN\u7684(c) Ni 2p\u548c(d) N 1s\u7684\u9ad8\u5206\u8fa8\u7387XPS\u5149\u8c31\u3002<\/p>\n

\u56fe4b\uff0cNi5<\/sub>@NCN\u7684FECO<\/sub>\u53ef\u4ee5\u8fbe\u523093.2%\u3002\u7a33\u5b9a\u6027\u6d4b\u8bd5\u5982\u56fe4d\u6240\u793a\uff0c\u5728-0.8 V vs. RHE\u4e0b\u6301\u7eed\u7535\u89e320 h\uff0c FECO<\/sub>\u548c\u7535\u6d41\u5bc6\u5ea6(j)\u6ca1\u6709\u660e\u663e\u4e0b\u964d\u3002\u50ac\u5316\u5242\u7684Nyquist\u56fe\u548cTafel\u56fe\u5982\u56fe4e,f\u6240\u793a\uff0cNi5<\/sub>@NCN\u8868\u73b0\u51fa\u66f4\u6709\u5229\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u3002<\/p>\n

\u56fe<\/strong>4<\/strong> \u7eb3\u7c73\u53cd\u5e94\u5668\u7684\u4e2d\u6027CO2<\/sub>RR\u7ed3\u679c<\/p>\n

\"\"<\/p>\n

\u50ac\u5316\u5242\u57280.5 M CO2<\/sub>\u9971\u548cKHCO3<\/sub>\u4e2d\u7684(a)LSV\uff0c(b) FECO<\/sub>\u548c(c) jCO\u3002(d)\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff1b (e) Nyquist\u56fe\uff1b(f) Tafel\u56fe\u3002<\/p>\n

Ni5<\/sub>@NCN\u5728\u8f83\u5bbd\u7684pH(1.0~7.2)\u8303\u56f4\u5185\u8868\u73b0\u51fa\u8f83\u597d\u7684CO2<\/sub>RR\u9009\u62e9\u6027\uff0c\u5728pH\u4e3a2.5\u65f6\uff0cNi5<\/sub>@NCN\u7684FECO<\/sub>\u4e3a84.3%\uff0c\u5373\u4f7f\u5728pH\u4e3a1.0\u65f6\uff0cFECO<\/sub>\u4e5f\u80fd\u8fbe\u523069.2%\uff0c\u4e14j\u8d85\u8fc730 mA cm-2<\/sup>(\u56fe5a-c)\u3002\u4e0e\u5176\u4ed6\u62a5\u9053\u7684\u9178\u6027\u6761\u4ef6\u50ac\u5316\u5242\u76f8\u6bd4\uff0cNi5<\/sub>@NCN\u53ef\u4ee5\u5728\u66f4\u4f4e\u7684pH\u503c\u4e0b\u5b9e\u73b0\u66f4\u9ad8\u7684FECO<\/sub> (\u56fe5d)\u3002\u5728Ar\u9971\u548c\u7684\u9178\u5316Na2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u8fdb\u884cCPE(\u56fe5e)\uff0c HER\u662f\u5728\u6b64\u6761\u4ef6\u4e0b\u552f\u4e00\u53ef\u884c\u7684\u53cd\u5e94\u3002\u5f53\u7535\u4f4d\u4f4e\u4e8e-1.4 V vs. Ag|AgCl\u65f6\uff0cNi5<\/sub>@NCN\u7684j\u8d8b\u4e8e\u7a33\u5b9a\uff0c\u8868\u73b0\u51fa\u53d7\u9650\u7684\u8d28\u5b50\u6269\u6563\u8fc7\u7a0b\u3002\u968f\u7740CO2<\/sub>RR\u7684\u8fdb\u884c\uff0c\u7eb3\u7c73\u53cd\u5e94\u5668\u5185\u7684H+<\/sup>\u4e0d\u65ad\u51cf\u5c11\uff0cOH–<\/sup>\u4e0d\u65ad\u79ef\u7d2f\uff0c\u7a7a\u95f4\u9650\u57df\u7684\u7eb3\u7c73\u53cd\u5e94\u5668\u6210\u4e3a\u4e86\u5c40\u90e8pH\u8c03\u8282\u5668\uff0c\u5f62\u6210\u78b1\u6027\u7684\u5fae\u5316\u5b66\u73af\u5883\u6765\u6291\u5236HER(\u56fe5f)\u3002<\/p>\n

\u56fe<\/strong>5<\/strong> \u7eb3\u7c73\u53cd\u5e94\u5668\u7684\u9178\u6027CO2<\/sub>RR\u7ed3\u679c<\/p>\n

\"\"<\/p>\n

(a)\u4e0d\u540cpH\u6761\u4ef6\u4e0b\u7684FECO<\/sub>\uff1bNi5<\/sub>@NCN\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u7684(b) FECO<\/sub>\u548c(c)j\uff1b(d)\u4e0e\u6587\u732e\u62a5\u9053\u76f8\u6bd4\u8f83\uff1b(e)\u9178\u6027\u7535\u89e3\u6db2\u4e2dHER\u7684j\uff1b (f) Ni5<\/sub>@NCN\u7684\u5fae\u5316\u5b66\u73af\u5883\u3002<\/p>\n

\u9178\u6027MEA\u7cfb\u7edf\u7684\u7ed3\u6784\u5982\u56fe6a\u6240\u793a\uff0c\u9634\u6781\u6db2\u548c\u9633\u6781\u6db2\u5206\u522b\u4e3a\u9178\u5316\u7684Na2<\/sub>SO4<\/sub>\u6eb6\u6db2\u548cH2<\/sub>SO4<\/sub>\u6eb6\u6db2\uff0c\u4f7f\u7528PEM\u5206\u9694\u9634\u9633\u4e24\u6781\u3002\u9178\u6027\u7535\u89e3\u6db2\u53ef\u4ee5\u907f\u514d\u4e2d\u6027\u6216\u78b1\u6027\u4f53\u7cfb\u4e2d\u7684\u78b3\u9178\u76d0\u751f\u6210\u73b0\u8c61\u3002pH\u4e3a2.5\u65f6\uff0c\u9178\u6027MEA\u7684FECO<\/sub>\u8fbe\u523080%(\u56fe6b)\u3002\u7531\u4e8ePEM\u5728\u9178\u6027\u6eb6\u6db2\u4e2d\u7684\u9ad8\u8d28\u5b50\u4f20\u5bfc\u7387\uff0c\u5176\u53ef\u5b9e\u73b0\u66f4\u9ad8\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u6700\u5927CO\u5c40\u90e8\u7535\u6d41\u5bc6\u5ea6(jCO<\/sub>)\u4e5f\u8fbe\u5230\u4e86102 mA cm-2<\/sup> (\u56fe6c)\u3002\u5728\u7a33\u5b9a\u6027\u6d4b\u8bd5\u4e2d(\u56fe6d)\uff0c\u9178\u6027\u4f53\u7cfb\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u7a33\u5b9a\u6027\uff1b\u800c\u5728\u4e2d\u6027\u4f53\u7cfb\u4e2d\uff0c K+<\/sup>\u4ece\u9633\u6781\u8fc1\u79fb\u5230\u9634\u6781\uff0c\u540c\u65f6\u9633\u6781\u6db2\u7531\u4e8e\u6790\u6c27\u53cd\u5e94(OER)\u800c\u9178\u5316\uff0c\u5bfc\u81f4\u7535\u89e3\u8d28\u7684\u51c0\u6d53\u5ea6\u4e0b\u964d\uff0cj\u4e0b\u964d\u3002\u5728\u9178\u6027\u7cfb\u7edf\u4e2d\uff0c\u8d28\u5b50\u4f5c\u4e3aMEA\u7684\u7535\u8377\u8f7d\u4f53\uff0c\u4e24\u4fa7\u7684H+<\/sup>\u6d53\u5ea6\u5728\u6574\u4e2a\u7535\u89e3\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u5e73\u8861\uff0c\u5f62\u6210\u4e86\u4e00\u4e2a\u957f\u671f\u7684\u3001\u7a33\u5b9a\u7684\u53cd\u5e94\u4f53\u7cfb\u3002<\/p>\n

\u56fe<\/strong>6<\/strong> \u9178\u6027MEA\u7535\u89e3\u7ed3\u679c<\/p>\n

\"\"<\/p>\n

(a)\u9178\u6027MEA\u6d41\u52a8\u7535\u89e3\u7cfb\u7edf\uff1b MEA\u7535\u89e3\u7684(b) FECO<\/sub>\u548c(c) j\uff1b(d)\u9178\u6027\u548c\u4e2d\u6027MEA\u7cfb\u7edf\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n

\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n

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\u3010\u6587\u732e\u94fe\u63a5\u3011<\/strong><\/p>\n

Zhikun Liu, Tao Yan, Han Shi, Hui Pan, Yingying Cheng and Peng Kang*\uff0cAcidic Electrocatalytic CO2<\/sub> Reduction Using Space-Confined Nanoreactors<\/p>\n

ACS Applied Materials & Interfaces, 2022, 10.1021\/acsami.1c21242<\/a><\/p>\n

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