{"id":233074,"date":"2022-02-15T12:00:35","date_gmt":"2022-02-15T04:00:35","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=233074"},"modified":"2022-02-15T12:00:38","modified_gmt":"2022-02-15T04:00:38","slug":"%e6%ad%a6%e6%b1%89%e7%90%86%e5%b7%a5-%e5%8d%8e%e4%b8%ad%e7%a7%91%e5%a4%a7%e8%81%94%e6%89%8b%e6%9c%80%e6%96%b0as%ef%bc%9a%e7%94%b5%e5%ad%90%e5%ae%9a%e4%bd%8d%e6%b3%95%e4%bd%bf%e8%b6%85%e8%96%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=233074","title":{"rendered":"\u6b66\u6c49\u7406\u5de5\/\u534e\u4e2d\u79d1\u5927\u8054\u624b\u6700\u65b0AS\uff1a\u7535\u5b50\u5b9a\u4f4d\u6cd5\u4f7f\u8d85\u8584\u5408\u91d1\u9502\u91d1\u5c5e\u8d1f\u6781\u5177\u6709\u4f18\u826f\u7a33\u5b9a\u6027"},"content":{"rendered":"<p style=\"text-align: center;\"><strong><b>[\u80cc\u666f\u4ecb\u7ecd]<\/b><\/strong><\/p>\n<p>\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u3001\u5b89\u5168\u6027\u597d\u3001\u7a33\u5b9a\u6027\u597d\u7684\u50a8\u80fd\u5668\u4ef6\u662f\u4e0b\u4e00\u4ee3\u7535\u6c60\u6280\u672f\u53d1\u5c55\u7684\u5fc5\u8981\u548c\u8feb\u5207\u8981\u6c42\u3002\u7535\u6781\u6750\u6599\u662f\u51b3\u5b9a\u80fd\u91cf\u5bc6\u5ea6\u7684\u5173\u952e\u3002\u9502\u91d1\u5c5e\u88ab\u8ba4\u4e3a\u662f\u6700\u7ec8\u7684\u8d1f\u6781\u6750\u6599\uff0c\u56e0\u4e3a\u5176\u7406\u8bba\u6bd4\u5bb9\u91cf\u4e3a3860 mAh g<sup>-1<\/sup>\uff0c\u4e0e\u6807\u51c6\u6c22\u7535\u6781\u76f8\u6bd4\u5177\u6709\u6781\u4f4e\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d(-3.04 V)\u3002\u7136\u800c\uff0c\u9502\u91d1\u5c5e\u8d1f\u6781\u76ee\u524d\u9762\u4e34\u7684\u4e24\u4e2a\u6700\u5927\u7684\u95ee\u9898\u662f\uff1a\u9502\u679d\u6676\u95ee\u9898(Li dendrites)\u548c\u65e0\u9650\u4f53\u79ef\u53d8\u5316\u95ee\u9898(Infinite volume change)\u3002\u9502\u679d\u6676\u95ee\u9898\u4e3b\u8981\u7531\u4e8e\u9502\u79bb\u5b50\u901a\u91cf\u4e0d\u5747\u5300\u548c\u7535\u6d41\u5bc6\u5ea6\u8f83\u5927\uff1b\u65e0\u9650\u4f53\u79ef\u53d8\u5316\u95ee\u9898\u5219\u7531\u4e8e\u9502\u91d1\u5c5e\u7535\u6781\u672c\u8eab\u5c5e\u6027\u6240\u51b3\u5b9a\u3002<\/p>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b>[\u6210\u679c\u7b80\u4ecb]<\/b><\/strong><\/p>\n<p>\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u8d75\u6587\u4fde\u3001\u8d75\u7131\u548c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u9ec4\u4e91\u8f89\u8bfe\u9898\u7ec4\u5408\u4f5c\uff0c\u63d0\u51fa\u901a\u8fc7\u5728\u94dc\u7b94\u8868\u9762\u6c89\u79efBi\u3001Al\u6216Au\u91d1\u5c5e\u4e0e\u9502\u8fdb\u884c\u539f\u4f4d\u5408\u91d1\u5316\uff0c\u5236\u5907\u5177\u6709\u7535\u5b50\u5c40\u57df\u5316\u548c\u9ad8\u8868\u9762\u529f\u51fd\u6570\u7684\u9502\u57fa\u8d85\u8584\u5408\u91d1\u3002<strong><b>\u672c\u5de5\u4f5c<\/b><\/strong><strong><b>\u53d1\u73b0\u7535\u5b50<\/b><\/strong><strong><b>\u5c40\u57df<\/b><\/strong><strong><b>\u5316\u53ef\u4ee5\u8bf1\u5bfc\u9502\u79bb\u5b50\u7684\u81ea\u5e73\u6ed1\u6548\u5e94\uff0c\u4ece\u800c\u663e\u7740\u6291\u5236\u679d\u6676\u9502\u7684\u751f\u957f\u3002\u540c\u65f6\uff0c\u9ad8\u8868\u9762\u529f\u51fd\u6570\u53ef\u4ee5\u6709\u6548\u7f13\u89e3\u7535\u89e3\u8d28\u4e0e\u9502\u4e4b\u95f4\u7684\u526f\u53cd\u5e94<\/b><\/strong>\u3002\u4ee5\u6240\u83b7\u5f97\u7684\u9502\u91d1\u5c5e\u8d85\u8584\u5408\u91d1\u4f5c\u4e3a\u8d1f\u6781\uff0c\u5b9e\u73b0\u4e86\u4f18\u5f02\u7684\u5faa\u73af\u6027\u80fd\u3002S||Bi\/Cu-Li\u5168\u7535\u6c60\u5728200\u6b21\u5faa\u73af\u540e\u63d0\u4f9b736 mAh g<sup>-1<\/sup>\u7684\u6bd4\u5bb9\u91cf\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5236\u9020\u957f\u5bff\u547d\u548c\u9ad8\u5bb9\u91cf\u9502\u7535\u6c60\u63d0\u4f9b\u4e86\u65b0\u7684\u7b56\u7565\u3002\u76f8\u5173\u8bba\u6587\u4ee5\u9898\u4e3a\uff1a\u201c<strong><em><i>Electronic Localization Derived Excellent Stability of Li Metal Anode with Ultrathin Alloy<\/i><\/em><\/strong>\u201d\u53d1\u8868\u5728<strong><em><i>Adv.Sci.<\/i><\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-233080 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72471-5.png\" alt=\"\" width=\"709\" height=\"287\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72471-5.png 709w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72471-5-300x121.png 300w\" sizes=\"(max-width: 709px) 100vw, 709px\" \/><\/p>\n<p><span style=\"text-decoration: line-through;\">\u00a0<\/span><\/p>\n<p style=\"text-align: center;\"><strong><b>[\u56fe\u6587\u89e3\u6790]<\/b><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>\u6c89\u79ef\u9502\u81ea\u5e73\u6ed1\u884c\u4e3a\u7684\u7406\u8bba\u9884\u6d4b<\/b><\/strong><\/li>\n<\/ul>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p><span style=\"color: #003366;\"><strong>\u7535\u5b50\u5c40\u57df\u51fd\u6570(ELF)<\/strong><\/span>\u5df2\u88ab\u6a21\u62df\u4e3a\u8868\u5f81\u81ea\u7531\u7535\u5b50\u5206\u5e03\u7684\u6709\u7528\u6307\u6807\u3002\u5177\u6709\u5927\u91cf\u5c40\u57df\u5316\u81ea\u7531\u7535\u5b50\u7684ELF\u8fd8\u610f\u5473\u7740\u7535\u5b50\u8f6c\u79fb\u8def\u5f84\u548c\u79bb\u5b50\u7684\u6f5c\u5728\u6c89\u79ef\u4f4d\u70b9\u3002Li(001)\u3001LiBi(111)\u3001LiAl(111) \u548c LiAu(011)\u8868\u9762\u7684ELF\u7ed3\u679c\u5206\u522b\u5982<strong>\u56fe1a1-d1<\/strong>\u6240\u793a\u3002\u81ea\u7531\u7535\u5b50\u5747\u5300\u5206\u5e03\u5728\u9502\u91d1\u5c5e\u7684\u8868\u9762\u548c\u4f53\u76f8\u4e2d\uff08<strong>\u56fe1a1<\/strong>\uff09\uff0c\u8fd9\u5bfc\u81f4\u9502\u79bb\u5b50\u5728\u8868\u9762\u4e0a\u6c89\u79ef\u7684\u6982\u7387\u76f8\u540c\u3002\u5f53\u5728Li(001)\u8868\u9762\u4e0a\u6c89\u79efLi\u7c07\u65f6\uff0c\u5728\u5b8c\u5168\u5f1b\u8c6b\u540e\uff0cLi\u7c07\u88ab\u5438\u9644\u5728Li\u91d1\u5c5e\u8868\u9762\u4e0a\uff0c\u5e76\u4e14\u7c07\u7684\u7ed3\u6784\u4ecd\u7136\u5b58\u5728\uff08<strong>\u56fe1a2<\/strong>\uff09\uff0c\u8fd9\u5bfc\u81f4\u4e86Li\u8868\u9762\u7684\u5c16\u7aef\u5f62\u72b6\u3002\u5982ELF\u7ed3\u679c\u6240\u793a\uff0c\u672a\u5206\u89e3\u7684\u7c07\u663e\u793a\u51fa\u5f3a\u70c8\u7684\u5c40\u57df\u5206\u5e03\u3002\u8fd9\u8868\u660e\u5747\u5300\u7684\u7535\u5b50\u5206\u5e03\u5bf9\u9502\u7c07\u7684\u9502\u6c89\u79ef\u548c\u5206\u89e3\u7684\u8c03\u8282\u4f5c\u7528\u8f83\u5c0f\u3002\u901a\u8fc7\u5bf9\u6bd4\uff0c\u9502\u5408\u91d1\uff08LiBi\u3001LiAl\u3001LiAu\uff09\u5728\u8868\u9762\u663e\u793a\u51fa\u81ea\u7531\u7535\u5b50\u7684\u5c40\u57df\u5206\u5e03\uff08<strong>\u56fe 1b1-d1<\/strong>\uff09\u3002\u5177\u4f53\u800c\u8a00\uff0c\u81ea\u7531\u7535\u5b50\u96c6\u4e2d\u5728Bi\u6216Al\u539f\u5b50\u5468\u56f4\uff0c\u503c\u5206\u522b\u4e3a0.5\u548c0.7\uff0c\u8fd9\u4e9b\u5177\u6709\u5c40\u57df\u7535\u5b50\u7684\u4f4d\u70b9\u53ef\u80fd\u8868\u73b0\u51fa\u5bf9Li<sup>+<\/sup>\u7684\u4eb2\u548c\u529b\uff0c\u5e76\u901a\u8fc7\u6709\u6548\u7684\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u8c03\u8282\u6c89\u79ef\u884c\u4e3a\u3002\u800c\u5728LiAu\u8868\u9762\uff0c\u81ea\u7531\u7535\u5b50\u96c6\u4e2d\u5728Li\u539f\u5b50\u5468\u56f4\uff0cAu\u539f\u5b50\u5468\u56f4\u7684ELF\u503c\u4f4e\u81f30.2\uff0c\u5bf9Li<sup>+<\/sup>\u7684\u8c03\u8282\u4f5c\u7528\u8f83\u5f31\u3002\u8fd9\u4e00\u7ed3\u679c\u8868\u660e\uff0c\u5728LiBi\u548cLiAl\u8868\u9762\u4e0a\u6c89\u79ef\u7684Li\u53ef\u4ee5\u5b9e\u73b0\u201c\u81ea\u5e73\u6ed1\u6548\u5e94\u201d\u3002\u6b64\u5916\uff0c\u5728\u5f62\u6210Li\u7c07\u540e\uff0cLiBi\u4e2d\u7684\u5c40\u57df\u7535\u5b50\u4ecd\u7136\u5747\u5300\u5206\u5e03\u5728Bi\u539f\u5b50\u5468\u56f4\uff0c\u4f46\u7535\u5b50\u4f3c\u4e4e\u5728LiAl\u4e2d\u5f62\u6210\u4e0d\u5229\u7684\u504f\u6790\uff0c\u8868\u660eLiBi\u5408\u91d1\u66f4\u6709\u5229\u4e8e\u9502\u7c07\u7684\u5438\u9644\u548c\u5206\u89e3\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-233081 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72472-4.png\" alt=\"\" width=\"793\" height=\"677\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72472-4.png 793w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72472-4-300x256.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72472-4-768x656.png 768w\" sizes=\"(max-width: 793px) 100vw, 793px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe1<\/strong> \u00a0\u9502\u5408\u91d1\u76f8\u95f4\u7535\u5316\u5b66\u6c89\u79ef\u9502\u81ea\u5e73\u6ed1\u884c\u4e3a\u7684\u7406\u8bba\u9884\u6d4b <span style=\"color: #999999;\">\u00a92022 The Authors<\/span><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><b><\/b><strong><b>\u8d85\u8584\u9502\u5408\u91d1\u5c42\u7684\u8bbe\u8ba1\u4e0e\u5236\u9020<\/b><\/strong><\/li>\n<\/ul>\n<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p>\u4e3a\u4e86\u7b80\u5355\u5730\u5c06\u9502\u5408\u91d1\u5f15\u5165\u9502\u8d1f\u6781\uff0c\u672c\u5de5\u4f5c\u5728\u5546\u7528\u94dc\u7b94\u8868\u9762\u6c89\u79ef\u8d85\u8584\u91d1\u5c5e\u819c\uff0c\u7136\u540e\u5728\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u4e0e\u9502\u53cd\u5e94\u539f\u4f4d\u5f62\u6210\u8d85\u8584\u5408\u91d1\u5c42\u3002\u4e0e\u5e38\u7528\u7684\u6d46\u6599\u6d82\u5e03\u6cd5\u548c\u771f\u7a7a\u8fc7\u6ee4\u6cd5\u76f8\u6bd4\uff0c\u78c1\u63a7\u6e85\u5c04\u6cd5\u53ef\u5b9e\u73b0\u5927\u89c4\u6a21\u751f\u4ea7\u5747\u5300\u8584\u819c\uff0c\u5177\u6709\u826f\u597d\u7684\u673a\u68b0\u7a33\u5b9a\u6027\uff0c\u53ef\u7528\u4e8e\u5c06Bi\u8584\u819c\u6c89\u79ef\u5230Cu\u7b94\u4e0a\uff0c\u5f97\u5230Bi\/Cu\u7b94\u3002\u78c1\u63a7\u6e85\u5c04\u540e\uff0cCu\u7b94\u7684\u7c97\u7cd9\u548c\u6709\u68f1\u7eb9\u7684\u8868\u9762\u88ab\u4e00\u5c42\u5747\u5300\u5206\u5e03\u7684\u7ec6\u9897\u7c92\u8986\u76d6\uff08<strong>\u56fe2a<\/strong>\uff09\u3002\u4eceX\u5c04\u7ebf\u884d\u5c04(XRD)\u56fe\u6848\u53ef\u4ee5\u786e\u8ba4\uff0cBi\/Cu\u7b94\u4e2d\u7684\u7ec6\u9897\u7c92\u662f\u7eaf\u94cb\uff0c\u6ca1\u6709\u6c27\u5316\u94cb\u3002\u8fd9\u5f52\u56e0\u4e8e\u78c1\u63a7\u6e85\u5c04\u7684\u9ad8\u771f\u7a7a\u548c\u94cb\u7684\u5f3a\u6297\u6c27\u5316\u6d3b\u6027\u3002\u8fd9\u4e5f\u610f\u5473\u7740\u5728\u751f\u4ea7\u8fc7\u7a0b\u4e2d\u5982\u679c\u5728Cu\u7b94\u4e0a\u6e85\u5c04Bi\uff0c\u96c6\u6d41\u4f53\u4e0d\u6613\u88ab\u6c27\u5316\uff0c\u8fd9\u6709\u5229\u4e8e\u7535\u6c60\u7684\u5bfc\u7535\u6027\u3002\u4ece\u9ad8\u89d2\u5ea6\u73af\u5f62\u6697\u573a(HAADF)\u56fe\u50cf\u548c\u76f8\u5e94\u7684\u5143\u7d20\u6620\u5c04\u53ef\u4ee5\u53d1\u73b0\uff0c\u539a\u5ea6\u7ea6\u4e3a300 nm\u7684\u5747\u5300\u81f4\u5bc6\u7684Bi\u8584\u819c\u7d27\u5bc6\u5730\u7c98\u9644\u5728\u94dc\u7b94\u8868\u9762\uff08<strong>\u56fe2b<\/strong>\uff09\u3002\u867d\u7136\u6539\u6027\u5c42\u975e\u5e38\u8584\uff0c\u4f46\u94cb\u7684\u5c0f\u7c92\u5f84\u53ca\u5176\u5bf9\u94dc\u7b94\u7c97\u7cd9\u8868\u9762\u7684\u7d27\u5bc6\u7c98\u9644\u53ef\u4ee5\u589e\u5f3a\u94dc\u7b94\u7684\u673a\u68b0\u53d8\u5f62\u6027\u80fd\uff0c\u5982\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\u6240\u793a\uff08<strong>\u56fe2c<\/strong>\uff09\u3002Bi\/Cu\u7b94\u7684\u6781\u9650\u5f3a\u5ea6\u548c\u5f39\u6027\u6a21\u91cf\u5206\u522b\u4e3a406 MPa\u548c62 GPa\uff0c\u5927\u4e8eCu\u7b94\uff0c\u8868\u660eBi\/Cu\u96c6\u6d41\u4f53\u66f4\u9002\u5408\u5de5\u4e1a\u8fd0\u8f93\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-233082 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72473-4.png\" alt=\"\" width=\"797\" height=\"617\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72473-4.png 797w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72473-4-300x232.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72473-4-768x595.png 768w\" sizes=\"(max-width: 797px) 100vw, 797px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2<\/strong> \u00a0\u8d85\u8584\u9502\u5408\u91d1\u5c42\u7684\u8bbe\u8ba1\u4e0e\u5236\u9020\u00a0<span style=\"color: #999999;\">\u00a92022 The Authors<\/span><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><b><\/b><strong><b>\u53d7\u7535\u5b50\u5b9a\u4f4d\u8c03\u8282<\/b><\/strong><strong><b>\u7684<\/b><\/strong><strong><b>\u9502\u6210\u957f<\/b><\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p>\u57fa\u4e8e\u4e0a\u8ff0\u8868\u5f81\u7ed3\u679c\u7684\u786e\u5b9a\uff0c\u672c\u5de5\u4f5c\u4f7f\u7528Bi\/Cu\u7b94\u901a\u8fc7SEM\u548c\u539f\u4f4d\u5149\u5b66\u663e\u5fae\u955c\u9a8c\u8bc1\u4e86\u7535\u5b50\u5b9a\u4f4d\u5bf9\u9502\u6c89\u79ef\u884c\u4e3a\u7684\u5f71\u54cd\u3002\u4f7f\u7528\u94dc\u7b94\u4f5c\u4e3a\u96c6\u6d41\u4f53\uff0c\u6c89\u79ef\u7684\u9502\u6709\u8bb8\u591a\u88c2\u7eb9\u548c\u7c97\u7cd9\u7684\u8868\u9762\u3002\u9502\u542b\u91cf\u589e\u52a0\u4f1a\u5e26\u6765\u5927\u91cf\u679d\u6676\u9502\u3001\u591a\u5b54\u9502\u548c\u6b7b\u9502\uff0c\u8fd9\u662f\u7531\u4e8e\u9502\u6c89\u79ef\u4e0d\u5747\u5300\u9020\u6210\u7684\u3002\u4e0e\u6b64\u5f62\u6210\u9c9c\u660e\u5bf9\u6bd4\u7684\u662f\uff0c\u6c89\u79ef\u5728Bi\/Cu\u96c6\u6d41\u4f53\u4e0a\u7684Li\u7684\u8868\u9762\u5f62\u6001\u66f4\u52a0\u5e73\u5766\u548c\u81f4\u5bc6\u3002\u5373\u4f7f\u5728\u7535\u9540\u4e864 mAh cm<sup>-2<\/sup>\u7684\u5bb9\u91cf\u540e\uff0c\u8868\u9762\u4ecd\u7136\u975e\u5e38\u5149\u6ed1\uff0c\u6ca1\u6709\u51fa\u73b0\u591a\u5b54\u6216\u679d\u6676\u9502\uff08<strong>\u56fe3c<\/strong>\uff09\u3002\u4ece\u6a2a\u622a\u9762\u56fe\uff08<strong>\u56fe 3d<\/strong>\uff09\u53ef\u4ee5\u770b\u51fa\uff0c\u95404 mAh cm<sup>-2<\/sup>\u540e\uff0cBi\/Cu\u7b94\u4e0a\u6c89\u79ef\u7684\u9502\u539a\u5ea6\u7ea6\u4e3a24 \u00b5m\uff0c\u63a5\u8fd1\u542b4 mA h cm<sup>-2<\/sup>(20 \u00b5m)\uff0c<strong><b>\u8fdb\u4e00\u6b65\u8868\u660e\u5728\u521d\u59cb\u5faa\u73af\u4e2d\u5f62\u6210\u7684Li<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>Bi\u5c42\u53ef\u4ee5\u6709\u6548\u5730\u8bf1\u5bfc\u9502\u6c89\u79ef\u5e76\u5bfc\u81f4\u6c89\u79ef\u7684\u9502\u975e\u5e38\u81f4\u5bc6\uff0c\u6ca1\u6709\u6b7b\u9502\u6216\u679d\u6676\u9502<\/b><\/strong>\u3002\u56e0\u6b64\uff0cBi\/Cu\u96c6\u6d41\u4f53\u80fd\u591f\u5ef6\u957f\u7535\u6c60\u7684\u4f7f\u7528\u5bff\u547d\uff0c\u5373\u4f7f\u5728\u9ad8\u5bb9\u91cf\u7684\u60c5\u51b5\u4e0b\u4e5f\u662f\u5982\u6b64\u3002\u672c\u5de5\u4f5c\u8fdb\u4e00\u6b65\u901a\u8fc7\u539f\u4f4d\u5149\u5b66\u663e\u5fae\u955c\u6765\u8868\u5f81Li\u7684\u6c89\u79ef\u8fc7\u7a0b\u5e76\u786e\u8ba4Bi\/Cu\u96c6\u6d41\u4f53\u7684\u7a33\u5b9a\u6027\u3002\u5bf9\u4e8e\u88f8\u94dc\u7b94\uff0c\u968f\u7740\u9540\u8986\u65f6\u95f4\u7684\u5ef6\u957f\uff0c\u8868\u9762\u4f1a\u51fa\u73b0\u7070\u8272\u6c89\u79ef\u7684\u91d1\u5c5e\u9502\u9897\u7c92\uff0c\u88f8\u94dc\u7b94\u8868\u9762\u9010\u6e10\u88ab\u9488\u72b6\u9502\u679d\u6676\u8986\u76d6\uff0c\u663e\u793a\u51fa\u9502\u79bb\u5b50\u5206\u5e03\u4e0d\u5747\u5300\uff0c\u9502\u91d1\u5c5e\u65e0\u5e8f\u751f\u957f \u5728\u5546\u4e1a\u94dc\u7b94\u4e0a\uff08<strong>\u56fe3e<\/strong>\uff09\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cBi\/Cu\u7535\u6781\u5bf9\u91d1\u5c5e\u9502\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u3002\u867d\u7136\u7535\u9540\u65f6\u95f4\u6301\u7eed\u4e862\u5c0f\u65f6\uff0c\u4f46\u4e0e\u521d\u59cb\u72b6\u6001\u76f8\u6bd4\uff0cBi\/Cu\u7b94\u8868\u9762\u6ca1\u6709\u51fa\u73b0\u7070\u8272\u9502\u679d\u6676\uff08<strong>\u56fe3f<\/strong>\uff09\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u5728\u5b9e\u9a8c\u4e2d\uff0c\u9502\u5728\u9502\u5408\u91d1\u5c42\u7684\u81ea\u5e73\u6ed1\u884c\u4e3a\u5bf9\u4e8e\u4fc3\u8fdb\u9502\u79bb\u5b50\u7684\u5747\u5300\u548c\u81f4\u5bc6\u6c89\u79ef\u975e\u5e38\u6709\u6548\u3002 \u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u5f53\u66f4\u591a\u7684\u9502\u7c07\u6c89\u79ef\u5728Li<sub>3<\/sub>Bi\u76f8\u4e0a\u65f6\uff08<strong>\u56fe3g<\/strong>\uff09\uff0c\u9502\u7c07\u4ecd\u4f1a\u4e0d\u65ad\u5206\u89e3\u5e76\u8868\u73b0\u51fa\u81ea\u5e73\u6ed1\u884c\u4e3a\u3002\u4ece\u76f8\u5e94\u7684ELF\u6765\u770b\uff0c\u901a\u8fc7\u7b2c\u4e8c\u6b21Li\u7c07\u7535\u9540\uff0c\u5c40\u57df\u7535\u5b50\u4ecd\u7136\u96c6\u4e2d\u5728Bi\u539f\u5b50\u5468\u56f4\uff0c\u901a\u8fc7\u6709\u6548\u7684\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u6765\u8c03\u8282\u6c89\u79ef\u884c\u4e3a\uff08<strong>\u56fe3h<\/strong>\uff09\u3002\u901a\u8fc7\u8fde\u7eed\u7535\u9540Li\u7c07\uff08<strong>\u56fe3i<\/strong>\uff09\uff0c\u4ece\u4e0a\u5f80\u4e0b\u770b\uff0c\u8868\u9762\u5c40\u57df\u7535\u5b50\u5206\u5e03\u5e7f\u6cdb\uff0cBi\u539f\u5b50\u5468\u56f4\u7684ELF\u503c\u7565\u4f4e\u3002<strong><b>\u4f46\u4ece\u6a2a\u622a\u9762\u6765\u770b\uff0c<\/b><\/strong><strong><b>\u672c\u5de5\u4f5c<\/b><\/strong><strong><b>\u60ca\u5947\u5730\u53d1\u73b0\u6709\u4e00\u4e2a\u975e\u5e38\u5f3a\u7684\u5c40\u57df\u7535\u5b50\u5438\u9644\u9502\u539f\u5b50\u7684\u533a\u57df\uff0c\u800c\u4e14\u8fd9\u4e2a\u533a\u57df\u662f\u56db\u4e2a\u9502\u539f\u5b50\u5f62\u6210\u7684\u7a7a\u9699\uff0c\u8fd9\u53ef\u4ee5\u89e3\u91ca\u4e3a\u4ec0\u4e48\u91d1\u5c5e\u9502\u6c89\u79ef\u5728Bi\/Cu\u7b94\u4e0a<\/b><\/strong><strong><b>\u4f1a<\/b><\/strong><strong><b>\u975e\u5e38\u5e73\u5766\u548c\u5bc6\u96c6<\/b><\/strong>\u3002\u8fd9\u79cd\u6df1\u5ea6\u8ba1\u7b97\u6709\u529b\u5730\u5339\u914d\u4e86\u5177\u6709\u4e0d\u540c\u5bb9\u91cf\u7684\u5747\u5300\u9502\u6c89\u79ef\u7684\u5b9e\u9a8c\u7ed3\u679c\uff08<strong>\u56fe3c\u3001d\u3001f<\/strong>\uff09\u3002<strong><b>\u6b64\u5916\uff0c\u8fd9\u610f\u5473\u7740\u9502\u5408\u91d1\u5c42\u4e0d\u4ec5\u53ef\u4ee5\u5728\u521d\u59cb\u9636\u6bb5\u8bf1\u5bfc\u9502\u6c89\u79ef\uff0c\u800c\u4e14\u53ef\u4ee5\u5728\u6574\u4e2a\u7535\u9540\u8fc7\u7a0b\u4e2d\u5b9e\u73b0\u9502\u79bb\u5b50\u7684\u53ef\u6301\u7eed\u5747\u5300\u5206\u5e03<\/b><\/strong>\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-233083 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72474-4.png\" alt=\"\" width=\"795\" height=\"767\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72474-4.png 795w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72474-4-300x289.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/02\/\u56fe\u72474-4-768x741.png 768w\" sizes=\"(max-width: 795px) 100vw, 795px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe3<\/strong> \u00a0\u9502\u6210\u957f\u53d7\u7535\u5b50\u5b9a\u4f4d\u7684\u8c03\u8282\u00a0<span style=\"color: #999999;\">\u00a92022 The Authors<\/span><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><b><\/b><strong><b>\u534a\u7535\u6c60<\/b><\/strong><strong><b>\u548c\u5168\u7535\u6c60<\/b><\/strong><strong><b>\u7684\u7535\u5316\u5b66\u8868\u5f81<\/b><\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p>\u57fa\u4e8e\u4e0a\u8ff0\u5bf9\u9502\u5408\u91d1\u5c42\u7535\u5b50\u5c40\u57df\u5316\u5bf9Li<sup>+<\/sup>\u5747\u5300\u6c89\u79ef\u7684\u5f71\u54cd\u7684\u9884\u6d4b\uff0c\u5e76\u4e14\u7531\u4e8e\u9996\u6548(CE)\u5bf9\u4e8e\u4fdd\u6301\u7535\u6c60\u7684\u957f\u5faa\u73af\u5bff\u547d\u81f3\u5173\u91cd\u8981\uff0c\u672c\u5de5\u4f5c\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u901a\u8fc7\u4e0d\u5bf9\u79f0\u534a\u7535\u6c60\u7684Li\u6c89\u79ef\u6548\u7387\u3002 \u56fe4a-c\u6bd4\u8f83\u4e86\u4e0d\u540c\u7535\u6781\uff08Cu\u3001Bi\/Cu\u3001Al\/Cu\u548cAu\/Cu\uff09\u57281 mA cm<sup>-2<\/sup>\u7684\u56fa\u5b9a\u7535\u6d41\u5bc6\u5ea6\u548c\u4e0d\u540c\u5bb9\u91cf\u4e0b\u7684CE\u3002\u663e\u7136\uff0c\u6240\u6709\u5177\u6709\u9502\u5408\u91d1\u5c42\u7684\u96c6\u7535\u5668\u5728\u4e0d\u540c\u5bb9\u91cf\u4e0b\u90fd\u8868\u73b0\u51fa\u66f4\u957f\u7684\u5faa\u73af\u5bff\u547d\u3002\u4ece30\u6b21\u7535\u9540\/\u5265\u79bb\u5faa\u73af\uff081 \u548c 4 mAh cm<sup>&#8211;<\/sup><sup>2<\/sup>\uff09\u540e\u6c89\u79ef\u9502\u7684FESEM\u56fe\u50cf\u53ef\u4ee5\u770b\u51fa\uff0c<strong><b>\u88f8\u94dc\u7b94\u4e0a\u6c89\u79ef\u7684\u9502\u88ab\u9502\u679d\u6676\u548c\u6b7b\u9502\u5360\u636e\uff08\u56fe 4e\uff09\uff0c\u539a\u5ea6\u9ad8\u8fbe78 \u00b5m\uff08\u56fe 4f\uff09\uff0c\u8fdc\u8fdc\u8d85\u8fc74 mAh cm<\/b><\/strong><strong><sup><b>&#8211;<\/b><\/sup><\/strong><strong><sup><b>2<\/b><\/sup><\/strong><strong><b>\u7684\u9502\u7b94<\/b><\/strong>\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u7531\u4e8e\u9502\u5728\u5408\u91d1\u5c42\u4e0a\u7684\u81ea\u5e73\u6ed1\u884c\u4e3a\u53ca\u5176\u9ad8SWF\uff0c\u6c89\u79ef\u5728Bi\/Cu\u7b94\u4e0a\u7684\u9502\u4ecd\u7136\u5149\u6ed1\u81f4\u5bc6\uff08\u56fe4g\uff0ch\uff09\uff0c\u539a\u5ea6\u4ec5\u4e3a25 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