{"id":233087,"date":"2022-02-14T06:45:09","date_gmt":"2022-02-13T22:45:09","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=233087"},"modified":"2022-02-13T12:45:25","modified_gmt":"2022-02-13T04:45:25","slug":"%e7%8e%8b%e6%98%a5%e7%94%9f%e5%9b%a2%e9%98%9f-%e6%9c%80%e6%96%b0nature-energy%ef%bc%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=233087","title":{"rendered":"\u738b\u6625\u751f\u56e2\u961f \u6700\u65b0Nature Energy\uff01"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u76d0\u5305\u6eb6\u5242\u7535\u89e3\u8d28\uff08\u2018solvent-in-salt\u2019 electrolytes\uff09\u7684\u6700\u65b0\u6982\u5ff5\uff0c\u5373\u7528\u4e8e\u6c34\u7cfb\u7535\u6c60\u7684\u76d0\u5305\u6c34\u7535\u89e3\u8d28\uff08\u2018water-in-salt\u2019 electrolytes, WISE\uff09\u548c\u7528\u4e8e\u975e\u6c34\u7cfb\u7535\u6c60\u7684\u8d85\u9ad8\u6d53\u7535\u89e3\u8d28\uff08\u2018super-concentrated\u2019 electrolytes\uff09\uff0c\u6781\u5927\u5730\u6269\u5c55\u4e86\u8fd9\u4e9b\u7535\u6c60\u7cfb\u7edf\u7684\u7535\u5316\u5b66\u7a97\u53e3\uff0c\u8fdb\u800c\u6269\u5927\u4e86\u5b83\u4eec\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u5bf9\u4e8e\u6c34\u7cfb\u7535\u89e3\u8d28\uff0c\u901a\u8fc7\u5c06\u6c34\u5408\u7269\u7194\u76d0\u7535\u89e3\u8d28\u4e2d\u7684\u76d0\u6d53\u5ea6\u63d0\u9ad8\u523027.7 m\uff08mol kgsolvent<\/sub>-1<\/sup>\uff09\u6765\u51cf\u5c11Li\u79bb\u5b50\u6eb6\u5242\u5316\u9798\u4e2d\u7684H2<\/sub>O\u5206\u5b50\uff0cWISE\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3\u4e5f\u5f97\u5230\u4e86\u6269\u5c55\uff0c\u5728\u542b\u6dfb\u52a0\u5242\u7684\u53cc\u76d0\u5305\u6c34\u7535\u89e3\u8d28\u4e2d\u4e3a28 m\uff0c\u5728\u6df7\u5408\u9633\u79bb\u5b50\u7535\u89e3\u8d28\u4e2d\u4e3a40 m\uff0c\u5728\u9502\u76d0\u6c34\u5408\u7269\u4e2d\u4e3a55.5 m\uff0c\u5728\u79bb\u5b50\u6db2\u4f53WISE\u4e2d\u4e3a63 m\u3002\u7136\u800c\uff0c\u5373\u4f7f\u76d0\u6d53\u5ea6\u8fbe\u523063 m\uff0cWISE\u7684\u9634\u6781\u7535\u4f4d\u4ec5\u6269\u5c55\u81f31.75 V\uff0c\u6574\u4f53\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3<3.25 V\u3002\u5982\u679c\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\uff08solid-electrolyte interphase, SEI\uff09\u4e0d\u591f\u7a33\u5b9a\u4ee5\u4f7f\u6c34\u4eceLi\u79bb\u5b50\u4e2d\u53bb\u6eb6\u5242\u5316\uff0c\u5219Li\u79bb\u5b50\u6eb6\u5242\u5316\u7684\u6c34\u5c06\u88ab\u8fd8\u539f\uff0c\u5e76\u4e14\u5f62\u6210\u7684SEI\u5c06\u88ab\u6d17\u6389\u3002\u6216\u8005\uff0c\u6dfb\u52a0\u80fd\u591f\u6eb6\u89e3\u5927\u91cf\u76d0\u548c\u6eb6\u5242\u7684\u6709\u673a\u6eb6\u5242\u6216\u51dd\u80f6\u805a\u5408\u7269\u662f\u51cf\u5c11WISE\u4e2d\u6c34\u91cf\u7684\u7b80\u5355\u7b56\u7565\uff0c\u4f46\u8fd9\u4e9b\u6709\u673a\u6eb6\u5242-\u51dd\u80f6\u805a\u5408\u7269\uff08organic solvents-gel polymers\uff09\u6613\u71c3\uff0c\u635f\u5bb3\u4e86\u6c34\u7cfb\u7535\u89e3\u8d28\u7684\u5b89\u5168\u6027\u3002<\/p>\n

\u76ee\u524d\uff0c\u7531\u4e8eLi\u76d0\u6c89\u6dc0\/\u6eb6\u89e3\u5e73\u8861\u7684\u9650\u5236\uff0c\u4f3c\u4e4e\u4e0d\u53ef\u80fd\u901a\u8fc7\u8d85\u9ad8\u6d53\u7535\u89e3\u6db2\u7684\u7b56\u7565\u8fdb\u4e00\u6b65\u51cf\u5c11Li\u79bb\u5b50\u6eb6\u5242\u5316\u9798\u5185\u7684H2O\u5206\u5b50\u3002\u4e3a\u4e86\u8bbe\u8ba1\u4e0b\u4e00\u4ee3\u6c34\u7cfb\u7535\u89e3\u8d28\uff0c\u5373\u5177\u6709\u66f4\u5bbd\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3\u548c\u66f4\u4f4e\u6210\u672c\u4f46\u4ecd\u4fdd\u6301\u4e0d\u53ef\u71c3\u6027\u4f18\u70b9\u7684\u7535\u89e3\u8d28\uff0c\u7a00\u91ca\u6c34\u7cfb\u7535\u89e3\u8d28\u5fc5\u987b\u6ee1\u8db3\u4ee5\u4e0b\u4e09\u4e2a\u6807\u51c6\uff1a\uff081\uff09\u9502\u76d0\u548c\u7a00\u91ca\u5242\u90fd\u5fc5\u987b\u80fd\u591f\u5f62\u6210\u7a33\u5b9a\u7684SEI\uff0c\u4ee5\u4fbfLi4<\/sub>Ti5<\/sub>O12<\/sub>\u8d1f\u6781\u7684\u6b63\u6781\u6781\u9650\u7535\u4f4d\u53ef\u4ee5\u964d\u4f4e\u5230<1.5 V\uff1b\uff082\uff09\u7a00\u91ca\u5242\u5fc5\u987b\u80fd\u591f\u4e0e\u76d0\u548cH2<\/sub>O\u5f62\u6210\u4e09\u5143\u5171\u6676\uff0c\u4ee5\u540c\u65f6\u5b9e\u73b0>10-3<\/sup> S cm-1<\/sup>\u7684\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u4f4e\u7c98\u5ea6\uff1b\uff083\uff09\u7a00\u91ca\u5242\u5fc5\u987b\u4fbf\u5b9c\u4e14\u4e0d\u6613\u71c3\u3002
\n \"\"<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u57282022\u5e742\u67087\u65e5\uff0c\u7f8e\u56fd\u9a6c\u91cc\u5170\u5927\u5b66\u738b\u6625\u751f\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u901a\u8fc7\u4f7f\u7528\u5c3f\u7d20\uff08CO(NH2<\/sub>)2<\/sub>\uff09\u4f5c\u4e3a\u7a00\u91ca\u5242\u4e3a\u4f8b\uff0c\u5236\u5907\u4e86\u4e00\u79cd\u6ee1\u8db3\u4ee5\u4e0a\u4e09\u4e2a\u6807\u51c6\u7684\u4e0d\u53ef\u71c3\u4e09\u5143\u5171\u6676\u7535\u89e3\u8d28\uff0c\u53734.5 m LiTFSI-KOH-CO(NH2<\/sub>)2<\/sub>-H2<\/sub>O\u4e0d\u53ef\u71c3\u4e09\u5143\u5171\u6676\u7535\u89e3\u8d28\u3002\u8be5\u6c34\u7cfb\u7535\u89e3\u8d28\u5c06\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3\u6269\u5927\u52303.3 V\uff0c\u8d1f\u6781\u6781\u9650\u7535\u4f4d\u4e3a1.5 V\uff0c\u5176\u4e2dCO(NH2<\/sub>)2<\/sub>\u8fdb\u4e00\u6b65\u964d\u4f4e\u4e86Li+<\/sup>\u6eb6\u5242\u5316\u58f3\u4e2d\u7684H2<\/sub>O\u5206\u5b50\u6570\u91cf\uff0c\u5373\u4eceWISE\u4e2d\u76842.6\u51cf\u5c11\u52300.7\uff0c\u5e76\u4e14\u5728KOH\u50ac\u5316\u5242\u4e0bLiTFSI\u548cCO(NH2<\/sub>)2<\/sub>\u7684\u8fd8\u539f\u5f62\u6210\u4e86\u7a33\u5b9a\u7684LiF\/\u805a\u5408\u7269\u53cc\u5c42SEI\u3002\u5177\u67093 g Ah-1<\/sup>\u76844.5 m LiTFSI-KOH-CO(NH2<\/sub>)2<\/sub>-H2<\/sub>O\u8d2b\u6c34\u7cfb\u7535\u89e3\u8d28\uff0c\u6b63\/\u8d1f\uff08P\/N\uff09\u6781\u5bb9\u91cf\u6bd4\u4e3a1.14\u548c\u9762\u5bb9\u91cf\u4e3a2.5 mAh cm-2<\/sup>\u7684Li1.5<\/sub>Mn2<\/sub>O4<\/sub>||Li4<\/sub>Ti5<\/sub>O12<\/sub>\u8f6f\u5305\u7535\u6c60\uff0c\u5728\u8fdb\u884c470\u6b21\u5145\u7535\/\u653e\u7535\u5faa\u73af\u540e\u4ecd\u7136\u4fdd\u630192%\u7684\u521d\u59cb\u5bb9\u91cf\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0cSEI\u5f62\u6210\u8fc7\u7a0b\u4e2d\u7684Li\u635f\u5931\u7531Li1.5<\/sub>Mn2<\/sub>O4<\/sub>\u4e2d\u989d\u5916\u76840.5 Li\u8865\u507f\uff0c\u5728SEI\u5f62\u6210\u540e\uff0c\u5c06Li1.5<\/sub>Mn2<\/sub>O4<\/sub>||Li4<\/sub>Ti5<\/sub>O12<\/sub>\u7535\u6c60\u8f6c\u5316\u6210\u4f20\u7edf\u7684LiMn2<\/sub>O4<\/sub>||Li4<\/sub>Ti5<\/sub>O12<\/sub>\uff0c\u5e76\u5728\u4e0d\u635f\u5bb3\u7535\u6c60\u80fd\u91cf\u5bc6\u5ea6\u7684\u60c5\u51b5\u4e0b\u663e\u7740\u63d0\u9ad8\u4e86\u5faa\u73af\u5bff\u547d\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cAqueous electrolyte design for super-stable 2.5\u2009 V LiMn2<\/sub>O4<\/sub>\u2009||\u2009Li4<\/sub>Ti5<\/sub>O12<\/sub> pouch cells\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNature Energy<\/strong>\u4e0a\u3002<\/p>\n

\u672c\u6587\u6240\u6709\u56fe\u6765\u6e90\u4e8e\u00a92022 Springer Nature Limited<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u5206\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\u7684\u5149\u8c31\u5206\u6790<\/strong>
\n \"\"\uff08a-c\uff09CO(NH2<\/sub>)2<\/sub>\u3001H2<\/sub>O\u3001CO(NH2<\/sub>)2<\/sub>-H2<\/sub>O\u30014.1 m\u30014.5 m\u548c5.1 m\u7535\u89e3\u8d28\u7684\u62c9\u66fc\u5149\u8c31\u548cFTIR\u5149\u8c31\uff1b<\/p>\n

\uff08d\uff0917<\/sup>O NMR\u5728\u4e0d\u540c\u7535\u89e3\u8d28\u4e2d\u7684\u5316\u5b66\u4f4d\u79fb\uff1b<\/p>\n

\uff08e\uff09\u4e0e21 m WISE\u76f8\u6bd4\uff0c4.1 m\u30014.5 m\u548c5.1 m\u7535\u89e3\u8d28\u7684CO(NH2<\/sub>)2<\/sub>\u3001TFSI\u548cH2<\/sub>O\u5728Li+<\/sup>\u5468\u56f4\u7684\u914d\u4f4d\u6570\uff08\u57283.0 \u00c5\u4ee5\u5185\uff09\uff1b<\/p>\n

\uff08f\uff094.5 m\u7535\u89e3\u8d28\u4e2dLi+<\/sup>\u521d\u7ea7\u6eb6\u5242\u5316\u58f3\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u4e8c\u3001\u6c34\u7cfb\u7535\u89e3\u8d28\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3<\/strong>
\n \"\"\uff08a\uff09\u5177\u6709\u4e0d\u540cLiTFSI\u6d53\u5ea6\u7684\u7535\u89e3\u8d28\u7684\u6574\u4f53\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3\uff0c\u4ee5\u53ca\u5728\u96c6\u6d41\u4f53\u4e0a\u8986\u76d6\u6709\u5faa\u73af\u4f0f\u5b89\u56fe\u7684\u7535\u6781\u7684\u6c27\u5316\u8fd8\u539f\u66f2\u7ebf\uff1b<\/p>\n

\uff08b-c\uff09\uff08a\uff09\u4e2d\u6b63\u6781\u548c\u8d1f\u6781\u6781\u7aef\u9644\u8fd1\u533a\u57df\u7684\u653e\u5927\u56fe\uff1b<\/p>\n

\uff08d\uff09\u901a\u8fc7\u91cf\u5b50\u5316\u5b66\u8ba1\u7b97\u9884\u6d4b\u7684\u8fd8\u539f\u7535\u4f4d\uff08\u7535\u538bvs. Li\/Li+<\/sup>\uff09\u3002<\/p>\n

\u56fe\u4e09\u3001SEI\u5c42\u7684\u7ed3\u6784\u548c\u5316\u5b66\u5206\u6790<\/strong>
\n \"\"\uff08a-d\uff09C 1s\u3001N 1s\u3001O 1s\u548cF 1s\u7684XPS\u7ed3\u679c\uff1b<\/p>\n

\uff08e\uff09\u4f7f\u75282\u00d72 \u03bcm2<\/sup>\u5149\u6805\u8fdb\u884c\u98de\u884c\u65f6\u95f4\u4e8c\u6b21\u79bb\u5b50\u8d28\u8c31\u5206\u6790\u542b\u67094.5 m\u7535\u89e3\u8d28\u7684Li4<\/sub>Ti5<\/sub>O12<\/sub>\u9897\u7c92\u5faa\u73af\u540e\u7684\u8868\u9762\u5f62\u8c8c\uff1b<\/p>\n

\uff08f\uff09\u5728\u5faa\u73af\u7684Li4<\/sub>Ti5<\/sub>O12<\/sub>\u9897\u7c92\u4e0aO–<\/sup>\u3001F–<\/sup>\u548cCN–<\/sup>\u4e8c\u6b21\u79bb\u5b50\u7684\u98de\u884c\u65f6\u95f4\u4e8c\u6b21\u79bb\u5b50\u8d28\u8c31\u6df1\u5ea6\u5206\u5e03\uff1b<\/p>\n

\uff08g\uff09\u8986\u76d6\u6709LiF\/\u805a\u5408\u7269\u53cc\u5c42SEI\u7684\u5faa\u73afLi4<\/sub>Ti5<\/sub>O12<\/sub>\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

\uff08h\uff09\u65e0\u673a\/\u6709\u673a\u6df7\u5408SEI\u7684\u5f62\u6210\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u56db\u30012.5 V LiMn2<\/sub>O4<\/sub>||Li4<\/sub>Ti5<\/sub>O12<\/sub>\u548c2.6 V LiVPO4<\/sub>F||Li4<\/sub>Ti5<\/sub>O12<\/sub>\u5168\u7535\u6c60\u5728\u9762\u5bb9\u91cf\u4e3a1.5 mAh cm-2<\/sup>\u4e0b\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong>
\n \"\"\uff08a-b\uff09\u5728\u4e0d\u540c\u7684\u6c34\u7cfb\u7535\u89e3\u8d28\u4e2d\uff0cP\/N=1.14\u7684LiMn2<\/sub>O4<\/sub>||Li4<\/sub>Ti5<\/sub>O12<\/sub>\u5168\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u548c\u5e93\u4ed1\u6548\u7387\uff1b<\/p>\n

\uff08c-d\uff09\u57284.5 m\u7535\u89e3\u8d28\u30010.5 C\u4e0b\uff0cLiMn2<\/sub>O4<\/sub>||Li4<\/sub>Ti5<\/sub>O12<\/sub>\u5168\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n

\uff08e-f\uff09\u57284.5 m\u7535\u89e3\u8d28\u30010.5 C\u4e0b\uff0cLiVPO4<\/sub>F||Li4<\/sub>Ti5<\/sub>O12<\/sub>\u5168\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e94\u30012.5 V LiMn2<\/sub>O4<\/sub>||Li4<\/sub>Ti5<\/sub>O12<\/sub>\u8f6f\u5305\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong>
\n \"\"\uff08a-b\uff09\u57284.5 m\u7535\u89e3\u8d28\u3001\u9762\u5bb9\u91cf\u4e3a1.5 mAh cm-2<\/sup>\u548c2.5 mAh cm-2<\/sup>\u4ee5\u53ca1 C\u4e0b\uff0cLiMn2<\/sub>O4<\/sub>||Li4<\/sub>Ti5<\/sub>O12<\/sub>\u8f6f\u5305\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\uff08c\uff09\u57284.5 m\u7535\u89e3\u8d28\u3001\u9762\u5bb9\u91cf\u4e3a2.5 mAh cm-2<\/sup>\u548c1 C\u4e0b\uff0cLi1.5<\/sub>Mn2<\/sub>O4<\/sub>||Li4<\/sub>Ti5<\/sub>O12<\/sub>\u8f6f\u5305\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\uff08d\uff09\u6bd4\u8f83\u4e0d\u540c\u76d0\u6d53\u5ea6\u7684\u4f20\u7edf\u6c34\u7cfb\u7535\u89e3\u8d28\u7684\u7535\u89e3\u8d28\u7a33\u5b9a\u6027\u7a97\u53e3\uff1b<\/p>\n

\uff08e\uff09\u6bd4\u8f834.5 m\u7535\u89e3\u8d28\u57fa\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u4e0e\u5176\u4ed6\u5546\u7528\u6c34\u7cfb\u7535\u5316\u5b66\u50a8\u80fd\u6280\u672f\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u5f00\u53d1\u4e86\u4e00\u79cd4.5m LiTFSI-KOH-CO(NH2<\/sub>)2<\/sub>-H2<\/sub>O\u4e0d\u53ef\u71c3\u4e09\u5143\u5171\u6676\u7535\u89e3\u8d28\uff0c\u5176\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3\u4e3a3.3 V\u3002\u901a\u8fc7\u6dfb\u52a0\u4e0d\u53ef\u71c3\u7684CO(NH2<\/sub>)2<\/sub>\u6765\u53d6\u4ee3LiTFSI\uff0c\u5e76\u8fdb\u4e00\u6b65\u5c06Li+<\/sup>\u6eb6\u5242\u5316\u58f3\u4e2d\u7684H2<\/sub>O\u5206\u5b50\u6570\u91cf\u4ece2.6\u51cf\u5c11\u52300.7\u6765\u5b9e\u73b0\u3002\u4e0eLiTFSI\u76d0\u4e00\u6837\uff0c\u5171\u6676CO(NH2<\/sub>)2<\/sub>\u7a00\u91ca\u5242\u5206\u5b50\u5f62\u6210\u5f3a\u70c8\u7684CO(NH2<\/sub>)2<\/sub>\u00b7H2<\/sub>O\u76f8\u4e92\u4f5c\u7528\uff0c\u5fae\u5999\u5730\u53d6\u4ee3\u4e86Li+<\/sup>\u6eb6\u5242\u5316\u58f3\u4e2d\u7684H2<\/sub>O\u5206\u5b50\u4f4d\u7f6e\uff0c\u5e76\u6709\u52a9\u4e8e\u5f62\u6210\u7531\u6709\u673a\u5916\u5c42\u548c\u5bcc\u542bLiF\u7684\u5185\u5c42\u7ec4\u6210\u7684\u7a33\u5b9aSEI\u30024.5 m LiTFSI-KOH-CO(NH2<\/sub>)2<\/sub>-H2<\/sub>O\u4e0d\u53ef\u71c3\u4e09\u5143\u5171\u6676\u7535\u89e3\u8d28\u4f7fLiMn2<\/sub>O4<\/sub>||Li4<\/sub>Ti5<\/sub>O12<\/sub>\u8f6f\u5305\u7535\u6c60\u63a5\u8fd1\u5b9e\u9645\u5e94\u7528\u6761\u4ef6\uff0c\u5305\u62ec\u539a\u7535\u6781\uff082.5 mAh cm-2<\/sup>\uff09\u548c1.14\u7684\u4f4eP\/N\u5bb9\u91cf\u6bd4\u3002\u5728500\u6b21\u5faa\u73af\u4e2d\u83b7\u5f97\u4e86\u4f18\u5f02\u7684\u53ef\u9006\u6027\u548c72%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u5f15\u5165\u4e86\u5bcc\u9502Li1.5<\/sub>Mn2<\/sub>O4<\/sub>\u4f5c\u4e3aLi\u6e90\uff0c\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u91ca\u653e\u51faLi\u79bb\u5b50\u4ee5\u8865\u507f\u8d1f\u6781\u4e2d\u7684Li\u635f\u5931\uff0c\u4ece\u800c\u5c06\u81ea\u8eab\u8f6c\u5316\u4e3aLiMn2<\/sub>O4<\/sub>\u3002\u5728\u4e0d\u5f15\u5165\u975e\u6d3b\u6027\u6750\u6599\u7684\u60c5\u51b5\u4e0b\u63d0\u9ad8\u4e86\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u5728470\u6b21\u5faa\u73af\u540e\u4ecd\u670992%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\uff09\u3002\u8fd9\u79cd\u7535\u89e3\u8d28\u8bbe\u8ba1\u7b56\u7565\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u524d\u9014\u7684\u65b9\u6cd5\u6765\u6269\u5c55\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u5e76\u5c06\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u63a8\u5411\u9ad8\u5b89\u5168\u6027\u548c\u4f4e\u6210\u672c\u81f3\u5173\u91cd\u8981\u7684\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aAqueous electrolyte design for super-stable 2.5\u2009V LiMn2<\/sub>O4<\/sub>\u2009||\u2009Li4<\/sub>Ti5<\/sub>O12<\/sub> pouch cells<\/a><\/strong>. Nature Energy<\/em>, 2022<\/strong>, DOI: 10.1038\/s41560-021-00977-5.<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

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