{"id":235151,"date":"2022-03-30T06:08:31","date_gmt":"2022-03-29T22:08:31","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=235151"},"modified":"2022-03-29T15:10:10","modified_gmt":"2022-03-29T07:10:10","slug":"%e5%8d%97%e5%bc%80%e5%a4%a7%e5%ad%a6%e9%99%88%e5%86%9b%ef%bc%8c%e4%b8%a5%e6%8c%af%e5%8d%8e%e8%af%be%e9%a2%98%e7%bb%84%e5%8f%af%e5%85%85%e7%94%b5%e9%94%8c%e7%94%b5%e6%b1%a0%e6%9c%80%e6%96%b0nsr","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=235151","title":{"rendered":"\u5357\u5f00\u5927\u5b66\u9648\u519b\uff0c\u4e25\u632f\u534e\u8bfe\u9898\u7ec4\u53ef\u5145\u7535\u950c\u7535\u6c60\u6700\u65b0NSR"},"content":{"rendered":"<p style=\"text-align: left;\"><strong><b>\u89e3\u8bfb-N\uff0cN-\u4e8c\u7532\u57fa\u7532\u9170\u80fa\u8c03\u6574\u6eb6\u5242\u6548\u5e94\u4ee5\u63d0\u9ad8\u6c34\u7535\u89e3\u8d28\u4e2d\u950c\u8d1f\u6781\u7684\u53ef\u9006\u6027<\/b><\/strong><\/p>\n<p style=\"text-align: left;\"><strong><b>\u3010\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p>\u4e3a\u6ee1\u8db3\u5feb\u901f\u53d1\u5c55\u7684\u6d88\u8d39\u7535\u5b50\u5668\u4ef6\u3001\u7535\u52a8\u6c7d\u8f66\u548c\u5927\u89c4\u6a21\u50a8\u80fd\u7684\u5e94\u7528\u9700\u6c42\uff0c\u8feb\u5207\u9700\u8981\u5f00\u53d1\u5177\u6709\u9ad8\u5bb9\u91cf\u3001\u73af\u5883\u53cb\u597d\u548c\u6027\u4ef7\u6bd4\u7684\u65b0\u578b\u7535\u6c60\u3002\u5728\u6240\u6709\u53ef\u53ef\u4ee5\u7528\u7684\u50a8\u80fd\u5668\u4ef6\u4e2d\uff0c\u7406\u8bba\u5bb9\u91cf(820 mAh g<sup>-1<\/sup>)\u9ad8\u3001\u5b89\u5168\u6027\u9ad8\u3001\u6210\u672c\u4f4e\u7684\u53ef\u5145\u7535\u6c34\u7cfb\u950c\u7535\u6c60(RZBs)\u88ab\u8ba4\u4e3a\u662f\u5f88\u6709\u524d\u666f\u7684\u50a8\u80fd\u5019\u9009\u6750\u6599\u3002\u7136\u800c\uff0c\u5728\u666e\u901a\u6c34\u7535\u89e3\u8d28\u4e2d\u7684\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u548c\u679d\u6676\u950c\u7684\u751f\u957f\u4e25\u91cd\u9650\u5236\u4e86\u950c\u7535\u6c60\u7684\u5e94\u7528\u3002<\/p>\n<p style=\"text-align: left;\"><strong><b>\u3010\u6210\u679c\u63a0\u5f71\u3011<\/b><\/strong><\/p>\n<p>\u4e3a\u4e86\u89e3\u51b3\u4e0a\u8ff0\u6311\u6218\uff0c<strong><b>\u5357\u5f00\u5927\u5b66\u9648\u519b\uff0c\u4e25\u632f\u534e<\/b><\/strong><strong><b>\u8bfe\u9898\u7ec4\u5f00\u53d1\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u7b56\u7565\u6765\u6291\u5236\u526f\u53cd\u5e94\u5e76\u63d0\u9ad8\u950c\u7535\u6781\u7684\u53ef\u9006\u6027<\/b><\/strong><strong><b>\u3002<\/b><\/strong><strong><b>\u5177\u4f53\u6765\u8bf4\uff0c\u672c\u5de5\u4f5c<\/b><\/strong>\u901a\u8fc7\u57282 MZn(CF<sub>3<\/sub>SO<sub>3<\/sub>)<sub>2<\/sub>-H<sub>2<\/sub>O\u7535\u89e3\u6db2(ZHD30)\u4e2d\u5f15\u516530%(\u4f53\u79ef\u5206\u6570)N\uff0cN-\u4e8c\u7532\u57fa\u7532\u9170\u80fa(DMF)\uff0cDMF\u4e0eH<sub>2<\/sub>O\u4e4b\u95f4\u7684\u4f18\u5148\u6c22\u952e\u4f5c\u7528\u6709\u6548\u5730\u964d\u4f4e\u4e86\u7535\u89e3\u6db2\u7684\u6c34\u6d3b\u6027\uff0c\u963b\u788d\u4e86\u7535\u89e3\u6db2\u7684\u53bb\u8d28\u5b50\u5316\u3002ZHD30\u7535\u89e3\u6db2\u4f7f\u9540\u950c\/\u8131\u950c\u6548\u7387\u7531-95.3%\u63d0\u9ad8\u5230- 99.4%\uff0c\u5faa\u73af\u6b21\u6570\u753165\u6b21\u63d0\u9ad8\u5230300\u6b21\u3002\u91c7\u7528ZHD30\u7535\u89e3\u6db2\u7684Zn-\u805a\u82ef\u80fa\u5168\u7535\u6c60\u5728-40~+25\u2103\u8303\u56f4\u5185\u5de5\u4f5c\uff0c\u572825\u2103\u3001-20\u2103\u548c-40\u2103\u4e0b\u7684\u653e\u7535\u5bb9\u91cf\u5206\u522b\u4e3a161.6\u3001127.4\u548c65.8mAh g<sup>-1<\/sup>\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u8c03\u8282\u6eb6\u5242\u6548\u5e94\u5728\u8bbe\u8ba1\u4f4e\u6210\u672c\u548c\u6709\u6548\u7684\u6c34\u7cfb\u7535\u89e3\u8d28\u4e2d\u7684\u4f5c\u7528\u63d0\u4f9b\u4e86\u89c1\u89e3\u3002\u76f8\u5173\u8bba\u6587\u4ee5\u9898\u4e3a\uff1a\u201c<em><i>N, N\u2013dimethylformamide tailors solvent effect to boost Zn anode reversibility in aqueous electrolyte<\/i><\/em>\u201d\u53d1\u8868\u5728<em><i>Nat<\/i><\/em><em><i>ional<\/i><\/em><em><i>\u00a0Science Review<\/i><\/em>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235152\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u72471-6.png\" alt=\"\" width=\"579\" height=\"323\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u72471-6.png 579w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u72471-6-300x167.png 300w\" sizes=\"(max-width: 579px) 100vw, 579px\" \/><\/p>\n<p style=\"text-align: left;\"><strong><b>\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/b><\/strong><\/p>\n<ul>\n<li>\u672c\u5de5\u4f5c\u8bc1\u660eDMF\u5728\u6df7\u5408\u7535\u89e3\u8d28\u4e2d\u7684\u52a0\u5165\u4f18\u5148\u4e0eH<sub>2<\/sub>O\u5f62\u6210\u6c22\u952e\uff0c\u6210\u529f\u964d\u4f4e\u4e86\u7535\u89e3\u8d28\u7684\u6c34\u6d3b\u6027\uff0c\u6291\u5236\u4e86\u6c34\u7684\u53bb\u8d28\u5b50\u5316\u3002<\/li>\n<li>\u672c\u5de5\u4f5c\u5f00\u53d1\u7684ZHD30\u7535\u89e3\u6db2\u4f7f\u9540\u950c\/\u8131\u950c\u6548\u7387\u7531-95.3%\u63d0\u9ad8\u5230- 99.4%\uff0c\u5faa\u73af\u6b21\u6570\u753165\u6b21\u63d0\u9ad8\u5230300\u6b21\u3002<\/li>\n<li>\u672c\u5de5\u4f5c\u91c7\u7528ZHD30\u7535\u89e3\u6db2\u7684Zn-\u805a\u82ef\u80fa\u5168\u7535\u6c60\u5728-40~+25\u2103\u8303\u56f4\u5185\u5de5\u4f5c\uff0c350\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a6%\u3002<\/li>\n<\/ul>\n<p><strong><b>\u3010\u6570\u636e\u6982\u89c8\u3011<\/b><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>ZHD\u7535\u89e3\u6db2<\/b><\/strong><strong><b>\u7684\u6784\u5efa<\/b><\/strong><\/li>\n<\/ul>\n<p><strong><b>\u672c\u6587\u901a\u8fc7\u57282 M Zn(CF<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>SO<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>)<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>-H<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>O\u7535\u89e3\u6db2(ZHD)\u4e2d\u5f15\u5165\u4e0d\u540c\u91cf\u7684DMF\uff0c\u63a2\u7a76\u4e24\u79cd\u6eb6\u5242\u6548\u5e94\u5bf9HER\u7684\u4f18\u5148\u987a\u5e8f\u548c\u5f71\u54cd\uff0c\u5373DMF\u5bf9\u6c22\u952e\u7684\u91cd\u65b0\u5efa\u7acb\u548c\u5bf9\u5185\u6eb6\u5242\u5316\u9798\u7684\u8c03\u63a7<\/b><\/strong>\u3002\u5728ZHD30\u7535\u89e3\u6db2\u4e2d\uff0c\u7531\u4e8eDMF\u4e0d\u8fdb\u5165Zn<sup>2+<\/sup>\u7684\u7b2c\u4e00\u914d\u4f4d\u58f3\u5c42\uff0cDMF\u4e2dO\u548c\u6c34\u4e2dH\u4e4b\u95f4\u7684\u6c22\u952e\u7f51\u7edc\u88ab\u91cd\u65b0\u6784\u5efa\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e86\u6c34\u6d3b\u5ea6\u7684\u6700\u5927\u70ed\u529b\u5b66\u964d\u4f4e(\u56fe1)\u3002\u6291\u5236HER\u53ef\u4f7f\u9540\u950c\/\u5265\u79bbCE\u589e\u5f3a\u523099.4%(300\u4e2a\u5faa\u73af)\uff0c\u4f7fZn||Zn\u5bf9\u79f0\u7535\u6c60\u7684\u5faa\u73af\u5bff\u547d\u5ef6\u957f\u52302000 h\u3002\u6b64\u5916\uff0c\u91cd\u65b0\u5efa\u7acb\u7684\u6c22\u952e\u7f51\u7edc\u6291\u5236\u4e86\u4f4e\u6e29\u4e0b\u7684\u6210\u6838\u8fc7\u7a0b\uff0c\u63d0\u9ad8\u4e86\u7535\u89e3\u6db2\u7684\u73af\u5883\u9002\u5e94\u6027\u3002\u57fa\u4e8e\u8fd9\u79cd\u9ad8\u53ef\u9006\u7535\u89e3\u6db2\u7684Zn-\u805a\u82ef\u80fa(PANI)\u5168\u7535\u6c60\u5177\u6709\u8f83\u5bbd\u7684\u6e29\u5ea6\u8303\u56f4(-40~+25\u2103)\uff0c\u672c\u7814\u7a76\u4e3a\u6eb6\u5242\u6548\u5e94\u6291\u5236\u754c\u9762\u526f\u53cd\u5e94\u63d0\u4f9b\u4e86\u601d\u8def\uff0c\u4e3a\u8bbe\u8ba1\u4f4e\u6210\u672c\u3001\u9ad8\u6548\u7684\u6c34\u7535\u89e3\u8d28\u63d0\u4f9b\u4e86\u65b0\u7b56\u7565\u3002<\/p>\n<p>\u4e3a\u4e86\u8fdb\u4e00\u6b65\u7814\u7a76\u4e0d\u540c\u6eb6\u5242\u6548\u5e94\u7684\u4f18\u5148\u6027\uff0c\u4ee5\u919b\u6c22\u5728DMF\u4e0a\u76841H\u5316\u5b66\u4f4d\u79fb\u4f5c\u4e3a\u654f\u611f\u6307\u6807\u3002\u5728\u56fe2a\u4e2d\uff0c\u968f\u7740DMF\u542b\u91cf\u7684\u589e\u52a0\uff0cH<sub>2<\/sub>O-DMF\u6df7\u5408\u6eb6\u6db2(HD)\u4e2d\u76841H\u4fe1\u53f7\u5f00\u59cb\u5411\u4f4e\u573a\u504f\u79fb\u3002\u8fd9\u79cd\u8f6c\u53d8\u662f\u7531\u4e8eDMF\u4e2d\u7684O\u539f\u5b50\u4e0e\u6c34\u5206\u5b50\u4e2d\u7684H\u539f\u5b50(CO\u00b7H-O)\u53d1\u751f\u6c22\u952e\u4f5c\u7528\uff0c\u4f7f\u919b\u6c22\u7684\u6838\u8131\u5c4f\u853d\u3002\u5f53Zn(CF<sub>3<\/sub>SO<sub>3<\/sub>)<sub>2<\/sub>(2M)\u52a0\u5165\u5230\u4f4e\u91cfDMF\u7684HD\u4e2d\u65f6\uff0cZHD\u7535\u89e3\u6db2\u4e2d1H\u4fe1\u53f7\u7684\u4e0b\u79fb\u4e0eHD\u4e2d\u7684\u4e0b\u79fb\u4e00\u81f4\uff0c\u8bc1\u5b9e\u53ea\u6709DMF\u7684\u6c22\u952e\u4f5c\u7528\u3002\u56fe2b\u7ed9\u51fa\u4e86\u4e0d\u540cDMF\u4f53\u79ef\u5206\u6570ZHD\u7535\u89e3\u6db2\u7684\u533a\u57dfFTIR\u56fe\u8c31\u3002\u53ef\u4ee5\u53d1\u73b0\uff0cZHD\u7535\u89e3\u8d28\u57281660cm<sup>-1<\/sup>\u5904\u8868\u73b0\u51fa\u7fb0\u57fa(C=O)\u57fa\u56e2\u72ec\u7279\u7684\u62c9\u4f38\u6a21\u5f0f\u3002\u968f\u7740DMF\u542b\u91cf\u7684\u589e\u52a0(\u4f4e30%)\uff0cZHD\u7535\u89e3\u8d28\u7684\u8c31\u5e26\u5411\u4f4e\u6ce2\u6570\u79fb\u52a8(\u7ea2\u79fb)\uff0c\u8fd9\u53ef\u4ee5\u89e3\u91ca\u4e3aDMF\u901a\u8fc7\u6c22\u952e\u4f5c\u7528\u6355\u83b7\u7684\u6c34\u3002\u968f\u7740DMF\u542b\u91cf\u7684\u589e\u52a0\uff0c\u6839\u636e\u62df\u5408\u51fa\u7684\u5cf0\u9762\u79ef\uff0c\u8ba1\u7b97\u4e86\u4e0d\u540c\u6c22\u952e\u72b6\u6001\u4e0b\u6c34\u7684\u6bd4\u4f8b\u3002<strong><b>\u5bf9\u4e0d\u540c\u6c22\u952e\u72b6\u6001\u7684\u91cf\u5316\u8868\u660e\uff0c\u6c34\u5206\u5b50\u4e0e\u6c22\u952e\u53d7\u4f53\u7ed3\u5408\u7684\u91cf\u663e\u8457\u589e\u52a0\uff0c\u8bf4\u660eDMF\u7684\u52a0\u5165\u6210\u529f\u5730\u8c03\u63a7\u4e86ZHD\u7535\u89e3\u8d28\u4e2d\u521d\u59cb\u6c22\u952e\u7f51\u7edc(\u56fe2d)<\/b><\/strong>\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235153\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724714.png\" alt=\"\" width=\"628\" height=\"208\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724714.png 628w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724714-300x99.png 300w\" sizes=\"(max-width: 628px) 100vw, 628px\" \/><\/p>\n<p>\u56fe1. (a)2 M Zn(CF<sub>3<\/sub>SO<sub>3<\/sub>)<sub>2<\/sub>\u548c(b)ZHD30\u7535\u89e3\u8d28\u7684\u5185\u90e8\u7535\u89e3\u8d28\u7ed3\u6784\u548c\u6eb6\u5242\u6548\u5e94\u793a\u610f\u56fe\u00a9 The Author(s) 2022<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235154\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724715.png\" alt=\"\" width=\"639\" height=\"543\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724715.png 639w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724715-300x255.png 300w\" sizes=\"(max-width: 639px) 100vw, 639px\" \/><\/p>\n<p>\u56fe2. H<sub>2<\/sub>O-DMF\u548cZn(CF<sub>3<\/sub>SO<sub>3<\/sub>)<sub>2<\/sub>-H2O-DMF\u5728\u4e0d\u540c\u4f53\u79ef\u4e0b\u76841H\u5316\u5b66\u4f4d\u79fb<\/p>\n<p>\u5206\u6570\u00a9 The Author(s) 2022<\/p>\n<ul>\n<li><b><\/b><strong><b>\u5316\u5b66\u6210\u5206\u548c\u7535\u5b50\u7ed3\u6784<\/b><\/strong><\/li>\n<\/ul>\n<p>\u56fe3a\u8bf4\u660e\u4e86\u52a0\u5165DMF\u540e2 M Zn(CF<sub>3<\/sub>SO<sub>3<\/sub>)<sub>2<\/sub>\u7535\u89e3\u6db2\u4e2d\u6eb6\u5242\u6548\u5e94\u7684\u6f14\u53d8\u3002\u5728\u6ca1\u6709DMF\u76842 M Zn(CF<sub>3<\/sub>SO<sub>3<\/sub>)<sub>2<\/sub>\u7535\u89e3\u6db2\u4e2d\uff0c\u6c34\u79bb\u5b50Zn(H<sub>2<\/sub>O)<sub>6<\/sub><sup>2+<\/sup>\u4e3b\u5bfc\u4e86\u6eb6\u5242\u5316\u7ed3\u6784\u3002\u5f15\u5165\u540e\uff0cDMF\u9996\u5148\u4e0eH<sub>2<\/sub>O\u7ed3\u5408\u5f62\u6210\u6c22\u952e( HBs)\u3002\u968f\u7740DMF\u4f53\u79ef\u589e\u52a0\u523030%\u4ee5\u4e0a\uff0cDMF\u9010\u6e10\u63d2\u5165\u5230Zn<sup>2+<\/sup>\u7684\u5185\u5916\u6eb6\u5242\u5316\u9798\u4e2d\uff0c\u663e\u8457\u5f71\u54cdZn<sup>2+<\/sup>\u7684\u914d\u4f4d\u5e73\u8861\u3002\u56e0\u6b64\uff0c<strong><b>DMF\u7684\u5f15\u5165\u91cf\u5e94\u63a7\u5236\u5728\u6700\u4f73\u70ed\u529b\u5b66\u6291\u5236HER\u7684\u4e34\u754c\u6d53\u5ea6<\/b><\/strong>\u3002\u8fd9\u79cd\u6d53\u5ea6\u5e94\u6709\u5229\u4e8eDMF\u4e0e\u6c34\u5206\u5b50\u5f62\u6210\u5e7f\u6cdb\u7684\u6c22\u952e\uff0c\u800c\u4e0d\u6d89\u53caDMF\u5728Zn<sup>2+<\/sup>\u6eb6\u5242\u5316\u9798\u5c42\u4e2d\u3002<strong><b>DMF\u6d53\u5ea6\u4e3a30%(ZHD30)\u662fDMF\u5f15\u53d1\u6eb6\u5242\u6548\u5e94\u4ece\u5355\u4e00\u6c22\u952e\u6548\u5e94\u5230\u914d\u4f4d\u6548\u5e94\u548c\u6c22\u952e\u6548\u5e94\u5171\u5b58\u7684\u4e34\u754c\u70b9<\/b><\/strong>\u3002\u56e0\u6b64\uff0c\u9009\u62e9ZHD30\u4f5c\u4e3a\u6700\u4f73\u7535\u89e3\u6db2\u8fdb\u4e00\u6b65\u63a2\u7a76\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n<p>\u8003\u8651\u5230\u4e0d\u540c\u7ed9\u7535\u5b50\u80fd\u529b\u7684\u6709\u673a\u6eb6\u5242\u53ef\u4ee5\u91cd\u6784\u7535\u89e3\u8d28\u7ed3\u6784\uff0c\u6d88\u9664HER\u526f\u53cd\u5e94\uff0c\u9009\u62e9\u4e0d\u540c\u79cd\u7c7b\u7684\u6709\u673a\u6eb6\u5242\uff0c\u5982\u4e8c\u7532\u57fa\u4e9a\u781c(DMSO)\u3001\u4e8c\u7532\u6c27\u57fa\u4e59\u70f7(DME)\u3001\u78b3\u9178\u4e8c\u7532\u916f(DMC)\u5bf9\u6709\u673a\u6eb6\u5242-\u6c34\u590d\u5408\u7269\u7684\u8fd8\u539f\u7a33\u5b9a\u6027\u8fdb\u884c\u6bd4\u8f83\u3002\u56fe4a\u4e2d\uff0c\u57fa\u4e8e2 M Zn (CF<sub>3<\/sub>SO<sub>3<\/sub>)<sub>2<\/sub>\u7684CE\u4ec5\u4e3a73.0%\u3002\u7531\u4e8e\u8fd9\u79cd\u5e38\u89c4\u7a00\u6eb6\u6db2\u5177\u6709\u8f83\u9ad8\u7684\u6c34\u6d3b\u6027\uff0c\u5728\u9540\u950c\/\u53cd\u8403\u8fc7\u7a0b\u4e2d\u53d1\u751f\u4e86HER\uff0c\u4f7fCE\u4e0b\u964d\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u8150\u8680\u548c\u679d\u6676\u5f62\u6210\u7b49\u7ade\u4e89\u6027\u526f\u53cd\u5e94\u7684\u53d1\u751f\uff0c2 M Zn(CF<sub>3<\/sub>SO<sub>3<\/sub>)<sub>2<\/sub>\u5728\u5c0f\u4e8e65\u4e2a\u5faa\u73af\u4e2d\u89c2\u5bdf\u5230\u4e0d\u7a33\u5b9a\u7684\u5265\u79bb\u4fe1\u53f7\uff0c\u5e73\u5747CE\u503c\u4e3a95.3%(\u56fe4c)\u3002<strong><b>\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u4f7f\u7528ZHD30\uff0c\u7b2c\u4e00\u6b21\u5faa\u73af\u7684CE\u663e\u7740\u589e\u52a0\u81f387.7%\uff0c\u8fd9\u6781\u5927\u5730\u63d0\u9ad8\u4e86\u7535\u89e3\u8d28\u9632\u6b62\u8fd8\u539f\u7684\u5185\u5728\u80fd\u529b(\u56fe4b)<\/b><\/strong>\u3002\u4e3a\u76f4\u89c2\u63a2\u7a76DMF\u6dfb\u52a0\u5242\u5bf9\u7535\u89e3\u6db2\u4e2dHER\u3001\u8150\u8680\u548c\u949d\u5316\u7684\u6291\u5236\u4f5c\u7528\uff0c\u91c7\u7528\u914d\u5907\u5149\u5b66\u76f8\u673a\u7684\u539f\u4f4dAFM\uff0c\u83b7\u5f97\u9540\u950c\u8fc7\u7a0b\u4e2d\u7535\u6781\u8868\u9762\u7684\u5149\u5b66\u56fe\u50cf\u3002\u5982\u56fe4e\u6240\u793a\uff0c\u57282 M Zn (CF<sub>3<\/sub>SO<sub>3<\/sub>) 2\u4e2d\uff0c\u968f\u7740\u9540\u950c\u8fc7\u7a0b\u4e2d\u6c22\u6c14\u7684\u751f\u6210\uff0c\u7535\u6781\u4e0a\u7684\u91d1\u5c42\u5bb9\u6613\u5265\u79bb\u7535\u6781\uff0cHER\u5728\u4f53\u7cfb\u4e2d\u5f15\u8d77\u660e\u663e\u7684\u7a81\u8d77\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235155\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724716.png\" alt=\"\" width=\"641\" height=\"583\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724716.png 641w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724716-300x273.png 300w\" sizes=\"(max-width: 641px) 100vw, 641px\" \/><\/p>\n<p>\u56fe3. Zn<sup>2+<\/sup>\u6eb6\u5242\u9798\u5c42\u548c\u5c40\u90e8\u6c22\u952e\u7f51\u7edc\u968fDMF\u52a0\u5165\u53d8\u5316\u7684\u56fe\u5f0f\u00a9 The Author(s) 2022<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235156\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724717.png\" alt=\"\" width=\"646\" height=\"328\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724717.png 646w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724717-300x152.png 300w\" sizes=\"(max-width: 646px) 100vw, 646px\" \/><\/p>\n<p>\u56fe4. Zn||Cu\u7535\u6c60\u9540\u950c\/\u5265\u79bb\u7684\u7535\u538b\u5256\u9762\u548cCE\u00a9 The Author(s) 2022<\/p>\n<ul>\n<li><b><\/b><strong><b>\u9540\u950c\u8fc7\u7a0b\u4e2d\u7684H<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>O\u8fd8\u539f\u884c\u4e3a<\/b><\/strong><\/li>\n<\/ul>\n<p>\u4e3a\u4e86\u8fdb\u4e00\u6b65\u8bc4\u4ef7\u9540\u950c\u8fc7\u7a0b\u4e2d\u7684H<sub>2<\/sub>O\u8fd8\u539f\u884c\u4e3a\uff0c\u91c7\u7528\u8bbe\u8ba1\u7535\u6c60\u7684\u6c14\u76f8\u8272\u8c31\u6cd5\uff0c\u5bf9\u6dfb\u52a0\u548c\u4e0d\u6dfb\u52a0DMF\u7684\u7535\u89e3\u6db2\u4e2d\u7684\u6c14\u4f53\u6f14\u5316\u8fdb\u884c\u4e86\u76d1\u6d4b\u3002<strong><b>\u4e0e2 M Zn (CF<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>SO<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>)<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u7535\u89e3\u8d28\u76f8\u6bd4\uff0cZHD30\u7535\u89e3\u8d28\u663e\u8457\u6291\u5236HER<\/b><\/strong>\u3002\u4eceSEM\u56fe\u53ef\u4ee5\u770b\u51fa\uff0c\u57282 M Zn (CF<sub>3<\/sub>SO<sub>3<\/sub>)<sub>2<\/sub>\u7535\u89e3\u6db2\u4e2d\u5faa\u73af\u540e\uff0c\u7eb3\u7c73\u7247\u5c42\u590d\u76d6\u4e86Zn\u7535\u6781(\u56fe5a)\u3002XRD\u8868\u5f81(\u56fe5e)\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u8be5\u5c42\u7531ZnO\u7ec4\u6210\u3002\u8fd9\u79cd\u663e\u8457\u7684\u8150\u8680\u548c\u949d\u5316\u5bf9\u9540\u950c\/\u5265\u79bb\u7684CE\u4ea7\u751f\u4e86\u663e\u8457\u7684\u5f71\u54cd\uff0c\u6700\u7ec8\u7834\u574f\u4e86\u950c\u7535\u6781\u3002\u76f8\u53cd\uff0c\u5728\u76f8\u540c\u7684\u8bd5\u9a8c\u6761\u4ef6\u4e0b\uff0cZn\u8d1f\u6781\u5728ZHD30\u7535\u89e3\u6db2\u4e2d\u5faa\u73af50\u6b21\u540e\u8868\u9762\u4ecd\u5448\u73b0\u5e73\u6574\u65e0\u679d\u6676\u7684\u5f62\u8c8c(\u56fe5c)\u3002\u950c\u8868\u9762\u7684\u6da6\u6e7f\u6027\u76f4\u63a5\u5f71\u54cd\u950c\u521d\u59cb\u6210\u6838\u548c\u751f\u957f\u7684\u80fd\u5792\u3002\u56e0\u6b64\uff0c\u91c7\u7528\u63a5\u89e6\u89d2\u6280\u672f\u8bc4\u4ef7\u6dfb\u52a0DMF\u5bf9\u7535\u6781\u6da6\u6e7f\u6027\u7684\u5f71\u54cd\u3002\u7531\u4e8e\u5176\u758f\u6c34\u6027\uff0cZn\u91d1\u5c5e\u57282M Zn(CF<sub>3<\/sub>SO<sub>3<\/sub>)<sub>2<\/sub>\u7535\u89e3\u6db2\u4e2d\u7684\u63a5\u89e6\u89d2\u9ad8\u8fbe74.3\u00b0(\u56fe5g)\u3002\u4f46DMF(30%)\u5f15\u5165\u540e\uff0c\u63a5\u89e6\u89d2\u964d\u4f4e\u523052.7\u00b0\uff0c\u8868\u660eDMF\u5bf9Zn\u91d1\u5c5e\u5177\u6709\u8f83\u9ad8\u7684\u6da6\u6e7f\u6027(\u56fe5h)\u3002<strong><b>\u4f4e\u63a5\u89e6\u89d2\u8868\u660eDMF\u53ef\u80fd\u4f18\u5148\u5438\u9644\u5728\u7535\u6781\u8868\u9762\uff0c\u4ece\u800c\u6291\u5236\u8150\u8680\u548c\u949d\u5316\uff0c\u6709\u6548\u63d0\u9ad8\u4e86Zn<\/b><\/strong><strong><b>\u8d1f\u6781<\/b><\/strong><strong><b>\u7684CE\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u867d\u7136\u5f15\u5165\u4e86\u53ef\u71c3DMF\uff0c\u4f46ZHD30\u7535\u89e3\u8d28\u4e2d\u4ecd\u542b\u6709\u8db3\u591f\u7684H<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>O\uff0c\u4ecd\u5177\u6709\u62b5\u6297\u71c3\u70e7\u7684\u80fd\u529b<\/b><\/strong>\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235157\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724718.png\" alt=\"\" width=\"653\" height=\"481\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724718.png 653w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724718-300x221.png 300w\" sizes=\"(max-width: 653px) 100vw, 653px\" \/><\/p>\n<p>\u56fe5. \u6c89\u79efZn\u91d1\u5c5e\u7684SEM\u56fe\u548c\u653e\u5927\u540e\u7684SEM\u56fe\u00a9 The Author(s) 2022<\/p>\n<ul>\n<li><b><\/b><strong><b>\u5168\u7535\u6c60<\/b><\/strong><strong><b>\u6027\u80fd<\/b><\/strong><\/li>\n<\/ul>\n<p>\u4e3a\u4e86\u6ee1\u8db3\u5927\u89c4\u6a21\u5b9e\u9645\u5e94\u7528\u7684\u9700\u8981\uff0c\u5bbd\u6e29\u8303\u56f4\u7535\u6c60\u7684\u6709\u673a\u6750\u6599\u7531\u4e8e\u5176\u7279\u6b8a\u7684\u7535\u8377\u50a8\u5b58\u673a\u5236\u4e3b\u8981\u4f4d\u4e8e\u8868\u9762\u57fa\u56e2\uff0c\u4e0d\u540c\u4e8e\u4f20\u7edf\u65e0\u673a\u6750\u6599\u7684\u7f13\u6162\u63d2\u5165\u52a8\u529b\u5b66\uff0c\u53d7\u5230\u4e86\u4eba\u4eec\u7684\u5173\u6ce8\u3002\u56e0\u6b64\uff0c\u9009\u62e9\u805a\u82ef\u80fa( PANI)\u6784\u5efa\u5168\u7535\u6c60\u3002<strong><b>\u56fe6b\u663e\u793a\uff0c\u5cf0\u7684b\u503c\u63a5\u8fd1\u4e8e1\uff0c\u8868\u660eZn|ZHD30|PANI\u7535\u6c60\u4e2d\u7684\u7535\u5316\u5b66\u53cd\u5e94\u5141\u8bb8\u4ee5\u8d5d\u7535\u5bb9\u884c\u4e3a\u4e3a\u4e3b<\/b><\/strong>\u3002\u8fd9\u79cd\u6709\u673a\u805a\u5408\u7269\u7535\u6781\u963b\u6b62\u4e86\u6eb6\u89e3\u79bb\u5b50\u7684\u8131\u6eb6\uff0c\u663e\u793a\u4e86\u5176\u5728\u4f4e\u6e29\u4e0b\u7684\u5e94\u7528\u6f5c\u529b\u3002\u968f\u540e\u5728\u5ba4\u6e29\u4e0b\u5bf9Zn|ZHD30|PANI\u7535\u6c60\u7684\u957f\u671f\u5faa\u73af\u7a33\u5b9a\u6027\u8fdb\u884c\u4e86\u8bc4\u4ef7(\u56fe6e)\u3002\u57281 A g<sup>-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cZn||PANI\u7535\u6c60\u5728ZHD30\u7535\u89e3\u6db2\u4e2d\u5faa\u73af350\u6b21\u540e\u5bb9\u91cf\u4fdd\u6301\u5728133.1 mAh g<sup>-1<\/sup>\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a91.6%\u3002\u7ed3\u679c\u8868\u660e\uff0cZHD30\u57fa\u950c\u7535\u6c60\u5177\u6709\u4f18\u8d8a\u7684\u6027\u80fd\u3001\u826f\u597d\u7684\u5e94\u7528\u524d\u666f\u548c\u53ef\u884c\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235158\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724719.png\" alt=\"\" width=\"577\" height=\"294\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724719.png 577w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/03\/\u56fe\u724719-300x153.png 300w\" sizes=\"(max-width: 577px) 100vw, 577px\" \/><\/p>\n<p>\u56fe6. 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