{"id":235194,"date":"2022-03-30T06:33:30","date_gmt":"2022-03-29T22:33:30","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=235194"},"modified":"2022-03-29T15:33:59","modified_gmt":"2022-03-29T07:33:59","slug":"%e7%8e%8b%e7%92%90%e7%ad%89%e4%ba%ba-nat-commun-%ef%bc%9a%e6%96%b0%e5%9e%8b%e9%bb%91%e8%89%b2%e6%b0%a7%e5%8c%96%e9%93%9f%e4%b8%b2%e8%81%94%e5%85%89%e7%83%ad%e5%82%ac%e5%8c%96co2%e5%92%8ch2%e5%88%b6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=235194","title":{"rendered":"\u738b\u7490\u7b49\u4eba Nat. Commun.\uff1a\u65b0\u578b\u9ed1\u8272\u6c27\u5316\u94df\u4e32\u8054\u5149\u70ed\u50ac\u5316CO2\u548cH2\u5236\u7532\u9187"},"content":{"rendered":"

\u3010\u5bfc\u8bfb\u3011<\/p>\n

\u7532\u9187\uff08methanol\uff09\u662f\u6700\u6709\u4ef7\u503c\u7684\u5316\u5b66\u54c1\u4e4b\u4e00\uff0c2019\u5e74\u5168\u7403\u9700\u6c42\u91cf\u8d85\u8fc78000\u4e07\u516c\u5428\u3002\u5b83\u53ef\u4ee5\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u6e05\u6d01\u71c3\u6599\u3001\u66ff\u4ee3\u6c22\u8f7d\u4f53\uff0c\u4ee5\u53ca\u5927\u7ea630%\u5df2\u77e5\u5316\u5b66\u7269\u8d28\u7684\u57fa\u672c\u7ec4\u6210\u90e8\u5206\u3002\u56e0\u6b64\uff0c\u4ee5\u53ef\u518d\u751f\u7532\u9187\u7684\u5f62\u5f0f\u50a8\u5b58\u592a\u9633\u80fd\uff0c\u540c\u65f6\u964d\u4f4e\u5927\u6c14\u4e2d\u7684CO2\u6d53\u5ea6\uff0c\u6709\u53ef\u80fd\u5173\u95ed\u78b3\u5faa\u73af\u3001\u751f\u4ea7\u53ef\u518d\u751f\u71c3\u6599\uff0c\u5e76\u6539\u5584\u6c14\u5019\u53d8\u5316\u3002\u7136\u800c\uff0c\u57fa\u4e8eLe Chatelier\u2019s\u539f\u7406\u4ee5\u53ca\u9006\u6c34\u7164\u6c14\u8f6c\u6362\uff08reverse water-gas shift, RWGS\uff09\u53cd\u5e94\u548c\u7532\u9187\u5408\u6210\u7684\u7ade\u4e89\u6027\uff0c\u4f20\u7edf\u7684\u7532\u9187\u751f\u4ea7\u8def\u7ebf\u901a\u5e38\u91c7\u7528\u9ad8\u6d53\u5ea6H2\u548c\u9ad8\u538b\u6765\u6539\u53d8\u53cd\u5e94\u5e73\u8861\uff0c\u63d0\u9ad8\u7532\u9187\u9009\u62e9\u6027\u3002
\n \"\"\u901a\u8fc7\u6839\u636e\u65b9\u7a0b\u5f0f1<\/strong>\u52303<\/strong>\u8fdb\u884cRWGS\u548cCO\u52a0\u6c22\u53cd\u5e94\uff0c\u4e32\u8054\u53cd\u5e94\u9014\u5f84\u53ef\u4ee5\u4e3a\u4f4e\u538b\u548c\u4f4eH2<\/sub>\u6d53\u5ea6\uff0850%\uff09\u7684\u7532\u9187\u5408\u6210\u94fa\u5e73\u9053\u8def\u3002\u4e3a\u4e86\u5b9e\u73b0\u8fd9\u79cd\u60c5\u51b5\uff0c\u9700\u8981\u4e00\u79cd\u5177\u6709\u591a\u529f\u80fd\u6d3b\u6027\u4f4d\u70b9\u7684\u50ac\u5316\u5242\uff0c\u8be5\u50ac\u5316\u5242\u53ef\u4ee5\u4eceCO2<\/sub>\u548cCO\u4e2d\u8fdb\u884c\u7532\u9187\u5408\u6210\uff0c\u4f46\u8fd9\u79cd\u6750\u6599\u5c1a\u5f85\u5f00\u53d1\u3002
\n \"\"
\n \u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u52a0\u62ff\u5927\u591a\u4f26\u591a\u5927\u5b66Geoffrey A. Ozin\u548cChengliang Mao\u3001\u9999\u6e2f\u4e2d\u6587\u5927\u5b66\uff08\u6df1\u5733\uff09\u738b\u7490\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u5229\u7528\u6c27\u5316\u94df\uff08In2<\/sub>O3<\/sub>\uff09\u7eb3\u7c73\u6676\u4f53\uff08\u8868\u793a\u4e3aS1\uff09\u548cNaBH4<\/sub>\u4f5c\u4e3a\u524d\u4f53\u6750\u6599\uff0c\u901a\u8fc7\u56fa\u6001\u5408\u6210\u8def\u7ebf\u6210\u529f\u5408\u6210\u7684\u65b0\u578b\u9ed1\u8272\u7684\u5b9a\u5236\u7eb3\u7c73\u7ea7\u6c27\u5316\u94df\uff0c\u5373Hz<\/sub>In2<\/sub>O3-x<\/sub>(OH)y<\/sub>\uff08\u8868\u793a\u4e3aS2\uff09\uff0c\u5176\u5177\u6709\u6c27\u7a7a\u4f4d\u3001\u7f9f\u57fa\u548c\u6c22\u5316\u7269\u4f4d\u70b9\u3002\u7531\u6de1\u9ec4\u8272\u7684\u5149\u70ed\u975e\u6d3b\u6027In2<\/sub>O3<\/sub>\u7eb3\u7c73\u6676\u4f53\u8f6c\u53d8\u4e3a\u9ed1\u8272\u5177\u6709\u5149\u70ed\u6d3b\u6027\u7684Hz<\/sub>In2<\/sub>O3-x<\/sub>(OH)y<\/sub>\u7eb3\u7c73\u6676\u4f53\uff0c\u5176\u4e2d\u542b\u6709surface frustrated Lewis pairs\uff08SFLPs\uff09\u4f5c\u4e3a\u6d3b\u6027\u4f4d\u70b9\u3002\u65b0\u578b\u7684\u9ed1\u8272Hz<\/sub>In2<\/sub>O3-x<\/sub>(OH)y<\/sub>\u901a\u8fc7\u521d\u59cbRWGS\u53cd\u5e94\u548c\u968f\u540eCO\u52a0\u6c22\u53cd\u5e94\u5728\u4f4e\u6c22\u6c14\u6d53\u5ea6\uff0850%\uff09\u548c\u5e38\u538b\u4e0b\u5b9e\u73b0\u4e86\u4e32\u8054\u5408\u6210\u7532\u9187\uff0c\u5176\u4e2d\u526f\u4ea7\u7269CO\u7528\u4f5c\u7532\u9187\u5408\u6210\u7684\u539f\u4f4d\u539f\u6599\uff0c\u5176\u4e2d\u5728\u4f4e\u6c22\u6c14\u6d53\u5ea6\u548c\u9ad8\u6c22\u6c14\u6d53\u5ea6\u4e0b\uff0c\u7532\u9187\u9009\u62e9\u6027\u5206\u522b\u8fbe\u523033.24%\u548c49.23%\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cNew black indium oxide-tandem photothermal CO2<\/sub>-H2<\/sub> methanol selective catalyst\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNature Communications<\/strong>\u4e0a\u3002
\n \u672c\u6587\u6240\u6709\u56fe\u6765\u6e90\u4e8e\u00a9 2022 Springer Nature Limited\u3002<\/p>\n

\u3010\u6838\u5fc3\u521b\u65b0\u3011<\/strong><\/p>\n

1\u3001\u5236\u5907\u4e86\u4e00\u79cd\u65b0\u578b\u9ed1\u8272\u5177\u6709\u5149\u70ed\u6d3b\u6027\u7684\u7eb3\u7c73\u7ea7\u6c27\u5316\u94df\uff0c\u5373Hz<\/sub>In2<\/sub>O3-x<\/sub>(OH)y<\/sub>\u7eb3\u7c73\u6676\u4f53\u3002<\/p>\n

2\u3001Hz<\/sub>In2<\/sub>O3-x<\/sub>(OH)y<\/sub>\u7eb3\u7c73\u6676\u4f53\u901a\u8fc7RWGS\u53cd\u5e94\u548cCO\u52a0\u6c22\u53cd\u5e94\u5728\u4f4e\u6c22\u6c14\u6d53\u5ea6\uff0850%\uff09\u548c\u5e38\u538b\u4e0b\u5b9e\u73b0\u4e86\u4e32\u8054\u5408\u6210\u7532\u9187\uff0c\u5176\u4e2d\u526f\u4ea7\u7269CO\u7528\u4f5c\u7532\u9187\u5408\u6210\u7684\u539f\u4f4d\u539f\u6599\u3002<\/p>\n

\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u7ed3\u6784\u8868\u5f81<\/strong>
\n \"\"\uff08a\uff09S1\u548cS2\u7684\u7c89\u672bXRD\u56fe\u8c31\uff1b<\/p>\n

\uff08b\uff09S2\u7684TEM\u56fe\u50cf\u548c\u53f3\u4e0a\u65b9\u63d2\u5165\u7684\u9ad8\u5206\u8fa8\u7387TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff09S1\u548cS2\u7684\u9ad8\u5206\u8fa8\u7387O1s\u6838\u5fc3\u7ea7XPS\u5149\u8c31\uff1b<\/p>\n

\uff08d\uff09\u4e0d\u540c\u6761\u4ef6\u4e0b\uff0cS2\u50ac\u5316\u5242\u7684\u539f\u4f4dXANES\u3002<\/p>\n

\u56fe\u4e8c\u3001\u50ac\u5316\u6027\u80fd<\/strong>
\n \"\"\uff08a\uff09Cu\/ZnO\/Al2<\/sub>O3<\/sub>(CZA)\u3001S1\u548cS2\u5728\u95f4\u6b47\u53cd\u5e94\u5668\u4e2d\u7684\u5149\u70ed\u50ac\u5316\u6027\u80fd\uff1b<\/p>\n

\uff08b\uff09\u4e0d\u540cH2<\/sub>: CO2<\/sub>\u6bd4\u7387\u4e0b\u7684\u7532\u9187\u9009\u62e9\u6027\uff1b<\/p>\n

\uff08c-d\uff09\u5728\u660e\/\u6697\u6761\u4ef6\u4e0b\u6d41\u52a8\u53cd\u5e94\u5668\u4e2dS2\u7684CO\u901f\u7387\u548c\u76f8\u5e94\u7684Arrhenius\u56fe\uff1b<\/p>\n

\uff08e-f\uff09S2\u7684\u7532\u9187\u901f\u7387\u548c\u76f8\u5e94\u7684Arrhenius\u56fe\u3002<\/p>\n

\u56fe\u4e09\u3001\u7a33\u5b9a\u6027\u6d4b\u8bd5\u548c\u539f\u4f4dDRIFTS\u5206\u6790<\/strong>
\n \"\"\uff08a-b\uff09\u572875% H2<\/sub>\u548c50% H2<\/sub>\u4e0b\uff0cS2\u5728250 \u00b0C\u548c\u5149\u7167\u4e0b\u8fdb\u884c75 h\u8fde\u7eed\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff1b<\/p>\n

\uff08c-d\uff09S2\u4e0eCO2<\/sub>\/H2<\/sub>\uff081: 1\uff09\u3001CO\/H2<\/sub>\uff081: 1\uff09\u7684\u539f\u4f4dDRIFTS\u3002<\/p>\n

\u56fe\u56db\u3001DFT\u8ba1\u7b97\u7528\u4e8e\u673a\u7406\u5206\u6790<\/strong>
\n \"\"\uff08a\uff09Mulliken\u7535\u8d1f\u6027\u5206\u6790\u548c\u76f8\u5e94\u7684\u8d28\u5b50\u5316\u548c\u6c22\u5316SFLP\u4f4d\u70b9\u7684\u5fae\u5206\u7535\u8377\u5bc6\u5ea6\uff1b<\/p>\n

\uff08b\uff09SFLP\u4f4d\u70b9\u4e0a\u7684RWGS\u53cd\u5e94\u548c\u968f\u540e[O]\u4f4d\u70b9\u4e0a\u7684\u7532\u9187\u5408\u6210\u7684\u81ea\u7531\u80fd\u56fe\uff1b<\/p>\n

\uff08c\uff09\u53ef\u80fd\u7684\u7532\u9187\u5408\u6210\u4e32\u8054\u53cd\u5e94\u673a\u7406\u548c\u76f8\u5e94\u7684\u539f\u5b50\u6784\u578b\u3002<\/p>\n

\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u56fa\u6001\u5408\u6210\u65b9\u6cd5\u6210\u529f\u5730\u5236\u5907\u4e86\u4e00\u79cd\u65b0\u578b\u9ed1\u8272\u5177\u6709\u5149\u70ed\u6d3b\u6027\u7684\u6c27\u5316\u94df\u50ac\u5316\u5242\uff0c\u5728\u5e38\u538b\u4e0b\u7532\u9187\u9009\u62e9\u6027\u4e3a30-50%\u3002\u4ece\u5b9e\u9a8c\u548c\u7406\u8bba\u4e0a\u63a2\u7d22\u4e86\u7532\u9187\u7684\u9014\u5f84\uff0c\u5e76\u63ed\u793a\u4e86\u4e32\u8054\u53cd\u5e94\u65b9\u6848\u7684\u64cd\u4f5c\uff0c\u5176\u4e2d\u6765\u81eaRWGS\u7684\u526f\u4ea7\u7269CO\u4f5c\u4e3a\u539f\u4f4d\u539f\u6599\u7528\u4e8e\u5f62\u6210\u7532\u9187\u3002\u4e32\u8054\u5de5\u827a\u5c06\u4f20\u7edf\u7684\u7ade\u4e89\u6027RWGS\u548c\u7532\u9187\u5408\u6210\u5de5\u827a\u8f6c\u53d8\u4e3a\u6d41\u52a8\u53cd\u5e94\u5668\u7cfb\u7edf\u4e2d\u7684\u7ec4\u5408\u53cd\u5e94\u9014\u5f84\u3002\u901a\u8fc7\u8868\u9762\u4f4d\u70b9\u5de5\u7a0b\uff0c\u65b0\u578b\u9ed1\u8272\u6c27\u5316\u94df\u5149\u70ed\u50ac\u5316\u5242\u514b\u670d\u4e86\u63a7\u5236\u7532\u9187\u5e38\u89c4\u5408\u6210\u7684\u70ed\u529b\u5b66\u9650\u5236\u3002\u5728\u5927\u6c14\u538b\u6761\u4ef6\u4e0b\u89c2\u5bdf\u5230\u7684\u9009\u62e9\u6027\u63d0\u9ad8\uff0c\u9884\u793a\u7740\u53ef\u4ee5\u5f00\u53d1\u65b0\u578b\u50ac\u5316\u5242\u7528\u4e8e\u751f\u4ea7\u53ef\u6301\u7eed\u7532\u9187\u7684\u592a\u9633\u80fd\u7cbe\u70bc\u5382\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aNew black indium oxide-tandem photothermal CO2<\/sub>-H2<\/sub> methanol selective catalyst<\/a><\/strong>. Nat. Commun.<\/em>, 2022<\/strong>, DOI: 10.1038\/s41467-022-29222-7.<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5bfc\u8bfb\u3011 \u7532\u9187\uff08methanol\uff09\u662f\u6700\u6709\u4ef7\u503c\u7684\u5316\u5b66\u54c1\u4e4b\u4e00\uff0c2019\u5e74\u5168\u7403\u9700\u6c42\u91cf\u8d85\u8fc78000\u4e07\u516c\u5428\u3002\u5b83\u53ef\u4ee5\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u6e05\u6d01\u71c3\u6599\u3001\u66ff\u4ee3\u6c22\u8f7d\u4f53\uff0c\u4ee5\u53ca\u5927\u7ea630%\u5df2\u77e5\u5316\u5b66…<\/p>\n","protected":false},"author":7770,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[4833],"class_list":["post-235194","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-4833"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/235194"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7770"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=235194"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/235194\/revisions"}],"predecessor-version":[{"id":235287,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/235194\/revisions\/235287"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=235194"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=235194"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=235194"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}