{"id":235389,"date":"2022-04-02T06:45:42","date_gmt":"2022-04-01T22:45:42","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=235389"},"modified":"2022-04-02T11:32:57","modified_gmt":"2022-04-02T03:32:57","slug":"%e5%8d%97%e5%bc%80%e7%8e%8b%e5%b0%8f%e9%87%8e%e8%af%be%e9%a2%98%e7%bb%84angew-chem-%ef%bc%9a%e5%9f%ba%e4%ba%8e%e7%a1%bc%e6%b0%ae%e8%92%bd%e7%9a%84%e9%ab%98%e6%80%a7%e8%83%bd%e6%9c%89%e6%9c%ba","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=235389","title":{"rendered":"\u5357\u5f00\u738b\u5c0f\u91ce\u8bfe\u9898\u7ec4Angew. 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cm<sup>2<\/sup>\u00a0V<sup>-1<\/sup>\u00a0s<sup>-1<\/sup>\uff09\u3002<strong><b>\u80fd\u5426\u57fa\u4e8e<\/b><\/strong><strong><b>BN-PAHs<\/b><\/strong><strong><b>\u5b9e\u73b0\u9ad8\u6027\u80fd\u6709\u673a\u5149\u7535\u6750\u6599\uff08\u5c24\u5176\u662f\u80fd\u548c\u65e0\u5b9a\u5f62\u7845\u5ab2\u7f8e\u7684\u8fc1\u79fb\u7387\u8d85\u8fc7<\/b><\/strong><strong><b>1 cm<\/b><\/strong><strong><sup><b>2<\/b><\/sup><\/strong><strong><b>\u00a0V<\/b><\/strong><strong><sup><b>-1<\/b><\/sup><\/strong><strong><b>\u00a0s<\/b><\/strong><strong><sup><b>-1<\/b><\/sup><\/strong><strong><b>\u7684\u6709\u673a\u534a\u5bfc\u4f53\u6750\u6599\uff09\u662f\u8fd9\u4e00\u9886\u57df\u5907\u53d7\u5173\u6ce8\u7684\u95ee\u9898\u4e0e\u4e9f\u5f85\u89e3\u51b3\u7684\u6311\u6218\u3002<\/b><\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235390\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-1-1.png\" alt=\"\" width=\"688\" height=\"349\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-1-1.png 688w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-1-1-300x152.png 300w\" sizes=\"(max-width: 688px) 100vw, 688px\" \/><\/p>\n<p>\u56fe1.\u00a0\u901a\u8fc7BN-PAHs\u7684\u201c\u8fb9\u7f18\u5de5\u7a0b\u201d\uff08periphery engineering\uff09\u5b9e\u73b0\u9ad8\u6027\u80fd\u6709\u673a\u5149\u7535\u6750\u6599\uff08\u56fe\u4e2d\u626d\u8f6c\u89d2\u662f\u901a\u8fc7\u7ed3\u6784\u4f18\u5316\u83b7\u5f97\uff09<\/p>\n<p><strong>\u3010\u4e8c\u3001\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u5357\u5f00\u5927\u5b66\u738b\u5c0f\u91ce<\/strong>\u8bfe\u9898\u7ec4\u63d0\u51fa\u4e86\u901a\u8fc7BN-PAHs\u7684\u201c\u8fb9\u7f18\u5de5\u7a0b\u201d\uff08periphery\u00a0engineering\uff09\u6765\u5b9e\u73b0\u9ad8\u6027\u80fd\u6709\u673a\u5149\u7535\u6750\u6599\u7684\u7b56\u7565\u3002\u57fa\u4e8e\u787c\u6c2e\u84bd\uff08BNA\uff09\u9aa8\u67b6\uff0c\u4f5c\u8005\u8bbe\u8ba1\u5408\u6210\u4e86\u56db\u82ef\u57fa\u787c\u6c2e\u84bd\uff08TPBNA\uff09\u548c\u4e8c\u82ef\u57fa\u787c\u6c2e\u84bd\uff08DPBNA\uff09\u5206\u5b50\uff08\u56fe1\uff09\u3002\u5916\u56f4\u82ef\u57fa\u7684\u6570\u91cf\u53ef\u4ee5\u663e\u8457\u8c03\u63a7\u5206\u5b50\u7684\u51e0\u4f55\u6784\u578b\u53ca\u56fa\u6001\u4e0b\u5206\u5b50\u4e4b\u95f4\u7684\u7535\u5b50\u8026\u5408\u3002\u5176\u4e2d\uff0c\u57fa\u4e8eDPBNA\u7684\u5355\u6676OFET\u5668\u4ef6\u8868\u73b0\u51fa\u9ad8\u8fbe1.3 cm<sup>2<\/sup>\u00a0V<sup>-1<\/sup>\u00a0s<sup>-1<\/sup>\u7684\u7a7a\u7a74\u8fc1\u79fb\u7387\uff0c\u8fdc\u8fdc\u9ad8\u4e8eTPBNA\u5355\u6676\u7684\u8fc1\u79fb\u7387\u3002\u8fd9\u662f\u76ee\u524d\u62a5\u9053\u7684<strong>\u7b2c\u4e00\u4f8b\u8fc1\u79fb\u7387\u53ef\u4ee5\u8d85\u8fc71<\/strong><strong>\u00a0<\/strong><strong>cm<\/strong><strong><sup>2<\/sup><\/strong><strong>\u00a0V<\/strong><strong><sup>-1<\/sup><\/strong><strong>\u00a0s<\/strong><strong><sup>-1<\/sup><\/strong><strong>\u7684BN-PAH\uff0c\u4f7f\u5f97BN<\/strong><strong>&#8211;<\/strong><strong>PAHs\u80fd\u591f\u9996\u6b21\u8dfb\u8eab\u4e8e\u9ad8\u8fc1\u79fb\u7387\u6709\u673a\u534a\u5bfc\u4f53\u884c\u5217\uff0c\u8bc1\u660e\u4e86\u201c\u8fb9\u7f18\u5de5\u7a0b\u201d\u5bf9\u4e8e\u6316\u6398<\/strong><strong>BN-PAHs<\/strong><strong>\u7684\u5149\u7535\u6027\u80fd\u5177\u6709\u91cd\u8981\u7684\u4ef7\u503c\u3002<\/strong>\u8fdb\u4e00\u6b65\u7814\u7a76\u8868\u660e\uff0c\u57fa\u4e8eDPBNA\u5355\u6676\u7684\u5149\u6676\u4f53\u7ba1\u5668\u4ef6\u4e5f\u5c55\u793a\u51fa\u4f18\u5f02\u7684\u5149\u63a2\u6d4b\u6027\u8d28\uff0c\u63ed\u793a\u4e86BN-PAHs\u5728\u5149\u7535\u5668\u4ef6\u4e2d\u5e7f\u6cdb\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<p><strong>\u3010\u4e09\u3001\u56fe\u6587\u89e3\u6790\u3011<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235391\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-3.png\" alt=\"\" width=\"781\" height=\"385\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-3.png 781w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-3-300x148.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-3-768x379.png 768w\" sizes=\"(max-width: 781px) 100vw, 781px\" \/><\/p>\n<p>\u56fe2. TPBNA\u548cDPBNA\u7684\u5408\u6210\u8def\u7ebf<\/p>\n<p>TPBNA\u548cDPBNA\u7684\u5408\u6210\u8def\u7ebf\u5982\u56fe2\u6240\u793a\u3002\u4e24\u4e2a\u5316\u5408\u7269\u7684\u5408\u6210\u5747\u4ee52,5-\u4e8c\u6eb4\u5bf9\u82ef\u4e8c\u80fa<strong><b>1<\/b><\/strong>\u4f5c\u4e3a\u8d77\u59cb\u539f\u6599\uff0c\u7ecf\u4e24\u6b65\u53cd\u5e94\u5206\u522b\u4ee529%\u548c30%\u7684\u603b\u6536\u7387\u5236\u5f97\u3002\u9996\u5148<strong><b>1<\/b><\/strong>\u7ecf\u8fc7\u4e00\u6b65\u94af\u50ac\u5316\u7684Suzuki\u5076\u8054\u548cStille\u5076\u8054\u53cd\u5e94\u5206\u522b\u5f97\u5230\u5316\u5408\u7269<strong><b>2<\/b><\/strong>\u548c<strong><b>3<\/b><\/strong>\uff0c\u7136\u540e\u901a\u8fc7\u4e00\u6b65\u82b3\u9999\u4eb2\u7535\u787c\u5316\u53cd\u5e94\u5206\u522b\u4ee544%\u548c39%\u7684\u4ea7\u7387\u5f97\u5230TPBNA\u548cDPBNA\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235392\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-4.png\" alt=\"\" width=\"2642\" height=\"1072\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-4.png 2642w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-4-300x122.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-4-768x312.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-4-1024x415.png 1024w\" sizes=\"(max-width: 2642px) 100vw, 2642px\" \/><\/p>\n<p>\u56fe3. TPBNA\u548cDPBNA\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\uff08a\uff09\u548c\u8367\u5149\uff08b\uff09\u5149\u8c31<\/p>\n<p>\u7531\u4e8e\u5916\u56f4\u82ef\u57fa\u53d6\u4ee3\u57fa\u7684\u03c0\u62d3\u5c55\uff0c\u4e0e\u6bcd\u4f53BNA\u76f8\u6bd4\uff0cTPBNA\u548cDPBNA\u4f4e\u80fd\u91cf\u5438\u6536\u5cf0\u53d1\u751f\u4e86\u663e\u8457\u7684\u7ea2\u79fb\uff0cDPBNA\u548cTPBNA\u7684\u5149\u5b66\u5e26\u9699\u66f4\u7a84\uff0c\u5206\u522b\u4e3a3.01 eV\u548c2.93 eV\uff08BNA: 3.23 eV\uff09\uff0c\u5728\u8367\u5149\u5149\u8c31\u4e2d\u4e5f\u89c2\u5bdf\u5230\u4e86\u7c7b\u4f3c\u7684\u7ea2\u79fb\u8d8b\u52bf\uff08\u56fe3\uff09\u3002TPBNA\u548cDPBNA\u5747\u4e3a\u4f18\u5f02\u7684\u84dd\u5149\u53d1\u5c04\u6750\u6599\uff0c\u5206\u522b\u5177\u67090.87\u548c0.68\u7684\u9ad8\u8367\u5149\u91cf\u5b50\u6548\u7387\uff08PLQY\uff09\u3002\u6839\u636e\u7535\u5316\u5b66\u6d4b\u8bd5\u548c\u5149\u5b66\u5e26\u9699\u8fdb\u884c\u8ba1\u7b97\uff0cTPBNA\u548cDPBNA\u7684HOMO\u80fd\u7ea7\u5206\u522b\u4e3a\u20135.25 eV\u548c\u20135.28 eV\uff0cLUMO\u80fd\u7ea7\u5206\u522b\u4e3a\u20132.32 eV\u548c\u20132.27 eV\u3002\u8fd9\u8868\u660e\u5b83\u4eec\u662f\u5408\u9002\u7684<em>p<\/em>\u578b\u534a\u5bfc\u4f53\u6750\u6599\uff0c\u5177\u6709\u76f8\u8fd1\u7684\u7a7a\u7a74\u6ce8\u5165\u52bf\u5792\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235393\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-5.png\" alt=\"\" width=\"2641\" height=\"2606\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-5.png 2641w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-5-300x296.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-5-768x758.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-5-1024x1010.png 1024w\" sizes=\"(max-width: 2641px) 100vw, 2641px\" \/><\/p>\n<p>\u56fe4. TPBNA\uff08a-b\uff09\u548cDPBNA\uff08c-d\uff09\u7684\u5355\u6676\u7ed3\u6784\u4ee5\u53ca\u8f6c\u79fb\u79ef\u5206\u8ba1\u7b97\u7ed3\u679c<\/p>\n<p>\u901a\u8fc7\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\u53ef\u4ee5\u53d1\u73b0\uff08\u56fe4\uff09\uff0c\u7531\u4e8eTPBNA\u5206\u5b50\u5916\u56f4\u56db\u4e2a\u82ef\u57fa\u7684\u4f4d\u963b\u6548\u5e94\uff0c\u5176\u4e0eBNA\u9aa8\u67b6\u4e4b\u95f4\u7684\u626d\u8f6c\u89d2\u8fbe\u523047.41\u00b0\u548c35.20\u00b0\u3002\u540c\u65f6\u6cbf\u7740<em>b<\/em>\u8f74\u65b9\u5411\u4e0a\uff0c\u5728C\u2013H\u00b7\u00b7\u00b7\u03c0\u76f8\u4e92\u4f5c\u7528\u4e0b\u76f8\u90bb\u4e24\u4e2aTPBNA\u5206\u5b50\u4ee5\u5c42\u72b6\u5806\u79ef\u7684\u65b9\u5f0f\u6392\u5217\uff0c\u5c42\u95f4\u8ddd\u4e3a3.97 \u00c5\uff0c\u8fd9\u5bfc\u81f4\u4e86\u5176\u6cbf\u7740<em>b<\/em>\u8f74\u65b9\u5411\u4e0a\u5177\u6709\u66f4\u5f3a\u7684\u7535\u5b50\u8026\u5408\uff08\u8f6c\u79fb\u79ef\u5206\uff0c<em>t<\/em>\uff09\uff0c\u800c\u5728\u5176\u4ed6\u65b9\u5411\u4e0a<em>t<\/em>\u503c\u5f88\u5c0f\u3002\u901a\u8fc7\u201c\u8fb9\u7f18\u5de5\u7a0b\u201d\u7684\u7b56\u7565\uff0c\u4f5c\u8005\u51cf\u5c11\u4e86TPBNA\u5916\u56f4\u7684\u82ef\u57fa\u53d6\u4ee3\u57fa\u6570\u91cf\uff0c\u6240\u5f97\u7684DPBNA\u5177\u6709\u66f4\u597d\u7684\u5e73\u9762\u6027\uff0c\u626d\u8f6c\u89d2\u51cf\u5c0f\u523010.45\u00b0\u548c7.68\u00b0\u3002\u5728\u591a\u91cd\u7684C\u2013H\u00b7\u00b7\u00b7\u03c0\u76f8\u4e92\u4f5c\u7528\u4e0b\uff0c\u76f8\u90bb\u4e24\u4e2aDPBNA\u5206\u5b50\u8868\u73b0\u51fa\u5178\u578b\u7684\u9c7c\u9aa8\u72b6\u5806\u79ef\uff0c\u8fd9\u6709\u5229\u4e8e\u7535\u8377\u6cbf\u7740\u4e8c\u7ef4\u65b9\u5411\u4f20\u8f93\uff0c\u540c\u65f6\u7406\u8bba\u8ba1\u7b97\u4e5f\u663e\u793a\u5176\u5728\u4e24\u4e2a\u65b9\u5411\u4e0a\u5747\u5177\u6709\u8f83\u5927\u7684<em>t<\/em>\u503c\uff0c\u8fd9\u610f\u5473\u7740DPBNA\u6709\u671b\u6210\u4e3a\u9ad8\u8fc1\u79fb\u7387\u534a\u5bfc\u4f53\u6750\u6599\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235394\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-6.png\" alt=\"\" width=\"2639\" height=\"3270\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-6.png 2639w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-6-242x300.png 242w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-6-768x952.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u7247-6-826x1024.png 826w\" sizes=\"(max-width: 2639px) 100vw, 2639px\" \/><\/p>\n<p>\u56fe5. DPBNA\u5355\u6676\u5f62\u8c8c\u3001\u7ed3\u6784\u8868\u5f81\u4ee5\u53caOFET\u5668\u4ef6\u6027\u80fd<\/p>\n<p>\u4e3a\u4e86\u8bc4\u4f30TPBNA\u548cDPBNA\u7684\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\uff0c\u4f5c\u8005\u901a\u8fc7\u7269\u7406\u6c14\u76f8\u6c89\u79ef\u6cd5\uff08PVT\uff09\u751f\u957f\u4e86\u5355\u6676\u5e76\u6784\u7b51\u4e86\u5e95\u6805-\u9876\u63a5\u89e6\u578bOFET\u5668\u4ef6\u3002TPBNA\u6676\u4f53\u4e3a\u4e0d\u89c4\u5219\u7684\u5e26\u72b6\u5f62\u8c8c\uff0c\u5176\u8868\u73b0\u51fa\u5178\u578b\u7684<em>p<\/em>\u578b\u534a\u5bfc\u4f53\u4f20\u8f93\u6027\u8d28\uff0c\u6700\u5927\u8fc1\u79fb\u7387\u4ec5\u4e3a1.85 \u00d7 10<sup>-3<\/sup>\u00a0cm<sup>2<\/sup>\u00a0V<sup>-1<\/sup>\u00a0s<sup>-1<\/sup>\u3002\u800cDPBNA\u5219\u53ef\u4ee5\u751f\u957f\u4e3a\u89c4\u5219\u7684\u4e8c\u7ef4\u516d\u8fb9\u5f62\u6676\u4f53\uff0c\u7ed3\u5408\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u4ee5\u53ca\u9009\u533a\u7535\u5b50\u884d\u5c04\u53ef\u4ee5\u786e\u5b9a\u6676\u4f53\u4e2d\u5206\u5b50\u7684\u6392\u5217\u7ed3\u6784\uff08\u56fe5\uff09\u3002DPBNA\u7684\u5355\u6676\u5668\u4ef6\u8868\u73b0\u51fa\u7535\u8377\u4f20\u8f93\u7684\u5404\u5411\u5f02\u6027\uff1a\u6cbf\u7740<em>a<\/em>\u8f74\u65b9\u5411\uff0c\u6700\u5927\u8fc1\u79fb\u7387\u4e3a0.73 cm<sup>2<\/sup>\u00a0V<sup>-1<\/sup>\u00a0s<sup>-1<\/sup>\uff0c\u5e73\u5747\u8fc1\u79fb\u7387\u4e3a0.34 cm<sup>2<\/sup>\u00a0V<sup>-1<\/sup>\u00a0s<sup>-1<\/sup>\uff1b\u800c\u6cbf\u7740<em>b<\/em>\u8f74\uff0c\u6700\u5927\u8fc1\u79fb\u7387\u4e3a1.3 cm<sup>2<\/sup>\u00a0V<sup>-1<\/sup>\u00a0s<sup>-1<\/sup>\uff0c\u5e73\u5747\u8fc1\u79fb\u7387\u4e3a0.56 cm<sup>2<\/sup>\u00a0V<sup>-1<\/sup>\u00a0s<sup>-1<\/sup>\u3002\u8fd9\u8868\u660e<em>b<\/em>\u8f74\u662fDPBNA\u5355\u6676\u4e2d\u7684\u6700\u4f18\u7535\u8377\u4f20\u8f93\u65b9\u5411\uff0c\u8fd9\u4e0e\u8f6c\u79fb\u79ef\u5206\u8ba1\u7b97\u5f97\u51fa\u7684\u7ed3\u8bba\u4e00\u81f4\u3002\u56e0\u6b64\uff0c\u5f97\u76ca\u4e8e\u5206\u5b50\u95f4\u5f3a\u7684\u7535\u5b50\u8026\u5408\u4ee5\u53ca\u5236\u5907\u7684\u9ad8\u8d28\u91cf\u5355\u6676\uff0cDPBNA\u8868\u73b0\u51fa\u7684\u8fc1\u79fb\u7387\u8fdc\u8fdc\u9ad8\u4e8eTPBNA\uff0c\u5e76\u9996\u6b21\u8d85\u8fc7\u4e861 cm<sup>2<\/sup>\u00a0V<sup>-1<\/sup>\u00a0s<sup>-1<\/sup>\uff0c\u8fd9\u4e5f\u662f\u76ee\u524d\u62a5\u9053\u7684\u8fc1\u79fb\u7387\u6700\u9ad8\u7684BN-PAH\u5206\u5b50\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235397\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72472.png\" alt=\"\" width=\"2640\" height=\"2215\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72472.png 2640w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72472-300x252.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72472-768x644.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72472-1024x859.png 1024w\" sizes=\"(max-width: 2640px) 100vw, 2640px\" \/><\/p>\n<p>\u56fe6. \u57fa\u4e8eDPBNA\u7684\u6709\u673a\u5149\u6676\u4f53\u7ba1\u5668\u4ef6\u6027\u80fd<\/p>\n<p>\u6700\u540e\uff0c\u57fa\u4e8eDPBNA\u51fa\u8272\u7684\u7535\u8377\u4f20\u8f93\u6027\u8d28\uff0c\u4f5c\u8005\u5236\u5907\u4e86\u57fa\u4e8eDPBNA\u5355\u6676\u7684\u5149\u6676\u4f53\u7ba1\u5668\u4ef6\uff08phototransistor\uff09\u3002\u5728405 nm\u7684\u5149\u7167\u5c04\u4e0b\uff0cDPBNA\u663e\u793a\u51fa\u4f18\u5f02\u7684\u5149\u63a2\u6d4b\u6027\u8d28\uff08\u56fe6\uff09\u3002\u901a\u8fc7\u6539\u53d8\u6805\u538b\u548c\u5149\u7167\u5f3a\u5ea6\uff0c\u5668\u4ef6\u8868\u73b0\u51fa\u53ef\u63a7\u7684\u5149\u54cd\u5e94\u6027\u80fd\uff0c\u5176<em>R<\/em><sub>max<\/sub>\uff0c<em>P<\/em><sub>max<\/sub>\uff0c\u548c<em>D<\/em>*<sub>max<\/sub>\u5206\u522b\u8fbe\u52304.3 \u00d7 10<sup>4<\/sup>\u00a0A W<sup>-1<\/sup>\uff0c6.3 \u00d7 10<sup>8<\/sup>\uff0c1.7 \u00d7 10<sup>15<\/sup>\u00a0Jones\uff0c\u8fd9\u662f\u76ee\u524d\u62a5\u9053\u7684\u6027\u80fd\u6700\u4f18\u5f02\u7684\u6709\u673a\u5149\u6676\u4f53\u7ba1\u4e4b\u4e00\uff0c\u5e76\u4e14\u4f18\u4e8e\u57fa\u4e8e\u975e\u6676\u7845\u7684\u5149\u6676\u4f53\u7ba1\u5668\u4ef6\uff08<em>R<\/em>\uff1a300 A W<sup>-1<\/sup>\uff09\u3002\u5728\u76f8\u540c\u7684\u5668\u4ef6\u52a0\u5de5\u4e0e\u6d4b\u8bd5\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u4e5f\u5c06DPBNA\u4e0e\u5176\u5bf9\u5e94\u7684\u78b3\u9aa8\u67b62,6-\u4e8c\u82ef\u57fa\u84bd\uff08DPA\uff09\u7684\u5668\u4ef6\u6027\u80fd\u8fdb\u884c\u4e86\u5bf9\u6bd4\u3002\u5c3d\u7ba1DPBNA\u7684\u8fc1\u79fb\u7387\u7565\u4f4e\uff0c\u5374\u8868\u73b0\u51fa\u76f8\u5f53\u7684\u5149\u63a2\u6d4b\u6027\u8d28\uff0c\u8fd9\u8868\u660eBN\u5355\u5143\u7684\u5f15\u5165\u6709\u53ef\u80fd\u5728\u6291\u5236\u7535\u8377\u590d\u5408\u7b49\u65b9\u9762\u4e2d\u5177\u6709\u6f5c\u5728\u7684\u4f18\u52bf\uff0c\u503c\u5f97\u672a\u6765\u8fdb\u4e00\u6b65\u6df1\u5165\u7814\u7a76\u3002<\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u201c\u8fb9\u7f18\u5de5\u7a0b\u201d\uff0c\u9996\u6b21\u5b9e\u73b0\u4e86\u57fa\u4e8eBN-PAHs\u7684\u9ad8\u8fc1\u79fb\u7387OFET\u5668\u4ef6\u3002DPBNA\u7684\u8fc1\u79fb\u7387\u9ad8\u8fbe1.3 cm<sup>2<\/sup>\u00a0V<sup>-1<\/sup>\u00a0s<sup>-1<\/sup>\uff0c\u662f\u76ee\u524d\u62a5\u9053\u7684BN-PAHs\u4e2d\u7684\u6700\u9ad8\u503c\uff0c\u5e76\u9996\u6b21\u8d85\u8fc7\u4e86\u975e\u6676\u7845\uff080.5 ~ 1 cm<sup>2<\/sup>\u00a0V<sup>-1<\/sup>\u00a0s<sup>-1<\/sup>\uff09\uff0c\u662f\u7b2c\u4e00\u4f8b\u53ef\u4ee5\u8dfb\u8eab\u9ad8\u8fc1\u79fb\u7387\u6709\u673a\u534a\u5bfc\u4f53\u884c\u5217\u7684BN-PAH\u5206\u5b50\uff08\u56fe7\uff09\u3002\u6b64\u5916\uff0c\u57fa\u4e8eDPBNA\u5355\u6676\u7684\u5149\u6676\u4f53\u7ba1\u5668\u4ef6\u5728405 nm\u5149\u7167\u4e0b\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5149\u63a2\u6d4b\u6027\u80fd\uff0c\u8fdb\u4e00\u6b65\u62d3\u5c55\u4e86BN-PAHs\u5728\u5149\u7535\u5668\u4ef6\u9886\u57df\u7684\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u57fa\u4e8e\u4e30\u5bcc\u7684BN-PAHs\u9aa8\u67b6\uff0c\u201c\u8fb9\u7f18\u5de5\u7a0b\u201d\u7b56\u7565\u5c06\u5bf9\u4ece\u4e2d\u5f00\u53d1\u9ad8\u6027\u80fd\u6709\u673a\u5149\u7535\u6750\u6599\u8d77\u5230\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u8be5\u5de5\u4f5c\u5c06\u8fdb\u4e00\u6b65\u4fc3\u8fdb\u787c\u6c2e\u6742\u7a20\u73af\u82b3\u70c3\u6750\u6599\u7684\u53d1\u5c55\uff0c\u4e3a\u672a\u6765\u5f00\u53d1\u9ad8\u6027\u80fd\u3001\u591a\u529f\u80fd\u7684\u6709\u673a\u5149\u7535\u6750\u6599\u4e0e\u5668\u4ef6\u63d0\u4f9b\u65b0\u7684\u673a\u9047\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235398\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72473.png\" alt=\"\" width=\"2640\" height=\"1311\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72473.png 2640w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72473-300x149.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72473-768x381.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72473-1024x509.png 1024w\" sizes=\"(max-width: 2640px) 100vw, 2640px\" \/><\/p>\n<p>\u56fe7. \u672c\u6587\u5de5\u4f5c\u6982\u89c8<\/p>\n<p><strong>\u3010\u56db\u3001\u6587\u7ae0\u4fe1\u606f\u3011<\/strong><\/p>\n<p>\u8be5\u5de5\u4f5c\u8fd1\u671f\u53d1\u8868\u5728<strong><em><b>Angew. Chem. Int. Ed.<\/b><\/em><\/strong>\u4e0a\uff0c<strong>\u7b2c\u4e00\u4f5c\u8005<\/strong>\u4e3a\u5357\u5f00\u5927\u5b66\u535a\u58eb\u7814\u7a76\u751f<strong>\u674e\u742c\u5349<\/strong>\u548c\u7855\u58eb\u7814\u7a76\u751f<strong>\u675c\u5448\u5353<\/strong>\uff0c<strong>\u901a\u8baf\u4f5c\u8005<\/strong>\u4e3a<strong>\u738b\u5c0f\u91ce\u7814\u7a76\u5458<\/strong>\u3002\u5408\u4f5c\u8005\u5305\u62ec\u5317\u4eac\u5927\u5b66\u88f4\u575a\u6559\u6388\u3001\u738b\u5a55\u59a4\u526f\u6559\u6388\u3001\u59da\u6cfd\u51e1\u535a\u58eb\u4ee5\u53ca\u5929\u6d25\u5927\u5b66\u80e1\u6587\u5e73\u6559\u6388\u3002<\/p>\n<p>\u539f\u6587\u4fe1\u606f\uff1aBN-Anthracene for High-Mobility Organic Optoelectronic Materials through Periphery Engineering<\/p>\n<p>Wanhui Li,<sup>\u2020<\/sup>\u00a0Cheng-Zhuo Du,<sup>\u2020<\/sup>\u00a0Xing-Yu Chen, Lin Fu, Rong-Rong Gao, Ze-Fan Yao, Jie-Yu Wang, Wenping Hu, Jian Pei, and Xiao-Ye Wang*<\/p>\n<p><em><i>Angew. Chem. Int. Ed.<\/i><\/em>, <strong><b>2022<\/b><\/strong>, DOI:\u00a010.1002\/anie.202201464<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202201464\"><u>https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202201464<\/u><\/a><\/p>\n<p><strong>\u4e94\u3001\u3010\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-235399\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72474.png\" alt=\"\" width=\"206\" height=\"274\" \/><\/b><\/strong><\/p>\n<p>\u738b\u5c0f\u91ce\uff0c\u5357\u5f00\u5927\u5b66\u5316\u5b66\u5b66\u9662\u7279\u8058\u7814\u7a76\u5458\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u3001\u72ec\u7acb\u8bfe\u9898\u7ec4\u7ec4\u957f\uff08PI\uff09\u30022009\u5e74\u672c\u79d1\u6bd5\u4e1a\u4e8e\u5357\u5f00\u5927\u5b66\uff1b2014\u5e74\u535a\u58eb\u6bd5\u4e1a\u4e8e\u5317\u4eac\u5927\u5b66\uff08\u5bfc\u5e08\uff1a\u88f4\u575a\u6559\u6388\uff09\uff1b2014\u81f32019\u5e74\u5728\u5fb7\u56fd\u9a6c\u666e\u9ad8\u5206\u5b50\u6240\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\uff08\u5bfc\u5e08\uff1a\u5fb7\u56fd\u53ca\u6b27\u6d32\u79d1\u5b66\u9662\u9662\u58ebKlaus M\u00fcllen\u6559\u6388\uff09\u30022019\u5e74\u52a0\u5165\u5357\u5f00\u5927\u5b66\u5316\u5b66\u5b66\u9662\uff0c\u4f9d\u6258\u5143\u7d20\u6709\u673a\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u72ec\u7acb\u5f00\u5c55\u7814\u7a76\u5de5\u4f5c\u3002\u957f\u671f\u4ece\u4e8b\u6709\u673a\u5171\u8f6d\u5206\u5b50\u6750\u6599\u7684\u8bbe\u8ba1\u5408\u6210\u53ca\u529f\u80fd\u5668\u4ef6\u7814\u7a76\uff0c\u5df2\u5728\u56fd\u9645\u9ad8\u6c34\u5e73\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u658760\u4f59\u7bc7\uff0c\u88ab\u5f15\u75284000\u4f59\u6b21\uff0c\u4ee5\u7b2c\u4e00\/\u901a\u8baf\u4f5c\u8005\u53d1\u8868\u8bba\u658730\u7bc7\uff0c\u5305\u62ec<em><i>Nat. Rev. Chem<\/i><\/em>.\uff081\u7bc7\uff09\u3001<em><i>Nat. Commun.<\/i><\/em>\uff083\u7bc7\uff09\u3001<em><i>J. Am. Chem. Soc.<\/i><\/em>\uff088\u7bc7\uff09\u3001<em><i>Angew. Chem. Int. Ed.<\/i><\/em>\uff084\u7bc7\uff09\u3001<em><i>Acc. Chem. Res.<\/i><\/em>\uff081\u7bc7\uff09\u7b49\u3002<\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u7a20\u73af\u82b3\u70c3\uff08PAHs\uff09\u5728\u6709\u673a\u5149\u7535\u6750\u6599\u7684\u53d1\u5c55\u4e2d\u626e\u6f14\u7740\u91cd\u8981\u89d2\u8272\u3002\u5728\u7a20\u73af\u82b3\u70c3\u9aa8\u67b6\u4e2d\u5f15\u5165\u6742\u539f\u5b50\u4e3a\u6784\u7b51\u65b0\u578b\u6709\u673a\u5149\u7535\u6750\u6599\u5e26\u6765\u4e86\u65b0\u7684\u53d1\u5c55\u5951\u673a\u3002\u8fd1\u5e74\u6765\uff0c\u4eba\u4eec\u901a\u8fc7\u4ee5B&#8230;<\/p>\n","protected":false},"author":35234,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-235389","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/235389"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/35234"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=235389"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/235389\/revisions"}],"predecessor-version":[{"id":235403,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/235389\/revisions\/235403"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=235389"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=235389"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=235389"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}