{"id":235660,"date":"2022-04-12T06:09:57","date_gmt":"2022-04-11T22:09:57","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=235660"},"modified":"2022-04-11T16:15:43","modified_gmt":"2022-04-11T08:15:43","slug":"%e5%8d%97%e5%bc%80%e5%a4%a7%e5%ad%a6nature-reviews-chemistry%ef%bc%9a%e9%87%91%e5%b1%9e-%e6%9c%89%e6%9c%ba%e7%ac%bc%e7%9a%84%e5%90%8e%e4%bf%ae%e9%a5%b0%e5%90%88%e6%88%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=235660","title":{"rendered":"\u5357\u5f00\u5927\u5b66Nat. Rev. Chem.\uff1a\u91d1\u5c5e-\u6709\u673a\u7b3c\u7684\u540e\u4fee\u9970\u5408\u6210"},"content":{"rendered":"

\u5bfc\u8bfb<\/strong><\/p>\n

\u91d1\u5c5e-\u6709\u673a\u7b3c (Metal\u2013organic cages, MOCs)\u662f\u7531\u91d1\u5c5e\u79bb\u5b50\/\u7c07\u548c\u6709\u673a\u914d\u4f53\u7ec4\u6210\u7684\u79bb\u6563\u7b3c\u72b6\u5206\u5b50\uff0c\u662f\u8d85\u5206\u5b50\u7b3c\u7684\u4e00\u4e2a\u7279\u6b8a\u5206\u652f\u3002MOCs\u7684\u8bbe\u8ba1\u3001\u5408\u6210\u4ee5\u53ca\u529f\u80fd\u5f00\u53d1\uff0c\u662f\u5f53\u524d\u5316\u5b66\u9886\u57df\u7684\u7814\u7a76\u524d\u6cbf\u3002\u9664\u4e86\u6e05\u6670\u660e\u786e\u7684\u6676\u4f53\u7ed3\u6784\u3001\u53ef\u8c03\u8282\u7684\u7a7a\u8154\u4ee5\u53ca\u53ef\u4fee\u9970\u5404\u79cd\u5b98\u80fd\u56e2\u7684\u7279\u6027\uff0cMOCs\u8fd8\u5177\u6709\u6eb6\u89e3\u7279\u6027\uff08\u6eb6\u89e3\u540e\u7b3c\u72b6\u7ed3\u6784\u53ef\u7a33\u5b9a\u5b58\u5728\uff09\uff0c\u4f7f\u5176\u53ef\u4ee5\u8fdb\u884c\u540e\u5408\u6210\u4fee\u9970(post-synthetic modifications, PSMs)\uff0c\u4ece\u800c\u83b7\u5f97\u76f4\u63a5\u5408\u6210\u65e0\u6cd5\u83b7\u5f97\u7684\u65b0\u6750\u6599\u4ee5\u53ca\u65b0\u529f\u80fd\u3002<\/p>\n

\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u5f20\u632f\u6770<\/strong>\u3001<\/strong>\u9648\u7476\uff08\u5171\u540c\u901a\u8baf\uff09\uff0c\u5728<\/strong>Nature Reviews Chemistry<\/em><\/strong>\u4e0a\u53d1\u8868\u7efc\u8ff0\u6587\u7ae0<\/strong>\uff0c\u9898\u4e3a\u201cPost-synthetic modifications of metal\u2013organic cages\u201d\u3002\u63a2\u8ba8\u4e86\u76ee\u524d\u7528\u4e8e\u91d1\u5c5e-\u6709\u673a\u7b3cMOCs\u7684PSM\u7b56\u7565\uff0c\u5305\u62ec\u5171\u4ef7\u3001\u914d\u4f4d\u548c\u975e\u5171\u4ef7\u65b9\u6cd5\u3002\u4f5c\u8005\u8be6\u7ec6\u63cf\u8ff0\u4e86\u65b0\u5f15\u5165\u7684\u5b98\u80fd\u56e2\u6216\u7ec4\u88c5\u6210\u7684\u591a\u7ef4\u6750\u6599\u7684\u4f18\u52bf\uff0c\u4f8b\u5982\u63d0\u9ad8\u7ed3\u6784\u7a33\u5b9a\u6027\u6216\u8d4b\u4e88\u6240\u9700\u529f\u80fd\u6027\u7b49\uff0c\u8fd9\u4e9b\u7b56\u7565\u4e3aMOCs\u7684\u53d1\u5c55\u63d0\u4f9b\u4e86\u65b0\u52a8\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u6838\u5fc3\u521b\u65b0\u70b9\uff1a<\/strong><\/p>\n

    \n
  1. \u63a2\u8ba8\u4e86\u5f53\u524d\u7528\u4e8eMOCs\u7684PSM\u7b56\u7565\uff0c\u5305\u62ec\u5171\u4ef7\u3001\u914d\u4f4d\u548c\u975e\u5171\u4ef7\u65b9\u6cd5\u3002<\/li>\n
  2. \u4f5c\u8005\u8be6\u7ec6\u4ecb\u7ecd\u4e86\u65b0\u5f15\u5165\u7684\u5b98\u80fd\u56e2\u6216\u7ec4\u88c5\u6210\u7684\u591a\u7ef4\u6750\u6599\u7684\u4f18\u52bf\u3002<\/li>\n<\/ol>\n

    \u6570\u636e\u6982\u89c8<\/strong><\/p>\n

    \u56fe1\uff1a\u91d1\u5c5e-\u6709\u673a\u7b3c\u540e\u5408\u6210\u4fee\u9970\u7684\u65f6\u5e8f\u53d1\u5c55\u4e0e\u4ee3\u8868\u6027\u5b9e\u4f8b\u00a92022 Springer Nature Limited<\/p>\n

    \"\"<\/p>\n

    \u56fe2\uff1a\u91d1\u5c5e-\u6709\u673a\u7b3c\u7684\u540e\u5408\u6210\u4fee\u9970\u7b56\u7565\u548c\u5e94\u7528\u00a92022 Springer Nature Limited<\/p>\n

    \"\"<\/p>\n

    MOCs\u7684PSM\u8fc7\u7a0b\u53ef\u5206\u4e3a\u4e09\u7c7b\uff1a\u96f6\u7ef4\uff080D\uff09\u7b3c\u5230\u96f6\u7ef4\u7b3c\uff1b\u96f6\u7ef4\u7b3c\u5230\u4e00\u7ef4\uff081D\uff09\u6216\u4e8c\u7ef4\uff082D\uff09\u7ed3\u6784\uff1b\u96f6\u7ef4\u7b3c\u5230\u4e09\u7ef4\uff083D\uff09\u7f51\u7edc\u7ed3\u6784\u3002\u6b64\u5916\uff0cMOCs\u7684PSM\u8fd8\u53ef\u4ee5\u6839\u636ePSM\u8fc7\u7a0b\u4e2d\u5f62\u6210\u7684\u5316\u5b66\u952e\u6216\u76f8\u4e92\u4f5c\u7528\u7684\u7c7b\u578b\u8fdb\u884c\u5212\u5206\uff0c\u5305\u62ec\u5171\u4ef7\u952e\u3001\u914d\u4f4d\u952e\u548c\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n

    \u56fe3\uff1a\u901a\u8fc7\u5171\u4ef7\u7b56\u7565\u4ece0D\u7b3c\u52300D\u7b3c\u7684\u5408\u6210\u540e\u4fee\u9970\u00a92022 Springer Nature Limited<\/p>\n

    \"\"<\/p>\n

    \u5bf9\u4e8e\u96f6\u7ef4MOCs\u5230\u96f6\u7ef4MOCs\u7684\u8f6c\u6362\uff0cMOCs\u5728\u4fee\u9970\u4e4b\u540e\u4ecd\u4fdd\u6301\u5176\u79bb\u6563\u7ed3\u6784\u3002\u8fd9\u79cd\u4fee\u9970\u53ef\u4ee5\u8fdb\u4e00\u6b65\u5206\u4e3a\u5171\u4ef7\u7b56\u7565\u3001\u914d\u4f4d\u7b56\u7565\u6216\u975e\u5171\u4ef7\u7b56\u7565\u3002\u901a\u5e38\u8fd9\u7c7b\u540e\u4fee\u9970\u53ef\u4ee5\u63d0\u4f9b\u4ee5\u4e0b\u4e00\u4e2a\u6216\u591a\u4e2a\u4f18\u52bf\uff1a\u5f15\u5165\u65b0\u7684\u5b98\u80fd\u56e2\uff1b\u4fdd\u62a4\u6d3b\u6027\u57fa\u56e2\uff1b\u8c03\u6574MOCs\u7684\u7279\u6027\uff0c\u4f8b\u5982\u7a33\u5b9a\u6027\u3001\u6eb6\u89e3\u5ea6\u3001\u5b54\u9699\u5ea6\uff1b\u6539\u5584\u6750\u6599\u6027\u80fd\u7b49\u3002<\/p>\n

    \u56fe4\uff1a\u901a\u8fc7\u5171\u4ef7\u6216\u914d\u4f4d\u7b56\u7565\u4ece0D\u7b3c\u52300D\u7b3c\u7684\u540e\u5408\u6210\u4fee\u9970\u00a92022 Springer Nature Limited<\/p>\n

    \"\"<\/p>\n

    \u914d\u4f4d\u540e\u4fee\u9970\u7b56\u7565\u6709\u4e24\u79cd\u53cd\u5e94\u4f4d\u70b9\uff1a\u9876\u70b9\uff08\u91d1\u5c5e\u8282\u70b9\uff09\u6216\u8fb9\uff08\u914d\u4f4d\uff09\u3002<\/p>\n

    \u56fe5\uff1a\u4ece0D\u7b3c\u52300D\u7b3c\uff0c\u4ee5\u53ca\u4ece0D\u7b3c\u52301D\u62162D\u7ed3\u6784\u7684\u914d\u4f4d\u548c\u975e\u5171\u4ef7\u540e\u5408\u6210\u4fee\u9970\u00a92022 Springer Nature Limited<\/p>\n

    \"\"<\/p>\n

    \u5f53PSM\u8fc7\u7a0b\u4e2d\u52a0\u5165\u53cc\u9f7f\u6216\u591a\u9f7f\u7684\u6865\u8054\u914d\u4f53\u65f6\uff0cMOCs\u53ef\u4ee5\u901a\u8fc7\u914d\u4f4d\u8fde\u63a5\u3001\u5f62\u6210\u4e00\u7ef4\u6216\u4e8c\u7ef4\u7ed3\u6784\u3002\u6b64\u5916\uff0c\u975e\u5171\u4ef7\u952e\u7684\u5f62\u6210\u6216\u5468\u56f4\u73af\u5883\u7684\u53d8\u5316\u4e5f\u53ef\u4ee5\u9a71\u52a8\u7b3c\u7684\u7ed3\u6784\u8f6c\u53d8\u3002<\/p>\n

    \u56fe6\uff1a0D\u7b3c\u5171\u4ef7\u4ea4\u8054\u4ee5\u5f62\u62103D\u805a\u5408\u6750\u6599\u00a92022 Springer Nature Limited<\/p>\n

    \"\"<\/p>\n

    \u56fe7\uff1a\u901a\u8fc7\u914d\u4f4d\u4fee\u9970\u5c060D\u7b3c\u7ec4\u88c5\u62103D\u7f51\u7edc\u00a92022 Springer Nature Limited<\/p>\n

    \"\"<\/p>\n

    \u56fe8\uff1a\u901a\u8fc7\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u5c060D\u7b3c\u7ec4\u88c5\u62103D\u7ed3\u6784\u00a92022 Springer Nature Limited<\/p>\n

    \"\"<\/p>\n

    \u6210\u679c<\/strong>\u542f\u793a<\/strong><\/p>\n

    MOCs\u7684PSMs\u7814\u7a76\u662f\u4e00\u4e2a\u70ed\u95e8\u7814\u7a76\u9886\u57df\u3002\u672c\u6587\u4ece\u65b9\u6cd5\u8bba\u7684\u89d2\u5ea6\u5bf9MOCs\u7684PSMs\u8fdb\u884c\u4e86\u5206\u7c7b\uff0c\u5e76\u603b\u7ed3\u4e86\u4e00\u4e9b\u65b0\u5174\u7684\u5e94\u7528\u3002MOCs\u7684\u540e\u5408\u6210\u4fee\u9970\uff0c\u4ecd\u6709\u8bb8\u591a\u65b9\u9762\u6709\u5f85\u63a2\u7d22\u3002\u5982\u524d\u6240\u8ff0\uff0c\u5c06\u96f6\u7ef4\u7b3c\u8f6c\u5316\u4e3a\u4e09\u7ef4\u805a\u5408\u7269\u6750\u6599\uff0c\u901a\u5e38\u4f1a\u4ea7\u751f\u975e\u6676\u6001\u7c89\u672b\u6216\u51dd\u80f6\uff0c\u5176\u7ed3\u6784\u8868\u5f81\u4ecd\u662f\u4e00\u4e2a\u6311\u6218\u3002\u96f6\u7ef4\u7b3c\u8f6c\u5411\u4e00\u7ef4\/\u4e8c\u7ef4\u7ed3\u6784\u7684\u8f6c\u53d8\u4e5f\u5c11\u6709\u7814\u7a76\u3002\u672a\u6765\u7684\u7814\u7a76\u65b9\u5411\uff0c\u4f1a\u66f4\u4fa7\u91cd\u4e8e\u6269\u5927\u5176\u5e94\u7528\u8303\u56f4\uff0c\u5c24\u5176\u4f1a\u8003\u8651\u5bf9\u6548\u7387\u3001\u73af\u5883\u548c\u6210\u672c\u7684\u5f71\u54cd\uff0c\u8bbe\u8ba1\u7eff\u8272\u3001\u9ad8\u6548\u548c\u5ec9\u4ef7\u7684\u5408\u6210\u8def\u7ebf\uff0c\u4f8b\u5982\uff0c\u4f7f\u7528\u5149\u548c\u6c22\u7b49\u7eff\u8272\u80fd\u6e90\uff0c\u5f00\u53d1\u6c14\u76f8\u5408\u6210\u540e\u4fee\u9970\uff0c\u6216\u901a\u8fc7\u53ef\u9006\u540e\u4fee\u9970\uff0c\u5b9e\u73b0\u201c\u667a\u80fd\u201dMOCs\u6750\u6599\u7b49\u3002\u603b\u4e4b\uff0cPSMs\u7684\u591a\u6837\u6027\uff0c\u53cd\u6620\u4e86MOCs\u53ef\u63d0\u4f9b\u7684\u591a\u79cd\u4fee\u9970\u4f4d\u70b9\uff08\u91d1\u5c5e\u7ed3\u70b9\u6216\u914d\u4f53\uff09\uff0c\u4ee5\u53ca\u591a\u79cd\u9014\u5f84\uff08\u5171\u4ef7\u952e\u3001\u914d\u4f4d\u952e\u6216\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528)\u3002MOCs\u7684PSMs\u4e30\u5bcc\u4e86\u65b0\u6750\u6599\u7684\u5236\u5907\u65b9\u6cd5\uff0c\u62d3\u5bbd\u4e86MOPs\u57fa\u6750\u6599\u7684\u5e94\u7528\u8303\u56f4\u3002\u672a\u6765\u7684\u7814\u7a76\u53ef\u4ee5\u66f4\u591a\u5730\u5173\u6ce8\u6027\u80fd\u4f18\u5316\u548c\u5b9e\u7528\u5f00\u53d1\u3002<\/p>\n

    \u6587\u732e\u94fe\u63a5\uff1aPost-synthetic modifications of metal\u2013organic cages<\/u><\/a>.\u00a02022,\u00a0Nature Reviews Chemistry<\/em>, DOI: 10.1038\/s41570-022-00380-y.<\/p>\n

    \u672c\u6587\u7531\u7eb3\u7c73\u5c0f\u767d\u4f9b\u7a3f<\/p>\n

    \u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n

    \u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"

    \u5bfc\u8bfb \u91d1\u5c5e-\u6709\u673a\u7b3c (Metal\u2013organic cages, MOCs)\u662f\u7531\u91d1\u5c5e\u79bb\u5b50\/\u7c07\u548c\u6709\u673a\u914d\u4f53\u7ec4\u6210\u7684\u79bb\u6563\u7b3c\u72b6\u5206\u5b50\uff0c\u662f\u8d85\u5206\u5b50\u7b3c\u7684\u4e00\u4e2a\u7279\u6b8a\u5206\u652f\u3002MOCs\u7684\u8bbe\u8ba1…<\/p>\n","protected":false},"author":31345,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-235660","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/235660"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/31345"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=235660"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/235660\/revisions"}],"predecessor-version":[{"id":235756,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/235660\/revisions\/235756"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=235660"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=235660"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=235660"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}