{"id":235787,"date":"2022-04-14T06:41:15","date_gmt":"2022-04-13T22:41:15","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=235787"},"modified":"2022-04-13T23:15:58","modified_gmt":"2022-04-13T15:15:58","slug":"snse-sns%e4%bd%93%e7%b3%bb%e7%9a%84%e5%a4%9a%e9%a2%86%e5%9f%9f%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=235787","title":{"rendered":"SnSe\/SnS\u4f53\u7cfb\u7684\u591a\u9886\u57df\u5e94\u7528"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235788\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72471-1.png\" alt=\"\" width=\"1144\" height=\"610\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72471-1.png 1144w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72471-1-300x160.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72471-1-768x410.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72471-1-1024x546.png 1024w\" sizes=\"(max-width: 1144px) 100vw, 1144px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u5218\u4e1c\u9510 \uff08\u5317\u822a2021\u7ea7\u7855\u58eb\u7814\u7a76\u751f\uff09<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u8d75\u7acb\u4e1c\uff0c\u79e6\u70b3\u8d85<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\uff0c\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662<\/p>\n<p>&nbsp;<\/p>\n<p>2022\u5e744\u67088\u65e5\uff0c<strong><em>Materials Lab<\/em><\/strong>\u671f\u520a\u5728\u7ebf\u53d1\u8868\u4e86\u5317\u822a\u6750\u6599\u5b66\u9662\u8d75\u7acb\u4e1c\u6559\u6388\u8bfe\u9898\u7ec4\u5173\u4e8e\u4e8c\u7ef4\u70ed\u7535\u6750\u6599SnSe\/SnS\u4f53\u7cfb\u7684\u6700\u65b0\u7814\u7a76\u7efc\u8ff0\u8bba\u6587\uff1aSnSe\/SnS: Multifunctions Beyond Thermoelectricity\uff0c\u603b\u7ed3\u4e86SnSe\/SnS\u4f53\u7cfb\u5728\u5305\u542b\u70ed\u7535\u9886\u57df\u5728\u5185\u7684\u5341\u4f59\u79cd\u591a\u5b66\u79d1\u4ea4\u53c9\u9886\u57df\u7684\u5e94\u7528\u548c\u7814\u7a76\u8fdb\u5c55\uff0c\u5e76\u5bf9\u8fd9\u4e00\u7c7b\u591a\u529f\u80fd\u6750\u6599\u672a\u6765\u7684\u53d1\u5c55\u65b9\u5411\u63d0\u51fa\u4e86\u89c4\u5212\u6027\u7684\u524d\u77bb\u3002<\/p>\n<p>SnSe\/SnS\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u7269\u7406\u8f93\u8fd0\u6027\u80fd\uff0c\u8fd1\u5e74\u6765\u5728\u70ed\u7535\u9886\u57df\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u540c\u65f6\uff0c\u72ec\u7279\u7684\u6676\u4f53\u7ed3\u6784\u4e5f\u786e\u4fdd\u4e86SnSe\/SnS\u80fd\u591f\u6ee1\u8db3\u529f\u80fd\u5668\u4ef6\u5c0f\u578b\u5316\u548c\u96c6\u6210\u5316\u7684\u8981\u6c42\uff0c\u8fd9\u4f7f\u5f97\u8fd9\u4e00\u7c7b\u6750\u6599\u6210\u4e3a\u591a\u9886\u57df\u4ea4\u53c9\u5b66\u79d1\u5e94\u7528\u548c\u7814\u7a76\u7684\u70ed\u70b9\u3002\u968f\u7740\u8584\u819c\u6750\u6599\u548c\u7eb3\u7c73\u6750\u6599\u5236\u5907\u6280\u672f\u7684\u53d1\u5c55\uff0cSnSe\/SnS\u5df2\u4e0d\u518d\u62d8\u6ce5\u4e8e\u70ed\u7535\u6750\u6599\u9886\u57df\uff0c\u5176\u9010\u6e10\u5728\u592a\u9633\u80fd\u7535\u6c60\u3001\u5149\u7535\u63a2\u6d4b\u5668\u3001\u5149\u50ac\u5316\u548c\u62d3\u6251\u7edd\u7f18\u4f53\u7b49\u9886\u57df\u53d1\u6325\u7740\u4f5c\u7528\uff0c\u8fd1\u5e74\u6765\u5df2\u6709\u591a\u4e2a\u91cd\u8981\u7684\u76f8\u5173\u7406\u8bba\u7814\u7a76\u548c\u5b9e\u9a8c\u8fdb\u5c55\uff0c\u672c\u7efc\u8ff0\u8bba\u6587\u5bf9\u8fd9\u4e9b\u8fdb\u5c55\u8fdb\u884c\u4e86\u5f52\u7eb3\u603b\u7ed3\u3002<\/p>\n<p>\u5728\u5ba4\u6e29\uff0cSnSe\/SnS\u5747\u4ee5<em><i>Pnma<\/i><\/em>\u7a7a\u95f4\u7fa4\u7684\u5c42\u72b6\u6b63\u4ea4\u7ed3\u6784\uff0c\u53ef\u89c6\u4e3a\u5ca9\u76d0\u76f8\u6c2f\u5316\u94a0\u7ed3\u6784\u7684\u4e00\u79cd\u53d8\u5f62\u3002\u5728600\u00a0K\u81f3800\u00a0K\u7684\u6e29\u5ea6\u8303\u56f4\u5185\uff0cSnSe\u7684\u6676\u4f53\u7ed3\u6784\u4ece<em><i>Pnma<\/i><\/em>\u7a7a\u95f4\u7fa4\uff08<strong>\u56fe1a<\/strong>\uff09\u53d1\u751f\u53ef\u6301\u7eed\u6027\u76f8\u53d8\u8fc7\u6e21\u5230<em><i>Cmcm<\/i><\/em>\u7a7a\u95f4\u7fa4\uff08<strong>\u56fe1b<\/strong>\uff09\uff0c\u6676\u683c\u5e38\u6570\u4ecea=11.49\u00c5\uff0cb=4.15\u00c5\uff0cc=4.44\u00c5\u53d8\u5316\u5230a=4.31\u00c5\uff0cb=11.71\u00c5\uff0cc=4.42\u00c5\u3002\u56e0\u6b64\uff0c<em><i>Cmcm<\/i><\/em>\u76f8\u7684\u6676\u4f53\u7ed3\u6784\u6bd4Pnma\u76f8\u5177\u6709\u66f4\u9ad8\u7684\u5bf9\u79f0\u6027\u3002\u6b64\u5916\uff0c\u6bcf\u4e2aSn\uff08Se\uff09\u539f\u5b50\u901a\u8fc7sp<sup>2<\/sup>\u8f68\u9053\u4e0e\u5176\u4ed6\u4e09\u4e2aSe\uff08Sn\uff09\u539f\u5b50\u7ed3\u5408\uff0cSn\u76845s<sup>2<\/sup>\u5b64\u5bf9\u7535\u5b50\u7acb\u4f53\u5730\u5b58\u5728\u4e8e\u56db\u4e2a\u8f83\u957f\u7684\u8303\u5fb7\u534e\u952e\u4e4b\u95f4\uff08<strong>\u56fe1c<\/strong>\uff09\u3002\u5728<strong>\u56fe1a<\/strong>\u4e2d\uff0c\u6bcf\u4e2aSn\u539f\u5b50\u901a\u8fc7\u5f3a\u5316\u5b66\u952e\u5728\u5e73\u9762\u5185\u65b9\u5411\u4e0e\u4e09\u4e2a\u76f8\u90bb\u7684Se\uff08S\uff09\u539f\u5b50\u76f8\u8fde\uff0c\u5176\u4ed6\u56db\u4e2aSe\uff08S\uff09\u539f\u5b50\u901a\u8fc7\u5f31\u8303\u5fb7\u534e\u529b\u76f8\u8fde\uff0c\u5176\u4e2d\u4e09\u4e2a\u5728\u5e73\u9762\u5916\u65b9\u5411\uff0c\u4e00\u4e2a\u5728\u5e73\u9762\u5185\u65b9\u5411\uff0c\u8fd9\u5bfc\u81f4\u4e86\u5404\u5411\u5f02\u6027\u548c\u5f3a\u975e\u8c10\u6027\u3002SnS\u5177\u6709\u4e0eSnSe\u76f8\u4f3c\u7684\u6676\u4f53\u7ed3\u6784\uff0c\u5373\u5ba4\u6e29\u4e0b\u4e3a<em><i>Pnma<\/i><\/em>\u76f8\uff0c\u9ad8\u6e29\u4e0b\u4e3a<em><i>Cmcm<\/i><\/em>\u76f8\u3002\u76f8\u4f3c\u7684\u6676\u4f53\u7ed3\u6784\u51b3\u5b9a\u4e86SnSe\u548cSnS\u5177\u6709\u76f8\u4f3c\u7684\u57fa\u672c\u8f93\u8fd0\u6027\u8d28\u3001\u80fd\u5e26\u7ed3\u6784\u548c\u5149\u5b66\u6027\u8d28\u3002\u00a0<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235789\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72472-2.png\" alt=\"\" width=\"1036\" height=\"425\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72472-2.png 1036w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72472-2-300x123.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72472-2-768x315.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72472-2-1024x420.png 1024w\" sizes=\"(max-width: 1036px) 100vw, 1036px\" \/><\/p>\n<p><strong><b>\u56fe1<\/b><\/strong>\u00a0SnSe\/SnS\u7684\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\uff0c\u7ea2\u8272\u4ee3\u8868Sn\u539f\u5b50\uff0c\u6a59\u8272\u4ee3\u8868Se\uff08S\uff09\u539f\u5b50\u3002(a)\u00a0<em><i>Pnma<\/i><\/em>\u76f8\u6cbfb\u8f74\u7684\u6676\u4f53\u7ed3\u6784\uff1b(b)\u00a0<em><i>Cmcm<\/i><\/em>\u76f8\u6cbfb\u8f74\u7684\u6676\u4f53\u7ed3\u6784\u3002(c)\u00a0SnSe<sub>7<\/sub>\/SnS<sub>7<\/sub>\u00a03D\u7ed3\u6784\uff0c\u865a\u7ebf\u4ee3\u8868\u5f31\u5171\u4ef7\u952e<sup>[<\/sup><sup>1]<\/sup>\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u4e00<\/strong><strong>. <\/strong><strong>\u70ed\u7535\u6027\u80fd<\/strong><\/p>\n<p>\u5728SnSe\/SnS\u6750\u6599\u53d1\u5c55\u521d\u671f\uff0c\u4eba\u4eec\u6ce8\u610f\u5230\u4e24\u79cd\u6750\u6599\u5177\u6709\u5f88\u9ad8\u7684\u5149\u5438\u6536\u7cfb\u6570\uff0c\u975e\u5e38\u9002\u5408\u4f5c\u4e3a\u592a\u9633\u80fd\u7535\u6c60\u7684\u5438\u6536\u5c42\u3002\u4f46\u662f\uff0c\u6750\u6599\u7684\u7535\u8f93\u8fd0\u6027\u8d28\uff0c\u5c24\u5176\u662f\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u4e5f\u662f\u5f71\u54cd\u529f\u80fd\u5668\u4ef6\u7684\u91cd\u8981\u53c2\u6570\u3002\u5728\u5ba4\u6e29300K\u65f6\uff0c\u672c\u5f81SnSe\u7684\u5bfc\u7535\u6027\u4ec5\u4e3a12 S cm<sup>\u2212<\/sup><sup>1<\/sup>\uff0c\u4e0d\u9002\u5408\u7528\u4e8e\u529f\u80fd\u5668\u4ef6\u3002SnSe\u7684\u540c\u65cf\u7c7b\u4f3c\u7269SnS\u4e5f\u5b58\u5728\u7c7b\u4f3c\u7684\u95ee\u9898\u3002\u8fd1\u5e74\u6765\uff0c\u5355\u6676\u4f53\u751f\u957f\u5de5\u827a\u7684\u53d1\u5c55\u6210\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\u7684\u5173\u952e\uff0c\u5236\u5907\u5f97\u5230\u7684\u6676\u4f53SnSe\/SnS\u9762\u5185\u65b9\u5411\u7684\u9ad8\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u6ee1\u8db3\u4e86\u6750\u6599\u4f5c\u4e3a\u529f\u80fd\u5668\u4ef6\u7ec4\u5143\u7684\u8981\u6c42\uff0c\u672c\u5f81\u7684SnSe\/SnS\u5355\u6676\u4f53\u6750\u6599\u5df2\u7ecf\u5177\u5907\u4e86\u5341\u5206\u4f18\u5f02\u7684\u70ed\u7535\u6027\u80fd\u3002\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u8c03\u63a7\u8d39\u7c73\u80fd\u7ea7\u3001\u80fd\u5e26\u5de5\u7a0b\u3001\u5fae\u7ed3\u6784\u8c03\u63a7\u7b49\u7b56\u7565\u5bf9\u4e8eSnSe\/SnS\u4f53\u7cfb\u7684\u7535\u5b50\u548c\u58f0\u5b50\u8f93\u8fd0\u6027\u8d28\u5f00\u5c55\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u548c\u4f18\u5316\u30022014\u5e74\uff0cSnSe\u6676\u4f53\u88ab\u53d1\u73b0\u662f\u4e00\u79cd\u5177\u6709\u5f3a\u975e\u8c10\u6027\uff08\u56fe2a\uff09\u548c\u672c\u5f81\u4f4e\u70ed\u5bfc\u7387\u7684\u5177\u6709\u5f00\u53d1\u6f5c\u529b\u7684\u70ed\u7535\u6750\u6599\uff08<strong><em><b><i>Nature<\/i><\/b><\/em><\/strong>\u00a0508 (2014) 373\uff09\u30022016\u5e74\uff0c\u901a\u8fc7\u7a7a\u7a74\u63ba\u6742\u53ef\u4ee5\u6fc0\u6d3bP\u578bSnSe\u7684\u591a\u4ef7\u5e26\u8f93\u8fd0\uff08\u56fe2b\uff09\uff0c\u540c\u65f6\u63d0\u9ad8\u6e29\u5dee\u7535\u52a8\u52bf\u548c\u8f7d\u6d41\u5b50\u6d53\u5ea6\uff0c\u589e\u5f3a\u4e86\u6750\u6599\u7684\u5bbd\u6e29\u57df\u70ed\u7535\u6027\u80fd\uff08<strong><em><b><i>Science<\/i><\/b><\/em><\/strong>\u00a0351 (2016) 141\uff09\u30022021\u5e74\uff0c\u5229\u7528\u5176\u591a\u80fd\u5e26\u7ed3\u6784\u7279\u70b9\uff0c\u8fdb\u4e00\u6b65\u63d0\u51fa\u91c7\u7528\u534f\u540c\u8c03\u63a7\u52a8\u91cf\u7a7a\u95f4\u548c\u80fd\u91cf\u7a7a\u95f4\u7684\u591a\u4ef7\u5e26\u4f20\u8f93\u7b56\u7565\uff0c\u5b9e\u73b0\u4e86P\u578bSnSe\u6676\u4f53\u6027\u80fd\u7684\u5927\u5e45\u63d0\u5347\uff0c\u5728300 K\u65f6\u8fbe\u5230\u4e86~ 75 \u00b5W cm<sup>\u20131<\/sup>\u00a0K<sup>\u20132<\/sup>\u7684\u529f\u7387\u56e0\u5b50\u548c~1.2\u7684<em><i>Z<\/i><\/em><em><i>T<\/i><\/em>\u503c\uff0c\u5c55\u73b0\u4e86\u5bbd\u5e26\u9699SnSe\u6676\u4f53\u5728\u8fd1\u5ba4\u6e29\u533a\u57df\u7684\u53d1\u7535\u548c\u5236\u51b7\u80fd\u529b\uff08<strong><em><b><i>Science<\/i><\/b><\/em><\/strong>\u00a0373 (2021)\u00a06554\uff09\u3002N\u578b\u70ed\u7535\u6750\u6599\u6027\u80fd\u7684\u4f18\u5316\uff0c\u5bf9\u4e8e\u70ed\u7535\u5668\u4ef6\u6027\u80fd\u7684\u63d0\u5347\u540c\u6837\u91cd\u8981\u30022018\u5e74\uff0c\u7814\u7a76\u53d1\u73b0\u7535\u5b50\u63ba\u6742\u7684N\u578bSnSe\u5728\u9762\u5916\u65b9\u5411\u5177\u6709\u4f18\u5f02\u7684\u70ed\u7535\u6027\u80fd\uff0c\u5c55\u73b0\u4e86\u201c\u4e8c\u7ef4\u58f0\u5b50\/\u4e09\u7ef4\u7535\u8377\u201d\u7684\u4f20\u8f93\u7279\u6027\uff08<strong><em><b><i>Science<\/i><\/b><\/em><\/strong>\u00a0360 (2018) 778\uff09\u3002\u8fd1\u671f\uff0c\u901a\u8fc7\u8fdb\u4e00\u6b65\u5229\u7528SnSe\u7684\u5c42\u72b6\u7ed3\u6784\u89e3\u8026\u7535\u58f0\u4f20\u8f93\uff0cN\u578bSnSe\u6676\u4f53\u5728\u9762\u5916\u65b9\u5411\u8868\u73b0\u51fa\u66f4\u5927\u7684\u53d1\u5c55\u6f5c\u529b\uff08<strong><em><b><i>Science<\/i><\/b><\/em><\/strong>\u00a0375\u00a0(2022) 1385\uff09\u3002\u4f5c\u4e3aSnSe\u7684\u7c7b\u4f3c\u7269\uff0cSnS\u6676\u4f53\u7684\u70ed\u7535\u6027\u80fd\u968f\u540e\u5f15\u8d77\u4e86\u9ad8\u5ea6\u7684\u671f\u5f85\u3002\u901a\u8fc7\u5f15\u5165Se\u4fc3\u8fdb\u4e86SnS\u4e2d\u591a\u4e2a\u4ef7\u5e26\u968f\u6e29\u5ea6\u53d8\u5316\u7684\u6f14\u53d8\u8fc7\u7a0b\uff0c\u534f\u540c\u8c03\u63a7\u4e86\u6709\u6548\u8d28\u91cf\u548c\u8fc1\u79fb\u7387\u4e4b\u95f4\u7684\u77db\u76fe\u3002\u5728\u50a8\u91cf\u4e30\u5bcc\u3001\u6210\u672c\u4f4e\u5ec9\u3001\u73af\u5883\u53cb\u597d\u7684SnS\u6676\u4f53\u6750\u6599\u4e2d\u5b9e\u73b0\u4e86\u9ad8\u7684\u70ed\u7535\u6027\u80fd\uff08<strong><em><b><i>Science<\/i><\/b><\/em><\/strong>\u00a0365 (2019) 1418\uff09\u3002\u8fd1\u671f\u7684\u89c2\u70b9\u8bba\u6587\u603b\u7ed3\u4e86SnSe\u7531\u4e8e\u5728\u6676\u4f53\u3001\u7535\u5b50\u548c\u58f0\u5b50\u7ed3\u6784\u7684\u4e0d\u540c\u800c\u4ea7\u751f\u4e86N\u578b\u548cP\u578b\u5728\u6676\u4f53\u5b66\u65b9\u5411\u7684\u62e9\u4f18\u6027\u80fd(<strong><em>Science Bulletin<\/em><\/strong>\u00a0(2022), <a href=\"https:\/\/doi.org\/10.1016\/j.scib.2022.04.007\"><u>https:\/\/doi.org\/10.1016\/j.scib.2022.04.007<\/u><\/a>\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235790\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72473-2.png\" alt=\"\" width=\"1270\" height=\"587\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72473-2.png 1270w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72473-2-300x139.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72473-2-768x355.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72473-2-1024x473.png 1024w\" sizes=\"(max-width: 1270px) 100vw, 1270px\" \/><\/p>\n<p><strong><b>\u56fe2<\/b><\/strong>\u00a0\uff08a\uff09SnSe\u975e\u8c10\u6027\u793a\u610f\u56fe\uff1b\uff08b\uff09SnSe\u7684\u591a\u80fd\u5e26\u793a\u610f\u56fe\u3002<\/p>\n<p>\u5728\u8fd1\u5341\u5e74\u7684\u53d1\u5c55\u8fc7\u7a0b\u4e2d\uff0c\u7eff\u8272\u65e0\u6bd2\u7684SnSe\/SnS\u5df2\u7ecf\u5177\u5907\u4e86\u9762\u5185\u9ad8\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u3001\u53ef\u8c03\u8c10\u5e26\u9699\u548c\u9ad8\u5438\u6536\u7cfb\u6570\uff0c\u8fd9\u4e9b\u90fd\u662f\u591a\u529f\u80fd\u6750\u6599\u7684\u91cd\u8981\u7279\u6027\u3002\u968f\u7740\u7406\u8bba\u8ba1\u7b97\u548c\u5b9e\u9a8c\u7684\u6df1\u5165\u7814\u7a76\uff0cSnSe\/SnS\u4f53\u7cfb\u5728\u66f4\u591a\u7684\u5e94\u7528\u6f5c\u80fd\u4e5f\u5f97\u4ee5\u6316\u6398\u548c\u9a8c\u8bc1\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u4e8c<\/strong><strong>. <\/strong><strong>\u592a\u9633\u80fd\u7535\u6c60<\/strong><\/p>\n<p>\u592a\u9633\u80fd\u7535\u6c60\u662f\u4e00\u79cd\u5229\u7528\u592a\u9633\u80fd\u53d1\u7535\u7684\u534a\u5bfc\u4f53\u5668\u4ef6\uff0c\u901a\u8fc7\u5149\u4f0f\u6548\u5e94\u76f4\u63a5\u5c06\u5149\u8f6c\u5316\u4e3a\u7535\u80fd\u3002\u8fd1\u4e9b\u5e74\u6765\uff0c\u6ee1\u8db3\u4f4e\u6210\u672c\u3001\u9ad8\u6548\u7387\u548c\u7eff\u8272\u73af\u4fdd\u7684\u65b0\u4e00\u4ee3\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60\u6280\u672f\u8d8a\u6765\u8d8a\u53d7\u5230\u4eba\u4eec\u7684\u5173\u6ce8\u3002\u4e8c\u7ef4SnSe\/SnS\u8584\u819c\u56e0\u5176\u5236\u5907\u7b80\u5355\u3001\u73af\u4fdd\u3001\u65e0\u6bd2\u3001\u6210\u672c\u4f4e\u3001\u5149\u5b66\u548c\u7535\u5b66\u6027\u80fd\u4f18\u5f02\u7b49\u7279\u70b9\uff0c\u9010\u6e10\u6210\u4e3a\u592a\u9633\u80fd\u7535\u6c60\u5408\u9002\u7684\u5149\u5438\u6536\u6750\u6599\u3002\u6839\u636eShockley-Queisser\u51c6\u5219\uff0cSnSe\/SnS\u57fa\u592a\u9633\u80fd\u7535\u6c60\u7684\u6781\u9650\u6548\u7387\u5206\u522b\u8fbe\u523032%\u548c33%\u3002\u5728\u672a\u6765\u7684\u7814\u7a76\u4e2d\uff0c\u901a\u8fc7\u4f18\u5316\u8584\u819c\u6750\u6599\u7684\u5236\u5907\u65b9\u6cd5\u3001\u8c03\u8282\u590d\u5408\u6750\u6599\u7684\u6676\u683c\u5931\u914d\u4ee5\u53ca\u9009\u62e9\u5408\u9002\u7684N\u578b\u7f13\u51b2\u5c42\uff0c\u53ef\u4ee5\u9010\u6e10\u63a5\u8fd1SnSe\/SnS\u57fa\u592a\u9633\u80fd\u7535\u6c60\u7684\u7406\u8bba\u8f6c\u6362\u6548\u7387\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-235791 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72474-1.png\" alt=\"\" width=\"471\" height=\"507\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72474-1.png 471w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72474-1-279x300.png 279w\" sizes=\"(max-width: 471px) 100vw, 471px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe<\/b><\/strong><strong><b>3<\/b><\/strong>\u00a0SnSe\u57fa\u592a\u9633\u80fd\u7535\u6c60\u7684\u5668\u4ef6\u7ed3\u6784\u793a\u610f\u56fe\uff0cSnSe\u819c\u4e3a\u5438\u6536\u5c42\uff0cCdS\u4e3aN\u578b\u7f13\u51b2\u5c42<sup>[2<\/sup><sup>]<\/sup>\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u00a0<\/strong><strong>\u4e09<\/strong><strong>. <\/strong><strong>\u79bb\u5b50\u7535\u6c60<\/strong><\/p>\n<p>\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u548c\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIBs\uff09\u88ab\u8ba4\u4e3a\u662f\u66ff\u4ee3\u5316\u77f3\u80fd\u6e90\u7684\u7eff\u8272\u50a8\u80fd\u88c5\u7f6e\u3002\u5c3d\u7ba1\uff0cLIBs\u5df2\u7ecf\u5360\u636e\u4e86\u5f88\u5927\u7684\u5e02\u573a\u4efd\u989d\uff0c\u4f46\u4f4e\u6210\u672c\u7684SIBs\u6709\u7740\u66f4\u5927\u7684\u53d1\u5c55\u524d\u666f\u3002\u4e0eLIBs\u76f8\u6bd4\uff0c\u5faa\u73af\u6027\u80fd\u5dee\u548c\u7535\u8377\u5bb9\u91cf\u4e0d\u8db3\u662f\u9521\u57faSIBs\u9633\u6781\u6750\u6599\u7684\u81f4\u547d\u95ee\u9898\u3002\u4ee4\u4eba\u60ca\u8bb6\u7684\u662f\uff0c\u5177\u6709\u72ec\u7279\u7535\u5b50\u7279\u6027\u548c\u4e8c\u7ef4\u7ed3\u6784\u7684SnSe\/SnS\u57faSIBs\u7535\u6781\u53ef\u4ee5\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\uff0c\u5e76\u4e14\u7535\u6781\u5141\u8bb8\u50a8\u5b58\u66f4\u591a\u7684Na<sup>+<\/sup>\u3002\u56e0\u6b64\uff0c\u57fa\u4e8eSnSe\/SnS\u7684SIBs\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u9ad8\u529f\u7387\u5bc6\u5ea6\u548c\u4f18\u8d8a\u7684\u52a8\u529b\u5b66\u7279\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235792\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72475.png\" alt=\"\" width=\"284\" height=\"268\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>4<\/b><\/strong>\u00a0\u79bb\u5b50\u7535\u6c60\u4e2d\uff0cSnS-\u4e09\u7ef4\u6c2e\u63ba\u6742\u77f3\u58a8\u70ef\u590d\u5408\u9633\u6781\u6750\u6599\u7684\u7acb\u4f53\u793a\u610f\u56fe\uff0c\u5176\u4e2d\u6a59\u8272\u7403\u4f53\u4ee3\u8868SnS\uff0c\u7070\u8272\u5c42\u72b6\u7ed3\u6784\u4ee3\u8868\u4e09\u7ef4\u6c2e\u63ba\u6742\u77f3\u58a8\u70ef<sup>[3]<\/sup>\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56db<\/strong><strong>. <\/strong><strong>\u8d85\u7ea7\u7535\u5bb9\u5668<\/strong><\/p>\n<p>\u968f\u7740\u592a\u9633\u80fd\u7b49\u53ef\u518d\u751f\u80fd\u6e90\u7684\u53d1\u5c55\uff0c\u5f00\u53d1\u9ad8\u6548\u50a8\u80fd\u8bbe\u5907\u8feb\u5728\u7709\u776b\u3002\u8d85\u7ea7\u7535\u5bb9\u5668\u662f\u901a\u8fc7\u7535\u6781\u4e0e\u7535\u89e3\u8d28\u4e4b\u95f4\u5f62\u6210\u7684\u754c\u9762\u53cc\u5c42\u6765\u5b58\u50a8\u80fd\u91cf\u7684\u65b0\u578b\u5143\u5668\u4ef6\u3002\u4e0e\u79bb\u5b50\u7535\u6c60\u76f8\u6bd4\uff0c\u8d85\u7ea7\u7535\u5bb9\u5668\u5177\u6709\u66f4\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6\u548c\u66f4\u957f\u7684\u5faa\u73af\u5bff\u547d\u3002SnSe\/SnS\u56e0\u5176\u72ec\u7279\u7684\u7535\u5b50\u6027\u8d28\u548c\u6c27\u5316\u8fd8\u539f\u53ef\u9006\u6027\u9010\u6e10\u51fa\u73b0\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u9886\u57df\u3002\u5728\u63a5\u4e0b\u6765\u7684\u7814\u7a76\u4e2d\uff0c\u63d0\u9ad8\u7535\u5bb9\u5668\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u4fdd\u6301\u7535\u6781\u3001\u7535\u89e3\u8d28\u548c\u5668\u4ef6\u7cfb\u7edf\u4e4b\u95f4\u7684\u9ad8\u5ea6\u517c\u5bb9\u6027\u662f\u6838\u5fc3\u53d1\u5c55\u65b9\u5411\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-235793 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72476.png\" alt=\"\" width=\"462\" height=\"481\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72476.png 462w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72476-288x300.png 288w\" sizes=\"(max-width: 462px) 100vw, 462px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe<\/b><\/strong><strong><b>5<\/b><\/strong>\u00a03D\u591a\u5b54SnS-\u786b\u63ba\u6742\u77f3\u58a8\u70ef\u6742\u5316\u7eb3\u7c73\u7ed3\u6784\u793a\u610f\u56fe<sup>[4]<\/sup>\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u00a0<\/strong><strong>\u4e94<\/strong><strong>. <\/strong><strong>\u5fc6\u963b\u5668<\/strong><\/p>\n<p>\u5927\u91cf\u7814\u7a76\u8868\u660e\uff0c\u6839\u636e\u5fc6\u963b\u5668\u7684\u5de5\u4f5c\u539f\u7406\uff0c\u5176\u6700\u6709\u53ef\u80fd\u6210\u4e3a\u4eba\u5de5\u667a\u80fd\u7684\u6838\u5fc3\u7535\u5b50\u5143\u4ef6\u3002\u5fc6\u963b\u5668\u901a\u8fc7\u8fde\u7eed\u53ef\u8c03\u7684\u7535\u5bfc\u6a21\u62df\u4eba\u8111\u5b66\u4e60\u3001\u8bb0\u5fc6\u548c\u5904\u7406\u4fe1\u606f\u7684\u8fc7\u7a0b\uff0c\u4f46\u5176\u6838\u5fc3\u95ee\u9898\u662f\u5bfb\u627e\u80fd\u591f\u5b58\u50a8\u6d77\u91cf\u4fe1\u606f\u548c\u9ad8\u6548\u5904\u7406\u4fe1\u606f\u7684\u6750\u6599\u3002\u968f\u7740\u5bf9\u5fc6\u963b\u5668\u8fd0\u884c\u901f\u5ea6\u548c\u4fe1\u606f\u5b58\u50a8\u5bb9\u91cf\u8981\u6c42\u7684\u63d0\u9ad8\uff0c\u5668\u4ef6\u9010\u6e10\u5411\u5c0f\u578b\u5316\u548c\u96c6\u6210\u5316\u65b9\u5411\u53d1\u5c55\u3002\u5728\u5e73\u9762\u5916\u65b9\u5411\uff0c\u4e8c\u7ef4SnSe\/SnS\u7684\u5c42\u95f4\u7531\u51c6\u8303\u5fb7\u534e\u529b\u8fde\u63a5\u3002\u6839\u636e\u8fd9\u4e00\u7279\u6027\uff0c\u5f53\u51cf\u5c0f\u5668\u4ef6\u4f53\u79ef\u65f6\uff0c\u4e8c\u7ef4\u5fc6\u963b\u5668\u7684\u4f18\u826f\u6027\u80fd\u51e0\u4e4e\u4e0d\u4f1a\u53d7\u5230\u5f71\u54cd\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235794\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72477.png\" alt=\"\" width=\"646\" height=\"641\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72477.png 646w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72477-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72477-300x298.png 300w\" sizes=\"(max-width: 646px) 100vw, 646px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>6<\/b><\/strong>\u00a0\u5177\u5907\u540c\u65f6\u91ca\u653e\u5174\u594b\u6027\u548c\u6291\u5236\u6027\u795e\u7ecf\u9012\u8d28\u7684\u751f\u7269\u7a81\u89e6\u793a\u610f\u56fe<sup>[5]<\/sup>\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u00a0<\/strong><strong>\u516d<\/strong><strong>. <\/strong><strong>\u6c14\u4f53\u4f20\u611f\u5668<\/strong><\/p>\n<p>NO<sub>2<\/sub>\u548cSO<sub>2<\/sub>\u6392\u653e\u7684\u4e3b\u8981\u6765\u6e90\u662f\u5316\u77f3\u71c3\u6599\u71c3\u70e7\u3001\u6c7d\u8f66\u5c3e\u6c14\u548c\u5de5\u4e1a\u751f\u4ea7\uff0c\u4e0d\u4ec5\u5bf9\u81ea\u7136\u73af\u5883\u9020\u6210\u5de8\u5927\u5371\u5bb3\uff0c\u800c\u4e14\u5bf9\u4eba\u4f53\u547c\u5438\u7cfb\u7edf\u548c\u80be\u810f\u9020\u6210\u4e25\u91cd\u635f\u5bb3,\u7528\u4e8e\u68c0\u6d4bNO<sub>2<\/sub>\u548cSO<sub>2<\/sub>\u7684\u6c14\u4f53\u4f20\u611f\u5668\u662f\u4e00\u4e2a\u6311\u6218\u6027\u95ee\u9898\u3002\u4e8c\u7ef4SnSe\/SnS\u7531\u4e8e\u6bd4\u8868\u9762\u79ef\u5927\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u89e3\u51b3\u4e0a\u8ff0\u95ee\u9898\u3002\u6c14\u4f53\u5206\u5b50\uff08NO<sub>2<\/sub>\u3001SO<sub>2<\/sub>\u7b49\uff09\u53ef\u5438\u9644\u5728\u8584\u819c\u57fa\u5e95\u4e0a\uff0c\u5e76\u8f6c\u79fb\u7535\u5b50\u4ee5\u6539\u53d8\u80fd\u5e26\u7ed3\u6784\uff0c\u4ece\u800c\u5f71\u54cd\u6750\u6599\u7684\u7535\u5b50\u6027\u8d28\uff08\u5982\u5bfc\u7535\u6027\uff09\uff0c\u8fd9\u4e00\u8fc7\u7a0b\u53d1\u751f\u901f\u5ea6\u5feb\uff0c\u53ef\u4ee5\u88ab\u8fc5\u901f\u68c0\u6d4b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-235795 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72478.png\" alt=\"\" width=\"553\" height=\"618\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72478.png 553w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72478-268x300.png 268w\" sizes=\"(max-width: 553px) 100vw, 553px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>7<\/b><\/strong>\u00a0SnSe(50%)-\u00a0SnSe<sub>2<\/sub>(50%)\u5f02\u8d28\u7ed3\u6784\u7684\u4f20\u611f\u539f\u7406\u793a\u610f\u56fe\u5728\u5ba4\u6e29\u4e0b\uff0c\u5728\u6fc0\u5149\u7167\u5c04\u4e0b\u5bf9NO<sub>2<\/sub>\u4f5c\u51fa\u54cd\u5e94<sup>[6]<\/sup>\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u4e03<\/strong><strong>. <\/strong><strong>\u5b58\u50a8\u5668<\/strong><\/p>\n<p>\u73b0\u4ee3\u4fe1\u606f\u5b58\u50a8\u548c\u5904\u7406\u6280\u672f\u662f\u901a\u8fc7\u78c1\u6027\u6750\u6599\u4e2d\u7684\u78c1\u77e9\u548c\u8f7d\u6d41\u5b50\u8f93\u8fd0\u6765\u5b9e\u73b0\u7684\u3002\u57fa\u4e8e\u91d1\u5c5e\u548c\u94c1\u6c27\u4f53\u7684\u94c1\u78c1\u6027\u6750\u6599\u4e0d\u5177\u5907\u534a\u5bfc\u4f53\u7279\u6027\uff0c\u5c45\u91cc\u6e29\u5ea6\u4f4e\uff0c\u5728\u5b9e\u9645\u5e94\u7528\u7684\u5ba4\u6e29\u6761\u4ef6\u4e0b\u78c1\u6027\u6d88\u5931\u3002\u5177\u6709\u9ad8\u8fc1\u79fb\u7387\u548c\u4fe1\u53f7\u5904\u7406\u80fd\u529b\u7684\u534a\u5bfc\u4f53\u6750\u6599\u4e0e\u94c1\u7535\u548c\u94c1\u78c1\u7279\u6027\u4e0d\u517c\u5bb9\u3002\u56e0\u6b64\uff0c\u5728\u975e\u78c1\u6027\u534a\u5bfc\u4f53\u4e2d\u63ba\u6742\u78c1\u6027\u5143\u7d20(\u5982Ni\u7b49)\u53ef\u4ee5\u5f62\u6210\u5177\u6709\u94c1\u78c1\u3001\u94c1\u7535\u548c\u94c1\u5f39\u6027\u6027\u8d28\u7684\u7a00\u78c1\u534a\u5bfc\u4f53\u3002\u901a\u8fc7\u8fd9\u79cd\u65b9\u6cd5\uff0c\u4e00\u4e9b\u6027\u80fd\u4f18\u8d8a\u7684\u534a\u5bfc\u4f53\u6750\u6599\uff08\u5982SnSe\/SnS\uff09\u4e5f\u53ef\u4ee5\u7528\u4e8e\u975e\u6613\u5931\u6027\u5b58\u50a8\u5668\u3002\u9664\u4e86\u7a00\u78c1\u534a\u5bfc\u4f53\u5916\uff0cSnSe\/SnS\u4e5f\u53ef\u7528\u4e8e\u94c1\u7535\u96a7\u9053\u7ed3\u5b58\u50a8\u5668\u548c\u76f8\u53d8\u5b58\u50a8\u5668\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-235796 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72479.png\" alt=\"\" width=\"564\" height=\"452\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72479.png 564w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u72479-300x240.png 300w\" sizes=\"(max-width: 564px) 100vw, 564px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>8<\/b><\/strong>\u00a0\u57fa\u4e8e\u540c\u8d28\u7ed3\u6784\u7684\u4e8c\u7ef4\u94c1\u7535\u96a7\u9053\u7ed3\u5668\u4ef6\u793a\u610f\u56fe\u3002\u5177\u6709\u9762\u5185\u94c1\u7535\u6027\u7684\u672c\u5f81SnSe\u534a\u5bfc\u4f53\u5145\u5f53\u94c1\u7535\u52bf\u5792\u3002\u4e24\u4fa7\u7684\u7535\u6781\u5206\u522b\u4e3ap\u578b\u548cn\u578bSnSe<sup>[7]<\/sup>\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u00a0<\/strong><strong>\u516b<\/strong><strong>. <\/strong><strong>\u5149\u7535\u4f20\u611f\u5668<\/strong><\/p>\n<p>\u5149\u7535\u63a2\u6d4b\u5668\u662f\u5c06\u5149\u8f90\u5c04\u4fe1\u53f7\u8f6c\u6362\u6210\u7535\u4fe1\u53f7\u7684\u88c5\u7f6e\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u51e0\u4e4e\u6ca1\u6709\u5149\u7535\u63a2\u6d4b\u5668\u7684\u63a2\u6d4b\u8303\u56f4\u80fd\u4ece\u7ea2\u5916\u5ef6\u4f38\u5230\u7d2b\u5916\u3002SnSe\/SnS\u7684\u51fa\u73b0\u4e3a\u5149\u7535\u63a2\u6d4b\u5668\u7684\u53d1\u5c55\u5e26\u6765\u4e86\u7a81\u7834\u3002\u4e0e\u4f20\u7edf\u534a\u5bfc\u4f53\u6750\u6599\u76f8\u6bd4\uff0c\u5b83\u4eec\u5177\u6709\u66f4\u9ad8\u7684\u9762\u5185\u8fc1\u79fb\u7387\u3001\u7a33\u5b9a\u7684\u5316\u5b66\u6027\u80fd\u3001\u826f\u597d\u7684\u673a\u68b0\u67d4\u6027\u548c\u4f18\u5f02\u7684\u5149\u7535\u8f6c\u6362\u6027\u80fd\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5728\u5782\u76f4\u4e8e\u4e8c\u7ef4\u5e73\u9762\u7684\u65b9\u5411\u4e0a\u6ca1\u6709\u5316\u5b66\u952e\uff0c\u8fd9\u79cd\u7279\u6027\u4fbf\u4e8e\u6784\u5efa\u4e8c\u7ef4\u5f02\u8d28\u7ed3\u3002\u4ee5\u524d\uff0c\u4f20\u7edf\u7684\u4f18\u5316\u7b56\u7565\u662f\u6539\u8fdbSnSe\/SnS\u8584\u819c\u3001\u7eb3\u7c73\u7ed3\u6784\u6216\u5176\u4ed6\u590d\u5408\u6750\u6599\u7684\u5408\u6210\u5de5\u827a\u3002\u901a\u8fc7\u5728\u4f20\u7edf\u5149\u7535\u8bbe\u5907\u4e0a\u53e0\u52a0\u5404\u79cd\u6548\u5e94\u3002\u4f8b\u5982\uff0c\u5149\u7535\u6548\u5e94\u4e0e\u5149\u70ed\u6548\u5e94\u3001\u538b\u7535\u6548\u5e94\u548c\u94c1\u7535\u6548\u5e94\u8026\u5408\u3002\u8fd9\u4e00\u7b56\u7565\u4e3a\u63d0\u9ad8SnSe\/SnS\u57fa\u5149\u7535\u63a2\u6d4b\u5668\u7684\u6027\u80fd\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-235797 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724710.png\" alt=\"\" width=\"550\" height=\"513\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724710.png 550w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724710-300x280.png 300w\" sizes=\"(max-width: 550px) 100vw, 550px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe<\/b><\/strong><strong><b>9<\/b><\/strong>\u00a0\u5229\u7528\u5149\u7535\u6548\u5e94\u548c\u70ed\u7535\u6548\u5e94\u8026\u5408\u7684\u5149\u7535\u63a2\u6d4b\u5668\u7ed3\u6784\u793a\u610f\u56fe<sup>[8]<\/sup><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u00a0<\/strong><strong>\u4e5d<\/strong><strong>. <\/strong><strong>\u5149\u50ac\u5316<\/strong><\/p>\n<p>\u5de5\u4e1a\u5316\u5e26\u6765\u7684\u73af\u5883\u95ee\u9898\u5bf9\u5168\u7403\u751f\u7269\u5b89\u5168\u6784\u6210\u4e86\u4e25\u91cd\u5a01\u80c1\u3002\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u6280\u672f\u662f\u6709\u6548\u89e3\u51b3\u73af\u5883\u6c61\u67d3\u95ee\u9898\u7684\u5173\u952e\u6280\u672f\u4e4b\u4e00\uff0c\u5b83\u5229\u7528\u592a\u9633\u80fd\u5904\u7406\u73af\u5883\u6c61\u67d3\u7269\u3002\u5c06\u9ad8\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u7684SnSe\/SnS\u548c\u50ac\u5316\u6d3b\u6027\u9ad8\u7684\u6750\u6599\u590d\u5408\u6784\u5efa\u5f02\u8d28\u7ed3\u662f\u63d0\u9ad8\u5149\u50ac\u5316\u6d3b\u6027\u7684\u6709\u6548\u9014\u5f84\u3002\u4e0e\u5355\u76f8\u6750\u6599\u56fa\u6709\u7684\u80fd\u5e26\u7ed3\u6784\u76f8\u6bd4\uff0c\u5f02\u8d28\u7ed3\u5149\u50ac\u5316\u6750\u6599\u53ef\u4ee5\u8c03\u8282\u5149\u5438\u6536\u8303\u56f4\u3002\u901a\u8fc7\u8c03\u6574\u80fd\u5e26\u7ed3\u6784\uff0c\u53ef\u4ee5\u52a0\u901f\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u5206\u79bb\uff0c\u6291\u5236\u5b83\u4eec\u7684\u590d\u5408\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235798\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724711.png\" alt=\"\" width=\"1175\" height=\"618\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724711.png 1175w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724711-300x158.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724711-768x404.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724711-1024x539.png 1024w\" sizes=\"(max-width: 1175px) 100vw, 1175px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>10<\/b><\/strong>\u00a0SnSe-SnO<sub>2<\/sub>\u6838\u58f3\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7684\u5408\u6210\u793a\u610f\u56fe\uff0c\u4ee5\u53ca\u5149\u7167\u6761\u4ef6\u4e0b\u6c61\u6c34\u964d\u89e3\u7684\u5149\u70ed\u548c\u5149\u50ac\u5316\u673a\u7406<sup>[9]<\/sup><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u5341<\/strong><strong>. <\/strong><strong>\u62d3\u6251\u7edd\u7f18\u4f53<\/strong><\/p>\n<p>\u81ea2007\u5e74\u53d1\u73b0\u62d3\u6251\u7edd\u7f18\u4f53\u4ee5\u6765\uff0c\u8fd9\u4e00\u7814\u7a76\u65b9\u5411\u9010\u6e10\u6210\u4e3a\u51dd\u805a\u6001\u7269\u7406\u7684\u65b0\u70ed\u70b9\u3002\u62d3\u6251\u7edd\u7f18\u4f53\uff08TIs\uff09\u662f\u5177\u6709\u5185\u90e8\u7edd\u7f18\uff0c\u5141\u8bb8\u7535\u8377\u5728\u754c\u9762\u4e0a\u79fb\u52a8\u7684\u6750\u6599\u30022011\u5e74\uff0c\u62d3\u6251\u6676\u4f53\u7edd\u7f18\u4f53\uff08TCI\uff09\u7684\u6982\u5ff5\u9996\u6b21\u88ab\u63d0\u51fa\u3002\u76f8\u6bd4\u4e8e\u62d3\u6251\u7edd\u7f18\u4f53\uff0c\u62d3\u6251\u6676\u4f53\u7edd\u7f18\u4f53\u662f\u4e00\u79cd\u65b0\u578b\u62d3\u6251\u6750\u6599\u3002\u5176\u65e0\u95f4\u9699\u7684\u5bfc\u7535\u8868\u9762\u6001\u53d7\u5230\u6676\u4f53\u5bf9\u79f0\u6027\u548c\u5185\u90e8\u5bf9\u79f0\u6027\uff08\u65f6\u95f4\u53cd\u8f6c\u3001\u624b\u6027\u7b49\uff09\u7684\u4fdd\u62a4\uff0c\u8fd9\u964d\u4f4e\u4e86\u6539\u5584\u6750\u6599\u62d3\u6251\u6027\u8d28\u7684\u96be\u5ea6\u3002\u5df2\u7ecf\u6709\u7406\u8bba\u8ba1\u7b97\u9a8c\u8bc1\u4e86SnSe\u548cSnS\u662f\u56fa\u6709\u7684\u62d3\u6251\u6676\u4f53\u7edd\u7f18\u4f53\u3002\u76ee\u524d\uff0c\u5927\u591a\u6570\u6587\u7ae0\u90fd\u53ea\u5c40\u9650\u4e8e\u7406\u8bba\u8ba1\u7b97\uff0c\u4f46\u662f\u901a\u8fc7\u5206\u5b50\u675f\u5916\u5ef6\u6cd5\u5236\u5907\u7684\u7acb\u65b9\u76f8SnSe\uff0c\u5b9e\u9a8c\u8bc1\u5b9e\u4e86\u5176\u62d3\u6251\u7edd\u7f18\u6001\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235799\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724712.png\" alt=\"\" width=\"981\" height=\"689\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724712.png 981w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724712-300x211.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724712-768x539.png 768w\" sizes=\"(max-width: 981px) 100vw, 981px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>11<\/b><\/strong>\u00a0\uff08a\uff09 SnSe\uff08111\uff09\u8868\u9762\u5e03\u91cc\u6e0a\u533a\uff1b\uff08b-e\uff0916nm SnSe\uff08111\uff09\u8584\u819c\u7684\u80fd\u5e26\u7ed3\u6784\u3002\u901a\u8fc7\uff08b\uff09ARPES\uff08\u89d2\u5206\u8fa8\u5149\u7535\u5b50\u80fd\u8c31\uff09\u548c\uff08c\uff09\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u5f97\u5230\u7684\u70b9\u9644\u8fd1\u7684\u80fd\u5e26\u56fe\u3002\u901a\u8fc7\uff08d\uff09ARPES\u548c\uff08e\uff09\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u5f97\u5230\u7684\u70b9\u9644\u8fd1\u7684\u80fd\u5e26\u56fe<sup>[10]<\/sup><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u5341\u4e00<\/strong><strong>. <\/strong><strong>\u4ece\u521a\u6027\u5230\u67d4\u6027<\/strong><\/p>\n<p>\u968f\u7740\u79d1\u6280\u7684\u8fdb\u6b65\u548c\u4eba\u4eec\u751f\u6d3b\u6c34\u5e73\u7684\u63d0\u9ad8\uff0c\u521a\u6027\u6750\u6599\u4e0d\u8db3\u4ee5\u6ee1\u8db3\u53ef\u7a7f\u6234\u8bbe\u5907\u7684\u9700\u6c42\u3002\u65b0\u578b\u67d4\u6027\u7ea4\u7ef4\/\u7eba\u7ec7\u54c1\/\u8584\u819c\u6027\u80fd\u7684\u4f18\u5316\u4e3a\u67d4\u6027\u53ef\u7a7f\u6234\u8bbe\u5907\u7684\u5f00\u53d1\u63d0\u4f9b\u4e86\u4e00\u6761\u6709\u5e0c\u671b\u7684\u9014\u5f84\u3002\u4f5c\u4e3a\u6838\u5fc3\u5668\u4ef6\u7684\u67d4\u6027\u70ed\u7535\u53d1\u7535\u673a\u3001\u67d4\u6027\u50a8\u80fd\u6750\u6599\u548c\u67d4\u6027\u5149\u7535\u63a2\u6d4b\u5668\u6210\u4e3a\u7814\u7a76\u7684\u65b0\u524d\u6cbf\u3002SnSe\/SnS\u8584\u819c\u751a\u81f3\u7ea4\u7ef4\u56fa\u6709\u7684\u673a\u68b0\u67d4\u6027\u5df2\u7ecf\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u5927\u91cf\u7814\u7a76\u5df2\u7ecf\u8868\u660e\uff0c\u57fa\u4e8eSnSe\/SnS\u7684\u67d4\u6027\u5668\u4ef6\u5728\u7ecf\u5386\u6570\u767e\u6b21\u5f2f\u6298\u540e\uff0c\u4f9d\u7136\u53ef\u4ee5\u4fdd\u6301\u4f18\u5f02\u7684\u6027\u80fd\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235800\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724713.png\" alt=\"\" width=\"772\" height=\"554\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724713.png 772w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724713-300x215.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724713-768x551.png 768w\" sizes=\"(max-width: 772px) 100vw, 772px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe<\/b><\/strong><strong><b>12<\/b><\/strong>\u00a0\u70ed\u62c9\u4f38SnSe\u7ea4\u7ef4\u548c\u62c9\u4f38\u6fc0\u5149\u518d\u7ed3\u6676\u5de5\u827a\u793a\u610f\u56fe<sup>[11]<\/sup><\/p>\n<p>\u672c\u8bba\u6587\u5bf9\u4e8c\u7ef4\u6750\u6599SnSe\/SnS\u4f53\u7cfb\u5728\u591a\u4e2a\u9886\u57df\u6f5c\u5728\u5e94\u7528\u8fdb\u884c\u4e86\u5206\u6790\u548c\u603b\u7ed3\uff0c\u6210\u529f\u5efa\u7acb\u4e86\u8fd9\u4e00\u4f53\u7cfb\u4e2d\u7684\u6750\u6599\u7269\u7406\u4f20\u8f93\u673a\u5236\u548c\u5e94\u7528\u4e4b\u95f4\u7684\u6865\u6881\u3002\u5728\u5c0f\u578b\u5316\u3001\u8f7b\u91cf\u5316\u548c\u9ad8\u5ea6\u96c6\u6210\u5316\u7684\u73b0\u4ee3\u79d1\u6280\u53d1\u5c55\u8d8b\u52bf\u4e0b\uff0c\u53d1\u5c55\u6ee1\u8db3\u8fd9\u4e9b\u8981\u6c42\u7684\u6750\u6599\u53ca\u5176\u5e94\u7528\u6280\u672f\u81f3\u5173\u91cd\u8981\u3002\u800c\u5728\u5f53\u524d\u7684\u79d1\u5b66\u7814\u7a76\u4e2d\uff0c\u591a\u5b66\u79d1\u4ea4\u53c9\u662f\u53d1\u5c55\u7684\u5fc5\u7136\u8d8b\u52bf\uff0c\u5efa\u7acbSnSe\/SnS\u8fd9\u79cd\u80fd\u591f\u5b9e\u73b0\u591a\u4e2a\u9886\u57df\u53ca\u5176\u4ea4\u53c9\u5e94\u7528\u7684\u6750\u6599\u4f53\u7cfb\u4e5f\u663e\u5f97\u5c24\u4e3a\u91cd\u8981\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttp:\/\/matlab.labapress.com\/article\/doi\/10.54227\/mlab.20220006<\/p>\n<p>\u8c28\u4ee5\u6b64\u6587\u5bf9Kanatzidis\u6559\u6388\u81f4\u4ee565\u5c81\u751f\u65e5\u8877\u5fc3\u7684\u795d\u798f\u548c\u5d07\u9ad8\u7684\u656c\u610f\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<p>[1] L. D. Zhao, S. H. Lo, Y. Zhang, H. Sun, G. Tan, C. Uher, C. Wolverton, V. P. Dravid, M. G. Kanatzidis, <em><i>Nature,<\/i><\/em>\u00a02014, 508, 373<\/p>\n<p>[2] Shinde, D. V.; Min, S.-K.; Sung, M.-M.; Shrestha, N. K.; Mane, R. S.; Han, S.-H., Photovoltaic properties of nanocrystalline SnSe\u2013CdS. <em><i>Mater<\/i><\/em><em><i>.<\/i><\/em><em><i>\u00a0Lett<\/i><\/em><em><i>.<\/i><\/em><em><i>,<\/i><\/em>\u00a02014, 115, 244-247<\/p>\n<p>[3] X. Xiong, C. Yang, G. Wang, Y. Lin, X. Ou, J.-H. Wang, B. Zhao, M. Liu, Z. Lin, K. Huang, <em><i>Energy Environ. Sci<\/i><\/em><em><i>.<\/i><\/em><em><i>,<\/i><\/em>\u00a02017, 10, 1757<\/p>\n<p>[4] C. Liu, S. Zhao, Y. Lu, Y. Chang, D. Xu, Q. Wang, Z. Dai, J. Bao, M. Han, <em><i>Small,<\/i><\/em>\u00a02017, 13, 1603494<\/p>\n<p>[5] H. Tian, X. Cao, Y. Xie, X. Yan, A. Kostelec, D. DiMarzio, C. Chang, L. D. Zhao, W. Wu, J. Tice, J. J. Cha, J. Guo, H. Wang, <em><i>ACS Nano,<\/i><\/em>\u00a02017, 11, 7156<\/p>\n<p>[6] X. Wang, Y. Liu, J. Dai, Q. Chen, X. Huang, W. Huang, <em><i>Chemistry,<\/i><\/em>\u00a02020, 26, 3870<\/p>\n<p>[7] X.-W. Shen, Y.-W. Fang, B.-B. Tian, C.-G. Duan, <em><i>ACS Appl. Electron. Mater<\/i><\/em>., 2019, 1, 1133<\/p>\n<p>[8] B. Ouyang, C. Chang, L.-D. Zhao, Z. L. Wang, Y. Yang, <em><i>Nano Energy<\/i><\/em>., 2019, 66, 104111<\/p>\n<p>[9] Z. Li, L. Sun, Y. Liu, L. Zhu, D. Yu, Y. Wang, Y. Sun, M. Yu, <em><i>Environ. Sci.:Nano,<\/i><\/em>\u00a02019, 6, 1507<\/p>\n<p>[10] Z. Wang, J. Wang, Y. Zang, Q. Zhang, J. A. Shi, T. Jiang, Y. Gong, C. L. Song, S. H. Ji, L. L. Wang, L. Gu, K. He, W. Duan, X. Ma, X. Chen, Q. K. Xue, <em><i>Adv. Mater.,<\/i><\/em>\u00a02015, 27, 4150<\/p>\n<p>[11] J. Zhang, T. Zhang, H. Zhang, Z. Wang, C. Li, Z. Wang, K. Li, X. Huang, M. Chen, Z. Chen, Z. Tian, H. Chen, L. D. Zhao, L. Wei, <em><i>Adv. Mater.,<\/i><\/em>\u00a02020, 32, 2002702<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u671f\u520a\u7b80\u4ecb<\/strong><\/p>\n<p><em><i>Materials Lab<\/i><\/em>\uff08http:\/\/matlab.labapress.com\/\uff09\u662f\u7531Lab Academic Press\u51fa\u7248\u7684\u4e00\u672c\u5f00\u653e\u83b7\u53d6\u671f\u520a\uff08Open Access\uff09\uff0c\u7531\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u7684\u8d75\u7acb\u4e1c\u6559\u6388\u548c\u6fb3\u5927\u5229\u4e9a\u5367\u9f99\u5c97\u5927\u5b66\u7684\u9648\u4fca\u6559\u6388\u5171\u540c\u62c5\u4efb\u4e3b\u7f16\u3002<em><i>Materials Lab<\/i><\/em>\u81f4\u529b\u4e8e\u53d1\u8868\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u9886\u57df\u7684\u524d\u6cbf\u79d1\u6280\u6210\u679c\uff0c\u6db5\u76d6\u4e0e\u6750\u6599\u76f8\u5173\u7684\u5408\u6210\u5236\u5907\u3001\u663e\u5fae\u7ed3\u6784\u3001\u529b\u5b66\u6027\u80fd\u3001\u7279\u79cd\u529f\u80fd\uff08\u58f0\u3001\u5149\u3001\u7535\u3001\u78c1\u3001\u70ed\uff09\u3001\u8ba1\u7b97\u6a21\u62df\u7b49\u7269\u7406\u3001\u5316\u5b66\u3001\u80fd\u6e90\u7b49\u591a\u5b66\u79d1\u4ea4\u53c9\u9886\u57df\u3002\u6211\u4eec\u5e0c\u671b\u6253\u9020\u4e00\u672c\u7528\u4e8e\u53d1\u8868\u5728\u201c\u6750\u6599\u5b9e\u9a8c\u5ba4\u201d\u4e2d\u8fdb\u884c\u7684\uff0c\u5177\u6709\u5e7f\u6cdb\u5f71\u54cd\u7684\u79d1\u7814\u5de5\u4f5c\u7684\u9ad8\u8d28\u91cf\u5f00\u653e\u83b7\u53d6\u65d7\u8230\u671f\u520a\u3002\u6b22\u8fce\u5404\u4f4d\u540c\u884c\u5782\u8be2\u8d50\u7a3f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235801\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724714.png\" alt=\"\" width=\"400\" height=\"400\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724714.png 400w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724714-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724714-300x300.png 300w\" sizes=\"(max-width: 400px) 100vw, 400px\" \/><\/p>\n<p>\u671f\u520a\u4e3b\u9875\uff1ahttp:\/\/matlab.labapress.com\/<\/p>\n<p>\u6295\u7a3f\u94fe\u63a5\uff1ahttps:\/\/mc03.manuscriptcentral.com\/matlab<\/p>\n<p>\u7f16\u8f91\u90e8\u90ae\u7bb1\uff1a<a href=\"mailto:matlab@labapress.com\"><u>matlab@labapress.com<\/u><\/a><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-235802\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724715.png\" alt=\"\" width=\"976\" height=\"497\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724715.png 976w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724715-300x153.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/04\/\u56fe\u724715-768x391.png 768w\" sizes=\"(max-width: 976px) 100vw, 976px\" \/><\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; \u7b2c\u4e00\u4f5c\u8005\uff1a\u5218\u4e1c\u9510 \uff08\u5317\u822a2021\u7ea7\u7855\u58eb\u7814\u7a76\u751f\uff09 \u901a\u8baf\u4f5c\u8005\uff1a\u8d75\u7acb\u4e1c\uff0c\u79e6\u70b3\u8d85 \u901a\u8baf\u5355\u4f4d\uff1a\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\uff0c\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662 &nbsp; 2022\u5e74&#8230;<\/p>\n","protected":false},"author":14360,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-235787","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/235787"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/14360"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=235787"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/235787\/revisions"}],"predecessor-version":[{"id":235810,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/235787\/revisions\/235810"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=235787"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=235787"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=235787"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}