{"id":237932,"date":"2022-05-31T06:09:28","date_gmt":"2022-05-30T22:09:28","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=237932"},"modified":"2022-05-30T18:12:56","modified_gmt":"2022-05-30T10:12:56","slug":"%e5%90%89%e6%9e%97%e5%a4%a7%e5%ad%a6%e6%9d%8e%e6%a5%a0inorg-chem-%e4%b8%a81t-mos2%e7%ba%b3%e7%b1%b3%e7%89%87%e8%80%a6%e5%90%88cos2%e7%ba%b3%e7%b1%b3%e9%a2%97%e7%b2%92%ef%bc%9a%e7%94%b5%e5%ad%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=237932","title":{"rendered":"\u5409\u6797\u5927\u5b66\u674e\u6960Inorg. Chem.\u4e281T-MoS2\u7eb3\u7c73\u7247\u8026\u5408CoS2\u7eb3\u7c73\u9897\u7c92\uff1a\u7535\u5b50\u7ed3\u6784\u8c03\u5236\u5b9e\u73b0\u9ad8\u6548\u56fa\u6c2e.files"},"content":{"rendered":"<p><strong>01<\/strong> <strong>\u5bfc\u8bfb<\/strong><\/p>\n<p>\u4e8c\u786b\u5316\u94bc\u7531\u4e8e\u5176\u4e0e\u56fa\u6c2e\u9176\u76f8\u4f3c\u7684Mo-S\u7ed3\u6784\u5728\u7535\u50ac\u5316\u8fd8\u539fN<sub>2<\/sub>\u5408\u6210\u6c28\uff08eNRR\uff09\u9886\u57df\u5907\u53d7\u5173\u6ce8\u30021T-MoS<sub>2<\/sub>\u5177\u6709\u7c7b\u91d1\u5c5e\u7684\u5bfc\u7535\u80fd\u529b\uff0c\u8fd9\u6709\u5229\u4e8e\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7684\u7535\u5b50\u4f20\u8f93\uff0c\u4ece\u800c\u52a0\u901f\u7535\u50ac\u5316\u53cd\u5e94\u7684\u8fdb\u884c\u3002\u7136\u800c\uff0c1T-MoS<sub>2<\/sub>\u7684eNRR\u50ac\u5316\u6027\u80fd\u4ecd\u5dee\u5f3a\u4eba\u610f\u3002\u8fd9\u4e3b\u8981\u5f52\u56e0\u4e8e\u4ee5\u4e0b\u4e24\u70b9\uff1a\uff081\uff091T-MoS<sub>2<\/sub>\u4e2d\u7528\u4e8eN<sub>2<\/sub>\u5438\u9644\u548c\u6d3b\u5316\u7684\u6d3b\u6027\u4f4d\u70b9\u5c40\u9650\u4e8e\u5360\u5c0f\u9762\u79ef\u7684\u8fb9\u7f18\u4f4d\u7f6e\uff0c\u8fd9\u4f7f\u5f971T-MoS<sub>2<\/sub>\u5177\u6709\u8f83\u4f4e\u7684\u672c\u5f81eNRR\u6d3b\u6027\uff1b\uff082\uff091T-MoS<sub>2<\/sub>\u4e2d\u5360\u5927\u90e8\u5206\u9762\u79ef\u7684\u57fa\u9762\u88ab\u7535\u8d1f\u6027\u7684S\u539f\u5b50\u8986\u76d6\uff0c\u4e0d\u80fd\u591f\u6709\u6548\u5438\u9644N<sub>2 <\/sub>\uff08\u2206G<sub>N2*<\/sub> = 0.43 eV\uff09\uff0c\u5e76\u4e141T-MoS<sub>2<\/sub>\u7684\u57fa\u9762\u5bf9\u7ade\u4e89\u6027\u7684\u6790\u6c22\uff08HER\uff09\u53cd\u5e94\u5177\u6709\u6d3b\u6027\uff0c\u56e0\u6b641T-MoS<sub>2<\/sub>\u901a\u5e38\u5177\u6709\u8f83\u4f4e\u7684eNRR\u9009\u62e9\u6027\u3002<\/p>\n<p><strong>02<\/strong> <strong>\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u5409\u6797\u5927\u5b66\u674e\u6960\u6559\u6388\u56e2\u961f\u901a\u8fc7\u6784\u7b51CoS<sub>2<\/sub>\/1T-MoS<sub>2<\/sub>\u5f02\u8d28\u7ed3\u6784\u5b9e\u73b0\u5bf91T-MoS<sub>2<\/sub>\u57fa\u9762\u7535\u5b50\u7ed3\u6784\u7684\u8c03\u5236\uff0c\u8be5\u50ac\u5316\u5242\u8868\u73b0\u51fa\u4f18\u5f02\u7684eNRR\u50ac\u5316\u6027\u80fd\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u8bc1\u660e\uff0c1T-MoS<sub>2<\/sub> eNRR\u6027\u80fd\u7684\u63d0\u5347\u6e90\u4e8eCoS<sub>2<\/sub>\/1T-MoS<sub>2<\/sub>\u5f02\u8d28\u7ed3\u6784\u534f\u540c\u4fc3\u8fdbN<sub>2<\/sub>\u5438\u9644\u548c\u6d3b\u5316\u4fc3\u8fdbeNRR\u53cd\u5e94\u8fdb\u884c\u4ee5\u53ca\u76f8\u8f83\u4e8eH\u5438\u9644\uff0c\u5f02\u8d28\u7ed3\u6784\u5bf9N<sub>2<\/sub>\u7684\u4f18\u5148\u5438\u9644\u4fc3\u8fdbeNRR\u9009\u62e9\u6027\u7684\u63d0\u9ad8\u3002\u6240\u5236\u5907\u50ac\u5316\u5242\u7684\u6c28\u4ea7\u7387\u548c\u6cd5\u62c9\u7b2c\u6548\u7387\u5206\u522b\u4e3a59.3 \u00b5g h<sup>-1<\/sup> mg<sup>-1<\/sup>\u548c26.6%\u3002\u8be5\u6210\u679c\u53d1\u8868\u5728<em>Inorganic Chemistry<\/em>\u4e0a\u3002<\/p>\n<p><strong>03<\/strong> <strong>\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n<p>\u901a\u8fc7\u5728\u7535\u50ac\u5316\u60f0\u6027\u76841T-MoS<sub>2<\/sub>\u7eb3\u7c73\u7247\u57fa\u9762\u5f15\u5165CoS<sub>2<\/sub>\u7eb3\u7c73\u9897\u7c92\uff0c\u6709\u6548\u8c03\u63a7\u4e861T-MoS<sub>2<\/sub>\u57fa\u9762\u7684\u7535\u5b50\u7ed3\u6784\u4e14\u5728CoS<sub>2<\/sub>\u548c1T-MoS<sub>2<\/sub>\u9644\u8fd1\u5206\u522b\u5f62\u6210\u7f3a\u7535\u5b50\u533a\u548c\u5bcc\u7535\u5b50\u533a\uff0c\u4e24\u8005\u534f\u540c\u4f5c\u7528\u4fc3\u8fdb\u4e86\u5bf9N<sub>2<\/sub>\u7684\u6709\u6548\u5438\u9644\u548c\u6d3b\u5316\uff0c\u5927\u5927\u52a0\u5feb\u4e86eNRR\u8fc7\u7a0b\u7684\u52a8\u529b\u5b66\u3002<\/p>\n<p>\u5f31H\u5438\u9644\u80fd\u529b\u7684CoS<sub>2<\/sub>\u7684\u5f15\u5165\u4f7f\u5f97\u5f02\u8d28\u7ed3\u6784\u5728\u50ac\u5316\u8fc7\u7a0b\u4e2d\u66f4\u5bb9\u6613\u5438\u9644N<sub>2<\/sub>\u800c\u975eH\u3002CoS<sub>2<\/sub>\/1T-MoS<sub>2<\/sub>\u4e0a\u7684\u7ade\u4e89\u6027HER\u53cd\u5e94\u88ab\u6291\u5236\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86CoS<sub>2<\/sub>\/1T-MoS<sub>2<\/sub>\u7684\u9009\u62e9\u6027\u3002<\/p>\n<p><strong>04<\/strong> <strong>\u6570\u636e\u6982\u89c8<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-237935\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image001-2.jpg\" alt=\"\" width=\"866\" height=\"619\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image001-2.jpg 866w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image001-2-300x214.jpg 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image001-2-768x549.jpg 768w\" sizes=\"(max-width: 866px) 100vw, 866px\" \/><\/p>\n<p>\u56fe1. CoS<sub>2<\/sub>\/1T-MoS<sub>2<\/sub>\u7684\u7ed3\u6784\u8868\u5f81\uff1a\uff08a\uff09TEM\u56fe\uff0c\uff08b-c\uff09HRTEM\u56fe\uff0c\uff08d-e\uff091T\u548c2H\u76f8MoS<sub>2<\/sub>\u7684\u539f\u5b50\u7ed3\u6784\u653e\u5927\u56fe\uff0c\uff08f-i\uff09HAADF-STEM\u56fe\u548c\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-237936\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image003-4.png\" alt=\"\" width=\"1173\" height=\"880\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image003-4.png 1173w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image003-4-300x225.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image003-4-768x576.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image003-4-1024x768.png 1024w\" sizes=\"(max-width: 1173px) 100vw, 1173px\" \/><\/p>\n<p>\u56fe2. \uff08a\uff09 \u4e0d\u540cMo\/Co\u6bd4\u7684CoS<sub>2<\/sub>\/1T-MoS<sub>2<\/sub>\u7684\u6c28\u4ea7\u7387\u548c\u6cd5\u62c9\u7b2c\u6548\u7387\uff0c\uff08b\uff09 CoS<sub>2<\/sub>\/1T-MoS<sub>2<\/sub>\u5728N<sub>2<\/sub>\u548cAr\u9971\u548c\u7535\u89e3\u6db2\u4e2d\u7684LSV\u66f2\u7ebf\uff0c\uff08c\uff09CoS<sub>2<\/sub>\/1T-MoS<sub>2<\/sub>\u5728\u4e0d\u540c\u7535\u538b\u4e0b\u7684\u6c28\u4ea7\u7387\u548c\u6cd5\u62c9\u7b2c\u6548\u7387\uff0c\uff08d\uff09\u4e0d\u540c\u6837\u54c1\u7684EIS\u5bf9\u6bd4\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-237937\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image005-3.png\" alt=\"\" width=\"1041\" height=\"843\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image005-3.png 1041w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image005-3-300x243.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image005-3-768x622.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/image005-3-1024x829.png 1024w\" sizes=\"(max-width: 1041px) 100vw, 1041px\" \/><\/p>\n<p>\u56fe3. CoS<sub>2<\/sub>\/1T-MoS<sub>2<\/sub>\u50ac\u5316\u5242\u7684DFT\u8ba1\u7b97\u56fe<\/p>\n<p><strong>05<\/strong> <strong>\u6210\u679c\u542f\u793a<\/strong><\/p>\n<p>CoS<sub>2<\/sub>\/1T-MoS<sub>2<\/sub>\u50ac\u5316\u5242\u7684\u4f18\u5f02eNRR\u50ac\u5316\u6027\u80fd\u4e3b\u8981\u5f52\u529f\u4e8e\u4ee5\u4e0b\u4e24\u70b9\uff1a1)\u5728CoS<sub>2<\/sub>\/1T-MoS<sub>2<\/sub>\u5f02\u8d28\u7ed3\u6784\u4e2d\uff0c\u7535\u5b50\u81ea\u53d1\u4eceCoS<sub>2<\/sub>\u54111T-MoS<sub>2<\/sub>\u8f6c\u79fb\uff0c\u4ece\u800c\u5728CoS<sub>2<\/sub>\u4fa7\u5f62\u6210\u7f3a\u7535\u5b50\u533a\u800c\u57281T-MoS<sub>2<\/sub>\u4fa7\u7535\u5b50\u5bcc\u96c6\u5f62\u6210\u5bcc\u7535\u5b50\u533a\u3002\u524d\u8005\u6709\u5229\u4e8e\u63a5\u6536\u6765\u81eaN<sub>2<\/sub>\u7684\u5b64\u5bf9\u7535\u5b50\u4ee5\u4fc3\u8fdbN<sub>2<\/sub>\u7684\u5438\u9644\uff0c\u800c\u540e\u8005\u53ef\u4ee5\u5411\u7a7a\u7684N<sub>2<\/sub>\u53cd\u952e\u8f68\u9053\u63d0\u4f9b\u7535\u5b50\uff0c\u4fc3\u8fdbN\u2261N\u4e09\u952e\u65ad\u88c2\u3002\u4e24\u8005\u534f\u540c\u63a8\u52a8eNRR\u8fc7\u7a0b\u7684\u8fdb\u884c\uff1b2) CoS<sub>2<\/sub>\/1T-MoS<sub>2<\/sub>\u4e0eH\u7684\u5f31\u76f8\u4e92\u4f5c\u7528\u53ef\u4ee5\u6291\u5236\u7ade\u4e89\u6027HER\uff0c\u63d0\u9ad8eNRR\u9009\u62e9\u6027\u3002<\/p>\n<p><strong>06<\/strong> <strong>\u6587\u732e\u94fe\u63a5<\/strong><\/p>\n<p>Shihan Liu, Guohua Yang, Lei Zhao, Zhipeng Liu, Kaiwen Wang, Xiaotian Li and Nan Li<sup>*<\/sup>, 1T-MoS<sub>2<\/sub> Nanosheets Coupled with CoS<sub>2<\/sub> Nanoparticles: Electronic Modulation for Efficient Electrochemical Nitrogen Fixation. <strong><em>Inorg. Chem., <\/em><\/strong>2022, DOI: 10.1021\/acs.inorgchem.2c00829<\/p>\n","protected":false},"excerpt":{"rendered":"<p>01 \u5bfc\u8bfb \u4e8c\u786b\u5316\u94bc\u7531\u4e8e\u5176\u4e0e\u56fa\u6c2e\u9176\u76f8\u4f3c\u7684Mo-S\u7ed3\u6784\u5728\u7535\u50ac\u5316\u8fd8\u539fN2\u5408\u6210\u6c28\uff08eNRR\uff09\u9886\u57df\u5907\u53d7\u5173\u6ce8\u30021T-MoS2\u5177\u6709\u7c7b\u91d1\u5c5e\u7684\u5bfc\u7535\u80fd\u529b\uff0c\u8fd9\u6709\u5229\u4e8e\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7684\u7535&#8230;<\/p>\n","protected":false},"author":35234,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-237932","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/237932"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/35234"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=237932"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/237932\/revisions"}],"predecessor-version":[{"id":237939,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/237932\/revisions\/237939"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=237932"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=237932"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=237932"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}