{"id":237953,"date":"2022-06-01T14:00:13","date_gmt":"2022-06-01T06:00:13","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=237953"},"modified":"2022-06-01T11:12:33","modified_gmt":"2022-06-01T03:12:33","slug":"%e9%ba%a6%e5%85%8b%e9%98%bf%e7%91%9f%e5%a4%a9%e6%89%8d%e5%a5%96%e5%be%97%e4%b8%bbphil-s-baran%e5%88%9a%e5%8f%91nature%ef%bc%9a%e9%92%b4%e5%9f%ba%e6%b0%a2%e5%8c%96%e7%89%a9%e9%ab%98%e6%95%88%e5%82%ac","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=237953","title":{"rendered":"\u9ea6\u514b\u963f\u745f\u5929\u624d\u5956\u5f97\u4e3bPhil S. Baran\u521a\u53d1Nature\uff1a\u94b4\u57fa\u6c22\u5316\u7269\u9ad8\u6548\u50ac\u5316\u6709\u673a\u5408\u6210"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u81ea20\u4e16\u7eaa60\u5e74\u4ee3\u521d\u4ee5\u6765\uff0c\u8fc7\u6e21\u91d1\u5c5e\u6c22\u5316\u7269\uff08TMHs\uff09\u7684\u7814\u7a76\u548c\u5e94\u7528\u4e00\u76f4\u662f\u5316\u5b66\u9886\u57df\u7684\u91cd\u8981\u5206\u652f\uff0c\u5728\u50a8\u80fd\u9886\u57df\u4e2d\uff0cTMHs\u53ef\u4ee5\u5b9e\u73b0\u8d28\u5b50\u8fd8\u539f\u5236\u6c22\uff1b\u5728\u6709\u673a\u5408\u6210\u4e2d\uff0cTMHs\u80fd\u5b9e\u73b0\u4e0d\u9971\u548cC-C\u3001C-O\u548cC-N\u952e\u7684\u529f\u80fd\u5316\u3002\u81ea20\u4e16\u7eaa50\u5e74\u4ee3\u4ee5\u6765\uff0c\u7535\u5316\u5b66\u53cd\u5e94\u6280\u672f\u5c31\u88ab\u5e7f\u6cdb\u91c7\u7528\u6765\u751f\u6210\u94b4\u6c22\u5316\u7269\u5b9e\u73b0\u5236\u6c22\u53cd\u5e94\uff0c\u4f46\u5728\u5408\u6210\u5316\u5b66\u4e2d\u4f7f\u7528\u5916\u6e90\u6027\u7684\u6709\u673a\u548c\u91d1\u5c5e\u8fd8\u539f\u5242\u6765\u5229\u7528TMHs\u7684\u80fd\u529b\u4ecd\u7136\u662f\u5e38\u89c1\u7684\u505a\u6cd5\u3002\u4f8b\u5982\uff0c\u94b4\u57faTMHs\u5e7f\u6cdb\u7528\u4e8e\u590d\u6742\u5206\u5b50\u7ed3\u6784\u4e2d\u8fc7\u6e21\u91d1\u5c5e\u6c22\u5316\u7269\u50ac\u5316\u7684\u70ef\u70c3\u548c\u7094\u70c3\u7684\u884d\u751f\u5316\u3002\u7136\u800c\uff0c\u5927\u89c4\u6a21\u5e94\u7528\u6c22\u539f\u5b50\u8f6c\u79fb\uff08HAT\uff09\u5316\u5b66\u53ef\u80fd\u4f1a\u51fa\u73b0\u95ee\u9898\uff0c\u56e0\u4e3a\u9700\u8981\u4f7f\u7528\u8fc7\u91cf\u7684\u5916\u90e8\u8fd8\u539f\u5242\uff0c\u5bfc\u81f4\u539f\u5b50\u7ecf\u6d4e\u6027\u8f83\u5dee\uff0c\u4ee5\u53ca\u5728\u540c\u4e00\u53cd\u5e94\u4f53\u7cfb\u4e2d\u4f7f\u7528\u6709\u673a\u8fd8\u539f\u5242\u548c\u6c27\u5316\u5242\u65f6\u9690\u542b\u7684\u5b89\u5168\u95ee\u9898\u7b49\u3002<\/p>\n<p><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u65af\u514b\u5229\u666e\u65af\u7814\u7a76\u6240\u7684<\/strong><strong>Phil S. Baran<\/strong><strong>\u6559\u6388\u3001<\/strong><strong>Donna G. Blackmond<\/strong><strong>\u6559\u6388\u3001\u72b9\u4ed6\u5927\u5b66<\/strong><strong>Matthew S. Sigman<\/strong><strong>\u6559\u6388\u3001<\/strong><strong>Shelley D. Minteer<\/strong><strong>\u6559\u6388\u3001\u52a0\u5dde\u7406\u5de5\u5b66\u9662<\/strong><strong>Sarah E. Reisman<\/strong><strong>\u6559\u6388\u3001\u5eb7\u5948\u5c14\u5927\u5b66<\/strong><strong>Hector D. Abruna<\/strong><strong>\u6559\u6388<\/strong>\u7b49\u8054\u5408\u5c55\u793a\u4e86\u5229\u7528\u51e0\u5341\u5e74\u6765\u50a8\u80fd\u7814\u7a76\u6240\u5e7f\u6cdb\u91c7\u7528\u7684\u7535\u50ac\u5316\u65b9\u6cd5\u6765\u5b9e\u73b0\u6709\u673a\u5408\u6210\uff0c\u5373\u9ad8\u5316\u5b66\u9009\u62e9\u6027\u7684\u3001\u53ef\u63a7\u7684\u7535\u5316\u5b66HAT\uff08e-HAT\uff09\u3002\u8fd9\u79cd\u7b56\u7565\u4e0d\u4ec5\u5728\u53ef\u6301\u7eed\u6027\u548c\u6548\u7387\u65b9\u9762\u63d0\u4f9b\u4e86\u597d\u5904\uff08\u65e0\u9700\u5316\u5b66\u8fd8\u539f\u5242\u3001\u6c27\u5316\u5242\u4ee5\u53ca\u4e25\u82db\u7684\u53cd\u5e94\u6761\u4ef6\uff09\uff0c\u800c\u4e14\u8fd8\u80fd\u591f\u589e\u5f3a\u5316\u5b66\u9009\u62e9\u6027\u548c\u72ec\u7279\u7684\u3001\u53ef\u8c03\u53cd\u5e94\u3002\u901a\u8fc7\u5b9e\u9a8c\u4e3e\u4f8b\u8bf4\u660e\u4e86\u6570\u5341\u79cd\u5e95\u7269\u4e0a\u7684\u5341\u79cd\u4e0d\u540c\u53cd\u5e94\uff0c\u5e76\u63d0\u4f9b\u4e86\u8fd9\u79cd\u901a\u8fc7\u4f4e\u4ef7\u4e2d\u95f4\u4ea7\u7269\u751f\u6210Co-H\u7684\u53ef\u6269\u5c55\u7535\u5316\u5b66\u9014\u5f84\u7684\u673a\u7406\u89e3\u91ca\u3002\u8be5\u8bba\u6587\u4ee5\u9898\u4e3a\u201c<strong>Cobalt-electrocatalytic HAT for functionalization of unsaturated C\u2013C bonds\u201d<\/strong>\u53d1\u8868\u5728\u77e5\u540d\u671f\u520a<strong><em>Nature<\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-237961\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/0-8.jpg\" alt=\"\" width=\"600\" height=\"393\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/0-8.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/0-8-300x197.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/p>\n<p>1\u3001\u53d7\u94b4\u7535\u50ac\u5316\u6790\u6c22\u5316\u5b66\u7684\u542f\u53d1\uff0c\u7814\u7a76\u4eba\u5458\u5f00\u53d1\u4e86\u4e00\u7ec4\u9ad8\u5316\u5b66\u9009\u62e9\u6027\u7684\u3001\u53ef\u8c03\u63a7\u7684e-HAT\u7b56\u7565\uff0c\u65e0\u9700\u5316\u5b66\u8fd8\u539f\u5242\u548c\u6c27\u5316\u5242\u6216\u4e25\u683c\u7684\u5b9e\u9a8c\u6761\u4ef6\u3002<\/p>\n<p>2\u3001\u8be5\u7b56\u7565\u53ef\u5b9e\u73b0\u70ef\u70c3\u548c\u7094\u70c3\u7684\u591a\u79cd\u53ef\u8c03\u53cd\u5e94\uff0c\u4f8b\u5982\u5f02\u6784\u5316\u3001\u9009\u62e9\u6027\u8fd8\u539f\u548c\u52a0\u6c22\u5b98\u80fd\u5316\u3002<\/p>\n<p>3\u3001\u63d0\u51fae-HAT\u673a\u7406\u5e76\u5f97\u5230\u9a8c\u8bc1\u3002<\/p>\n<p><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1 <\/strong><strong>\u901a\u8fc7\u80fd\u91cf\u50a8\u5b58\u542f\u53d1\u7684\u94b4\u50ac\u5316\u7535\u5316\u5b66\u6c22\u539f\u5b50\u8f6c\u79fb\uff08<\/strong><strong>HAT<\/strong><strong>\uff09<\/strong><strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-237962\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/1-22.jpg\" alt=\"\" width=\"600\" height=\"322\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/1-22.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/1-22-300x161.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p>\uff08a\uff09\u7ecf\u5178\u7684\u6c22\u539f\u5b50\u8f6c\u79fb\uff08HAT\uff09\u5316\u5b66\u3002<\/p>\n<p>\uff08b\uff09\u94b4\u50ac\u5316\u6790\u6c22\u548ce-HAT\u3002<\/p>\n<p>\uff08c\uff09\u7535\u5316\u5b66\u9a71\u52a8\u7684e-HAT\u8f6c\u6362\u3002<\/p>\n<p>\uff08d\uff09\u70ef\u70c3\u5f02\u6784\u5316\u4e0e\u7ecf\u5178HAT\u65b9\u6cd5\u7684\u6bd4\u8f83\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>2 e-HAT<\/strong><strong>\u5f02\u6784\u5316\u9002\u7528\u8303\u56f4<\/strong><strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-237963\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/2-25.jpg\" alt=\"\" width=\"600\" height=\"537\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/2-25.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/2-25-300x269.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>3 e-HAT<\/strong><strong>\u8fd8\u539f\u53cd\u5e94\u9002\u7528\u8303\u56f4<\/strong><strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-237965\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/3-24.jpg\" alt=\"\" width=\"600\" height=\"383\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/3-24.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/3-24-300x192.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>4 e-HAT<\/strong><strong>\u7684\u9009\u62e9\u6027\u3001\u53ef\u62d3\u5c55\u6027\u53ca<\/strong><strong>HAT<\/strong><strong>\u53cd\u5e94<\/strong> <strong>\u00a9 2022 Springer Nature<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-237966\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/4-23.jpg\" alt=\"\" width=\"600\" height=\"771\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/4-23.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/4-23-233x300.jpg 233w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p>\uff08a\uff09\u70ef\u70c3\u5f02\u6784\u5316\u548c\u8fd8\u539f\u7684\u9009\u62e9\u6027\u3002<\/p>\n<p>\uff08b\uff09\u73af\u5f02\u6784\u5316\u3001\u5f02\u6784\u5316\u548c\u8fd8\u539fe-HAT\u53cd\u5e94\u7684\u653e\u5927\u7ed3\u679c\u3002<\/p>\n<p>\uff08c\uff09HAT\u53cd\u5e94\u7684\u666e\u9002\u6761\u4ef6\u3002<\/p>\n<p>\uff08d\uff09HAT\u65b0\u53cd\u5e94\uff1aE-\u9009\u62e9\u6027\u7094\u70c3\u534a\u52a0\u6c22\u53cd\u5e94\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>5 <\/strong><strong>\u673a\u7406\u7814\u7a76<\/strong> <strong>\u00a9 2022 Springer Nature<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-237967\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/5-13.jpg\" alt=\"\" width=\"600\" height=\"765\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/5-13.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/05\/5-13-235x300.jpg 235w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09e-HAT\u53ef\u80fd\u7684\u673a\u7406\u9014\u5f84\u3002<\/p>\n<p>\uff08b\uff09\u4f7f\u7528\u5faa\u73af\u4f0f\u5b89\u6cd5\uff08CV\uff09\u3001\u7d2b\u5916\u53ef\u89c1\u5149\u8c31\u7535\u5316\u5b66\u3001\u52a8\u529b\u5b66\u5206\u6790\u3001\u5fae\u5206\u7535\u5316\u5b66\u8d28\u8c31\u3001\u952e\u79bb\u89e3\u80fd\uff08BDE\uff09\u548cDFT\u8ba1\u7b97\u7b49\u8fdb\u884c\u673a\u7406\u7684\u9a8c\u8bc1\u3002<\/p>\n<p><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u672c\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u4e2a\u65b0\u7684\u89c6\u89d2\uff0c\u5c06\u5df2\u7ecf\u7814\u7a76\u4e86\u6570\u5341\u5e74\u7684\u7528\u4e8e\u50a8\u80fd\u65b9\u5411\u7684\u7535\u50ac\u5316\u65b9\u6cd5\uff0c\u5728\u73b0\u4ee3\u6709\u673a\u5408\u6210\u4e2d\u5b9e\u73b0\u591a\u79cd\u5e94\u7528\u3002\u8be5\u7535\u8fd8\u539f\u65b9\u6848\u53ef\u4ee5\u5728\u672a\u9694\u65ad\u7535\u6c60\u4e2d\u548c\u591a\u4e2a\u5c3a\u5ea6\u53cd\u5e94\u8303\u56f4\u5185\u8fdb\u884c\uff0c\u65e0\u9700\u4e25\u683c\u53bb\u9664\u7a7a\u6c14\u6216\u6c34\uff0c\u4e14\u65e0\u9700\u6602\u8d35\u7684\u7845\u70f7\/\u787c\u70f7\u6216\u5316\u5b66\u8ba1\u91cf\u6c27\u5316\u5242\u3002\u901a\u8fc7\u5bf9\u8de8\u8d8a\u6570\u5341\u79cd\u5e95\u7269\u7684\u5f02\u6784\u5316\u3001\u8fd8\u539f\u548c\u6c22\u5b98\u80fd\u5316\u7684\u5341\u79cd\u4e0d\u540c\u53cd\u5e94\u8bc1\u660e\u4e86\u8fd9\u79cd\u7535\u5316\u5b66\u5728Co-H\u5316\u5b66\u7684\u5e7f\u6cdb\u5e94\u7528\u8303\u56f4\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41586-022-04595-3\" target=\"_blank\" rel=\"noopener\">Cobalt-electrocatalytic HAT for functionalization of unsaturated C-C bonds<\/a> ( <em>Naure <\/em><strong>2022<\/strong>, <em>605<\/em>, 687-695)<\/p>\n<p>\u672c\u6587\u7531\u8d5b\u6069\u65af\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 \u81ea20\u4e16\u7eaa60\u5e74\u4ee3\u521d\u4ee5\u6765\uff0c\u8fc7\u6e21\u91d1\u5c5e\u6c22\u5316\u7269\uff08TMHs\uff09\u7684\u7814\u7a76\u548c\u5e94\u7528\u4e00\u76f4\u662f\u5316\u5b66\u9886\u57df\u7684\u91cd\u8981\u5206\u652f\uff0c\u5728\u50a8\u80fd\u9886\u57df\u4e2d\uff0cTMHs\u53ef\u4ee5\u5b9e\u73b0\u8d28\u5b50\u8fd8\u539f\u5236\u6c22\uff1b\u5728\u6709\u673a\u5408\u6210\u4e2d&#8230;<\/p>\n","protected":false},"author":36791,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[4864],"class_list":["post-237953","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-tmhhat"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/237953"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/36791"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=237953"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/237953\/revisions"}],"predecessor-version":[{"id":238020,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/237953\/revisions\/238020"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=237953"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=237953"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=237953"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}