{"id":238308,"date":"2022-06-13T06:17:10","date_gmt":"2022-06-12T22:17:10","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=238308"},"modified":"2022-06-12T20:17:31","modified_gmt":"2022-06-12T12:17:31","slug":"nature-nanotechnology%ef%bc%9a%e9%87%8f%e5%ad%90%e7%9b%b8%e5%b9%b2%e7%9a%84%e5%88%86%e5%ad%90%e9%97%b4%e8%83%bd%e9%87%8f%e4%bc%a0%e9%80%92-%e4%b8%ba%e5%85%89%e5%90%88%e4%bd%9c%e7%94%a8%e5%92%8c","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=238308","title":{"rendered":"Nature Nanotechnology\uff1a\u91cf\u5b50\u76f8\u5e72\u7684\u5206\u5b50\u95f4\u80fd\u91cf\u4f20\u9012 &#8212;&#8212;\u4e3a\u5149\u5408\u4f5c\u7528\u548c\u5149\u4f0f\u7ed3\u6784\u4e2d\u6709\u6548\u5149\u5b50\u6355\u83b7\u63d0\u4f9b\u4e86\u8bbe\u8ba1\u57fa\u7840"},"content":{"rendered":"<p style=\"text-align: center;\"><strong>\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u9633\u5149\u662f\u6211\u4eec\u53ef\u4ee5\u4f7f\u7528\u7684\u6700\u4e30\u5bcc\u7684\u80fd\u6e90\u3002<strong>\u592a\u9633\u80fd\u7684\u8f6c\u5316\u901a\u5e38\u4ece\u5149\u80fd\u88ab\u4e00\u4e2a\u5206\u5b50\u96c6\u5408\u4f53\u5438\u6536\u5f00\u59cb\uff0c\u7136\u540e\u8be5\u7535\u5b50\u6fc0\u53d1\u80fd\u91cf\u968f\u540e\u88ab\u8f6c\u79fb\u5230\u5408\u9002\u7684\u53d7\u4e3b\u3002<\/strong>\u4f8b\u5982\uff0c\u5728\u5149\u5408\u4f5c\u7528\u4e2d\uff0c\u5929\u7ebf\u590d\u5408\u7269\u6355\u83b7\u9633\u5149\u5e76\u5c06\u80fd\u91cf\u5f15\u5bfc\u5230\u53cd\u5e94\u4e2d\u5fc3\uff0c\u7136\u540e\u518d\u8fdb\u884c\u76f8\u5173\u7684\u5316\u5b66\u53cd\u5e94\u3002<strong>\u4e3a\u4e86\u6709\u6548\u5730\u5229\u7528\u4ece\u9633\u5149\u4e2d\u6536\u96c6\u7684\u80fd\u91cf\u6765\u4fc3\u8fdb\u5149\u5316\u5b66\u53cd\u5e94\u6216\u751f\u4ea7\u592a\u9633\u80fd\u71c3\u6599\uff0c\u6211\u4eec\u5fc5\u987b\u4e86\u89e3\u5206\u5b50\u96c6\u5408\u4f53\u662f\u5982\u4f55\u6709\u6548\u6355\u83b7\u5149\u5b50\u5e76\u8fdb\u884c\u80fd\u91cf\u4f20\u9012\u7684\u3002<\/strong>\u8fd9\u5c06\u5141\u8bb8\u8bbe\u8ba1\u5206\u5b50\u201c\u7535\u8def\u201d\uff0c\u4ee5\u590d\u6742\u7684\u65b9\u5f0f\u5f15\u5bfc\u3001\u5206\u7c7b\u548c\u54cd\u5e94\u6fc0\u53d1\u80fd\u91cf\u3002<strong>\u91cf\u5b50\u76f8\u5e72\u7684\u5206\u5b50\u95f4\u80fd\u91cf\u4f20\u9012\u88ab\u8ba4\u4e3a\u5728\u5149\u5408\u4f5c\u7528\u548c\u5149\u4f0f\u53d1\u7535\u7684\u5149\u6536\u96c6\u4e2d\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002\u7136\u800c\uff0c<\/strong>\u7531\u4e8e\u590d\u6742\u5206\u5b50\u7cfb\u7edf\u4e2d\u7684\u8017\u6563\u6bd4\u8f83\u5927\uff0c\u91cf\u5b50\u76f8\u5e72\u6027\u5f88\u8106\u5f31\uff0c\u8fc4\u4eca\u4e3a\u6b62<strong>\u4ecd\u7136\u7f3a\u4e4f\u5bf9\u65bd\u4e3b<\/strong><strong>&#8211;<\/strong><strong>\u53d7\u4e3b\u7cfb\u7edf\u4e2d\u91cf\u5b50\u76f8\u5e72\u6027\u4f20\u80fd\u7684\u76f4\u63a5\u3001\u771f\u5b9e\u7a7a\u95f4\u7684\u5c55\u793a\u3002<\/strong><\/p>\n<p><strong>\u626b\u63cf\u96a7\u9053\u663e\u5fae\u955c\u8bf1\u5bfc\u53d1\u5149\uff08STML<\/strong><strong>\uff09\u6280\u672f<\/strong>\u5177\u6709\u5206\u5b50\u64cd\u4f5c\u548c\u4e9a\u7eb3\u7c73\u5206\u8fa8\u7387\u7684\u5149\u8c31\u6210\u50cf\u80fd\u529b\uff0c<strong>\u4e3a\u5206\u5b50\u95f4\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\uff08<\/strong><strong>EET<\/strong><strong>\uff09\u8fc7\u7a0b\u7684\u5b9e\u7a7a\u95f4\u7814\u7a76\u63d0\u4f9b\u4e86\u72ec\u7279\u7684\u5e73\u53f0\u3002<\/strong>\u57fa\u4e8eSTML\u6280\u672f\uff0c\u524d\u4eba\u5df2\u6f14\u793a\u4e86\u540c\u8d28\u4e8c\u805a\u4f53\u7684\u76f8\u5e72\u5076\u6781-\u5076\u6781\u8026\u5408\u548c\u5f02\u8d28\u4e8c\u805a\u4f53\u548c\u4e09\u805a\u4f53\u7684\u975e\u76f8\u5e72\u5171\u632f\u80fd\u91cf\u8f6c\u79fb\u3002<strong>\u7136\u800c\uff0c\u5173\u4e8e\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u7684\u51e0\u4e2a\u957f\u671f\u5b58\u5728\u7684\u57fa\u672c\u95ee\u9898\u4ecd\u6709\u5f85\u4e8e\u901a\u8fc7\u5b9e\u9a8c\u52a0\u4ee5\u6f84\u6e05<\/strong>\uff1a<\/p>\n<p>\uff081\uff09\u65bd\u4e3b-\u53d7\u4e3b\u5f02\u4e8c\u805a\u4f53\u7cfb\u7edf\u4e2d\u662f\u5426\u5b58\u5728\u76f8\u5e72\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\uff1f<\/p>\n<p>\uff082\uff09\u5982\u679c\u662f\uff0c\u5206\u5b50\u95f4\u8ddd\u79bb\u4e3a\u591a\u5c11\u65f6\u76f8\u5e72\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u4f1a\u51fa\u73b0\uff1f<\/p>\n<p>\uff083\uff09\u76f8\u5e72\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u901a\u9053\u6bd4\u975e\u76f8\u5e72F\u00f6rster\u5171\u632f\u80fd\u91cf\u8f6c\u79fb\uff08FRET\uff09\u901a\u9053\u6548\u7387\u9ad8\u591a\u5c11\uff1f<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><strong>\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u4faf\u5efa\u56fd\u6559\u6388\u3001\u8463\u632f\u8d85\u6559\u6388\u548c\u5f20\u6768\u6559\u6388<strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong><strong>\u7b49\u7814\u7a76\u8005\u6784\u5efa\u4e86\u7531\u915e\u83c1\u5206\u5b50\u7ec4\u6210\u7684\u5b9a\u4e49\u660e\u786e\u7684\u65bd\u4e3b<\/strong><strong>&#8211;<\/strong><strong>\u53d7\u4e3b\u7cfb\u7edf\uff0c\u901a\u8fc7\u89c2\u5bdf\u5176<\/strong>\u626b\u63cf\u96a7\u9053\u663e\u5fae\u955c\u8bf1\u5bfc\u53d1\u5149(STML)\u5149\u8c31\u968f<strong>\u5206\u5b50\u95f4\u8ddd\u7684\u6f14\u53d8\uff0c\u63ed\u793a\u4e86\u4ece\u975e\u76f8\u5e72\u5230\u76f8\u5e72\u7684\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u7684\u6f14\u5316\u8fc7\u7a0b\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u4e3a\u5355\u5206\u5b50\u6c34\u5e73\u7684\u65bd\u4e3b<\/strong><strong>&#8211;<\/strong><strong>\u53d7\u4e3b\u7cfb\u7edf\u4e2d\u7684\u91cf\u5b50\u76f8\u5e72<\/strong>\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb<strong>\u63d0\u4f9b\u4e86\u76f4\u63a5\u7684\u5149\u8c31\u548c\u7a7a\u95f4\u8bc1\u636e\u3002<\/strong>\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a<strong>\u201cWavelike electronic energy transfer in donor\u2013acceptor molecular systems through quantum coherence\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520a<em>Nature Nanotechnology<\/em>\u4e0a\u3002<\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-238319\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/0612.png\" alt=\"\" width=\"697\" height=\"332\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/0612.png 697w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/0612-300x143.png 300w\" sizes=\"(max-width: 697px) 100vw, 697px\" \/><\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u5de7\u5999\u5730\u8bbe\u8ba1\u5e76\u6784\u5efa\u4e86\u5206\u5b50\u7ed3\u6784\uff0c\u5229\u7528\u9ad8\u5206\u8fa8\u7684\u626b\u63cf\u96a7\u9053\u663e\u5fae\u955c\u8bf1\u5bfc\u53d1\u5149\u6280\u672f\uff0c\u89e3\u7b54\u4e86\u4e0a\u9762\u63d0\u5230\u7684\u4e09\u4e2a\u57fa\u672c\u95ee\u9898\uff1a<\/p>\n<p><strong>\uff08<\/strong><strong>1<\/strong><strong>\uff09<\/strong><strong>\u8bc1\u660e\u4e86<\/strong><strong>\u65bd\u4e3b\uff08PtPc<\/strong><strong>\uff09-<\/strong><strong>\u53d7\u4e3b\uff08ZnPc<\/strong><strong>\uff09\u5f02\u4e8c\u805a\u4f53\u7cfb\u7edf\u4e2d\u5b58\u5728\u76f8\u5e72\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb<\/strong><\/p>\n<p><strong>\u4e00\u65b9\u9762\uff0c\u968f\u7740\u5206\u5b50\u95f4\u8ddd\u79bb\u7684\u51cf\u5c0f\uff0c\u5076\u6781\u8026\u5408\u5f3a\u5ea6\u589e\u52a0\uff0c\u5b9e\u9a8c\u89c2\u5bdf\u5230\u5f02\u4e8c\u805a\u4f53\u7684<\/strong>\u626b\u63cf\u96a7\u9053\u663e\u5fae\u955c\u8bf1\u5bfc\u53d1\u5149\u5149\u8c31<strong>\u51fa\u73b0\u4e24\u4e2a\u65b0\u7684\u53d1\u5c04\u5cf0\uff1a\u4e00\u4e2a\u662f\u76f8\u5bf9\u4e8e\u65bd\u4e3b\u53d1\u5149\u80fd\u91cf\u84dd\u79fb\u7684\u5f31\u5cf0\uff0c\u53e6\u4e00\u4e2a\u662f\u76f8\u5bf9\u4e8e\u53d7\u4e3b\u53d1\u5149\u80fd\u91cf\u7ea2\u79fb\u7684\u5f3a\u5cf0\u3002\u7ea2\u79fb\u53d1\u5149\u7684\u7a7a\u95f4\u5206\u8fa8\u5149\u8c31\u56fe\u50cf\u8868\u73b0\u51fa\u7c7b\u4f3c\u03c3\u53cd\u952e\u7684\u5149\u5b50\u5f3a\u5ea6\u5206\u5e03\u6a21\u5f0f\uff0c\u8868\u660e\u5206\u5b50\u6fc0\u53d1\u6001\u53d1\u751f\u4e86\u5171\u7ebf\u540c\u76f8\u53e0\u52a0\uff0c\u6fc0\u53d1\u80fd\u91cf\u79bb\u57df\u5728\u6574\u4e2a\u5f02\u4e8c\u805a\u4f53\u4e0a\u3002<\/strong><strong>\u53e6\u4e00\u65b9\u9762\uff0c\u53d1\u73b0\u65bd\u4e3b\u548c\u53d7\u4e3b\u4e4b\u95f4\u4f20\u80fd\u76f8\u5173\u7684\u80fd\u91cf\u632f\u8361\u9891\u7387\u6bd4\u4efb\u4e00\u4f4d\u70b9\u7684\u80fd\u91cf\u8017\u6563\u8981\u5feb\u3002<\/strong><strong>\u4ee5\u4e0a\u4e24\u70b9\u6e05\u695a\u5730\u8868\u660e\uff0c\u53d1\u751f\u4e86\u6ce2\u72b6\u7684\u91cf\u5b50\u76f8\u5e72<\/strong>\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u3002<\/p>\n<p><strong>\uff08<\/strong><strong>2<\/strong><strong>\uff09<\/strong><strong>\u627e\u5230\u4e86\u975e\u76f8\u5e72\u5230\u76f8\u5e72\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u8fc7\u6e21\u7684\u4e34\u754c\u5206\u5b50\u95f4\u8ddd\u79bb<\/strong><\/p>\n<p><strong>1.72nm<\/strong><strong>\u662f<\/strong>\u975e\u76f8\u5e72\u5230\u76f8\u5e72\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u8fc7\u6e21\u7684\u4e34\u754c\u5206\u5b50\u95f4\u8ddd\u79bb\u3002<strong>\u5f53\u4f9b\u53d7\u4f53\u5206\u5b50\u95f4\u8ddd\u79bb\u5c0f\u4e8e<\/strong><strong>1.72nm<\/strong><strong>\u65f6\uff0c\u80fd\u91cf\u4f20\u9012\u8fc7\u7a0b\u4e2d\u7684\u975e\u76f8\u5e72\u5230\u76f8\u5e72\u7684\u8f6c\u53d8\u5c31\u4f1a\u53d1\u751f\u3002\u800c\u5f53\u5206\u5b50\u95f4\u8ddd\u79bb\u5927\u4e8e\u6216\u7b49\u4e8e<\/strong><strong>1.72 nm<\/strong><strong>\u65f6\uff0c<\/strong>\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb<strong>\u8fc7\u7a0b\u5219\u9075\u5faa<\/strong>F\u00f6rster\u5171\u632f\u80fd\u91cf\u8f6c\u79fb<strong>\u673a\u5236\uff0c\u8868\u73b0\u4e3a\u5355\u5411\u3001\u8df3\u8dc3\u5f0f\u548c\u4e0d\u76f8\u5e72\u7684\u5f62\u5f0f\u3002\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u7684\u901f\u7387\u4e0e\u5206\u5b50\u8ddd\u79bb\u7684<\/strong><strong>6<\/strong><strong>\u6b21\u65b9\u6210\u53cd\u6bd4\u3002<\/strong><\/p>\n<p><strong>\uff08<\/strong><strong>3<\/strong><strong>\uff09<\/strong><strong>\u6bd4\u8f83\u4e86<\/strong><strong>\u76f8\u5e72\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u901a\u9053\u548c\u975e\u76f8\u5e72F\u00f6rster<\/strong><strong>\u5171\u632f\u80fd\u91cf\u8f6c\u79fb\uff08FRET<\/strong><strong>\uff09\u901a\u9053\u7684\u6548\u7387<\/strong><\/p>\n<p>\u5728\u76f8\u90bb\u5206\u5b50\u95f4\u7684\u4e00\u6b65\u4f20\u8f93\u8fc7\u7a0b\u4e2d\uff0c\u76f8\u5e72\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u901a\u9053\u7684\u6548\u7387\u5927\u7ea6\u662f\u975e\u76f8\u5e72\u901a\u9053\u7684\u4e09\u500d\u3002<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><strong>\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n<p><strong>1 \u65bd\u4e3b-\u53d7\u4e3b\u5f02\u4e8c\u805a\u4f53\u4e2d\u7684\u975e\u76f8\u5e72\u80fd\u91cf\u8f6c\u79fb<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-238309\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig1_HTML.png\" alt=\"\" width=\"685\" height=\"788\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig1_HTML.png 685w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig1_HTML-261x300.png 261w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p>\u56fe1 \u915e\u83c1\u94c2\uff08PtPc\uff09\u4e0e\u915e\u83c1\u950c\uff08ZnPc\uff09\u8ddd\u79bb\u76f8\u5bf9\u8f83\u5927\uff08d\u22482.21\u2009nm\uff09\u65f6\uff0cPtPc-ZnPc\u4e8c\u805a\u4f53\u4e2d\u7684\u5206\u5b50\u95f4\u80fd\u91cf\u8f6c\u79fb\uff1a<strong>\uff08a<\/strong><strong>\uff09<\/strong>\u5728 3ML NaCl\/Ag(100) \u4e0a\uff0c\u65bd\u4e3b (D; PtPc) \u548c\u53d7\u4e3b (A; ZnPc) \u5206\u5b50\u4e4b\u95f4\u7684\u5206\u5b50\u95f4\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u7684\u626b\u63cf\u96a7\u9053\u663e\u5fae\u955c\u8bf1\u5bfc\u53d1\u5149\uff08STML\uff09\u5b9e\u9a8c\u793a\u610f\u56fe\uff1b<strong>\uff08<\/strong><strong>b<\/strong><strong>\uff09<\/strong>\u5438\u9644\u5728 3ML NaCl\/Ag(100)\u4e0a\u7684\u5355\u4e2aPtPc\u548cZnPc\u5206\u5b50\u7684 STM \u56fe\u50cf\uff1b<strong>\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong>\u4ece\u5206\u79bb\u7684\u5355\u4e2aPtPc\u548cZnPc\u5206\u5b50\u83b7\u5f97\u7684 STML \u5149\u8c31\uff1b<strong>\uff08<\/strong><strong>d<\/strong><strong>\uff09<\/strong>\u4f4d\u70b9\u76f8\u5173\u7684STML\u5149\u8c31\uff1b<strong>\uff08<\/strong><strong>e<\/strong><strong>\uff09<\/strong>STM \u5f62\u8c8c\u56fe\uff1b<strong>\uff08<\/strong><strong>f-g<\/strong><strong>\uff09<\/strong>STML\u5149\u8c31\u56fe\uff1b<strong>\uff08<\/strong><strong>h<\/strong><strong>\uff09<\/strong>ZnPc Q(0,0) \u5cf0\u80fd\u91cf\u7684\u7a7a\u95f4\u5206\u5e03\uff1b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-238310\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig2_HTML.png\" alt=\"\" width=\"685\" height=\"383\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig2_HTML.png 685w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig2_HTML-300x168.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p>\u56fe2 \u5728PtPC\u4e0eZnPc\u8ddd\u79bb\u76f8\u5bf9\u8f83\u5927\uff08d\u2009\u2265\u20091.72\u2009nm\uff09\u65f6\u51fa\u73b0\u7684\u8df3\u8dc3\u5f0f\u7684F\u00f6rster \u5171\u632f\u80fd\u91cf\u8f6c\u79fb\uff1a<strong>\uff08a<\/strong><strong>\uff09<\/strong>\u968f\u7740\u5206\u5b50\u95f4\u8ddd\u79bb\u7684\u51cf\u5c0f\uff0c\u626b\u63cf\u96a7\u9053\u663e\u5fae\u955c\u8bf1\u5bfc\u53d1\u5149\uff08STML\uff09\u5149\u8c31\u6f14\u53d8\uff1b<strong>\uff08<\/strong><strong>b<\/strong><strong>\uff09<\/strong>\u5728\u4e0d\u540c\u5206\u5b50\u95f4\u8ddd\u79bb d\uff08\u4ece1.41\u2009nm\u52303.16\u2009nm\uff09\u5904 PtPc\uff08\u7a7a\u5fc3\u9ed1\u8272\u5706\u5708\uff09\u548c ZnPc\uff08\u5b9e\u5fc3\u7ea2\u8272\u5706\u5708\uff09\u7684STML \u5f3a\u5ea6\uff1b<strong>\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong>\u4ecePtPc\u5230ZnPc\u7684\u5355\u5411\u80fd\u91cf\u8f6c\u79fb\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<strong>\uff08<\/strong><strong>d-e<\/strong><strong>\uff09<\/strong>d \u2009\u22651.72 nm\u65f6PtPc\u548cZnPc\u5206\u5b50\u4e4b\u95f4\u7684\u5171\u632f\u80fd\u91cf\u8f6c\u79fb\u793a\u610f\u56fe\uff1b<\/p>\n<p>&nbsp;<\/p>\n<p><strong>2<\/strong><strong>\u65bd\u4e3b<\/strong><strong>&#8211;<\/strong><strong>\u53d7\u4e3b\u5f02\u4e8c\u805a\u4f53\u4e2d\u7684\u76f8\u5e72\u80fd\u91cf\u8f6c\u79fb<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-238311\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig3_HTML.png\" alt=\"\" width=\"685\" height=\"438\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig3_HTML.png 685w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig3_HTML-300x192.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p>\u56fe3 \u7d27\u5bc6\u63a5\u89e6PtPc\u2013ZnPc\u5f02\u4e8c\u805a\u4f53\uff08d=1.41nm\uff09\u4e2d\u5076\u6781\u53d6\u5411\u76f8\u5173\u7684\u91cf\u5b50\u76f8\u5e72\u80fd\u91cf\u8f6c\u79fb\uff1a<strong>\uff08a<\/strong><strong>\uff09<\/strong>\u5728\u5f02\u4e8c\u805a\u4f53\u4e0a\u7684\u516d\u4e2a\u4ee3\u8868\u6027\u4f4d\u70b9\u83b7\u5f97\u7684\u4f4d\u70b9\u4f9d\u8d56\u6027STML\u5149\u8c31\uff1b<strong>\uff08<\/strong><strong>b<\/strong><strong>\uff09<\/strong>STM \u5f62\u8c8c\u56fe\uff1b<strong>\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong>\u4e8c\u805a\u4f53\u53d1\u5c04\u5cf0\u7684STML\u5149\u8c31\u56fe\u50cf\uff1b<strong>\uff08<\/strong><strong>d<\/strong><strong>\uff09<\/strong>PtPc\u53d1\u5c04\u5cf0\u7684STML\u5149\u8c31\u56fe\u50cf\uff1b<strong>\uff08<\/strong><strong>e<\/strong><strong>\uff09<\/strong>ZnPc\u53d1\u5c04\u5cf0\u7684STML\u5149\u8c31\u56fe\u50cf\uff1b<strong>\uff08<\/strong><strong>f<\/strong><strong>\uff09<\/strong>\u5f02\u4e8c\u805a\u4f53\u76f8\u5e72\u8026\u5408\u548c\u975e\u76f8\u5e72\u8026\u5408\u53d1\u5c04\u6a21\u5f0f\u7684\u6fc0\u5b50\u76f8\u4e92\u4f5c\u7528\u793a\u610f\u56fe\uff1b<\/p>\n<p>&nbsp;<\/p>\n<p><strong>3 <\/strong><strong>\u8d85\u8d8a\u4e8c\u805a\u4f53\u7684\u5206\u5b50\u7ed3\u6784\u4e2d\u7684\u80fd\u91cf\u4f20\u9012<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-238312\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig4_HTML.png\" alt=\"\" width=\"685\" height=\"839\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig4_HTML.png 685w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig4_HTML-245x300.png 245w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p>\u56fe4 \u901a\u8fc7\u6784\u5efa\u5206\u5b50\u7f51\u7edc\u6bd4\u8f83\u76f8\u5e72\u548c\u975e\u76f8\u5e72\u901a\u9053\u4e4b\u95f4\u7684\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u6548\u7387\uff1a<strong>\uff08a<\/strong><strong>\uff09<\/strong>\u5177\u6709\u76f4\u89d2\u5f62\u72b6\u7684ZnPc\u2013PtPc\u2013ZnPc\u4e09\u805a\u4f53\u7ed3\u6784\u7684\u793a\u610f\u56fe\uff08\u5de6\uff09\u548cSTM\u56fe\u50cf\uff08\u53f3\uff09\uff1b<strong>\uff08b<\/strong><strong>\uff09<\/strong>\u5728\u4e09\u805a\u4f53\u4e0a\u7684\u4ee3\u8868\u6027\u4f4d\u70b9\u83b7\u5f97\u7684\u4f4d\u70b9\u76f8\u5173STML\u5149\u8c31\uff0c\u5982\u56fe\u4e2d\u7684\u5f69\u8272\u5341\u5b57\u6240\u793a\uff1b<strong>\uff08c<\/strong><strong>\uff09<\/strong>STM \u5f62\u8c8c\u56fe\uff1b<strong>\uff08d<\/strong><strong>\uff09<\/strong>\u76f8\u5e72\u53d1\u5c04\u5cf0\u7684\u5149\u8c31\u56fe\u50cf\uff1b<strong>\uff08e<\/strong><strong>\uff09<\/strong>PtPc\u53d1\u5c04\u5cf0\u7684\u5149\u8c31\u56fe\u50cf\uff1b<strong>\uff08f<\/strong><strong>\uff09<\/strong>ZnPc\u53d1\u5c04\u5cf0\u7684\u5149\u8c31\u56fe\u50cf\uff1b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-238313\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig5_HTML.png\" alt=\"\" width=\"685\" height=\"601\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig5_HTML.png 685w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/06\/41565_2022_1142_Fig5_HTML-300x263.png 300w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/p>\n<p>\u56fe5 \u7ebf\u6027\u4e09\u805a\u4f53\u4e2d\u7684\u91cf\u5b50\u76f8\u5e72\u80fd\u91cf\u8f6c\u79fb\uff1a<strong>\uff08a<\/strong><strong>\uff09<\/strong>\u9876\u90e8\uff1aZnPc\u2013PtPc\u2013ZnPc\u4e09\u805a\u4f53\u7ed3\u6784\u793a\u610f\u56fe\uff0c\u4e0b\u56fe\uff1a\u4eba\u5de5\u6784\u5efa\u7684\u7ebf\u6027\u4e09\u805a\u4f53\u7684STM\u56fe\u50cf\uff1b<strong>\uff08b<\/strong><strong>\uff09<\/strong>\u5728\u4e09\u805a\u4f53\u4e0a\u7684\u4e09\u4e2a\u4ee3\u8868\u6027\u4f4d\u70b9\u83b7\u5f97\u7684\u4f4d\u70b9\u76f8\u5173STML\u5149\u8c31\uff0c\u5982\u56fe\u4e2d\u7684\u5f69\u8272\u5341\u5b57\u6240\u793a\uff1b<strong>\uff08c<\/strong><strong>\uff09<\/strong>\u4e09\u805a\u4f53\u6a21\u5f0f\u7684\u5149\u8c31\u56fe\u50cf\uff1b<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><strong>\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p><strong>\uff081<\/strong><strong>\uff09\u968f\u7740\u5206\u5b50\u95f4\u8ddd\u79bb<\/strong>\u7684<strong>\u51cf\u5c0f<\/strong>\uff0c\u65bd\u4e3b(PtPc)\u548c\u53d7\u4e3b(ZnPc)\u4e4b\u95f4\u7684\u5206\u5b50\u95f4\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u8fc7\u7a0b\u4ece<strong>\u975e\u76f8\u5e72\u673a\u5236\u5411\u91cf\u5b50\u76f8\u5e72\u673a\u5236\u8f6c\u53d8<\/strong>\u3002<\/p>\n<p><strong>1<\/strong><strong>\uff09\u5bf9\u4e8ed<\/strong><strong>\u22651.72nm<\/strong><strong>\u65f6\uff0c<\/strong>\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb<strong>\u8fc7\u7a0b<\/strong><strong>\u9075\u5faa<\/strong>F\u00f6rster\u5171\u632f\u80fd\u91cf\u8f6c\u79fb<strong>\u673a\u5236<\/strong><strong>\uff0c\u8868\u73b0\u4e3a\u5355\u5411\u3001\u8df3\u8dc3\u5f0f\u548c\u4e0d\u76f8\u5e72\u7684\u5f62\u5f0f\u3002\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u7684\u901f\u7387\u4e0e\u5206\u5b50\u8ddd\u79bb\u7684<\/strong><strong>6<\/strong><strong>\u6b21\u65b9\u6210\u53cd\u6bd4\u3002<\/strong><\/p>\n<p><strong>2<\/strong><strong>\uff09\u5bf9\u4e8ed \u2009&lt; 1.72 nm<\/strong><strong>\u65f6\uff0c<\/strong>\u7531\u4e8e\u5f3a\u5171\u7ebf\u5076\u6781\u8026\u5408\uff0c\u51fa\u73b0\u4e86\u4e24\u4e2a\u65b0\u7684\u53d1\u5149\u5cf0\uff08P<sub>dimer<\/sub>\u548cP\u2032<sub>dimer<\/sub>\uff09\uff0c\u5176\u4e2dP<sub>dimer<\/sub>\u7684\u53d1\u5149\u73b0\u8c61\u51fa\u73b0\u5728\u5f02\u4e8c\u805a\u4f53\u7684\u5404\u5904\uff0c\u5e76\u8868\u73b0\u51fa\u03c3\u53cd\u952e\u7684\u6210\u50cf\u6a21\u5f0f\uff0c\u8fd9\u8868\u660e\u662f\u4ee5\u53cc\u5411\u7684\u79bb\u57df\u5316\u65b9\u5f0f\u8f6c\u79fb\u3002\u53e6\u5916\uff0c\u53d1\u73b0\u65bd\u4e3b\u548c\u53d7\u4e3b\u4e4b\u95f4\u4f20\u80fd\u76f8\u5173\u7684\u80fd\u91cf\u632f\u8361\u9891\u7387\u6bd4\u4efb\u4e00\u4f4d\u70b9\u7684\u80fd\u91cf\u8017\u6563\u8981\u5feb\u3002<strong>\u5feb\u7684\u632f\u8361\u9891\u7387\uff0c\u52a0\u4e0a\u6fc0\u5b50\u6001\u7684\u79bb\u57df\u6027\u8d28\uff0c\u6e05\u695a\u5730\u8868\u660e\u6ce2\u72b6\u91cf\u5b50\u76f8\u5e72\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u7684\u53d1\u751f\u3002<\/strong><\/p>\n<p>\uff082\uff09\u5728\u76f8\u90bb\u5206\u5b50\u95f4\u7684\u4e00\u6b65\u4f20\u80fd\u8fc7\u7a0b\u4e2d\uff0c<strong>\u76f8\u5e72\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb<\/strong><strong>(EET)<\/strong><strong>\u901a\u9053\u7684\u6548\u7387\u5927\u7ea6\u662f\u975e\u76f8\u5e72\u901a\u9053\u7684\u4e09\u500d\u3002<\/strong>\u672c\u6587\u7684\u7814\u7a76\u7ed3\u679c\u4e3a\u5355\u5206\u5b50\u6c34\u5e73\u7684\u65bd\u4e3b-\u53d7\u4e3b\u7cfb\u7edf\u4e2d\u7684\u91cf\u5b50\u76f8\u5e72\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u63d0\u4f9b\u4e86\u76f4\u63a5\u7684\u5149\u8c31\u548c\u7a7a\u95f4\u8bc1\u636e\u3002\u8fdb\u4e00\u6b65\u7684\u7814\u7a76\u5c06\u4e0e\u8d85\u5feb\u65f6\u95f4\u5206\u8fa8\u5149\u8c31\u76f8\u7ed3\u5408\uff0c\u4ee5\u4fbf\u8fdb\u4e00\u6b65\u4e86\u89e3\u80fd\u91cf\u8f6c\u79fb\u52a8\u529b\u5b66\uff0c\u4e3a\u5408\u7406\u8bbe\u8ba1\u5229\u7528\u76f8\u5e72\u6027\u7684\u4eba\u5de5\u5206\u5b50\u7cfb\u7edf\u63d0\u4f9b\u5168\u9762\u6307\u5bfc\uff0c\u4f7f\u5176\u5728\u5149\u5408\u4f5c\u7528\u3001\u5206\u5b50\u5149\u7535\u548c\u91cf\u5b50\u751f\u7269\u7b49\u4f53\u7cfb\u4e2d\u5b9e\u73b0\u6700\u4f73\u7684\u7535\u5b50\u80fd\u91cf\u8f6c\u79fb\u6548\u7387\u3002<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><strong>\u3010\u56e2\u961f\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u8463\u632f\u8d85\u6559\u6388\u56e2\u961f\u957f\u671f\u4ece\u4e8b\u5355\u5206\u5b50\u7269\u7406\u5316\u5b66\u3001\u5355\u5206\u5b50\u5149\u7535\u5b50\u5b66\u9886\u57df\u7684\u7814\u7a76\u5de5\u4f5c\uff0c\u81f4\u529b\u4e8e\u9762\u5411\u4fe1\u606f\u3001\u80fd\u6e90\u548c\u751f\u7269\u6280\u672f\u7684\u5355\u5206\u5b50\u5149\u7535\u6548\u5e94\u524d\u6cbf\u57fa\u7840\u7814\u7a76\uff0c\u7279\u522b\u662f\u901a\u8fc7\u7814\u5236\u9ad8\u7a7a\u95f4\u5206\u8fa8\u626b\u63cf\u96a7\u9053\u663e\u5fae\u6280\u672f\u4e0e\u9ad8\u7075\u654f\u5355\u5149\u5b50\u68c0\u6d4b\u5149\u5b66\u6280\u672f\u76f8\u878d\u5408\u7684\u8054\u7528\u7cfb\u7edf\uff0c\u6df1\u5165\u5f00\u5c55\u5355\u5206\u5b50\u5c3a\u5ea6\u7684\u5149\u7535\u8c03\u63a7\u548c\u5149\u8c31\u6210\u50cf\u7814\u7a76\uff0c\u5728\u5355\u5206\u5b50\u62c9\u66fc\u6563\u5c04\u3001\u5355\u5206\u5b50\u7535\u81f4\u4e0e\u5149\u81f4\u53d1\u5149\u3001\u5355\u5206\u5b50\u5c3a\u5ea6\u80fd\u91cf\u8f6c\u79fb\u3001\u4ee5\u53ca\u7eb3\u7c73\u7b49\u79bb\u6fc0\u5143\u5149\u5b50\u5b66\u7b49\u65b9\u9762\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u6807\u5fd7\u6027\u6210\u679c\uff0c\u76f8\u5173\u5de5\u4f5c\u53d1\u8868\u5728\u5305\u62ec\u300aNature\u300b\uff082\u7bc7\uff09\u3001\u300aNature Photonics\u300b\uff082\u7bc7\uff09\u3001\u300aNature Nanotechnology\u300b\uff082\u7bc7\uff09\u7b49\u5728\u5185\u7684\u56fd\u5185\u5916\u91cd\u8981\u5b66\u672f\u520a\u7269\u4e0a\u3002\u8bba\u6587\u5355\u7bc7\u6700\u9ad8\u5f15\u7528\u8d85\u5343\u6b21\u3002\u4e9a\u7eb3\u7c73\u5206\u8fa8\u7684\u5355\u5206\u5b50\u62c9\u66fc\u6210\u50cf\u6210\u679c\u5165\u90092013\u5e74\u5ea6\u201c\u4e2d\u56fd\u79d1\u5b66\u5341\u5927\u8fdb\u5c55\u201d\u4ee5\u53ca\u4e24\u9662\u9662\u58eb\u8bc4\u9009\u7684\u201c\u4e2d\u56fd\u5341\u5927\u79d1\u6280\u8fdb\u5c55\u65b0\u95fb\u201d\uff0c\u4e9a\u7eb3\u7c73\u5206\u8fa8\u7684\u5355\u5206\u5b50\u5149\u81f4\u8367\u5149\u6210\u50cf\u6210\u679c\u5165\u90092020\u5e74\u5ea6\u201c\u4e2d\u56fd\u5149\u5b66\u5341\u5927\u8fdb\u5c55\u201d\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a 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