{"id":238324,"date":"2022-06-13T06:16:29","date_gmt":"2022-06-12T22:16:29","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=238324"},"modified":"2022-06-12T20:16:59","modified_gmt":"2022-06-12T12:16:59","slug":"edward-h-sargent%e7%8e%8b%e8%8e%b9-nature-catalysis%ef%bc%9a%e9%ab%98%e7%a2%b3%e5%88%a9%e7%94%a8%e7%8e%87%ef%bc%81%e9%85%b8%e6%80%a7%e4%bb%8b%e8%b4%a8%e4%b8%adco2%e8%bf%98%e5%8e%9f%e4%b8%ba","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=238324","title":{"rendered":"Edward H. Sargent&\u738b\u83b9 Nature Catalysis\uff1a\u9ad8\u78b3\u5229\u7528\u7387\uff01\u9178\u6027\u4ecb\u8d28\u4e2dCO2\u8fd8\u539f\u4e3a\u591a\u78b3\u4ea7\u7269"},"content":{"rendered":"

\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u7531\u53ef\u518d\u751f\u7535\u529b\u9a71\u52a8\u7684CO2<\/sub>\u7535\u8fd8\u539f\uff08CO2<\/sub>RR\uff09\u4ea7\u751f\u7684\u4e59\u70ef\u3001\u4e59\u9187\u7b49\u591a\u78b3\uff08C2+<\/sub>\uff09\u4ea7\u54c1\uff0c\u56e0\u5176\u9ad8\u5e02\u573a\u4ef7\u503c\u800c\u5907\u53d7\u5173\u6ce8\u3002\u5728\u73b0\u6709\u7684\u53cd\u5e94\u5668\u4e2d\uff0c\u78b1\u6027\u6216\u4e2d\u6027pH\u7535\u89e3\u6db2\u901a\u5e38\u7528\u4e8e\u6291\u5236\u7ade\u4e89\u6027\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\uff0c\u540c\u65f6\u4fc3\u8fdb\u975e\u5747\u76f8\u7535\u50ac\u5316\u5242\u4e0a\u7684C-C\u5076\u8054\uff0c\u800cCO2<\/sub>RR\u4f9d\u8d56\u78b1\u6027\u548c\u4e2d\u6027\u7535\u89e3\u8d28\u4f1a\u5bfc\u81f4\u78b3\u9178\u76d0\u7684\u5f62\u6210\u3002\u5728CO2<\/sub>RR\u548cHER\u53cd\u5e94\u4e2d\uff0cH+<\/sup>\u7684\u6d88\u8017\u5728\u50ac\u5316\u5242\u8868\u9762\u9644\u8fd1\u9020\u6210\u5c40\u90e8\u78b1\u6027\u73af\u5883\u3002\u4e00\u4e2aCO2<\/sub>\u5206\u5b50\u4e0e\u4e24\u4e2aOH–<\/sup>\u53cd\u5e94\u4ea7\u751f\u7684CO3<\/sub>2-<\/sup>\uff0c\u4e0d\u5229\u4e8eCO2<\/sub>\u7684\u9ad8\u5229\u7528\u7387\uff08\u6bcf\u603bCO2<\/sub>\u8f93\u5165\u8f6c\u5316\u7684CO2<\/sub>\u767e\u5206\u6bd4\uff09\u3002\u6b64\u5916\uff0c\u78b3\u9178\u76d0\u5411\u9633\u6781\u7684\u8f93\u9001\u548c\u968f\u540e\u7684CO2<\/sub>\u6f14\u5316\u8981\u6c42\u4ece\u9633\u6781\u6d41\u4e2d\u5206\u79bb\u548c\u56de\u6536CO2<\/sub>\uff0c\u6210\u672c\u9ad8\u6602\u3002\u5f53\u4f7f\u7528C2+<\/sub>\u5316\u5b66\u54c1\u65f6\uff0c\u81f3\u5c1175%\u7684\u8f93\u5165CO2<\/sub>\u88ab\u6d88\u8017\u4ee5\u5f62\u6210\u78b3\u9178\u76d0\uff0c\u800c\u4e0d\u662f\u88ab\u8fd8\u539f\uff0c\u8fd9\u662f\u5b9e\u73b0\u9ad8\u6548\u76ca\u7684CO2<\/sub>\u7535\u89e3\u7684\u4e3b\u8981\u969c\u788d\u3002\u6b64\u5916\uff0c\u6db2\u4f53\u4ea7\u54c1\u4ea4\u53c9\u8fd8\u9700\u8981\u89e3\u51b3\uff1a\u7532\u9178\u76d0\u3001\u918b\u9178\u76d0\u548c\u4e59\u9187\u901a\u8fc7\u8fc1\u79fb\u3001\u6269\u6563\u548c\u7535\u6e17\u963b\u529b\u7a7f\u8fc7\u9634\u79bb\u5b50\u4ea4\u6362\u819c\uff08AEM\uff09\uff0c\u5bfc\u81f4\u4ea7\u54c1\u635f\u5931\u3002\u7535\u89e3\u6db2\u4e2d\u7684\u9ad8\u8d28\u5b50\u6d53\u5ea6\u548c\u4f7f\u7528Nafion\u819c\u4f5c\u4e3a\u5206\u79bb\u5668\uff0c\u6709\u671b\u6700\u5927\u9650\u5ea6\u5730\u51cf\u5c11\u78b3\u9178\u76d0\u7684\u5f62\u6210\u548c\u6db2\u4f53\u4ea7\u7269\u7684\u4ea4\u53c9\u3002\u7136\u800c\uff0cCO2<\/sub>RR\u901a\u5e38\u4e0d\u4f1a\u5728\u9178\u6027\u7535\u89e3\u8d28\u4e2d\u6709\u6548\u8fdb\u884c\uff0c\u5c24\u5176\u662f\u751f\u4ea7C2+<\/sub>\u4ea7\u54c1\u65f6\u3002\u6b64\u5916\uff0cH*\u5373HER\u7684\u4e2d\u95f4\u4f53\uff0c\u5728CO2<\/sub>RR\u8fc7\u7a0b\u4e2d\u4e0e\u6d3b\u6027\u4f4d\u70b9\u4e0a\u7684CO*\u5438\u9644\u7ade\u4e89\u3002<\/p>\n

\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u52a0\u62ff\u5927\u591a\u4f26\u591a\u5927\u5b66Edward H. Sargent\u9662\u58eb\u3001\u9999\u6e2f\u4e2d\u6587\u5927\u5b66\u738b\u83b9\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u8bbe\u8ba1\u7b56\u7565\uff0c\u8be5\u7b56\u7565\u901a\u8fc7\u6700\u5927\u5316CO\u548cCO2<\/sub>\u5728Cu\u57fa\u50ac\u5316\u5242\u4e0a\u7684\u5171\u5438\u9644\u4ee5\u524a\u5f31H*\u7ed3\u5408\uff0c\u4ece\u800c\u6291\u5236\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u6d3b\u6027\u3002\u4f5c\u8005\u5f15\u5165\u4e86\u53cc\u91d1\u5c5eX-Cu\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u8c03\u8282\u5c40\u90e8CO*\u8986\u76d6\u5e76\u901a\u8fc7\u5438\u9644\u7269-\u5438\u9644\u7269\u76f8\u4e92\u4f5c\u7528\u6291\u5236H*\u5438\u9644\u3002\u4f5c\u8005\u5229\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\uff0c\u9996\u5148\u7b5b\u9009\u4e86\u5bf9CO*\u5177\u6709\u5f3a\u4eb2\u548c\u529b\u7684\u4e0d\u540c\u91d1\u5c5e\uff0c\u53d1\u73b0Pd-Cu\u50ac\u5316\u5242\u662f\u9178\u6027\u4ecb\u8d28\u4e2d\u50ac\u5316CO2<\/sub>\u8f6c\u5316\u4e3aC2+<\/sub>\u7684\u6700\u6709\u5e0c\u671b\u7684\u5019\u9009\u8005\uff0c\u56e0\u4e3a\u5176\u8868\u73b0\u51fa\u6700\u4f4e\u7684\u0394GOCCOH*<\/sub>\uff0c\u540c\u65f6\u2206GOCCOH*<\/sub>-\u2206GCHO*<\/sub>\u6700\u4f4e\uff0c\u8fd9\u8868\u660e\u5bf9C2+<\/sub>\u4ea7\u7269\u5177\u6709\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002\u5728\u5b9e\u9a8c\u6d4b\u8bd5\u65f6\uff0c\u4f5c\u8005\u5c06Pd-Cu\u53cc\u91d1\u5c5e\u50ac\u5316\u5242\u7528\u4e8e\u5728\u9178\u6027CO2<\/sub>RR\u7535\u89e3\u69fd\u4e2d\uff0c\u800c\u8be5\u7535\u89e3\u69fd\u91c7\u7528\u9178\u6027\u672c\u4f53\u73af\u5883\uff0c\u5e76\u5728\u50ac\u5316\u5242\u8868\u9762\u4ea7\u751f\u5f31\u78b1\u6027\u5c40\u90e8\u73af\u5883\u7684\u6761\u4ef6\u4e0b\u8fd0\u884c\u3002\u8fd9\u79cdpH\u68af\u5ea6\u786e\u4fdd\u5c40\u90e8\u4ea7\u751f\u7684\u78b3\u9178\u76d0\u88ab\u8f6c\u5316\u4e3aCO2<\/sub>\uff0c\u4ee5\u63d0\u9ad8\u78b3\u5229\u7528\u7387\u5e76\u4fc3\u8fdb\u8868\u9762C-C\u8026\u5408\u4ee5\u4ea7\u751fC2+<\/sub>\u3002\u7136\u540e\uff0c\u4f5c\u8005\u5c55\u793a\u4e86\u6db2\u4f53\u4ea7\u54c1\u4ea4\u53c9<0.05%\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a500 mA cm-2<\/sup>\u9178\u6027\u4ecb\u8d28\u4e2d\uff0cCO2<\/sub>\u8f6c\u5316\u4e3aC2+<\/sub>\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff08FE\uff09\u4e3a89\u00b14%\uff0c\u5355\u7a0b\u78b3\u6548\u7387\u4e3a60\u00b12%\uff08\u8003\u8651\u603b\u548c\u65f6\u7684\u603bCO2<\/sub>\u5229\u7528\u7387\u4e3a68\u00b14%\uff0c\u5305\u62ecC1<\/sub>\u548cC2+<\/sub>\u4ea7\u7269\uff09\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cHigh carbon utilization in CO2<\/sub> reduction to multi-carbon products in acidic media\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNature Catalysis<\/em>\u4e0a\u3002
\n \"\"
\n \u3010\u6838\u5fc3\u521b\u65b0\u3011<\/strong><\/p>\n

1\u3001Pd-Cu\u53cc\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\u50ac\u5316CO2<\/sub>\u8f6c\u5316\u4e3aC2+<\/sub>\u65f6\uff0c\u5176\u8868\u73b0\u51fa\u6700\u4f4e\u7684\u0394GOCCOH*<\/sub>\uff0c\u540c\u65f6\u2206GOCCOH*<\/sub>-\u2206GCHO*<\/sub>\u6700\u4f4e\uff0c\u8868\u660e\u5bf9C2+<\/sub>\u4ea7\u7269\u5177\u6709\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002<\/p>\n

2\u3001Pd-Cu\u53cc\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a500 mA cm-2<\/sup>\u9178\u6027\u4ecb\u8d28\u4e2d\uff0cCO2<\/sub>\u8f6c\u5316\u4e3aC2+<\/sub>\u7684FE\u4e3a89\u00b14%\uff0c\u5355\u7a0b\u78b3\u6548\u7387\u4e3a60\u00b12%\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u5c40\u90e8\u7269\u79cd\u60c5\u51b5\uff08CO2<\/sub>\u548cH+<\/sup>\uff09<\/strong>\u00a92022 Springer Nature Limited
\n \"\"\uff08a-b\uff09\u5728\u65bd\u52a0\u7535\u6d41\u5bc6\u5ea6\u4e3a500\u2009mA\u2009cm-2<\/sup>\u4ee5\u53ca\u65bd\u52a0\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\uff08j<\/em>\uff09\u548c\u4f53\u79efpH\u4e0b\u7684\u8868\u9762pH\u503c\u4e0b\uff0c\u5728\u4e0d\u540cpH\u503c\u4e0b\u6eb6\u6db2\u4e2d\u7684\u6a21\u62dfpH\u503c\u53d8\u5316\uff1b<\/p>\n

\uff08c-d\uff09\u4e0d\u540c\u6eb6\u6db2pH\u503c\u4e0bCO2<\/sub>\u7684\u6d53\u5ea6\u5206\u5e03\u548c\u5728\u65bd\u52a0\u7535\u6d41\u5bc6\u5ea6\u4e3a500\u2009mA\u2009cm-2<\/sup>\u4e0b\u6eb6\u6db2\u4e2dpH\u2009=2.0\u7684\u78b3\u9178\u76d0\u5206\u6570\u3002<\/p>\n

\u56fe\u4e8c\u3001\u53cc\u91d1\u5c5eX\u2013Cu(111)\u4e0aCO2<\/sub>RR\u7684DFT\u8ba1\u7b97<\/strong>\u00a92022 Springer Nature Limited
\n \"\"\uff08a\uff09CO2<\/sub>RR\u5bf9C1<\/sub>\u548cC2+<\/sub>\u4ea7\u7269\u76842D C2+<\/sub>\u6d3b\u6027\uff08\u0394GOCCOH*<\/sub>\uff09\u548cC2+<\/sub>\u4e0eC1<\/sub>\u9009\u62e9\u6027\uff08\u0394GOCCOH*<\/sub>-\u0394GCHO*<\/sub>\uff09\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n

\uff08b\uff09CO2<\/sub>RR\u901a\u8fc7CHO\u9014\u5f84\u901a\u5f80C1<\/sub>\u4ea7\u7269\u7684\u81ea\u7531\u80fd\u56fe\uff0c\u4ee5CH4<\/sub>\u7528\u4f5c\u4ee3\u8868\u4ea7\u7269\uff0c\u4ee5\u53caOCCOH\u9014\u5f84\u901a\u5f80C2+<\/sub>\u4ea7\u7269\uff0c\u4ee5C2<\/sub>H4<\/sub>\u7528\u4f5c\u4ee3\u8868\u4ea7\u7269\uff1b<\/p>\n

\uff08c\uff09\u53c2\u4e0e\u751f\u6210C1<\/sub>\u548cC2+<\/sub>\u4ea7\u7269\u7684\u4e0d\u540c\u9014\u5f84\u7684\u9009\u5b9a\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u51e0\u4f55\u5f62\u72b6\u3002<\/p>\n

\u56fe\u4e09\u3001PTFE\u4e0aPd-Cu\u50ac\u5316\u5242\u7684\u7ed3\u6784\u548c\u7ec4\u6210\u8868\u5f81<\/strong>\u00a92022 Springer Nature Limited
\n \"\"\uff08a\uff09\u4e00\u7cfb\u5217\u5177\u6709\u4e0d\u540c\u7535\u7f6e\u6362\u53cd\u5e94\u65f6\u95f4\u7684Pd-Cu\u50ac\u5316\u5242\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

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\uff08d-e\uff09PTFE\u4e0a6.2% Pd-Cu\u50ac\u5316\u5242\u7684Pd\u20093d\u548cCu\u20092p\u7684\u9ad8\u5206\u8fa8\u7387XPS\u5149\u8c31\u3002<\/p>\n

\u56fe\u56db\u3001Pd-Cu\u50ac\u5316\u5242\u7684CO2<\/sub>RR\u6027\u80fd<\/strong>\u00a92022 Springer Nature Limited
\n \"\"\uff08a\uff09\u968f\u7740Pd\u539f\u5b50\u767e\u5206\u6bd4\u7684\u589e\u52a0\uff0cC2+<\/sub>\u4ea7\u7269\u3001C1<\/sub>\u548cH2<\/sub>\u5728PTFE\u4e0a\u4e00\u7cfb\u5217Pd-Cu\u50ac\u5316\u5242\u4e0a\u7684FE\uff1b<\/p>\n

\uff08b-c\uff09\u5728\u4e0d\u540c\u65bd\u52a0\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c6.2% Pd-Cu\u50ac\u5316\u5242\u4e0a\u6240\u6709\u4ea7\u7269\u7684FE\u503c\u548cC2+<\/sub>\u5c40\u90e8\u7535\u6d41\u5bc6\u5ea6\uff1b<\/p>\n

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\uff08f\uff09CO2<\/sub>RR\u5c40\u90e8\u7535\u6d41\u5bc6\u5ea6\u3001C2+<\/sub>\u4ea7\u7269FE\u3001\u6db2\u4f53\u4ea7\u7269\u4ea4\u53c9\u5206\u6570\u3001\u672c\u4f53\u7535\u89e3\u8d28\u7684pH\u503c\u548c6.2% Pd-Cu\u7684SPCE\u4e0e\u6700\u5148\u8fdb\u7684CO2<\/sub>RR\u50ac\u5316\u5242\u7684\u6bd4\u8f83\uff1b<\/p>\n

\uff08g\uff09Pd-Cu\u50ac\u5316\u5242\u5728AEM CO2<\/sub>\u7535\u89e3\u69fd\u4e2d\u8fd0\u884c0.5\u2009h\u540e\u548cNafion CO2<\/sub>\u7535\u89e3\u69fd\u4e2d\u8fd0\u884c4.5\u2009h\u540e\u7684\u4ea7\u7269\u4ea4\u53c9\u3002<\/p>\n

\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u4f4e\u4ea4\u53c9\u7387\u3001\u9ad8\u5355\u7a0b\u78b3\u5229\u7528\u7387\u7684\u7535\u50ac\u5316CO2<\/sub>\u8f6c\u5316\u4e3aC2+<\/sub>\u3002\u6709\u9650\u5143\u4eff\u771f\u6a21\u62df\u7814\u7a76\u8868\u660e\uff0cpH=2.0\u662f\u9178\u6027\u7535\u89e3\u8d28\u4e2dCO2<\/sub>RR\u7684\u6700\u5408\u9002\u53cd\u5e94\u6761\u4ef6\uff0c\u8fd9\u662f\u672c\u4f53pH\u503c\u548c\u78b3\u9178\u76d0\u5f62\u6210\u4e4b\u95f4\u7684\u6709\u6548\u5e73\u8861\u3002DFT\u7ed3\u679c\u8868\u660e\uff0c\u5c06Pd\u5f15\u5165Cu\u589e\u5f3a\u4e86\u5c40\u90e8CO*\u6d53\u5ea6\u4ee5\u4fc3\u8fdbC-C\u8026\u5408\u3002\u5bf9CO*\u7684\u9ad8\u4eb2\u548c\u529b\u4e0eH*\u7684\u6d3b\u6027\u4f4d\u70b9\u7ade\u4e89\u4ee5\u524a\u5f31H\u7ed3\u5408\u80fd\uff0c\u4ece\u800c\u6291\u5236HER\uff0c\u8fdb\u800c\u5b9e\u73b0\u5bf9Pd-Cu\u4e0aC2+<\/sub>\u7684\u9ad8\u9009\u62e9\u6027\u3002\u4f5c\u8005\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u7528\u4e8eCO2<\/sub>RR\u7684Pd-Cu\u50ac\u5316\u5242\uff0c\u5e76\u62a5\u9053\u4e86\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a500 mA cm-2<\/sup>\u4e0bCO2<\/sub>\u8f6c\u5316\u4e3aC2+<\/sub>\u7684\u5355\u7a0b\u78b3\u6548\u7387\u4e3a60%\u3002\u8fd9\u4e9b\u53d1\u73b0\u8868\u660e\u672a\u6765\u5728\u514b\u670dCO2<\/sub>\u7535\u89e3\u69fd\u4e2dCO2<\/sub>\u635f\u5931\u65b9\u9762\u53d6\u5f97\u8fdb\u4e00\u6b65\u8fdb\u5c55\u7684\u65b9\u5411 .<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aHigh carbon utilization in CO2<\/sub> reduction to multi-carbon products in acidic media<\/a><\/strong>. Nature Catalysis<\/em>, 2022<\/strong>, DOI: 10.1038\/s41929-022-00788-1.<\/p>\n

\u56e2\u961f\u4ecb\u7ecd\uff1a<\/strong><\/p>\n

\u738b\u83b9\u6559\u6388\u4e8e2019\u5e747\u6708\u4f5c\u4e3a\u52a9\u7406\u6559\u6388\u52a0\u5165\u9999\u6e2f\u4e2d\u6587\u5927\u5b66\u5316\u5b66\u7cfb<\/strong>\uff0c\u5176\u6bd5\u4e1a\u4e8e\u725b\u6d25\u5927\u5b66\uff0c\u5e08\u4ece\u6b27\u6d32\u79d1\u5b66\u9662\u9662\u58ebRichard G. Compton\u6559\u6388\uff0c\u957f\u671f\u4e13\u6ce8\u4e8e\u7535\u6781\u52a8\u529b\u5b66\u53ca\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u7814\u7a76\u5de5\u4f5c\u3002\u8fd1\u4e94\u5e74\u6765\u4ee5\u7b2c\u4e00\/\u6216\u901a\u8baf\u4f5c\u8005\u5728Nature Catalysis<\/em>\u3001Nature Communications<\/em>\u3001Proceedings of the National Academy of Sciences of the United States of American<\/em>\u3001Chemical Science<\/em>\u3001Chem<\/em>\u3001ACS Energy Letters<\/em>\u7b49\u671f\u520a\u53d1\u8868\u8bba\u658730\u4f59\u7bc7\u3002<\/p>\n

\u8bfe\u9898\u7ec4\u7f51\u9875\uff1ahttps:\/\/ywanggroup.com\/.<\/p>\n

\u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u5de5\u4f5c\u6c47\u603b<\/strong>\uff1a<\/p>\n

1. Z. Xu, M. Sun, Z. Zhang, Y. Xie, H. Hou, X. Ji, T. Liu, B. Huang*, Y. Wang*, Steering the Selectivity of Electrochemical CO2<\/sub> Reduction in Acidic Media, ChemCatChem<\/em>, 2022<\/strong>, e202200052<\/p>\n

2. Z. Zhang, Y. Xie, Y. Wang*, What Matters in the Emerging Application of CO2<\/sub> Electrolysis, Curr. Opin. Electrochem.<\/em>, 2022,<\/strong> 34<\/em>, 101012<\/p>\n

3. Y. Chen1, W. Li1, Y. Yao, P. Gogoi, X. Deng, Y. Xie, Z. Yang, Y. Wang, Y. C. Li, \u201c Enabling Acidic Oxygen Reduction Reaction in Zinc Air Battery with Bipolar Membrane, ACS, Appl, Mater, Interfaces<\/em>, 2022<\/strong>, 14<\/em>, 12257<\/p>\n

\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350<\/strong><\/p>\n

1. CO2<\/sub> electrolysis to multicarbon products in strong acid (DOI: 10.1126\/science.abg6582 )<\/p>\n

2. Absence of CO2<\/sub> electroreduction on copper, gold and silver electrodes without metal cations in solution ( https:\/\/www.nature.com\/articles\/s41929-021-00655-5)<\/p>\n

3. Modulating electric field distribution by alkali cations for CO2<\/sub> electroreduction in strongly acidic medium ( https:\/\/www.nature.com\/articles\/s41929-022-00761-y )<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n

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\n \u2003<\/p>\n","protected":false},"excerpt":{"rendered":"

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