{"id":239139,"date":"2022-07-03T06:59:33","date_gmt":"2022-07-02T22:59:33","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=239139"},"modified":"2022-07-02T21:59:43","modified_gmt":"2022-07-02T13:59:43","slug":"jacs%ef%bc%9aaucd%e5%8f%8c%e9%87%91%e5%b1%9e%e5%9b%a2%e7%b0%87%e5%90%88%e6%88%90%e5%92%8c%e5%8f%af%e9%80%86%e8%bd%ac%e5%8c%96%e7%9a%84%e7%9c%9f%e5%ae%9e%e5%8c%96%e5%ad%a6%e6%80%a7%e8%b4%a8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=239139","title":{"rendered":"JACS\uff1aAuCd\u53cc\u91d1\u5c5e\u56e2\u7c07\u5408\u6210\u548c\u53ef\u9006\u8f6c\u5316\u7684\u771f\u5b9e\u5316\u5b66\u6027\u8d28"},"content":{"rendered":"

\u5bfc<\/strong>\u00a0 <\/strong>\u8bfb<\/strong><\/p>\n

\u5177\u6709\u539f\u5b50\u7cbe\u5ea6\u7684\u91d1\u5c5e\u7c07\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u7eb3\u7c73\u6750\u6599\uff0c\u5e76\u4e14\u8fd1\u5e74\u6765\u5df2\u53d1\u5c55\u6210\u4e3a\u4e00\u4e2a\u65b0\u5174\u9886\u57df\u3002\u7cbe\u786e\u6784\u5efa\u5177\u6709\u539f\u5b50\u7cbe\u5ea6\u7684\u53cc\u91d1\u5c5e\u56e2\u7c07\u4e3a\u6784\u5efa\u5b83\u4eec\u7684\u7ed3\u6784-\u6027\u8d28\u76f8\u5173\u6027\u63d0\u4f9b\u4e86\u7edd\u4f73\u7684\u673a\u4f1a\u3002\u7136\u800c\uff0c\u5316\u5b66(\u524d\u4f53\u7684\u7535\u8377\u72b6\u6001\u3001\u914d\u4f53\u7684\u6027\u8d28\u3001\u63ba\u6742\u5242\u7684\u6570\u91cf\u7b49)\u51b3\u5b9a\u4e86\u5728\u539f\u5b50\u6c34\u5e73\u63a7\u5236\u3001\u5236\u5907\u56e2\u7c07\u4e00\u76f4\u662f\u4e00\u4e2a\u957f\u671f\u7684\u6311\u6218\u3002\u672c\u6587\u57fa\u4e8e\u660e\u786e\u7684Au25<\/sub>(SR)18<\/sub>\u56e2\u7c07(SR=\u786b\u9178\u76d0)\uff0c\u7cfb\u7edf\u5730\u7814\u7a76\u4e86\u914d\u4f53\u7684\u7a7a\u95f4\u4f4d\u963b\u548c\u7535\u5b50\u6548\u5e94\u3001Au25<\/sub>(SR)18<\/sub>\u7535\u8377\u72b6\u6001\u3001\u63ba\u6742\u91cf\u7b49\u56e0\u7d20\u5bf9AuCd\u56e2\u7c07\u7ed3\u6784\u7684\u5f71\u54cd\u3002<\/p>\n

 <\/p>\n

\u6210\u679c\u63a0\u5f71<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u897f\u5317\u5de5\u4e1a\u5927\u5b66\u59da\u4f20\u597d\u6559\u6388\uff0c\u5357\u65b9\u79d1\u6280\u5927\u5b66\u8bb8\u806a\u4fcf\u526f\u7814\u7a76\u5458<\/strong>\u5e26\u9886\u5176\u56e2\u961f<\/strong>\u57fa\u4e8eAu25<\/sub>(SR)18<\/sub>\u56e2\u7c07(SR=\u786b\u9178\u76d0)\uff0c\u7cfb\u7edf\u5730\u7814\u7a76\u4e86\u914d\u4f53\u7684\u7a7a\u95f4\u4f4d\u963b\u548c\u7535\u5b50\u6548\u5e94\u3001Au25<\/sub>(SR)18<\/sub>\u7535\u8377\u72b6\u6001\u3001\u63ba\u6742\u91cf\u7b49\u56e0\u7d20\u5bf9AuCd\u56e2\u7c07\u7ed3\u6784\u7684\u5f71\u54cd\u3002\u7814\u7a76\u53d6\u5f97\u4e86\u5f88\u5927\u7684\u7a81\u7834\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cIdentifying the Real Chemistry of the Synthesis and Reversible Transformation of AuCd Bimetallic Clusters\u201d\u53d1\u8868\u4e8eJACS<\/em><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

 <\/p>\n

\u6838\u5fc3\u521b\u65b0\u70b9<\/strong><\/p>\n

    \n
  1. \u914d\u4f53\u7a7a\u95f4\u4f4d\u963b\u7684\u5927\u5c0f\u4f1a\u5bfc\u81f4\u4e0d\u540c\u7ed3\u6784\u7684\u4ea7\u751f\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5f53\u4f7f\u7528\u7a7a\u95f4\u4f4d\u963b\u8f83\u5c0f\u7684\u914d\u4f53\u65f6\uff0c\u53ef\u4ee5\u5f97\u5230[Au19<\/sub>Cd3<\/sub>(SR)18<\/sub>]\u2212<\/sup>\uff0c\u800c\u5f53\u4f7f\u7528\u7a7a\u95f4\u4f4d\u963b\u8f83\u5927\u7684\u914d\u4f53\u65f6\uff0c\u53ef\u4ee5\u5f97\u5230Au24<\/sub>Cd(SR)18<\/sub>\u3002<\/li>\n<\/ol>\n

     <\/p>\n

      \n
    1. \u901a\u8fc7\u5de7\u5999\u5730\u64cd\u7eb5\u5177\u6709\u4e0d\u540c\u7a7a\u95f4\u4f4d\u963b\u7684\u914d\u4f53\uff0c[Au19<\/sub>Cd3<\/sub>(SR)18<\/sub>]–<\/sup>\u548cAu24<\/sub>Cd(SR)18<\/sub>\u4e4b\u95f4\u53ef\u4ee5\u8fdb\u884c\u53ef\u9006\u8f6c\u5316\u3002\u6b64\u5916\uff0c\u5728Cd\u63ba\u6742\u8fc7\u7a0b\u4e2d\uff0c\u5e26\u8d1f\u7535\u8377\u7684[Au25<\/sub>(SR)18<\/sub>]\u2212<\/sup>\u5bb9\u6613\u5f62\u6210[Au19<\/sub>Cd3<\/sub>(SR)18<\/sub>]\u2212<\/sup>\uff0c\u5f53\u4f7f\u7528\u4e2d\u6027\u7684Au25<\/sub>(SR)18<\/sub>\u4f5c\u4e3a\u524d\u9a71\u4f53\u65f6\uff0c\u4f1a\u4ea7\u751fAu24<\/sub>Cd(SR)18<\/sub>\u3002<\/li>\n<\/ol>\n

       <\/p>\n

      3.\u901a\u8fc7\u5f15\u5165\u8fc7\u91cf\u7684\u63ba\u6742\uff0c\u6210\u529f\u5236\u5907\u4e86\u4e00\u79cd\u65b0\u578b\u53cc\u91d1\u5c5e\u56e2\u7c07Au4<\/sub>Cd4<\/sub>(SR)12<\/sub>\uff0c\u5e76\u5b8c\u5168\u786e\u5b9a\u4e86\u5176\u6574\u4f53\u7ed3\u6784\u3002\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u65b9\u6cd5\u786e\u5b9a\u4e86Au4<\/sub>Cd4<\/sub>(SR)12<\/sub>\u7684\u7535\u5b50\u7ed3\u6784\u548c\u624b\u6027\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u672c\u6587\u62a5\u9053\u7684Au4<\/sub>Cd4<\/sub>(SR)12<\/sub>\u662f\u6700\u5c0f\u7684\u5177\u6709\u624b\u6027\u7684AuCd\u53cc\u91d1\u5c5e\u7c07\u3002<\/p>\n

       <\/p>\n

       <\/p>\n

      \u6570\u636e\u6982\u89c8<\/strong><\/p>\n

      \u00a0<\/strong><\/p>\n

      \u56fe<\/strong>1<\/strong>\u00a0<\/strong> \u7279\u5b9a\u7ed3\u6784\u7684\u7d2b\u5916\u53ef\u89c1\u8fd1\u7ea2\u5916\u5149\u8c31\u53ca\u76f8\u5e94\u7684\u7535\u55b7\u96fe\u7535\u79bb\u8d28\u8c31\u56fe\u3002<\/strong><\/p>\n

      \u00a0\"\"<\/strong><\/p>\n

      \u56fe 2\uff1a [Au19<\/sub>Cd3<\/sub>(4TMBT)18<\/sub>]–<\/sup>, [Au19<\/sub>Cd3<\/sub>(4MOBT)18<\/sub>]\u548c[Au19<\/sub>Cd3<\/sub>(TBBT)18<\/sub>]–<\/sup> \u7684\u7d2b\u5916\u53ef\u89c1\u8fd1\u7ea2\u5916\u5149\u8c31\u56fe\u548c\u76f8\u5e94\u7684\u5206\u5b50\u7ed3\u6784\u3002<\/p>\n

      \u00a0\"\"<\/strong><\/p>\n

      \u00a0<\/strong><\/p>\n

      \u56fe<\/strong>3<\/strong>\uff1a\u4e0d\u540c\u5e26\u7535\u91cf\u7684<\/strong>Au25<\/sub>(PET)18<\/sub>q<\/sup> (q =\u22121\/0)<\/strong>\u4e0e<\/strong>Cd<\/strong>\u4e4b\u95f4\u53cd\u5e94\u7684\u56fe\u89e3\u53ca\u6307\u5b9a\u7ed3\u6784\u7684<\/strong>\u53ef\u89c1\u8fd1\u7ea2\u5916\u5149\u8c31\u56fe\u3002<\/p>\n

      \"\"<\/p>\n

       <\/p>\n

      \u56fe4\uff1aAu24<\/sub>Cd(SR)18<\/sub> and [Au19<\/sub>Cd3<\/sub>(SR)18<\/sub>]–<\/sup>\u4e4b\u95f4\u7684\u53ef\u9006\u8f6c\u5316\u3002<\/p>\n

      \"\"<\/p>\n

       <\/p>\n

      \u56fe5\uff1aAu4<\/sub>Cd4<\/sub>(2,4DMBT)12<\/sub>\u7684\u7d2b\u5916\u53ef\u89c1\u5149\u8c31\u56fe\u3001\u7eb3\u7c73\u7c07\u7ed3\u6784\u3001\u7535\u55b7\u96fe\u7535\u79bb\u8d28\u8c31\u56fe<\/strong>\u7b49\u3002<\/p>\n

      \"\"<\/p>\n

      \u00a0<\/strong><\/p>\n

      \u00a0<\/strong><\/p>\n

      \u5c0f\u7ed3<\/strong><\/p>\n

      \u7814\u7a76\u8868\u660e\uff0c\u4e3a\u4e86\u63ed\u793a\u4e0eCd\u63ba\u6742\u7684\u91d1\u5c5e\u56e2\u7c07\u7684\u771f\u5b9e\u5316\u5b66\u6027\u8d28\u5e76\u7406\u89e3\u5176\u53cd\u5e94\uff0c\u7814\u7a76\u4eba\u5458\u9009\u62e9\u5e26\u8d1f\u7535\u8377\u6216\u5448\u4e2d\u6027\u7684Au25<\/sub>(SR)18<\/sub>\u4f5c\u4e3a\u6a21\u677f\uff0c\u5728\u4e0d\u540c\u7684\u786b\u9187\u914d\u4f53\u8f85\u52a9\u4e0b\u63ba\u6742Cd\u3002\u7ed3\u679c\u8868\u660e\uff0c\u914d\u4f53\u7684\u7a7a\u95f4\u4f4d\u963b\u548c\u524d\u9a71\u4f53(Au25<\/sub>(SR)18<\/sub>q<\/sup>)\u7684\u7535\u8377\u72b6\u6001\u5bf9\u4ea7\u7269\u7684\u9009\u62e9\u6027\u6709\u91cd\u8981\u5f71\u54cd\u3002\u5e26\u8d1f\u7535\u8377\u7684[Au25<\/sub>(SR)18<\/sub>]–<\/sup>\u548c\u7a7a\u95f4\u4f4d\u963b\u8f83\u5c0f\u7684\u914d\u4f53\u66f4\u5bb9\u6613\u751f\u6210[Au19<\/sub>Cd3<\/sub>(SR)18<\/sub>]–<\/sup>\uff0c\u800c\u4f7f\u7528\u4e2d\u6027\u7684Au25<\/sub>(SR)18<\/sub>\u548c\u7a7a\u95f4\u4f4d\u963b\u8f83\u5927\u7684\u914d\u4f53\u66f4\u5bb9\u6613\u751f\u6210Au24<\/sub>Cd(SR)18<\/sub>\u3002\u6709\u8da3\u7684\u662f\uff0c[Au19<\/sub>Cd3<\/sub>(SR)18<\/sub>]–<\/sup>\u548cAu24<\/sub>Cd(SR)18<\/sub>\u4e4b\u95f4\u53ef\u4ee5\u901a\u8fc7\u9009\u62e9\u4e0d\u540c\u914d\u4f53\u6765\u5b9e\u73b0\u53ef\u9006\u8f6c\u5316\u3002<\/p>\n

       <\/p>\n

      \u6700\u91cd\u8981\u7684\u662f\uff0c\u901a\u8fc7\u7cbe\u786e\u63a7\u5236\u5408\u6210\u6761\u4ef6\uff0c\u6210\u529f\u5236\u5907\u4e86\u4e00\u79cd\u65b0\u578b\u624b\u6027\u53cc\u91d1\u5c5e\u7c07\u5408\u7269Au4<\/sub>Cd4<\/sub>(SR)12<\/sub>\uff0c\u5e76\u5b8c\u5168\u786e\u5b9a\u4e86\u5176\u6574\u4f53\u7ed3\u6784\u3002Au4<\/sub>Cd4<\/sub>(SR)12<\/sub>\u7684\u8868\u9762\u91cd\u6784\u548c\u6838\u53d6\u4ee3\u5408\u6210\uff0c\u4e3a\u5236\u5907\u5177\u6709\u7279\u6b8a\u7ed3\u6784\u548c\u6027\u80fd\u7684\u56e2\u7c07\u63d0\u4f9b\u4e86\u65b0\u7684\u9014\u5f84\uff0c\u8fd9\u5f15\u8d77\u4e86\u4eba\u4eec\u5bf9\u53cc\u91d1\u5c5e\/\u5408\u91d1\u56e2\u7c07\u7684\u8bbe\u8ba1\u3001\u5408\u6210\u3001\u6027\u80fd\u7814\u7a76\u548c\u5e94\u7528\u7684\u5174\u8da3<\/p>\n

       <\/p>\n

      \u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1021\/jacs.2c05053<\/p>\n

      DOI\uff1a10.1021\/jacs.2c05053<\/p>\n","protected":false},"excerpt":{"rendered":"

      \u5bfc\u00a0 \u8bfb \u5177\u6709\u539f\u5b50\u7cbe\u5ea6\u7684\u91d1\u5c5e\u7c07\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u7eb3\u7c73\u6750\u6599\uff0c\u5e76\u4e14\u8fd1\u5e74\u6765\u5df2\u53d1\u5c55\u6210\u4e3a\u4e00\u4e2a\u65b0\u5174\u9886\u57df\u3002\u7cbe\u786e\u6784\u5efa\u5177\u6709\u539f\u5b50\u7cbe\u5ea6\u7684\u53cc\u91d1\u5c5e\u56e2\u7c07\u4e3a\u6784\u5efa\u5b83\u4eec\u7684\u7ed3\u6784-\u6027\u8d28\u76f8\u5173\u6027\u63d0\u4f9b\u4e86\u7edd\u4f73\u7684\u673a…<\/p>\n","protected":false},"author":35667,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-239139","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/239139"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/35667"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=239139"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/239139\/revisions"}],"predecessor-version":[{"id":239146,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/239139\/revisions\/239146"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=239139"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=239139"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=239139"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}