{"id":239287,"date":"2022-07-06T06:16:29","date_gmt":"2022-07-05T22:16:29","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=239287"},"modified":"2022-07-05T18:21:18","modified_gmt":"2022-07-05T10:21:18","slug":"%e6%9e%84%e5%bb%ba%e4%b8%89%e7%bb%b4%e5%85%b1%e4%bb%b7%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%e7%9a%84%e5%8a%9f%e8%83%bd%e8%b0%83%e6%8e%a7%e4%b8%8e%e7%a8%b3%e5%ae%9a%e6%80%a7%e5%b7%a5%e7%a8%8b","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=239287","title":{"rendered":"\u6784\u5efa\u4e09\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7684\u529f\u80fd\u8c03\u63a7\u4e0e\u7a33\u5b9a\u6027\u5de5\u7a0b"},"content":{"rendered":"<p>\u4e00\u3001\u5bfc\u8bfb<\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0 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Guan\u3002\u901a\u8fc7\u7814\u7a76\u4e09\u7ef4COF\u6750\u6599\u7684\u5236\u5907\u8bbe\u8ba1\u3001\u6027\u80fd\u4f18\u5316\u8c03\u8282\u548c\u5b9e\u9645\u672a\u6765\u5e94\u7528\uff0c\u5728Accounts of Chemical Research\u4e0a\u4ee5\u201cFunctional Regulation and Stability Engineering of Three Dimensional Covalent Organic Framework\u201d\u4e3a\u9898\u53d1\u8868\u6587\u7ae0\u3002\u5728\u6b64\u6587\u7ae0\u4e2d\uff0c\u901a\u8fc7\u4ecb\u7ecd\u51e0\u79cd\u5236\u5907\u9ad8\u5ea6\u7a33\u5b9a\u76843D COFs\u7b56\u7565\uff1a (1) 3D COFs \u7684\u62d3\u6251\u3001\u94fe\u63a5\u548c\u4e00\u822c\u5408\u6210\u65b9\u6cd5\uff1b (2) \u901a\u8fc7\u9884\u5148\u8bbe\u8ba1\u7684\u6784\u5efa\u5757\u6216\u901a\u8fc7\u5408\u6210\u540e\u529f\u80fd\u5316\u6784\u5efa\u5177\u6709\u4e3b\u52a8\u8fde\u63a5\u7684\u529f\u80fd\u6027 3D COFs\uff1b(3)\u5229\u7528\u7a33\u5065\u8fde\u63a5\u3001\u7a7a\u95f4\u4f4d\u963b\u6548\u5e94\u548c\u758f\u6c34\u5de5\u7a0b\uff1b \u4ee5\u53ca(4) 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(a) \u901a\u8fc7\u79bb\u5b50\u70ed\u5408\u6210\u5236\u5907 3D-IL-COFs \u7684\u7b56\u7565\u3002\uff08b-d\uff09\u5206\u522b\u4e3a 3D-IL-COF-1\u30013D-IL-COF-2 \u548c 3D-IL-COF-3 \u7684\u7ed3\u6784\u8868\u793a\u3002<strong>\u00a9 2022 The Authors<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239289\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/1-1.png\" alt=\"\" width=\"855\" height=\"571\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/1-1.png 855w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/1-1-300x200.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/1-1-768x513.png 768w\" sizes=\"(max-width: 855px) 100vw, 855px\" \/><\/p>\n<p>\u56fe2. (a) BF-COF \u7684\u793a\u610f\u56fe\u3002 (b) BF-COFs \u5728 Knoevenagel \u7f29\u5408\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6027\u80fd\u3002\uff08c\uff09DL-COF \u7684\u793a\u610f\u56fe\u3002 (d) \u50ac\u5316\u6027\u80fdDL-COFs \u5728\u9178\u78b1\u50ac\u5316\u7684\u4e00\u9505\u7ea7\u8054\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u3002<strong>\u00a9 2022 The Authors<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239290\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/2-1.png\" alt=\"\" width=\"858\" height=\"772\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/2-1.png 858w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/2-1-300x270.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/2-1-768x691.png 768w\" sizes=\"(max-width: 858px) 100vw, 858px\" \/><\/p>\n<p>\u56fe3. (a) 3D-\u79bb\u5b50-COF \u7684\u793a\u610f\u56fe\u3002 (b) \u7528 3D-\u79bb\u5b50-COF-1 \u53bb\u9664 MnO<sup>4-<\/sup> \u7684\u7d2b\u5916\u53ef\u89c1\u5149\u8c31\u3002(c) 3D-TTF-COF \u7684\u793a\u610f\u56fe\u3002 (d) JUC-518 \u7684\u65f6\u95f4\u4f9d\u8d56\u6027\u7535\u5bfc\u7387\u3002 <strong>\u00a9 2022 The Authors<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239291\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/3-1.png\" alt=\"\" width=\"871\" height=\"866\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/3-1.png 871w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/3-1-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/3-1-300x298.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/3-1-768x764.png 768w\" sizes=\"(max-width: 871px) 100vw, 871px\" \/><\/p>\n<p>\u56fe4.\uff08a\uff09\u57fa\u4e8e 3D \u51a0\u919a\u7684 COF \u7684\u793a\u610f\u56fe\u3002 (b) JUC-590-MMM \u5728 -1 \u548c +1 V \u65f6\u5bf9\u4e0d\u540c\u91d1\u5c5e\u79bb\u5b50\u7684\u95e8\u63a7\u6bd4\u3002(c) 3D \u8159\u529f\u80fd\u5316 COF \u7684\u793a\u610f\u56fe\u3002(d) \u4e0d\u540c pH \u503c\u4e0b Ara-C \u63a7\u91ca\u7684\u53ef\u9006\u6027\u3002<strong>\u00a9 2022 The Authors<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239292\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/4-1.png\" alt=\"\" width=\"832\" height=\"662\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/4-1.png 832w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/4-1-300x239.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/4-1-768x611.png 768w\" sizes=\"(max-width: 832px) 100vw, 832px\" \/><\/p>\n<p>\u56fe5. (a) 3D-OH-COF \u548c 3D-COOH-COF \u7684\u793a\u610f\u56fe\u548c\u9009\u62e9\u6027\u6d4b\u8bd5\u3002 (b) 3D-Salphen-COFs \u7684\u793a\u610f\u56fe\u3001\u4e0d\u540c\u6d53\u5ea6\u4e0b\u7684\u6e05\u9664\u7387\u548c\u53ef\u56de\u6536\u6027\u7814\u7a76\u3002<strong>\u00a9 2022 The Authors<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239293\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/5-1.png\" alt=\"\" width=\"688\" height=\"728\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/5-1.png 688w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/5-1-284x300.png 284w\" sizes=\"(max-width: 688px) 100vw, 688px\" \/><\/p>\n<p>\u56fe6. \u7528\u4e8e\u5236\u5907\u5177\u6709\u758f\u6c34\u6539\u6027\u7684\u7a33\u5065 3D COF \u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-239294\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/6.png\" alt=\"\" width=\"740\" height=\"608\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/6.png 740w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/07\/6-300x246.png 300w\" sizes=\"(max-width: 740px) 100vw, 740px\" \/><\/p>\n<p>\u56db\u3001\u6210\u679c\u542f\u793a<\/p>\n<p>\u00a0 \u00a0 \u00a0 \u00a0\u6700\u540e\uff0c\u5f3a\u8c03\u4e86\u4e00\u4e9b\u5b9e\u73b0 3D COFs \u6301\u4e45\u653e\u5927\u7684\u65b9\u6cd5\uff0c\u8fd9\u5bf9\u4e8e\u6846\u67b6\u529f\u80fd\u5316\u548c\u5b9e\u9645\u5e94\u7528\u975e\u5e38\u91cd\u8981\u3002\u8fd9\u4e00\u76ee\u6807\u4e0d\u4ec5\u53ef\u4ee5\u901a\u8fc7\u5f15\u5165\u4e00\u4e9b\u989d\u5916\u7684\u5f3a\u5316\u529b\u6765\u5b9e\u73b0\uff0c\u4f8b\u5982\u758f\u6c34\u6548\u5e94\u3001\u5e93\u4ed1\u6392\u65a5\u548c\u7a7a\u95f4\u4f4d\u963b\u6548\u5e94\uff0c\u8fd8\u53ef\u4ee5\u901a\u8fc7\u4f7f\u7528\u7a33\u5065\u7684\u8fde\u63a5\u6765\u589e\u5f3a\u6750\u6599\u6027\u8d28\u7684\u7a33\u5b9a\u6027\u3002\u7531\u4e8e\u5176\u9ad8\u8868\u9762\u79ef\u3001\u591a\u79cd\u4e92\u7a7f\u901a\u9053\u3001\u591a\u79cd\u529f\u80fd\u548c\u826f\u597d\u7684\u7a33\u5b9a\u6027\uff0c3D COFs\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u5728\u5438\u9644\u5206\u79bb\u3001\u591a\u76f8\u50ac\u5316\u3001\u50a8\u80fd\u7b49\u5e7f\u6cdb\u7684\u5e94\u7528\u9886\u57df\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\u3002\u5c3d\u7ba1\u8fd9\u4e9b\u6750\u6599\u7684\u53d1\u5c55\u53d7\u5230\u4e25\u91cd\u7684\u7ed3\u6676\u95ee\u9898\u548c\u7a33\u5b9a\u6027\u9650\u5236\u7684\u9650\u5236\uff0c\u4f46\u5728\u8fc7\u53bb\u5341\u5e74\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u4ed8\u51fa\u4e86\u5de8\u5927\u7684\u52aa\u529b\uff0c\u5e76\u5728 3D COFs \u7684\u5408\u6210\u63a7\u5236\u3001\u529f\u80fd\u5316\u8c03\u63a7\u548c\u7a33\u5b9a\u6027\u589e\u5f3a\u65b9\u9762\u5f00\u53d1\u4e86\u5927\u91cf\u7b56\u7565\u3002\u9884\u8ba1 3D COFs \u5c06\u5728\u672a\u6765\u5f97\u5230\u5b9e\u9645\u5e94\u7528\uff0c\u5e76\u5728\u8fd9\u4e9b\u6750\u6599\u7684\u8bbe\u8ba1\u3001\u5236\u5907\u548c\u529f\u80fd\u5316\u65b9\u9762\u53d6\u5f97\u8fdb\u4e00\u6b65\u8fdb\u5c55\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a Guan X, Fang Q, Yan Y, et al. Functional Regulation and Stability Engineering of Three-Dimensional Covalent Organic Frameworks [J]. Accounts of Chemical Research, 2022. https:\/\/pubs.acs.org\/doi\/10.1021\/acs.accounts.2c00200.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u5bfc\u8bfb \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u4e0d\u540c\u7684\u6750\u6599\u5bf9\u5e94\u4e8e\u7279\u6b8a\u7684\u5b54\u9053\u7c7b\u578b\uff0c\u5982\u901a\u8fc7\u6709\u673a\u5206\u5b50\u548c\u91d1\u5c5e\u6784\u7b51\u7684\u6846\u67b6\u7ed3\u6784\uff08MOFs\uff09\u7684\u5b54\u5177\u6709\u5fae\u5b54\u5c3a\u5ea6\uff0c\u6cb8\u77f3\u5177\u6709\u5fae\u5b54\u7ed3\u6784\uff0c\u901a\u8fc7\u6a21\u7248\u6cd5\u6784\u7b51\u7684\u4e8c&#8230;<\/p>\n","protected":false},"author":35611,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-239287","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/239287"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/35611"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=239287"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/239287\/revisions"}],"predecessor-version":[{"id":239325,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/239287\/revisions\/239325"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=239287"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=239287"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=239287"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}