{"id":239842,"date":"2022-07-16T06:11:33","date_gmt":"2022-07-15T22:11:33","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=239842"},"modified":"2022-07-15T21:17:17","modified_gmt":"2022-07-15T13:17:17","slug":"239842","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=239842","title":{"rendered":"\u4e13\u8bbf\u5510\u672c\u5fe0\u9662\u58eb\u56e2\u961fNat. Commun.\uff1a\u53ef\u5b9e\u73b0\u5355\u5206\u5b50\u767d\u5149\u53d1\u5c04\u7684\u7c07\u53d1\u5149\u56e2"},"content":{"rendered":"

\u4e00\u3001\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u53d1\u5149\u6750\u6599\u4e0d\u4ec5\u7167\u4eae\u4e86\u6211\u4eec\u7684\u751f\u6d3b\uff0c\u800c\u4e14\u5728\u8bb8\u591a\u9ad8\u79d1\u6280\u9886\u57df\u5e26\u6765\u4e86\u6df1\u8fdc\u7684\u9769\u547d\uff0c\u5982\u4fe1\u606f\u52a0\u5bc6\u3001\u751f\u7269\u6210\u50cf\u548c\u4f20\u611f\u5668\u3002\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u4e2d\uff0c\u57fa\u4e8e\u4ef7\u952e\u5171\u8f6d\uff08Through-bond conjugation\uff09\u7684\u5206\u5b50\u5149\u7269\u7406\u7406\u8bba\u4f53\u7cfb\u5df2\u7ecf\u5efa\u7acb\u8d77\u6765\u5e76\u7528\u4e8e\u6307\u5bfc\u9ad8\u6548\u591a\u529f\u80fd\u6709\u673a\u53d1\u5149\u6750\u6599\u7684\u8bbe\u8ba1\u3002\u5176\u4e2d\uff0c\u5177\u6709p\u7535\u5b50\u79bb\u57df\u7684\u5927\u5171\u8f6d\u7ed3\u6784\u88ab\u8ba4\u4e3a\u662f\u5b9e\u73b0\u9ad8\u6548\u53d1\u5149\u6027\u80fd\u7684\u5fc5\u8981\u6761\u4ef6\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u4e00\u4e9b\u975e\u5171\u8f6d\u5206\u5b50\u7684\u805a\u96c6\u4f53\u5728\u7d2b\u5916\u5149\u7167\u5c04\u4e0b\u4e5f\u53ef\u53d1\u51fa\u660e\u4eae\u7684\u53ef\u89c1\u5149\uff0c\u4f8b\u5982\u591a\u7cd6\u5316\u5408\u7269\u548c\u805a\u6c28\u916f\u7b49\u975e\u5171\u8f6d\u5927\u5206\u5b50\u4ee5\u53ca\u4e09\u82ef\u7532\u70f7\u3001\u9a6c\u6765\u9170\u4e9a\u80fa\u3001\u7425\u73c0\u9170\u4e9a\u80fa\u884d\u751f\u7269\u7b49\u975e\u5171\u8f6d\u5c0f\u5206\u5b50\u3002\u8fd9\u4e2a\u53cd\u5e38\u7684\u73b0\u8c61\u8fd1\u5e74\u6765\u5f15\u8d77\u4e86\u7814\u7a76\u8005\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u8fd9\u79cd\u975e\u5e38\u89c4\u7684\u53d1\u5149\u73b0\u8c61\u88ab\u79f0\u4e3a\u7c07\u53d1\u5149\uff08Clusteroluminescence\uff09\uff0c\u5177\u6709\u8fd9\u79cd\u6027\u8d28\u7684\u53d1\u5149\u56e2\u5219\u88ab\u79f0\u4e3a\u7c07\u53d1\u5149\u56e2\uff08Clusteroluminogens\uff09\u3002\u4e0e\u4f20\u7edf\u7684\u65e0\u673a\u6750\u6599\u548c\u5927\u5171\u8f6d\u6709\u673a\u6750\u6599\u76f8\u6bd4\uff0c\u975e\u5171\u8f6d\u7684\u6709\u673a\u6750\u6599\u5177\u6709\u66f4\u597d\u7684\u67d4\u97e7\u6027\u3001\u53ef\u52a0\u5de5\u6027\u3001\u4f4e\u6bd2\u6027\u3001\u66f4\u597d\u7684\u53ef\u964d\u89e3\u6027\u548c\u751f\u7269\u76f8\u5bb9\u6027\uff0c\u662f\u4e00\u79cd\u6f5c\u5728\u7684\u53ef\u7528\u4e8e\u751f\u7269\u4f53\u5185\u7684\u53d1\u5149\u6750\u6599\u3002\u4f20\u7edf\u5206\u5b50\u5149\u7269\u7406\u7406\u8bba\u867d\u7136\u53ef\u4ee5\u89e3\u91ca\u5927\u591a\u6570\u6709\u673a\u5206\u5b50\u7684\u5149\u7269\u7406\u884c\u4e3a\uff0c\u5374\u65e0\u6cd5\u89e3\u91ca\u5b58\u5728\u4e8e\u8fd9\u4e9b\u975e\u5171\u8f6d\u5206\u5b50\u4e2d\u7684\u53d1\u5149\u884c\u4e3a\u3002\u524d\u671f\u7684\u7814\u7a76\u5de5\u4f5c\u8868\u660e\uff0c\u975e\u5171\u8f6d\u5206\u5b50\u95f4\u6216\u5206\u5b50\u5185\u5f3a\u6709\u529b\u7684\u7a7a\u95f4\u76f8\u4e92\u4f5c\u7528\uff08Through-space interactions\uff09\u5bf9\u53ef\u89c1\u5149\u53d1\u5c04\u8d77\u5230\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u4f46\u662f\u5982\u4f55\u8bbe\u8ba1\u5e76\u8c03\u63a7\u7c07\u53d1\u5149\u56e2\u4e2d\u7684\u7a7a\u95f4\u76f8\u4e92\u4f5c\u7528\u4ecd\u7136\u5145\u6ee1\u6311\u6218\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u9999\u6e2f\u79d1\u6280\u5927\u5b66<\/strong>\/<\/strong>\u6d59\u6c5f\u5927\u5b66<\/strong>\u5510\u672c\u5fe0\u9662\u58eb<\/strong>\/<\/strong>\u5f20\u6d69\u53ef\u526f\u7814\u7a76\u5458\u56e2\u961f<\/strong>\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4e09\u4f8b\u5177\u6709\u975e\u5171\u8f6d\u7ed9\u4f53-\u53d7\u4f53\u7ed3\u6784\u548c\u4e0d\u540c\u5364\u7d20\u53d6\u4ee3\u57fa\u7684\u7c07\u53d1\u5149\u5206\u5b50\u3002\u8be5\u8bba\u6587\u4ee5\u9898\u4e3a\u201cSecondary through-space interactions facilitated single-molecule white-light emission from clusteroluminogens\u201d<\/strong>\u53d1\u8868\u5728\u77e5\u540d\u671f\u520a\u300aNature Communications<\/em><\/strong>\u300b\u4e0a\uff0c\u6d59\u6c5f\u5927\u5b66\u5f20\u6d69\u53ef\u526f\u7814\u7a76\u5458\u3001\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u6797\u8363\u4e1a\u6559\u6388\u4e3a\u672c\u6587\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n

\u672c\u6b21\uff0c\u6211\u4eec\u7279\u5730\u9080\u8bf7\u5230\u4e86\u5510\u672c\u5fe0\u9662\u58eb\u3001\u5f20\u6d69\u53ef\u526f\u7814\u7a76\u5458\u548c\u8bba\u6587\u4e00\u4f5c\u5f20\u9274\u4e88\u535a\u58eb\u8fdb\u884c\u4e13\u8bbf\u3002\u8ba9\u6211\u4eec\u4e00\u8d77\u770b\u770b\u4f5c\u8005\u56e2\u961f\u662f\u5982\u4f55\u6df1\u5165\u6d45\u51fa\u5730\u5bf9\u672c\u6b21\u6210\u679c\u8fdb\u884c\u4ecb\u7ecd\u3002<\/p>\n

\u4e8c\u3001\u3010\u4e13\u8bbf\u3011<\/strong><\/p>\n

    \n
  1. \u7c07\u53d1\u5149\u73b0\u8c61\u7684\u5149\u7269\u7406\u7814\u7a76\u5bf9\u5176\u4ed6\u53d1\u5149\u73b0\u8c61\u7684\u542f\u793a\u662f\u4ec0\u4e48\uff1f\u8fd8\u6709\u54ea\u4e9b\u5173\u952e\u79d1\u5b66\u95ee\u9898\u503c\u5f97\u63a2\u7d22\uff1f<\/strong><\/li>\n<\/ol>\n

    \u7b54\uff1a\u5bf9\u4e8e\u975e\u5171\u8f6d\u7ed3\u6784\u7684\u53d1\u5149\uff08\u7c07\u53d1\u5149\uff09\u53ef\u4ee5\u8ffd\u6eaf\u52301605\u5e74\uff0c\u82f1\u56fd\u8457\u540d\u7684\u54f2\u5b66\u5bb6\u5f17\u6717\u897f\u65af\u00b7\u57f9\u6839\u5728\u300aThe Advancement of Learning\u300b\u4e00\u4e66\u4e2d\u6307\u51fa\u4e86\u8517\u7cd6\u7684\u673a\u68b0\u53d1\u5149\u73b0\u8c61\u3002\u8fd1\u5e74\u6765\uff0c\u4eba\u4eec\u4e5f\u9646\u7eed\u5728\u4e00\u4e9b\u5929\u7136\u5316\u5408\u7269\uff08\u5982\u6dc0\u7c89\u3001\u7ea4\u7ef4\u7d20\u3001\u86cb\u767d\u8d28\uff09\u3001\u4eba\u5de5\u5408\u6210\u9ad8\u5206\u5b50\uff08\u5982\u805a\u9170\u4e9a\u80fa\u3001\u805a\u6c28\u916f\u3001\u805a\u4e59\u4e8c\u9187\uff09\u548c\u5c0f\u5206\u5b50\uff08\u5982\u4e09\u82ef\u7532\u70f7\u3001\u9a6c\u6765\u9170\u4e9a\u80fa\u3001\u7425\u73c0\u9170\u4e9a\u80fa\u884d\u751f\u7269\uff09\u4e2d\u89c2\u5bdf\u5230\u7c07\u53d1\u5149\u73b0\u8c61\u3002\u7136\u800c\uff0c\u666e\u904d\u5b58\u5728\u4e8e\u8fd9\u4e9b\u975e\u5171\u8f6d\u5206\u5b50\u4e2d\u7684\u53d1\u5149\u884c\u4e3a\u65e0\u6cd5\u6cbf\u7528\u4f20\u7edf\u7684\u4ef7\u952e\u5171\u8f6d\u7406\u8bba\u53bb\u89e3\u91ca\u3002\u6700\u8fd1\uff0c\u7814\u7a76\u8005\u9010\u6e10\u63ed\u793a\u4e86\u7c07\u53d1\u5149\u662f\u975e\u5171\u8f6d\u5316\u5408\u7269\u81ea\u8eab\u6240\u7279\u6709\u7684\u6027\u8d28\uff0c\u975e\u5171\u8f6d\u5206\u5b50\u95f4\u6216\u5206\u5b50\u5185\u7535\u5b50\u901a\u8fc7\u975e\u5171\u4ef7\u7684\u7a7a\u95f4\u79bb\u57df\u5f62\u6210\u7684\u7a7a\u95f4\u76f8\u4e92\u4f5c\u7528\uff08Through-space interactions\uff09\u8d77\u5230\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002<\/p>\n

    \u7c07\u53d1\u5149\u73b0\u8c61\u7684\u5149\u7269\u7406\u7814\u7a76\u5bf9\u5176\u4ed6\u53d1\u5149\u73b0\u8c61\u7684\u542f\u793a\u662f\uff1a\uff081\uff09\u7ecf\u5178\u7684\u4ef7\u952e\u5171\u8f6d\u7406\u8bba\u5728\u8fc7\u53bb\u6570\u5341\u5e74\u95f4\u6210\u529f\u5730\u6307\u5bfc\u4e86\u6709\u673a\u53d1\u5149\u6750\u6599\u7684\u8bbe\u8ba1\uff0c\u7136\u800c\u7a7a\u95f4\u76f8\u4e92\u4f5c\u7528\u5f15\u8d77\u7684\u7535\u5b50\u7ed3\u6784\u53d8\u5316\u4e5f\u5e94\u8be5\u5f15\u8d77\u4eba\u4eec\u7684\u91cd\u89c6\uff0c\u56e0\u4e3a\u5b83\u540c\u6837\u80fd\u591f\u5bf9\u6750\u6599\u7684\u5149\u7269\u7406\u6027\u8d28\u4ea7\u751f\u6781\u5927\u7684\u5f71\u54cd\u3002\uff082\uff09\u5173\u6ce8\u4ece\u5355\u5206\u5b50\u72b6\u6001\u5230\u805a\u96c6\u4f53\u72b6\u6001\u7684\u7ed3\u6784\u548c\u6027\u80fd\u7684\u53d8\u5316\uff0c\u4e00\u4e9b\u5728\u5355\u5206\u6563\u6001\u65e0\u6cd5\u89c2\u5bdf\u5230\u7684\u73b0\u8c61\u548c\u6027\u8d28\u53ef\u80fd\u5728\u805a\u96c6\u4f53\u72b6\u6001\u4e0b\u5c55\u73b0\u51fa\u6765\u3002\u4e0d\u540c\u4e8e\u4f20\u7edf\u7684\u5206\u5b50\u8bba\uff0c\u6211\u4eec\u9700\u8981\u4ece\u66f4\u52a0\u5b8f\u89c2\u7684\u805a\u96c6\u6001\u53bb\u601d\u8003\u548c\u8ba4\u8bc6\u5404\u79cd\u53d1\u5149\u73b0\u8c61\u3002\u5bf9\u4e8e\u7c07\u53d1\u5149\u4f53\u7cfb\uff0c\u5c24\u5176\u662f\u7eaf\u6709\u673a\u5206\u5b50\u7684\u7c07\u53d1\u5149\uff0c\u5b58\u5728\u7740\u8bf8\u591a\u79d1\u5b66\u95ee\u9898\u7b49\u5f85\u63a2\u7d22\uff0c\u5982\u56e2\u7c07\u7684\u672c\u8d28\u3001\u5c3a\u5bf8\u548c\u7ed3\u6784\u5c1a\u4e0d\u6e05\u6670\uff0c\u56e2\u7c07\u7684\u7269\u7406\u7279\u6027\u4e0d\u6e05\u695a\uff0c\u7c07\u53d1\u5149\u673a\u7406\u5c1a\u672a\u5efa\u7acb\uff0c\u5bf9\u4e8e\u7c07\u7ed3\u6784\u6a21\u578b\u7684\u5efa\u7acb\u548c\u7406\u8bba\u6a21\u62df\u4ecd\u5b58\u5728\u56f0\u96be\u3002<\/p>\n

     <\/p>\n

    2<\/strong>\u3001\u8bf7\u95ee\u5982\u4f55\u53d1\u73b0\u5b64\u7acb\u82ef\u73af\u7535\u5b50\u4f9b\u4f53\u548c\u7535\u5b50\u53d7\u4f53\u7684\u975e\u5171\u8f6d\u5c0f\u5206\u5b50\u53ef\u4ee5\u53d1\u5c04\u767d\u5149\uff1f\u53c8\u662f\u5982\u4f55\u786e\u7acb\u66ff\u6362\u5364\u7d20\u539f\u5b50\u6765\u8fdb\u884c\u8c03\u63a7\uff0c\u7075\u611f\u6765\u81ea\u54ea\u91cc\uff1f<\/strong><\/p>\n

    \u7b54\uff1a\u5728\u524d\u671f\u7684\u7814\u7a76\u4e2d\uff0c\u6211\u4eec\u53d1\u73b0\u4e86\u4e09\u82ef\u7532\u70f7\u5206\u5b50\u81ea\u8eab\u53ef\u4ee5\u4ea7\u751f\u84dd\u8272\u7684\u7c07\u53d1\u5149\u3002\u56e0\u6b64\uff0c\u6211\u4eec\u4e5f\u66fe\u8bd5\u60f3\u80fd\u5426\u5f15\u5165\u66f4\u591a\u7684\u57fa\u56e2\u6216\u8005\u5b64\u7acb\u7684\u82ef\u73af\uff0c\u4f7f\u5f97\u7c07\u53d1\u5149\u884c\u4e3a\u66f4\u52a0\u4e30\u5bcc\u3002\u5f53\u7136\uff0c\u9700\u8981\u627f\u8ba4\u7684\u662f\uff0c\u8be5\u7814\u7a76\u4e2dTPMI-Br\u5206\u5b50\u7684\u767d\u5149\u53d1\u5c04\u662f\u610f\u5916\u53d1\u73b0\u7684\u3002\u7531\u4e8e\u5b83\u8f83\u4e3a\u72ec\u7279\u7684\u7ed3\u6784\u548c\u5149\u7269\u7406\u6027\u8d28\uff0c\u6211\u4eec\u968f\u540e\u901a\u8fc7\u6539\u53d8\u5364\u7d20\u5408\u6210\u4e86\u53e6\u5916\u4e24\u4f8b\u5206\u5b50\uff0c\u5e76\u5bf9\u4ed6\u4eec\u7684\u6784\u6548\u5173\u7cfb\u548c\u5149\u7269\u7406\u884c\u4e3a\u8fdb\u884c\u4e86\u7cfb\u7edf\u6027\u7684\u7814\u7a76\uff0c\u63ed\u793a\u4e86\u5176\u4e2d\u7684\u5149\u7269\u7406\u8fc7\u7a0b\u3002<\/p>\n

    \u5364\u7d20\u539f\u5b50\u5728\u8fd9\u4e00\u4e2a\u4f53\u7cfb\u4e2d\u8d77\u5230\u4e86\u4e24\u4e2a\u4f5c\u7528\uff1a\uff081\uff09\u5229\u7528\u5185\u90e8\u91cd\u539f\u5b50\u6548\u5e94\u589e\u5f3a\u4e86\u7cfb\u95f4\u7a9c\u8d8a\u6548\u7387\uff0c\u4ece\u800c\u5b9e\u73b0\u4e0d\u540c\u5bff\u547d\u7684\u6709\u673a\u5ba4\u6e29\u78f7\u5149\u53d1\u5c04\uff1b\uff082\uff09\u4ece\u6676\u4f53\u7ed3\u6784\u5206\u6790\uff0c\u6bcf\u4e00\u4e2a\u5364\u7d20\u539f\u5b50\u4f1a\u4e0e\u76f8\u90bb\u5206\u5b50\u7684\u4e09\u82ef\u7532\u80fa\u57fa\u56e2\u4ea7\u751f\u76f8\u4e92\u4f5c\u7528\uff0c\u5176\u53ef\u901a\u8fc7\u5916\u90e8\u91cd\u539f\u5b50\u6548\u5e94\u8c03\u8282\u4e09\u82ef\u7532\u80fa\u57fa\u56e2\u4ea7\u751f\u7684\u77ed\u6ce2\u957f\u8367\u5149\u7684\u6548\u7387\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u4e09\u4f8b\u7c07\u53d1\u5149\u5206\u5b50\u5728\u7d2b\u5916\u5149\u6fc0\u53d1\u4e0b\u4ea7\u751f\u7684\u4e24\u4e2a\u8367\u5149\u53d1\u5c04\u5cf0\u5f3a\u5ea6\u7684\u5dee\u5f02\u53ca\u4e0d\u540c\u989c\u8272\u7684\u53d1\u5149\u3002<\/p>\n

     <\/p>\n

    3<\/strong>\u3001\u673a\u5236\u786e\u5b9a\u65b9\u9762\uff0c\u5982\u4f55\u786e\u5b9a\u767d\u5149\u6765\u81ea\u4e8c\u7ea7\u7a7a\u95f4\u76f8\u4e92\u4f5c\u7528\uff08<\/strong>Secondary TSI<\/strong>\uff09\u800c\u975e\u5176\u4ed6\u673a\u5236\uff0c\u4f8b\u5982\u5206\u5b50\u4e0d\u540c\u53d7\u9650\u7a0b\u5ea6\u53d1\u5c04\u4e0d\u540c\u6ce2\u957f\u7684\u5149\uff1f<\/strong><\/p>\n

    \u7b54\uff1a\u8be5\u7814\u7a76\u4e2d\uff0c\u4e09\u4f8b\u7c07\u53d1\u5149\u5206\u5b50\u7684\u8fd1\u4f3c\u767d\u5149\u53d1\u5c04\u662f\u6765\u81ea\u4e8e\u4e09\u4e2a\u4e0d\u540c\u7535\u5b50\u8dc3\u8fc1\u8fc7\u7a0b\uff08\u5373\u4e09\u4e2a\u4e0d\u540c\u6ce2\u957f\u7684\u53d1\u5c04\uff09\uff0c\u800c\u4e8c\u7ea7\u7a7a\u95f4\u76f8\u4e92\u4f5c\u7528\u5219\u662f\u8d21\u732e\u4e86\u5176\u4e2d\u4e00\u4e2a\u6ce2\u957f\u7684\u53d1\u5c04\u3002\u4e3a\u4e86\u63a2\u7a76\u591a\u6ce2\u957f\u7684\u673a\u5236\uff0c\u6211\u4eec\u9996\u5148\u5408\u6210\u4e86\u72ec\u7acb\u7684\u7535\u5b50\u4f9b\u4f53\u548c\u7535\u5b50\u53d7\u4f53\u7684\u6a21\u578b\u5206\u5b50\uff0c\u901a\u8fc7\u5bf9\u6bd4\u6a21\u578b\u5206\u5b50\u4ee5\u53ca\u7b49\u6bd4\u4f8b\u6df7\u5408\u7269\u7684\u5149\u7269\u7406\u6027\u8d28\uff0c\u6392\u9664\u4e86\u5206\u5b50\u95f4\u5f3a\u76f8\u4e92\u4f5c\u7528\u5bf9\u5176\u53d1\u5149\u884c\u4e3a\u7684\u76f4\u63a5\u5f71\u54cd\u3002\u5355\u6676\u7ed3\u6784\u5206\u6790\u8868\u660e\uff0c\u6bcf\u4e00\u4e2a\u5206\u5b50\u53d7\u5230\u7684\u5206\u5b50\u95f4\u4f5c\u7528\u529b\u60c5\u51b5\u662f\u76f8\u540c\u7684\uff0c\u53ef\u4ee5\u6392\u9664\u5206\u5b50\u4e0d\u540c\u53d7\u9650\u7a0b\u5ea6\u53d1\u5c04\u4e0d\u540c\u6ce2\u957f\u5149\u7684\u53ef\u80fd\u6027\u3002\u968f\u540e\uff0c\u6211\u4eec\u5229\u7528\u7406\u8bba\u8ba1\u7b97\u5bf9TPMI-X\u5728\u6fc0\u53d1\u6001\u4e0b\u7684\u7ed3\u6784\u3001\u7535\u8377-\u7a7a\u7a74\u5206\u5e03\u3001\u80fd\u7ea7\u7b49\u8fdb\u884c\u4e86\u5206\u6790\uff0c\u8bc1\u660e\u4e86\u4e09\u4e2a\u53d1\u5c04\u5cf0\u7684\u6765\u6e90\uff0c\u5373\uff1a\uff081\uff09\u4e09\u82ef\u7532\u80fa\u57fa\u56e2\u4e2d\u5b64\u7acb\u82ef\u73af\u95f4\u53ef\u4ee5\u5f62\u6210\u7535\u5b50\u79bb\u57df\uff0c\u5176\u5f62\u6210\u7684\u7a7a\u95f4\u5171\u8f6d\u5b9e\u73b0\u4e86\u77ed\u6ce2\u957f\u7684\u8367\u5149\u53d1\u5c04\uff1b\uff082\uff09\u4e09\u82ef\u7532\u80fa\u57fa\u56e2\u4f5c\u4e3a\u7535\u5b50\u4f9b\u4f53\uff0c\u53ef\u4ee5\u4e0e\u4f5c\u4e3a\u7535\u5b50\u53d7\u4f53\u7684\u82ef\u4e9a\u7532\u80fa\u57fa\u56e2\u5f62\u6210\u7a7a\u95f4\u7535\u8377\u8f6c\u79fb\uff08Through-space charge transfer\uff09\u4f5c\u7528\uff0c\u4ece\u800c\u5b9e\u73b0\u957f\u6ce2\u957f\u7684\u8367\u5149\u53d1\u5c04\uff1b\uff083\uff09\u82ef\u4e9a\u7532\u80fa\u57fa\u56e2\u4e2d\u5364\u7d20\u7684\u91cd\u539f\u5b50\u6548\u5e94\u589e\u5f3a\u4e86\u7cfb\u95f4\u7a9c\u8d8a\u6548\u7387\uff0c\u4ece\u800c\u4ea7\u751f\u4e86\u6709\u673a\u5ba4\u6e29\u78f7\u5149\u53d1\u5c04\u3002<\/p>\n

    \u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u8be5\u7814\u7a76\u4e2d\u53d1\u73b0\u7684\u7a7a\u95f4\u7535\u8377\u8f6c\u79fb\u4f5c\u7528\u53d1\u751f\u5728\u975e\u5171\u9762\u4e14\u5177\u6709\u5b64\u7acb\u82ef\u73af\u7684\u4e09\u82ef\u7532\u80fa\u57fa\u56e2\u548c\u82ef\u4e9a\u7532\u80fa\u57fa\u56e2\u4e4b\u95f4\u3002\u4e09\u82ef\u7532\u80fa\u57fa\u56e2\u81ea\u8eab\u53ef\u4ee5\u5f62\u6210\u7a7a\u95f4\u5171\u8f6d\u4f5c\u7528\uff0c\u5176\u6574\u4f53\u53c8\u53ef\u4ee5\u4f5c\u4e3a\u7535\u5b50\u4f9b\u4f53\u5f62\u6210\u7a7a\u95f4\u7535\u8377\u8f6c\u79fb\uff0c\u56e0\u6b64\u6211\u4eec\u5c06\u8fd9\u79cd\u7a7a\u95f4\u7535\u8377\u8f6c\u79fb\u4f5c\u7528\u79f0\u4e3a\u201c\u4e8c\u7ea7\u7a7a\u95f4\u76f8\u4e92\u4f5c\u7528\uff08Secondary TSI\uff09\u201d\u3002\u7c7b\u4f3c\u4e8e\u86cb\u767d\u8d28\u4e2d\u7684\u4e8c\u7ea7\u7ed3\u6784\uff0c\u201c\u4e8c\u7ea7\u7a7a\u95f4\u76f8\u4e92\u4f5c\u7528\u201d\u4f7f\u5f97\u8fd9\u4e9b\u975e\u5171\u8f6d\u5206\u5b50\u5177\u6709\u66f4\u591a\u7684\u5149\u7269\u7406\u7279\u6027\u548c\u8fc7\u7a0b\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u975e\u5171\u8f6d\u5c0f\u5206\u5b50\u7684\u591a\u91cd\u53d1\u5149\u884c\u4e3a\u3002<\/p>\n

    4<\/strong>\u3001\u60a8\u8ba4\u4e3a\u767d\u5149\u7c07\u53d1\u5149\u7684\u5e94\u7528\u524d\u666f\u4e3b\u8981\u4f53\u73b0\u5728\u54ea\u4e9b\u65b9\u9762\uff1f<\/strong><\/p>\n

    \u7b54\uff1a\u6b63\u5982\u5728\u524d\u8a00\u4e2d\u4ecb\u7ecd\u7684\uff0c\u4e0e\u4f20\u7edf\u7684\u65e0\u673a\u6750\u6599\u548c\u5927\u5171\u8f6d\u6709\u673a\u6750\u6599\u76f8\u6bd4\uff0c\u975e\u5171\u8f6d\u7684\u6709\u673a\u6750\u6599\u5177\u6709\u66f4\u597d\u7684\u67d4\u97e7\u6027\u3001\u53ef\u52a0\u5de5\u6027\u3001\u4f4e\u6bd2\u6027\u3001\u66f4\u597d\u7684\u53ef\u964d\u89e3\u6027\u548c\u826f\u597d\u7684\u751f\u7269\u76f8\u5bb9\u6027\uff0c\u4e5f\u662f\u4e00\u79cd\u6f5c\u5728\u7684\u53ef\u7528\u4e8e\u751f\u7269\u4f53\u5185\u7684\u53d1\u5149\u6750\u6599\u3002\u6839\u636e\u767d\u5149\u6750\u6599\u7684\u7279\u70b9\u53ca\u5176\u9644\u52a0\u529f\u80fd\uff0c\u5176\u80fd\u591f\u88ab\u5e94\u7528\u4e8e\u6709\u673a\u53d1\u5149\u4e8c\u6781\u7ba1\u3001\u767d\u8272\u53d1\u5149\u67d3\u6599\u3001\u5706\u504f\u632f\u8367\u5149\u6750\u6599\u3001\u9632\u4f2a\u6750\u6599\u7b49\u591a\u79cd\u7528\u9014\u3002\u5f53\u7136\uff0c\u76ee\u524d\u5bf9\u4e8e\u7c07\u53d1\u5149\u6750\u6599\u7684\u5e94\u7528\u5b58\u5728\u7740\u8bf8\u591a\u95ee\u9898\uff0c\u5982\u53d1\u5149\u6548\u7387\u4f4e\u3001\u53d1\u5149\u6ce2\u957f\u77ed\u3001\u5bfc\u7535\u6027\u5dee\u7b49\u3002\u867d\u7136\u672c\u6b21\u7814\u7a76\u901a\u8fc7\u6d82\u8986\u6cd5\u5236\u5907\u4e86\u8f83\u4e3a\u7b80\u5355\u7684\u767d\u5149\u53d1\u5c04\u5668\u4ef6\uff0c\u4f46\u662f\u5bf9\u4e8e\u7c07\u53d1\u5149\u7684\u7814\u7a76\u76ee\u524d\u4ecd\u96c6\u4e2d\u4e8e\u5206\u5b50\u7684\u8bbe\u8ba1\u4e0e\u5408\u6210\u3001\u5149\u7269\u7406\u673a\u5236\u7b49\u57fa\u7840\u7814\u7a76\u9636\u6bb5\uff0c\u6211\u4eec\u671f\u5f85\u4e5f\u5c06\u4f1a\u63a2\u7d22\u7c07\u53d1\u5149\u6750\u6599\u5728\u591a\u9886\u57df\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n

    \u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

    \u8fd9\u4e9b\u5316\u5408\u7269\u7684\u6676\u4f53\u8868\u73b0\u51fa\u591a\u91cd\u53d1\u5c04\u751a\u81f3\u5355\u5206\u5b50\u767d\u5149\u53d1\u5c04\u7684\u7279\u6027\uff0c\u5e76\u4e14\u901a\u8fc7\u6539\u53d8\u6fc0\u53d1\u6ce2\u957f\u548c\u5364\u7d20\u53d6\u4ee3\u57fa\u53ef\u4ee5\u5bb9\u6613\u5730\u63a7\u5236\u591a\u91cd\u53d1\u5c04\u5cf0\u7684\u76f8\u5bf9\u5f3a\u5f31\u3002\u540e\u7eed\u7684\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u6210\u529f\u5730\u63ed\u793a\u4e86\u8fd9\u4e9b\u591a\u91cd\u53d1\u5c04\u7684\u7535\u5b50\u6027\u8d28\uff1a\uff081\uff09\u4e09\u82ef\u7532\u80fa\u57fa\u56e2\u4e2d\u5f62\u6210\u7684\u7a7a\u95f4\u5171\u8f6d\uff08Through-space conjugation\uff09\u5b9e\u73b0\u4e86\u77ed\u6ce2\u957f\u7684\u8367\u5149\u53d1\u5c04\uff1b\uff082\uff09\u975e\u5171\u8f6d\u7ed9\u4f53-\u53d7\u4f53\u4e4b\u95f4\u7684\u7a7a\u95f4\u7535\u8377\u8f6c\u79fb\uff08Through-space charge transfer\uff09\u4f5c\u7528\u5b9e\u73b0\u4e86500 nm\u957f\u6ce2\u957f\u7684\u8367\u5149\u53d1\u5c04\uff1b\uff083\uff09\u82ef\u4e9a\u7532\u80fa\u57fa\u56e2\u4e2d\u5364\u7d20\u7684\u91cd\u539f\u5b50\u6548\u5e94\u4fc3\u8fdb\u4e86\u7cfb\u95f4\u7a9c\u8d8a\u8fc7\u7a0b\u5e76\u589e\u5f3a\u4e86\u5ba4\u6e29\u78f7\u5149\u7684\u53d1\u5c04\u3002\u7c07\u53d1\u5149\u5206\u5b50\u4e2d\u7684\u591a\u7ea7\u7a7a\u95f4\u76f8\u4e92\u4f5c\u7528\u4e0d\u4ec5\u4e30\u5bcc\u4e86\u5b83\u4eec\u7684\u5404\u79cd\u5149\u7269\u7406\u6027\u8d28\uff0c\u800c\u4e14\u5bf9\u805a\u96c6\u6001\u5149\u7269\u7406\u673a\u5236\u7684\u5b8c\u6574\u6784\u5efa\u5177\u6709\u91cd\u8981\u7684\u610f\u4e49\u548c\u5f71\u54cd\u3002<\/p>\n

    \"\"<\/p>\n

    \u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/p>\n

    1\u3001\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4e09\u79cd\u5177\u6709\u975e\u5171\u8f6d\u7ed9\u4f53-\u53d7\u4f53\u7ed3\u6784\u548c\u4e0d\u540c\u5364\u7d20\u53d6\u4ee3\u57fa\u7684\u7c07\u53d1\u5149\u5206\u5b50\u3002<\/p>\n

    2\u3001\u6210\u529f\u5730\u5b9e\u73b0\u4e86\u5bf9\u5355\u5206\u5b50\u4e2d\u591a\u7ea7\u7a7a\u95f4\u76f8\u4e92\u4f5c\u7528\u7684\u8c03\u63a7\uff0c\u5b9e\u73b0\u4e86\u591a\u91cd\u53d1\u5c04\u53ca\u5355\u5206\u5b50\u767d\u5149\u53d1\u5c04\u3002<\/p>\n

    3\u3001\u9996\u6b21\u63d0\u51fa\u4e86\u201c\u4e8c\u7ea7\u7a7a\u95f4\u76f8\u4e92\u4f5c\u7528\u201d\u7684\u6982\u5ff5\uff0c\u6709\u671b\u6210\u4e3a\u7c07\u53d1\u5149\u6750\u6599\u4e2d\u91cd\u8981\u7684\u673a\u5236\u3002<\/p>\n

    \u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011<\/strong><\/p>\n

    \u56fe\u4e00\u3001\u5177\u6709\u591a\u91cd\u53d1\u5c04\u7684\u975e\u5171\u8f6d\u5206\u5b50\u7684\u8bbe\u8ba1\u7b56\u7565<\/strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n

    \"\"<\/p>\n

    \uff08a\uff09\u57fa\u4e8e\u4ef7\u952e\u5171\u8f6d\u7ed3\u6784\u5b9e\u73b0\u591a\u91cd\u53d1\u5c04\u7684\u6709\u673a\u5206\u5b50\u8bbe\u8ba1\u7b56\u7565\u3002<\/p>\n

    \uff08b\uff09\u5177\u6709\u591a\u91cd\u53d1\u5c04\u7684\u975e\u5171\u8f6d\u5206\u5b50\u7684\u8bbe\u8ba1\u7b56\u7565\u3002<\/p>\n

    \uff08c\uff09\u672c\u7814\u7a76\u4e2d\u5408\u6210\u7684\u4e09\u4f8b\u7c07\u53d1\u5149\u5206\u5b50\u7684\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

    \uff08d\uff09\u4e09\u4f8b\u7c07\u53d1\u5149\u5206\u5b50\u5728THF\u6eb6\u6db2\u548c\u56fa\u4f53\u72b6\u6001\u7684\u5438\u6536\u5149\u8c31\u3002<\/p>\n

    \u56fe\u4e8c\u3001\u4e09\u4f8b\u7c07\u53d1\u5149\u5206\u5b50\u7684\u5149\u7269\u7406\u6027\u8d28\u8868\u5f81<\/strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n

    \"\"<\/p>\n

    \uff08a-c\uff09\u4e09\u4f8b\u7c07\u53d1\u5149\u5206\u5b50\u7684\u6676\u4f53\u6837\u54c1\u5728\u4e0d\u540c\u6fc0\u53d1\u6ce2\u957f\u4e0b\u7684\u8367\u5149\u5149\u8c31\u3002<\/p>\n

    \uff08d-f\uff09\u5bf9\u5e94\u53d1\u5149\u6ce2\u957f\u7684\u65f6\u95f4\u5206\u8fa8\u8870\u51cf\u66f2\u7ebf\u548c\u8367\u5149\u5bff\u547d\u3002<\/p>\n

    \uff08g\uff09\u957f\u6ce2\u957f\u548c\u77ed\u6ce2\u957f\u53d1\u5c04\u5cf0\u7684\u76f8\u5bf9\u5f3a\u5ea6\u968f\u6fc0\u53d1\u6ce2\u957f\u589e\u957f\u7684\u53d8\u5316\u66f2\u7ebf\u3002<\/p>\n

    \uff08h\uff09TPMI-Br\u6676\u4f53\u5728\u53d1\u5c04\u6ce2\u957f\u4e3a415 nm\u548c500\u2009 nm\u65f6\u7684\u6fc0\u53d1\u5149\u8c31\u3002<\/p>\n

    \uff08i\uff09\u65e0\u5b9a\u578b\u6001\u7684TPMI-Br\u5728\u4e0d\u540c\u6fc0\u53d1\u6ce2\u957f\u4e0b\u7684\u8367\u5149\u5149\u8c31\u548c\u91cf\u5b50\u4ea7\u7387\u3002<\/p>\n

    \u56fe\u4e09\u3001\u4e09\u4f8b\u7c07\u53d1\u5149\u5206\u5b50\u7684\u5ba4\u6e29\u78f7\u5149\u73b0\u8c61<\/strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n

    \"\"<\/p>\n

    \uff08a-c\uff09\u4e09\u4f8b\u7c07\u53d1\u5149\u5206\u5b50\u5728\u6676\u4f53\u72b6\u6001\u4e0b\u7a33\u6001\u548c\u5ef6\u8fdf\u5149\u8c31\u56fe\u3002<\/p>\n

    \uff08d\uff09\u78f7\u5149\u53d1\u5c04\u5cf0\u5728\u5ba4\u6e29\u53ca77 K\u7684\u65f6\u95f4\u5206\u8fa8\u8870\u51cf\u66f2\u7ebf\u53ca\u78f7\u5149\u5bff\u547d\u3002<\/p>\n

    \u56fe\u56db\u3001<\/strong>\u6a21\u578b\u5316\u5408\u7269\u7684\u5149\u7269\u7406\u6027\u8d28\u53ca\u5206\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\u5206\u6790<\/strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n

    \"\"<\/p>\n

    \uff08a\uff09365 nm\u6fc0\u53d1\u6ce2\u957f\u4e0bMe-TPMA\u5728\u56fa\u4f53\u4e2d\u7684\u8367\u5149\u5149\u8c31\u3002<\/p>\n

    \uff08b\uff09\u53d1\u5c04\u6ce2\u957f\u4e3a445 nm\u65f6Me-TPMA\u7684\u6fc0\u53d1\u5149\u8c31\u3002<\/p>\n

    \uff08c\uff09280 nm\u6fc0\u53d1\u6ce2\u957f\u4e0bMe-PMI-Br\u7684\u8367\u5149\u5149\u8c31\u3002<\/p>\n

    \uff08d\uff09\u53d1\u5c04\u6ce2\u957f\u4e3a301 nm\u65f6Me-PMI-Br\u7684\u6fc0\u53d1\u5149\u8c31\u3002<\/p>\n

    \uff08e\uff09\u6469\u5c14\u6bd4\u4e3a1:1\u7684Me-TPMA\/Me-PMI-Br\u56fa\u6001\u6df7\u5408\u7269\u5728\u4e0d\u540c\u6fc0\u53d1\u6ce2\u957f\u4e0b\u7684\u5f52\u4e00\u5316\u8367\u5149\u5149\u8c31\u3002<\/p>\n

    \uff08f\uff09Me-TPMA\/Me-PMI-Br\u56fa\u6001\u6df7\u5408\u7269\u5728533 nm\u53d1\u5c04\u4e0b\u7684\u6fc0\u53d1\u5149\u8c31\u3002<\/p>\n

    \uff08g\uff09\u57fa\u4e8e\u5355\u6676\u7ed3\u6784\u7684Hirshfeld\u8868\u9762\u53ca\u5206\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\u5206\u6790\u3002<\/p>\n

    \u56fe\u4e94\u3001\u7c07\u53d1\u5149\u56e2\u7684\u591a\u91cd\u53d1\u5c04\u673a\u5236\u63a2\u7a76<\/strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n

    \"\"<\/p>\n

    \uff08a\uff09TPMI-Br\u5728\u6fc0\u53d1\u6001\u4e0b\u7684\u4e09\u79cd\u7a7a\u7a74-\u7535\u5b50\u5206\u5e03\u3002<\/p>\n

    \uff08b-c\uff09N1<\/sub>-N2<\/sub>\u8ddd\u79bb\u4ee5\u53ca\u4e8c\u9762\u89d2\u2220N1<\/sub>-C1<\/sub>-C2<\/sub>-N2<\/sub>\u968fTPMI-Br\u4ece\u57fa\u6001\u5230\u6fc0\u53d1\u6001\u7684\u53d8\u5316\u66f2\u7ebf\u3002<\/p>\n

    \uff08d\uff09TPMI-Br\u5728\u6676\u6001\u4e0b\u7684\u80fd\u7ea7\u56fe\u53ca\u81ea\u65cb\u8f68\u9053\u8026\u5408\u5e38\u6570\u3002<\/p>\n

    \uff08e\uff09TPMI-Br\u5728\u6eb6\u6db2\u53ca\u6676\u6001\u4e0b\u6700\u4f18\u57fa\u6001\u4e0e\u6fc0\u53d1\u6001\u7ed3\u6784\u7684\u91cd\u53e0\u56fe\u53caRSMD\u6570\u503c\u3002<\/p>\n

    \uff08f\uff09\u6240\u8bbe\u8ba1\u7684\u7c07\u53d1\u5149\u56e2\u5b9e\u73b0\u591a\u91cd\u53d1\u5c04\u7684\u52bf\u80fd\u9762\u548c\u7535\u5b50\u8dc3\u8fc1\u884c\u4e3a\u793a\u610f\u56fe\u3002<\/p>\n

    \u56fe\u516d\u3001\u5206\u5b50\u70ed\u7a33\u5b9a\u6027\u4e0e\u767d\u5149\u53d1\u5c04\u5668\u4ef6\u7684\u6027\u80fd<\/strong> \u00a9 2022 Springer Nature<\/strong><\/p>\n

    \"\"<\/p>\n

    \uff08a\uff09\u4e09\u4f8b\u7c07\u53d1\u5149\u5206\u5b50\u7684\u70ed\u91cd\u5206\u6790\u548c\u5206\u89e3\u6e29\u5ea6\u3002<\/p>\n

    \uff08b\uff09\u5728\u5546\u7528\u7d2b\u5916\u5149LED\u706f\u4e0a\u6d82\u8986TPMI-Br\u5fae\u6676\u548c\u73af\u6c27\u6811\u8102\u5236\u5907\u7684\u767d\u5149\u53d1\u5c04\u5668\u4ef6\u7684\u5149\u8c31\u548c\u7167\u7247\u3002<\/p>\n

    \uff08c\uff09\u767d\u5149\u53d1\u5c04\u5668\u4ef6\u7684CIE\u8272\u5750\u6807\u3002<\/p>\n

    \u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n

    \u7efc\u4e0a\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u5236\u5907\u4e86\u4e09\u4f8b\u975e\u5171\u8f6d\u7684\u7c07\u53d1\u5149\u5206\u5b50\uff0c\u5e76\u5bf9\u5176\u5149\u7269\u7406\u6027\u8d28\u8fdb\u884c\u4e86\u7cfb\u7edf\u6027\u7684\u7814\u7a76\u3002\u6240\u6709\u5316\u5408\u7269\u5728\u6676\u4f53\u72b6\u6001\u4e0b\u90fd\u663e\u793a\u51fa\u7531\u4e24\u4e2a\u8367\u5149\u548c\u4e00\u4e2a\u5ba4\u6e29\u78f7\u5149\u7ec4\u6210\u7684\u591a\u91cd\u53d1\u5c04\uff0c\u6700\u9ad8\u7edd\u5bf9\u91cf\u5b50\u4ea7\u7387\u4e3a34.8%\u3002\u901a\u8fc7\u6539\u53d8\u5364\u7d20\u53d6\u4ee3\u57fa\u548c\u6fc0\u53d1\u6ce2\u957f\uff0c\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u63a7\u5236\u8fd9\u4e9b\u591a\u91cd\u53d1\u5c04\u7684\u5f3a\u5ea6\u6bd4\u4f8b\uff0c\u751a\u81f3\u5b9e\u73b0\u5355\u5206\u5b50\u767d\u5149\u53d1\u5c04\u3002\u540c\u65f6\uff0c\u8be5\u7814\u7a76\u4e2d\u9996\u6b21\u63d0\u51fa\u4e86\u201c\u4e8c\u7ea7\u7a7a\u95f4\u76f8\u4e92\u4f5c\u7528\u201d\u7684\u6982\u5ff5\uff0c\u5176\u4e0d\u4ec5\u6709\u671b\u6210\u4e3a\u7c07\u53d1\u5149\u6750\u6599\u4e2d\u666e\u904d\u5b58\u5728\u7684\u673a\u5236\uff0c\u4e5f\u5bf9\u805a\u96c6\u6001\u5149\u7269\u7406\u673a\u5236\u7684\u5b8c\u6574\u6784\u5efa\u5177\u6709\u91cd\u8981\u7684\u610f\u4e49\u548c\u5f71\u54cd\u3002<\/p>\n

    \u6587\u732e\u94fe\u63a5\uff1aSecondary through-space interactions facilitated single-molecule white-light emission from clusteroluminogens<\/a> ( Nat. Commun. <\/em>2022<\/strong>, 13, 3492. DOI: 10.1038\/s41467-022-31184-9)<\/p>\n

    \u672c\u6587\u7531\u8d5b\u6069\u65af\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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