{"id":239965,"date":"2022-07-19T07:25:27","date_gmt":"2022-07-18T23:25:27","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=239965"},"modified":"2022-07-18T18:33:25","modified_gmt":"2022-07-18T10:33:25","slug":"%e5%94%90%e6%9c%ac%e5%bf%a0%e5%9b%a2%e9%98%9fnat-commun-%ef%bc%9a%e5%85%89%e7%83%ad%e8%af%b1%e5%af%bc%e7%9a%84%e5%ae%a4%e6%b8%a9%e7%a3%b7%e5%85%89","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=239965","title":{"rendered":"\u5510\u672c\u5fe0\u56e2\u961fNat. Commun.\uff1a\u5149\u70ed\u8bf1\u5bfc\u7684\u5ba4\u6e29\u78f7\u5149"},"content":{"rendered":"

\u4e00\u3001<\/strong>\u3010<\/strong>\u5bfc\u8bfb<\/strong>\u3011<\/strong><\/p>\n

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\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0cNature <\/em><\/strong>Communications<\/em><\/strong>\u4ee5\u9898\u4e3a\u201cPhoto-thermo-induced room-temperature phosphorescence through solid-state molecular motion<\/strong>\u201d\u5728\u7ebf\u520a\u53d1\u4e86\u5510\u672c\u5fe0\u9662\u58eb\u56e2\u961f<\/strong>\u5173\u4e8e\u5149\u70ed\u54cd\u5e94\u5ba4\u6e29\u78f7\u5149\u6750\u6599\u7684\u6587\u7ae0\u3002\u8be5\u56e2\u961f\u8bbe\u8ba1\u5e76\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u5305\u542b\u4e09\u55ea\u6838\u548c\u4e09\u4e2a\u6eb4\u8054\u82ef\u5355\u5143\u7684\u5206\u5b50\u8f6c\u5b50\uff1ao-Br-TRZ\u3001m-Br-TRZ\u548cp-Br-TRZ\u3002\u6eb4\u548c\u4e09\u55ea\u90e8\u5206\u7528\u4f5c\u5ba4\u6e29\u78f7\u5149\u6d3b\u6027\u5355\u5143\uff0c\u6eb4\u8054\u82ef\u5355\u5143\u7528\u4f5c\u8f6c\u5b50\u4ee5\u9a71\u52a8\u5206\u5b50\u5185\u65cb\u8f6c\u3002\u5f53\u53d7\u5230\u5f3a\u7d2b\u5916\u5149\u7167\u5c04\u65f6\uff0co-Br-TRZ\u3001m-Br-TRZ\u548cp-Br-TRZ\u7684\u5206\u5b50\u5185\u65cb\u8f6c\u589e\u52a0\uff0c\u4ece\u800c\u901a\u8fc7\u5206\u5b50\u8fd0\u52a8\u4ea7\u751f\u5149\u70ed\u6548\u5e94\u3002\u4ee4\u4eba\u5370\u8c61\u6df1\u523b\u7684\u662f\uff0cp-Br-TRZ\u83b7\u5f97\u7684\u5149\u70ed\u6e29\u5ea6\u9ad8\u8fbe102\u2009\u2103\u65f6\uff0c\u7531\u4e8e\u5206\u5b50\u8fd0\u52a8\u540e\u7684\u6709\u5e8f\u5206\u5b50\u6392\u5217\uff0c\u540c\u6b65\u89e6\u53d1\u5176\u78f7\u5149\u3002\u70ed\u6548\u5e94\u5bf9\u4e8e\u89e6\u53d1\u6709\u6548\u7684\u78f7\u5149\u975e\u5e38\u91cd\u8981\uff0c\u5149\u5b50\u8f93\u5165\u5bf9\u4e8e\u63d0\u4f9b\u7cbe\u786e\u548c\u65e0\u521b\u7684\u523a\u6fc0\u975e\u5e38\u91cd\u8981\u3002\u8fd9\u79cd\u8fde\u7eed\u7684\u5149\u70ed\u78f7\u5149\u8f6c\u6362\u6709\u671b\u5f00\u53d1\u51fa\u4e00\u79cd\u65b0\u578b\u65e0\u521b\u3001\u523a\u6fc0\u54cd\u5e94\u78f7\u5149\u6750\u6599\u3002\u6df1\u5733\u5927\u5b66\u4e3a\u672c\u8bba\u6587\u7b2c\u4e00\u5355\u4f4d\uff0c\u6df1\u5733\u5927\u5b66\u4f59\u632f\u5f3a\u526f\u6559\u6388\u3001Wu Yue\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n

1\u3001\u8bbe\u8ba1\u5e76\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u5206\u5b50\u8f6c\u5b50\uff1ao-Br-TRZ\u3001m-Br-TRZ\u548cp-Br-TRZ\uff0c\u6eb4\u548c\u4e09\u55ea\u90e8\u5206\u7528\u4f5c\u5ba4\u6e29\u78f7\u5149\u6d3b\u6027\u5355\u5143\uff0c\u6eb4\u8054\u82ef\u5355\u5143\u7528\u4f5c\u8f6c\u5b50\u4ee5\u9a71\u52a8\u5206\u5b50\u5185\u65cb\u8f6c\u3002<\/p>\n

2\u3001\u7d2b\u5916\u5149\u7167\u540e\uff0c\u5206\u5b50\u5185\u65cb\u8f6c\u589e\u52a0\uff0c\u4ece\u800c\u901a\u8fc7\u5206\u5b50\u8fd0\u52a8\u4ea7\u751f\u5149\u70ed\u6548\u5e94\u3002<\/p>\n

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\u56fe\u4e09\u3001<\/strong>\u4e09\u55ea\u884d\u751f\u7269\u7684\u5149\u70ed\u6548\u5e94<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe<\/strong>\u56db\u3001\u70ed\u6548\u5e94\u6fc0\u6d3b\u7684RTP<\/strong><\/p>\n

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\uff08c\uff09\u5728-40\u2103\u4e0b\u7d2b\u5916\u7ebf\u8f90\u7167\uff08365 nm\uff0c516 mW\/cm2<\/sup>\uff09\u524d\u540ep<\/em>-Br-TRZ\u7684\u53d1\u5c04\u5149\u8c31\u3002<\/p>\n

\u56fe<\/strong>\u4e94\u3001\u5149\u529f\u7387\u54cd\u5e94RTP\u53ca\u5176\u5e94\u7528<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5c06\u7d2b\u5916\u5149\u7684\u529f\u7387\u4ece0\u589e\u52a0\u5230516 mW\/cm2<\/sup>\u7c89\u672b\u72b6p<\/em>-BR-TRZ\u7684\u5149\u70ed\u6e29\u5ea6\u7684\u53d8\u5316\uff0c\u8868\u660e\u5149\u70ed\u6e29\u5ea6\u548c\u8f90\u7167\u529f\u7387\u4e4b\u95f4\u5b58\u5728\u7ebf\u6027\u5173\u7cfb\u3002<\/p>\n

\uff08b\uff09p<\/em>-BR-TRZ\u4e0e365 nm\u5149\u7684\u529f\u7387\u4e0e\u6ce2\u957f\u7684\u53d1\u5149\u7684\u4e09\u7ef4\u56fe\u663e\u793a\u4e86\u589e\u5f3a\u8f90\u5c04\u529f\u7387\u589e\u5f3a\u78f7\u5149\u548c\u78f7\u5149\/\u8367\u5149\u5f3a\u5ea6\u6bd4\u7684\u52a8\u529b\u5b66\u3002<\/p>\n

\uff08c\uff09\u4e0d\u540c\u7684\u529f\u7387365 nm\u5149\u8f90\u7167\u7684p<\/em>-BR-TRZ\uff0c\u4e0e\uff08b\uff09\u4e2d\u5bf9\u5e94\u7684CIE\u5750\u6807\u56fe\u3002<\/p>\n

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\u4e94\u3001\u3010\u524d\u666f\u5c55\u671b\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aPhoto-thermo-induced room-temperature phosphorescence through solid-state molecular motion<\/u><\/a>\u00a0(\u00a0Nat. <\/em>Commun.,<\/em>\u00a0<\/em>2022<\/strong>, DOI:\u00a010.1038\/s41467-022-31481-3)<\/p>\n

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