{"id":240995,"date":"2022-08-13T06:08:25","date_gmt":"2022-08-12T22:08:25","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=240995"},"modified":"2022-08-12T17:37:33","modified_gmt":"2022-08-12T09:37:33","slug":"%e9%9f%a9%e5%9b%bd%e4%b8%89%e6%98%9fnature%e9%ab%98%e6%95%88%e7%9a%84%e7%ba%b3%e7%b1%b3%e5%b0%ba%e5%af%b8ingan%e5%8f%91%e5%85%89%e4%ba%8c%e6%9e%81%e7%ae%a1","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=240995","title":{"rendered":"\u97e9\u56fd\u4e09\u661fNature:\u9ad8\u6548\u7684\u7eb3\u7c73\u5c3a\u5bf8InGaN\u53d1\u5149\u4e8c\u6781\u7ba1"},"content":{"rendered":"<p><strong><b>\u4e00\u3001<\/b><\/strong><strong><b>\u3010\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p>\u968f\u7740\u53d1\u6280\u672f\u7684\u4e0d\u65ad\u8fdb\u6b65\uff0c\u5149\u7535\u4e8c\u6781\u7ba1\uff08LED\uff09\u88ab\u7528\u4e8e\u5404\u79cd\u5e94\u7528\uff0c\u5982\u56fa\u6001\u7167\u660e\u3001\u663e\u793a\u5668\u3001\u5149\u6570\u636e\u901a\u4fe1\u548c\u5149\u5b50\u5b66\u3002\u5176\u4e2d\u4eba\u7c7b\u5bf9\u9ad8\u4eae\u5ea6\u548c\u9ad8\u5bf9\u6bd4\u5ea6\u663e\u793a\u5668\u5e94\u7528\u7684\u5de8\u5927\u9700\u6c42\u6781\u5927\u5730\u63a8\u52a8\u4e86\u5fae\u578bLED\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u76ee\u524d\uff0c\u5fae\u7c73\u7ea7\u5c3a\u5bf8\u7684LED\u9762\u4e34\u7740\u5c3a\u5bf8\u8d8a\u4f4e\uff0c\u5916\u91cf\u5b50\u6548\u7387\uff08EQE\uff09\u8d8a\u4f4e\u7684\u95ee\u9898\uff0c\u8fd9\u662f\u7531\u4e8e\u5c0f\u82af\u7247\u5c3a\u5bf8\u7684\u8868\u9762\u4f53\u79ef\u66f4\u5927\uff0c\u5bfc\u81f4\u5176\u8868\u9762\u7684\u975e\u8f90\u5c04\u590d\u5408\u635f\u8017\u589e\u52a0\u3002\u636e\u62a5\u9053\uff0c\u84dd\u8272InGaN-LED\u7684EQE\u4ece\u6a2a\u5411\u5c3a\u5bf810\u00a0\u03bcm\u4e0b\u7684~10%\uff0c\u4e0b\u964d\u52301\u03bcm\u5c3a\u5bf8\u65f6\u7684~2-3%\u3002\u56e0\u6b64\uff0c\u867d\u7136nLED\u663e\u793a\u5c4f\u5728\u5b9e\u73b0\u9ad8\u6027\u80fd\u663e\u793a\u5668\u65b9\u9762\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\uff0c\u4f46\u901a\u8fc7\u514b\u670d\u4e0e\u5c3a\u5bf8\u76f8\u5173\u7684EQE\u51cf\u5c0f\u95ee\u9898\u6765\u5f00\u53d1\u9ad8\u6548\u7684\u5fae\u578bLED\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002<\/p>\n<p><strong><b>\u4e8c\u3001<\/b><\/strong><strong><b>\u3010\u6210\u679c\u63a0\u5f71\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u6765\u81ea\u97e9\u56fd\u4e09\u661f\u663e\u793a\u516c\u53f8\u7684Mihyang Sheen\uff0cChanghee Lee\u7b49\u4eba\u5728<strong><em><i>Nature<\/i><\/em><\/strong>\u4e0a\u5728\u7ebf\u62a5\u9053\u4e86\u4e00\u79cd\u5177\u6709\u9ad8EQE\u7684\u84dd\u8272InGaN \/ GaN\u591a\u91cf\u5b50\u9631\uff08MQW\uff09\u7eb3\u7c73\u68d2LED\uff08nLED\uff09\uff0c\u9898\u76ee\u4e3a\u201cHighly efficient blue InGaN nanoscale light-emitting diodes\u201d\u3002\u7814\u7a76\u8005\u7cfb\u7edf\u5730\u5206\u6790\u7814\u7a76\u4e86GaN\u8868\u9762\u4e0e\u4fa7\u58c1\u949d\u5316\u5c42\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u901a\u8fc7\u6eb6\u80f6-\u51dd\u80f6\u6cd5\u5c06SiO<sub>2<\/sub>\u7eb3\u7c73\u9897\u7c92\u5438\u9644\u5728GaN\u8868\u9762\uff0c\u5b9e\u73b0\u4e86\u6709\u6548\u7684\u8868\u9762\u949d\u5316\uff0c\u964d\u4f4e\u4e86\u975e\u8f90\u5c04\u590d\u5408\uff0c\u514b\u670d\u4e86\u4e0e\u5c3a\u5bf8\u76f8\u5173\u7684EQE\u51cf\u5c0f\u95ee\u9898\uff0c\u5b9e\u73b0\u4e86\u5cf0\u503cEQE\u8fbe<strong>20.2\u2009\u00b1\u20090.6%<\/strong>\u7684\u65b0\u578bInGaN nLEDs\u7684\u5236\u9020\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-241000\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-7-9.png\" alt=\"\" width=\"1246\" height=\"649\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-7-9.png 1246w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-7-9-300x156.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-7-9-768x400.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-7-9-1024x533.png 1024w\" sizes=\"(max-width: 1246px) 100vw, 1246px\" \/><\/p>\n<p><strong><b>\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/b><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>\u4f4e\u6e29\u6eb6\u80f6-\u51dd\u80f6\u5de5\u827a\u53ef\u4ee5\u6700\u5927\u7a0b\u5ea6\u5730\u51cf\u5c11\u8868\u9762\u949d\u5316\u8fc7\u7a0b\u4e2d\u7f3a\u9677\u7684\u5f62\u6210\uff0c\u5b9e\u73b0\u5cf0\u503cEQE\u4e3a2\u00b10.6%\u7684\u84dd\u8272InGaN<\/b><\/strong><strong><b>n-LED<\/b><\/strong><\/li>\n<\/ul>\n<p><strong><b>\u56db\u3001<\/b><\/strong><strong><b>\u3010\u6570\u636e\u6982\u89c8\u3011<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-240996\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-1-12.png\" alt=\"\" width=\"1437\" height=\"737\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-1-12.png 1437w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-1-12-300x154.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-1-12-768x394.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-1-12-1024x525.png 1024w\" sizes=\"(max-width: 1437px) 100vw, 1437px\" \/><\/p>\n<p><strong><b>\u56fe1<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>nLED\u7684\u5236\u5907\u53ca\u5176\u5149\u5b66\u7279\u6027 <\/b><\/strong><strong><b>\u00a9 2022 S<\/b><\/strong><strong><b>p<\/b><\/strong><strong><b>ringer Nature<\/b><\/strong><\/p>\n<p>\u00a0(a-c) \u901a\u8fc7\u4f20\u7edf\u7684\u81ea\u4e0a\u800c\u4e0b\u7684\u5904\u7406\u65b9\u6cd5\u5236\u9020\u7684nLED\u7684\u539f\u7406\u56fe\u548c\u76f8\u5e94\u7684SEM\u56fe\u50cf\u3002\u5e72\u6cd5\u8680\u523b\uff08a\uff09\uff0c\u6e7f\u6cd5\u8680\u523b\uff08b\uff09\u548c(c) \u6eb6\u80f6-\u51dd\u80f6\u6cd5\u6c89\u79efSiO<sub>2<\/sub>\u8868\u9762\u949d\u5316\u5c42<\/p>\n<p>\u63d2\u56fe\u662fGaN LED\u7eb3\u7c73\u68d2\u4e0a\u6eb6\u80f6-\u51dd\u80f6\u53cd\u5e94\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p>(d) PL\u56fe\u50cf\uff08\u9876\u90e8;\u84dd\u8272\u548c\u9ec4\u8272\u53d1\u5c04\u5171\u540c\u663e\u793a\uff09\u548c\u8367\u5149\u6fc0\u53d1 &#8211; \u53d1\u5c04\u5149\u8c31\uff08\u5e95\u90e8\uff09\u7684\u7eb3\u7c73\u68d2\u4e0e\u7b49\u79bb\u5b50\u4f53\u589e\u5f3a\u7684ALD SiO<sub>2<\/sub>\u949d\u5316\uff08\u5de6\uff09\u548c\u6eb6\u80f6-\u51dd\u80f6 SiO2\u949d\u5316\uff08\u53f3\uff09\u3002<\/p>\n<p>(e) \u6676\u5706\u4e0a\uff0c\u7b49\u79bb\u5b50\u4f53\u589e\u5f3aALD\u5236\u9020\u7684 SiO<sub>2<\/sub>\u548c\u6eb6\u80f6-\u51dd\u80f6 SiO<sub>2<\/sub>\u949d\u5316\u5c42\uff08\u53f3\uff09\uff08<em>\u03bb<\/em>\u00a0= 300\u2013700 nm\uff09\u7684\u4e9a\u5fae\u7c73LED\u68d2\u9635\u5217\u7684\u5168\u8272CL\u56fe\u50cf<\/p>\n<p>(f, g) PL\u5149\u8c31\uff08f\uff09\u548cPL\u8870\u53d8\u8ff9\u7ebf\uff08g\uff09<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-240997\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-2-11.png\" alt=\"\" width=\"1254\" height=\"643\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-2-11.png 1254w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-2-11-300x154.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-2-11-768x394.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-2-11-1024x525.png 1024w\" sizes=\"(max-width: 1254px) 100vw, 1254px\" \/><\/p>\n<p><strong><b>\u56fe2\u7b49\u79bb\u5b50\u4f53\u589e\u5f3aA<\/b><\/strong><strong><b>LD<\/b><\/strong><strong><b>\u548c\u6eb6\u80f6-\u51dd\u80f6\u4e24\u79cdSiO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u8868\u9762\u949d\u5316\u6cd5\u5bf9\u5e94\u7684\u7535\u6d41\u5bc6\u5ea6-\u7535\u538b\u66f2\u7ebf<\/b><\/strong><\/p>\n<p><strong><b>\u00a9 2022 S<\/b><\/strong><strong><b>p<\/b><\/strong><strong><b>ringer Nature<\/b><\/strong><\/p>\n<p>(a) \u57fa\u4e8e\u949d\u5316\u7c7b\u578b\u7684\u50cf\u7d20\u5185\u5355\u4e2a\u7eb3\u7c73\u68d2\u7684EL\u548cPL\u590d\u5408\u56fe\u50cf\uff1a\u7b49\u79bb\u5b50\u4f53\u589e\u5f3a\u7684ALD SiO<sub>2<\/sub>\uff08\u5de6\uff09\u548c\u6eb6\u80f6-\u51dd\u80f6 SiO<sub>2<\/sub>\uff08\u53f3\uff09\u3002<\/p>\n<p>(b) \u56fe2a\u4e2d\u6c34\u5e73\u65b9\u5411\u4e0aMQW\u7684EL\u5f3a\u5ea6\u5206\u5e03\uff0c\u7528\u653e\u7f6e\u5728\u7eb3\u7c73\u68d2\u6b63\u4e0a\u65b9\u7684\u5171\u805a\u7126\u663e\u5fae\u955c\u6d4b\u91cf\u3002<\/p>\n<p>(c)\u00a0nLED\u7684EQE\u66f2\u7ebf<\/p>\n<p>(d, e) nLED\u5728\u7ebf\u6027\u523b\u5ea6\uff08d\uff09\u548c\u5bf9\u6570\u523b\u5ea6\uff08e\uff09\u4e2d\u7684\u7535\u6d41\u5bc6\u5ea6-\u7535\u538b\uff08J-V\uff09\u7279\u6027\u3002<\/p>\n<p>(f) \u4ece2.5 V\u65f6\u7684J-V\u66f2\u7ebf\u83b7\u5f97\u7684\u7406\u60f3\u7cfb\u6570<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-240998\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-3-10.png\" alt=\"\" width=\"1265\" height=\"586\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-3-10.png 1265w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-3-10-300x139.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-3-10-768x356.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-3-10-1024x474.png 1024w\" sizes=\"(max-width: 1265px) 100vw, 1265px\" \/><\/p>\n<p><strong><b>\u56fe3<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u6bcf\u4e2a\u5236\u9020\u6b65\u9aa4\u540enLED\u7684\u8868\u9762\u5206\u6790 <\/b><\/strong><strong><b>\u00a9 2022 S<\/b><\/strong><strong><b>p<\/b><\/strong><strong><b>ringer Nature<\/b><\/strong><\/p>\n<p>(a) HAADF-STEM\u56fe\u50cf\u6839\u636e\u5236\u9020\u6b65\u9aa4\u5728MQW\u4e2d\u4fa7\u58c1\u3002\u767d\u8272\u7bad\u5934\u8868\u793a\u5e72\u8680\u523b\u8868\u9762\u7684\u975e\u6676\u5316\u3002\u9ec4\u8272\u7bad\u5934\u8868\u793a\u7b49\u79bb\u5b50\u4f53\u635f\u4f24\u96c6\u4e2d\u5728InGaN\u91cf\u5b50\u9631\u7684\u4fa7\u58c1\u4e0a\u3002<\/p>\n<p>(b)\u00a02 nm\u539aSiO<sub>2<\/sub>\u7684nLED\u7684XPS\u5185\u6838\u7ea7\u5149\u8c312\u6d82\u5c42\uff1aGa 3d\uff08\u5de6\uff09\u548cN 1s\uff08\u53f3\uff09\u3002<\/p>\n<p>(c)\u4eceXPS\u5149\u8c31\u83b7\u5f97\u7684Ga 3d\u72b6\u6001\u6bd4\u3002<\/p>\n<p>(d)\u6bcf\u4e2a\u5236\u9020\u6b65\u9aa4\u540e\u7eb3\u7c73\u68d2\u7684ESR\u5149\u8c31\u3002<\/p>\n<p>(e) N-N\u57fa\u4e8eESR\u5149\u8c31\u5206\u88c2\u7eb3\u7c73\u68d2\u7684\u95f4\u9699\u3002<\/p>\n<p><strong><b>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-240999\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-4-8.png\" alt=\"\" width=\"1078\" height=\"555\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-4-8.png 1078w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-4-8-300x154.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-4-8-768x395.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2022\/08\/\u56fe\u7247-4-8-1024x527.png 1024w\" sizes=\"(max-width: 1078px) 100vw, 1078px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe4<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u91c7\u7528\u4e0d\u540c\u949d\u5316\u65b9\u6cd5\u5236\u5907\u7684InGaN\u91cf\u5b50\u9631\u4fa7\u58c1\u7f3a\u9677 <\/b><\/strong><strong><b>\u00a9 2022 S<\/b><\/strong><strong><b>p<\/b><\/strong><strong><b>ringer Nature<\/b><\/strong><\/p>\n<p>(a) InGaN\u91cf\u5b50\u9631\u7684\u9ad8\u5206\u8fa8\u7387STEM\u56fe\u50cf (b)N-K\u8fb9\u5149\u8c31a\u56fe\u4e2d\u6240\u793a\u533a\u57df\uff0c\u53ca\u5176DFT\u8ba1\u7b97\u3002<\/p>\n<p><strong><b>\u4e94\u3001<\/b><\/strong><strong><b>\u3010\u6210\u679c\u542f\u793a\u3011<\/b><\/strong><\/p>\n<p>\u7814\u7a76\u8005\u901a\u8fc7\u6eb6\u80f6-\u51dd\u80f6\u6c89\u79efSiO<sub>2<\/sub>\u949d\u5316\u7b56\u7565\u5f00\u53d1\u4e86EQE\u8fbe\u523020.2\u00b10.6%\u7684\u84dd\u8272InGaN nLED\u3002\u7ed3\u679c\u8868\u660e\uff0c\u901a\u8fc7\u5e38\u89c4\u7b49\u79bb\u5b50\u4f53\u589e\u5f3a\u7684\u539f\u5b50\u5c42\u6c89\u79efSiO<sub>2<\/sub>\u8fdb\u884c\u949d\u5316\u7684GaN\u7eb3\u7c73\u68d2\u7684\u4fa7\u58c1\u4e0a\u4f1a\u4ea7\u751f\u70b9\u7f3a\u9677\uff0c\u4ece\u800c\u589e\u52a0\u975e\u8f90\u5c04\u590d\u5408\u533a\u57df\u3002\u800c\u6eb6\u80f6-\u51dd\u80f6\u5de5\u827a\u4e3aGaN\u8868\u9762\u63d0\u4f9b\u6709\u6548\u7684\u949d\u5316\uff0c\u964d\u4f4e\u4e86\u6f0f\u7535\u6d41\uff0c\u5b9e\u73b0\u4e86\u9ad8\u7684EQE\u3002<\/p>\n<p><strong><b>\u539f\u6587\u8be6\u60c5\uff1a<\/b><\/strong><a href=\"https:\/\/www.nature.com\/articles\/s41586-022-04933-5\"><u>https:\/\/www.nature.com\/articles\/s41586-022-04933-5<\/u><\/a>\u00a0<\/p>\n<p><strong><b>\u00a0\u672c\u6587\u7531\u91d1\u4e5f\u4f9b\u7a3f\u3002<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u5bfc\u8bfb\u3011 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